Abstract: A salt of an acidic chelating agent including an amine functionality, the salt comprising at least 0.25 mole of an alkaline earth metal per mole of acidic protons provided by the chelating agent; wherein the acidic chelating agent is not ethylene diamine disuccinic acid.

Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%. Other embodiments include one or more oxidatively active halides of a nonoxidative metal dispersed on sorbent substrate particles mixed with activated carbon in an amount up to 30% by weight. Further embodiments include physical blending of a flow modifier into the sorbent composition.

Abstract: The present invention discloses a compound comprising an expanded percarbonate salt having less than about 24 wt. % hydrogen peroxide. Also disclosed in this invention is a composition including the above-mentioned compound and a liquid loaded thereon. Further, there is disclosed a method of manufacturing the above-described compound.

Abstract: A method for the combined chemical oxidation/assisted bioremediation of contaminated materials, comprising contacting a contaminated material with at least one metal chelate and at least one peroxide compound.

Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.

Abstract: The present invention relates to a process for producing odor-inhibiting water-absorbing composites comprising water-absorbing polymer particles and fibers, wherein the fibers are premixed with at least one metal peroxide, metal hyperoxide or metal ozonide.

Abstract: Mixtures of additives in granular form comprising: one or more stabilizers for organic polymers; one or more organic or inorganic pigments; and/or one or more dyes; obtained by extrusion at a temperature capable of enabling the partial or total melting of the lowest-melting component. The above mixtures can be used in the stabilization and dyeing of organic polymers.

Abstract: The present invention is directed to a water treatment composition, comprising: calcium hypochlorite coated with a coating comprising at least one hydrated or anhydrous salt. The present invention is also directed to a water treatment composition, comprising: (a) an inner core layer comprising calcium hypochlorite; (b) one or more interlayers of selected salts positioned on top of said inner core layer, and (c) one or more outer layers of selected salts positioned on top of said interlayer(s).

Abstract: A hard surface detergent composition is provided, said composition comprising a peroxygen bleach capable of exhibiting bleaching properties at a pH of below 9, and an amino ketone or derivative thereof bleach activator, and wherein a 1% wt solution in distilled water at 25° C. of the composition has a pH lower than 9. Potassium monopersulphate is the preferred bleach compound and diethyl amino acetone or derivative thereof is the preferred bleach activator. The compositions exhibit good bleaching performance at pHs of less than 9.

Abstract: Sodium percarbonate particles with a coating layer which comprises from 70 to 99.8% by weight of anhydrous sodium sulfate and from 0.2 to 20% by weight of a sodium borate, and whose proportion by weight is from 1 to 10% based on the mass of the sodium percarbonate particle, exhibit a high storage stability in detergent and cleaning composition formulations through a synergistic effect of sodium sulfate and sodium borate on the storage stability, and at the same time only have a small content of boron.

Abstract: A salt of an acidic chelating agent including an amine functionality, the salt comprising at least 0.25 mole of an alkaline earth metal per mole of acidic protons provided by the chelating agent; wherein the acidic chelating agent is not ethylene diamine disuccinic acid.

Abstract: The invention relates to a bleach system comprising at least one component selected from bleach, bleach activator or bleach catalyst, wherein the bleach system is enveloped with at least one polymer layer and the polymer has urethane and urea groups. The inventive bleach system and detergent formulations comprising this bleach system are suitable for washing or cleaning textiles or dishware.

Abstract: A method of reducing styrene emissions in aqueous cured-in-place pipe closed molding processes and other aqueous environments using a styrene reduction agent. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. Capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process in order to reduce the residual monomer content in either process or waste streams.

Abstract: The present invention relates to a use of a two-way spray nozzle (1) with protective gas for manufacturing granular sodium percarbonate, said nozzle comprising a central tube (2) having an outlet for an aqueous hydrogen peroxide solution, an inner jacket tube (3) arranged coaxially around the central tube, and having an outlet for aqueous sodium carbonate solution, an outer jacket tube (4) arranged coaxially around the central tube and inner jacket tube, and having an outlet for a protective gas, a threaded ring slot (5) arranged around the central tube at a distance from the outlet of the central tube, wherein the threads of the ring slot are arranged at an angle ? with respect of the direction of the longitudinal axis (12) of the central tube, and in which said protective gas is used at a pressure of less than 0.7 bar. The present invention also relates to a method for manufacturing granular sodium percarbonate.

Abstract: The production of bleaching agent granulates, wherein a particulate peroxide compound and a water soluble polymer which can be ionotropically cross-linked are granulated into a primary granulate using a liquid binding agent containing water, and the primary granulate is brought into contact with a cross-linking agent for the water soluble polymer which can be ionotropically cross-linked. A particle so obtained can be worked into liquid detergents and cleaning agents containing water and remain stable.

Abstract: A cleaning, disinfection, and indicator agent comprising a water-soluble permanganate, particularly for mixture with an agent for ensuring an alkaline milieu having a pH value of at least 11, which, in addition to the water-soluble permanganate, contains a further oxidizing agent, whose oxidation potential is above that of manganese VII to manganese VI, pH buffer substances, preferably primary and/or secondary alkali carbonates such as sodium carbonate and/or sodium hydrogen carbonate, as well as oxidation-resistant polyphosphates. Furthermore, methods for cleaning, disinfecting, and monitoring the cleanliness of commercial and industrial plants or plant components and the use of an agent according to the present invention as an indicator solution for ascertaining the cleanliness of commercial and industrial plants or plant components by ascertaining the intensity of the light emitted in the violet wavelength range by the solution are described.

Abstract: Coated sodium percarbonate particles having a mean particle size of from 300 to 1600 ?m containing a sodium percarbonate core surrounded by at least one coating layer, the coating layer comprising at least one coating agent and small sodium percarbonate particles of a mean particle size smaller than 100 ?m. Process for the production of these particles by coating sodium percarbonate core particles with at least one coating agent and with small sodium percarbonate particles of a size smaller than 100 ?m. Use of these particles as bleaching agent in detergent compositions and detergent compositions containing them.

Abstract: The present invention concerns the treatment of a cellulose material in the presence of a transition metal catalyst, hydrogen peroxide whilst maintaining the pH of the treatment mixture.

Abstract: A styrene reduction agent that effectively and economically reduces styrene emissions in Cured-In-Place Pipe, closed molding processes. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. Capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process in order to reduce the residual monomer content in either process or waste streams.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fiber material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a polylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 5. The invention also relates to peroxide bleaching processes.

Abstract: The current invention encompasses a microemulsion having environmentally safe components, the microemulsion exhibiting optical clarity and stability over a wide range of temperatures. The microemulsion also forms a part of a decontaminant solution for treating chemical and biological contaminant agents, the solution preferably containing peroxycarboxylic acids generated from solids as the primary decontamination agent. The solution is a single phase emulsion that is both stable and effective over a broad range of temperatures, the range extending well below 0° C. There is also disclosed a microemulsion decontaminate solution having components that stabilize the included solid and peroxycarboxylic acids.

Abstract: A combination of a styrene reduction agent and a catalyst that effectively and economically reduces styrene emissions in Cured-In-Place Pipe, closed molding processes. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. The catalyst is hydrogen peroxide (H2O2). A calibrated amount of the styrene reduction agent capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process, and this is followed by a calibrated amount of the H2O2 catalyst in order to reduce the residual monomer content in either process or waste streams.

Abstract: Compositions and methods for their use are presented that substantially increase the rate of inactivation of microbiological organisms, especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines, cyanuric acid and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.

Abstract: This invention relates to a novel non-aqueous liquid oxygen bleach composition prepared by dispersing solid peroxygen compound in the liquid in which the content of an anhydrous non-polar organic solvent and a non-ionic and anionic surfactant is controlled. The composition is formed in a high viscous paste or a gel-type suspension and can be used as a multi-purpose composition, for example, the bleach and stain remover of clothes and the cleanser of bathroom and kitchen since they have a chemical/physical stability of no loss of available oxygen, an excellent bleaching and cleaning ability due to their alkaline pH range, no change of viscosity or no phase separation during the storage and so on.

Abstract: The current invention encompasses a microemulsion having environmentally safe components, the microemulsion exhibiting optical clarity and stability over a wide range of temperatures. The microemulsion also forms a part of a decontaminant solution for treating chemical and biological contaminant agents, the solution preferably containing peroxycarboxylic acids generated from solids as the primary decontamination agent. The solution is a single phase emulsion that is both stable and effective over a broad range of temperatures, the range extending well below 0° C. There is also disclosed a microemulsion decontaminate solution having components that stabilize the included solid and peroxycarboxylic acids.

Abstract: Coated sodium percarbonate particles, having an inner shell layer which comprises at least one inorganic, hydrate-forming salt as the main constituent, and an outer shell layer which comprises an alkali metal thiosulfate, an alkaline earth metal thiosulfate and/or an ammonium thiosulfate, are stable to storage and have an improved storage stability in detergents and cleaning agents. Detergents and cleaning agents which comprise such sodium percarbonate particles show a reduced oxidative attack on oxidation-sensitive constituents of the composition during storage. Machine dishwashing agents in the form of tablets which comprise such sodium percarbonate particles and a corrosion protection agent for silver show a reduced yellowing of the tablets during storage.

Abstract: The present invention is directed to stabilized peracid compositions. Stabilizing compositions including a metal salt and a chelating agent are added to compositions including peracids. The results stabilized peracid compositions have increased shelf life and storage stability.

Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.

Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fiber material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a polylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 8, The invention also relates to peroxide bleaching processes.

Abstract: A laundry detergent composition with a limited number of natural ingredients containing a hydrogen peroxide source, sodium carbonate and a surfactant selected from a fatty alcohol sulfate, alkyl polyglucoside and a lauryl sarcosinate. The laundry composition optionally has a fragrance, colored speckles, builder and enzymes. The laundry detergent composition can be used to clean tough stains on fabrics and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.

Abstract: The invention concerns coated sodium percarbonate granules comprising a core produced by fluidized bed spray granulation, containing sodium percarbonate as its main component, an inner coating layer containing an organic, hydrate-forming salt as its main component, and an outer coating layer containing as its main component at least one surfactant containing in the molecule one or more sulfate or sulfonate groups in the form of an alkali metal, alkaline-earth metal or ammonium salt. The invention also concerns a process for the production of the granules, the use of the granules in bleaching and cleaning agents, and bleaching and cleaning agents containing the granules. The sodium percarbonate granules according to the invention display improved storage stability combined with high internal stability and a high active oxygen content.

Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.

Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor, a transition metal catalyst in contact with the persulfate donor, and a cationic electrolyte. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing product may be applied while the aquatic facilities are being used. A free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate. The cationic electrolyte facilitates the removal of the catalyst from the water.

Abstract: A method of treating a peroxygen compound (e.g., potassium monopersulfate) for use in applications where controlled release rate, exposure to incompatible compounds, and/or moisture is presented. The method incorporates coating the peroxygen compound with one or more of the following polymers: 1) chitin/chitosan, 2) carboxylate/sulfonate copolymer or tertiary polymer, and 3) carboxylate polymer selected from polymaleic acid, polyepoxysuccinic acid and/or phosphinocarboxylate polymers. Optionally, the peroxygen compound is also coated with an inorganic salt layer and a silicate layer. Potassium monopersulfate coated with an organic polymer is useful in reduced allergenic formulations and as an anti-caking agent. When the organic polymer is a polysaccharide, the coated potassium monopersulfate is also effective for shock treatment of water systems (e.g., pools). The oxidizing composition prepared with this method has a prolonged shelf life while demonstrating good solubility during use.

Abstract: The present invention relates to the use as perfuming ingredient of a compound of formula wherein R represents a hydrogen atom or a methyl or ethyl group, and R1 represents (i) a (Me)(R2)C?C(R3) group, R2 representing a hydrogen atom or a methyl group and R3 representing a methyl or ethyl group, or (ii) a phenyl group optionally substituted by one or two methyl groups; as well as to the compositions or articles associated with these compounds.

Abstract: Dust-free alkaline earth peroxides are obtained by mixing alkaline earth peroxides with a compacting aid and dry-compacted in a compactor, for example, a roller press. Examples of suitably useful compacting aids include sodium bicarbonate, cellulose, magnesium montanate and cross-linked silicone compounds.

Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.

Abstract: A dissolved oxygen releasing blend is disclosed utilizing magnesium peroxide blended with powdered Bentonite and/or vegetable oil. The Bentonite (or other clay material) reduces the hydraulic conductivity of magnesium peroxide, thereby reducing the rate of magnesium peroxide disassociation.

Abstract: A reactor for an in-situ production of a chemical product in high yield are presented. The reactor, which may be placed in a main solvent, includes a core and a reactor wall around the core. The reactor wall allows controlled permeation of the main solvent to the core. The core contains a reactant that reacts to produce a target product upon being contacted by a main solvent. The target product leaves the reactor at a controlled rate. Because the amount of the main solvent that permeates into the reactor is controlled, a high concentration of the reactant is maintained inside the reactor, resulting in a higher yield of the desired chemical product than if the reactants were directly added to the body of main solvent.

Abstract: Stable oxidizing compositions and a method of preparing such compositions are presented. The compositions include a peroxygen, for example, a potassium monopersulfate or, percarbonate particle suspended in an alcoholic gel. The alcohol content in the gel is such that the peroxygen particle is prevented from coming into contact with water during storage, thereby helping maintain a high available oxygen level. When the alcoholic gel is mixed with water, it becomes less viscous and exposes the peroxygen particle to the water. The peroxygen is ready for use when it dissolves in the water.

Abstract: Use of metal complex compounds of formula (1) and/or (1?) [LnMemXp]zYq,??(1) [L?nMemXp]zYq,??(1?) wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.

Abstract: The invention relates to a process for the preparation of coated granular sodium percarbonate having a low TAM value. The preparation is carried out by fluidized-bed spray granulation at a temperature TG in the range from 45 to 75° C., and the coating is effected by the spray application of an aqueous solution containing at least one coating component in a fluidized bed at a temperature TU in the range from 35 to 100° C. According to the invention, a) after the fluidized-bed spray granulation but before the coating, drying is carried out at TNT of greater than TG, or b) the fluidized-bed granulation is carried out in at least two steps at TG1, TG2 . . . TGn, TG2 or TGn being higher than TG1, and drying being unnecessary if ? of the granulate have been formed at TG1, or c) drying takes place not after the granulation but after the coating, at TUNT, TUNT being at least 20° C. higher than TG.

Abstract: Use of metal complex compounds of formula (1) and/or (1?) [LnMemXp]zYq (1), [L?MemXp]zYq (1?), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.

Abstract: A method of preparing a potassium monopersulfate composition is presented, wherein the potassium monopersulfate composition has the formula (KHSO5)x(KHSO4)y(K2SO4)z, where x+y+z=1 and x=0.46–0.64, y=0.15–0.37, and z=0.15–0.37, said potassium monopersulfate composition having an active oxygen content greater than or equal to 4.9 wt. % and K2S2O8 at a concentration of <0.5 wt. % of the potassium monopersulfate composition. The method includes reacting an H2O2 solution containing at least 70 wt. % H2O2 with a H2SO4 solution at a substoichiometric ratio of the H2SO4 to H2O2 to generate a weak Caro's acid solution, then combining the weak Caro's acid solution with oleum to produce a rich Caro's acid solution. The rich Caro's acid solution may be combined with an alkali potassium compound to produce the potassium monopersulfate composition. During the process, the temperature is maintained at below 30 ° C.

Abstract: A process for the production of particulate detergents or premixes suitable for their production by application of a flowable acidic component to a particle consisting at least partly of an alkaline detergent ingredient selected from the group consisting of alkali metal silicates, alkali metal alumosilicates, alkali metal perborates, alkali metal percarbonates, and mixtures thereof, the percentage of acidic component applied being governed by the formula mc/(mc+mp)=c·l/r, where mc is the weight of the acidic component, mp is the weight of the particle, r is the radius of the particle and c is a factor of 5 length units to 10 length units.

Abstract: The invention relates to ammonium nitriles of general formula (I), wherein the radicals R3, R4, R5 and X? have the meaning as cited in the description and R1 and R2 respectively represent individually a straight or branched chained C5–C24-alkyl, alkenyl or alkylether group. The inventive compounds are used as bleaching activators in washing, cleaning, and disinfective agents and in textile and paper bleaching.

Abstract: The use of compounds of the formula (1) M(L)nXm??(1) where M is a metal atom from the group Mn, Fe, Co, Ni, Mo, W, L is a ligand from the group of nitrogen-containing heterocycles, X is chloride, bromide, nitrate, perchlorate, sulfate, ammonia, tetrafluoroborate, hexafluorophosphate or an anion of an organic acid having 1 to 22 carbon atoms, n is a number from 2 to 4 and m is a number from 0 to 4, as catalyst for peroxygen compounds, in particular in washing, bleaching and cleaning compositions is claimed.

Abstract: The present invention relates to bleach activator particles that are useful in compositions such as detergent compositions. The present invention also encompasses detergent compositions containing such particles.

Abstract: The present invention relates to a process for pickling hot rolled, hot rolled & annealed, and cold rolled & annealed stainless steel strip in a continuous fashion. The process comprises a series of pre-pickling tanks and pickling tanks, and optionally includes a scrubber-brush tank, a de-smutting tank, a filtration unit and a heat exchanger.