Organic Material Patents (Class 252/589)
  • Patent number: 5041244
    Abstract: Ophthalmic dosages of chromophores in aqueous gel to block transmission of all or various spectrums of U.V. from the eyes, when used as ophthalmic liquid sunglasses.
    Type: Grant
    Filed: May 16, 1990
    Date of Patent: August 20, 1991
    Assignee: Liquid Sunglasses Corporation
    Inventor: Neville A. Baron
  • Patent number: 5035839
    Abstract: Composition which form hydrogen bridges are suitable for the preparation of materials of non-linear optical properties.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: July 30, 1991
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Dieter Dorsch, Rudolf Eidenschink, Bernhard Rieger, Gerd Marowsky
  • Patent number: 5030387
    Abstract: An organic conductive complex comprising an electron donor and an electron acceptor, the electron donor being an anthraquinone derivative represented by formula (1): ##STR1## wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4, which may be the same or different, each represents an electron donating group.
    Type: Grant
    Filed: June 27, 1989
    Date of Patent: July 9, 1991
    Assignee: Sumitomo Electric Industries Ltd.
    Inventors: Masaru Matsuoka, Teijiro Kitao, Yo Shimizu
  • Patent number: 5015057
    Abstract: A polarization insensitive optical attenuator (10,40) uses a polymer-dispersed liquid crystal (PDLC) film (14,56) to provide attenuation control over a wide range of attenuation values. The attenuator has a relatively low minimum attenuation and reliable light transmission with minimal insertion loss. The present invention is also adaptable for use with a temperature controller (200) that stabilizes the PDLC film, which promotes more uniform, predictable attenuation values.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: May 14, 1991
    Assignee: Tektronix, Inc.
    Inventors: Scott H. Rumbaugh, Michael D. Jones, Friedrich Scheu, Philip J. Bos
  • Patent number: 5011628
    Abstract: Substituted benzamidines and their hydrochloride salts are useful as ultraviolet light absorbers, the benzamidines having the formula ##STR1## wherein: A.sup.1 and A.sup.2 may be the same or different and represent --COOR.sup.1, --CONR.sup.1 R.sup.2, --C.tbd.N or --C.sub.6 H.sub.5 ;A.sup.3 represents --H, --OH, --OR, --Cl, --NO.sub.2, --C.tbd.N, --C.sub.6 H.sub.5, or an alkyl group of one to five carbon atoms;R.sup.1 and R.sup.2 may be the same or different and represent hydrogen or an alkyl group of one to ten carbon atoms; and,R represents an alkyl group of one to ten carbon atoms.
    Type: Grant
    Filed: April 11, 1989
    Date of Patent: April 30, 1991
    Assignee: Givaudan Corporation
    Inventors: Isaac D. Cohen, Joseph A. Virgilio
  • Patent number: 5000547
    Abstract: Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole with at least one fluoro comonomer selected from one or more of ten defined classes having a recited minimum mole proportion of perfluoro-2,2-dimethyl-1,3-dioxole, in no event less than 65%, have high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, which make them suitable for cladding optical fibers as well as for many electronics applications, including the manufacture of substrates for circuit boards. They all are soluble at room temperature in perfluoro(2-butyltetrahydrofuran), which makes it practical to apply them as coatings from solution.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: March 19, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Edward N. Squire
  • Patent number: 4985179
    Abstract: An optical material obtained by electrically polarizing a high polymer molded article obtained from a composition comprising a copolymer of vinylidene cyanide and at least one comonomer selected from vinyl compounds, other vinylidene compounds and dienes having uniformly dispersed therein from 0.1 to 70% by weight of an organic molecular crystal having nonlinear optical effects, with the total amount of the copolymer and the organic molecular crystal being 100% by weight. The optical material has excellent orientation of the organic molecular crystal, great nonlinear optical effects, and excellent moldability.
    Type: Grant
    Filed: May 31, 1989
    Date of Patent: January 15, 1991
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Iwao Seo, Kenji Nakajima, Manabu Kishimoto
  • Patent number: 4981613
    Abstract: A light source composed of a semiconductor laser and a nonlinear optical element which converts a laser beam emitted from the semiconductor laser to a laser beam having a shorter wavelength, disposed in the path of a laser beam produced by the laser, the nonlinear optical element containing a compound represented by formula (I): ##STR1## wherein Z.sup.1, Z.sup.2, X and n are as defined in the specification, of formula (II) ##STR2## wherein Z.sup.3 and Z.sup.4 are defined in the specification, or an acid adduct therefore. the nonlinear optical element exhibits high transmittances to blue light and generates a laser beam having a shorter wavelength than that of the laser applied.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: January 1, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaki Okazaki, Seiiti Kubodera
  • Patent number: 4975223
    Abstract: An optical material of a high refractive index is formed of a copolymer obtained by copolymerizing 3-40 wt. % of 4-isopropenylbiphenyl, 30-97 wt. % of a monofunctional aromatic monomer represented by the following formula (I) or (II) and 0-67 wt. % of another monomer copolymerizable with 4-isopropenylbiphenyl and the monofunctional aromatic monomer. ##STR1## wherein R means a hydrogen atom or methyl group, X denotes ##STR2## in which n stands for an integer of 0-3, Y is a halogen atom other than a fluorine atom, or a methyl, hydroxyl or methoxy group, and m stands for an integer of 0-3, with the proviso that Y may be different from each other when m is 2 or 3.
    Type: Grant
    Filed: February 3, 1989
    Date of Patent: December 4, 1990
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hideaki Doi, Teruo Sakagami
  • Patent number: 4973429
    Abstract: A material in the form of a film is described which contains, in an orientated arrangement which does not display point symmetry, compounds of formula I ##STR1## wherein X is .dbd.CH-- or .dbd.N--, R.sup.1 is C.sub.12 -C.sub.30 -alkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.30 -alkyl, R.sup.3 is --NO.sub.2, --CN, --CF.sub.3, --COCF.sub.3, --SO.sub.2 CH.sub.3 or --SO.sub.2 CF.sub.3, R.sup.4 is hydrogen or is defined in the same way as R.sup.3, R.sup.5 is hydrogen or --NR.sup.6 R.sup.7 and R.sup.6 and R.sup.7 independently of one another are hydrogen or C.sub.1 -C.sub.30 -alkyl, it also being possible for any of the alkyl radicals to be partially fluorinated or perfluorinated.The compounds of formula I can be arranged in Langmuir-Blodgett layer systems. Such systems can be used for example for the manufacture of opto-electronic units.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: November 27, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Gero Decher, Bernd Tieke, Christian Bosshard, Peter Gunter
  • Patent number: 4973142
    Abstract: Articles made from amorphous dipolymers of perfluoro-2,2-dimethyl-1,3-dioxole with tetrafluoroethylene having high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, include, among others, substrates for circuit boards, composites, sheets and films, optical lenses, and electronic current carrying devices.
    Type: Grant
    Filed: April 9, 1990
    Date of Patent: November 27, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward N. Squire
  • Patent number: 4966730
    Abstract: Certain derivatives of stilbene and diphenylacetylene are capable of second harmonic generation when illuminated by coherent optical radiation.
    Type: Grant
    Filed: December 20, 1989
    Date of Patent: October 30, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert A. Clement, Wilson Tam, Ying Wang
  • Patent number: 4960538
    Abstract: Disclosed are near-infrared absorbents comprising 1,2-naphthalocyanine derivatives wherein the four naphthalene rings contained in the molecule independently have 1 to 6 substituents. Also disclosed is the use of these near-infrared absorbents in optical recording media, near-infrared absorption filters and display materials.
    Type: Grant
    Filed: October 20, 1988
    Date of Patent: October 2, 1990
    Assignees: Mitsui Toatsu Chemicals, Inc, Yamamoto Chemicals, Inc.
    Inventors: Hisato Itoh, Takahisa Oguchi, Katashi Enomoto, Masakatsu Nakatsuka, Tsutomu Nishizawa
  • Patent number: 4957655
    Abstract: In a preferred embodiment this invention provides a second order nonlinear optical film medium which consists of a thermoplastic copolymer which has a crystallographic molecular alignment, and a net dipolar molecular orientation normal to the film plane. The crystallographic molecular alignment is formed by axial mechanical stressing, and the dipolar molecular orientation is induced by an electric or magnetic field.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: September 18, 1990
    Assignee: Hoechst Celanese Corp.
    Inventors: Garo Khanarian, Donald Raskin, Alan Buckley, Gordon W. Calundann, Anthony J. East
  • Patent number: 4954288
    Abstract: This invention provides novel side chain liquid crystalline polymers. An invention polymer exhibits nonlinear optical response, and has utility as a transparent nonlinear optical component in optical light switch and light modulator devices.
    Type: Grant
    Filed: November 14, 1989
    Date of Patent: September 4, 1990
    Assignee: Hoechst Celanese Corp.
    Inventor: Anthony J. East
  • Patent number: 4946629
    Abstract: (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 & R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 & R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;and R.sup.6 & R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms;or R.sup.4 & R.sup.6 together comprise ring fused to Ring A and R.sup.5 & R.sup.7 are as hereinbefore defined;or R.sup.5 & R.sup.7 together comprise ring fused to Ring A and R.sup.4 & R.sup.6 are as hereinbefore defined;or R.sup.2 & R.sup.4 together with the N atom to which R.sup.2 is attached from a ring fused to Ring A and R.sup.3 & R.sup.5 are as hereinbefore defined;or R.sup.3 & R.sup.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: August 7, 1990
    Assignee: Imperial Chemical Industries, Plc
    Inventors: Simon Allen, Paul F. Gordon, Richard A. Hann
  • Patent number: 4941996
    Abstract: Inclusion complexes, comprising a host and a guest, that exhibit greater second harmonic generation efficiency than either the host or the guest exhibits by itself. Preferred hosts can be selected from cyclodextrins, cyclodextrin derivatives, and cyclodextrin polymers. Preferred guests can be selected from aromatic compounds in which the molecule contains both an electron-donating functional group and an electron-withdrawing functional group.
    Type: Grant
    Filed: October 19, 1987
    Date of Patent: July 17, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John E. Trend, Kent B. Rochford
  • Patent number: 4937017
    Abstract: This invention provides a nonlinear optical medium which is a composite of a microporous inorganic oxide glass which contains an incorporated solution of a solvent and an organic component which exhibits nonlinear optical response.In one embodiment the solution incorporated in the microporous glass monolith is composed of dioxane and 4-N,N-dimethylamino-4'-nitrostilbene.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: June 26, 1990
    Assignee: Hoechst Celanese Corp.
    Inventors: Gunilla E. Gillberg-LaForce, Thomas M. Leslie, Tessie M. Che, Marie Borzo
  • Patent number: 4933112
    Abstract: This invention provides novel sidechain liquid crystalline polymers which exhibit nonlinear response, and which have utility as a transparent nonlinear optical component in optical light switch and light modular devices.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: June 12, 1990
    Assignee: Hoechst Celanese Corp.
    Inventors: Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
  • Patent number: 4933110
    Abstract: Optical light filters, useful for eye protection from laser radiation, are provided. The filter can absorb harmful radiation from lasers of several (at least six (6)) types which have a range of different specific wavelengths, yet permit sufficient visibility. A novel mixture of compatible absorbers in a transparent plastic carrier, having the required stability to withstand processing conditions and having satisfactory stability for use under environmental conditions is disclosed.
    Type: Grant
    Filed: December 28, 1988
    Date of Patent: June 12, 1990
    Assignee: American Cyanamid Company
    Inventor: Robert J. Tucker
  • Patent number: 4931221
    Abstract: Described are a series of novel photochromic benzopyran and naphthopyran compounds in which two cyclopropyl groups are appended at the 2-position of the benzopyran or naphthopyran ring. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic or plano lenses that incorporate the noval pyran compounds or combinations of the novel pyran compounds with other complementary photochromic compounds are described.
    Type: Grant
    Filed: December 30, 1988
    Date of Patent: June 5, 1990
    Assignee: PPG Industries, Inc.
    Inventor: Harry G. Heller
  • Patent number: 4919972
    Abstract: A composition and process for modifying the surface region of a polymer article. The composition is a mixture of a resin surface modifier ingredient, a resin-swellable organic solvent and a surfactant additive. The composition is contacted with the surface of a resin article, while the article is immersed in a liquid which may also contain a surfactant which is non-aggressive toward the article and immiscible with the solvent. The surfactant alters the wetting characteristics of the air-liquid, or liquid-surface modifier interfaces, or both interfaces, so that a film of the modifier ingredient does not form on the surface of the liquid layer.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: April 24, 1990
    Assignee: M & T Chemicals Inc.
    Inventors: Neal Conrad, Michael T. Burchill, Joseph Silbermann, Thomas Hoffman, Maurice Bourrel
  • Patent number: 4919926
    Abstract: In order to prevent an evil caused by flying insects, an insect attraction protectant containing a light shielding agent which absorbs the light ranging from 200 to 500 nm in wave length is used to coat a transparent portion of a window glass and the like.Further, the above insect attraction protectant comprises a transparent synthetic resin such as an acrylic resin, or the like.The light shielding agent comprises an ultraviolet ray absorbent, a mixture of the ultraviolet ray absorbent and a dye, or a dye only.
    Type: Grant
    Filed: November 23, 1987
    Date of Patent: April 24, 1990
    Assignees: Ikari Corporation, Taisei Kako Co., Ltd.
    Inventors: Yosuke Watanabe, Yuji Kawakami, Koichiro Kikuchi, Yoshiyuki Ogawa, Hiroshi Sato
  • Patent number: 4915491
    Abstract: This invention provides novel acrylic copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices.
    Type: Grant
    Filed: October 3, 1986
    Date of Patent: April 10, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
  • Patent number: 4913844
    Abstract: This invention provides novel isotropic acrylic polymers and copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: April 3, 1990
    Assignee: Hoechst Celanese Corp.
    Inventor: Ronald N. DeMartino
  • Patent number: 4909963
    Abstract: Described are photochromic spiro(indoline)benzoxazine compounds having substituents on the benzoxazine portion of the compound, and their use in plastic hosts to impart a photochromic response thereto.
    Type: Grant
    Filed: December 6, 1988
    Date of Patent: March 20, 1990
    Assignee: PPG Industries, Inc.
    Inventors: Won S. Kwak, Chin-Wen Chen
  • Patent number: 4909964
    Abstract: Certain derivatives of stilbene and diphenylacetylene capable of second harmonic generation when illuminated by coherent optical radiation are presented.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: March 20, 1990
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: Robert A. Clement, Wilson Tam, Ying Wang
  • Patent number: 4906407
    Abstract: In one embodiment this invention provides a novel class of azomethine compounds which exhibit nonlinear optical response, such as 4-(4-dimethylaminobenzylideneamino)-4'-nitrostilbene: ##STR1##
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: March 6, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
  • Patent number: 4898691
    Abstract: In one embodiment this invention provides a nonlinear optical medium consisting of a solid solution of components comprising (1) a thermoplastic polymer such as poly(methyl acrylate/butyl acrylate); (2) a first organic compound which exhibits nonlinear optical response such as 4-amino-4'-nitrostilbene; and (3) a second organic compound such as methyl acrylate which complexes with and enhances the nonlinear optical response of the first organic compound.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: February 6, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Marie Borzo, Dagobert E. Stuetz
  • Patent number: 4895981
    Abstract: A process is described for improving the photochemical stability of dyeings on polyester fibre materials by means of UV absorbers of the formula ##STR1## in which R is alkyl, alkoxy, halogen or hydroxyl, R.sub.1 is alkyl, R.sub.2 is hydrogen, halogen, alkyl, alkylamino, hydroxyalkylamino, aralkylamino, alkoxyalkylamino, alkenyl, alkoxy, alkoxy which is substituted by hydroxyl, carboxyl or C.sub.2 -C.sub.5 alkoxycarbonyl, alkenyloxy, phenyl or phenyl which is substituted by halogen, alkyl, hydroxy-C.sub.1 -C.sub.4 alkyl, alkenyloxy, alkoxy, hydroxyl or carboxy-C.sub.1 -C.sub.4 alkoxy, m is 0 or 1 and n is 0, 1 or 2, and also novel compounds of the formula (1) in which m and n are both 0 and R.sub.2 is alkylamino, hydroxyalkylamino, aralkylamino or alkoxyalkylamino.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: January 23, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Kurt Burdeska
  • Patent number: 4894263
    Abstract: The invention relates to polymeric materials usable in non linear optics. The structure of the material of the invention includes a skeleton to which side chains are attached, the material resulting from the association of a first and a second monomer, the first monomer including a mesomorphogenic group connected to the skeleton by a spacer, the second monomer including a group capable of generating the second harmonic of an electromagnetic wave and also being connected to the skeleton by a spacer.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: January 16, 1990
    Assignee: Thomson-CSF
    Inventors: Jean C. Dubois, Gilles Ravaux, Pierre Le Barny
  • Patent number: 4892682
    Abstract: In one embodiment this invention provides a novel class of azomethine compounds which exhibit nonlinear optical response, such as 4-(4-dimethylaminobenzylideneamino)-4'- nitrostilbene: ##STR1##
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: January 9, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
  • Patent number: 4892681
    Abstract: A non-linear optical article is constituted of a derivative of benzalacetophenone represented by the following general formula: ##STR1## wherein A and B each represent the same or different atom or group and stand for a hydrogen atom, an alkoxy group having 1 to 4 carbon atoms, a chlorine atom, a bromine atom, an amino group or a dialkylamino group having 1 to 2 carbon atoms.
    Type: Grant
    Filed: September 29, 1987
    Date of Patent: January 9, 1990
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Seizo Miyata, Toshiyuki Watanabe, Yoshitaka Goto, Masaharu Nakayama
  • Patent number: 4891075
    Abstract: Photovoltaic cell and wavelength-shifting device, comprising a dihydropyridine condensation product chelated to a lanthanide metal ion, to expand the solar spectrum available to the cell for conversion into electricity. Method to detect an amine or an aldehyde for forming a dihydropyridine condensation product chelated to a lanthanide metal ion and measuring the long life fluorescence of the chelated metal ion to determine the amount of amine or aldehyde present.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: January 2, 1990
    Assignee: Golight, Inc.
    Inventor: Salifu Dakubu
  • Patent number: 4885113
    Abstract: This invention provides a nonlinear optical medium which is a composite of a microporous inorganic oxide glass which contains an incorporated solution of a solvent and an organic component which exhibits nonlinear optical response.In one embodiment the solution incorporated in the microporous glass monolith is composed of dioxane and 4-N,N-dimethylamino-4'-nitrostilbene.
    Type: Grant
    Filed: August 20, 1987
    Date of Patent: December 5, 1989
    Assignee: Hoechst Celanese Corporation
    Inventors: Gunilla E. Gillberg-LaForce, Thomas M. Leslie, Tessie M. Che, Marie Borzo
  • Patent number: 4885114
    Abstract: Transparent selective optical absorption filters of improved stability to ambient solar light and radiation in the near UV range are provided by incorporating metallized tetra ((meso)-5-methyl-2-thiophene) phorphines, platinum (5-bromo octaethylporphine) or mixtures thereof into suitable filter matrices such as plastic, glass or the like. Optical filters absorbing in narrow radiation bands and useful as transparent protective laser shields are provided.
    Type: Grant
    Filed: October 5, 1988
    Date of Patent: December 5, 1989
    Assignee: Barnes Engineering Co.
    Inventors: Bruce S. Gordon, Alan Adler
  • Patent number: 4882402
    Abstract: This invention provides a process for producing a transparent optical medium consisting of a liquid crystalline polymer which exhibits third order nonlinear optical response.Illustrative of an invention optical medium is a transparent film of a side chain liquid crystalline polymer corresponding to the formula: ##STR1## The transparent film has an isotropic molecular configuration with macroscopic centrosymmetry, and exhibits essentially no scattering of a transmitted incident light beam.
    Type: Grant
    Filed: October 15, 1987
    Date of Patent: November 21, 1989
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas M. Leslie, Hyun N. Yoon, Ronald N. DeMartino, James B. Stamatoff
  • Patent number: 4877313
    Abstract: Light-polarizing materials, and uses thereof in liquid suspensions, set suspensions and light valves.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: October 31, 1989
    Assignee: Research Frontiers Incorporated
    Inventors: Robert L. Saxe, Robert I. Thompson
  • Patent number: 4876688
    Abstract: A systematic approach to the production of frequency conversion crystals is described in which a chiral molecule has attached to it a "harmonic generating unit" which contributes to the noncentrosymmetry of the molecule. Certain preferred embodiments of such harmonic generating units include carboxylate, guanadyly and imidazolyl units. Certain preferred crystals include L-arginine fluoride, deuterated L-arginine fluoride, L-arginine chloride monohydrate, L-arginine acetate, dithallium tartrate, ammonium N-acetyl valine, N-acetyl tyrosine and N-acetyl hydroxyproline. Chemical modifications of the chiral molecule, such as deuteration, halogenation and controlled counterion substitution are available to adapt the dispersive properties of a crystal in a particular wavelength region.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: October 24, 1989
    Assignee: The United States of America as represented by the Secetary of the Department of Energy
    Inventors: Francis Wang, Stephan P. Velsko
  • Patent number: 4797493
    Abstract: Disclosed herein are benzylidene compounds represented by the formula (I): ##STR1## wherein A represents ##STR2## (wherein B represents hydrogen atom or an acetyl group, W represents hydrogen atom or --CH.sub.2 --CH.sub.2 --CO--O--R, X.sup.1, X.sup.2 and X.sup.3 represent independently hydrogen atom, a hydroxyl group or a methoxyl group (two or three of them may be the same or all of them may be different), Y represents oxygen atom or imino group (--NH--), Z represents a methyl group or a phenyl group, and R represents a straight chain alkyl group having 1 to 18 carbon atoms, or branched or cyclic alkyl group having 3 to 18 carbon atoms, provided that when A is ##STR3## R is not an alkyl group having 1 to 2 carbon atoms, and when A is ##STR4## and X.sup.1, X.sup.2 and X.sup.3 are hydrogen atom, R is not an alkyl group having 1 to 2 carbon atoms), a cosmetic composition containing the same and an ultraviolet absorber comprising the same.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: January 10, 1989
    Assignee: Ajinomoto Co., Inc.
    Inventors: Kazuhiro Matsuno, deceased, Toru Kobayashi, Takeshi Miyoshi, Hideaki Kawashima
  • Patent number: 4795461
    Abstract: The invention is concerned with a UV absorbing plastics material to be used in intraocular lenses, said material having been produced by means of incorporating in the plastics monomer mixture, prior to the polymerization thereof, a combination of chromophores selected from two groups of substances.
    Type: Grant
    Filed: June 12, 1986
    Date of Patent: January 3, 1989
    Assignee: Pharmacia AB
    Inventors: Bengt Lindqvist, Bjarne Hogstrom, Martin Sandberg, Per I. Nilsson
  • Patent number: 4790959
    Abstract: A dispersion of oil globules which contains an ultra-violet absorber and a high-boiling solvent is disclosed. The UV absorber is a mixture of 15 to 45 wt % of a compound of formula (I) and 85 to 55 wt % of a compound of formula (II): ##STR1## (wherein R.sub.1 and R.sub.2 each represents an alkyl group having 1 to 4 carbon atoms; X is a hydrogen atom, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group or an aryl group); ##STR2## (wherein R.sub.3 and R.sub.4 each represents an alkyl group, provided that the total number of carbon atoms in the alkyl groups represented by R.sub.3 and R.sub.4 is 9 or more; Y is a hydrogen atom, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group or an aryl group).
    Type: Grant
    Filed: January 12, 1987
    Date of Patent: December 13, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masao Sasaki, Kaoru Onodera, Hideki Inahata
  • Patent number: 4789490
    Abstract: The invention provides an immersion oil composition for microscope especially suitable for use in the microscopic study using a fluorescence microscope by virtue of the greatly decreased fluorescence emission under ultraviolet irradiation in comparison with conventional immersion oils. The inventive immersion oil composition comprises a liquid dienic polymer, e.g. liquid polybutadiene, as a first component and, as a second component, one or a combination of compounds including (a) chlorinated paraffins, (b) polybutene, (c) carboxylic acid esters, (d) liquid paraffins, (e) saturated aliphatic alcohols and (f) alicyclic alcohols; said composition having a refractive index in the from 1.501 to 1.519 and a Abbe's number in the range from 40 to 46.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: December 6, 1988
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Toshiaki Tanaka
  • Patent number: 4788007
    Abstract: Method of using ophthalmic dosage of aqueous aloe vera gel as emollient and absorbent of UV radiation to shield eye retina by topically applying said gel in the eye.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: November 29, 1988
    Inventor: Neville A. Baron
  • Patent number: 4783142
    Abstract: The invention relates to a radiation protection filter for skin pigmentation during solar irradiation. The light transmittance of the radiation protection filter in the wavelength range between 380 and 780 nm is such that, when the radiation protection filter is used, the amount of radiation that penetrates the eye lens in the 340 to 400 nm range is, at the very most, that amount which would penetrate the eye lens when the radiation protection filter is not used. Radiation-caused eye damage is thus prevented.
    Type: Grant
    Filed: April 23, 1987
    Date of Patent: November 8, 1988
    Inventor: Maximilian F. Mutzhas
  • Patent number: 4783393
    Abstract: A dye mixture comprising at least two different unsymmetrical bis[1,2-diphenyl-1,2-ethanedithiolato(2.sup.-)-S,S'] -platinum compounds is disclosed. The mixture is useful in optical recording layers.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: November 8, 1988
    Assignee: Eastman Kodak Company
    Inventors: John C. Brazas, Jr., Harold T. Thomas, Neil F. Haley, Michael W. Fichtner
  • Patent number: 4765977
    Abstract: Method of establishing U.V. absorption spectrum equilibrium between the tear film and epithelium of the cornea by topically applying an aqueous dispersion of a high molecular weight polymer and an ocular chromophore as ophthalmic liquid sunglasses.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: August 23, 1988
    Inventor: Neville A. Baron
  • Patent number: 4758366
    Abstract: A leak detectable refrigeration composition including a polyhalogenated hydrocarbon refrigerant, a refrigeration oil, or a mixture of the two having a fluorescent dye dissolved therein, is prepared for use in refrigeration systems in automobile air conditioning systems, commercial refrigeration systems, and the like. Upon exposure to ultraviolet light, there is sufficient fluoresence by the refrigeration liquid to allow one to visually detect a leak in the system due to the presence of the dye at the source of the leak. Small leaks which were previously nondetectable with dye coloring systems detectable in normal light may now be detected due to the greater visibility of the flourescent dye under an ultraviolet light.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: July 19, 1988
    Assignee: Widger Chemical Corporation
    Inventor: Manher Parekh
  • Patent number: 4740070
    Abstract: Polyol(allyl carbonate) monomer, e.g., diethylene glycol bis(allyl carbonate), containing 1,4-dihydroxy anthraquinone in amounts sufficient to selectively absorb at least 94 percent of the visible and ultraviolet light segments of the electromagnetic spectrum below 530 nanometers is described. Also described are ophthalmic articles prepared by curing the monomer.
    Type: Grant
    Filed: November 4, 1986
    Date of Patent: April 26, 1988
    Assignee: PPG Industries, Inc.
    Inventor: Jeffrey D. Vance
  • Patent number: 4722595
    Abstract: A process for recording, storing and displaying optically readable information on a support using a polymer mixture P as the information carrier, wherein P comprises at least two different, mutually compatible polymers P.sub.1 and P.sub.2, and has a lower critical solution temperature (LCST), the optically differentiable modification of the information carrier being brought about by phase transition from a compatible polymer mixture below the LCST to demixed polymers P.sub.1 and P.sub.2 above the LCST or the reverse of this transition.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: February 2, 1988
    Assignee: Rohm GmbH Chemische Fabrik
    Inventor: Werner Siol