Including Organic Agent Patents (Class 210/727)
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Patent number: 8147695Abstract: A process for removing phosphorus from wastewater wherein an iron or aluminum salt is added to the wastewater. The iron or aluminum salt results in the precipitation of certain iron or aluminum species that include phosphorus adsorption sites. These iron or phosphorus species are settled and become a part of sludge produced in the course of the wastewater treatment process. By recycling substantial portions of the sludge, the concentration of these iron or aluminum species in the wastewater is increased. This increased concentration results in the presence of large quantities of unused phosphorus adsorption sites that attract and adsorb phosphorus, resulting in phosphorus being removed from the wastewater.Type: GrantFiled: October 26, 2010Date of Patent: April 3, 2012Assignee: I. Kruger Inc.Inventors: Kashi Banerjee, Charles D. Blumenschein, John Charles Schrader
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Patent number: 8147651Abstract: Methods to control and suppress odor in papermaking sludge are described. One method involves admixing sludge from a papermaking process and cyclodextrin to provide treated sludge with the cyclodextrin present in an effective amount to control odors in the treated sludge. The deodorized sludge may be used as a component of resin-wood composite products, such as composite decking materials, walls, flooring, casting forms, and the like.Type: GrantFiled: June 27, 2008Date of Patent: April 3, 2012Assignee: Buckman Laboratories International, Inc.Inventors: Gerald M. Dykstra, James N. Graham, Scott D. Branum
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Patent number: 8147696Abstract: A method for purifying a water process stream whereby a precipitating agent is added to the water process stream to elevate the process stream pH to at least 10.5 to drop out precipitates which form separated solids comprising at least one of calcium precipitate, magnesium precipitate, barium precipitate, strontium precipitate, and silica precipitate. The separated solids are then coagulated and removed from the water process stream so as to yield a purified water process stream.Type: GrantFiled: September 19, 2006Date of Patent: April 3, 2012Inventor: Ken V. Pandya
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Patent number: 8147703Abstract: The invention relates to a method for processing sludge, comprising the addition of a lime-based basic agent to a sludge having a first pH value in order to raise the pH to a second value higher than the first one, adding at least one anionic organic flocculating agent that is active at said second pH value, flocculating the sludge, and separating the flocculated sludge between dehydrated sludge and a liquid phase, wherein the sludge to be dehydrated has a first above-mentioned pH value lower than 9, while the lime-based basic agent induces said pH raise to said above-mentioned second value within less than 5 minutes. The invention also relates to a composition for implementing said processing.Type: GrantFiled: November 13, 2007Date of Patent: April 3, 2012Assignee: S.A. Lhoist Recherche et DeveloppementInventor: Marc Joseph Henri Remy
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Patent number: 8137566Abstract: A method of treating tailings comprising a solids fraction and a hydrocarbon fraction is disclosed. A primary flow is supplied to a jet pump, the primary flow comprising water and less than 20% solids by mass. A secondary flow is supplied to a mixing chamber of the jet pump, the secondary flow comprising a slurry of water and tailings, the slurry comprising more solids by mass than the primary flow. The jet pump is operated using the primary flow such that the tailings are agitated to effect at least a partial phase separation of the hydrocarbon fraction from the tailings. The methods disclosed herein may also be applied to treat tailings ponds.Type: GrantFiled: June 13, 2008Date of Patent: March 20, 2012Assignee: RJ Oil Sands Inc.Inventors: Wade Ralph Bozak, Michael A. Kessick, Roderick Michael Facey
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Patent number: 8119011Abstract: Substitution of a single Ga-atom or single Ge-atom (GaAl12 and GeAl12 respectively) into the center of an aluminum Keggin polycation (Al13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl12 consistently shows ˜1 order of magnitude increase in pathogen reduction, compared to Al13. At a concentration of 2 ppm, GaAl12 performs equivalently to 40 ppm alum, removing ˜90% of the dissolved organic material. The substituted GaAl12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO4Al12(OH)24(H2O)12]7+.Type: GrantFiled: February 11, 2009Date of Patent: February 21, 2012Assignee: Sandia CorporationInventors: May D. Nyman, Thomas A. Stewart
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Patent number: 8101086Abstract: A process for the separation of production fluids is provided. The production fluids comprise an oil/water emulsion stabilized with fine solids. The emulsion may further comprise asphaltenes and naphthenic acids and resins. The process includes subjecting the emulsion to a flocculating agent to flocculate solids within the emulsion, and separating water and solids from crude oil in a first separator. The process further includes subjecting the separated crude oil to a demulsifier after subjecting the emulsion to a flocculating agent, and further separating water from the crude oil in a second separator. A process for producing fluids from a hydrocarbon-bearing reservoir is also provided, using the separation processes herein.Type: GrantFiled: June 14, 2007Date of Patent: January 24, 2012Assignee: ExxonMobil Upstream Research CompanyInventors: Ramesh Varadaraj, Lee A. Littlejohn
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Patent number: 8101085Abstract: Described is a process for treating an animal husbandry effluent slurry, such as hog manure, containing suspended solid particles. The process includes a) providing a liquid portion of the effluent, b) diluting the liquid to a Newtonian fluid, c) assuring the pH is under 10, d) adding to the fluid i) a soluble salt of alkaline earth metal (e.g. CaCl2) and ii) an insoluble basic salt of the same alkaline earth metal (e.g. CaCO3) to balance available cations and promote agglomeration of the suspended solid particles, e) adding a cationic coagulant to obtain a pre-treated destabilized colloid mixture with zero zeta potential value, and f) performing electroflotation to obtain a treated liquid and floated solids.Type: GrantFiled: May 8, 2008Date of Patent: January 24, 2012Assignee: Agriculture and Agri-Food CanadaInventors: Simon Guertin, Daniel Massé, François Lamarche
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Patent number: 8097167Abstract: The present invention relates to a process of concentrating an aqueous suspension of solid particles comprising the steps of adding at least one organic polymeric flocculant to the suspension thereby forming flocculated solids in which the flocculated solids are allowed form a layer of solids and thereby forming a more concentrated suspension in which the process comprises the addition of an effective amount of an agent that is selected from the group consisting of free radical agents, oxidising agents, enzymes and radiation, in which the agent is applied to the suspension prior to or substantially simultaneously with adding the organic polymeric flocculant and/or the organic polymeric flocculant is added to the suspension in a vessel and the agent is applied to the suspension in the same vessel. The process is particularly suitable for solids liquid separation in which the flocculated solids are allowed to settle by sedimentation in a gravity thickener.Type: GrantFiled: January 4, 2007Date of Patent: January 17, 2012Assignee: BASF SEInventors: Gillian Moody, Anthony Allen, Stephen Adkins, Brian Dymond, Paul Stocks
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Patent number: 8092688Abstract: A method for treating water in a ballasted flocculation system comprises directing water into a ballasted flocculation zone and adding ballast and a flocculation reagent to the water to form a water-floc mixture. The water-floc mixture is directed into a settling zone to form treated water and sludge containing ballast. The ballast is then directed to a recirculation line where the ballast is recirculated to the ballasted flocculation zone. The method further includes determining the ballast concentration and comparing the ballast concentration with a predetermined threshold value. The rate at which ballast is recirculated to the ballasted flocculation zone is adjusted based on the determined ballast concentration and the predetermined threshold value.Type: GrantFiled: July 25, 2007Date of Patent: January 10, 2012Assignee: OTV SAInventors: Philippe Sauvignet, Jean-Francois Beaudet, Sonia Guillot, Valery Ursel
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Patent number: 8062529Abstract: A method for treating water includes directing untreated water into a mixing zone in a water treatment system and mixing the untreated water with a flocculating agent and a ballast to form a ballast-floc mixture. Thereafter, the ballast-floc mixture is directed to a settling zone where the mixture settles to form sludge. Treated water is discharged from the settling zone and the sludge is directed to a separator. The method further includes separating at least a portion of the ballast from the sludge and directing the separated ballast from the separator to the mixing zone. Finally, the sludge is directed from the separator to a sludge treatment reactor where at least some of the remaining ballast settles from the sludge and substantially ballast-free sludge is discharged from the sludge treatment reactor.Type: GrantFiled: February 19, 2007Date of Patent: November 22, 2011Assignee: OTV SAInventor: Philippe Sauvignet
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Publication number: 20110272362Abstract: Oily and/or solids-containing water is clarified by chemical treatment to form flocculated and agglomerated solid phases and a clear water phase. In the clarification process, microbubbles of air or other gas are introduced at atmospheric pressure, via an eductor or other suitable device, together with a flocculant. During the subsequent formation of floes and their agglomeration into larger masses, microbubbles become entrained within and adhered to the solid flocculated materials. The resulting masses are very buoyant and easily separated from the water via a variety of approaches that include skimming, decanting, filtration, and screening. This process results in a solids phase that may be disposed of as waste, if desired, and a highly clarified water phase.Type: ApplicationFiled: July 23, 2009Publication date: November 10, 2011Inventors: C. Steven Sikes, T. Daniel Sikes, Mark A. Hochwalt
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Patent number: 8021556Abstract: A method is provided for clarifying wastewater containing contaminants including soluble organic compounds and insoluble organic compounds. The wastewater is treated with a paculant admixture including a cationic coagulant polymer and powdered activated carbon. The cationic coagulant polymer is polydiallydimethylammonium chloride, poly quaternary amine, and/or a starch-based organic polymer. After an at least 2 second delay, a flocculent is added to the wastewater to achieve (i) microcoagulation of the cationic coagulant polymer with the contaminants to form coagulated particles having an effective mass and cationic charge to react with an anionic flocculent to be added thereafter, and (ii) absorption of the soluble organic compounds on the powdered activated carbon. The anionic flocculent as added and reacted with the coagulated particles to form a sludge, containing agglomerated particles including the coagulated particles and powdered activated carbon, of sufficient size for mechanical removal.Type: GrantFiled: January 9, 2007Date of Patent: September 20, 2011Inventors: Stuart G. Davis, Robert A. Davis
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Patent number: 8017018Abstract: A phosphorus removal system is operable to remove phosphorus from an influent. The system includes a first section receiving the influent and discharging a first flow. A first coagulant inlet is positioned upstream of the first section and is in fluid communication with the influent to introduce a first coagulant selected to precipitate phosphorus. A second section receives the first flow and discharges a second flow, and a third section receives the second flow and discharges an effluent. A second coagulant inlet is positioned downstream of the first section and upstream of the third section to introduce a second coagulant selected to precipitate phosphorus.Type: GrantFiled: November 5, 2009Date of Patent: September 13, 2011Assignee: Siemens Industry, Inc.Inventors: Eric Allen Lawrence, Joseph E. Zuback
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Patent number: 8012358Abstract: A system is provided that includes: (a) a mobile platform; (b) an input pump operatively connected to be capable of pumping a treatment stream through the system; (c) a centrifugal separator operatively connected downstream of the input pump to centrifugally treat the treatment stream; (d) a borate filter operatively connected downstream of the centrifugal separator to filter the treatment stream capable of removing at least some of a borate when the treatment stream is at a pH of 8 or above; and (e) a chemical-additive subsystem operatively connected to be capable of: (i) selectively adding one or more chemical agents to the treatment stream upstream of the centrifugal separator, wherein the chemical agents can be selected to be capable of precipitating dissolved ions selected from the group consisting of: sulfate, calcium, strontium, or barium, magnesium, iron; and (ii) selectively adding a chemical agent to the treatment stream upstream of the borate filter to increase the pH of the treatment stream to 8 oType: GrantFiled: August 26, 2010Date of Patent: September 6, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Billy F. Slabaugh, Arron L. Karcher, Michael J. R. Segura, Randy S. Rosine, Max L. Phillippi, Donna L. Harris
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Patent number: 7998439Abstract: A separation and recycling method for recycling uranium and fluoride from a waste liquid sequentially and separately is disclosed. The method comprises a uranium-recycling process and a fluoride-recycling process. In the uranium-recycling process, an alkali metal compound or monovalent cation and a coagulant aid are added into the waste liquid to promote the precipitation of uranium. In the fluoride-recycling process, an alkaline earth metal compound, a strong acid and a coagulant aid are added into the uranium-removed waste liquid to precipitate fluoride. By means of the method of the present invention, the uranium and fluoride contents of the uranium-removed and fluoride-removed waste liquid are compliant with the effluent standards of the environmental laws.Type: GrantFiled: December 29, 2009Date of Patent: August 16, 2011Assignee: Institute of Nuclear Energy ResearchInventors: Chen-Te Lin, Kuo-Hao Tsao, Ben-Li Pen
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Patent number: 7988867Abstract: A method of treating silicon powder-containing drainage water, comprising the steps of: including an inorganic flocculant composed of a silica sol-water-soluble metal salt having a molar ratio of silicon to metal of 0.05 to 3.0 into drainage water containing silicon powders to ensure that the metal concentration becomes 15 to 300 mg/L; and adding an organic polymer flocculant. In this method, the coagulation treatment of drainage water containing fine silicon powders can be carried out.Type: GrantFiled: August 17, 2006Date of Patent: August 2, 2011Assignee: Tokuyama CorporationInventors: Shinji Tokunaga, Yoshiaki Koga, Toshihiko Inoue
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Patent number: 7988866Abstract: In a process for treatment of powdery fumed silica, fumed silica to be discarded is collected by dispersing the fumed silica in water. Disclosed is a method for treatment of a fumed silica-containing wastewater collected in the process. The method comprises the steps of: adding an inorganic coagulant containing a metal to a fumed silica-containing wastewater in an amount of 15 to 300 mg/l. in terms of the metal, wherein the wastewater is either a wastewater containing fumed silica at a concentration of 0.05 to 3.0% by mass or a wastewater whose fumed silica content is adjusted to 0.05 to 3.0% by mass; and adding an organic polymeric coagulant to the mixture.Type: GrantFiled: August 17, 2006Date of Patent: August 2, 2011Assignee: Tokuyama CorporationInventors: Shinji Tokunaga, Yoshiaki Koga, Toshihiko Inoue
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Patent number: 7981297Abstract: A method for removing helminth egg and other suspended solids from a wastewater stream includes directing the wastewater to a ballasted flocculation system and adding a coagulation agent, flocculation agent and a ballast into the wastewater. Sludge is settled from the wastewater in a settling tank at a rate of at least 10 meters per hour. The method further includes removing helminth egg by filtering the effluent through a fine screen having a mesh diameter of approximately 5 micrometers to approximately 25 micrometers. After passing through the fine screen, the filtered effluent has less than one helminth egg per liter.Type: GrantFiled: November 2, 2006Date of Patent: July 19, 2011Assignee: OTV SAInventors: Philippe Sauvignet, Claus Poulsen Dahl
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Patent number: 7972517Abstract: A method for treating a portion of liquid waste manure comprising adding a first reagent to the portion in a first vessel to cause the formation of waste manure flocs of a first size; adding a second reagent to liquid portion to cause growth of the waste manure flocs of the first size into separable waste manure flocs; adding optionally a third reagent to the portion of liquid containing waste manure flocs to cause further growth of the separable waste manure flocs; separating the liquid volume containing separable waste manure flocs into a waste manure sludge and a first filtrate; and dewatering the waste manure sludge in a filtration system comprising a first filter including a first housing, a first displaceable filter medium, and a first displacement actuator disposed between the first housing and the first displaceable filter medium.Type: GrantFiled: February 22, 2008Date of Patent: July 5, 2011Assignee: Innovative environmental Products, Inc.Inventor: Francis C. Miller
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Patent number: 7967988Abstract: A method and a apparatus for treating a liquid volume containing latex waste, the method comprising providing a treatment apparatus comprising at least a first vessel, and a filtration system in liquid communication with the first vessel; delivering a portion of the liquid containing waste latex to the first vessel; adding a first reagent to the portion of liquid containing waste latex to cause the formation of waste latex flocs of a first size; adding a second reagent to the portion of liquid containing waste latex to cause growth of the waste latex flocs of the first size into separable waste latex flocs; separating the separable waste latex flocs within the filtration system into a waste latex sludge and a first filtrate; and dewatering the waste latex sludge to produce a waste latex solid and a second filtrate. The filtrates may be reusable in a latex manufacturing process.Type: GrantFiled: January 2, 2008Date of Patent: June 28, 2011Assignee: Innovative Environmental Products, Inc.Inventor: Francis C. Miller
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Patent number: 7892437Abstract: A method of managing water is provided, in which the water is discharged from an aggregate plant, and therefore contains a large number of fines. The water is first passed through a mesh screen to remove large particles and then collected in a sump. From the sump the water is pumped to a centrifugal cyclone, where some of the fines are separated from the water. Flocculent is then applied to the water, before the water is collected in a pond.Type: GrantFiled: March 28, 2008Date of Patent: February 22, 2011Assignee: Allard Contractors Ltd.Inventors: Barry Allard, James Allard
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Publication number: 20110024358Abstract: A process removes boron from ion exchange system regeneration solution including introducing a borate precipitator into the regeneration solution in a precipitation zone to generate borate precipitate; introducing a coagulator into the regeneration solution that coagulates solids and/or borate precipitate generated by the borate precipitator and absorbs boron into the solids; introducing the regeneration solution, solids and borate precipitate into a separation zone; introducing anionic polymer into the regeneration solution adjacent to or in the separation zone to increase the propensity of borate precipitate and solids to separate from the regeneration solution; and filtering the regeneration solution to remove residual suspended solids from the regeneration solution.Type: ApplicationFiled: July 30, 2009Publication date: February 3, 2011Applicant: INFILCO DEGREMONT, INC.Inventor: Michael L. Pudvay
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Publication number: 20110006013Abstract: A method for removing submicron colloidal particulates, such as hydrocarbons, from water. The method includes first adding a soluble, cationic polymer, such as chitosan, a salt, or solution of chitosan to water containing the submicron particulates and a halogenating agent, followed by adding a soluble, anionic polymer or anionic salt to the water. The resulting flocs are filtered to remove the submicron particulates.Type: ApplicationFiled: September 3, 2010Publication date: January 13, 2011Applicant: HALOSOURCE, INC.Inventors: Everett J. Nichols, Jeffrey F. Williams, James R. Scott, Christine M. Palczewski
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Patent number: 7867400Abstract: A process of separating suspended solids from a fermentation liquor by subjecting the liquor to a solids-liquid separation stage, wherein the fermentation liquor is produced in a fermentation process for the production of a fermentation product, and which liquor comprises lignin, wherein the solids-liquid separation stage is assisted by a treatment system, characterised in that the treatment system comprises an anionic polymer, with the proviso that the treatment system and does not include a cationic polymer having an intrinsic viscosity (IV) of at least 4 dl/g.Type: GrantFiled: September 11, 2009Date of Patent: January 11, 2011Assignee: Ciba Speacialty Chemicals Water treaments Ltd.Inventors: Jonathan Hughes, Rajesh Mistry, Kenneth Charles Symes
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Patent number: 7828976Abstract: A process for removing phosphorus from wastewater wherein an iron or aluminum salt is added to the wastewater. The iron or aluminum salt results in the precipitation of certain iron or aluminum species that include phosphorus adsorption sites. These iron or phosphorus species are settled and become a part of sludge produced in the course of the wastewater treatment process. By recycling substantial portions of the sludge, the concentration of these iron or aluminum species in the wastewater is increased. This increased concentration results in the presence of large quantities of unused phosphorus adsorption sites that attract and adsorb phosphorus, resulting in phosphorus being removed from the wastewater.Type: GrantFiled: June 22, 2007Date of Patent: November 9, 2010Assignee: I. Kruger, Inc.Inventors: Kashi Banerjee, Charles D. Blumenschein, John Charles Schrader
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Patent number: 7824552Abstract: A system is provided that includes: (a) a mobile platform; (b) an input pump operatively connected to be capable of pumping a treatment stream through the system; (c) a centrifugal separator operatively connected downstream of the input pump to centrifugally treat the treatment stream; (d) a borate filter operatively connected downstream of the centrifugal separator to filter the treatment stream capable of removing at least some of a borate when the treatment stream is at a pH of 8 or above; and (e) a chemical-additive subsystem operatively connected to be capable of: (i) selectively adding one or more chemical agents to the treatment stream upstream of the centrifugal separator, wherein the chemical agents can be selected to be capable of precipitating dissolved ions selected from the group consisting of: sulfate, calcium, strontium, or barium, magnesium, iron; and (ii) selectively adding a chemical agent to the treatment stream upstream of the borate filter to increase the pH of the treatment stream to 8 oType: GrantFiled: September 5, 2007Date of Patent: November 2, 2010Assignee: Halliburton Energy Services, Inc.Inventors: Billy F. Slabaugh, Arron L. Karcher, Michael J. R. Segura, Randy S. Rosine, Max L. Phillippi, Donna L. Harris
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Patent number: 7824553Abstract: The present invention provides a process for dewatering a mineral slurry concentrate and increasing the production of the resulting filter cake consisting essentially of mixing an aqueous mineral slurry concentrate with an effective amount of a nonionic surfactant and an effective amount of a cationic polymer to form a nonionic surfactant and cationic polymer treated aqueous mineral slurry concentrate, and subjecting the treated aqueous mineral slurry concentrate to a liquid water removal process for dewatering the treated aqueous mineral slurry and for increasing the production of a resulting filter cake of the dewatered mineral slurry. An improved mineral slurry concentrate composition and an improved mineral concentrate filter cake is also disclosed.Type: GrantFiled: July 24, 2007Date of Patent: November 2, 2010Assignee: Neo Solutions, Inc.Inventors: Keith C. Hovland, Todd W. Groff, Monica A. Yorke, Charles R. Sundberg, Michael P. Lesar, Ruta O. Rakutis
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Patent number: 7820057Abstract: The invention relates to a method for removing at least one constituent from a solution, comprising:—forming a liquid mixture by bringing together said solution (1) and a particulate seed material (6) under conditions or in the presence of one or more substances which cause the constituent to be removed to crystallize out on the surface of the seed material; and—separating the seed material having the constituent to be removed crystallized out thereon from the liquid mixture by passing the liquid mixture through a filter (3), wherein the pore size of the filter (3) is greater than or equal to the particle size of the seed material (6). The invention also relates to a method for preparing a particulate material wherein use is made of the method according to the present invention. The invention also relates to the particulate material obtainable by this method. The invention further relates to an apparatus that can be used in the process of the present invention.Type: GrantFiled: October 8, 2004Date of Patent: October 26, 2010Assignee: Nederlandse Organisatie voor toegepastnatuurwetenschappelijk Onderzoek TNOInventors: Dirk Verdoes, Johannes van der Meer, Earl Lawrence Vincent Goetheer
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Patent number: 7820058Abstract: A new method of improving the process of dewatering fine particulate materials is disclosed. In this method, an aqueous slurry of fine particles is treated with appropriate hydrophobizing reagents so that the particulate material becomes moderately hydrophobic with its water contact angle considerably below 90°. A low hydrophile-lipophile balance (HLB) number surfactant is then added to the slurry, so that the surfactant molecules adsorb on the moderately hydrophobic surface primarily by hydrophobic attraction and, thereby, increase its contact angle close to or above 90°. By virtue of the greatly enhanced hydrophobicity, the water molecules adhering to the surface are destabilized and removed more readily by a mechanical dewatering process. Any nonionic surfactant with its HLB number below about 15 may be used for the hydrophobicity enhancement. The surfactants may be used in conjunction with appropriate solvents such as light hydrocarbon oils and short-chain alcohols.Type: GrantFiled: August 3, 2007Date of Patent: October 26, 2010Assignee: Mineral and Coal Technologies, Inc.Inventor: Roe Hoan Yoon
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Patent number: 7815804Abstract: A method or process for treating wastewater containing high organics, silica, boron, hardness, and suspended and dissolved solids. The method includes degasifying the wastewater for the removal of dissolved gases and thereafter chemically softening the wastewater. After the chemical softening step, the wastewater is directed through a media filter or membrane which removes additional solids and precipitants. Thereafter the wastewater is directed through a sodium ion exchange that further softens the wastewater. The effluent from the ion exchange is directed through a cartridge filter and the effluent from the cartridge filter is directed through one or more reverse osmosis units. At a selected phase of the process, prior to the wastewater reaching the reverse osmosis unit or units, the pH of the wastewater is raised and maintained such that the pH of the wastewater reaching a reverse osmosis unit is at a pH greater than 10.5.Type: GrantFiled: December 12, 2006Date of Patent: October 19, 2010Assignee: OTV SA S.A.Inventor: LNSP Nagghappan
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Patent number: 7811458Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: GrantFiled: June 4, 2009Date of Patent: October 12, 2010Assignees: Stockhausen GmbH & Co. KG, Detlef Hegeman GmbH & Co. KGInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
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Patent number: 7790042Abstract: A method for removing submicron colloidal particulates, such as hydrocarbons, from water. The method includes first adding a soluble, cationic polymer, such as chitosan, a salt, or solution of chitosan to water containing the submicron particulates and a halogenating agent, followed by adding a soluble, anionic polymer or anionic salt to the water. The resulting flocs are filtered to remove the submicron particulates.Type: GrantFiled: February 15, 2006Date of Patent: September 7, 2010Assignee: HaloSource, Inc.Inventors: Everett J. Nichols, Jeffrey F. Williams, James R. Scott, Christine M. Palczewski
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Patent number: 7758758Abstract: A method for removing metals from metal-containing acidic mine wastewater uses a basic sludge produced by the method for treating the wastewater. The wastewater is mixed with a lime slurry and with the basic sludge. This mixture is allowed to separate into an aqueous effluent and an acidic sludge. The effluent is mixed with the lime slurry and with a composition containing an iron compound, to produce a mixture. This mixture is allowed to separate into an aqueous effluent and the basic sludge. Lignin derivatives, such as calcium lignosulfonate, may be included in the treatment mixture.Type: GrantFiled: February 28, 2007Date of Patent: July 20, 2010Assignee: Noram Engineering and Constructors Ltd.Inventors: J. Ming Zhuang, Anthony S. Walsh
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Patent number: 7754087Abstract: A process of dewatering aqueous suspension employing a flocculating system comprising treating the suspension with a flocculating amount of a first flocculant and a dewatering amount of a second flocculant, and subjecting the suspension to mechanical dewatering to form a cake, wherein the first flocculant brings about flocculation and assists thickening of the suspension and the second flocculant is a water-soluble or water swellable polymer that is mixed into the suspension is a water-soluble or water swellable particulate polymer having a particle diameter of at least 20 microns.Type: GrantFiled: February 28, 2005Date of Patent: July 13, 2010Assignee: Ciba Specialty Chemicals Water Treatments, LTDInventors: Tony Whittaker, Peter Norman, Darryl Smith
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Patent number: 7754086Abstract: A process of dewatering an aqueous suspension comprising dosing the suspension with a flocculating amount of a first flocculant to form a thickened suspension and mixing into the thickened suspension a dewatering amount of a second flocculant and subjecting the thickened suspension to mechanical dewatering to form a cake, characterised in that the second flocculant comprises a water-soluble or water swellable polymer that is mixed into the suspension in the form of (i) substantially dry polymer particles or (ii) an aqueous composition comprising dissolved or hydrated polymer having a polymer concentration of at least 2% by weight and having a intrinsic viscosity of at least 3 dl/g.Type: GrantFiled: February 28, 2005Date of Patent: July 13, 2010Assignee: Ciba Specialty Chemicals Water Treatments Ltd.Inventors: Tony Whittaker, Peter Norman, Darryl Smith
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Patent number: 7749392Abstract: A process of dewatering an aqueous suspension employing a flocculating system comprising treating the suspension with a flocculating amount of a first flocculant and a dewatering amount of a second flocculant, and subjecting the suspension to mechanical dewatering to form a cake, wherein the first flocculant brings about flocculation and assists thickening of the suspension and the second flocculant further dewaters the suspension, characterized in that the second flocculant is a water-soluble or water swellable polymer that is mixed into the suspension in the form of aqueous composition comprising dissolved or hydrated polymer having a Brookfield viscosity of above 30,000 cps (measured at 20° C.).Type: GrantFiled: February 28, 2005Date of Patent: July 6, 2010Assignee: Ciba Specialty Chemicals Water Treatments LtdInventors: Tony Whittaker, Peter Norman, Darryl Smith
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Patent number: 7736515Abstract: There is provided a method for highly treating distillation waste generated in the process of separating a distilled alcoholic material after alcoholic fermentation of starchy materials. The method includes the steps of adding sodium polyacrylate to the distillation waste from the starchy materials, then adding chitosan to treat the distillation waste, and further adding sodium polyacrylate to the waste. Furthermore, solid-liquid separation is then carried out. A liquid material thus separated is brought into contact with a reverse osmosis membrane.Type: GrantFiled: January 17, 2008Date of Patent: June 15, 2010Assignees: Mitsubishi Gas Chemical Company, Inc., Dia Aqua Solutions Co., Inc.Inventors: Hiroshi Takamiya, Shoichiro Kajiwara, Koji Hirukawa, Kimihisa Iwashiro
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Patent number: 7727404Abstract: A method for removal of dissolved materials and/or particles from a liquid stream comprising flocculation by vigorously mixing polysaccharides or hydrocolloids into the liquid stream and subsequent gelation of the polysaccharides or hydrocolloids with cations capable of gelling same. Large, strong gelled agglomerates of pollutant and polysaccharide or hydrocolloid are formed with the help of suitable cations. The gelled agglomerates are well suited to separation from a liquid stream by flotation, in a sieve, in a centrifuge, in a cyclone or via other conventional separation processes. Also described is a method for mixing of un-dissolved polysaccharide or hydrocolloid with a polluted aqueous stream by shearing the polysaccharide or hydrocolloid into the aqueous stream to improve logistics and provide economic savings in treatment of large volumes of water. Also described is the use of dilute solutions of polysaccharides for treatment of a variety of effluent streams.Type: GrantFiled: March 30, 2007Date of Patent: June 1, 2010Assignee: Sorbwater Technology ASInventors: Atle Mundheim Ylikangas, Christian Klein Larsen
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Patent number: 7718075Abstract: Methods are provided for treating suspensions of particles to improve the drainage rate and/or the solids content of flocs of the particles. The method includes the steps of (i) providing a suspension which comprises particles in a fluid; (ii) adding a cyclodextrin compound to the suspension; and (iii) dewatering the suspension by removing at least a portion of the fluid to form a cake comprising the particles. The cyclodextrin compound desirably is added in an amount effective to increase the dewatering rate of the flocs, to increase the solids content, or both, over that rate, solids content, or both, that would be obtained without the addition of the cyclodextrin compound. The suspension may be, for example, a biological or non-biological sludge, or a suspension of pulp fibers, such as in a pulping or papermaking process.Type: GrantFiled: February 14, 2006Date of Patent: May 18, 2010Assignee: Georgia Tech Research CorporationInventor: Sujit Banerjee
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Patent number: 7704399Abstract: A system and method for the treatment of water for human consumption using a naturally occurring inorganic catalyst working within a pH range between 3 and 13, combining the inorganic catalyst at 3 parts per million to an oxidant, primarily hydrogen peroxide and a metal salt used as a coagulant and a primary catalyst, resulting in an efficient and economical phasic water purification and filtration system and process. The inorganic catalyst is a zeolite a synthetic zeolite or preferably chabazite.Type: GrantFiled: May 30, 2007Date of Patent: April 27, 2010Inventor: Randy Gene Condit
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Patent number: 7699991Abstract: A conditioning process and equipment are provided for removing hardness from water circulated in a system. A sidestream from such system is routed to a reaction chamber and back to the system. A conditioner is added to the sidestream water and in some embodiments is routed through a sidestream inlet from the top of the reaction chamber to its lower portion in a swirling motion. A buffer is added to the sidestream exiting the reaction chamber, and in some embodiments is added upstream of a pH sensor. In some embodiments a polymer is added. A fluid bed develops in the reaction chamber consisting of conditioner, buffer, precipitated solids and sidestream water. An upper outlet on the reaction chamber regulates the height of the fluid bed, and a drain provides for periodic discharge of the lower fluid bed. In some embodiments, a corrosion inhibitor blend is pre-mixed with the buffer.Type: GrantFiled: July 17, 2007Date of Patent: April 20, 2010Inventor: Samuel Rupert Owens
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Patent number: 7695630Abstract: An ionic conditioning process and molecular arrangement for removing colloids from an aqueous solution, where the aqueous solution is transported to and/or through several conditioning zones for purification. The process utilizes vessels within which stages of conditioning are performed and are monitored. The conditioning processes perform ionic, chemical and physical conditioning to the colloids in the aqueous solution causing the colloids to be transformed into a state that reacts with a polymer flocculating agent and is thereby precipitated rapidly and efficiently for removal. The effluent as well as the precipitate can be further treated with conventional means to meet certain specifications for discharge and disposal.Type: GrantFiled: November 10, 2006Date of Patent: April 13, 2010Inventor: Cesar Ladron de Guevara
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Patent number: 7686960Abstract: A multi-stage process for removing dissolved contaminants and suspended solids from water employing a magnetic separation technique. The process includes two tanks and magnetic seed. In the first tank, water is clarified by magnetic technologies and in the second tank dissolved solutes are sorbed on magnetic seed.Type: GrantFiled: September 27, 2007Date of Patent: March 30, 2010Inventor: Steven L. Cort
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Patent number: 7678280Abstract: A mobile apparatus and method for recycling an invert emulsion based drilling fluid, in which the invert emulsion based drilling fluid includes an oleaginous component and an aqueous component. The apparatus includes an emulsion breaking tank, a water treatment tank, a filter press, and hydrocarbon filters. The method includes: mixing said invert emulsion drilling fluid with a emulsion breaker, wherein the emulsion breaker is a mixture of an alkyl glucoside and an alkane sulfonate; and separating the oleaginous component of the invert emulsion drilling fluid from the aqueous component of the invert emulsion drilling fluid. The method preferably utilizes an emulsion breaker that is a combination of an anionic surfactant, a nonionic surfactant and an alkyl polyglycoside surfactant.Type: GrantFiled: March 23, 2009Date of Patent: March 16, 2010Assignee: M-I L.L.C.Inventor: Frank Manfred Franz Mueller
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Publication number: 20100059453Abstract: Systems and methods for de-watering waste drilling fluid. In some embodiments, the de-watering system includes a drilling fluid reclamation system receiving the waste drilling fluid from a wellbore and removing at least some solids from the waste drilling fluid, a manifold combining the waste drilling fluid from the drilling fluid reclamation system and organic polymers, whereby an aggregated mixture of solids in the waste drilling fluid and water are formed, and a centrifuge receiving the aggregated mixture and separating the solids from the water in the aggregated mixture, whereby solid drilling fluid waste and substantially colloidal-free water are formed.Type: ApplicationFiled: September 9, 2009Publication date: March 11, 2010Applicant: KEM-TRON TECHNOLOGIES, INC.Inventors: David B. REARDON, Dilipkumar P. SHAH
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Patent number: 7645389Abstract: Process for water purification and for the separation of beneficial materials that are obtained from an aqueous solution, comprising determining a turbidity index and adding to the water or to said solution a composition comprising one or more natural or mixtures of natural substances, chosen from the group consisting of substances having a cationic molecular charge and substances having an anionic molecular charge, in an amount determined as a function of said turbidity index, thereby, allowing water purification and the aggregation of said beneficial materials.Type: GrantFiled: June 19, 2003Date of Patent: January 12, 2010Assignee: Dead Sea Medica Co., Ltd.Inventor: Raziel Ronen
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Patent number: 7641801Abstract: A method and system of removing or decreasing waste liquor manganese concentration to less than about 1 mg/L total manganese without the precipitation of significant amounts of magnesium. The method and system include steps for treating the waste liquor using three separate circuits in which in the first circuit, manganese is reduced, for example, from about 2 g/L to <500 mg/L using pH adjustment with a suitable neutralizing agent; and in the second circuit, the final target manganese level is achieved by oxidative precipitation using a suitable oxidizing agent. Part of the precipitated manganese product, e.g., MnO2, is recycled to the oxidative precipitation circuit as seed and the balance proceeds to a third circuit wherein the precipitated manganese product is re-dissolved, and then recycled to the first neutralization circuit. In the first neutralization circuit and the second oxidative precipitation circuit, the process conditions are selected to minimize the precipitation of magnesium, e.g., Mg(OH)2.Type: GrantFiled: February 28, 2007Date of Patent: January 5, 2010Assignee: Vale Inco LimitedInventors: Mohamed Buarzaiga, Eric Devuyst, Julian Edwards, Joe Paventi
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Patent number: 7635434Abstract: Solid and liquid concrete waste is collected from a construction site and safely off-loaded at a treatment site. Solid waste is separated and sent to a crusher to be made into road bed aggregate. Liquid waste is put in a first tank to settle the solids, then moved to a second tank to settle remaining fine solids, and moved to a third tank coupled to a circulation pump with CO2 gas injection to lower the pH. The liquid in the third tank is then filtered before discharging for recycle, irrigation or dust control. A precipitate agent is preferable added to the liquid in the third tank to remove heavy metals and the precipitate is periodically backwashed from the filter into the first tank. The sludge created in the settling and filtering process is periodically dewatered in the first tank and mixed with the solid concrete waste sent to the crusher.Type: GrantFiled: May 13, 2008Date of Patent: December 22, 2009Assignee: Concrete Washout Systems, Inc.Inventors: Kevin Mickelson, Roger Engelsgaard
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Patent number: 7628925Abstract: The invention concerns a method for dehydrating sludge, comprising adding a basic agent to sludge having a pH not more than 8, adding to the sludge at least one organic flocculating constituent, by adding said basic agent, increasing the sludge pH to a value not more than a pH at which occurs degradation of said at least one organic constituent, flocculating the sludge and separating in the flocculated sludge dehydrated sludge from a liquid phase, said basic agent being a magnesian limestone compound of formula xCaCO3,(1?x)[yMg(OH)2+(1?Y) MgO], wherein 0,45:=x=0,75, and 0=y=, the treated sludge having, until after said separation, said value less than a pH at which occurs degradation of said at least one organic constituent.Type: GrantFiled: July 8, 2004Date of Patent: December 8, 2009Assignee: S.A Lhoist Recherche et DeveloppementInventors: Marc Remy, Eric Judenne, Matthias Rohmann