Abstract: A process for producing syngas with a high content of carbon monoxide, reflected in a high CO:CO2 ratio. The process involves integrating membrane-based gas separation and steam methane reforming.

Abstract: This invention relates to a process and an apparatus for conducting simultaneous endothermic and exothermic reactions in a microchannel reactor. A start-up procedure for the microchannel reactor is disclosed.

Abstract: A catalytic water gas shift process at temperatures above about 450° C. up to about 900° C. or so wherein the catalyst includes rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.

Abstract: A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

Abstract: The present invention relates to processes for producing industrial products such as hydrocarbon products from non-polar lipids in a vegetative plant part. Preferred industrial products include alkyl esters which may be blended with petroleum based fuels.

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a hydrocarbon containing feed, particularly natural gas (100), is subjected to catalytic partial oxidation (CPO) (2), followed by the water gas shift (WGS) (4) reaction of a part of the reformed feed. At least part of the shifted feed is then subjected to hydrogen purification, preferably by pressure swing adsorption (PSA) (5) to obtain pure hydrogen (108), which hydrogen is subsequently combined with the remaining parts of the feeds to yield synthesis gas particularly suitable for methanol synthesis. The recombined stream preferably has an R ratio, being the molar ratio (H2—CO2)/(CO+CO2), in the range 1.9-2.2 and preferably about 2.

Abstract: Process for increasing the hydrogen content of a synthesis gas containing one or more sulphur compounds, the synthesis gas including hydrogen, carbon oxides and steam, and having a ratio defined as R?(H2—CO2)/(CO+CO2)?0.6 and a steam to carbon monoxide ratio ?1.8, including the steps of (i) heating the synthesis gas; (iii) subjecting at least a portion of the heated synthesis gas to a first stage of water-gas shift in a first shift vessel containing a first sulphur-tolerant water-gas shift catalyst that is cooled in heat exchange with boiling water, to form a pre-shifted gas stream; and (iii) forming a shifted gas stream by subjecting at least a portion of the pre-shifted gas stream to a second stage of water-gas shift in a second shift vessel containing a second sulphur-tolerant water-gas shift catalyst that is cooled in heat exchange with a gas stream including the synthesis gas.

Abstract: Gasification of carbon-containing raw material into gasified gas and recovery of CO2 are enabled at the same pressure throughout a system.

Abstract: A method for the transport of carbon dioxide from a feed means to a removal means in a pressure pipe, which method includes the production of a transport mixture containing up to 80 mol % carbon dioxide and an inert gas, in particular nitrogen, in the feed means, the pressurised feeding of the transport mixture into the pressure pipe, and the pressurised transport of the transport mixture in the pressure pipe to the removal means.

Abstract: A process is provided for producing syngas that is effective for use in downstream processes. The process for producing syngas includes operating a gasification apparatus in a start-up mode until the gasification apparatus and equipment downstream of the gasification apparatus are adequately warmed up to a first target temperature. Upon reaching a first target temperature, the process is then operated in a production mode to produce a second syngas with a higher CO/CO2 molar ratio. Operation in a start-up mode until reaching a first target temperature, provides a process that is effective for reducing fouling in downstream equipment and for providing a second syngas can be more effectively cooled and cleaned.

Abstract: An integrated plant that includes a steam explosion process unit and biomass gasifier to generate syngas from biomass is discussed. A steam explosion process unit applies a combination of heat, pressure, and moisture to the biomass to make the biomass into a moist fine particle form. The steam explosion process unit applies steam with a high pressure to heat and pressurize any gases and fluids present inside the biomass to internally blow apart the bulk structure of the biomass via a rapid depressurization of the biomass with the increased moisture content. Those produced moist fine particles of biomass are subsequently fed to a feed section of the biomass gasifier, which reacts the biomass particles in a rapid biomass gasification reaction to produce syngas components.

Abstract: Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results, and/or results that can not be achieved with any prior art devices.

Abstract: A method and an apparatus for generating a gas containing hydrogen (H2) and carbon monoxide (CO), as a raw material for chemical utilization in, for example, synthesis processes based on export gas from a metallurgical process, are shown. Part of the export gas is subjected to CO conversion with the addition of water vapor, crude synthesis gas with a defined quantity ratio of H2 to CO being formed. Even the water vapor required for CO conversion can be at least partially generated in at least one steam generator in the method.

Abstract: A process for increasing the hydrogen content of a synthesis gas including hydrogen and carbon oxides and having a carbon monoxide content?45 mole % on a dry-gas basis, including the steps of: (i) combining the synthesis gas with steam to form a steam-enriched feed gas mixture (ii) passing the feed gas mixture at an inlet temperature in the range 220-370° C. over an iron-based water-gas shift catalyst to form a hydrogen-enriched shifted gas mixture having a carbon monoxide content?10 mole % on a dry gas basis, and (iii) recovering the hydrogen-enriched shifted gas mixture, where a portion of the hydrogen-enriched shifted gas mixture is recycled to the feed gas mixture.

Abstract: The present invention discloses a pyrolysis unit that operates using a plasma pyrolysis reactor. Hydrocarbon material that is to be converted to syngas can be in gas, liquid and/or solid form including a slurry of very small powder particles. The hydrocarbons are subjected to very high levels of heat from one or more plasma torches in order to break the hydrocarbon chemical bonds. The residue from heating the hydrocarbon material drops into a pyrolysis unit quench section where the residue and molten ash are removed. Syngas that is extracted from the pyrolysis unit passes through syngas preparation processes that remove contaminants from the syngas. The syngas then passes through a syngas-to-liquid hydrocarbons process. Carbon dioxide that is removed from the syngas preparation and syngas-to-hydrocarbons processes is recycled to the pyrolysis unit.

Abstract: Provided is a method for producing a production gas and an apparatus using the same with which a load may be increased in biomass treatment and the quality of the production gas may be improved. According to the present invention, a raw material fluid (F2) containing a biomass (M1) is supplied from an upstream end (22a) toward a downstream end (22b) in a raw material passage (22) separated from the outside by a reaction tube wall (21), and the raw fluid (F2) of the raw material passage (22) is heated from the outer side of the raw material passage (22) through the reaction tube wall (21) by a first heating means (F1). The raw material passage (22) comprises a first gasification region (23) where a first gasification reaction occurs in which at least part of the biomass is gasified by heating conducted by the first heating means (F1), and a second gasification area (25) disposed closer to the downstream end (22b) than to the first gasification region (23).

Abstract: An environmentally beneficial process for the production of fuels and chemicals employs carbon dioxide from a natural source or from an artificial chemical source that would otherwise be discharged into the environment. The carbon dioxide is converted to formic acid and the formic acid is then non-biologically converted to fuels and/or chemicals without the intermediate process of hydrogenating the formic acid to methanol or reacting the formic acid with ammonia to form formamide. In the present process, formic acid is converted to one of seven primary feedstocks: formaldehyde, acrylic acid, methane, ethylene, propylene, syngas, and C5-C7 carbohydrates. The formaldehyde, acrylic acid, methane, ethylene, propylene, syngas and/or short chain carbohydrates can either be used directly, or can be converted into a wealth of other products.

Abstract: Embodiments relate to methods of generating hydrogen including contacting magnesium and silicon to form a mixture and reacting the mixture with an aqueous solution, sufficient to generate hydrogen. The solution can include water and salt.

Abstract: A process for increasing the hydrogen content of a synthesis gas including hydrogen and carbon oxides and having a carbon monoxide content 45 mole % on a dry-gas basis, including the steps of: (i) combining the synthesis gas with steam to form a steam-enriched feed gas mixture (ii) passing the feed gas mixture at an inlet temperature in the range 220-370° C. over an iron-based water-gas shift catalyst to form a hydrogen-enriched shifted gas mixture having a carbon monoxide content 10 mole % on a dry gas basis, and (iii) recovering the hydrogen-enriched shifted gas mixture, where a portion of the hydrogen-enriched shifted gas mixture is recycled to the feed gas mixture.

Abstract: The method in accordance with the present invention has steps of: preparing a hydrogen producing device with a high gravitational rotating packed bed, initiating the device, adjusting the temperature of the device, inputting a reagent gas and a liquid vaporized for mixing with the reagent gas into a reagent mixture, and passing the reagent mixture through the device to obtain hydrogen.

Abstract: Novel methods of electroless plating are described. Catalyst coatings can be applied within microchannel apparatus. Various reactions, including combustion and steam reforming, can be conducted over electroless catalyst coatings.

Abstract: Process for the production of synthesis gas (3), in which methane and carbon dioxide (2) are introduced into a reaction space (R) and reacted in the presence of a solid (W) at elevated temperatures to give hydrogen and carbon monoxide. Methane and carbon dioxide are passed through a carbon-containing granular material (W) and reacted in a high-temperature zone (H).

Abstract: The invention relates to a method of torrefaction of an optionally predried biomass in a torrefaction reactor such that torrefied biomass and torrefaction gases are obtained, and wherein an oxygen-containing gas is supplied to the torrefaction reactor at a first position in the reactor such that oxygen reacts with components of the torrefaction gases under the formation of heat and wherein torrefaction gases are withdrawn from the torrefaction reactor at a second position of the torrefaction reactor and wherein the first position is located downstream of the second position in relation to a biomass transport direction in the torrefaction reactor such that the torrefaction gases moves through the torrefaction reactor countercurrent with the biomass transport and wherein the optionally predried biomass has a temperature of between 30° C. and 230° C., preferably between 50° C. and 200° C., most preferably between 60° C. and 180° C. when entering the torrefaction rector.

Abstract: Two or more acidic gaseous species such as hydrogen sulphide and carbon dioxide from an adsorbent can be selectively removed from a Fig. la feed gas by contacting the feed gas with an adsorbent for these acidic species, followed by: a. subjecting the adsorbent to a first purging gas, said first purging gas not containing said first acidic gaseous species and containing said second acidic gaseous species at a partial pressure which is at least the partial pressure of said second gaseous species in said feed gas; b. subsequently subjecting the adsorbent to a second purging gas, said second purging gas not containing said first gaseous species and, containing this second gaseous species at a partial pressure which is lower than the partial pressure of said second gaseous species in said feed gas.

Abstract: A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.

Abstract: Pressure swing adsorption (PSA) assemblies with optimized startup times, as well as to hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. Startup and shutdown methods for a PSA assembly, and optionally an associated fuel processing system, are disclosed to provide for shortened startup times. The PSA assemblies may be in fluid communication with a hydrogen source that may be used or otherwise configured or controlled to purge the PSA adsorbent columns of adsorbents during startup and/or shutdown procedures, the hydrogen source additionally or alternatively may be used or otherwise configured or controlled to charge the columns with hydrogen for idling in a pressurized state. The use of this hydrogen source, together with specific startup and shutdown methodologies, provides for reducing the startup time of the PSA assembly.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions have the LEV topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.

Abstract: A new family of crystalline microporous silicometallophosphates designated MAPSO-64 and modified forms thereof have been synthesized. These silicometallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as ETMA+ or DEDMA+, M is an alkaline earth or transition metal cation of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The MAPSO-64 compositions are characterized by a BPH framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.

Abstract: Methods and systems for converting gaseous hydrocarbons to synthesis gas are disclosed. In some embodiments, the methods include the following: thermochemically decomposing a gaseous hydrocarbon stream in an oxygen-free environment to develop carbon and hydrogen; partially oxidizing the carbon in a hydrogen-free environment to develop carbon monoxide; mixing amounts of the carbon monoxide and the hydrogen to generate a synthesis gas; and processing the synthesis gas to generate a synthetic fuel.

Abstract: A system and method for providing an integrated indirectly fired reactor and steam generator are disclosed. According to one embodiment, the reactor comprises an indirect heating zone heating water and generating steam, a mixing zone mixing feedstock and the steam and providing a mixture of the feedstock and the steam, and a reaction zone comprising a first reactor and a second reactor. The first reactor converts the mixture to a first syngas at a first temperature. The second reactor converts the first syngas to a second syngas at a second temperature, the second temperature being higher than the first temperature.

Abstract: A methane steam reforming process for converting a syngas in the presence of permeable composite fibrous catalytic sheets comprised of at least three distinct solid phases. A first solid phase is a 3-dimensional porous network of a non-conductive porous ceramic material. A second solid phase is an electrically conductive phase comprised of randomly oriented electrically conductive fibers. A third phase is comprised of methane steam reforming catalytic particles dispersed on said 3-dimensional porous network, said conductive fibers, or both. A fourth phase can be present, which fourth phase is comprised one or more conductive species or one or more non-conductive species embedded in said first solid phase.

Abstract: A non-thermal, repetitively-pulsed gliding discharge reactor includes a high-voltage power source configured to provide a pulsed high-voltage potential; a gas inlet; a liquid sorbent inlet; a product outlet; a plurality of first electrodes connected to the high-voltage power source; a plurality of second electrodes that are grounded; and a trough; the plurality of first electrodes being separated from the plurality of second electrodes by a discharge region.

Abstract: Method and device for introducing pulverulent material (C) into a gasification reactor (2), wherein a process gas (P) supplied to a gasification reactor (2) is reduced to a synthesis gas (S) by the pulverulent material (C) and the pulverulent material (C) is introduced into the gasification reactor (2) via an inlet area, a negative pressure being generated in the inlet area for the pulverulent material (C) via a Laval nozzle (15) and the negative pressure being generated in that the process gas (P) passes through the Laval nozzle (15). The method is characterized in that the process gas (P) expands in a gasification space (5) in the gasification reactor (2).

Abstract: A system includes a gasifier configured to gasify a mixture of a biomass feedstock and an oxidant to generate a producer gas and a producer gas purification system configured to purify the producer gas from the gasifier. The system also includes a gas supply system configured to supply a gas that is not the oxidant to at least one of the gasifier, or the producer gas purification system, or any combination thereof.

Abstract: The invention relates to an improved plant and method for chemical looping combustion of at least one hydrocarbon feed with independent control of the circulation of the solid active mass particles between the fluidized bed reaction zones, by means of one or more non-mechanical valves of L-valve type.

Abstract: A system includes a slag additive slurry feed system configured to combine a slurrying agent, a mineral slag additive, and a liquid slurrying medium to generate a stabilized mineral slurry. The slurrying agent is configured to increase a viscosity of the stabilized mineral slurry. The system also includes a partial oxidation system configured to receive the stabilized mineral slurry, a feedstock, and oxygen into a gasifier reaction chamber. The partial oxidation system is configured to partially oxidize the feedstock to produce a gaseous product and a solid product.

Abstract: A method and apparatus for sequestering carbon dioxide from a waste gas and reusing it as a recycled gas without emissions concerns, including: given a gas source divided into a process gas and a waste gas: mixing the process gas with a hydrocarbon and feeding a resulting feed gas into a reformer for reforming the feed gas and forming a reducing gas; and feeding at least a portion of the waste gas into a carbon dioxide scrubber for removing at least some carbon dioxide from the waste gas and forming a carbon dioxide lean gas that is mixed with the reducing gas. Optionally, the method also includes feeding at least a portion of the waste gas into the carbon dioxide scrubber for removing at least some carbon dioxide from the waste gas and forming a fuel gas after the addition of a hydrocarbon that is fed into the reformer.

Abstract: Process for the preparation of synthesis gas from an essentially dry hydrocarbon feedstock (1) comprising olefins, hydrogen and carbon monoxide, the process comprising the steps: (a) selectively hydrogenating the olefins in the hydrocarbon feedstock at a temperature between 60 to 190° C. (2) to obtain a hydrogenated hydrocarbon feedstock comprising hydrogen, carbon monoxide and saturated hydrocarbons (3; (b) adding steam (4) to the hydrogenated hydrocarbon feedstock; (c) performing a water gas shift reaction in the presence of steam on the hydrogenated hydrocarbon feedstock (6) to obtain a shifted, hydrogenated hydrocarbon mixture; (d) converting the shifted, hydrogenated hydrocarbon mixture (8) to obtain a synthesis gas.

Abstract: The invention relates to a method for controlling a hydrocarbon vapor reforming reaction using a combustion chamber containing burners and tubes, said tubes being filled with catalysts and capable of being crossed by a mixture of hydrocarbons and vapor, the burners being arranged so as to transfer their combustion heat to the mixture of hydrocarbons and vapor through the walls of the tubes, wherein the temperature T of the wall of each tube is measured in the downstream part of the tube, and if for at least one tube, the measured temperature“is higher or equal to the MOT (DTT-15° C.), DTT being the design temperature of the measured tube, the functional parameters of the reforming method are then modified so as to decrease the measured temperature T of this tube down to a value lower than the MOT.

Abstract: Gasification systems and associated processes are disclosed herein. In one embodiment, a gasification process includes simultaneously supplying a carbonaceous material and steam to a gasifier, the gasifier containing a liquid volume containing at least about 10% by weight of iron oxide (FexOy where x and y are positive integers). The gasification process also includes performing a gasification reaction between the carbonaceous material and steam in the liquid volume, facilitating the gasification reaction with the iron oxide in the liquid volume, and producing a gas from the gasification reaction, the gas containing carbon monoxide (CO) and hydrogen (H2).

Abstract: A method and apparatus are described for supplying municipal solid waste (MSW), and/or other types of solid waste comprising both organic waste material and inorganic waste material, into a plasma gasifier reactor (PGR) in which the solid waste is to be processed.

Abstract: The disclosure relates to a continuous or semi-continuous, cyclic, countercurrent sorption-desorption method for enhanced control, separation, and/or purification of CO2 from one or more sources of a mixture of gases (and/or carbonaceous liquids that have sufficient vapor pressure) through integrated use of solid monolithic sorbents having a selectivity for sorption of the CO2.

Abstract: A supply source for delivery of a CO-containing dopant gas composition is provided. The composition includes a controlled amount of a diluent gas mixture such as xenon and hydrogen, which are each provided at controlled volumetric ratios to ensure optimal carbon ion implantation performance. The composition can be packaged as a dopant gas kit consisting of a CO-containing supply source and a diluent mixture supply source. Alternatively, the composition can be pre-mixed and introduced from a single source that can be actuated in response to a sub-atmospheric condition achieved along the discharge flow path to allow a controlled flow of the dopant mixture from the interior volume of the device into an ion source apparatus.

Abstract: Process for the endothermic, catalytic gas phase oxidation of hydrocarbons with steam and carbon dioxide to hydrogen and carbon monoxide (synthesis gas), performed in 5 to 30 series-connected reaction zones under adiabatic conditions.

Abstract: A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO3, CaS and CaX2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO2, in the presence of synthesis gas, in the presence of H2 and O2, under partial vacuum, and combinations thereof.

Abstract: A second stage gasification unit in a staged gasification integrated process flow scheme and operating methods are disclosed to gasify a wide range of low reactivity fuels. The inclusion of second stage gasification unit operating at high temperatures closer to ash fusion temperatures in the bed provides sufficient flexibility in unit configurations, operating conditions and methods to achieve an overall carbon conversion of over 95% for low reactivity materials such as bituminous and anthracite coals, petroleum residues and coke. The second stage gasification unit includes a stationary fluidized bed gasifier operating with a sufficiently turbulent bed of predefined inert bed material with lean char carbon content. The second stage gasifier fluidized bed is operated at relatively high temperatures up to 1400° C. Steam and oxidant mixture can be injected to further increase the freeboard region operating temperature in the range of approximately from 50 to 100° C. above the bed temperature.

Abstract: A method of producing a synthetic gas or a synthesis gas from a biosolid, such as dewatered sludge, that has a solids content that does not exceed 30 wt. %. The biomass having a solids content that does not exceed 30 wt. % is mixed with tar-rich materials and/or char particles, and optionally a bulking agent. The tar-rich materials and/or char particles may be a by-product of producing synthesis gas from a biomass such as refuse-derived fuels. The resulting mixture then is heated to provide a mixture having a solids content of at least 75 wt. %. The mixture having a solids content of at least 75 wt. % then is gasified under conditions to produce a synthetic gas rich in CO/CO2 or a synthesis gas rich in H2/CO.

Abstract: A catalyst precursor for preparing a catalyst suitable for use in a sour water-gas shift process is described, including; 5 to 30% by weight of a catalytically active metal oxide selected from tungsten oxide and molybdenum oxide; 1 to 10% by weight of a promoter metal oxide selected from cobalt oxide and nickel oxide; and 1 to 15% by weight of an oxide of an alkali metal selected from sodium, potassium and caesium; supported on a titania catalyst support.

Abstract: The invention relates to a catalytic reactor including: a reaction chamber; at least one catalytic structure made up of at least one catalytic cell-like architecture having outer dimensions at most 10% smaller than the inner dimensions of the reaction chamber; an annular space between the inner wall of the reaction chamber and the cell-like architectures; and at least one second structure positioned in the annular space, selected from among: a) a fibrous structure, or b) a structure including at least one metal collar clasping at least one portion of the cell-like architectures and supporting metal fins.

Abstract: A method of starting up an autothermal reactor for the production of synthesis gas by reforming of hydrocarbon-containing feed gases in a reaction chamber in which oxidation reactions and reforming reactions are carried out, by feeding a hydrocarbon containing feed gas, steam and an oxidant.