Abstract: A process for separating and recovering minerals, such as molybdenum or graphite, from ores with which they occur by addition of an amino mercaptothiadiazole to an ore flotation process.

Abstract: A deinking composition is used for reclamation of waste paper and comprises (a) an alkylene oxide adduct to a mixture of a natural oil or fat and a polyhydric alcohol and (b-1) an alkylene oxide adduct of a higher alcohol, (b-2) a sulfate of (b-1) or (b-3) a higher fatty acid.

Abstract: Particles of a desired mineral are recovered from particles of an unwanted mineral in an aqueous slurry by a froth flotation process in which, after treatment of the mineral particles with a collector, a predominantly hydrophobic polymeric flocculating agent, which will selectively flocculate the desired mineral particles, is added to the slurry. The predominantly hydrophobic polymeric flocculating agent may be for example a polyvinyl ether or a polybutadiene and may be predispersed in a carrier liquid, which may be the frother used to produce the froth.

Abstract: Bicyclic decanedioic acids corresponding to the following general formula ##STR1## in which R represents a C.sub.1 -C.sub.22 alkyl radical, a C.sub.2 -C.sub.34 alkylcarbonyl radical, or a residue of a polyalkoxylated C.sub.2 -C.sub.22 fatty alcohol, represent a new class of dicarboxylic acids which are useful as flotation aids in the flotation of non-sulfidic ores.

Abstract: A new depressant composition is provided for the enhanced separation into separate value metal concentrates of copper, nickel, zinc, lead present in polymetallic and massive sulphide ores.The depressant is added in an aqueous solution prepared by dissolving first a mixture of quebrachio and dextrin, or quebracho and guar gum. To the solution of modified quebracho a water soluble salt of lignin sulphonate is added. The aqueous polymer of modified quebracho lignin sulphonate is further mixed with one or more of the following inorganic reagents: water soluble cyanide, metal sulphates and water soluble sulphites. The resulting depressant is added together with conventional flotation reagents in conventional mineral separation stages as required.

Abstract: Collector compositions for use in froth flotation processes for the beneficiation of gold and silver values from base metal sulfide ores are disclosed. The collector compositions comprise at least one mercaptobenzothiazole compound selected from compounds of the formula: ##STR1## wherein R is a C.sub.1 -C.sub.8 alkyl or a C.sub.2 -C.sub.8 alkoxy radical. The use of the substituted mercaptobenzothiazole collectors provides excellent metallurgical recoveries of gold and silver values in froth flotation processes conducted over a broad range of pH conditions including acid, neutral and mildly alkaline pH.

Abstract: Collector compositions for use in froth flotation processes for the beneficiation of gold, silver and platinum group values from base metal ores are disclosed. The collector compositions comprises at least one monothiophosphate compound selected from compounds of the formula: ##STR1## wherein each R is a C.sub.2 -C.sub.8 alkyl or a ##STR2## radical, R.sup.1 and R.sup.2 are, individually, hydrogen or C.sub.1 -C.sub.4 alkyl radicals, n is 0 or 1 and X is a cation. The use of the monothiophosphate collectors provides excellent selective recovery of gold, silver and platinum group metal values in froth flotation processes conducted under alkaline conditions.

Abstract: Derivatives of tricyclo-[5.2.1.0.sup.2,6 ]-dec-3-ene corresponding to the following general formula ##STR1## in which R.sup.1 is hydrogen; a linear or branched C.sub.1 -C.sub.8 alkyl radical; an acyl radical R.sup.2 -CO, where R.sup.2 is hydrogen or a linear or branched C.sub.1 -C.sub.18 alkyl or alkenyl radical; or a hydroxyalkyl radical ##STR2## in which R.sup.3 and R.sup.4 independently of one another may be hydrogen or a hydroxy group and m and n are integers of 0 to 5 and the sum (m+n) is an integer of 1 to 5, with the proviso that at least one of the radicals R.sup.3 and R.sup.4 is a hydroxy group; are used as frothers in the flotation of coal and ores.

Abstract: An improved froth flotation process wherein solid coal particles are selectively separated under coal froth flotation conditions as a froth phase from remaining solid feed particles as an aqueous phase in the presence of a frother, the improvement comprising a frother of at least 4-methyl cyclohexane methanol.

Abstract: The invention is a collector composition for a flotation process containing a primary or secondary amine or amine salt and at least one of xanthates, dithiophosphates, mercaptobenzothiazoles, xanthogen formate and thioaocarbamate and a flotation process which utilizes the collector composition.

Abstract: A method of selectively recovering an arsenopyrite, pyrrhotite or like mineral from a material containing such a mineral and pyrite which includes the steps of providing a slurry of the material, adding a dialkyl (C.sub.3-8)-dithiophosphate to the slurry, passing a gas through the slurry to cause the mineral to be carried to the surface of the slurry and report in a first float concentrate, removing this concentrate from the slurry, activating the mineral remaining in the slurry by adding a suitable water-soluble copper salt to the slurry, adding a monoalkyl (C.sub.3-10)-dithiocarbamate to the slurry, passing a gas through the slurry to cause mineral to be carried to the surface of the slurry and form a second float concentrate, removing the second concentrate from the slurry and combining the first and the second float concentrates.

Abstract: A process for purifying calcium carbonate ore by the removal of silicate impurities from the ore by reverse flotation. The process achieves high yields and low acid insoluble content of the calcium carbonate product by employing novel collectors. These novel collectors which characterize the invention comprise organo-nitrogen compounds including propoxylated quaternary ammonium compounds, unsymmetrical dialkyl dimethyl quaternary ammonium compounds and dialkyl hexahydropyrimidine compounds.

Abstract: Various acrylamide/allyl thiourea polymers and their use as depressants in the beneficiation of sulfide minerals from ores are disclosed.

Abstract: A process for froth flotation for the recovery of sulfide minerals, or sulfidized oxide minerals, from their ores utilizing a methylene bisxanthate as a collector reagent, either alone or in combination with other known collector reagents in the froth flotation of an aqueous pulp of such ores.

Abstract: A process for the recovery of minerals from an ore or concentrate containing the same wherein the minerals are recovered in a froth from an aqueous pulp containing the ore or concentrate and wherein one or more mineral flotation agents are employed in the aqueous pulp to control the type of mineral in the froth is provided. The mineral flotation agent or agents employed in the process comprise sulfenyl dithiocarbamates characterized by the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of hydrogen and hydrocarbyl groups with not more than one of R.sub.1 and R.sub.2 being hydrogen, n is 1 or 2, and R.sub.3 is a hydrocarbyl group.

Abstract: A new depressant composition is provided for the enhanced separation into separate value metal concentrates of copper, nickel, zinc, lead present in polymetallic and massive sulphide ores.The depressant is added in an aqueous solution prepared by dissolving first a mixture of quebracho and dextrin, or quebracho and guar gum. To the solution of modified quebracho a water soluble salt of lignin sulphonate is added. The aqueous polymer of modified quebracho lighin sulphonate is further mixed with one or more of the following inorganic reagents: water soluble cyanide, metal sulphates and water soluble sulphites. The resulting depressant is added together with conventional flotation reagents in conventional mineral separation stages as required.

Abstract: The present invention relates to an improved process for beneficiating an ore containing sulfide materials with selective rejection of pyrite, pyrrhotite and other metals and gangue. In particular, the process is useful for beneficiating ores and recovering copper from said ores. In one embodiment the process comprises the steps of(A) grinding the ore to an appropriate size range;(B) preparing a slurry comprising(B-1) said ground ore;(B-2) at least one collector which is a water-dispersible or soluble dihydrocarbyldithiodiphosphoric acid or salt having the formula ##STR1## wherein R.sup.1 and R.sup.2 are different hydrocarbyl groups containing up to about 12 carbon atoms, n is an integer equal to the valence of X and X.sup.n+ is a dissociating cation; and(B-3) water;(C) conditioning the slurry with SO.sub.2 under aeration at a pH of about 5.5 to about 7.

Abstract: A process for separating and recovering minerals, such as molybdenum or coal, from ores with which they occur by addition of a dimercaptothiadiazole to an ore flotation process.

Abstract: A new depressant for use in enhanced separation of polymetallic sulphides is described. The depressant agent is used in conjunction with conventional collector agents and frothing agents in the flotation separation of copper, nickel, lead, zinc sulphides by depressing iron sulphides such as pyrrhotite, pyrite and marcasite in the tailing. The depressant consists of a cross-linked starch chemically combined with a polyacrylate and sugar free lignin sulphonate.

Abstract: A method for the production of alkyl or alkaryl hydroxamic acids and/or salts wherein a C.sub.8 -C.sub.22 alcohol is employed with water as the solvent is disclosed as well as the resultant salt and/or acid solutions per se and their use in the flotation of non-sulfide minerals, preferably clay.

Abstract: Various acrylamide/allyl thiourea polymers and their use as depressants in the beneficiation of sulfide minerals from ores are disclosed.

Abstract: Coal fines are recovered from an aqueous slurry which also contains shale as suspended fine solids by adding to the slurry a hydrophobic polymer such as a polybutadiene or a polyvinylether in a liquid organic carrier such as gas oil, diesel oil or kerosene, agitating the resulting mixture, introducing gas such as air into the mixture to form bubbles whereby flocs of coal fines formed are caused to float, and discarding the underlying slurry containing shale. To aid solution of the polymer a co-solvent, such as an aromatic solvent or a paraffinic solvent, compatible with the carrier may be used. The method is preferably carried out as a froth flotation in a froth flotation cell using a conventional frother such as methyl isobutyl carbinol or a mixture of polypropylene glycol ethers in addition to the polymer and carrier.

Abstract: Coal fines are recovered from an aqueous slurry which also contains shale as suspended fine solids by adding to the slurry a hydrophobic polymer such as a polybutadiene or a polyvinylether in a liquid organic carrier such as gas oil, diesel oil or kerosene, agitating the resulting mixture, introducing gas such as air into the mixture to form bubbles whereby flocs of coal fines formed are caused to float, and discarding the underlying slurry containing shale. To aid solution of the polymer a co-solvent, such as an aromatic solvent or a paraffinic solvent, compatible with the carrier may be used. The method is preferably carried out as a froth flotation in a froth flotation cell using a conventional frother such as methyl isobutyl carbinol or a mixture of polypropylene glycol ethers in addition to the polymer and carrier.

Abstract: A process for the recovery of minerals from an ore or concentrate containing the same wherein the minerals are recovered in a froth from an aqueous pulp containing the ore or concentrate and wherein one or more mineral flotation agents are employed in the aqueous pulp to control the type of minerals in the froth is provided. The mineral flotation agents used in carrying out the process comprise compounds formed by the addition of hydrogen sulfide to dicyclopentadiene.

Abstract: Various 1,4-disubstituted-2,3,5,6-tetrahydroxy-1,4-diphosphorinanes, their oxides and sulfides, methods for the production thereof, and flame-retarded compositions of matter containing them, are disclosed.

Abstract: A process is described for the mineral separation of rare earth metal compounds, such as bastnaesite, contained in oxidic minerals. The process is a froth flotation process utilizing a novel collector emulsion, which is an emulsified mixture of:a secondary amine modified sulphonated fatty acid,a high rosin containing tall oil fatty acid,an anionic petroleum sulphonate, anda high molecular weight primary amine.The collector emulsion mixture is added to the aqueous slurry of the comminuted rare earth metal compound containing oxidic mineral, which has been previously conditioned in a conventional manner. The conditioning reagents may include alkaline pH modifiers and gangue depressants such as citric acid, oxalic acid, sodium silicates and fatty acids.The rare earth metal compounds will be concentrated in the froth, and are separated in the conventional manner.

Abstract: Ionic organic collecting agents for the selective flotation of lead and zinc ores, said agents having the following general formula ##STR1## wherein the symbols employed have the meaning given below: R represents H, CH.sub.3, C.sub.2 H.sub.5, or an alkoxyalkyl group,R.sub.1 and R.sub.2, which can be the same or different, represent H, a linear or a branched alkyl group, an alkoxyalkyl group or a hydroxyalkyl group containing up to 12 carbon atoms;X represents H, Cl, Br, I, F, CN, CONH.sub.2, NO.sub.2 ;m represents H, Na, K, Li, Cs;as well as a process for the production of said collecting agents.

Abstract: Modified starch compositions and their use for flocculating mineral waste residues, particularly the red mud containing alumina liquors from bauxite residues, comprising the addition to an alumina liquor of a flocculating amount of a methylated starch which, optionally, may be hydrolyzed, or a methylated starch which is also sulfonated and, optionally, may be hydrolyzed. Preferably, the methylated starch compositions are potato and dasheen starch derivatives prepared at temperatures of about 50.degree. to about 85.degree. C.

Abstract: A process and composition are provided for the froth flotation beneficiation of iron minerals from iron ores containing silicate and phosphate minerals, comprising as collectors a combination of a primary amine and a nitrogen compound containing an anionic group selected from methylene carboxylic acid, ethylene phosphoric acid and methylene phosphonic acid.

Abstract: The separation of coal from pyrite is enhanced by the use of an effective amount of a polymeric acid or salt thereof as a pyrite depressant in conventional flotation processes. The polymeric acid may be a carboxylic or sulfonic acid. An example of a salt of a polymeric acid useful in the process is sodium polyacrylate.

Abstract: Matter is floated to the surface of a liquid by bonding ions to the surface of the matter to give the matter a charge, and forming a froth with the aid of a frothing agent having groups of opposite charge to the ions so that the frothing agent bonds to the matter and is carried in the froth to the surface of the liquid. By removing the froth the matter can be separated from any inert matter present in the liquid. The oxidation state of the surface of the matter may be changed before bonding takes place with the ions to one which facilitates that bonding. The matter can be particulate or dissolved ions. For example, uranium dioxide particles are oxidized with hydrogen peroxide, sodium carbonate added to produce a negatively charged uranyl carbonate complex and a froth formed with the aid of cetyl trimethylammonium bromide. Cationic groups in the latter bond to the uranyl carbonate complex causing the uranyl carbonate complex to be concentrated in the froth at the surface of the liquid.

Abstract: A method for enhancing hydrophobicity of high volatile bituminous coal and coals of a lower grade and for separating ash and sulfur (including pyritic sulfur) contaminants from coal in a floatation process. The method comprises the steps of grinding the coal to small particulate size, forming a slurry of the ground coal and mixing the slurry with at least one compound selected from the group comprising inorganic peroxy compounds, the preferred compound being oxone which is a mixture of potassium monopersulfate, potassium hydrogen sulfate and potassium sulfate. This slurry is allowed to react to condition the particulate coal and develop increased hydrophobicity for the coal while depressing the sulfur contaminants and ash during froth flotation.

Abstract: A froth flotation process in which an amphoteric compound is used as a collector for oxide and salt type minerals. The amphoteric compound has the formula ##STR1## in which R is a hydrocarbon group having 4 to 18 carbon atoms; n is 0 or 1;; p is a number from 0 to 5; and R.sub.1 is a hydrocarbon group having 5 to 18 carbon atoms or the group ##STR2## in which R, n and p have the above mentioned meaning; or a salt thereof.

Abstract: The separation of coal from pyrite during a froth flotation process is enhanced by the use of an effective amount of a pyrite depressant. The depressant is a hydrophilic nitrogen-sulfur-containing compound.

Abstract: A collector composition for use in froth flotation processes comprises two collectors. One of the collectors is preferably an N-(hydrocarbyl)-alpha, omega-alkanediamine, an (omega-aminoalkyl) hydrocarbon amide or mixture thereof. The second collector is a thiocarbonate, a thionocarbamate, a thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, xanthogen formate, xanthic ester or mixture thereof. The collector composition floats a broad range of metal-containing minerals.

Abstract: The froth flotation of coal is conducted in the presence of an epoxide conditioner.

Abstract: Alkyl sulfosuccinates based on propoxylated and propoxylated and ethoxylated fatty alcohols as flotation collectors for non-sulfidic ores and to a process for the separation of non-sulfidic ores by flotation in which the alkyl sulfosuccinates used contain one or two identical or different, straight-chain and/or branched-chain, saturated or unsaturated alkyl radicals based on propoxylated or propoxylated and ethoxylated C.sub.8 -C.sub.22 fatty alcohols.

Abstract: The flotation of desired mineral ores is selectively depressed by the use of an effective amount of a polycarboxylic acid or salt thereof in a reverse flotation process. As an example, the flotation of iron-containing minerals, such as iron oxides or iron powder, is selectively depressed when compared to the flotation of silicate gangue thus facilitating the recovery of the desired mineral by the use of an effective amount of a polycarboxylic acid or salt thereof such as sodium polyacrylate.

Abstract: A polyamine substituted dithiocarbamate composition is provided. Also provided are minerals depressant compositions for recovering mineral values from an ore or concentrate wherein the values are recovered in a froth from an aqueous slurry. A process of forming the minerals depressant compositions and an improved ore flotation process using the minerals depressant compositions are also provided.

Abstract: At present the usual method of recycling of drilling muds by the exclusive application of classifying processes during drilling rig operation leads to the disposal of fine grained barite containing waste materials. In this invention, a simple one-stage flotation process using alkylphosphate based collecting and foaming reagents is applied to recover the barite content of such muds thus producing a marketable barite concentrate. The flotation should preferably be carried out at pH 8 to 9 with CaO, Ca(OH).sub.2 or KOH as regulating reagents and with the optimal solids content in the flotation pulp (preferably 100 g/l). The solids content in the flotation pulp can easily be adjusted by diluting with process water.

Abstract: Minerals are recovered from ore by subjecting the ore, in the form of an aqueous pulp, to a froth flotation process in the presence of a collector of the formula:R.sup.1 --X--(R).sub.n --N--(R.sup.2).sub.2 (Ia)orR.sup.1 --X--(R).sub.n --N=Y (Ib)wherein --(R).sub.n -- is ##STR1## each R' is independently hydrogen, methyl or ethyl; y+p+m=n; n is an integer from 1 to 6; y and m are independently 0 or 1 and y+m=0 or 1 and p is an integer from 1 to 6 and each moiety can occur in random sequence; R.sup.1 is a C.sub.1-22 hydrocarbyl or a C.sub.1-22 substituted hydrocarbyl and each R.sup.2 is independently hydrogen, a C.sub.1-22 hydrocarbyl or a C.sub.1-22 substituted hydrocarbyl; --X-- is --N(R.sup.3)-- or ##STR2## R.sup.3 is H or a C.sub.1-22 hydrocarbyl or a C.sub.1-22 substituted hydrocarbyl; =Y is =S, =O, a hydrocarbylene or a substituted hydrocarbylene radical.

Abstract: A process and composition are provided for the froth flotation beneficiation of iron minerals from iron ores containing silicate and phosphate minerals, comprising as collectors a combination of a primary amine and a nitrogen compound containing an anionic group selected from methylene carboxylic acid, ethylene phosphoric acid and methylene phosphonic acid.

Abstract: Use of N-alkyl and/or N-alkenyl aspartic acids or salts thereof as co-collectors in the flotation of non-sulfidic ores and a process for the separation of non-sulfidic ores by flotation wherein N-alkyl and/or N-alkenyl aspartic acids or salts thereof are used in collector mixtures.

Abstract: Mixtures of(a) at least one alkyl or alkenyl polyethylene glycol ether which is terminally blocked by a hydrophobic radical, and(b) at least one anion-active surfactant are used as collectors in the flotation of non-sulfide ores.

Abstract: A process for separating non-sulfidic minerals from an ore by flotation in which the ore is contacted with a mixture of(a) at least one adduct of ethylene oxide and propylene oxide with a C.sub.8 -C.sub.22 fatty alcohol and(b) at least one anionic, cationic or ampholytic surfactant.

Abstract: Minerals are recovered from ore by subjecting the ore, in the form of an aqueous pulp, to a froth flotation process in the presence of a collector of the formula:R.sup.1 --X--(R).sub.n --N--(R.sup.2).sub.2 or (Ia)R.sup.1 --X--(R).sub.n --N.dbd.Y (Ib)wherein (--R--).sub.n is ##STR1## each R' and R" is independently hydrogen, methyl or ethyl; y+p+m=n; n is an integer from 1 to 6; y and m are independently 0 or 1 and y+m=0 or 1 and p is an integer from 1 to 6 and each moiety can occur in random sequence; R.sup.1 is a C.sub.1-22 hydrocarbyl or a C.sub.1-22 substituted hydrocarbyl; each R.sup.2 is independently hydrogen, a C.sub.1-22 hydrocarbyl or a C.sub.1-22 substituted hydrocarbyl; --X-- is --S-- or ##STR2## and .dbd.Y is .dbd.S, .dbd.O, a hydrocarbylene or a substituted hydrocarbylene radical.

Abstract: The invention relates to a method of separating phosphatic minerals from phosphate ores, especially from phosphate carbonate ores by flotation in the presence of a collector, which comprises a compound having the general formulaX.sub.1 --(CH.sub.2).sub.1 --Y--(CH.sub.2).sub.m --X.sub.2 Ior its salt, in which formulal and m are mutually independently 0 or 1,Y is --S--, --SO-- or --OSO--,X.sub.1 and X.sub.2 are mutually independently --R or --CR(R'Z.sub.1)Z.sub.2, Z.sub.1 and Z.sub.2 are mutually independently --H, --OR, --COOR, --OCOR, --NR'COR, --CONR'R, --COSR, --CSOR, --COR or --SO.sub.3 H or Z.sub.1 and Z.sub.

Abstract: The invention is a process for recovering coal or mineral values from raw coal or mineral ore which comprises subjecting the raw coal or mineral ore in the form of an aqueous pulp, to a floatation process in the presence of a floatation collector, and a flotating amount of a floatation frother which comprises the reaction product of an alitphatic C.sub.6 alcohol and between about 1 and 5 moles of propylene oxide, butylene oxide or mixtures thereof, under conditions such that the coal or mineral values are recovered.

Abstract: New and improved collector compositions for use in froth flotation processes for the beneficiation of mineral values from base metal sulfide ores are disclosed. The collector compositions comprise at least one hydrocarboxycarbonyl thiourea compound selected from compounds of the formula: ##STR1## wherein R.sup.1 is hydrogen or R.sup.2 ; R.sup.2 is selected from saturated and unsaturated hydrocarbyl radicals, hydrocarboxy radicals and aromatic radicals; and R.sup.3 is selected from saturated and unsaturated hydrocarbyl radicals, alkyl polyether radicals and aromatic radicals, said R.sup.2 and R.sup.3 radicals, optionally, and independently, being substituted by polar groups selected from halogen, nitrile and nitro groups. The use of the hydrocarboxycarbonyl thiourea collectors provides excellent metallurgical recoveries of sulfide mineral values in froth flotation processes conducted over a very broad range of pH including acid, neutral and mildly alkaline pH.

Abstract: New and improved collector compositions for use in froth flotation processes for the beneficiation of mineral values from base metal sulfide ores are disclosed. The collector compositions comprise at least one hydrocarboxycarbonyl thionocarbamate compound selected from compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each, independently, selected from saturated and unsaturated hydrocarbyl radicals, alkyl polyether radicals and aromatic radicals, or such radicals optionally substituted by polar groups selected from halogen, nitrile and nitro groups. The use of the hydrocarboxycarbonyl thionocarbamate collectors provides excellent metallurgical recoveries of sulfide mineral values in froth flotation processes conducted over a broad range of pH conditions including acid, neutral and mildly alkaline pH.