Organic Material Patents (Class 252/589)
  • Patent number: 6030554
    Abstract: A method of sterilizing an intraocular lens formed of a cross-linked polymer, wherein the intraocular lens is accommodated in a sealed container which permits transmission of an electron beam therethrough but inhibits entry of microorganisms thereinto, and the intraocular lens is irradiated with the electron beam, for sterilization of the intraocular lens accommodated in the container.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: February 29, 2000
    Assignee: Menicon Co., Ltd.
    Inventor: Masuji Ichihara
  • Patent number: 6007744
    Abstract: Liquids, such as petroleum fuels, are tagged with chemical compounds having a light-absorbing identifying chemical moiety and at least one polymerizable chemical moiety. The marker is identified in a specimen of the liquid by polymerizing the marker compound, generally along with additional co-polymerizable material.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: December 28, 1999
    Assignee: Morton International, Inc.
    Inventor: Wayne Earl Nacker
  • Patent number: 6001755
    Abstract: The invention relates to a thin layer of UV absorbing material, and a method of making such material by grinding UV absorbing glass into fine powder which can be suspended in a liquid matrix, for example, in index matching oil, thereby producing a transparent liquid which can be used to coat any material to impart UV absorption to such material.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: December 14, 1999
    Assignee: Corning Incorporated
    Inventors: Roger J. Araujo, Alain R. E. Carre, Serge A. M. Renault
  • Patent number: 5993700
    Abstract: This invention provides an aggregate of a compound capable of forming helical structures such that the aggregate is capable of achieving a specific rotation of at least 100,000.degree. for plane polarized light having a wavelength of 589 nm.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: November 30, 1999
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Thomas J. Katz, Colin P. Nuckolls
  • Patent number: 5977201
    Abstract: Polymer systems having reversibly temperature-dependent radiation transmission which are crosslinked with radiation induction, a process for their production, and their use for reversibly temperature-dependent control of the radiation transmission of glazing systems and solar-energy devices.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Ekkehard Jahns, Hubertus Kroner, Wolfgang Schrof, Utz Klodwig
  • Patent number: 5973093
    Abstract: Describes polymerizable organic compositions of a major amount of a first monomer component which is a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from about 2 to 35 weight percent of a second monomer component which is an alkoxylated bisphenol (or hydrogenated bisphenol) having acrylate or methacrylate groups, e.g., dimethacrylate of bisphenol A having 25 to 35 ethoxy units. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: October 26, 1999
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Randy E. Daughenbaugh, Robert D. Herold, Charles R. Wiedrich, John C. Crano
  • Patent number: 5965066
    Abstract: Compounds of the formula I according to claim 1 are excellently suitable as UV absorbers for use in cosmetic products, in particular sunscreen compositions, daytime care products and hair care products. They are furthermore suitable for protection of products.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: October 12, 1999
    Assignee: Haarmann & Reimer GmbH
    Inventors: Oskar Koch, Horst Surburg, Roland Langner, Horst Sommer
  • Patent number: 5961894
    Abstract: Bubbles are formed for entertainment and decorative purposes utilizing a liquid solution that includes a sufficient amount of a surface active agent to form the bubbles and a sufficient amount of a flourescent agent to provide illumination of the bubbles when viewed in the dark and under an external source of invisible ultraviolet or infrared radiation, such as a black light. The bubble solution is a pre-mixed, non-toxic solution that includes the surface active agent, or soap, to provide formation of the bubble and a flourescent agent such as Radiant.RTM. flourescent pigment dispersions to react to the illumination under the external source of invisible ultraviolet or infrared radiation such as a black light. Alternatively, the solution may be spread on a surface in decorative designs to be illuminated with the black light.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: October 5, 1999
    Inventors: Wallace Byron Swetland, Jr., Melody Sue Swetland
  • Patent number: 5961889
    Abstract: A process for producing a polythiol oligomer having disulfide linkages by reacting polythiol (with the functionality of two or above) with sulfur in a molar ratio of m to (m-1) (where m is an integer of 2 to 21) in the presence of a basic catalyst, whereby the oligomers produced have a degree of oligomerization of m (wherein m is defined as above). Specifically disclosed is a process for reacting 2,5-dimercaptomethyl-1,4-dithiane (DMMD) with sulfur in a molar ratio 2:1 or 3:2 in the presence of a basic catalyst, thereby producing an oligomer represented by the below formula: ##STR1## (wherein n is an integer of up to 21). Also disclosed are optical polymers made with the oligomer and optical materials and devices made with the polymer.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: October 5, 1999
    Assignee: Hoya Corporation
    Inventors: Jian Jiang, Masahisa Kosaka
  • Patent number: 5955005
    Abstract: An aqueous dispersion comprising at least one of the UV absorbing compounds of the following formulae I, II or III as below defined: A--B (I); A--C--A (II); or B--A--B (III); wherein in Formula (I) and (II) ##STR1## and in Formula III, A is ##STR2## Y being a direct bond, a substitute C.sub.1-4 alkylene group, ##STR3## and R.sub.1 to R.sub.5 independently of each other are hydrogen; C.sub.4-4 alkyl, the alkyl optionally being substituted; aryl; heterocyclyl; or any two of R.sub.1 to R.sub.5 which are adjacent, together form part of a ring, with the proviso that no more than four of R.sub.1 to R.sub.5 are hydrogen.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: September 21, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jurg Heller, Jean-Luc Mura
  • Patent number: 5922246
    Abstract: A lens for eyeglasses and a molded synthetic resin for light transmitting filters are disclosed, which can reduce the glare of light and can provide a clear color sense, while retaining the lightness in the field of vision. The lens for eyeglasses and the molded synthetic resin for light transmitting filter are made of a synthetic resin base material comprising an organic dye with an absorption maximum in the vicinity of the central wavelength on the standard relative visibility curve, as well as an ultraviolet light absorbing agent and a blue light absorbing agent, the base material having a transmittance minimum in the range of wavelength extending from 550 to 585 nm on the transmittance curve, the transmittance of light at the transmittance minimum being not greater than 25%, the average transmittance of light over the range of wavelength extending from 590 to 660 nm being not less than 15%, and the average transmittance over the range of wavelength extending from 470 to 550 nm being not less than 10%.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: July 13, 1999
    Assignees: Kyowa Hakko Kogyo Co., Ltd, Yamamoto Kogaku
    Inventors: Shoshiro Matsushita, Ikuo Shimizu, Kazuko Mabuchi, Yoshihisa Ishiba, Oritoshi Murata
  • Patent number: 5919403
    Abstract: This invention relates to homopolyester compositions having fluorescence quenchers polymerized therein ("poly quenchers"). Specifically the "poly quencher" polymeric compositions comprises repeating units from(a) a dicarboxylic acid component and(b) a diol component, wherein at least one of (a) and (b) is comprised of at least one fluorescence polyquencher capable of reducing fluorescence of a polymer below the fluorescence displayed when said polyquencher is not included.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: July 6, 1999
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
  • Patent number: 5872882
    Abstract: The invention relates to non-linear optically active (NLO) polycarbonates and to NLO active waveguides containing these polycarbonates. Waveguides containing these NLO polycarbonates have a low loss of signal, a high glass transition temperature and good polability and a high stability of the Pockel's coefficient.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: February 16, 1999
    Assignee: Akzo Nobel NV
    Inventors: Richard Herman Woudenberg, Tjerk Oedse Boonstra, Johannes Wilhelm Ladage, Ulfert Elle Wiersum
  • Patent number: 5849403
    Abstract: Disclosed is an organic thin film device having an organic thin film consisting of a mixed-stacked charge-transfer complex, wherein the organic thin film contains n species of donor molecule D.sub.1 . . . D.sub.n and m species of acceptor molecule A.sub.1 . . . A.sub.m and forms mixed crystal represented by (D.sub.1).sub.x1 . . . (D.sub.n).sub.xn -(A.sub.1).sub.y1 . . . (A.sub.m).sub.ym and the combinations of a donor molecule and an acceptor molecule consist of a group forming ionic complex crystal and a group forming neutral complex crystal.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: December 15, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Shinya Aoki, Toshio Nakayama
  • Patent number: 5817256
    Abstract: The invention is directed to an immersion oil for microscopy. The immersion oil includes an ester or ether with tricyclodecane structure as a main constituent and one or more high-boiling liquids as minor constituents. The immersion oil is free of halogens and exhibits a high UV-transmissibility and is characterized by low intrinsic fluorescence because the components utilized can be vacuum distilled.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: October 6, 1998
    Assignee: Carl-Zeiss-Stiftung
    Inventor: Hans-Joachim Weippert
  • Patent number: 5811503
    Abstract: Describes polymerizable organic compositions of from about 30 to 95 weight percent of a first monomer component which is an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, i.e., dimethacrylate of bisphenol A having an average of 1 to 4 ethoxy units, and from about 5 to 70 weight percent of a second monomer component which is an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, i.e., dimethacrylate of bisphenol A having 25 to 70 ethoxy units. Optionally there may also be present from about 0 to 65 weight percent of at least one monomer component which is selected from: (i) a monoethylenically unsaturated monomer that is polymerizable by free radical initiation; (ii) a bis?(meth)acryloyl-terminated!polyethylene glycol monomer; and (iii) a monomer having at least three terminal ethylenically-unsaturated groups. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: September 22, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Robert D. Herold, Randy E. Daughenbaugh, Charles R. Wiedrich
  • Patent number: 5806834
    Abstract: An ultraviolet-absorbing polymer film consists of a polymer and ultraviolet absorbers contained therein. The ultraviolet absorbers are composed of a compound having the formula (I): ##STR1## wherein each of R.sup.1 and R.sup.2 represents hydrogen, alkyl of 1 to 10 carbon atoms which may be substituted with phenyl, each of R.sup.3, R.sup.4 and R.sup.5 represents hydrogen, phenyl or alkyl of 1 to 5 carbon atoms, and each of X and Y represents cyano, --COOR, --CONHR, COR, --SO.sub.2 R or --SO.sub.2 NHR (R represents hydrogen, alkyl or aryl), or R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3 are linked each other to form a 5 or 6-membered ring; and at least one other compound capable of abosorbing light in a portion of ultraviolet region in which the ultraviolet absorber of the formula (I) cannot absorb.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: September 15, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toru Yoshida
  • Patent number: 5803929
    Abstract: An ultraviolet absorber comprising, as an effective component, a benzotriazole compound represented by the following general formula (I) ##STR1## wherein R represents hydrogen, methyl, ethyl or phenyl. The ultraviolet absorber undergoes minimal sublimation, has excellent thermal resistance, provides satisfactory light fastness for materials made of polyester-based synthetic fibers, particularly cation-dyeable polyester-based fibers, and is also inexpensive, generates few by-products and is easy to produce industrially.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: September 8, 1998
    Assignee: Nicca Chemical Co., Ltd.
    Inventors: Hajime Saito, Masahiro Makino
  • Patent number: 5792389
    Abstract: Novel water soluble dyes of the formula I are provided ##STR1## wherein R.sup.1 and R.sup.4 are alkyl of 1 to 4 carbon atoms or hydrogen; or R.sup.1 -R.sup.2 or R.sup.2 -R.sup.4 form part of aliphatic heterocyclic rings; R.sup.2 is hydrogen or joined with R.sup.1 or R.sup.4 as described above; R.sup.3 is --(CH.sub.2).sub.m --SO.sub.3.sup.-, where m is 1 to 6;X is N, CH or ##STR2## where Y is 2 --SO.sub.3.sup.- ; Z is 3, 4, 5 or 6 --SO.sub.3.sup.-. The novel dyes are particularly useful as the active media in water solution dye lasers.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: August 11, 1998
    Assignee: United States of America
    Inventors: Peter R. Hammond, James F. Feeman, George F. Field
  • Patent number: 5782969
    Abstract: Present invention provides ionic spiropyran compounds having a C10-C22 alkyl group or groups at the 1'- and/or 8-positions of 3',3'-dimethyl-6-nitrospiro?2H-1-benzopyran-2',2'-indoline! and a composite material made by conjugating the said ionic spiropyrans with clay mineral, the said composite material being capable of forming a transparent thin film which is photo-interconvertible between the said spiropyrans and the corresponding merocyanines.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: July 21, 1998
    Assignee: Nissho Iwai Bentonite Co., Ltd.
    Inventor: Katsuhiko Takagi
  • Patent number: 5772925
    Abstract: An anti-reflective coating composition comprising a polyimide dissolved in an organic solvent is used to form an anti-reflective coating beneath a chemical amplification type resist layer. The composition allows a fine resist pattern to be formed with high accuracy in a convenient, efficient, reproducible manner.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: June 30, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Satoshi Watanabe, Toshinobu Ishihara, Ichiro Kaneko, Katsuyuki Oikawa, Yoshihumi Takeda
  • Patent number: 5770114
    Abstract: The present invention concerns compositions, which comprise an aprotic polar solvent, at least one electrochromic compound, and a compound of the formula I ##STR1## wherein R.sub.1 is, for example, tert-butyl, and R.sub.2 is, for example, --CH.sub.2 --CH.sub.2 --COO--R.sub.7 --, where R.sub.7 is n-butyl or n-pentyl. Among embodiments of the invention are compositions used as media of variable transmittance in electrochromic devices, especially single-compartment, self-erasing, solution-phase electrochromic devices. The compounds of Formula I have increased solubility in aprotic polar solvents used in electrochromic devices and are effective in stabilizing compositions, which comprise at least one electrochromic compound and are useful as media of variable transmittance in electrochromic devices, against degradation due to exposure to UV-radiation.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: June 23, 1998
    Assignee: Gentex Corporation
    Inventors: Harlan J. Byker, Ramanujan Srinivasa
  • Patent number: 5759447
    Abstract: An erasable optical memory is provided by an erasable bistable photoactive chromophore that is covalently bonded to a polymer microsphere. An azobenzene chromophore that is bonded to the microsphere by an oxygen or NH replacement of chlorine, or a CH double bond to N, is preferred. An array of such microspheres is encoded by applying radiation at a resonant wavelength to induce a conformational change in the chromophores for selected microspheres, and the encoded pattern is read out by detecting changes in either absorption or fluorescence.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: June 2, 1998
    Assignee: Hughes Electronics Corporation
    Inventors: Uzi Efron, Chiung-Sheng Wu, Larry Raymond Dalton, Eli Wiener-Avnear
  • Patent number: 5756010
    Abstract: The present invention provides a UVA protective eyeshield that includes a transparent substrate having dispersed therein an effective amount of 1-di-n-hexylamino-4,4-dicyanobutadiene.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: May 26, 1998
    Assignee: Eastman Kodak Company
    Inventors: Charles Howard Appell, Raymond Thomas Jones
  • Patent number: 5731890
    Abstract: A compound having nonlinear optical properties of the general formula:Ar.sup.1 CR.sup.1 .dbd.CR.sup.2 (Ar.sup.2 CR.sup.3 .dbd.CR.sup.4).sub.n Ar.sup.3 (I)wherein, n represents a whole number; R.sup.1, R.sup.1, R.sup.3 and R.sup.4 groups are independently selected from H, branched aliphatic, straight chain aliphatic, branched silane or straight chain silane; Ar.sup.1 and Ar.sup.3 are aromatic radicals having a substituent in at least one position adjacent to a site of attachment of the C.dbd.C double bond and having at least one electron withdrawing or electron donating substituent in at least one of the remaining positions; Ar.sup.2 is an aromatic radical having a substituent in at least one position adjacent to a site of attachment of the C.dbd.C double bond; with the proviso that the substituent in at least one position adjacent to the site of attachment of the C.dbd.C double bond and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 groups are sufficiently large to cause Ar.sup.1, Ar.sup.2 and Ar.sup.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: March 24, 1998
    Assignee: The University of Toledo
    Inventors: James E. Gano, Padmanabhan Sekher
  • Patent number: 5731137
    Abstract: There is disclosed an emulsified dispersion, in which at least one compound of the formula (1) dissolved in an organic solvent comprising at least one high-boiling organic solvent satisfying the condition X.gtoreq.85 in formula (A) is emulsified in a water medium; with the proviso that phthalates and compounds having an epoxy group and having the viscosity less than 100 mPas are excluded from said high-boiling organic solvents: formula (1) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6, which are the same or different, each represent a hydrogen atom or a substituent, and R.sup.5 and R.sup.6 may bond together to form a 6-membered ring,formula (A)X=24.7.times.Log.sub.10 Y-11.7.times.Z+43.7wherein Y and Z stand for, respectively, the viscosity in mPas at 25.degree. C. and the specific water content in % by weight of the high-boiling organic solvent. There is also disclosed a silver halide color light-sensitive material containing the emulsified dispersion.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: March 24, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuko Saito, Masatoshi Nakanishi
  • Patent number: 5716554
    Abstract: An ultraviolet light absorbent comprising an ester mixture derived from esterification of pentaerythritol or trimethylolpropane and a saturated branched-chain fatty acid with a carbon number of 8-18 and ortho- or paramethoxycinnamic acid in a specific ratio. The ultraviolet light absorbent with prescribed ultraviolet light absorbing power has a moderate viscosity and can be handled and worked without inconvenience and/or difficulty.
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: February 10, 1998
    Assignees: Shiseido Co., Ltd., The Nisshin Oil Mills, Ltd.
    Inventors: Sadaki Takada, Toshihiko Nakane, Tsuyoshi Tsuchiya, Yutaka Nishida
  • Patent number: 5705102
    Abstract: A naphthopyran compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are each selected from the group consisting essentially of hydrogen, a stable organic radical, a heterocyclic group, a halogen, a nitrogen-substituted group, and a nitrogen-substituted ring compound and wherein A is a substituted divalent aromatic radical that includes substituents selected from the group consisting essentially of hydrogen and the stable organic radical.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: January 6, 1998
    Assignee: Vision-Ease Lens, Inc.
    Inventors: Frank J. Hughes, Edward A. Travnicek
  • Patent number: 5677050
    Abstract: Retroreflective sheeting having an abrasion-resistant ceramer coating that is prepared from about 20% to about 80% ethylenically unsaturated monomers; about 10% to about 50% of acrylate functionalized colloidal silica; and about 5% to about 40% N,N-disubstituted acrylamide or N-substituted-N-vinyl-amide monomer having a molecular weight between 99 and 500 atomic mass units; wherein said percentages are weight percents of the total weight of said coating. A method of coating retroreflective sheeting with an abrasion-resistant cured ceramer layer is also disclosed.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: October 14, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Zayn Bilkadi, David C. May
  • Patent number: 5628935
    Abstract: A naphthopyran compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are each selected from the group consisting essentially of hydrogen, a stable organic radical, a heterocyclic group, a halogen, a nitrogen-substituted group, and a nitrogen-substituted ring compound and wherein A is a substituted divalent aromatic radical that includes substituents selected from the group consisting essentially of hydrogen and the stable organic radical.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: May 13, 1997
    Assignee: Vision-Ease Lens, Inc.
    Inventors: Frank J. Hughes, Edward A. Travnicek
  • Patent number: 5620838
    Abstract: A polymeric UV absorbing compound which comprises UV absorbing monomeric units of at least 0.05 weight percent of ionic units which have an ionizable group which is ionized at all pH values between 5 to 10. Photographic elements which contain such polymeric compounds and methods of making such polymers and photographic elements, are also provided. The polymeric UV absorbing compounds are directly dispersible in water.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: April 15, 1997
    Assignee: Eastman Kodak Company
    Inventors: Tienteh Chen, Hwei-Ling Yau, Edward Schofield
  • Patent number: 5609797
    Abstract: A method for selectively altering the refractive index of selected portions of a polyimide material can be used to form a variety of optical components, such as waveguides that can be used as optical interconnections between elements in electronic or microelectronic circuits. The method includes the steps of introducing a dopant which is capable of altering the index of refraction of the film and which will be photoattached to the polyimide material after exposure to radiation, exposing selected portions of the material to radiation, removing at least some of the dopant from the non-irradiated portions of the material, and then exposing the non-irradiated portions of the material to radiation of a type and quantity sufficient to alter the index of refraction of the material.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: March 11, 1997
    Assignee: The Boeing Company
    Inventor: Kishore K. Chakravorty
  • Patent number: 5607624
    Abstract: A process for the preparation of compounds of formula I ##STR1## wherein the general symbols are as defined in claim 1, which comprises reacting a compound of formula III ##STR2## wherein the general symbols are as defined in claim 1, with a compound of formula IV[H].sub.n --R.sub.1 (IV).
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: March 4, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Nesvadba, Samuel Evans, Ralf Schmitt
  • Patent number: 5601756
    Abstract: Liquid UV stabilizers which are stable at room temperatures or below made from di-substituted and tri-substituted benzophenone compositions. A process to render di-substituted and tri-substituted benzophenone admixtures stable liquids at room temperatures or below involving heating the admixture to a temperature in the range of 80.degree.-175.degree. C. for a period of time sufficient that when the admixture is cooled to room temperature the admixture remains liquid.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: February 11, 1997
    Inventor: John V. Swearengin
  • Patent number: 5588083
    Abstract: The invention pertains to a non-linear optically active (NLO) side chain polycarbonate and to NLO active waveguides containing said polycarbonate. Waveguides containing this NLO polycarbonate have a low loss of signal. Polycarbonates based on bischloroformates of hexafluorobisphenol A, hexafluorotetrabromobisphenol A and bisphenol S or deuterated bisphenol A or sulphonylbiphenol are especially preferred within the framework of the invention: they were found to give an exceptionally low loss of signal. The invention further pertains to cross-linkable and already cross-linked polycarbonates. Especially preferred polycarbonates according to the invention are those where the diol comprises a rigid donor group. These polycarbonates have a high Tg, which renders them thermally stable.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: December 24, 1996
    Assignee: Akzo Nobel N.V.
    Inventors: Tjerk O. Boonstra, Ulfert E. Wiersum
  • Patent number: 5587112
    Abstract: A new class of proton transfer, benzazole, fluorescent compounds is composed of a 2-benzazolyl moiety covalently bonded to an aromatic fused ring heterocyclic moiety. The 2-benzazolyl moiety may be a 2-benzoxazolyl, 2-benzothiazolyl, or 2-benzimidazolyl. The aromatic fused ring heterocyclic moiety may be a 3-dibenzofuranyl or 3-dibenzothiophenyl each substituted at the 2 position with a proton donating group, or a 2-carbazolyl substituted at the 3 position with a proton donating group. The proton donating group may be hydroxy, sulfonamido, carbonamido, and the like, and preferably is hydroxy. The fluors are soluble in organic matrix materials such as solvents, monomers, resins, polymers, and the like. The UV-excited fluors emit short-lived fluorescence at .gtoreq.520 nm and may be used in the manufacture of fluorescent coatings, objects, scintillators, light sources and the like.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: December 24, 1996
    Assignee: Philadelphia College of Pharmacy and Science
    Inventors: Joel M. Kauffman, Peter T. Litak
  • Patent number: 5585228
    Abstract: Ultraviolet absorbing compounds of formula (I) and photographic elements containing such compounds: ##STR1## wherein: R.sub.4 is a bivalent linking group; the benzo or phenyl ring shown may be further substituted or unsubstituted;L is a bivalent linking group;p is 0 or 1;A* is an alkyl group having an asymmetric carbon or silicon atom, and;wherein the ultraviolet absorbing compound of formula (I) is a mixture of two enantiomers about the asymmetric carbon or silicon of A*.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 17, 1996
    Assignee: Eastman Kodak Company
    Inventors: Lal C. Vishwakarma, Glenn M. Brown
  • Patent number: 5575958
    Abstract: Aqueous dispersions of UV absorbing s-triazine compounds comprising(a) 5 to 50 percent by weight of an s-triazine compound of formula ##STR1## wherein R, R.sub.1, R.sub.2 and n are as defined in claim 1, and (b) 0 to 18 percent by weight of an anionic compound, and(c) 0 to 18 percent by weight of a nonionic compound, with the proviso that at least one of components (b) and (c) must be present.These dispersions are excellent formulations for enhancing the lightfastness of dyeings on synthetic fibers, especially on polyester or acid-modified polyester fibers.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: November 19, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin J ollenbeck, Josef Zelger
  • Patent number: 5552149
    Abstract: A method for microencapsulating agriculturally active substances such as pesticides to provide improved resistance to environmental degradation, especially ultra-violet light. The method employs as the UV protectant lignosulfonates, such as sulfite lignin or sulfonated lignin, or alternately sulfonated lignite, sulfonated tannins, napthalene sulfonates or other related compounds in combination with a protein such as a high bloom gelatin to form a capsule wall. The capsule wall formed by the interaction of these components is durable and has an ultra-violet protectant as an integral part of its structure.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: September 3, 1996
    Assignee: Lignotech USA, Inc.
    Inventors: Stuart E. Lebo, Jr., William J. Detroit
  • Patent number: 5536453
    Abstract: Light screening compositions which contain a compound of the formula ##STR1## wherein R.sup.1 represents H, C.sub.1-19 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.2 represents H, C.sub.1-29 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.3 represents H, C.sub.1-19 -alkyl, C.sub.1-19 -hydroxyalkyl, C.sub.1-19 -polyhydroxyalkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl or optionally lower-alkyl or oxy-lower alkyl substituted pyridyl, a polyether residue, a phenylsulphonic acid residue andR.sup.2 and R.sup.3 together with the N atom can also form a ring.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: July 16, 1996
    Assignee: Givaudan-Roure Corporation,
    Inventor: Ulrich Huber
  • Patent number: 5523027
    Abstract: The present invention provides a UV light absorber comprising an azomethine compound represented by the formula: ##STR1## wherein R.sup.1 is a hydrogen atom, or a straight- or branched-chain alkyl group having 1 to 4 carbon atoms; and R.sup.2 and R.sup.3 independently represent a hydrogen atom, a carboxyl group, a halogen atom, an alkoxy group having 1 to 4 carbon atoms, a straight- or branched-chain alkyl group having 1 to 12 carbon atoms or an alkoxycarbonyl group having 2 to 5 carbon atoms as an active ingredient.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: June 4, 1996
    Assignee: Orient Chemical Industries, Ltd.
    Inventor: Masahiro Otsuka
  • Patent number: 5501821
    Abstract: An optical article, for the transmission of electromagnetic radiation. The optical article includes a medium, which exhibits a second-order electric susceptibility greater than 10.sup.-9 electrostatic units. The medium includes polar aligned dipole subunits. Each dipole subunit has a plurality of noncentrosymmetric molecular dipoles and a connector system. Each molecular dipole has an electron donor moiety, an electron acceptor moiety, and a linking moiety. The linking moiety has a pair of covalent bonds to the connector system. Each molecular dipole has a conjugated .pi. bonding system extending from the electron donor moiety along the linking moiety to the electron acceptor moiety to permit oscillation of the molecular dipole between a ground state and an excited state, which states differ in polarity. The connector system joins the linking moieties to complete a solitary ring or a system of fused rings, which retain the molecular dipoles in substantially parallel relative relation.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: March 26, 1996
    Assignee: Eastman Kodak Company
    Inventors: Craig S. Willand, Douglas R. Robello, Edward J. Urankar, Abraham Ulman
  • Patent number: 5498345
    Abstract: Aqueous stable dispersions of a mixture of sparingly soluble UV absorbers, which comprises(a) 5 to 50% by weight of a mixture of a benzotriazole of formula ##STR1## and a 2-hydroxybenzophenone of formula ##STR2## wherein R is halogen, C.sub.1 -C.sub.12 alkyl, lower alkoxy, lower alkoxycarbonyl, cycloalkyl, aryl, C.sub.1 -C.sub.12 alkylaryl or aralkyl, and the rings A and B, each independently of the other, may be further substituted by halogen, hydroxy, lower alkyl, lower alkoxy or lower alkoxycarbonyl,R.sub.1 is hydrogen, hydroxy, C.sub.1 -C.sub.14 alkoxy or phenoxy,R.sub.2 is hydrogen, halogen or lower alkyl,R.sub.3 is hydrogen, hydroxy or lower alkoxy, andR.sub.4 is hydrogen or hydroxy,(b) 2 to 18% by weight of an anionic compound, and(c) 0 to 10% by weight of a nonionic compound.These dispersions of a mixture of UV absorbers are excellent compositions for enhancing the lightfastness of dyeings on synthetic fibers and, in particular, on polyester fibers or acid-modified fibers.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: March 12, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Jollenbeck, Alfred J. Neukom
  • Patent number: 5443909
    Abstract: The present invention provides a heat sensitive recording material comprising a substrate, a recording layer formed over the substrate and containing a colorless or light-colored basic dye and a color acceptor, and a protective layer formed over the recording layer, the recording material being characterized in that microcapsules having an ultraviolet absorber enclosed therein and having substantially no color forming ability are incorporated in the protective layer.Further, the present invention provides microcapsules having an ultraviolet absorber and as required an organic solvent enclosed therein, which have capsule wall film of synthetic resin and mean particle size of 0.1 to 3 .mu.m.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: August 22, 1995
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Ritsuo Mandoh, Takehiro Minami, Katsuhiko Ishida, Hisayoshi Mitoh
  • Patent number: 5443758
    Abstract: A steroidal ketone compound having a substituted or unsubstituted aromatic group or heterocyclic aromatic group is useful as a non-linear optical material in a non-linear optical device.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: August 22, 1995
    Assignee: Hatachi Chemical Company, Ltd.
    Inventor: Makoto Kaji
  • Patent number: 5413740
    Abstract: A photochromic plastic has been discovered which is useful in the manufacture of protective eyeglasses. The photochromic plastic comprises a host polymer material and a dopant. The plastic exhibits photochromic properties due to excited state absorption which occurs when the material is exposed to UV light. The eyeglasses function as protection against radiation from the sun as well as from industrial and other sources. The dynamic range and response time of this novel photochromic plastic may be tailored in accordance with the particular use or application desired.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: May 9, 1995
    Assignee: Trustee of Boston University
    Inventor: Alexander Lempicki
  • Patent number: 5401438
    Abstract: Disclosed is a novel UV light absorbing compound which can preferably be employed in the art of colored molding plastics, resin films, heat-sensitive transfer materials, liquid crystal display materials, color photographs and the like, and method for producing thereof. The UV light absorbing compound is characterized by the general formula: ##STR1## wherein R.sup.1 represents linear or branched alkyl or aralkyl group, and R.sup.2 represents --CN or --COOR.sup.3, wherein R.sup.3 represents substituted or unsubstituted alkyl or aralkyl group.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: March 28, 1995
    Assignee: Orient Chemical Industries, Ltd.
    Inventor: Masahiro Otsuka
  • Patent number: 5395567
    Abstract: A novel photochromic spironaphthopyran composition having the general structural formula: ##STR1## in which phenyl substituents positioned adjacent to the oxygen of the pyran ring are linked at their adjacent ortho positions by the functionality (R).sub.n wherein n is the integer 0-2 and wherein R is methylene (--CH.sub.2 --), vinylene (--C.dbd.C--), or a carbon-carbon bond, i.e., when n is 0. The groups R.sub.1 and R.sub.5 -R.sub.10 may be hydrogen or a variety of substituents.
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: March 7, 1995
    Assignee: PPG Industries, Inc.
    Inventors: Barry Van Gemert, David B. Knowles
  • Patent number: 5383050
    Abstract: The compounds 4-chloro-4'-hydroxybenzophenone, methyl 3,4-diaminobenzoate, N-(4-aminobenzenesulfonyl)-acetamide, methyl 4-hydroxy-3,5-dimethoxybenzoate, 2-chloro-4-cyano-6-methylaniline, 4'-hydroxy-2-phenylacetophenone and methyl 3,4-dihydroxybenzoate form high quality crystals with high melting point. They are useful for second order non-linear optical process devices such as wavelength conversion devices.
    Type: Grant
    Filed: October 5, 1993
    Date of Patent: January 17, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hironobu Yamamoto, Robert Johnson, Satoru Funato
  • Patent number: H1586
    Abstract: An audio optical processor unit employing a nonlinear organic optical element which may be in the form of a nonlinear polymer, a nonlinear organic material or a mixture of liquid crystal materials or polymers. The nonlinear organic optical element is interfaced by a piezo-electric crystal which encodes a laser beam passing through the optical element by inducing changes in the index of refraction or the changes in voltage potential across the polymer or non-linear organic material. The resulting encoded output is detected in a conventional manner by a photodetector array.
    Type: Grant
    Filed: January 30, 1990
    Date of Patent: September 3, 1996
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: William G. Fellows, Lester Weinberger