Abstract: Techniques for increasing conductivity of graphene films by chemical doping are provided. In one aspect, a method for increasing conductivity of a graphene film includes the following steps. The graphene film is formed from one or more graphene sheets. The graphene sheets are exposed to a solution having a one-electron oxidant configured to dope the graphene sheets to increase a conductivity thereof, thereby increasing the overall conductivity of the film. The graphene film can be formed prior to the graphene sheets being exposed to the one-electron oxidant solution. Alternatively, the graphene sheets can be exposed to the one-electron oxidant solution prior to the graphene film being formed. A method of fabricating a transparent electrode on a photovoltaic device from a graphene film is also provided.

Abstract: The present invention relates to a composite sintering materials using a carbon nanotube (including carbide nano particles, hereinafter the same) and a manufacturing method thereof, the method comprises the steps of: combining or generating carbon nanotubes in metal powers, a compacted product, or a sintered product; growing and alloying the carbon nanotubes by compacting or sintering the metal powers, the compacted product, or the sintered product; and strengthening the mechanical characteristics by repeatedly performing the sintering process and the combining process or the generating process of the carbon nanotubes.

Abstract: A positive electrode material is disclosed which contains an iron lithium phosphate as a positive electrode active material and has a large charge/discharge capacity, high-rate adaptability, and good charge/discharge cycle characteristics at the same time. Also disclosed are a simple method for producing such a positive electrode material and a high-performance secondary battery employing such a positive electrode material. Specifically, disclosed is a positive electrode material for secondary battery characterized by mainly containing a positive electrode active material represented by the general formula: LinFePO4 (wherein n is a number of 0-1) and further containing at least one different metal element selected from the group consisting of vanadium (V), chromium (Cr), copper (Cu), zinc (Zn), indium (In) and tin (Sn). This positive electrode material can be produced using a halide of such a metal element as the raw material.

Abstract: A method for producing lithium iron phosphate includes: an aqueous solution preparing step of preparing an aqueous solution containing a phosphoric acid and a carboxylic acid; a first forming step of adding iron particles containing 0.5 mass % or more of oxygen to the aqueous solution, and making the phosphoric acid and the carboxylic acid and the iron particles react with each other in the aqueous solution under an oxidizing atmosphere, to form a first reaction liquid is formed by; the second forming step of adding a lithium source to the first reaction liquid obtained in the synthesizing step to form a second reaction liquid; the precursor forming step of drying the second reaction liquid to form a lithium iron phosphate precursor; and the primary baking step of baking the lithium iron phosphate precursor under a non-oxidizing atmosphere thus obtaining lithium iron phosphate.

Abstract: This invention relates to a composition for producing a cathode for an electricity storage device, including carbon nanofibers prepared by electrospinning a spinning solution including a cathode active material, a conductive material and a carbon fiber precursor; and a binder, and to a cathode for an electricity storage device made with the composition and to an electricity storage device including the cathode. The composition for producing a cathode includes carbon nanofibers instead of part or all of a conductive material, a dispersant and/or a binder, so that the cathode has remarkably increased specific surface area and electrical conductivity (decreased resistance), thus maximizing the efficiency of the cathode active material and the capacity.

Abstract: The present invention relates to a positive electrode composite material for Li-ion battery, to the preparation method thereof, and to the use thereof in a Li-ion battery. The composite material according to the invention includes: a) at least one conductive additive including carbon nanotubes at a content between 1 and 2.5 wt %, preferably between 1.5 and 2.2 wt %, relative to the total weight of the composite material; b) an active electrode material capable of reversibly forming an insertion compound with lithium, having an electrochemical potential greater than 2V relative to the Li/Li+ couple, and selected from among compounds having LiMv(XOz)n polyanionic framework; and c) a polymer binder. The positive electrode composite material according to the invention imparts, to the Li-ion battery incorporating said electrode, high support for the cycling capacity, weak internal resistance, and strong charge and discharge kinetics for the moderate cost of the stored KW.

Abstract: A technique capable of forming an oxide semiconductor target with a high quality in a low cost is provided. In a step of manufacturing zinc tin oxide (ZTO target) used in manufacturing an oxide semiconductor forming a channel layer of a thin-film transistor, by purposely adding the group IV element (C, Si, or Ge) or the group V element (N, P, or As) to a raw material, excessive carriers caused by the group III element (Al) mixed in the step of manufacturing the ZTO target are suppressed, and a thin-film transistor having good current (Id)-voltage (Vg) characteristics is achieved.

Abstract: A process for preparing a formulation comprising a carbon-deposited lithium metal phosphate, as precursor of a lithium ion battery electrode coating slurry.

Abstract: A process for forming a thermoelectric component having optimum properties is provided. The process includes providing a plurality of core-shell nanoparticles, the nanoparticles having a core made from silica, metals, semiconductors, insulators, ceramics, carbon, polymers, combinations thereof, and the like, and a shell containing bismuth telluride. After the core-shell nanoparticles have been provided, the nanoparticles are subjected to a sintering process. The result of the sintering provides a bismuth telluride thermoelectric component having a combined electrical conductivity and Seebeck coefficient squared of greater than 30,000 ?V2S/mK2 at 150° C.

Abstract: A lithium phosphorus complex oxide-carbon composite which has high electrode density and is capable of improving the rate characteristics of a lithium secondary battery. Specifically disclosed is a lithium phosphorus complex oxide-carbon composite which is characterized by being an aggregate of lithium phosphorus complex oxide particles represented by general formula (1), the lithium phosphorus complex oxide particles aggregating via a conductive carbon material. The lithium phosphorus complex oxide-carbon composite is also characterized in that the aggregate has an average particle diameter of 1-30 ?m and a tap density of not less than 0.8 g/cm3. General formula (1): LiMPO4 (In the formula, M represents one or more metal elements selected from the group consisting of Fe, Mn, Co, Ni and V.

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bMb1Fe1-cMc2Pd-eMe3Ox, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C.

Abstract: Carbon nanotube (CNT) based transparent conductive films and methods for preparing and patterning the same are disclosed. For example, CNT based transparent conductive films with controlled transmittance and conductivity and methods of preparing and patterning the same are provided. Methods of preparing a CNT ink for assembling on a transparent substrate to form a transparent conductive film is disclosed, the ink can include a desired ratio of CNT with polymer. The transparent conductive film can be patterned such that desired properties are exhibited.

Abstract: Provided are a positive electrode material for lithium ion batteries and a process for preparing the same. The positive electrode material for lithium ion batteries comprises a composite positive electrode material consists of LiCoO2 and an auxiliary positive electrode material, the general formula of the auxiliary positive electrode material is LiCo1?x?yNixMnyO2, wherein 0<x<0.9, 0<y<0.9, 0<x+y<0.9, and the LiCoO2 is a modified LiCoO2 coated with an Al2O3 film. The overcharge performance of the batteries can be significantly increased and the use amount of the overcharge additive can be reduced by using the positive electrode material so as to its improve the cycle performance of the batteries and improve the anti-overcharge safety in the special applications and the charging conditions.

Abstract: A composition of and method for forming activated carbon with magnetic properties for magnetic separation of the activated carbon from a liquid being treated is disclosed wherein a solution iron magnetic precursor is intimately mixed or absorbed into a porous carbon precursor or mixed with a solution or meltable carbon precursor to form an essentially homogeneous mixture or solution that when dried and pyrolized forms activated carbon particles with magnetic material evenly dispersed throughout the activated carbon material. The activated carbon particles may be of fine particle size, even powdered, and still retain magnetic properties sufficient for magnetic separation. In a particular aspect of the invention, a carbon precursor of soft wood is soaked in a solution of a ferric salt, dried, pyrolized and activated.

Abstract: Disclosed herein are an electrically conductive thermoplastic resin composition and a plastic article including the same. The electrically conductive thermoplastic resin composition comprises about 80 to about 99.9 parts by weight of a thermoplastic resin, about 0.1 to about 10 parts by weight of carbon nanotubes, about 0.1 to about 10 parts by weight of an impact modifier, based on a total of about 100 parts by weight of the thermoplastic resin and the carbon nanotubes, and about 0.1 to about 10 parts by weight of conductive metal oxide, based on a total of about 100 parts by weight of the thermoplastic resin and the carbon nanotubes.

Abstract: A high capacity lithium secondary battery includes a lithium manganese oxide having a layered structure exhibiting a great irreversible capacity in the event of overcharging at a high voltage and a spinel-based lithium manganese oxide. Because it is activated at a high voltage of 4.45 V or higher based on a positive electrode potential, additional lithium for utilizing a 3V range of the spinel-based lithium manganese oxide can be provided and an even profile in the entire SOC area can be obtained. Because the lithium secondary battery includes the mixed positive electrode active material including the spinel-based lithium manganese oxide and the lithium manganese oxide having a layered structure, and is charged at a high voltage, its stability can be improved. Also, the high capacity battery having a large available SOC area and improved stability without causing an output shortage due to a rapid voltage drop in the SOC area can be implemented.

Abstract: An electrode conductive material, an electrode material including the electrode conductive material, an electrode including the electrode material, and a lithium battery including the electrode material. When the electrode conductive material is used, the amount of a conductive material required is decreased, capacity of the lithium battery is improved, and a charge and discharge rate is increased.

Abstract: A method of making a treating wash includes mixing brass granules with acetone, mixing carbon nanotube material, iron pyrite granules and copper granules in the acetone brass mixture, and straining the liquid from the remaining solid material. Methods of treating materials such as brass granules, iron pyrite granules, carbon nanotube material, and brass granules comprises washing the materials in the treating wash, followed by straining and drying the materials.

Abstract: An anode of a lithium battery includes a composite film, the composite film includes a carbon nanotube film structure and a plurality of nanoscale tin oxide particles dispersed therein. A lithium battery includes at least a cathode, an electrolyte, and the anode mentioned above. A charge/discharge capacity of the lithium battery using the anode can be improved.

Abstract: A method for manufacturing a composite material including tin oxide particles and a fibrillar carbon material, including synthesising tin hydroxide particles obtained from a tin salt by precipitation/nucleation in a water-alcohol medium, in the presence of the fibrillar carbon material and an acid, the fibrillar carbon material being nanotubes, carbon nanofibres, or a mixture of the two. The method can be used for the production of negative electrodes for lithium-ion batteries.

Abstract: The invention relates to a process for coating nanoparticles with graphene, comprising the steps of (a) providing a suspension comprising a suspension medium and nanoparticles with positive surface charge, (b) adding graphene oxide particles to the suspension from step (a), the graphene oxide particles accumulating on the nanoparticles, and (c) converting the graphene oxide particles accumulated on the nanoparticles to graphene, to graphene-coated nanoparticles comprising at least one metal, a semimetal, a metal compound and/or a semimetal compound, and to the use of these graphene-coated nanoparticles in electrochemical cells and supercapacitors, and to supercapacitors and electrochemical cells comprising these nanoparticles.

Abstract: The present invention is one which provides a production process for lithium-silicate-system compound, the production process being characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a substance including at least one member of transition-metal elements that is selected from the group consisting of iron and manganese at 400-650° C. in a molten salt of a carbonate mixture comprising lithium carbonate and at least one member of alkali-metal carbonates that is selected from the group consisting of potassium carbonate, sodium carbonate, rubidium carbonate and cesium carbonate in a mixed-gas atmosphere including carbon dioxide and a reducing gas; and a positive-electrode active material for lithium-ion secondary battery that comprises a lithium-silicate-system compound being obtained by the aforesaid process.

Abstract: A compound of the general formula (I) AaMbPcOd??(I) in which the variables are each defined as follows: M is at least one transition metal selected from Co, Ni, Mn, Fe and Cr, A is Li or LixNa1-x where x is in the range from 0.2 to 1.0, a is in the range from 3.5 to 4.5, b is in the range from 0.8 to 1.2, c is in the range from 1.8 to 2.2 and d is in the range from 7.2 to 8.8.

Abstract: The invention relates generally to carbon nano-tube composites and particularly to carbon nano-tube compositions for electrochemical energy storage devices and a method for making the same.

Abstract: A method for producing nanospacer-graphene composite materials (i.e., mechanically-exfolitated graphene), wherein the graphene sheets are interspersed with nanospacers, thereby maintaining the 2D characteristics of the graphene sheets. The nanospacer-graphene composite material is highly porous, has a high surface area and is highly electrically conductive and may be optically transparent.

Abstract: A composite lithium compound having a mixed crystalline structure is provided. Such compound can be formed by heating lithium, iron, phosphorous and carbon sources with a lithium metal compound. The resulting mixed metal crystal can exhibit superior electrical property and is a better cathode material for lithium secondary batteries.

Abstract: A composite lithium compound having a mixed crystalline structure is provided. Such compound can be formed by heating a lithium, iron, phosphorous and carbon mixed compound with another metal compound together. The resulting mixed metal crystal can exhibit superior electrical property and is a better cathode material for lithium secondary batteries.

Abstract: Embodiments of the present invention are directed to negative active materials for lithium rechargeable batteries and to lithium rechargeable batteries including the negative active materials. The negative active material includes a crystalline carbon material having pores, and amorphous conductive nanoparticles in the pores, on the surface of the crystalline carbon, or both in the pores and on the surface of the crystalline carbon. The conductive nanoparticles have a FWHM of about 0.35 degrees (°) or greater at the crystal plane that produces the highest peak as measured by X-ray diffraction.

Abstract: An electrode material is created by forming a thin coating or small deposits of metal oxide as an intercalation host on a carbon powder. The carbon powder performs a role in the synthesis of the oxide coating, in providing a three-dimensional, electronically conductive substrate supporting the metal oxide, and as an energy storage contribution material through ion adsorption or intercalation. The metal oxide includes one or more metal oxides. The electrode material, a process for producing said electrode material, an electrochemical capacitor and an electrochemical secondary (rechargeable) battery using said electrode material is disclosed.

Abstract: An electrode material is created by forming a thin conformal coating of metal oxide on a highly porous carbon meta-structure. The highly porous carbon meta-structure performs a role in the synthesis of the oxide coating and in providing a three-dimensional, electronically conductive substrate supporting the thin coating of metal oxide. The metal oxide includes one or more metal oxides. The electrode material, a process for producing said electrode material, an electrochemical capacitor and an electrochemical secondary (rechargeable) battery using said electrode material is disclosed.

Abstract: A method of making a treating wash includes mixing brass granules with acetone, mixing carbon nanotube material, iron pyrite granules and copper granules in the acetone brass mixture, and straining the liquid from the remaining solid material. Methods of treating materials such as brass granules, iron pyrite granules, carbon nanotube material, and brass granules comprises washing the materials in the treating wash, followed by straining and drying the materials.

Abstract: The invention relates to a carbon nanotube composite material, to methods of its production and to uses of such composite material.

Abstract: A composite lithium compound having a mixed crystalline structure is provided. Such compound can be formed by heating a lithium, iron, phosphorous and carbon mixed compound with another metal compound together. The resulting mixed metal crystal can exhibit superior electrical property and is a better cathode material for lithium secondary batteries.

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bQ1-cM2cPd-eM3eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1: Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.

Abstract: A composite lithium compound having a mixed crystalline structure is provided. Such compound can be formed by heating lithium, iron, phosphorous and carbon sources with a lithium metal compound. The resulting mixed metal crystal can exhibit superior electrical property and is a better cathode material for lithium secondary batteries.

Abstract: An electrode for an electrochemical device of the present invention includes an electrode mixture layer that includes a lithium-containing composite oxide expressed by the general composition formula (1): Li1+xMO2 as an active material, where x satisfies ?0.3?x?0.3 and M represents an element group including Ni, Mn, and Mg. The relationships 70?a?97, 0.5<b<30, 0.5<c<30, ?10<b?c<10, and ?8?(b?c)/c?8 are established, where a, b, and c represent the ratios of the number of elements of Ni, Mn, and Mg in the element group M to the total number of elements in the element group M, respectively, in units of mol %. The Ni has an average valence of 2.5 to 3.2, the Mn has an average valence of 3.5 to 4.2, and the Mg has an average valence of 1.8 to 2.2.

Abstract: Provided are a porous anode active material, a method of preparing the same, and an anode and a lithium battery employing the same. The porous anode active material includes fine particles of metallic substance capable of forming a lithium alloy; a crystalline carboneous substance; and a porous carboneous material coating and attaching to the fine particles of metallic substance and the crystalline carboneous substance, the porous anode active material having pores exhibiting a bimodal size distribution with two pore diameter peaks as measured by a Barrett-Joyner-Halenda (BJH) pore size distribution from a nitrogen adsorption. The porous anode active material has the pores having a bimodal size distribution, and thus may efficiently remove a stress occurring due to a difference of expansion between a carboneous material and a metallic active material during charging and discharging.

Abstract: A method of making a polymer composite from a mixture of a polymeric material, carbon nanofibers, and nano-scale particles is provided. The carbon nanofibers are less than about 1 micrometer in diameter, and the nano-scale particles are shorter in length than the carbon nanofibers. The nano-scale particles are selected from nano-scale carbon additives, non-conductive nano-clays, nano-scale conductive metallic additives, or combinations thereof. The components are mixed to form a polymer composite. A polymer composite having a resistivity of less than about 107 ohm-cm is also described.

Abstract: The present invention provides an electrode mixture, an electrode and a nonaqueous electrolyte secondary battery. The electrode mixture includes a lithium mixed metal oxide represented by formula (1): Liz(Ni1-x-yMnxMy)O2??(1), an electrically conductive material, and a water-dispersible polymeric binder, wherein x is 0.30 or more and less than 1, y is 0 or more and less than 1, x+y is 0.30 or more and less than 1, z is 0.5 or more and 1.5 or less, and M represents one or more members selected from the group consisting of Co, Al, Ti, Mg and Fe.

Abstract: The present invention relates to a composite material for a negative electrode, including: a plurality of iron oxide particles; and a conductivity improver, which is selected form the group consisting of copper, cobalt, nickel, tin, antimony, bismuth, indium, silver, gold, lead, cadmium, carbon black, graphite, copper salt, cobalt salt, nickel salt, tin salt, antimony salt, bismuth salt, indium salt, silver salt, gold salt, lead salt, cadmium salt, copper hydroxide, cobalt hydroxide, nickel hydroxide, stannic hydroxide, antimony hydroxide, bismuth hydroxide, indium hydroxide, silver hydroxide, gold hydroxide, lead hydroxide, cadmium hydroxide and the combination thereof. In the case of applying the composite material for a negative electrode according to the present invention in an electrochemical device, the improved charge/discharge characteristics and high capacity can be achieved.

Abstract: An electrode material comprising at least one compound of the general formula (I) LiaMbFcOd??(I) in which the variables are each defined as follows: M is at least one transition metal selected from Ti, Cr, V and Mn, where Ti, Cr, V and Mn may be replaced partially by Al, Ga, Ni, Fe or Co, a is in the range from 2.5 to 3.5, b is in the range from 0.8 to 1.2, c is in the range from 5.0 to 6.5 and d is in the range from zero to 1.0.

Abstract: Embodiments of the present invention generally relate to lithium-ion batteries, and more specifically, to a method of fabricating such batteries using thin-film deposition processes. In one embodiment In one embodiment, a method of forming a film on a substrate is provided. The method comprises combining a lithium-containing precursor, an iron containing precursor, and an organic solvent to form a deposition mixture, optionally exposing the deposition mixture to vibrational energy, applying microwave energy to the deposition mixture to heat the deposition mixture, optionally exposing the heated deposition mixture to vibrational energy, and depositing the heated deposition mixture on a substrate to form a film comprising lithium containing nanocrystals.

Abstract: A method of making a primary alkaline battery that includes a cathode including ?-MnO2 as an active material, an anode including zinc or zinc alloy as an active material, a separator between the cathode and anode, and an alkaline electrolyte contacting the anode and cathode having improved discharge performance. Methods of making high-purity, essentially lithium-free ?-MnO2 having high electrochemical activity from nominally stoichiometric lithium manganese oxide spinels are disclosed.

Abstract: Process for improving the electrochemical performance of an alkali metal oxyanion electrode material having a pyrolitic carbon deposit thereon, comprising a heat treatment under a humidified atmosphere where the heat treatment is performed at a temperature in the range of about 300° C. to about 950° C.

Abstract: The efficient dispersion of carbon nanotubes in various media and methods of using the same in such applications as inks, coatings, and composites and in various electrical and electronic articles are disclosed. A dispersant is used which has the formula P-(U-Y)s where P is a metal or metal-free phthalocyanine, Y is a compatibilizing moiety with a molecular weight between 500 and 5000 g/mol, U is a linking moiety covalently bonding Y to P, and s is an integer between 1 and 4.

Abstract: An electrically conductive carbon nanotube-metal composite ink may include a carbon nanotube-metal composite in which metal nanoparticles are bound to a surface of a carbon nanotube by chemical self-assembly. The electrically conductive carbon nanotube-metal composite ink may have higher electrical conductivity than a commonly used metal nanoparticles-based conductive ink, and may also be used in deformable electronic devices that are flexible and stretchable, as well as commonly used electronic devices, due to the bending and stretching properties of the carbon nanotube itself.

Abstract: Methods, systems and devices are implemented in connection with rechargeable batteries. One such device includes a cathode that has lithiated sulfur. The device also includes a porous structure having pores containing the lithium-sulfide particles introduced during a manufacturing stage thereof.

Abstract: Disclosed are bias charge rollers having an overcoat layer. The overcoat layer comprises a phenolic resin and a conductive agent. The resulting bias charge rollers have reduced streaking and increased service lifetimes.

Abstract: According to various embodiments of the present teachings, there is a metal-carbon nanotubes composite and methods of making it. A method of forming a metal-carbon nanotube composite can include providing a plurality of carbon nanotubes and providing a molten metal. The method can also include mixing the plurality of carbon nanotubes with the molten metal to form a mixture of the carbon nanotubes and the molten metal and solidifying the mixture of the carbon nanotubes and the molten metal to form a metal-carbon nanotube composite.

Abstract: The present invention is directed to electrochromic electrolyte polymer blends. These blends comprise an amorphous polymer and an electrochromophore component. The electrochromophore component comprises a polyalkylene polymer copolymerized with an electrochromic moiety. The blends can be used to make elastomeric films and coatings that can be used in laminates, which can be used to form manufactured articles such as architectural and vehicular glazing, eyewear, displays and signage.