Abstract: A method is disclosed for the induction of a suitable band gap and electron emissive properties into a substance, in which the substrate is provided with a surface structure corresponding to the interference of electron waves. Lithographic or similar techniques are used, either directly onto a metal mounted on the substrate, or onto a mold which then is used to impress the metal. In a preferred embodiment, a trench or series of nano-sized trenches are formed in the metal.

Abstract: A die used for molding an electronic component with resin includes a fixed, top die and a movable, bottom die and at least has a surface contacting a melted resin material that is electroplated with nickel-tungsten alloy. This plating can provide releaseability of a resin-molded body and the like superior to hard-chromium plating to allow an ejector pin to efficiently eject and release the resin-molded body from the die.

Abstract: A method of making a molded plastic component having enhanced surface finish uses a mold having at least one metal base, a mold cavity, and at least one self-lubricating surface layer which defines the plastic component within the mold cavity. The self-lubricating surface layer includes a porous metallic skin integrally connected to and extending from an interior surface of the at least one metal base and lubricating particles disposed on the skin and in pores of the skin. The lubricating particles are bonded together to form a sealed surface of the at least one self-lubricating surface layer such that the molded plastic component has the enhanced surface finish. The metallic skin includes a plurality of spaced, sinusoidally-shaped projections of autocatalytic nickel alloy. The lubricating particles are preferably submicron-sized particles of low friction fluoropolymers. The mold may be an injection mold, a compression mold, a blow mold or a vacuum mold.

Abstract: A method for forming a composite structure is disclosed. The method includes four steps. Step one calls for applying a primer (104) to a surface (102) of a tool (100). Step two requires applying a coating (106) to primer (104). Step three calls for curing primer (104) and coating (106). The last step calls for forming the composite structure on tool (100). More specifically, primer (104) may be a powdered primer, and coating (106) may be a powdered fluorinated organic compound.

Abstract: A device for stamping a detergent bar, i.e. a bar comprising soap, a synthetic detergent active or a mixture thereof, includes a die. The die has at least one bar stamping surface provided with at least one elastomeric coating which includes a conductive filler such as stainless steel powder. Good release of the detergent bars from the die is possible particularly when the dies are chilled. Use of the conductive filler facilitates chilling of the dies.

Abstract: An apparatus and related method for forming a three dimensional polymer based part including a die tool having a specified shape and size and exhibiting an exposed polymer adhering surface corresponding in configuration to a polymeric based part to be created. A bin is filled with a polymer material in particulate form and, upon positioning the die tool overhead, the die tool is inserted into the bin, such as by either lowering the tool or raising the bin. The tool is positioned within the bin such that the exposed and adhering surface is in contact with the particulate material. Heat is applied to either or both the die tool and the bin particulate and, in combination with an optional vibrating motion imparted to the bin, causes a specified volume of polymer material to adhere and to form upon the exposed surface of the die tool.

Abstract: An apparatus for the manufacture of chemical vapor deposited domes. The apparatus has a vapor deposition chamber with a plurality of sides, a base and a top where the base has a reactant port for receiving a flow of chemical reactants. A male mandrel is joined to one of a plurality of sides of the deposition chamber such that the flow of chemical reactants in the vapor deposition chamber does not impinge on the mandrel.

Abstract: A process for the production by a moulding process of a micro-cellular or non-cellular elastomeric polyurethane skin layer or, more generally, to a process for the production of a composite comprising a first layer shaped part, which is made by a moulding process from a polyurethane reaction mixture, and a second layer shaped part which is adhered to the first part to form the composite. In order to avoid the use of release agents on the back side of the first layer shaped part, and thus the negative effect on the adhesion of the second layer shaped part, and the penetration of reaction mixture on this back side between the slides (9-10) of the mould, the mould surface (4) is covered on the back side of the moulding with a removable flexible covering (12), with a removable rigid pre-shaped covering or with a permanent non-stick coating layer.

Abstract: A film is provided on a mold used during semiconductor device fabrication through surface modifications to the mold to provide non-stick characteristics and a mold surface that is resistant to abrasion or wear. Such surface modifications are particularly useful in a mold having a quartz planar surface adapted to contact a photocurable polymer material applied to a semiconductor wafer surface during a fabrication process. The planar surface of the mold is capable of allowing transmission of ultraviolet light therethrough to cure the polymer material. A non-stick film is formed on the planar surface of the mold by a coating or deposition process in order to modify the mold surface. The non-stick film can be formed of a fluoroalkylsilane compound, or a hard material such as diamond or diamond-like carbon. The non-stick film of diamond or diamond-like carbon provides protection against abrasion or wear on the planar surface of the mold.

Abstract: An oxidation and corrosion resistant coating is applied to glass forming equipment by physical vapor deposition. The coating material is preferably aluminum oxide.

Abstract: A metal mold for use in a nano-imprinting process comprises a firmly adhering monomolecular non-sticking layer. The layer was obtained by subjecting the mold to a reaction with a fluoroalkyl compound having a mercapto group. As a result of said reaction, the layer comprises an organic sulfide of said metal.

Abstract: This invention relates to the preparation of molds for the production of contact lenses and other ophthalmic articles. By using an inorganic material to coat the optical surfaces and sidewalls of mold parts made from clear-resin materials, manufacturers can produce lens molds with greater dimensional stability and chemical resistance. In addition to protecting the clear resin from interaction with otherwise reactive monomers from which the molded article is made, such coatings can also be used to achieve preferential release of the molded article. The resulting mold is especially useful for providing an economical way to improve manufacturing quality of contact lenses.

Abstract: A mold includes a bottom die, and an upper die closed on the bottom die and defining with the bottom die a cavity for folding molding food materials into a predetermined shape, the upper die having a coupling flange around the cavity and retaining means in the coupling flange, the bottom die having a coupling flange fitted into the coupling flange of the upper die, retaining means adapted for engaging the retaining means of the upper die, and an overflow outlet through which an overflow of inserted food passes to the outside of said mold.

Abstract: The invention provides non-stick coated molds, a process for the preparation thereof and their use for the production of plastics molded parts, particularly for the production of molded parts made of polyurethane foam.

Abstract: This invention relates to a flexible mould made of silicone for confectionery, bread-making or similar, particularly suited to the use both in traditional ovens and microwave ovens, consisting of a tray provided, on the upper side, with an edge which estends outwardly, wherein this edge is equipped with a support and stiffening element, preferably consisting of a metallic wire dippen in the silicone or of platic or metallic frame partially co-stamped at sight, or manually inserted into a corresponding seat provided in the edge.

Abstract: A device for stamping a detergent bar, i.e. a bar comprising soap, a synthetic detergent active or a mixture thereof, includes a die. The die has at least one bar stamping surface provided with at least one elastomeric coating which includes a conductive filler such as stainless steel powder. Good release of the detergent bars from the die is possible particularly when the dies are chilled. Use of the conductive filler facilitates chilling of the dies.

Abstract: The invention relates to a method of producing a matrix suitable for use in a plastic element-producing machine, a matrix produced in accordance with the method and the use of such a matrix to form a plastic element. One side of the matrix (2) is provided with a negative microstructure (2a) which is replicated in plastic material (3) to form a positive microstructure (3a) on a plastic element (3), wherewith the matrix (2) can be produced by applying a layer of material (7) to the positive microstructure side of a master. The positive microstructure side of the master has a thin wear-resistant layer (7) which serves as a first wear surface, wherewith said layer will present irregularities (7a) which correspond essentially to the microstructure, and wherein at least said irregularities are filled-in with a plastic composite (8′) so as to form a carrier element (8) for supporting the first wear layer (7). The layer (7) can further be provided with means for supplying heat energy to said matrix.

Abstract: A molding die having satisfactory releasability, a sol-gel composition produced using the molding die, and a process for producing a sol-gel composition. The molding die which is to be pressed against a sol-gel material for producing a sol-gel composition has a release film, e.g., a thin gold (Au) film, formed on the molding surface of the molding die through a buffer layer made of metals and/or inorganic oxides.

Abstract: Surface modifications of a mold used during semiconductor device fabrication provide non-stick characteristics and a mold surface that is resistant to abrasion or wear. Such surface modifications are particularly useful in a mold having a quartz planar surface adapted to contact a photocurable polymer material applied to a semiconductor wafer surface during a fabrication process. The planar surface of the mold is capable of allowing transmission of ultraviolet light therethrough to cure the polymer material. A non-stick film is formed on the planar surface of the mold by a coating or deposition process in order to modify the mold surface. The non-stick film can be formed of a fluoroalkylsilane compound, or a hard material such as diamond or diamond-like carbon. The non-stick film of diamond or diamond-like carbon provides protection against abrasion or wear on the planar surface of the mold.

Abstract: A method of patterning metallic building elements, and also to a metallic building element, where the measuring accuracy achieved can lie in the sub-micrometer range is disclored. Starting from a silicon master or original that can be etched to sub-micrometer precision and then plated with a metal, such as nickel, on the silicon surface, there can be produced a nickel shim where precision and surface fineness can lie in the sub-micrometer range. Subsequent to removal of the silicon master, a photo-sensitive material can be used in liquid form or in film form to create mould cavities that reach down to the nickel shim. These cavities can then be metal-plated to provide a building element of higher precision in three dimensions.

Abstract: A molding die having satisfactory releasability, a sol-gel composition produced using the molding die, and a process for producing a sol-gel composition. The molding die which is to be pressed against a sol-gel material for producing a sol-gel composition has a release film, e.g., a thin gold (Au) film, formed on the molding surface of the molding die through a buffer layer made of metals and/or inorganic oxides.

Abstract: A polymer mixture, a mold design including a porous steel part and a process for producing a one piece polymer hypodermic tip having a stiff needle part of uniform small diameter and a length exceeding 0.4 inches.

Abstract: A molding die having satisfactory releasability, a sol-gel composition produced using the molding die, and a process for producing a sol-gel composition. The molding die which is to be pressed against a sol-gel material for producing a sol-gel composition has a release film, e.g., a thin gold (Au) film, formed on the molding surface of the molding die through a buffer layer made of metals and/or inorganic oxides.

Abstract: A silicone-epoxy resin is mixed with a conductivity enhancing agent, such as carbon black, and is cured to control the resistivity of films that may be used as mold release agents in mold processing or mold shaping electrically sensitive energetic compositions, such as rocket fuels, explosives, gas generator fuels and the like. The uncured precursor to the mold release agent is placed as a coating on molds that are used in these processes. Upon curing on the mold, the enhanced conductivity of the film permits dissipation of static electricity from the electrically sensitive energetic compositions.

Abstract: A film is provided on a mold used during semiconductor device fabrication through surface modifications to the mold to provide non-stick characteristics and a mold surface that is resistant to abrasion or wear. Such surface modifications are particularly useful in a mold having a quartz planar surface adapted to contact a photocurable polymer material applied to a semiconductor wafer surface during a fabrication process. The planar surface of the mold is capable of allowing transmission of ultraviolet light therethrough to cure the polymer material. A non-stick film is formed on the planar surface of the mold by a coating or deposition process in order to modify the mold surface. The non-stick film can be formed of a fluoroalkylsilane compound, or a hard material such as diamond or diamond-like carbon. The non-stick film of diamond or diamond-like carbon provides protection against abrasion or wear on the planar surface of the mold.

Abstract: A concrete column forming tube is provided for receiving poured concrete therein to produce a concrete column and which eliminates spiral seam lines and other undesirable characteristics on the outside surface of the formed concrete column and provides a construction which may be easily removed from the concrete column. The forming tube includes a spirally-wound cylindrical paper tube including multiple plies of paper adhered together, a centrifugally-cast plastic coating sprayed on an inside wall surface of the spirally-wound paper tube for producing an inside coated surface having a thickness and smoothness sufficient to eliminate spiral seam lines and other undesirable characteristics, and a tear strip positioned between the inside surface of the cylindrical paper tube and the plastic coating before centrifugal-casting and extending longitudinally of the forming tube over the entire length thereof and having a predetermined width and readily detachable from the plastic coating.

Abstract: A film is provided on a mold used during semiconductor device fabrication through surface modifications to the mold to provide non-stick characteristics and a mold surface that is resistant to abrasion or wear. Such surface modifications are particularly useful in a mold having a quartz planar surface adapted to contact a photocurable polymer material applied to a semiconductor wafer surface during a fabrication process. The planar surface of the mold is capable of allowing transmission of ultraviolet light therethrough to cure the polymer material. A non-stick film is formed on the planar surface of the mold by a coating or deposition process in order to modify the mold surface. The non-stick film can be formed of a fluoroalkylsilane compound, or a hard material such as diamond or diamond-like carbon. The non-stick film of diamond or diamond-like carbon provides protection against abrasion or wear on the planar surface of the mold.

Abstract: A device for stamping a detergent bar, i.e. a bar comprising soap, a synthetic detergent active or a mixture thereof, includes a die. The die has at least one bar stamping surface provided with at least one elastomeric coating and includes an edge for delaying tearing of the elastomeric coating. Good release of the detergent bars from the die is possible without chilling of the dies. Use of the edge increases the useful life of the coating.

Abstract: An apparatus and method of manufacturing seal rings. The apparatus and method ensures that there is no wasted material during the manufacturing process and further ensures that the seal ring is manufactured to exacting standards without the need for any further milling processes. The apparatus and method has a mold which is heated and rotated at a predetermined rotation rate. A molten material is poured into the mold during the rotation thereof. The mold is then cooled and the rotation is decelerated so that the solidified material can be removed therefrom.

Abstract: A mold assembly for forming an ophthalmic lens, or a lens blank from which one ophthalmic lens is produced by effecting a cutting operation on at least one of a front surface and a back surface of the lens blank, the mold assembly consisting of a first mold having a molding surface and a second mold having a molding surface, which first and second molds are assembled together so as to define therebetween a mold cavity having a profile corresponding to that of the ophthalmic lens or the lens blank, the mold cavity being filled with a polymeric material which is polymerized to form the ophthalmic lens or the lens blank, wherein at least one of the first and second molds is a layered mold which is constituted by a composite sheet comprising a metal sheet layer and at least one resin layer which are laminated on each other, the at least one resin layer of the composite sheet providing the molding surface of the layered mold which partially defines the mold cavity.

Abstract: A rounder bar for shaping pieces of baking dough advancing upon a conveyor belt has an elongated configuration having top and rear surfaces and an arcuate dough-contacting surface of convex contour with respect to the top and rear surfaces. The dough-contacting surface is provided with a non-occluding texture which minimizes adherence of the dough.

Abstract: A lay-up mold is disclosed. The mold comprises a multi-sided vertically extending frame formed of sheet steel. A plurality of spaced apart vertically extending ribs also formed of sheet steel are positioned within the frame and rigidly affixed thereto, the ribs having upper edges which conform to the shape of the mold surface. The mold also comprises a plurality of spaced apart vertically extending partition elements formed of sheet steel positioned within the frame which transverse the ribs and rigidly and are affixed to the frame, with the partition elements having upper edges which conform to the shape of the mold surface. A layer of perforated sheet steel is rigidly affixed to the frame and the upper edges of the ribs and partition elements, with a coating of polyurethane overlying and bonded to and interlocked with the perforated sheet steel, the coating forming the mold surface.

Abstract: A process for preparing a mold used for producing, for example, high resilience polyurethane foamed articles, comprises the step of spraying an aqueous release compound on the inner, article-contacting surface of the mold, the release compound including: an aqueous carrier; and a release agent which forms a release film on the article-contacting surface, wherein the release film is formed by evaporating a majority of the aqueous carrier. An aqueous rinse solution is gently sprayed on the inner mold surface after formation of the release film. The rinse solution, now carrying residual water, emulsifier(s) and/or contaminants, is mechanically removed via an air entrainment device before significant evaporation of the rinse solution has taken place.

Abstract: A process for the production by a moulding process of a micro-cellular or non-cellular elastomeric polyurethane skin layer or, more generally, to a process for the production of a composite comprising a first layer shaped part, which is made by a moulding process from a polyurethane reaction mixture, and a second layer shaped part which is adhered to the first part to form the composite. In order to avoid the use of release agents on the back side of the first layer shaped part, and thus the negative effect on the adhesion of the second layer shaped part, and the penetration of reaction mixture on this back side between the slides (9-10) of the mould, the mould surface (4) is covered on the back side of the moulding with a removable flexible covering, such as a film (12) or a membrane, with a removable rigid pre-shaped covering or with a permanent non-stick coating layer.

Abstract: A flexible composite release sheet providing a replicative surface with a desired surface effect and a method of manufacturing such a release sheet is disclosed. The release sheet is suitable for use in multicomponent reactive urethane casting systems. The invention further provides flexible composite release sheets having a first acrylic functional coating layer containing the desired surface effect and a second silicone release coating layer overlying the acrylic functional coating layer.

Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.

Abstract: A process which allows elastomeric materials of different colors, durometers and/or other material characteristics to chemically bond to one another so as to eliminate any possibility of delamination. Latex-based liquid elastomer solutions having different material characteristics are applied sequentially to a heated mold to form a series of layers making up the article, with rapid partial curing taking place between each application; the partial curing forms a skin coat over each layer which prevents intermixing of the different solutions, but which still permits a chemical bond to form during full curing of the materials. The process applies equally to dip (immersion) molded and flat molded goods. An example of the invention as it relates to flat-molded goods is an athletic shoe sole, and an example as it relates to dip-molded goods is a resilient, one piece watersports boot which can be fitted over a human foot without a zipper.

Abstract: A casting includes a heat transfer surface having a plurality of cavities. The plurality of cavities include a density of at least about 25 cavities per square centimeter to about 1,100 cavities per square centimeter resulting in increased surface area and therefore enhanced heat transfer capability. Also disclosed is a mold for forming a pattern for molding the casting. The mold includes a surface defining a portion of a chamber to which are attached a plurality of particles having an average particle size in a range of about 300 microns to about 2,000 microns.

Abstract: A stamping die includes a substrate stamping surface comprising a base matrix of open structure having a coating of elastomeric material applied thereon. The resulting surface is a composite comprising predominantly elastomer having matrix protruding through the elastomer in places.

Abstract: Systems are provided to contour hardenable construction material to resemble a natural stone wall. A gang form is provided for molding the natural stone surface having multiple stone regions. The gang form includes a plurality of form liners each including only one lateral relief mold face for contouring a single stone region on the wall formed against the lateral relief mold face. The form liners are mounted to a backing member in an adjacent mating relationship to create a continuous lateral relief mold face.

Abstract: A rounder bar for shaping pieces of baking dough advancing upon a conveyor belt has an elongated configuration having top and rear surfaces and an arcuate dough-contacting surface of convex contour with respect to the top and rear surfaces. The dough-contacting surface is provided with a non-occluding texture which minimizes adherence of the dough.

Abstract: Disclosed herein is a method and apparatus for forming on-site tinted and coated optical elements from a mold. The apparatus is a mold having a polymer release layer; an optical coating, such as an anti-reflective coating; a coupling agent layer to bind to the optical coating and having unreacted chemical groups; and, optionally, a tinted hard coat layer having unreacted chemical groups. The mold can be shipped to a lab that prepares optical elements, such as ophthalmic lenses, after the coupling agent layer is added or after the tinted hard coat layer is added. When using the mold with a lens resin having unreacted chemical groups, the coupling agent layer, tinted hard coat layer and optical element all crosslink as the optical element is cured to form, on-site, a durable and stable lens with chemically bound optical coatings.

Abstract: The present invention relates to a mold for a chemically curable composition including a first shell component, a second shell component and a honeycomb core interposed therebetween. The invention further relates to providing an essentially adiabatic environment for chemically cured compositions using the previously described mold.

Abstract: Articles having at least one precision replicated surface are formed by chemical vapor deposition on a substrate surface which has been precision shaped and finished as the converse of the desired precision surface of the article. The substrate surface is provided with a thin release coating which adheres to the substrate when the article is removed thereby allowing the substrate to be reused. The method is particularly advantageous for forming the interior surfaces of domes and asymmetrical optical surfaces of zinc sulfide.

Abstract: A master brake cylinder comprises a reservoir and a cylinder for generating fluid pressure. Provided in the cylinder is a sliding piston, and mounted to front and rear ends of piston are piston cups for sealing a gap between the piston and the cylinder. The piston cups comprise a substrate made of rubber and a coating layer made of diamond-like carbon and provided on an outer peripheral surface (sliding surface) of the substrate. A surface of the coating layer constitutes a sliding surface, and so a frictional resistance thereof relative to an inner peripheral surface of the cylinder, on which the coating layer slides, is made relatively low. The coating layer can easily follow deformation of the substrate and securely adheres to the substrate.

Abstract: A mandrel of a high frequency heating type, comprising a conductive layer comprising a metal member having an aspect ratio of at least 100, in a proportion of at least 60% by volume, and a surface layer formed thereon which is made from an organic polymer, and a method for producing a rubber hose using the mandrel. Inasmuch as the inventive mandrel enables heating the curable rubber extruded on the mandrel, from the inner surface side thereof, the curing time of the rubber can be drastically reduced. Moreover, since the surface layer of the mandrel is composed of an organic polymer, the mandrel can be easily pulled out from the cured rubber layer. The production method of the present invention is free of the difficulty in heating the inside of the rubber layer. The concurrent application of external heating has accomplished continuous production of rubber hose.

Abstract: A process for forming such manufactured items as imitation leather, or the like, from thermoplastic materials, thermosetting materials or elastomers, having at least one foamed layer, characterized in that said process comprises the following steps: a) forming, inside a mold for slush molding, a first layer of material which will constitute the top (i.e.

Abstract: A gate portion constituting a gate of a resin molding die is made of a hard alloy having a hardness greater than the predetermined hardness in the iron-based hard alloy used to from a cavity block and a center block. Opposing surfaces of the cavity block halves include a silicone rubber layer at least at the portions thereof which contact portions of the lead frame in a semiconductor encapsulation molding apparatus.

Abstract: A concrete column forming tube and method of making same for receiving poured concrete column therein to produce a concrete column is characterized by a smooth inside coated surface in the forming tube to eliminate spiral seam lines and other undesirable characteristics on the outside surface of the formed concrete column. The tube is formed from spirally-wound plies of paper adhered together and has a centrifugally-cast epoxy resin coating sprayed onto the inside surface of the spirally-wound tube while the tube is rotating to produce a smooth inside coated surface on the forming tube.

Abstract: A mold for molding a synthetic resin coated with a highly durable thick heat insulating layer, and a molding method using the same are provided. The present invention relates to a mold comprising a base mold comprising a metal, with its inner wall constituting the mold cavity being coated with a heat insulating layer, wherein the heat insulating layer comprises a polymer alloy comprising (A) a heat-resistant non-crystalline resin of a linear high-molecular weight polymer containing an aromatic ring in the main chain thereof and having a glass transition temperature of not lower than 150.degree. C. and an elongation at break of not less than 10% and (B) a cured thermosetting resin at a (A)/(B) mixing ratio of 40/60 to 5/95 by weight; and further relates to a molding method using the mold.