Abstract: Hybrid copolymers for use as anti-scalant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one synthetic monomeric constituent that is chain terminated by a naturally occurring hydroxyl containing moiety. A process for preparing these hybrid copolymers is also provided.

Abstract: Methods, systems and compositions for a green sorption media for bioretention soil amendments in drainfields for on-site waste water systems filled with the green sorption media to foster an anaerobic or anoxic environment saturated. The green sorption media includes one or more recycled materials, including tire crumb, sawdust, orange peel, coconut husks, leaf compost, oyster shell, soy bean hulls and one or more naturally occurring materials including peat, sands, zeolites, and clay. The wastewater filtration system for a passive drainfield includes the green sorption material mixture, a cell including baffled compartments and a riser, the cell filled with green sorption material mixture to provide an alternating cycle of aerobic and anoxic environments, an influent distribution system to distribute the influent over the cell, and a piping system arranged for dosing the cell to sustain the functionality of the green sorption material mixture to remove nutrient content in wastewater.

Abstract: An efficient cyclic process and related compositions for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH. The cyclic process provides a means of safe and effective use of chlorine dioxide with reduced concern of chlorite accumulation in the aqueous system. The disclosed chemistry used to support the cyclic process can be applied independently or in various combinations that are effectively inert. This dramatically reduces safety concerns since the chlorine dioxide is produced in-situ to the application and in dilute concentrations. Also, the process allows for regeneration of inert anions such as bromide and chlorite thereby reducing operating cost.

Abstract: An efficient cyclic process and related compositions for the in-situ generation of oxyhalogens from anions of chloride, bromide and chlorite in an aqueous system using in-situ generated sulfate free radicals. The cyclic process and compositions enhance the rate of inactivation of microbiological organisms especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.

Abstract: This invention relates to a method for enhanced sanitation and oxidation of aqueous solutions at aquatic facilities. The method provides a means for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH, and enhanced inactivation rates of microbiological organisms including cryptosporidium.

Abstract: A process and method for liquid-solid separation in raw water by chemical treatment, comprising adding into the water, separately or together, an effective amount of at least one aluminum polymer with an effective amount of an ammonium polymer, including at least one medium, high, or very high molecular weight ammonium polymer, to clarify said raw water to a settled turbidity standard, and including methods for blending and storing solution polymers.

Abstract: Novel hydrated-lime slurry compositions are disclosed, which include a heat-stable polymeric dispersant. The polymeric dispersant is capable to withstand temperatures in excess of 212° F. experienced by the slurry as a result of the hydrolysis of quicklime to produce hydrated lime, and accordingly can be added to the slurry composition prior to the addition of quicklime. Methods for making such slurry compositions are also disclosed.

Abstract: A controlled release additive composition for use in aqueous coolant systems is disclosed and comprises a core containing at least one additive component and a polymeric coating including one or more defined polymers substantially surrounding the core. The controlled released additive composition slowly releases the additive component into the aqueous coolant of an open, circulating cooling water system, thereby delivering an effective concentration level of the additive component over an extended period.

Abstract: The present invention relates to a liquid additive product including at least one acid, intended, in combination with the water contained in a toilet flush cistern of a WC, to constitute an agent for treating polluting elements contained in the cistern, characterized in that the viscosity of the additive product is less than 500 mPa·s; wherein this acid is an organic acid, the concentration of which is at least equal to 30% by weight. It also relates to a treating agent consisting of the additive product and the water contained in the cistern; wherein the concentration of this additive product, in the water of the cistern, is between 100 ppm and 1000 ppm.

Abstract: The present invention provides for a mixture comprising a siloxane having the formula: M1 D M2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6) SiO1/2 and D=(R7)(Z) SiO2/2 where R1, R2, R3, R4, R5, W and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9Rc, and R10—Rz; RA being an anionic substituent, Rc a cationic substituent or Rz a zwitterionic substituent on the D group and an additional component selected from the group consisting of agricultural components, coating components, personal care components, home care components, oil or gas treating components, water processing components, and pulp or paper treating components, wherein said mixture has an enhanced resistance to hydrolysis.

Abstract: A water hardness controlling agent includes an acrylate polymer having a molecular weight of about 4,500 g/mol, an acrylate-maleic copolymer having a molecular weight of about 40,000 g/mol and a 2-phosphonobutane-1,2,4-tricarboxylic acid. A ratio of acrylate-maleic copolymer to acrylate polymer to the 2-phosphonobutane-1,2,4-tricarboxylic acid in parts per million is about 5-30:10-40:6-20.

Abstract: A water hardness controlling agent includes a polyacrylic acid or salt thereof having a molecular weight of between about 1,000 and about 50,000 g/mol, an acrylic-maleic acid copolymer or salt thereof having a molecular weight of between about 1,000 and about 100,000 g/mol and a phosphonocarboxylic acid or salt thereof. A ratio of acrylic-maleic acid copolymer or salt thereof to polyacrylic acid or salt thereof to phosphonocarboxylic acid or salt thereof in parts per million is about 1-30:10-80:6-20.

Abstract: A water hardness controlling agent includes a polyacrylic acid or salt thereof having a molecular weight of between about 1,000 and about 50,000 g/mol, an acrylic-maleic acid copolymer or salt thereof having a molecular weight of between about 1,000 and about 100,000 g/mol and a phosphonocarboxylic acid or salt thereof. A ratio of acrylic-maleic acid copolymer or salt thereof to polyacrylic acid or salt thereof to phosphonocarboxylic acid or salt thereof in parts per million is about 1-30:10-80:6-20.

Abstract: The invention pertains to a device for generating aqueous chlorine dioxide solutions when the device is contacted with liquid water. The device comprises an alkali metal or alkaline earth metal chlorite, e.g., sodium chlorite, and a chemical reagent comprising an acid or a material capable of releasing an acid upon exposure to liquid water, e.g., sodium bisulfate. The chlorite and the reagent are either combined as a mixture or are disposed as separate components adhered to the surface of one or more substrates. Upon exposure to liquid water, the chlorite and the reagent produce boundary layers. The chlorite and the reagent are disposed upon, and adhered to, the surface(s) of the substrates in a manner such that upon exposure to liquid water, the chlorite boundary layer comes into contact with the reagent boundary layer to thereby produce an aqueous chlorine dioxide solution.

Abstract: A microcapsule comprising A) a core containing a hydrophobic liquid or wax, B) a polymeric shell comprising a) a polymer formed from a monomer mixture containing: i) 1 to 95% by weight of a hydrophobic mono functional ethylenically unsaturated monomer, ii) 5 to 99% by weight of a polyfunctional ethylenically unsaturated monomer, and iii) 0 to 60% by weight of other mono functional monomer, and b) a further hydrophobic polymer which is insoluble in the hydrophobic liquid or wax. The invention includes a process for the manufacture of particles and the use of particles in articles, such as fabrics, and coating compositions, especially for textiles.

Abstract: A method and composition for processing natural water such as seawater, brackish, and estuarine water wherein the water is concentrated with or without heating comprising adding to the water (I) a water-soluble polymeric phosphonate and (II) a water-soluble polycarboxylate to control scale formation and deposition. Optionally a water -soluble poly[isopropenylphosphonic acid] can also be utilized as component (I) without the addition of component (II).

Abstract: This invention relates to metal oxides dispersant compositions comprising (a) certain a metal oxides dispersant, and (b) an oxime. The invention also relates to a process for dispersing metal oxides in an aqueous system that involves adding the dispersant composition to the aqueous system.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: The invention relates to a method of controlling silica scale in an aqueous system, including adding an effective amount of mixture of a first polymer and a second polymer into the aqueous system, wherein the first polymer and the second polymer each has at least one of a first structural unit derived from any of quaternary ammonium monomer, quaternary phosphonium monomer, and quaternary sulfonium monomer and a second structural unit derived from any of sulfonic acid, sulfuric acid, phosphoric acid, carboxylic acid and any salt thereof, the first polymer bears a first net charge or being neutral, the second polymer bears a second net charge opposite the first net charge or bearing positive net charge when the first polymer is neutral, the first structural unit is from about 1 mol % to about 99 mol % of the mixture.

Abstract: The present invention relates to a method for improving the hydrolysis stability of an ionic liquid (IL), in which at least one tertiary amine or one quaternary ammonium compound different from the ionic liquid (IL) is added to an ionic liquid (IL).

Abstract: Improved treatment blocks useful in the treatment of lavatory appliances, particularly toilets are provided. The improved treatment blocks are solid block compositions which comprise at least one detersive surfactant, a film forming constituent, optionally a bleach constituent and one or more further optional constituents. The improved treatment blocks provide good detersive characteristics and further provide a film forming material which contacts the surfaces of the lavatory appliance, e.g., toilet, in which the block compositions are used. Methods of producing the solid block composition and treatment blocks therefrom, as well as methods of use are also disclosed.

Abstract: A solid formulation for use with sodium chloride and a chlorine generator to provide safe, clean chlorinated recreational water. The formulation comprises a chlorine stabilizing agent and a phosphate remover agent. An enhanced salt comprising a chlorine stabilizing agent, a phosphate remover agent and sodium chloride is also described. The formulation and enhanced salt can also contain a metal chelating agent and a pH balancing agent. A cleaning agent may also be included. A fast dissolving sodium cyanurate compound is used for the chlorine stabilizing agent. A method, kit, and system for providing safe, clean chlorinated recreational water are also disclosed.

Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.

Abstract: Materials and a method are provided whereby polymers with least 0.5 mole % of the pendant group or end group containing —Si(OR?)3 (where R? is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in an industrial process having an alkaline process stream such as a pulping mill process stream. When materials of the present invention are added to the alkaline process stream, they reduce and even completely prevent formation of aluminosilicate scale on equipment surfaces such as evaporator walls and heating surfaces. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: The present invention proposes a composite material which can rapidly and effectively remove algae and transform them into submerged macrophytes. The composite material is a mixture of two functional materials: one can grow into submerged macrophytes, and the other is clays or modified local soil particles which can flocculate algae, inhibit phosphorus release from sediments and act as the carrier of the above-mentioned seeds, earthnuts, buds, and roots of submerged macrophytes. In addition, the present invention proposes a physical-chemical-ecological combined method for improving water quality and enhancing the ecological restoration of eutrophic lakes using the above-mentioned material. By spraying the composite material to the lake surface, the new method can remove algae and turbidity through flocculation and complete the planting process simultaneously so that HABs and eutrophication are effectively controlled.

Abstract: The present invention relates to a process for preparing a phosphorus-containing polymer, comprising the steps of (i) copolymerizing at least (a) monoethylenically unsaturated dicarboxylic anhydrides having from 4 to 6 carbon atoms with (b) olefins of the formula CH2?C(R1)R2 where R1 is H or CH3 and R2 is H, CH3, C2H5 or phenyl; (ii) reacting the polymer formed in step (i) with at least one primary or secondary phosphorus-containing amine or a phosphorus-containing alcohol and (iii) at least partly ring-opening the remaining anhydride groups. The invention further relates to phosphorus-containing polymers obtainable from this process, and to processes for preventing Ba/Sr scale with the aid of the polymer.

Abstract: Alkyl phosphonates prepared from amino acids suitable for use in inhibiting scale. The phosphonates are obtained as reaction mixtures where the level of alkyl phosphonation is deliberately controlled to provide only partial alkyl phosphonation of the amino acid. The resulting alkyl phosphonates exhibit improved environmental properties compared to the fully substituted species, while still exhibiting acceptable efficacy in the control of scale. The compositions possess advantages over existing phosphonates in that they exhibit higher biodegradation by method OECD 306. They also offer lower toxicity to marine life compared to the fully substituted species and are not expected to bioaccumulate.

Abstract: A solid zeolite free soluble water softening composition comprises an effervescent system including an organic acid and an alkali which react together upon dissolution in water.

Abstract: Novel hydrated-lime slurry compositions are disclosed, which include a heat-stable polymeric dispersant. The polymeric dispersant is capable to withstand temperatures in excess of 212° F. experienced by the slurry as a result of the hydrolysis of quicklime to produce hydrated lime, and accordingly can be added to the slurry composition prior to the addition of quicklime. Methods for making such slurry compositions are also disclosed.

Abstract: A swellable sol-gel composition includes a plurality of interconnected organosilica nanoparticles. When dried, the swellable sol-gel composition is capable of swelling to at least twice its dried volume when placed in contact with a non-polar or organic sorbate.

Abstract: One aspect of the present invention includes a swellable sol-gel composition including a plurality of interconnected organosilica nanoparticles. Another aspect of the present invention includes a swellable composite including a plurality of interconnected organosilica nanoparticles and a particulate material capable of binding to or reacting with a non-polar or organic sorbate. When dried, the sol-gel composition and the swellable composite may be capable of swelling to at least twice their dried volume when placed in contact with a non-polar or organic sorbate.

Abstract: A method is provided for inhibiting scale in a hydrocarbon system, including the steps of: providing a hydrocarbon system; providing an aloe-derived scale inhibitor; and mixing the aloe-derived scale inhibitor with the hydrocarbon system in amounts effective to inhibit formation of scale. The scale inhibitor is an aloe vera gel/aloe sap mix dissolved in water at a concentration of between about 5 and about 50% wt/wt, which includes polysaccharides having a hydrocarbon chain structure having carboxyl and alcohol functional groups that interact with divalent ions.

Abstract: A method is provided for inhibiting scale in a liquid hydrocarbon system, including the steps of: providing a liquid hydrocarbon system; providing an aloe-derived scale inhibitor; and mixing the aloe-derived scale inhibitor with the liquid hydrocarbon system in amounts effective to inhibit formation of scale. The scale inhibitor is aloe gel dissolved in water at a concentration of between about 5 and about 50% wt/wt, which includes polysaccharides having a hydrocarbon chain structure having carboxyl and alcohol functional groups that interact with divalent ions.

Abstract: Hybrid copolymers for use as anti-sealant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one synthetic monomeric constituent that is chain terminated by a naturally occurring hydroxyl containing moiety. A process for preparing these hybrid copolymers is also provided.

Abstract: Materials and a method are provided whereby polymers with least 0.5 mole % of the pendant group or end group containing —Si(OR?)3 (where R? is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in an industrial process having an alkaline process stream such as a pulping mill process stream or a high level nuclear waste processing plant. When materials of the present invention are added to the alkaline process stream, they reduce and even completely prevent formation of aluminosilicate scale on equipment surfaces such as evaporator walls and heating surfaces. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: Compositions for removing scale and/or inhibiting formation thereof include an alkaline agent, a primary scale inhibitor, a secondary scale inhibitor and a solvent. The primary scale inhibitor may include phosphonic acid, salts of phosphonic acids and combinations thereof. Suitable secondary scale inhibitor may include aminocarboxylic acids, salts of aminocarboxylic acids, carboxylic acids, salts of carboxylic acids, polycarboxylic acids, salts of polycarboxylic acids, gluconic acids, salts of gluconic acids, steroids, tetrapyrrols, ionophores, 2,2?-bipyridine, dimercaptopropanol, ortho-phenanthroline and combinations thereof. The compositions may be prepared as a stable concentrates that have pH values greater than or equal to 11. The compositions may also be prepared on site as a use solution. Methods of using the compositions to extend system operating times and to remove scale from and/or inhibit formation of scale on an article are also disclosed.

Abstract: A microcapsule comprising a core containing a hydrophobic liquid or wax and a polymeric shell formed from: i) 1 to 20% by weight of polymerisable silane compound, ii) 1 to 94% by weight of hydrophobic mono functional ethylenically unsaturated monomer, iii) 5 to 98% by weight of polyfunctional ethylenically unsaturated monomer, and iv) 0 to 60% by weight of other mono functional monomer(s), wherein components (i), (ii), (iii) and (iv) total 100%, and in which the microcapsule also includes a hydrophilic polymer which is covalently bonded to the microcapsule. The invention includes a process for the manufacture of particles and the use of particles in articles, such as fabrics, and coating compositions, especially for textiles.

Abstract: Water-soluble amino acid copolymers, modified polysaccharides, acrylamide polymers, and combinations thereof, are described, for uses including flocculation of solids, particularly flocculation of soil, such as in an agricultural setting. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.

Abstract: Heat exchanger fouling in organic chemical production processes may be reduced using an antifoulant additive. The antifoulant additive may have one component selected from the group consisting of an alkylphosphate ester, and an alpha olefin maleic anhydride copolymer; or it may have two components selected from the group consisting of a metallic overbase, an alkylphosphate ester, and an alpha olefin maleic anhydride copolymer, wherein at least one of the two components in not an overbase. An additive having three components: a metallic overbase, an alkylphosphate ester, and an alpha olefin maleic anhydride copolymer; is also within the scope of the disclosure. The abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.

Abstract: The present invention relates to use of compositions comprising: (a) a copolymer of an unsaturated phosphonic acid (or salt of such an acid) with an unsaturated sulphonic acid (or salt of such an acid) or an unsaturated carboxylic acid (or salt of such an acid); or (b) a terpolymer of an unsaturated phosphonic acid (or salt of such an acid) with an unsaturated sulphonic acid (or salt of such an acid) and an unsaturated carboxylic acid (or salt of such an acid). These compositions are used to control the formation of scale in water systems.

Abstract: The present invention relates to a method of preventing or alleviating the problems associated with corrosion and to novel formulations for use in such a method.

Abstract: Provided is an agglomeration for neutralizing acid mine drainage which includes a neutralizer and binder component consisting of steel slag in an amount of 75% to 95% by weight of the agglomeration, a sodium carbonate selected from the group consisting of soda ash and pulp liquor in an amount of 0.5% to 25% of the agglomeration, and, optionally, a lime component selected from the group consisting of limestone sand and slag. Further included is a dissolution control and filtration component consisting of an organic material in an amount of 0.24% to 15% by weight of the agglomeration selected from the group consisting of recycled newsprint, sphagnum peat moss, and sawdust. Next is a dispersant and neutralizer component consisting of a surfactant in an amount of 0.01% to 0.075% by weight of the agglomeration. The agglomeration may further comprise an oxidation component such as calcium peroxide, potassium permanganate, and hydrogen peroxide.

Abstract: The present invention provides a beverage surfactant composition that includes a surfactant, a phosphonium compound, and a carrier; wherein the beverage surfactant composition exhibits stability as a solution or as a dispersion at a temperature of about 0° C. to about 8° C. The present invention also provides a container or a conveyor for a container having a surface that is at least partially coated with the composition. The present invention also provides a process for lubricating a container that includes contacting at least a portion of a surface of the container and the composition together. The present invention also provides a process for lubricating a conveyor that includes contacting at least a portion of a surface of the conveyor and the composition together.

Abstract: A cleaning and purifying composition including at least one solvent, an alkaline agent, a deflocculant, at least one surfactant selected from the group comprising an alcohol ethoxylate surfactant, an alkylamino-polyethoxy-sulfate surfactant, a polyether-phosphate ester surfactant, a surfactant that is a phosphate ester of an ethoxylated alcohol, and a surfactant that is a polyethyleneglycol monoaklyl ether, and a bonding agent.

Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of at least 3000 g/mol to at most 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and other ethylenically unsaturated comonomers, the polymerization for producing the copolymer being performed in the presence of from 0.01 to 100 mol % of at least one base, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids, the quantitative figures in % by weight being respectively based on the total amount of all monomers used.

Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of greater than 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and optionally other ethylenically unsaturated comonomers, the quantitative figures being respectively based on the total amount of all monomers used.

Abstract: A phosphorus-acid-group-containing (meth)acrylamide polymer having high electrolytic group density and excellent conductivity is obtained by introducing a phosphorus acid group into a (meth)acrylamide monomer which may be N-substituted, and polymerizing the resultant monomer. This polymer is usable for conductive resins, proton-conductive polymer electrolyte membranes and coating agents.

Abstract: Materials and a process are provided whereby polymers with the pendant group or end group containing —Si(OR?)3 (where R? is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in a Bayer process. When materials of the present invention are added to the Bayer liquor before the heat exchangers, they reduce and even completely prevent formation of aluminosilicate scale on heat exchanger walls. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: This invention relates to a method of softening water and/or in which the deposition of hard water scale is inhibited. The invention relates in particular to such a method carried out in a domestic environment, in particular in ware-washing machines. A compressed water-softening composition comprising a water softening active and a blend of disintegrating agents, comprising a cross-linked polyplasdone, a water-swellable cellulose and optionally a water soluble salt is claimed.

Abstract: Materials and a method are provided whereby polymers with least 0.5 mole % of the pendant group or end group containing —Si(OR?)3 (where R? is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in an industrial process having an alkaline process stream such as a pulping mill process stream. When materials of the present invention are added to the alkaline process stream, they reduce and even completely prevent formation of aluminosilicate scale on equipment surfaces such as evaporator walls and heating surfaces. The present materials are effective at treatment concentrations that make them economically practical.