Oxygen Organic Compound Containing Patents (Class 252/396)
  • Patent number: 5302321
    Abstract: The corrosion of steam and condenser systems and piping therefor is minimized by the addition of anti-corrosion amounts of Vitamin A or Vitamin E.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: April 12, 1994
    Assignee: Aquas Corporation
    Inventors: Shunichi Akama, Takanobu Sasa, Tokuko Yanagisawa
  • Patent number: 5300235
    Abstract: Amine derivatives which are compounds of the formula (I): ##STR1## in which R is a C.sub.6-20 hydrocarbon; Y is --CO--NH-- and n is an integer of 1 to 6; or ##STR2## in which X is an alkylene group of 2 to 6 carbon atoms and n is an integer of 0 to 6;each R.sub.1 is independently H, --(CH.sub.2).sub.1-4 COOH, a C.sub.6-20 hydrocarbon or C.sub.6-20 hydrocarbon-carbonyl;R.sub.2 is H, (CH.sub.2).sub.1-4 COOH or C.sub.6-20 hydrocarboncarbonyl;the compound containing at least one (CH.sub.2).sub.1-4 COOH group; or a salt thereof are useful in inhibiting corrosion of metals in oil- and gas-field applications, and also show low toxicity to marine organisms.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: April 5, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Paul J. Clewlow, John A. Haselgrave, Niall Carruthers, Terence M. O'Brien
  • Patent number: 5290467
    Abstract: The present invention provides an antifreeze/coolant additive comprising polymeric polycarboxylates which resists cavitation erosion-corrosion of aluminum and aluminum alloys, is effective at relatively low concentrations and at varying pH.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: March 1, 1994
    Assignee: BASF Corporation
    Inventors: David E. Turcotte, James T. Lyon, John J. Conville, Shrikant V. DeSai, Stanley T. Hirozawa
  • Patent number: 5290469
    Abstract: The present invention provides an antifreeze/coolant composition with polymeric polycarboxylates which reduces the corrosion rate of heat rejecting aluminum, and is effective at relatively low concentrations.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: March 1, 1994
    Assignee: BASF Corporation
    Inventors: David E. Turcotte, John J. Conville, James T. Lyon, Stanley T. Hirozawa, Shrikant V. DeSai
  • Patent number: 5288419
    Abstract: The present invention provides an antifreeze/coolant composition with polymeric polycarboxylates which resists cavitation erosion-corrosion of aluminum and aluminum alloys, is effective at relatively low concentrations and at varying pH.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: February 22, 1994
    Assignee: BASF Corporation
    Inventors: David E. Turcotte, James T. Lyon, John J. Conville, Shrikant V. DeSai, Stanley T. Hirozawa
  • Patent number: 5275760
    Abstract: A method of corrosion inhibition using a gelled inhibitor is disclosed. The method comprises consecutively introducing into an annular region of a jacketed pipeline a hydrogel slurried in an environmentally innocuous oil medium and a corrosion inhibitor dissolved in an aqueous medium. The liquid media are contacted to form a gelled corrosion inhibitor in the annulus. The method is particularly useful in buried pipelines where corrosion monitoring is difficult.
    Type: Grant
    Filed: August 27, 1992
    Date of Patent: January 4, 1994
    Assignee: Nalco Chemical Company
    Inventor: John D. Johnson
  • Patent number: 5266104
    Abstract: A corrosion inhibiting composition for protection of the threads of oil country tubular goods, including a vapor phase corrosion inhibitor and a liquid phase corrosion inhibitor in water solution. The corrosion inhibitor may be left on the threads for use in combination with an anaerobic sealing compound. A transparent thread protector may be used to protect the threads coated with the corrosion inhibitor.
    Type: Grant
    Filed: October 20, 1992
    Date of Patent: November 30, 1993
    Inventor: Larry W. Vincent
  • Patent number: 5262089
    Abstract: An admixture for inhibiting chloride-induced corrosion in steel reinforcing in place in concrete comprises an O/W emulsion wherein the oil phase comprises an unsaturated fatty acid ester and ethoxylated nonyl phenol and the ester of an aliphatic carboxylic acid with a mono-, di- or trihydric alcohol and the water phase comprises a saturated fatty acid, an amphoteric compound, a glycol and a soap. The admixture is added to the concrete prior to placement.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: November 16, 1993
    Assignee: Sandoz Ltd.
    Inventors: Gregory S. Bobrowski, Mark A. Bury, Stephen A. Farrington, Charles K. Nmai
  • Patent number: 5256332
    Abstract: A low phosphorus process for controlling corrosion in aqueous systems by adding to the aqueous system an effective amount of a composition comprising orthophosphate, azole, polyepoxysuccinic acid and the copolymer of acrylic acid and allyl hydroxypropyl sulfonate ether.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: October 26, 1993
    Assignee: Betz Laboratories, Inc.
    Inventor: Stephen M. Kessler
  • Patent number: 5252289
    Abstract: Water-soluble 1,2-dithiole-3-thione derivatives are prepared by reacting a polyoxyalkylated starting material with sulfur. These derivatives are useful as corrosion inhibitors, particularly in aqueous environments.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: October 12, 1993
    Assignee: Petrolite Corporation
    Inventor: Bernardus A. Oude Alink
  • Patent number: 5250325
    Abstract: Coating composition comprising:A) an organic film-forming binder; andB) a corrosion-inhibiting amount of a water-insoluble salt of i) a carboxylic acid having the formula (I): ##STR1## and ii) a base selected from a) a cation of Group Ib, IIa, IIb, IIIa, IIIb, IVa, IVb, Va, VIa, VIIa or VIIIa of the Periodic Table of Elements, b) an amine of formula II: ##STR2## c) a guanidine of formula III:R.sub.7 --N.dbd.C(NH.sub.2).sub.2 IIId) an amidine of formula IV:R.sub.7 --C(.dbd.NH)NH.sub.2 IVor e) melamine.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: October 5, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Emyr Phillips, William P. Armstrong
  • Patent number: 5244600
    Abstract: A method for inhibiting or preventing corrosion of metals in contact with an aqueous system containing dissolved oxygen comprising adding to the system an oxygen scavenger having the formula ##STR1## wherein n is 5 or 6, lactone derivatives thereof, or its water soluble salts, in an amount effective to substantially remove the dissolved oxygen.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: September 14, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Dionisio G. Cuisia, Chih M. Hwa, Murrell L. Salutsky
  • Patent number: 5244591
    Abstract: Essentially chlorine-free lubricating compositions having a TBN of 10-30 designed for use in internal combustion engines having silver bearing parts which provide protection for said bearings via the incorporation therein of certain unsaturated aliphatic carboxylic acids. An additive concentrate for said lubricating compositions is also disclosed.
    Type: Grant
    Filed: March 23, 1992
    Date of Patent: September 14, 1993
    Assignee: Chevron Research and Technology Company
    Inventor: Wesley A. Middleton
  • Patent number: 5242621
    Abstract: Corrosion inhibitors containing alkanoic, hydrocarbyl dicarboxylic and carbocyclic-substituted, alkanoic acids or salts give high performance, heat transfer fluids and antifreezes, with improved properties including storage stability.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: September 7, 1993
    Assignee: Texaco Chemical Co.
    Inventors: David L. Miller, Brian L. Benac, John F. Knifton
  • Patent number: 5236626
    Abstract: An alkoxybenzotriazole, in combination with mercaptobenzothiazole, tolyltriazole, benzotriazole, a substituted benzotriazole and/or 1-phenyl-5-mercaptotetrazole, is used to inhibit the corrosion of metallic surfaces, particularly copper surfaces, in contact with an aqueous system. Systems and compositions are also claimed.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: August 17, 1993
    Assignee: Calgon Corporation
    Inventors: Daniel P. Vanderpool, Charles Y. Cha
  • Patent number: 5230730
    Abstract: The invention relates to a process for preparing stable low-viscosity O/W rust-inhibiting emulsions, characterized in that a mixture having the following composition is employed for the formation of the emulsion:a) from 10 to 60% by weight of an oil component;b) from 1 to 10% by weight of an emulsifier component consisting of at least one addition product of from 2 to 20 moles of ethylene oxide to fatty alcohols having from 10 to 22 carbon atoms;c) from 1 to 10% by weight of a corrosion inhibitor consisting of at least one carboxylic acid having the general formula (I):R--COOH (I),wherein R represents a straight-chain or branched saturated or unsaturated alkyl moiety comprising from 6 to 22 carbon atoms or a moiety having the general formula (II): ##STR1## wherein R.sup.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: July 27, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst-Dieter Speckmann, Gert-Lothar Striepling, Frank Wiechmann, Juergen Geke
  • Patent number: 5226956
    Abstract: A paint or varnish composition is described which comprises a medium, such as an alkyd resin, and an anticorrosion agent which is environmentally non-hazardous and soluble or adapted to be soluble in the medium. The composition is suitable for application to a metal substrate and the anticorrosion agent is selected so as to enable a dry paint or varnish film to be obtained on the metal substrate, preferably within 24 hours from the time of application.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: July 13, 1993
    Assignee: Alcan International, Inc.
    Inventors: Herbert F. Askew, Anthony R. Emery, John H. W. Turner
  • Patent number: 5217686
    Abstract: An alkoxybenzotriazole, in combination with mercaptobenzothiazole, tolyltriazole, benzotriazole, a substituted benzotriazole and/or 1-phenyl-5-mercaptotetrazole, is used to inhibit the corrosion of metallic surfaces, particularly copper surfaces, in contact with an aqueous system. Systems and compositions are also claimed.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: June 8, 1993
    Assignee: Calgon Corporation
    Inventors: Daniel P. Vanderpool, Charles Y. Cha
  • Patent number: 5204012
    Abstract: An esterification product obtained by reacting ethylene oxide/propylene oxide block copolymer with a long-chain monocarboxylic acid, when employed as a supplemental rust inhibitor in lubricating oils for internal combustion engines, has been found to furnish excellent rust inhibition in the engines and to be compatible with other components in the lubricating oils.A lubricating oil composition containing such product may be used to inhibit rust formation in an internal combustion engine.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: April 20, 1993
    Assignee: Ethyl Corporation
    Inventor: John G. Schaffhausen
  • Patent number: 5178786
    Abstract: The invention provides a composition comprising:(A) at least one dicarboxylic acid or anhydride or at least one ammonium or metal salt of the dicarboxylic acid or anhydride; and(B) at least one compound represented by the formula ##STR1## wherein R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each independently hydrogen, alkyl, hydroxyalkyl, polyhydroxyalkyl, polyalkoxyalkyl or hydroxypolyalkoxyalkyl; and R.sub.1 is a hydrocarbyl group. In another embodiment, the compositions include (C) at least one acid, or ammonium or metal salt of the acid represented by the formula: ##STR2## wherein R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently hydrogen or hydrocarbyl groups; and n is a number from 1 to about 10;(D) at least one ester-salt derived from at least alkyl or alkenyl succinic acid or anhydride of about 8 to about 28 carbon atoms and at least one alkanol amine;or mixtures of (C) and (D).The invention further provides for concentrates and functional fluids containing the above corrosion-inhibitors.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: January 12, 1993
    Assignee: The Lubrizol Corporation
    Inventors: Richard W. Jahnke, Theodore O. Johnson, Paul E. Adams, John W. Forsberg
  • Patent number: 5176850
    Abstract: The present invention provides a composition in contact with a corrodable metal surface, comprising a functional fluid and, as corrosion inhibitor, a compound having the formula 1A ##STR1## as well as salts or esters thereof, wherein R.sup.3 is C.sub.9 -C.sub.20 linear or branched alkyl, phenyl or C.sub.7 -C.sub.20 alkylphenyl;R.sup.4 is C.sub.1 -C.sub.3 alkyl;X is CH.sub.2, O or S;Y is O or S; andZ is--(CH.sub.2).sub.n -in which n is 1,2,3,4 or 5, or Z is--CH.sub.2 --CH(CH.sub.3)-.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: January 5, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Robert M. O'Neil
  • Patent number: 5173213
    Abstract: The corrosion and fouling of metal surfaces in contact with corrosive acid fluids or acid salts in the presence of an aqueous medium is reduced by contacting the surfaces with a composition which comprises (a) an anti-fouling amount of a hydroxyl amine compound of the formulaR.sub.1 R.sub.2 N--OHwherein R.sub.1 and R.sub.2 are independently hydrogen or a hydrocarbyl or inertly substituted hydrocarbyl or both R.sub.1 and R.sub.2 are collectively a divalent hydrocarbyl combined with said nitrogen to form a heterocyclic ring, and (b) a corrosion-inhibiting amount of a reaction product of or a mixture for the purpose of a reaction product of a polyalkylene polyamine and an alkynediol. The polyalkylene polyamine is one that contains from 2-10 amine groups, each separated from another by an alkylene group having from 2-6 carbon atoms. The alkynediol has from 2 to 6 carbon atoms.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: December 22, 1992
    Assignee: Baker Hughes Incorporated
    Inventors: Richard F. Miller, John Petersen
  • Patent number: 5171462
    Abstract: Mixtures of block alkoxy co- or terpolymer hydrocarboxylates and aminopolyazole increase the oxidation and corrosion resistance of lubricants, particularly diesel engine oil.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: December 15, 1992
    Assignee: Texaco Inc.
    Inventors: Thomas F. DeRosa, Rodney L. Sung, Benjamin J. Kaufman, Ronald L. O'Rourke
  • Patent number: 5169563
    Abstract: A water treatment agent for boilers which comprises as active ingredients a compound which can release aliphatic hydroxycarboxylic acid ions in water and a polyamine represented by the following formula (I) or an acid addition product thereof:H.sub.2 H(CH.sub.2 CH.sub.2 NH).sub.n H (I)(wherein n denotes an integer of 2 to 5), and a water treatment method for pure water boilers or soft boilers using the above active ingredients to prevent corrosion of the ferrous metal in the water system of the pure water boilers or soft water boilers.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: December 8, 1992
    Assignee: Katayama Chemical Inc.
    Inventors: Sakae Katayama, deceased, Sadaoki Kanada, Kazuo Marugame, Hiroshi Asai
  • Patent number: 5167701
    Abstract: A one-package zinc-rich coating composition having an inorganic binder which provides protection of metallic substrates against environmental attack comprises, in volume percent:from about 55% to about 60% of an alkyl silicate solution having a solids content of about 35% to about 45% by weight; about 10% to about 14% zinc dust of at least one different particle size grade; about 0.5% to about 2.5% zinc flakes; about 3% to about 6% particulate ferrophosphate; about 10% to about 17% of a particulate crystalline silica having an oil absorption value of less than 20 measured by ASTM Test D 281-84; about 1% to about 2.5% of at least two different size grades of pyrogenic amorphous silicas having average particle sizes ranging from about 0.007 to about 0.04 micron; about 0.3% to about 0.5% of a wetting agent; and about 7% to about 8% of an anhydrous alcohol solvent.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: December 1, 1992
    Inventor: Ronald R. Savin
  • Patent number: 5156759
    Abstract: A lubricating composition has been found which has particular utility in gas compressors. The composition comprises a polyalphaolefin base oil, an ester oil solubilizer, antioxidants and metal passivators. The composition replaces a mineral oil formulation and demonstrates comparable thermal and oxidative stability in the absence of sulfur, phosphorous and metal additives.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: October 20, 1992
    Assignee: Texaco Inc.
    Inventor: Douglas H. Culpon, Jr.
  • Patent number: 5151220
    Abstract: A method of inhibiting carbonate stress corrosion cracking is determined to involve the addition of certain treatment chemicals to refinery process streams containing at least 1 of the volatile chemicals, ammonia, carbon dioxide, hydrogen sulfide, hydrogen cyanide, and water. The treatment chemical is preferably a fatty imidazoline compound or fatty amides or fatty esters or mixtures thereof.The imidazoline compounds and the amide/esters are formed by reacting tall oil fatty acids, naphthenic acids, or mixtures thereof with essentially linear heterochemicals containing amine or alcohol functionality.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: September 29, 1992
    Assignee: Nalco Chemical Company
    Inventors: Veronica K. Majestic, Russell C. Strong
  • Patent number: 5139702
    Abstract: A composition useful for treating aqueous systems comprising a naphthylamine polycarboxylic acid having the formula: ##STR1## wherein X is CO.sub.2 H or SO.sub.3 H, Y is H, C.sub.1 to C.sub.6 alkyl, CO.sub.2 H or SO.sub.3 H, R is H, C.sub.1 to C.sub.6 alkyl, CO.sub.2 R' or COR', R' is C.sub.1 to C.sub.6 alkyl, n is an integer from 1 to 20, and water soluble salts thereof.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: August 18, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Charles G. Carter, Robert P. Kreh, Lai-Duien G. Fan
  • Patent number: 5139701
    Abstract: A composition and method for controlling corrosion of steel in aqueous systems such as cooling and boiler systems. The combination of a nonionic surfactant and an anionic oxygen containing group such as one or more alkali metal salts of borate, molybdate and nitrate/nitrite provide improved corrosion inhibition of steel in aqueous systems. The magnetite layers formed in the presence of this combination exhibit decreased porosity and increased corrosion resistance to acidic solutions. This combination also inhibits entry of hydrogen into steel when exposed to acidic solutions thereby inhibiting hydrogen embrittlement. The preferred nonionic surfactant is phenol/polyethylene oxide nonionic surfactant and the preferred alkali metal salt is Na.sub.2 MoO.sub.4.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: August 18, 1992
    Assignee: Betz Laboratories, Inc.
    Inventor: Alexander C. McDonald
  • Patent number: 5135681
    Abstract: A method is disclosed for inhibiting corrosion of a ferrous based metal in contact with an aqueous system comprising incorporating into the aqueous system an effective amount of a substituted carboxymethoxysuccinic acid selected from the group consisting of compounds having the formula: ##STR1## wherein R is --(CHOH).sub.n CH.sub.2 OH, --(CHOH).sub.m CO.sub.2 H or --(CHOH).sub.r (CHOR')CO.sub.2 H and R' is CH(CO.sub.2 H)CH.sub.2 CO.sub.2 H; n is 1,2,3 or 4; m is 1,2,3, or 4; r is 1,2, or 3; and water soluble salts thereof.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: August 4, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Charles G. Carter, Vladimir Jovancicevic
  • Patent number: 5120471
    Abstract: A composition and method for inhibiting the corrosion of steel containing greater than about 9% chromium in the presence of at least one mineral acid, especially at temperatures above 250.degree. F. The composition is made of a corrosion inhibitor selected from phenyl ketone, phenyl ketone with a quaternary salt of a nitrogen-containing heterocyclic aromatic compound, or cinnamaldehyde with a quaternary salt of a nitrogen-containing heterocyclic aromatic compound and an acid soluble metal from antimonium or bismuth.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: June 9, 1992
    Assignee: Dowell Schlumberger Incorporated
    Inventors: Raymond J. Jasinski, Wayne W. Frenier
  • Patent number: 5114608
    Abstract: A method of stabilizing chlorofluorocarbon compositions thereby is provided. The stabilized composition comprises a chlorofluorocarbon and a sufficient amount of an epoxidized, generally high molecular weight stabilizer having an oxirane content sufficient to effectively stabilize the chlorofluorocarbon. The stabilizer is preferably an epoxidized oil having a molecular weight in the range of about 300 to about 1,500 and an oxirane content of at least about 4%. The method includes the step of adding a sufficient amount of such a stabilizer to the chloroflurocarbon composition. The chlorofluorocarbon composition typically comprises chlorofluoromethane, chlorofluoroethane, mixtures thereof or a chlorofluorocarbon-alcohol azeotropic solution. Also provided is an improved continuous dialyzer cleaning method utilizing the stabilized chlorofluorocarbon composition.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: May 19, 1992
    Assignee: Baxter International Inc.
    Inventors: Robert M. Sluga, Randolph H. Watkins, Henry M. Gajewski, Jerry D. Fisher, Dennis C. Berry
  • Patent number: 5104578
    Abstract: A corrosion inhibitor formulation for oil and water systems which formulation is resistant to sludge formation and does not tend to stabilize oil/water emulsions when added to oil and water systems. The corrosion inhibitor includes an imidazoline dissolved in an aromatic solvent, a 2-hydroxyalkylcarboxylic acid such as glycolic acid and a glycol such as hexylene glycol. The imidazoline is preferably prepared from a long chain fatty acid and a polyamine in a molar ratio of about 1.5:1.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: April 14, 1992
    Assignee: Betz Laboratories, Inc.
    Inventor: T. M. McCullough
  • Patent number: 5096618
    Abstract: A composition and method for inhibiting corrosion of iron and steel in the presence of aqueous acid at high temperatures, containing an alkenylphenone having the following structure: ##STR1## wherein R.sub.1 may be aryl of 6 to about 10 carbons, and R.sub.2 and R.sub.3 may be the same or different and each may be hydrogen, halogen, or aliphatic of about 3 to about 12 carbons, and R.sub.2 may also be alkanol, ether, or aryl of 6 to about 10 carbons, provided that the total number of carbons in said alkenylphenone does not exceed 16, anda substituted 1-azanaphthalene of the structure: ##STR2## wherein R.sub.4 is alkyl of about 4 to about 16 carbons, or alkylaryl of about 7 to about 20 carbons, and X is chloro or bromo.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: March 17, 1992
    Assignee: Dowell Schlumberger Incorporated
    Inventor: Wayne W. Frenier
  • Patent number: 5094814
    Abstract: A combination product containing (a) dihydroxyacetone, (b) hydroquinone, and (c) a volatile amine that is capable of removing oxygen and neutralizing carbon dioxide in industrial waters, particularly boiler waters, including boiler feed waters, internal boiling waters, condensate waters, and return waters. The combination product preferably contains weight ratios of ingredients (a):(b):(c) ranging from 1:0.01:0.1 to about 1:1:100, and may additionally contain a filming amine.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: March 10, 1992
    Assignee: Nalco Chemical Company
    Inventors: Cynthia A. Soderquist, Mei-Jan L. Lin
  • Patent number: 5091113
    Abstract: R is a straight or branched chain C.sub.4 -C.sub.30 alkyl group, a straight or branched chain C.sub.4 -C.sub.30 alkyl group interrupted by one, two or three oxygen atoms or substituted by one, two or three hydroxy groups, a C.sub.5 -C.sub.12 cycloalkyl group, a C.sub.6 -C.sub.10 aryl group, C.sub.6 -C.sub.10 aryl group substituted by one, two or three C.sub.1 -C.sub.12 alkyl groups, a C.sub.7 -C.sub.13 aralkyl group or a C.sub.7 -C.sub.13 aralkyl group which is substituted by a hydroxyl group;R.sub.1 is H or a straight- or branched chain C.sub.1 -C.sub.4 alkyl group;R.sub.2 is H, a straight or branched chain C.sub.1 -C.sub.4 alkyl group or CO.sub.2 H;R.sub.3 is H, a straight or branched chain C.sub.1 -C.sub.4 alkyl group, --CH.sub.2 CO.sub.2 H or --CH.sub.2 CH.sub.2 CO.sub.2 H;R.sub.4 is H, a straight or branched chain C.sub.1 -C.sub.4 alkyl or CO.sub.2 H;R.sub.5 is H, a straight or branched chain C.sub.1 -C.sub.4 alkyl group, CH.sub.2 CO.sub.2 H or CH.sub.2 CH.sub.2 CO.sub.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: February 25, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Brian G. Clubley
  • Patent number: 5089226
    Abstract: A method of protecting an austenitic stainless steel-made equipment to be exposed to a fluid containing sulfides from the occurrence of stress-corrosion cracking is disclosed, comprising washing the equipment with a mineral oil containing at least one compound selected from organic amines and acid amide compounds in stopping the operation thereof.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: February 18, 1992
    Assignee: Nippon Mining Co., Ltd.
    Inventors: Mitsuhiro Ohashi, Shuzo Mimaya
  • Patent number: 5085791
    Abstract: A corrosion-inhibited antifreeze composition is disclosed. Specifically, the antifreeze composition comprises a major portion of a liquid alcohol freezing point depressant and a minor portion of at least one cyclohexane acid employed as a corrosion inhibitor. Cyclohexane carboxylic acid, cyclohexane acetic acid and cyclohexane propionic acid are preferred, with cyclohexane carboxylic acid being most preferred. Other conventional corrosion inhibitors may be employed in conjunction with the cyclohexane acid(s).In another embodiment, the present invention relates to a process for inhibiting the general pitting, crevice and deposit attack corrosion of metals present in the cooling system of an internal combustion engine which comprises intimately contacting the metal surface to be inhibited against corrosion with the antifreeze composition described above. Most preferably, the target substrates are aluminum and high lead solder.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: February 4, 1992
    Assignee: Texaco Chemical Company
    Inventor: Jeffrey M. Burns
  • Patent number: 5085793
    Abstract: A corrosion-inhibited antifreeze composition is disclosed. Specifically, the antifreeze composition comprises a major portion of a liquid alcohol freezing point depressant and a minor portion of at least one hydroxyl-substituted aromatic carboxylic acid having the hydroxyl radical disposed proximate to the carboxylic radical. The above described acid is employed as a corrosion inhibitor. Other conventional corrosion inhibitors may be employed in conjunction with the acids.In another embodiment, the present invention relates to a process for inhibitig the corrosion of metals present in the cooling system of an internal combustion engine which comprises intimately contacting the metal surface to be inhibited against corrosion with the antifreeze composition described above. Most preferably, the target substrate is high lead solder.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: February 4, 1992
    Assignee: Texaco Chemical Company
    Inventors: Jeffrey M. Burns, John R. Sanderson, John M. Larkin, David R. McCoy
  • Patent number: 5069966
    Abstract: The present invention provides a thin continuous organic coating on metals, particularly on continuous metal bodies, so that the product obtained is weldable and resistant to corrosion as well as to the effect of strongly acid and strongly alkaline baths, while being punchable and paintable. The coating according to the invention comprises epoxy resins characterized by ultimate elongation higher than 10%, electrical insulation resistance less than 2000 Ohm/cm.sup.2, able to produce a continuous coating on the metal substrate with micro-roughnesses (Ra) of about 3 .mu.m--Ra being average roughness--and capable of withstanding for thirty minutes liquids with pH between 2 and 12.5.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: December 3, 1991
    Assignee: Centro Sviluppo Materiale SpA
    Inventors: Ferdinando Colaiacovo, Domenico Derchi, Massimo Memmi
  • Patent number: 5066461
    Abstract: Compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 when taken independently, each represent the monovalent group of formula: ##STR2## wherein Y is a monovalent group selected from hydroxyl and a group of the formula: ##STR3## wherein n is a whole number integer of 0 to 6; X is selected from the group consisting of hydroxyl and amino when n is from 1 to 6; and when n is 0, X is selected from monovalent groups of the formula:--0--alkylene--NR.sup.3 R.sup.4 (IV)wherein n has the meaning previously ascribed to it; R.sup.3 is selected from the group consisting of hydrogen and R.sup.4 ; and R.sup.4 represents a monovalent group of the formula--Alkylene--OH; (V)provided that R.sup.1 and R.sup.2 are not both a carboxyl group; and R.sup.1 and R.sup.2 when taken together represent the divalent moiety of formula: ##STR4## wherein A represents one of oxygen and ##STR5## wherein n has the meaning previously ascribed to it; and applied to oxidation prone metals to inhibit corrosion.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: November 19, 1991
    Assignee: Union Camp Corporation
    Inventor: Ewa A. Bardasz
  • Patent number: 5062992
    Abstract: A corrosion inhibitor formulation for oil and water systems which formulation is resistance to sludge formation and does not tend to stabilize oil/water emulsions when added to oil and water systems. The corrosion inhibitor include an imidazoline dissolved in an aromatic solvent, a 2-hydroxylakylcarboxylic acid such as glycolic acid and a glycol such as hexylene glycol. The imidazoline is preferably prepared from a long chain fatty acid and a polyamine in a molar ratio of about 1.5:1.
    Type: Grant
    Filed: May 9, 1990
    Date of Patent: November 5, 1991
    Assignee: Betz Laboratories, Inc.
    Inventor: T. Miles McCullough
  • Patent number: 5055325
    Abstract: A blanking solution containing surfactants, corrosion inhibitors, and optionally biocides and antifoam agents can be applied to steel blanks in a stamping or drawing mill to prevent the transfer of solid film prelube lubricants from the steel blanks to the transfer rolls in the mill. The surfactant is preferably a nonionic surfactant which does not have any essential effect on the coefficient of friction when the prelubed steel blanks are stamped or drawn to form the final part.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: October 8, 1991
    Assignee: Nalco Chemical Company
    Inventor: Robert L. Trivett
  • Patent number: 5055230
    Abstract: A composition, in contact with a corrodable metal surface, comprising:a) an aqueous-based or oil-based system; andb) as an inhibitor for protecting the metal surface against corrosion, at least one compound having the formula I or II: ##STR1## in which R is C.sub.4 -C.sub.20 alkyl, C.sub.4 -C.sub.20 alkyl interrupted by one or more oxygen atoms, C.sub.4 -C.sub.20 alkenyl, C.sub.6 -C.sub.10 aryl, C.sub.7 -C.sub.15 alkaryl, C.sub.7 -C.sub.15 aralkyl or C.sub.5 -C.sub.12 cycloalkyl;R.sup.1, R.sup.2 and R.sup.3 are the same or different and each is methyl or, preferably, hydrogen;M is hydrogen, a metal ion, ammonium or substituted ammonium ion;a is 0 or 1;b is 0 or an integer from 1 to 6, preferably 0, 1, 2 or 3 especially 0 or 1; andc is an integer from 1 to 6; and/or at least one compound having the formula II: ##STR2## in which R, R.sup.3 and a are as defined above.
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: October 8, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Brian G. Clubley, David C. Parker
  • Patent number: 5049201
    Abstract: Disclosed is a method of inhibiting corrosion on an electronic component. The method includes the steps of obtaining an electronic component and then cleaning the electronic component in a solution consisting of a complexing agent and a solvent in which the complexing agent is soluble. The complexing agent is a crown compound.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: September 17, 1991
    Assignee: International Business Machines Corporation
    Inventors: Shirley Cheng, Constance J. Araps, Allen J. Arnold, Jeffrey T. Coffin, Luu T. Nguyen
  • Patent number: 5023016
    Abstract: A concentrate composition is disclosed which comprises (a) a blend of (i) a metal sulfonate and (ii) an alkali or alkaline earth metal or zinc salt of a carboxylic acid and (b) a carrier. The composition is useful as a rust- and corrosion-inhibitor in a petroleum or synthetic base medium and is capable of maintaining metal sulfonate content at temperatures greater than 150.degree. C., e.g., 200.degree. C., for 20 hours.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: June 11, 1991
    Assignee: King Industries, Inc.
    Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
  • Patent number: 5013482
    Abstract: The present invention provides a composition in contact with a corrodable metal surface, comprising a functional fluid and, as corrosion inhibitor, a compound having the formula I: ##STR1## as well as salts or esters thereof, wherein R.sup.1 is C.sub.4 -C.sub.20 linear or branched alkyl, phenyl or C.sub.7 -C.sub.20 alkylphenyl;R.sup.2 is C.sub.1 -C.sub.12 linear or branched alkyl, phenyl or C.sub.7 -C.sub.20 alkylphenyl, or arylalkyl containing 7-20 carbon atoms;X is CH.sub.2, O or S;Y is O or S; andZ is --(CH.sub.2).sub.n -- in which n is 1, 2, 3, 4 or 5, or Z is --CH.sub.2 --CH(CH.sub.3)--.Some of the compounds of formula I are new.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: May 7, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Robert M. O'Neil
  • Patent number: 5013483
    Abstract: A composition and method for inhibiting corrosion of iron and steel in the presence of aqueous acid, especially concentrated hydrochloric acid comprising at least 5% by weight HCl, comprising an effective corrosion inhibiting amount of an alkenylphenone having the following structure: ##STR1## wherein R.sub.1 may be unsubstituted or inertly substituted aryl of 6 to about 10 carbons, and R.sub.2 and R.sub.3 may be the same or different and each may be hydrogen, halogen, or inertly substituted aliphatic of about 3 to about 12 carbons, and R.sub.2 may also be alkanol, ether, or unsubstituted or inertly substituted aryl of 6 to about 10 carbons, provided that the total number of carbons in said alkenylphenone does not exceed 16, and preferably including a surfactant, and a process of using this composition.
    Type: Grant
    Filed: January 30, 1990
    Date of Patent: May 7, 1991
    Assignee: Dowell Schlumberger Incorporated
    Inventors: Wayne Frenier, Fred Growcock, Victoria R. Lopp, Brian Dixon
  • Patent number: 5008039
    Abstract: A low foaming, rust inhibiting composition is disclosed which contains:A. a rust inhibiting amount of a dicarboxylic acid of the formula: ##STR1## wherein Z is COOH or H, and one of each is present, and x and y are from 3 to 9, with x+y=12;B. a foam inhibiting amount of a triglyceride acid of the formula: ##STR2## wherein x and y are integers from 3 to 9, x and y together equal 12. R.sub.1 and R.sub.2 are saturated/unsaturated hydrocarbon terminals of fatty acids esterified with glycerol; andC. a base sufficient to adjust the pH of the composition of about 6.5 to 10.5.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: April 16, 1991
    Assignee: Westvaco Corporation
    Inventors: Fred E. Woodward, Alice P. Hudson
  • Patent number: 5000864
    Abstract: Perfluoropolyethers having antirust properties, suitable for being used as lubricating oils or as components of lubricating greases or as antirust additives for lubricating oils and greases based on perfluoropolyethers.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: March 19, 1991
    Assignee: Ausimont S.r.l.
    Inventors: Ezio Strepparola, Costante Corti, Piero Gavezotti, Alba Chittofrati