Including Organic Agent Patents (Class 210/727)
  • Patent number: 7608191
    Abstract: A process of separating suspended solids from a fermentation liquor by subjecting the liquor to a solids-liquid separation stage, wherein the fermentation liquor is produced in a fermentation process for the production of a fermentation product, and which liquor comprises lignin, wherein the solids-liquid separation stage is assisted by a treatment system, characterized in that the treatment system comprises an anionic polymer, with the proviso that the treatment system and does not include a cationic polymer having an intrinsic viscosity (IV) of at least 4 dl/g.
    Type: Grant
    Filed: January 20, 2005
    Date of Patent: October 27, 2009
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Jonathan Hughes, Rajesh Mistry, Kenneth Charles Symes
  • Patent number: 7591952
    Abstract: A product and apparatus for cleaning water or industrial and sewage waste water includes a mixture of diatomite that is heated and stirred to impart an enhanced negative electrical charge to the diatomite. A mixture of approximately 50% aluminium chloride (AlCl3) by volume is blended to provide a powder mixture for use as a flocculant in the system. According to a modification, the charged diatomite is instead blended with a mixture of approximately 50% ferric chloride (FeCl3) by volume and is stored in liquid form for later use as a flocculent in the system. From one to five percent, by volume, of polyacrylamide is preferably added to the mixture for use in sewage waste water treatment applications. An efficient system for reacting either the mixture or separately adding the diatomite and the metallic chloride to the water is described.
    Type: Grant
    Filed: July 9, 2007
    Date of Patent: September 22, 2009
    Inventor: Wing Yip Young
  • Patent number: 7582215
    Abstract: A process of separating suspended solids from a fermentation liquor by subjecting the liquor to a solids-liquid separation stage, wherein the fermentation liquor is produced in a fermentation process for the production of a fermentation product, which liquor comprises water, lignin and BOD, wherein the solids liquid separation stage is assisted by a treatment system, characterised in that the treatment system comprises either, (i) a cationic polymer having an intrinsic viscosity (IV) of at least 4 dl/g at a dose of above 2 kg/tonne based on dry weight of suspension, or (ii) a cationic polymer having an intrinsic viscosity (IV) of at least 4 dl/g and, (iii) an anionic polymer, and/or (iv) a cationic polymer of intrinsic viscosity of below 4 dl/g and a cationic charge density of at least 3 meq/g and/or (v) inorganic coagulants and/or (vi) charged microparticulate material.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: September 1, 2009
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Jonathan Hughes, Kenneth Charles Symes
  • Publication number: 20090211982
    Abstract: A process for treating a liquid fraction of effluent wastewater from post anaerobic digestion containing fine solids having a size less than about 25 microns is disclosed. A metal salt flocculant is added to the liquid fraction in an amount ranging from about 50 to 500 ppm in the liquid fraction. The metal salt flocculant is selected from inorganic iron and aluminum flocculent compounds having a +2 or +3 valence. A cationic organic polymer is added to the liquid fraction in an amount ranging from about 10 to about 150 ppm in the liquid fraction. The cationic organic polymer has a molecular weight greater than about 3,000,000 and cationicity in the range form 1.25 mole % to 30 mole %. The metal salt flocculent and the cationic organic polymer produce a separable solid fraction which is recovered. Pre-treatment with a small amount of the cationic organic polymer provides improved results.
    Type: Application
    Filed: February 23, 2009
    Publication date: August 27, 2009
    Applicant: WATER SOLUTIONS, INC.
    Inventor: Stephen D. Allen
  • Patent number: 7563378
    Abstract: A process to improve the polymeric filtration aid performance used in removal of gypsum from phosphoric acid/gypsum slurry. A synergistic effect has been observed by using a Dual Injection method. This method more specifically involves using two polymers (A & B) of different chemistry and injecting into slurry at a different time. The polymer chemistry of filtration aid A is selected from the group consisting of non-ionic, and anionic polymers and the polymer chemistry of filtration aid B is selected from the group consisting of sulfonated polymers. The polymer (A & B) usage is reduced by around 50% and performance improved.
    Type: Grant
    Filed: April 9, 2008
    Date of Patent: July 21, 2009
    Assignee: Arr-Max Products, LP
    Inventor: Louis Irwin
  • Patent number: 7560032
    Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: July 14, 2009
    Assignee: Nalco Company
    Inventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
  • Patent number: 7560031
    Abstract: A process for the treatment of phosphoric acid plant pond water facilitating the recovery of phosphorus values from the input pond water. In certain aspects the process recycles solids from a later stage neutralization and separation into the clarified liquid stream from an initial clarification and neutralization stage. A sufficient amount of solids are added to the clarified liquid stream to effect the pH-dependent precipitation of a phosphate product. In alternative aspects an intermediate pH-dependent precipitation of a phosphate product is achieved through the addition of a neutralizing agent. The phosphate product is further characterized by a low concentration of fluoride. In addition the phosphate product can be further processed to a high purity technical grade phosphoric acid. In certain aspects the process employs flocculating agents to enhance the formation of precipitates. In further aspects, methodologies taught herein facilitate the reduction of silica in the process streams.
    Type: Grant
    Filed: April 17, 2007
    Date of Patent: July 14, 2009
    Assignee: Dr. Phosphate, Inc.
    Inventors: Vaughn V. Astley, Dennis H. Michalski
  • Patent number: 7553423
    Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: June 30, 2009
    Assignees: Stockhausen GmbH & Co. KG, Detlef Hegemann GmbH & Co KG
    Inventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
  • Publication number: 20090120881
    Abstract: Treatment blends for removing metals from wastewater, method of producing and process of using the same. Treatment of industrial wastewater streams relate to the use of a pretreatment blend and a treatment blend, which remove heavy metals in industrial processes. The aqueous pretreatment blend comprises: 1) ferrous sulfate heptahydrate, 2) aluminum sulfate, 3) 85% phosphoric acid, and 4) coagulant. The aqueous treatment blend, which can be used in conjunction with or independent of the pretreatment blend comprises: 1) calcium hydroxide, 2) trimercapto-s-triazine 3) calcium hypochlorite, 4) sodium hydroxide, and 5) coagulant.
    Type: Application
    Filed: November 13, 2008
    Publication date: May 14, 2009
    Inventor: Sam Fanday
  • Patent number: 7510660
    Abstract: Pollutants, such as heavy metals, phosphorus, and pathogenic organisms, are removed from water by adding a chemical coagulant to water within an enclosure. With mixing, coagulation and flocculation occur, and a floc containing the pollutant settles to the enclosure bottom; so the treated water above the floc is free from at least some of the pollutant. Some of the treated water is removed from the enclosure, and new water is added. The new water and the settled floc are mixed to resuspend floc components. The process is repeated until the floc no longer exhibits contaminant-removal capability. In an alternate system, a matrix element is deployed within the enclosure, which captures a portion of the floc that settles within the water column. Pollutants in new water added to the enclosure encounter these suspended floc particles and are subsequently removed from the water.
    Type: Grant
    Filed: February 28, 2006
    Date of Patent: March 31, 2009
    Inventor: Thomas A. DeBusk
  • Patent number: 7507344
    Abstract: A mobile apparatus and method for recycling an invert emulsion based drilling fluid, in which the invert emulsion based drilling fluid includes an oleaginous component and an aqueous component. The apparatus includes an emulsion breaking tank, a water treatment tank, a filter press, and hydrocarbon filters. The method includes: mixing said invert emulsion drilling fluid with a emulsion breaker, wherein the emulsion breaker is a mixture of an alkyl glucoside and an alkane sulfonate; and separating the oleaginous component of the invert emulsion drilling fluid from the aqueous component of the invert emulsion drilling fluid. The method preferably utilizes an emulsion breaker that is a combination of an anionic surfactant, a nonionic surfactant and an alkyl polyglycoside surfactant.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 24, 2009
    Assignee: M-I L.L.C.
    Inventor: Frank Manfred Franz Mueller
  • Patent number: 7497956
    Abstract: The invention concerns a method for stabilizing and conditioning wastewater sludge. The invention is characterized in that it consists in treating sludge in an acid environment (3.0?pH?5.0), with an inorganic acid and two oxidizing agents, that is a ferric iron salt and hydrogen peroxide. The ferric iron salt is used in such an amount as to obtain a concentration ranging between 5 and 40 kg of Fe per ton of dry sludge; the hydrogen peroxide is used in such an amount as to obtain a concentration ranging between 5 and 40 kg of H2O2 per ton of dry sludge; mixing the treated sludge for a time interval sufficient to stabilize the sludge and improve its dehydrability; then flocculating the stabilized sludge by adding an organic polymer; then dehydrating the flocculated sludge. Said method enables to significantly improve the dehydrability properties of the sludge while increasing the dry solid content during its mechanical dehydration.
    Type: Grant
    Filed: November 29, 2002
    Date of Patent: March 3, 2009
    Assignee: Corporation Biolix
    Inventors: Jean-François Blais, Guy Mercier, Patrick Drogui
  • Patent number: 7497955
    Abstract: A method dewatering thin stillage process streams generated in the processing of grain to ethanol comprising adding to the process streams an effective flocculating amount of an anionic copolymer comprising acrylic acid sodium salt, methacrylic acid sodium salt or 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt to form a mixture of water and flocculated solids; and separating the water from the flocculated solids using a dewatering device.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: March 3, 2009
    Assignee: Nalco Company
    Inventors: David W. Scheimann, Angela S. Kowalski
  • Patent number: 7468137
    Abstract: A wastewater treatment process for treating wastewater comprising a water-based dispersion containing a surfactant, a colorant and silica, as well as other solid matter, wherein the wastewater is treated using a polysilicato-iron coagulant.
    Type: Grant
    Filed: November 7, 2005
    Date of Patent: December 23, 2008
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hitoshi Kojima, Shinichiro Kawashima, Kazuya Mori, Atsushi Yamahashi, Yuji Masuda
  • Patent number: 7455997
    Abstract: A process of producing fermentation product comprising the steps of, (i) forming an acidified suspension of particulate plant derived material comprising a first polysaccharide which is more readily hydrolysable and a second polysaccharide which is more difficult to hydrolysable, (ii) allowing the first polysaccharide to undergo hydrolysis by action of the acid at a temperature of at least 50° C.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: November 25, 2008
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd
    Inventor: Jonathan Hughes
  • Patent number: 7442311
    Abstract: An emulsion and affluent process which treats and breaks very tight emulsions and separates dissolved solids from associated fluids produced in industry, whereby solids and fluids are separated into clean interfacial phases thus providing an improved quality saleable product resulting in significant reductions in base sediments and water, and compliance with international saleable product and environmental effluent standards with a specific focus on biological oxygen demand and chemical oxygen demand levels for treated fluids.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: October 28, 2008
    Assignee: Hydrocarb (Trinadad) Limited
    Inventor: Dolly Nicholas
  • Publication number: 20080223792
    Abstract: A flow-through mixing apparatus for incorporating a dry treatment product into a waste stream. The apparatus comprises a pump for directing a liquid waste from a storage pit/tank, a mixer that receives the liquid waste from the pump, and a valve downstream of the mixer for either recirculating the liquid waste back to the storage pit/tank via a recirculation conduit, or directing the liquid waste to a discharge conduit. The mixer comprising a jet nozzle, a venturi tube and a high-shear assembly. The recirculation conduit establishes a calibration loop for determining the appropriate treatment regimen based on the characteristics of the waste liquid. The recirculation conduit also permits the homogenization of the pit/tank contents prior to addition of the dry treatment product. The dry treatment product introduced in the region of the mixer is subjected high shear forces, thereby incorporating the dry treatment product into the waste stream with increased dispersion and reduced agglomeration.
    Type: Application
    Filed: July 5, 2006
    Publication date: September 18, 2008
    Applicant: ROGER H. WOODS LIMITED
    Inventors: Roger H. Woods, Doug Pullman
  • Patent number: 7422692
    Abstract: Presently no chemicals are added in the pulp/paper mills wastewater treatment. There is a loop hole with the Biological Oxygen Demand test utilized. Regulators depend on the Biological Oxygen Demand test. All mills are discharging raw untreated wastes high in Chemical Oxygen Demand, (COD), Total Organic Carbon, (TOC) and COLOR. Liquid Alum solution is added to raw influent. All electrical energy aerated systems are eliminated. All flows from sewers join prior to the entrance to clarifier. The continuous in-line pH controller is proprietary as well as the continuous in-line COD analyzer. Because mills wastewater is amphoteric, it is mandatory that the raw influent pH be adjusted to range of 5.7 to 6.0 for optimum removal efficiencies. Aluminum chloride, ferric chloride and ferrous sulfate may be replaced for alum with higher operating costs. The precipitate is thickened, dewatered and incinerated, and approximately 75% of the chemicals regenerated.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: September 9, 2008
    Inventor: Launeil Neil Sanders
  • Patent number: 7419602
    Abstract: A process for removing selenium from a water stream, in particular a waste water stream, by: 1) the addition thereto of a ferric salt, followed by 2) the addition of a cupric salt and pH adjustment to a pH value in the range of from about 6.5 to about 8.0, thereby forming a copper-and-selenium-containing precipitate, and 3) removing the copper-and-selenium-containing precipitate to thereby form a treated water stream, is disclosed. The optional precipitation and removal of excess copper ions is also disclosed.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: September 2, 2008
    Assignee: ConocoPhillips Company
    Inventors: Roosevelt Alexander, Charles J. Lord, Steven C. Mitchell
  • Patent number: 7419605
    Abstract: A method for removing metal contaminants from water uses lignin derivatives, such as lignosulfonates and kraft lignin, a coagulant, such as a metal salt, and a pH-increasing composition. The lignin derivative is dispersed in the contaminated water, the coagulant is added and the pH is adjusted as required to cause flocculation. A sludge is formed that contains the metals and that is separated from the treated water by filtration. Related methods are used to reduce the leachable metal content of contaminated soils. The invention also provides a composition for stabilizing the metal contaminants in soil, comprising lignin derivatives, a coagulant and a composition for increasing the pH. The mixture is blended with the contaminated soil, reducing its leachable metal content.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: September 2, 2008
    Assignee: Noram Engineering and Constructors Ltd.
    Inventor: J. Ming Zhuang
  • Patent number: 7419604
    Abstract: A method is provided for removing uranium from water. The method includes the mixing of a boron reagent with water contaminated with uranyl dication ions, leading to removal of the uranium from that water.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: September 2, 2008
    Assignee: University of Kentucky Research Foundation
    Inventor: David A. Atwood
  • Patent number: 7410589
    Abstract: The invention relates to a method of treating manure such that odor from the manure is significantly reduced or eliminated and producing therefrom recyclable water, value-added biosolids and ammonia. Specifically, the manure is combined with lime at high pH. The material is mixed under negative pressure and the basic conditions cause ammonia to be evolved from the manure which is then drawn off and recovered. A coagulating agent is then added which further promotes floc formation within the manure. Following further mixing, flocs are separated from the liquid portion. A struvite-promoting chemical and a coagulant are then added to the liquid portion which causes further floc formation, and the flocs are again separated from the substantially clear liquid. It is of note that as a result of this process, the solids are highly hydrophobic and dry very quickly. It is of further note that solids isolated from either step can be combined and sold, for example, as fertilizer, as discussed below.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: August 12, 2008
    Inventor: Gurunathan Lakshman
  • Patent number: 7396474
    Abstract: A process to improve the polymeric filtration aid performance used in removal of gypsum from phosphoric acid/gypsum slurry. A synergistic effect has been observed by using a Dual Injection method. This method more specifically involves using two polymers (A & B) of different chemistry and injecting into slurry at a different time. The polymer chemistry of filtration aid A is selected from the group consisting of non-ionic, anionic, and cationic polymers and the polymer chemistry of filtration aid B is selected from the group consisting of sulfonated polymers. The polymer (A & B) usage is reduced by around 50% and performance improved.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: July 8, 2008
    Assignee: Arr-Maz Products, LP
    Inventor: Louis Irwin
  • Patent number: 7390416
    Abstract: An improved method to remove metals, including molybdenum, from industrial wastewater, by chemical precipitation of the metals, followed by settling and dewatering of the precipitate.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: June 24, 2008
    Assignee: American Airlines, Inc.
    Inventors: Kenneth F. Ede, Kerry C. Thorson
  • Patent number: 7384562
    Abstract: The invention is a process for treatment of brown grease, where the brown grease comprises water, food solids and free-oil. This process starts with the collection of the brown grease into a container. The brown grease's pH is adjusted with a chemical treatment to produce an adjusted brown grease phase. To the adjusted brown grease phase an anionic copolymer treatment mixture is added along with a cationic copolymer to form a reaction mixture. The reaction mixture reacts for a period of time, and during this time wastewater is discharged from the reaction mixture to produce resulting solids. The resulting solids are then transferred from the container for disposal or are processed further into a fuel or soil additive.
    Type: Grant
    Filed: August 2, 2005
    Date of Patent: June 10, 2008
    Assignee: EcoPlus, Inc.
    Inventor: Ralph W. Rogers
  • Patent number: 7374690
    Abstract: Processes for removing oil from a solid wellbore material such as drill cuttings or water such as produced by a subterranean formation include contacting the solid material/water with an amino-substituted polymer such as chitosan and a halogenating agent. The oil separates from the solid material and becomes bound within a flocculated solid. The flocculated solid containing the oil subsequently may be combined with a solvent of the amino-substituted polymer. Further, the flocculated solid may be contacted with a reducing agent, converting the flocculated solid back into the amino-substitute polymer and forming an oil-phase separate from the solvent-phase. The oil-phase may then be separated from the solvent phase and recovered. The solvent in which the amino-substituted polymer is dissolved may be recycled for treating more solid material removed from the well bore.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: May 20, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventor: B. Raghava Reddy
  • Patent number: 7374687
    Abstract: A decolorization treatment method in which not only can a liquid that has been obtained by treating raw water that is stock-raising treatment water in a purifier tank be decolorized swiftly with simple equipment, but moreover the treatment water can be purified to an extent that reuse as a washing liquid or the like is possible. The method of decolorizing stock-raising treatment water comprises adding ferric polysulfate and a nonionic or anionic organic coagulant to a filtrate that has been obtained by treating raw water that is stock-raising treatment water in a purifier tank, and agitating the obtained product to bring about reaction and thus separate into solid and liquid components, and removing the solid component. Preferably, a two-stage reaction is carried out in which the ferric polysulfate is added and agitation is carried out to bring about reaction, and then the nonionic or anionic organic coagulant is added thereafter.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: May 20, 2008
    Assignee: IK Shoji Co., Ltd.
    Inventor: Isamu Kobayashi
  • Patent number: 7371328
    Abstract: An animal treatment method comprises flushing the animal waste from a barn to a holding tank where the waste is mixed with an alkaline solution to kill pathogens. After neutralization, the solution is separated into solids and liquids. The liquid is treated and recycled as flushing water to clean the barns and/or drinking water for the animals. The solids are separated into digested and undigested feed. The digested feed is further processed for use as a fertilizer and the undigested feed is processed for use as animal feed.
    Type: Grant
    Filed: May 24, 2004
    Date of Patent: May 13, 2008
    Assignee: Recovery Systems, Inc.
    Inventors: Allan E. Hokanson, Christopher S. Williams, Derek Williams
  • Patent number: 7344647
    Abstract: Recycled waste water is treated to remove contaminants and produce a sludge cake with a high percentage of solids and to produce a treated recycled waste water that can be discharged into a municipal sewer system.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: March 18, 2008
    Assignee: Stewart Water Solutions, Ltd.
    Inventor: Timothy L. Stewart
  • Patent number: 7344648
    Abstract: A method for causing or facilitating the flow of dispersions of solid particulates in liquids, having characteristics of high viscosity or resistance to flow, with particular reference to sludges from purification plants of civil or industrial wastes, which method comprises the addition to the dispersions of silicones of formula wherein R and R? are identical or different and represent a radical chosen between C1-C5 alkyl and aryl; x is an integer comprised between 3 and 2000.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: March 18, 2008
    Assignee: Vomm Chemipharma S.r.l.
    Inventor: Giuseppina Cerea
  • Patent number: 7335309
    Abstract: A method for removing metal compounds from waste water comprising the steps of adjusting the pH of the water to from 5 to 12 and preferable 6 to 9; aerating the waste water; adding a flocculating agent to the water and allowing floccules including metal compounds to form; and separating said floccules including metal compounds from the water. An apparatus for carrying out this method is also disclosed.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: February 26, 2008
    Inventor: Sanford M. Stevenson
  • Patent number: 7311841
    Abstract: The invention concerns a water treatment method which consists in introducing coagulated water in a flocculation zone, to enable flocculation of microflocs in the presence and around a ballast; introducing the mixture in a decantation zone; separating the treated water in overflow and a mixture of sludge and the ballast in underflow; conveying at least part of said mixture to a sludge/ballast separating system and recycling into or upstream of the flocculation zone the ballast and part of the sludge introduced in said separation system.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: December 25, 2007
    Assignee: OTV SA S.A.
    Inventors: Patrick Binot, Claus Poulsen Dahl, Joseph Edward Zuback
  • Patent number: 7300585
    Abstract: A method for treating an effluent stream containing material which it is desired to remove from the effluent stream comprises treating the effluent stream with a solution of an acid and a first polymer to reduce the pH of the thus-treated stream to a range of about 5.5 to about 6.5 and to form a precipitate, treating the thus-treated stream with a second polymer to flocculate the precipitate, filtering the thus-treated effluent to remove the flocculated precipitate, treating the filtered effluent with at least one of a cationic resin, an anionic resin and carbon filtration, and discharging the resultant stream into a public waste treatment facility. Another method for treating an effluent stream having a pH in the range of about pH 2 to about pH 6.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: November 27, 2007
    Assignee: Mays Chemical Company, Inc.
    Inventors: Thomas R. Holzwarth, Bashir Samuel
  • Patent number: 7297278
    Abstract: A device for separating metal components from a colloidal suspension or solution uses a vessel for holding the colloidal suspension or solution. A membrane impermeable to the selected metal components of a colloidal suspension or solution is sealed over a support to form a leaf element. The leaf element includes an outlet for the selected components of the colloidal suspension or solution and is extended into the colloidal suspension or solution. The leaf element is controllably vibrated simultaneously with application of a negative or positive pressure which is used to motivate permeation of the membrane by the liquid of the colloidal suspension or solution to purify it. Metals removed by the method include metals with an atomic number greater than 10 including and/or silicon. The colloidal suspension or solution may optionally contain a metal precipitator such as a dithiocarbamate and/or trithiocarbamate to aid in the separation.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: November 20, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: Robert A. Steele, David J. Szykowny
  • Patent number: 7291275
    Abstract: Methods are described for removing contaminates from aqueous industrial wastewater process streams, specifically industrial laundries to yield a less contaminated aqueous effluent for discharge to a sewer and reduce the sludge generated therefrom. A premixed medium/high molecular weight and medium/high charged cationic coagulant solution polymer and an inorganic aluminum species is injected into the wastewater, and after at least a two second delay, a high molecular weight highly charged anionic flocculent polymer solution is injected into the wastewater which reduces sludge generation, while maintaining or exceeding effluent quality. Also, no coagulant, flocculent or sludge aids are needed to attain the results and the sludge can be dewatered in a plate and frame press.
    Type: Grant
    Filed: September 18, 2006
    Date of Patent: November 6, 2007
    Inventors: Robert A. Davis, Stuart G. Davis
  • Patent number: 7285222
    Abstract: A method for recycling sludge during waste-water treatment firstly utilizes a process of chemical coagulation to produce sludge rich in copper ions. The sludge is then leached in a sulfuric acid storage tank with sulfuric acid of concentration 1-2N, whereby a extractive solution with copper enrichment 18-39 g/L and residues can be obtained. The extractive solution is then processed in a refrigeration crystallization tank to form copper sulfate crystals. Further, the residues produced are added into the coagulation tank as a coagulant in the process of chemical coagulation for wastewater treatment, thereby achieving a goal of zero sludge production.
    Type: Grant
    Filed: June 13, 2005
    Date of Patent: October 23, 2007
    Assignee: National Cheng Kung University
    Inventors: Hung-Yuan Hsiao, Min-Shing Tsai, Li-Hsing Shih, Hung-Ta Chen, Yeu-Juin Tuan
  • Patent number: 7267777
    Abstract: Method for removal of heavy metal ions from aqueous wastes, which are produced during electroplating and other industrial processes. The method comprises a precipitation process that is conducted in a magnetic field.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: September 11, 2007
    Assignee: Veracon Metal Ltd.
    Inventors: Pavel Koren, Igal Raz, Robert Asimov, Rami Noach, Irena Trounkovsky
  • Patent number: 7264729
    Abstract: This invention relates to a process for reducing the contaminants in condensate resulting from the conversion of bauxite to alumina.
    Type: Grant
    Filed: June 2, 2005
    Date of Patent: September 4, 2007
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventor: Emmett R. Yawn
  • Patent number: 7264734
    Abstract: The present invention provides a method for treating dredged material in which liquid is first added to the dredged material, and dewatering the dredged material to obtain a filtrate and a solid portion. Contaminants are removed from the dredged material by at least one oxidation process. The solid portion may be used to form structural articles.
    Type: Grant
    Filed: January 3, 2002
    Date of Patent: September 4, 2007
    Assignee: AGL Resources
    Inventors: Joseph M. Kelly, Daniel J. Edwards
  • Patent number: 7255795
    Abstract: Process for selectively removing molybdenum from liquid mixtures containing it, in a quantity greater than (200) mg/l, together with vanadium characterized in that it comprises the following steps: bringing the liquid mixture to a pH of less than (3); adding a solution of an alkaline xanthate to the solution so that the molar ratio molybdenum/alkaline xanthate ranges from (¼) to (?), maintaining the pH constant by means of the addition of an inorganic acid; stirring the mixture causing the precipitation of the molybdenum present in the mixture.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: August 14, 2007
    Assignees: ENI S.p.A., Snamprogetti S.p.A., Enitecnologie S.p.A.
    Inventors: Emilio Sentimenti, Nicoletta Panariti
  • Patent number: 7255793
    Abstract: A two-step chemical precipitation process involving hydroxide precipitation and sulfide precipitation combined with “field separation ” technology such as magnetic separation, dissolved air flotation, vortex separation, or expanded plastics flotation, effectively removes chelated and non-chelated heavy metal precipitates and other fine particles from water. In the first-step, the non-chelated heavy metals are precipitated as hydroxides and removed from the water by a conventional liquid/solids separator such as an inclined plate clarifier to remove a large percentage of the dissolved heavy metals. The cleaned water is then treated in a second precipitation step to remove the residual heavy metals to meet discharge limits. In the second precipitation step, any metal precipitant more effective than hydroxide for metal precipitation can be used.
    Type: Grant
    Filed: May 24, 2005
    Date of Patent: August 14, 2007
    Inventor: Steven L. Cort
  • Patent number: 7244362
    Abstract: The invention concerns the use of a coagulation-flocculation-decantation device for water treatment to degrease water inside the device itself so as to eliminate therefrom more than 20% of hexane-extractable matter without resorting to separate degreasing means by flotation. The invention also concerns a plant comprising a coagulation-flocculation-decantation device by ballasted flocs having a coagulation zone (1), means supplying (4) a granular material denser than water (4), a flocculation (6), a decantation zone (8) and means for recycling (15) granular material including at least a hydrocyclone (17). The characterised in that it does nut comprise degreasing means provided upstream of the coagulation-flocculation-decantation device, the grease being removed from the water inside the coagulation-flocculation-decantation device itself without means for injecting air or an equivalent gas.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: July 17, 2007
    Assignee: OTV S.A.
    Inventor: Patrick Binot
  • Patent number: 7244361
    Abstract: A metals/minerals recovery and waste treatment process comprising a main separation stage in which a metal/mineral-bearing ore is slurried with water and separated into an enriched fraction and an aqueous metal/mineral waste fraction, and a waste sedimentation stage in which the aqueous metal/mineral waste fraction is sedimented in one or more settling lagoons to provide a thickened sediment layer and supernatant; and the waste sedimentation stage comprises feeding the aqueous metal/mineral waste into a solids contact vessel or other flocculating chamber, wherein the aqueous metal/mineral waste is diluted with water containing one or more flocculant(s) at more than one concentration, one of which concentrations is at least 10 times higher than the other, within the SCV, flocculating the diluted aqueous waste, and sedimenting the diluted and flocculated aqueous waste to provide a liquid supernatant layer and a pumpable thickened sediment layer in a settling basin.
    Type: Grant
    Filed: August 9, 2004
    Date of Patent: July 17, 2007
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventor: Patrick Joseph Dwyer
  • Patent number: 7198722
    Abstract: Water containing dissolved salts, such as calcium sulfate, calcium chloride, magnesium sulfate, magnesium chloride, sodium carbonate, sodium chloride, sodium sulfate, calcium bicarbonate, and mixtures thereof, is treated to reduce the concentration of those salts. About 0.1 to about 60 g/L of sodium hydroxide, sodium carbonate, potassium hydroxide, potassium carbonate, calcium hydroxide, calcium carbonate, aluminum hydroxide, aluminum sulfate, aluminum potassium sulfate, and mixtures thereof is added to the water, whereby a precipitate forms in the water. The precipitate is separated from said water and the water is desalinated using reverse osmosis, flash evaporation, or another method. The process is preferably performed by first adding calcium oxide or calcium hydroxide, separating the precipitate that forms, then adding sodium hydroxide and sodium carbonate to form a second precipitate.
    Type: Grant
    Filed: November 11, 2003
    Date of Patent: April 3, 2007
    Inventor: Mohammed Azam Hussain
  • Patent number: 7192527
    Abstract: Processes for removing oil from a solid wellbore material such as drill cuttings or water such as produced by a subterranean formation include contacting the solid material/water with an amino-substituted polymer such as chitosan and a halogenating agent. The oil separates from the solid material and becomes bound within a flocculated solid. The flocculated solid containing the oil subsequently may be combined with a solvent of the amino-substituted polymer. Further, the flocculated solid may be contacted with a reducing agent, converting the flocculated solid back into the amino-substitute polymer and forming an oil-phase separate from the solvent-phase. The oil-phase may then be separated from the solvent phase and recovered. The solvent in which the amino-substituted polymer is dissolved may be recycled for treating more solid material removed from the well bore.
    Type: Grant
    Filed: August 10, 2004
    Date of Patent: March 20, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventor: B. Raghava Reddy
  • Patent number: 7182873
    Abstract: First, a primary fluoric ion concentration detection process is performed, and a primary calcium salt addition process is performed to add calcium salt in a first reaction tank, wherein the dosage of the calcium salt in the primary calcium salt addition process is determined according to the detected fluoric ion concentration. Thereupon, a secondary calcium salt addition process is performed to add calcium salt into the second reaction tank. Following that, a solid-liquid separation process is performed to separate calcium fluoride from the wastewater, and a secondary fluoric ion concentration detection process is performed upon the wastewater after the calcium fluoride is separated. Finally, the dosage of the calcium salt in the secondary calcium salt addition process is determined in a feed back control manner according to the detected fluoric ion concentration.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: February 27, 2007
    Assignee: Powerchip Semiconductor Corp.
    Inventors: Chen-Hung Hsien, Wen-Ta Huang
  • Patent number: 7166227
    Abstract: A method of treating, in wastewater purification, sludge containing organic matter, divalent iron and phosphorus, in which the sludge that is treated is made to contain dissolved iron and phosphorus at a molar ratio Fe:P of above 1:1, the sludge is treated at 0–100° C. with an acid at a pH of 1–5 for dissolution of divalent iron and phosphorus from the sludge, the sludge is supplied with an oxidizer selected from hydrogen peroxide and percompounds, wherein divalent iron is oxidized by Fenton's reaction to trivalent iron, and (i) trivalent iron is precipitated as trivalent iron phosphate (ii) free radicals with a deodorization and sanitation effect are formed by Fenton's reaction, the sludge is then dewatered at a pH of at most 7, and the aqueous solution obtained in dewatering is recirculated to the wastewater purification.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: January 23, 2007
    Assignee: Kemira Kemi AB
    Inventors: Göran Karlsson, Ingemar Karsson, Lennart Pettersson, Michael Recktenwald
  • Patent number: 7160470
    Abstract: Methods are described for removing contaminates from aqueous industrial wastewater process streams, specifically industrial laundries to yield a less contaminated aqueous effluent for discharge to a sewer and reduce the sludge generated therefrom. A premixed medium/high molecular weight and medium/high charged cationic coagulant solution polymer and an inorganic aluminum species is injected into the wastewater, and after at least a two second delay, a high molecular weight highly charged anionic flocculent polymer solution is injected into the wastewater which reduces sludge generation, while maintaining or exceeding effluent quality. Also, no coagulant, flocculent or sludge aids are needed to attain the results and the sludge can be dewatered in a plate and frame press.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: January 9, 2007
    Inventors: Robert A. Davis, Stuart G. Davis
  • Patent number: 7157009
    Abstract: A method for stabilizing and removing Cryptosporidium oocysts or Giardia cysts from water. The method comprises adding chitosan, a salt or solution of chitosan to water containing Cryptosporidium oocysts or Giardia cysts and a halogenating agent. The method may also include adding a secondary polyelectrolyte flocculant to the water. The resulting flocs are filtered to remove the Cryptosporidium oocysts or Giardia cysts.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: January 2, 2007
    Assignee: Vanson Halosource, Inc.
    Inventors: Everett J. Nichols, Jeffrey F. Williams
  • Patent number: 7153436
    Abstract: The present invention is directed to a novel method and system for enhancing the efficiency of hydraulic centrifugal separators (cyclones) in the removal of fine size particles from a liquid carrying medium. More particularly, it is concerned with improvements in the removal efficiency of any number of cyclonic devices that rely on the use of centrifugal force to separate fine size particles of differing density from the liquid carrying medium by addition of polymeric additives, both before, and, as necessary, inside the cyclone body.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: December 26, 2006
    Inventors: Patrick W Bair, Charlynn Bair