Contains Group Ia Metal Peroxide Patents (Class 252/186.32)
  • Patent number: 8758631
    Abstract: A method for decontaminating a liquid having sulfides includes preparing a stabilized sodium percarbonate solution. In an embodiment, the method includes decontaminating a liquid. The liquid comprises reactive sulfides. The method also includes preparing a stabilized sodium percarbonate solution, which includes adding sodium percarbonate to a liquid solution. The liquid solution comprises a peroxide stabilizer and an acid. The method further includes dosing the liquid into the stabilized sodium percarbonate solution to decontaminate the liquid by oxidizing at least a portion of the reactive sulfides.
    Type: Grant
    Filed: May 13, 2011
    Date of Patent: June 24, 2014
    Assignee: United Laboratories International, LLC
    Inventors: Stephen D. Matza, Jack G. Frost
  • Patent number: 8652434
    Abstract: The present invention discloses a compound comprising an expanded percarbonate salt having less than about 24 wt. % hydrogen peroxide. Also disclosed in this invention is a composition including the above-mentioned compound and a liquid loaded thereon. Further, there is disclosed a method of manufacturing the above-described compound.
    Type: Grant
    Filed: February 27, 2012
    Date of Patent: February 18, 2014
    Assignee: ChemLink Laboratories, LLC
    Inventors: Ryan Giffin Moore, Joseph Matthew Garmon, Bridget Nicole Lemley
  • Publication number: 20120193302
    Abstract: A method for decontaminating a liquid having sulfides includes preparing a stabilized sodium percarbonate solution. In an embodiment, the method includes decontaminating a liquid. The liquid comprises reactive sulfides. The method also includes preparing a stabilized sodium percarbonate solution, which includes adding sodium percarbonate to a liquid solution. The liquid solution comprises a peroxide stabilizer and an acid. The method further includes dosing the liquid into the stabilized sodium percarbonate solution to decontaminate the liquid by oxidizing at least a portion of the reactive sulfides.
    Type: Application
    Filed: May 13, 2011
    Publication date: August 2, 2012
    Applicant: UNITED LABORATORIES INTERNATIONAL, LLC
    Inventors: Stephen D. Matza, Jack G. Frost
  • Patent number: 7794607
    Abstract: Compositions and methods for their use are presented that substantially increase the rate of inactivation of microbiological organisms, especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines, cyanuric acid and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: September 14, 2010
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7695631
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: April 13, 2010
    Assignee: Truox, Inc.
    Inventor: Roy W Martin
  • Patent number: 7572390
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor, a transition metal catalyst in contact with the persulfate donor, and a cationic electrolyte. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing product may be applied while the aquatic facilities are being used. A free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate. The cationic electrolyte facilitates the removal of the catalyst from the water.
    Type: Grant
    Filed: September 14, 2005
    Date of Patent: August 11, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7572384
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: August 11, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7488439
    Abstract: Dust-free alkaline earth peroxides are obtained by mixing alkaline earth peroxides with a compacting aid and dry-compacted in a compactor, for example, a roller press. Examples of suitably useful compacting aids include sodium bicarbonate, cellulose, magnesium montanate and cross-linked silicone compounds.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: February 10, 2009
    Assignee: Solvay Chemicals GmbH
    Inventors: Werner Doetsch, Ernst Buchholz
  • Patent number: 7476333
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: January 13, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7344656
    Abstract: Stable oxidizing compositions and a method of preparing such compositions are presented. The compositions include a peroxygen, for example, a potassium monopersulfate or, percarbonate particle suspended in an alcoholic gel. The alcohol content in the gel is such that the peroxygen particle is prevented from coming into contact with water during storage, thereby helping maintain a high available oxygen level. When the alcoholic gel is mixed with water, it becomes less viscous and exposes the peroxygen particle to the water. The peroxygen is ready for use when it dissolves in the water.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: March 18, 2008
    Assignee: Truox, Inc.
    Inventor: Perry L. Martin
  • Patent number: 7241433
    Abstract: The invention relates to a process for the preparation of coated granular sodium percarbonate having a low TAM value. The preparation is carried out by fluidized-bed spray granulation at a temperature TG in the range from 45 to 75° C., and the coating is effected by the spray application of an aqueous solution containing at least one coating component in a fluidized bed at a temperature TU in the range from 35 to 100° C. According to the invention, a) after the fluidized-bed spray granulation but before the coating, drying is carried out at TNT of greater than TG, or b) the fluidized-bed granulation is carried out in at least two steps at TG1, TG2 . . . TGn, TG2 or TGn being higher than TG1, and drying being unnecessary if ? of the granulate have been formed at TG1, or c) drying takes place not after the granulation but after the coating, at TUNT, TUNT being at least 20° C. higher than TG.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: July 10, 2007
    Assignee: Degussa GmbH
    Inventors: Harald Jakob, Waldemar Hessberger, Juergen Lattich, Ralph Overdick
  • Patent number: 6255272
    Abstract: The invention relates to particles comprising a peroxy compound with capability of realeasing hydrogen peroxide or peroxy acids in aqueous solutions and an amino acid of the formula (HOOC)2N—CnHmCOOH—R in which R is H, CH2OH OR CH3, n is 1, 2 or 3 and m is 0-2n; or a salt thereof. The invention also relates to use of the particles and a composition comprising such particles.
    Type: Grant
    Filed: April 5, 2000
    Date of Patent: July 3, 2001
    Assignee: Eka Chemicals AB
    Inventors: Hans Lagnemo, Monica Jigstam
  • Patent number: 6239095
    Abstract: A process for the preparation of coated peroxygen compounds, in particular sodium percarbonate, by fluidized bed coating. By using a fluidized bed reactor with a radial inflow base, the passage openings of which allow the fluidized bed gas to emerge in the region of the opening at an angle of less than 35°, measured with respect to the horizontal, in the form of directed part streams, and in which are arranged spray nozzles, the pulse of which points in the same direction as the pulse of the fluidizing gas, it is possible to obtain products with an increased active oxygen stability. A circular reactor, the inflow base of which has lamellae overlapping like turbine blades and nozzles aligned in the direction of rotation of the fluidized bed is preferred.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: May 29, 2001
    Assignee: Degussa-Huls Aktiengesellschaft
    Inventors: Birgit Bertsch-Frank, Martin Bewersdorf, Lothar Kaiser, Rainer Kohlen, Ralph Overdick, Michael Scheibe