Froth-flotation Or Differential Adherence Patents (Class 252/61)
  • Patent number: 4274950
    Abstract: Process using collectors for the flotation of minerals which allow the separation or enrichment of certain minerals, even at pH values around 7. These collectors are organic sulphides of the type R--S--R', in which the two groups R and R' are different and at least one of them preferably carries a substituent including oxygen or sulphur. The collectors are desirably used in a proportion of 10-100 ppm in relation to the weight of the mineral subject to flotation.
    Type: Grant
    Filed: June 25, 1979
    Date of Patent: June 23, 1981
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Etienne Larribau, Pierre Tozzolino
  • Patent number: 4269721
    Abstract: A method of treating stored coal to prevent dusting and reduce moisture penetration of the coal, comprising forming a hardened crust of a hydrated calcium sulfate containing composition over the exposed surface of the coal pile. The calcium sulfate product produced from the fluid bed combustion of coal in the presence of limestone is particularly useful.
    Type: Grant
    Filed: December 21, 1979
    Date of Patent: May 26, 1981
    Assignee: Stauffer Chemical Company
    Inventors: Klaus W. Mueller, Norman R. Olsen
  • Patent number: 4261846
    Abstract: Zinc sulfide is concentrated by a froth flotation process using a substituted benzotrifluoride compound as depressant for calcium fluoride. The benzotrifluoride compounds are substituted by hydrophilic groups such as hydroxy, carboxylic acid and amino.
    Type: Grant
    Filed: July 23, 1979
    Date of Patent: April 14, 1981
    Assignee: United States Borax & Chemical Corporation
    Inventor: Martin Wilson
  • Patent number: 4253944
    Abstract: Certain condensation products of a fatty acid or fatty acid ester and a hydroxyalkylated alicyclic nitrogen-containing compound are useful as conditioners to improve the recovery of clean coal in a froth flotation process. The presence of these condensation products in the flotation medium is particularly effective to enhance the recovery of oxidized bituminous coal.
    Type: Grant
    Filed: December 28, 1979
    Date of Patent: March 3, 1981
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4220524
    Abstract: A collector agent for use in froth flotation processes to recover metal values of sulphide ores is disclosed which agent comprises the reaction product resulting from mixing and reacting in the presence of visible light, heat, or both, a mixture of:(i) a mixture of hydrocarbons having from 5 to 10 (inclusive) carbon atoms,(ii) methyl isobutyl carbinol (MIBC),(iii) ethyl xanthyl ethylformic ester (EEF), and(iv) elemental sulphur (S).
    Type: Grant
    Filed: January 13, 1978
    Date of Patent: September 2, 1980
    Assignee: Codelco-Chile
    Inventor: Raul Poblete
  • Patent number: 4213871
    Abstract: The invention relates to a biological activator for septic tanks. The biological activator is characterized by the fact it is in the form of a non-corrosive, non-toxic, finely-divided product having a significant specific surface constituting a base for the optional anaerobic microbic flora, permitting an increase in the density of bacterial saturation in the septic tank for an equivalent quantity of nutriment.
    Type: Grant
    Filed: July 6, 1977
    Date of Patent: July 22, 1980
    Assignee: Societe Anonyme dite:EPARCO
    Inventor: Tristan Bavaveas
  • Patent number: 4211644
    Abstract: A collector composition for use in concentrating metallic mineral ores by froth flotation which comprises a mixture of a mercaptan and an emulsifying or wetting agent adapted to improve the dispersion of the mercaptan into the pulp, and a froth flotation method for concentrating metallic mineral ores wherein the above collector composition is employed as the collector, are disclosed herein.
    Type: Grant
    Filed: November 17, 1977
    Date of Patent: July 8, 1980
    Assignee: Pennwalt Corporation
    Inventor: Adriaan Wiechers
  • Patent number: 4208487
    Abstract: A combination of conventional frothing agent and a particular amino-aldehyde resin provides better recovery of mineral values than can be obtained with either agent alone.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: June 17, 1980
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Eugene L. Smith, Jr., Ernie F. Huliganga
  • Patent number: 4206063
    Abstract: The mixture of a hydrophobic alcohol and a nonionic surfactant is an effective dewatering aid for mineral concentrates, significantly lowering the moisture content.
    Type: Grant
    Filed: December 5, 1978
    Date of Patent: June 3, 1980
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Morris E. Lewellyn, Charles Dugan
  • Patent number: 4196092
    Abstract: A conditioning agent comprising a frother and a bis(alkyl)ester of a sulfosuccinic acid salt provides high coal recovery with reduced ash content.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: April 1, 1980
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Morris E. Lewellyn, Eugene L. Smith, Jr.
  • Patent number: 4191641
    Abstract: Process for flotation of copper sulfide ones using a flotation reagent produced by the reaction of an alkali metal lower alkyl xanthate and 2-chloroisopropyl formate.
    Type: Grant
    Filed: January 26, 1978
    Date of Patent: March 4, 1980
    Assignee: Mineric Corporation
    Inventors: Arthur H. Fischer, Lawrence E. Strow, Franklin A. Bolth
  • Patent number: 4171261
    Abstract: A process is provided for the flotation of ores, wherein compounds of the formula RO-(C.sub.x H.sub.2x O).sub.n CH.sub.2 COOM, wherein R is an aliphatic residue of 8-18 carbon atoms or an alkylaryl residue having 6-12 carbon atoms in the alkyl moiety, n has an average value of 0-10 and x has a value of 2 or 3, and M is a monovalent cation, are used as collectors, together with the usual fatty acid type collectors, these collector mixtures possessing synergistic properties. Also collector mixtures for use in such a process are provided.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: October 16, 1979
    Assignee: Chem-Y, Fabriek van Chemische Produkten B.V.
    Inventors: Wim Dorrepaal, Gerardus M. VAN DEN Haak, Joseph M. Weehuizen, Johan G. Aalbers
  • Patent number: 4147644
    Abstract: Combinations of fatty acids and anionic perfluoroalkyl compounds are superior collectors in the froth flotation of non-sulfide minerals.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: April 3, 1979
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Eugene L. Smith, Jr., Ernie F. Huliganga
  • Patent number: 4139482
    Abstract: A collector combination of a fatty acid and an N-sulfodicarboxylic acid aspartate provides boostering action in the recovery of non-sulfide minerals.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: February 13, 1979
    Assignee: American Cyanamid Company
    Inventor: Rudolph N. Holme
  • Patent number: 4139481
    Abstract: A combination of a fatty acid and an alkylamidoalkyl monoester of a sulfosuccinic acid or salt thereof provides improved recovery of non-sulfide ores by froth flotation.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: February 13, 1979
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Eugene L. Smith, Jr.
  • Patent number: 4138350
    Abstract: A combination of fatty acid and a monoester of sulfosuccinic acid or salt thereof provides improved recovery of non-sulfide ores by froth flotation.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: February 6, 1979
    Assignee: American Cyanamid Company
    Inventors: Samuel S. Wang, Eugene L. Smith, Jr.
  • Patent number: 4136020
    Abstract: The performance of xanthogen formates as reagents for the flotation of sulfide copper ores is significantly improved by reacting the xanthogen formate with an aromatic amine. In a preferred embodiment, up to about 20% of an aromatic diamine, most particularly o-phenylene diamine and o-toluene diamine, is used.
    Type: Grant
    Filed: November 11, 1976
    Date of Patent: January 23, 1979
    Assignee: Minerec Corporation
    Inventor: Arthur H. Fischer
  • Patent number: 4136019
    Abstract: Beneficiation of complex non-sulfide ores such as fluorspar is effected by flotation using organic compounds containing the CF.sub.3 group as selectivity agents.
    Type: Grant
    Filed: June 13, 1977
    Date of Patent: January 23, 1979
    Assignee: United States Borax & Chemical Corp.
    Inventor: Martin Wilson
  • Patent number: 4113638
    Abstract: An improved gypsum dispersion frothing composition is presented comprised of a first component which is a neutralized sulfonic acid or neutralized sulfuric acid ester and a second component which is a neutralized dipropyl benzene sulfonate or a mixture of neutralized alkyl benzene sulfonates containing at least 50% neutralized dipropyl benzene sulfonate. The preferred member of the first component is neutralized alkyl benzene sulfonates having 10 to 14 alkyl carbon atoms, and the preferred second component is neutralized diisopropyl benzene sulfonate. The preferred neutralizing agents are sodium, ammonium ion, or triethanolamine. The frothing composition is preferably used at a concentration of 0.01 to 0.1 parts per 100 parts of gypsum.
    Type: Grant
    Filed: August 4, 1976
    Date of Patent: September 12, 1978
    Assignee: Atlantic Richfield Company
    Inventor: Robert Coleman Taylor
  • Patent number: 4102827
    Abstract: Cationic polyelectrolytes are formed by the polymerization in absence of oxygen of a monomer of the general formula: ##STR1## where x is 3 or more than 6 and Z is I, Br or Cl to form high charge density linear polymers. Segments of the linear polymer may be attached to or formed in the presence of polyfunctional reactive tertiary amines or halogen polymeric substrates or polyfunctional lower molecular reactive polyfunctional substrates to form branched or star polyelectrolytes by a quaternization polymerization reaction.
    Type: Grant
    Filed: January 21, 1976
    Date of Patent: July 25, 1978
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Shiao-Ping Siao Yen
  • Patent number: 4090972
    Abstract: The use of a secondary alcohol or an ethoxylated secondary alcohol in conjunction with conventional fatty acid in the flotation of non-sulfide minerals eliminates or reduces requirements for fuel oil usage.
    Type: Grant
    Filed: September 16, 1976
    Date of Patent: May 23, 1978
    Assignee: American Cyanamid Company
    Inventors: Samuel Shan-Ning Wang, Eugene Leroy Smith, Jr.
  • Patent number: 4036746
    Abstract: The quality of dialkyl dithiophosphates as flotation promoters is improved by addition to the neutralized acid of small quantities of a trialkyl amine. More important, promoters thus stabilized exhibit markedly increased storage life and substantially no tendency to corrode steel. Shipping and storage of these products is thus facilitated.
    Type: Grant
    Filed: March 22, 1976
    Date of Patent: July 19, 1977
    Assignee: Minerec Corporation
    Inventors: Lawrence Evans Strow, Franklin Anderson Bolth
  • Patent number: 3992315
    Abstract: A process for concentrating and recovering water soluble glycosides from aqueous solution by foaming the solution, collecting the foam as a concentrated-in-glycoside product.
    Type: Grant
    Filed: August 20, 1974
    Date of Patent: November 16, 1976
    Assignee: Omni Research Incorporated
    Inventors: Douglas N. Dibb, John B. Barbour
  • Patent number: 3975295
    Abstract: Surface active compositions useful as cationic emulsifiers, flotation agents, corrosion inhibitors and the like are provided in the form of an admixture of a long chain aliphatic primary mono-amine or a similarly substituted trimethylenediamine and an alkoxylated derivative of said mono-amine. Additionally disclosed are the alcoholic concentrates of the aforesaid compositions. Such compositions and concentrates thereof are characterized in being homogenous liquids further exhibiting freeze-thaw stability and excellent dispersibility in water at ambient temperatures for forming their acid salts.
    Type: Grant
    Filed: August 26, 1974
    Date of Patent: August 17, 1976
    Assignee: Ashland Oil, Inc.
    Inventor: S. Don Koch
  • Patent number: 3971836
    Abstract: The quality of dialkyl dithiophosphates as flotation promoters is improved by addition to the neutralized acid of small quantities of a trialkyl amine. More important, promoters thus stabilized exhibit markedly increased storage life and substantially no tendency to corrode steel. Shipping and storage of these products is thus facilitated.
    Type: Grant
    Filed: August 16, 1974
    Date of Patent: July 27, 1976
    Assignee: Minerec Corporation
    Inventors: Lawrence Evans Strow, Franklin Anderson Bolth
  • Patent number: 3932274
    Abstract: Metal ions are effectively eliminated from aqueous solutions containing the ame by treating the solution with a metal sequestering agent which is a condensation product of a higher alkyl halide with a polyamine.
    Type: Grant
    Filed: June 11, 1974
    Date of Patent: January 13, 1976
    Assignee: Director-General of the Agency of Industrial Science and Technology
    Inventors: Gaku Izumi, Tetsuo Kimura, Katsuyoshi Mori, Michiko Koizumi