Abstract: A method for inhibiting silica scale formation which treats aqueous systems with a polymerizable-acid graft copolymer that includes an unsaturated grafting acid and having a percent acid graft of between about 3 wt. % and about 35 wt. %, as well as an alkylene oxide polymer backbone.

Abstract: Introducing metal ions into fluids produced from a wellbore may inhibit the formation of scale on downhole production equipment. The ions may be introduced by one or more electrodes disposed in downhole locations such as in a sand control screen assembly, an inflow control device or in a production tubing base pipe. Parameters indicative or predictive of scale formation may be monitored, and an electrical voltage supplied to the electrodes may be adjusted to in response to any predetermined threshold of the parameters being exceeded. In some embodiments, a chemical ion source may be provided, which may release ions in response to erosion or corrosion reaction controlled by electrical power. Electric control of scale production allows for targeted feedback control of the amount of metal ions released as a scale inhibitor without requiring storage of downhole chemical solutions or the passage of fluid lines to downhole locations.

Abstract: A heat transfer mixture is represented by the formula: 1=Vpg/Vnf+Vw/Vnf+Vpw/Vnf+Vsf/Vnf+Vbs/Vnf+Vac/Vnf+Vci/Vnf. Vnf is a volume of a nanofluid. Vpg is a volume of propylene glycol. Vw is a volume of water. Vpw is a volume of a nanopowder. Vsf is a volume of a surfactant. Vbs is a volume of a base additive. Vac is a volume of an acid additive. Vci is a volume of a corrosive inhibitor.

Abstract: A heat transfer mixture is represented by the formula: 1=Vpg/Vnf+Vw/Vnf+Vpw/Vnf+Vsf/Vnf+Vbs/Vnf+Vac/Vnf+Vci/Vnf. Vnf is a volume of a nanofluid. Vpg is a volume of propylene glycol. Vw is a volume of water. Vpw is a volume of a nanopowder. Vsf is a volume of a surfactant. Vbs is a volume of a base additive. Vac is a volume of an acid additive. Vci is a volume of a corrosive inhibitor.

Abstract: A fluorescent water treatment polymer comprises at least one water soluble carboxylic acid monomer other than maleic acid, at least one sulfonated pyrene-containing fluorescent monomer, and at least one phosphino group wherein the phosphorous atom of the phosphino group is in the polymer backbone. Additional monomers can be present, with the proviso that if maleic acid is present it comprises no greater than 75 mol % of the polymer. Surprisingly, it has been found that when the phosphino group is present the polymers exhibit an unexpectedly strong fluorescent signal strength. The signal strength of the fluorescent monomer in the polymer is further enhanced when the polymer comprises no greater than 75 mol % maleic acid.

Abstract: A slurry for polishing surfaces or substrates that at least partially comprise ruthenium and copper, wherein the slurry includes an alkali hydroxide, oxygenated halogen compound, and a halogen alkyl benzotriazole. The slurry may further include abrasive, acid(s), and, optionally, an alkoxylated alcohol. With these components, the slurry exhibits a high ruthenium to copper removal rate ratio.

Abstract: The present invention relates to a fluorescently-tagged (co)polymer and use thereof useful as a scale inhibitor in industrial water systems. Said (co)polymer comprises a (i) reactive fluorescent compound selected from a benzodiazole compound (ii) at least one monoethylenically unsaturated acid monomer, and (iii) optionally, at least one monoethylenically unsaturated acid-free monomer.

Abstract: Disclosed are methods of using nitrogen-containing compounds as corrosion inhibitors. The present method is used to inhibit corrosion of a metal surface in contact with an aqueous system using 2-substituted imidazoles and 2-substituted benzimidazoles, and provides enhanced protection against corrosion of metals in the aqueous system. The method comprises the use of corrosion inhibitors that are generally resistant to halogen attack and provide good corrosion resistance in the presence of oxidizing halogen-based biocides. Formulations comprising 2-substituted imidazoles and 2-substituted benzimidazoles are also disclosed.

Abstract: The present disclosure describes a strategy to create self-healing, slippery liquid-infused porous surfaces. Roughened (e.g., porous) surfaces can be utilized to lock in place a lubricating fluid, referred to herein as Liquid B to repel a wide range of materials, referred to herein as Object A (Solid A or Liquid A). Slippery liquid-infused porous surfaces outperforms other conventional surfaces in its capability to repel various simple and complex liquids (water, hydrocarbons, crude oil and blood), maintain low-contact-angle hysteresis (<2.5°), quickly restore liquid-repellency after physical damage (within 0.1-1 s), resist ice, microorganisms and insects adhesion, and function at high pressures (up to at least 690 atm). Some exemplary application where slippery liquid-infused porous surfaces will be useful include energy-efficient fluid handling and transportation, optical sensing, medicine, and as self-cleaning, and anti-fouling materials operating in extreme environments.

Abstract: Described are methods and compositions for inhibiting polymerization of a monomer (e.g., styrene) composition using a hydroxylated quinone antipolymerant. The hydroxylated quinone antipolymerant can be used with little or no nitroxyl group containing antipolymerant yet still provide excellent antipolymerant activity in a monomer-containing composition.

Abstract: A slurry for polishing surfaces or substrates that at least partially comprise ruthenium and copper, wherein the slurry includes an alkali hydroxide, oxygenated halogen compound, and a halogen alkyl benzotriazole. The slurry may further include abrasive, acid(s), and, optionally, an alkoxylated alcohol. With these components, the slurry exhibits a high ruthenium to copper removal rate ratio.

Abstract: Methods may include admixing an additive composition with a hydrocarbon fluid, wherein the additive composition contains at least one inhibitor and at least one sub-micron particle. Additional methods may include providing an additive composition containing at least one inhibitor and at least one sub-micron particle; adding the additive composition to a fluid capable of precipitating at least one of at least of asphaltenes, wax, scale, and gas hydrates; and transporting the fluid containing the additive composition.

Abstract: A near neutral pH pickling composition for the removal of oxides from metallic surfaces, including heat treated steel. The pickling composition comprises a) a water-soluble organic or inorganic nitro compound, wherein a central N atom has an oxidation state of 3+; b) a polarizing agent for the nitro compound, wherein the polarizing agent comprises at least one of a phosphonate and a carboxylate; c) a pH buffer, and d) at least one metal complexing agent. The composition is preferably maintained at a pH between about 4.5 and about 7.5. The near neutral pH pickle composition can be used on various metallic surfaces as well as composite surfaces comprising metallic and non-metallic portions.

Abstract: Embodiments of the present invention pertain to a composite decalcification agent of calcified anaerobic granular sludge and a decalcification regeneration process.

Abstract: A polyhydroxypolycarboxylic acid and a water soluble phosphino polycarboxylate may be added to an aqueous system, such as a cooling water system, in order to inhibit corrosion as well as the deposition of corrosion within the system. The water soluble phosphino polycarboxylate may be derived from a phosphinyl unsaturated monomer and an ethylenically unsaturated carboxylic acid monomer. The aqueous system may be a cooling water system such as a cooling tower, a closed cooling water system, an air-conditioning water systems, a wastewater treatment system as well as a deionized water production system.

Abstract: An oxidative breaker system for use in reducing the viscosity of a polysaccharide-based or derivatized polysaccharide-based suspension includes a silicone carrier fluid, an oxidizer, and a suspension aid. The suspension aid is preferably fumed silica. The oxidizer may be selected from the group consisting of alkali metal peroxide, transition metal peroxide, persulfate compound, bromide compound, and bromate compound. In highly preferred embodiments, the oxidizer is magnesium peroxide or calcium peroxide. Alternative carrier fluids and suspension agents are also included in the art. Also disclosed is a method for breaking a polysaccharide-based suspension with the inventive oxidative breaker system.

Abstract: Anticorrosion compounds and compositions can be used in methods for preventing metal corrosion. More specifically, the method comprises contacting an anticorrosion composition to an aqueous system in contact with a metal. The anticorrosion composition comprises substituted and/or hydrogenated benzotriazoles and tolyltriazoles.

Abstract: The current invention relates to a micro-encapsulated, volatile vapor corrosion inhibitor (VCI), and method for the use of same. More particularly, it relates to a fluid composition, and microencapsulation of the fluid composition, that inhibits corrosion and tarnishing and that may be relatively non-toxic. The VCI is intended to be employed in varying concentrations depending on the intended application and deployed via microcapsules. The microcapsules may be adapted to release the VCI over time, or all at once. To effect this, the microcapsules may be adapted to be breached at varying times or at the same time. By adapting the microcapsules, or the method of breaching the microcapsules, the rate at which the VCI is released may be controlled.

Abstract: The present disclosure describes a strategy to create self-healing, slippery liquid-infused porous surfaces. Roughened (e.g., porous) surfaces can be utilized to lock in place a lubricating fluid, referred to herein as Liquid B to repel a wide range of materials, referred to herein as Object A (Solid A or Liquid A). Slippery liquid-infused porous surfaces outperforms other conventional surfaces in its capability to repel various simple and complex liquids (water, hydrocarbons, crude oil and blood), maintain low-contact-angle hysteresis (<2.5°), quickly restore liquid-repellency after physical damage (within 0.1-1 s), resist ice, microorganisms and insects adhesion, and function at high pressures (up to at least 690 atm). Some exemplary application where slippery liquid-infused porous surfaces will be useful include energy-efficient fluid handling and transportation, optical sensing, medicine, and as self-cleaning, and anti-fouling materials operating in extreme environments.

Abstract: The invention relates to a composition for inhibiting corrosion of the upper part (or roof) of a pipeline for conveying wet hydrocarbons, i.e. hydrocarbons comprising a variable amount of water, said composition comprising at least one Amine 1 with vapor pressure greater than or equal to 10 mmHg, and at least one. Amine 2 with vapor pressure greater than or equal to 0.1 mmHg and strictly less than 10 mmHg. The invention also relates to the use of such a composition, and also to the method of inhibiting top-of-line corrosion employing said inhibitor composition.

Abstract: The invention disclosed herein is a multifunctional agricultural organic bio-complexed composition comprising essential and non-essential nutritional elements; useful as a fertilizer, nutrient, bio-stimulant, complexing agent, pH controller, pH indicator, pH corrector, hard water salts in-activator, surface tension reducer, Spreader, penetrator, adjuvant, alkaline hard water ill effects mitigator, water conditioner and drip system irrigation cleaner. The invention also disclosed herein a process for preparation thereof.

Abstract: Self-immolative polymers degrade by an end-to-end depolymerization mechanism in response to the cleavage of a stabilizing end-cap from the polymer terminus. Examples include homopolymers, mixed polymers including block copolymers, suitable for a variety of applications. A polyglyoxylate can be end-capped or capped with a linker as in a block copolymer.

Abstract: Disclosed are methods of using nitrogen-containing compounds as corrosion inhibitors. The present method is used to inhibit corrosion of a metal surface in contact with an aqueous system using 2-substituted imidazoles and 2-substituted benzimidazoles, and provides enhanced protection against corrosion of metals in the aqueous system. The method comprises the use of corrosion inhibitors that are generally resistant to halogen attack and provide good corrosion resistance in the presence of oxidizing halogen-based biocides. Formulations comprising 2-substituted imidazoles and 2-substituted benzimidazoles are also disclosed.

Abstract: The present invention relates to a formula for an improved, volatile vapor corrosion inhibitor (VCI), and methods for using the VCI. More particularly, it relates to a fluid composition, and applications for the fluid composition, that inhibits corrosion and tarnishing and that is relatively non-toxic.

Abstract: Methods and systems for inhibiting buildup of crystalline materials in a flue gas desulfurization (FGD) unit. Crystalline materials can accumulate in FGD units as a byproduct of chemical desulfurization processes and can adversely impact FGD unit function. The systems described in the present application include an FGD unit with one or more selected bacterial strains disposed therein. It is believed that the bacteria may form a biofilm on the surfaces in the FGD and/or form a biosurfactant to inhibit or prevent buildup of crystalline materials in the FGD unit. Methods include inoculating an FGD unit with one or more selected bacteria that inhibit or prevent buildup of crystalline materials in the FGD unit. Methods may include periodic reinoculation of the FGD unit.

Abstract: Methods and systems of delivering a treatment chemical are disclosed, including providing a plurality of porous particles each having an outer surface, wherein each of the plurality of porous particles comprises a plurality of pores; infusing the plurality of porous particles with the treatment chemical; coating the plurality of porous particles with a degradable film; adding the plurality of porous particles to a carrier fluid, wherein the degradable film substantially separates the treatment chemical from the carrier fluid; introducing the carrier fluid into a formation; and allowing the degradable film to degrade within the formation.

Abstract: Flame retardant polymer compositions comprising certain polymers, a flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C. and certain clays or metal compounds such as select metal borates, oxides, hydroxides, oxide hydroxides etc., are readily processed at elevated temperatures and under high stress conditions whereas similar compositions without the clays or metal compounds of the invention are prone to decomposition. For example, polyamide compositions comprising the flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C., hydrotalcite clays, and/or borates, oxides, hydroxides, oxide hydroxides of zinc or calcium, are highly stable to thermal processing under strenuous conditions such as high temperature extrusion.

Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. Various methods for preparing flame retardant materials from more than one phosphonic acid salts are provided, wherein each method can generate different flame retardant materials from the same mixture of starting phosphonic acids. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.

Abstract: Provided is a fibrous adsorbing material used for the adsorption and recovery of metals in a solution, which is a fibrous metal-adsorbing material that can be produced using existing production facilities without using special facilities or complicated operations, has high durability, is easy to diversify, and can be processed into various forms. The fibrous metal-adsorbing material is produced by a) a step of preparing an acrylate polymer having a large number of glycidyl groups in the molecule, b) a step of kneading a low-melting-point fiber matrix polymer therewith, c) a step of making the resulting mixture into a fibrous form by an melt-blend spinning method, and d) a step of allowing a long-chain ligand having an amino group or an imino group to react with glycidyl groups on the fiber surface to introduce a metal-adsorbing functional group. The fibrous metal-adsorbing material has high durability, is easy to diversify, and has various forms.

Abstract: Provided are scale-inhibition compositions comprising (a) a first acrylic acid polymer having an average molecular weight of about 3000 to about 6000; (b) a second acrylic acid polymer having an average molecular weight of about 6000 to about 10000; (c) an aminocarboxylic acid selected from methylglycine diacetic acid (MGDA), glutamic acid diacetic acid (GLDA), diethylene triamine pentaacetic acid (DTPA), hydroxyethyl ethylene diamine triacetic acid (HEDTA), ethylenediaminetetraacetic acid (EDTA), and a combination thereof; and (d) a phosphonic acid selected from 1-hydroxyethane 1,1-diphosphonic acid (HEDP), amino tris(methylenephosphonic acid) (ATMP), ethylenediamine tetra(methylene phosphonic acid) (EDTMP), tetramethylenediamine tetra(methylene phosphonic acid) (TDTMP), hexamethylenediamine tetra(methylene phosphonic acid) (HDTMP), diethylenetriamine penta(methylene phosphonic acid) (DTPMP), and a combination thereof.

Abstract: Powder blends are described comprising blends of particulate water soluble high molecular weight polymer flocculants. The polymer flocculants can include polyethylene oxide, polyDadmac, Dadmac-acrylamide copolymers, copolymers thereof and combinations thereof. The powder blends allows the use of fine powders while reducing potential air quality and safety issues. The powder blends can be used for waste water purification, fiber dewatering, and the like. The powder blends can be diluted by a water dilution flow prior to entering a waste water stream.

Abstract: Polysaccharide agents for removing solids from an aqueous suspension and methods for using the polysaccharide agents to remove solids from an aqueous suspension.

Abstract: An oleophilic product for absorbing and retaining a hydrophobic liquid such as oil. The product comprises cones of the plant species Pinus elliottii comminuted to a mixture of particles. A method of manufacturing the product is also disclosed, as is a method of absorbing and retaining a hydrophobic liquid using the product.

Abstract: Highly porous, lightweight, and sustainable organosilane-coated organic aerogels with ultra-low densities and excellent material properties and methods for preparing them are provided. The aerogels are modified to have a superhydrophobic and superoleophilic surface, thus leading to an extremely high affinity for oils and/or organic solvents.

Abstract: Storage stable polyhydroxylated aromatic ether adducts of polyalkylene oxide are described. Reactive compositions are formed by combining an ether adduct with an aldehyde, optionally further adding a phenolic-aldehyde prepolymer. The reactive compositions are cured by removing water, by acidification, or both. The cured compositions sorb solvated compounds from environments containing water. The cured compositions are also useful for pre-loading with compounds that are subsequently released at a controlled rate into environments containing water.

Abstract: A polymer solution is mechanically mixed with at least one surfactant solution under conditions preventing air access. The produced polymer-surfactant solution is saturated with a gas by increasing pressure to a value ensuring complete gas dissolution and exceeding an expected pressure of use of aphrons. Then, the pressure is rapidly reduced to a value corresponding to the expected pressure of use of the aphrons and narrow size distribution aphrons are produced.

Abstract: A formulation for the bioremediation of soil or groundwater includes from about 80 to 95% of an emulsifiable C4-C22 vegetable oil selected from the group consisting of soybean oil, coconut oil, rapeseed (canola) oil, peanut oil, crambe oil, sunflower oil and combinations thereof; and from about 5 to 20% of an emulsifier selected from the group consisting of a vegetable oil derived from a C16-C20 fatty acid ester or a mixture of such esters. The efficacy of the formulation is improved by adding hydrogen-enriched water to the emulsifiable oil as a dilution fluid.

Abstract: Scale inhibitor compositions and methods of inhibiting scale formation generally include a tagged scale inhibiting (co)polymer including at least one scale inhibiting moiety and an imidazole moiety. The imidazole moiety fluoresces at a wavelength of about 424 nm and can be used to detect the amount of scale inhibitor present.

Abstract: Provided are a method for treating water and a flocculant used in the method. The method includes the steps of adding a first polymer compound formed by multiply binding a first repeating unit into water to be treated, and adding a second polymer compound formed by multiply binding a second repeating unit into the water. The first repeating unit includes a first linked main chain which constructs a main chain via repeatedly bound one another, and an adsorption site directly or indirectly bound to the first linked main chain so as to adsorb organic compounds contained in the water to be treated. The second repeating unit has a similar structure to the first repeating unit except that the number of carbon atoms in the second linked main chain is different from that in the first linked main chain. The flocculant includes the first and second polymer compounds.

Abstract: A preparation including a) at least one N-formal and b) at least one dialkylhydroxylamine. The preparation is preferably formulated as a concentrate. The preparation can be used (in particular in the form of the concentrate) for the reduction of free oxygen and the preservation of water, and also correspondingly additivated water. The mixture of N-formals with dialkylhydroxylamine is not only outstandingly compatible, but considerably improves the activity of dialkylhydroxylamines as oxygen scavengers.

Abstract: Dewatering agents and methods of dewatering wastewater slurries are provided. Also disclosed are methods for improving the separation of solids from water. The water may be produced water, raw water, or wastewater, for example. The dewatering agents can be in solutions and the dewatering agent solutions may include flocculants, soy based components, and surfactants. The soy based components can include, for example, soy flour and soy protein.

Abstract: The invention relates to an aqueous solution of acrylic acid polymers, obtainable by polymerization of acrylic acid in feed mode with peroxodisulfate as initiator in the presence of hypophosphite in water as solvent, wherein (i) water and optionally one or more ethylenically unsaturated comonomers are initially charged, and (ii) acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous peroxodisulfate solution and aqueous hypophosphite solution are added continuously, and (iii) a base is added on completion of the acrylic acid feed to the aqueous solution, wherein the comonomer content does not exceed 30% by weight, based on total monomer content.

Abstract: A water hardness controlling agent includes a polyacrylic acid or salt thereof having a molecular weight of between about 1,000 and about 50,000 g/mol, an acrylic-maleic acid copolymer or salt thereof having a molecular weight of between about 1,000 and about 100,000 g/mol and a phosphonocarboxylic acid or salt thereof. A ratio of acrylic-maleic acid copolymer or salt thereof to polyacrylic acid or salt thereof to phosphonocarboxylic acid or salt thereof in parts per million is about 1-30:10-80:6-20.

Abstract: The present invention relates to a photo-responsive layer and layer assembly which can be used for controlling a flow of liquid for example in a water-purification device. The photo-responsive layer according to the invention comprises a first domain comprising a first material comprising molecules having a photo-responsive moiety, wherein the first domain of the photo-responsive layer is capable of undergoing a reversible geometrical change when said photo-responsive moiety is exposed to photo-activating illumination, such as UV-radiation. The photo-responsive layer is useful in UV controlled membranes e.g. for water purification.

Abstract: Provided herein is a water purification composition containing a magnesium oxide component and a binder. In certain embodiments, the binder is selected from the group consisting of a polymeric binder, calcium aluminum silicate, and combinations of these. In certain embodiments, the polymeric binder is selected from the group consisting of polymethyl methacrylate, polyethylene, and combinations of these and is present in the composition in an amount of from about 12% to about 20% by weight. In other embodiments, the binder contains calcium aluminum silicate in an amount of from about 1% to about 15% by weight.

Abstract: The present invention relates to a water treatment composition comprising blended phosphates which exhibit a synergistic effect for corrosion and scale control and as a sequestering chemical treatment of potable water and more particularly to chemistry which lowers the phosphate concentration necessary to achieve effective corrosion prevention. The composition controls corrosion and cleans the water distribution line by removing scale, tuberculation, and biofilm. Sequestration of the heavy metals and soft metals such as iron, manganese, calcium, and magnesium provides complete solubility of the material to be removed from the metal surface. The inclusion of citric acid with the blended phosphate formula improves drinking water quality in 2 ways: 1) a reducing agent reverses the oxidation of metals which would convert metal to metal salts (copper/lead, etc.

Abstract: There is disclosed certain hyperbranched polyester amides with a cloud point of at least 50° C. with end groups selected from: betaine-type end groups useful in various end uses such as a flocculant.

Abstract: Described herein are compounds and compositions useful for removing contaminants from water, as well as methods for making and using the compounds and compositions. In one aspect, the compositions contain a source of gallium ions and a polysaccharide such as chitosan, which are inexpensive and safe for the environment.

Abstract: The invention relates to an aqueous solution of acrylic acid polymers, obtainable by polymerization of acrylic acid in feed mode with peroxodisulfate as initiator in the presence of hypophosphite in water as solvent, wherein (i) water and optionally one or more ethylenically unsaturated comonomers are initially charged, and (ii) acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous peroxodisulfate solution and aqueous hypophosphite solution are added continuously, and (iii) a base is added on completion of the acrylic acid feed to the aqueous solution, wherein the comonomer content does not exceed 30% by weight, based on total monomer content.

Abstract: Problem To provide a method for easily producing an adsorbing material used for the removal and recovery of metals and ions in a solution, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes.