Pentavalent P, Except H(n+2)pno(3n+1) Patents (Class 252/389.23)
  • Patent number: 6645399
    Abstract: Compositions and methods have been discovered for inhibiting corrosion of metals, particularly iron alloys, in contact with fluids, either hydrocarbons, alcohols, or aqueous fluids, employing mercaptoalcohols. The mercaptoalcohols should have at least one water solubilizing hydroxyl group. In particular, suitable mercaptoalcohols have the formula: (HS)n—R—)(OH)m where R is a straight, branched, cyclic or heterocyclic alkylene, arylene, alkylarylene, arylalkylene, or hydrocarbon moiety having from 1 to 30 carbon atoms; n and m each independently averages from 1 to 3; and the heteroatom in the heterocyclic moiety substituent, if present, may be N, O, S and/or P. Preferred mercaptoalcohols include 2-mercaptoethanol, 2-mercaptopropanol, 1-mercapto-2-propanol, and 2-mercaptobutanol, in part because they are soluble in many fluids. These corrosion inhibitors show improved inhibition of both generalized and localized corrosion, specifically in high shear and high flow environments.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: November 11, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: Young Soo Ahn, Vladimir Jovancicevic
  • Patent number: 6620340
    Abstract: The invention is directed to a method for providing a corrosion inhibiting aqueous solution which includes zinc orthophosphate where the zinc orthophosphate is solubilized. The invention is directed to a method of making a substantially contaminant-free, concentrated aqueous solution of zinc orthophosphate from zinc metal or zinc oxide and aqueous phosphoric acid.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: September 16, 2003
    Assignee: Carus Corporation
    Inventors: Richard E. Deblois, Kenneth S. Pisarczyk
  • Patent number: 6572789
    Abstract: A method of inhibiting corrosion in aqueous systems comprising adding to the system a composition comprising mono, bis and oligomeric phosphinosuccinic acid adducts and a method of preparing a composition comprising mono, bis and oligomeric phosphinosuccinic acid adducts comprising adding hypophosphite to fumaric acid slurry or solution in water to create a reaction mixture; and effecting a reaction by introducing a free radical initiator to the reaction mixture.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: June 3, 2003
    Assignee: Ondeo Nalco Company
    Inventors: Bo Yang, Peter E. Reed, John D. Morris
  • Patent number: 6482483
    Abstract: A composition comprising tris(hydroxymethyl)phosphine or phosphorus-containing salts or condensates of those salts with nitrogen-containing compounds coated or absorbed onto a solid or porous substrate is disclosed. The salts or condensates are based on tetrakis(hydroxymethyl)phosphonium salts. The substrate has a melting point greater than 70° C. and is an optionally hydroxyl-substituted di- or polycarboxylic acid. The compositions may be used with water soluble film forming polymers to make sachets or bags containing sachets or bags of these phosphorous-containing compositions along with sachets or bags of compositions that are incompatible with these phosphorous-containing compositions.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: November 19, 2002
    Assignee: Rhodia Consumer Specialties Limited
    Inventors: Stephen David Fidoe, Christopher David Imrie, Christopher Raymond Jones, Robert Eric Talbot
  • Patent number: 6468364
    Abstract: An anticorrosion treatment of an aluminium/zinc alloy surface is disclosed. The treatment includes the steps of forming on the alloy surface a coating of a solution which contain 5-40 grams of molybdenum per litre of the solution, 2-19% by volume of a phosphoric acid, and a surface etchant. The treatment also includes drying the coating to form a dried coating having a loading of molybdenum of at least 10 mg/m2 of the dried coating and of phosphorus of at least 15 mg/m2 of the dried coating.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: October 22, 2002
    Assignee: BHP Steel (JLA) Pty Ltd
    Inventor: Shannon Marecic
  • Patent number: 6468470
    Abstract: A white rust inhibiting composition and method of inhibiting white rust for evaporative water coolers are disclosed. The composition includes, in combination, a blend of one or more organophosphorus compounds, one or more tannin compounds, and one or more water soluble metal compounds.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: October 22, 2002
    Assignee: Fremont Industries, Inc.
    Inventors: Michael T. Oldsberg, Bruce D. Busch
  • Patent number: 6465548
    Abstract: The present invention relates to a stabilizer composition for organic polymer material containing (a) 6-hydroxychroman compound, a phosphorus antioxidant and (c) phenolic antioxidant, wherein the component (a) is contained in a proportion of 0.5 wt %-10 wt % and the total amount of the component (b) and the component (c) is in a proportion of 99.5 wt %-90 wt %, of the total amount of the components (a), (b) and (c). The present invention also relates to an organic polymer material composition containing an organic polymer and the above-mentioned stabilizer composition for organic polymer material. The use of the stabilizer composition of the present invention as a stabilizer for organic polymer materials affords an industrially extremely useful stabilized organic polymer material composition superior in heat stability during processing.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: October 15, 2002
    Assignee: Yoshitomi Fine Chemicals, Ltd.
    Inventors: Takeshi Inoue, Shoichi Horie
  • Patent number: 6458874
    Abstract: The invention relates to a composition comprising a combination of compounds providing improved “direct to metal” adhesion and coating compositions comprising said composition. The coating compositions of the invention have improved adhesion when applied directly over metal substrates, especially untreated metal substrates such as galvanized steel, unsanded aluminum and unsanded cold-rolled steel.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: October 1, 2002
    Assignee: BASF Corporation
    Inventor: David L. Newton
  • Patent number: 6447594
    Abstract: A process for producing a strontium chromate corrosion inhibitor includes the steps of providing an aqueous slurry containing dispersed particulate strontium chromate, adding to the slurry a phosphoric acid or a neutral or acidic soluble salt of a phosphoric acid selected from the group consisting of ortho-phosphoric, pyro-phosphoric, tri-phosphoric, polyphosphoric, metaphosphoric, polymetaphosphoric, cyclic tri-metaphosphoric acid, and phosphorous acid, and, filtering and drying the resultant material whereby particulate strontium chromate of reduced solubility is produced.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: September 10, 2002
    Assignee: Wayne Pigment Corporation
    Inventors: John Sinko, Michael Denesha
  • Patent number: 6416712
    Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The corrosion inhibiting additive is a stannous salt of a non-carbon acid.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: July 9, 2002
    Assignee: A.S. Incorporated
    Inventor: Olen L. Riggs, Jr.
  • Patent number: 6383414
    Abstract: A process of inhibiting a corrosion of metal plugs formed in integrated circuits is described. The corrosion inhibiting process includes providing a partially fabricated integrated circuit surface including the metal plugs on a polishing pad to carry out chemical-mechanical polishing, introducing slurry including a corrosion inhibiting compound on the polishing pad in sufficient concentration to inhibit corrosion of the metal plugs of the partially fabricated integrated circuit surface, and polishing the partially fabricated integrated circuit surface.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: May 7, 2002
    Assignee: LSI Logic Corporation
    Inventor: Nicholas F. Pasch
  • Patent number: 6365067
    Abstract: Compositions and methods have been discovered for inhibiting corrosion of metals, particularly iron alloys, in contact with fluids, either hydrocarbons, alcohols, or aqueous fluids, employing mercaptoalcohols. The mercaptoalcohols should have at least one water solubilizing hydroxyl group. In particular, suitable mercaptoalcohols have the formula: (HS)n—R—(OH)m where R is a straight, branched, cyclic or heterocyclic alkylene, arylene, alkylarylene, arylalkylene, or hydrocarbon moiety having from 1 to 30 carbon atoms; n and m each independently averages from 1 to 3; and the heteroatom in the heterocyclic moiety substituent, if present, may be N, O, S and/or P. Preferred mercaptoalcohols include 2-mercaptoethanol, 2-mercaptopropanol, 1-mercapto-2-propanol, and 2-mercaptobutanol, in part because they are soluble in many fluids. These corrosion inhibitors show improved inhibition of both generalized and localized corrosion, specifically in high shear and high flow environments.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: April 2, 2002
    Assignee: Baker Hughes Incorporated
    Inventors: Young Soo Ahn, Vladimir Jovancicevic
  • Patent number: 6200529
    Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The preferred corrosion inhibiting additive is an aqueous solution of a stannous halide, preferably stannous chloride.
    Type: Grant
    Filed: July 26, 1999
    Date of Patent: March 13, 2001
    Assignee: A. S. Incorporated
    Inventor: Olen L. Riggs, Jr.
  • Patent number: 6183649
    Abstract: Water-circulating systems are treated with an aqueous, alkaline composition comprising I) an organo-phosphorus chelating agent, II) an acrylate homopolymer, III) a salt of an acrylic copolymer, a portion of the repeating units of which contain sulfonate groups, IV) a molybdate salt, and V) a salt of a fused-ring aromatic triazole. This composition (which is formulated in accordance with a specific order of addition of the ingredients) is effective against white rust (corrosion of galvanized metal parts). When the water-circulating system is also fouled with a biofilm, it is preferred to introduce a biofilm remover having biocidal, surfactant, and chelating properties into the system, but the biofilm remover is introduced separately from the above-described composition.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: February 6, 2001
    Inventor: Michael W. Fontana