Vaporization, Or Expansion, Refrigeration Or Heat Or Energy Exchange Patents (Class 252/67)
  • Patent number: 7438825
    Abstract: Provided are azeotrope-like compositions comprising 1,1,1-trifluoro-3-chloropropene (HCFO-1233zd) and dimethoxymethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, solvent, and aerosol propellants.
    Type: Grant
    Filed: March 7, 2008
    Date of Patent: October 21, 2008
    Assignee: Arkema Inc.
    Inventors: Benjamin Bin Chen, Philippe Bonnet
  • Patent number: 7438826
    Abstract: Provided are azeotrope-like compositions comprising 1,1,1-trifluoro-3-chloropropene (HCFO-1233zd) and methyl acetate and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, solvent, and aerosol propellants.
    Type: Grant
    Filed: March 7, 2008
    Date of Patent: October 21, 2008
    Assignee: Arkema Inc.
    Inventors: Benjamin Bin Chen, Philippe Bonnet
  • Publication number: 20080245992
    Abstract: The invention relates to the mixture of natural gases based on hydrocarbons (HC) which do not damage the ozone layer and which have an insignificant greenhouse effect, said gases being substitutes for CFC gases R-12 and R-22, whereby the R-12 substitute is known as HC-12 and the R-22 substitute is known as HC-22. The aforementioned mixtures, which generate a specific pressure/temperature curve, improve the efficiency of air conditioning and refrigeration compression systems. Specifically, since condensation pressures are lower, less pressure and, consequently, less work is required from the compressor, and hence power consumption is reduced. In addition, the refrigerant gases, based on HC mixtures, replace CFCs and HCFCs and are compatible with materials and elements used in commercial refrigeration and air conditioning systems. The resulting mixture generates a specific pressure/temperature curve with a range of plus or minus 5%.
    Type: Application
    Filed: May 4, 2005
    Publication date: October 9, 2008
    Inventor: Ruben Dario Ochoa Vivanco
  • Publication number: 20080230739
    Abstract: The objective of the present invention is to provide a composition capable of being used as a refrigerant and which corresponds to the desire for a reduced environmental impact. The composition according to the present invention comprises from 15-25 wt % of difluoromethane (HFC-32), 50-60 wt % of pentafluoroethane (HFC-125), 15-25 wt % of 1,1,1,2 tetrafluoroethane (HFC-134a) and 1-3 wt % of propene (HC-1270).
    Type: Application
    Filed: August 24, 2006
    Publication date: September 25, 2008
    Applicant: ARKEMA FRANCE
    Inventors: Laurent Caron, Agnes Tamin
  • Publication number: 20080230738
    Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
    Type: Application
    Filed: July 13, 2006
    Publication date: September 25, 2008
    Inventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao, Donald Bernard Bivens, Deepak Perti, Mark Steven Baunchalk
  • Publication number: 20080224091
    Abstract: Compositions of 1,1,1,2,2,4,5,5,5-nonafluoro-4 (trifluoromethyl)-3 pentanone can be used in heat transfer refrigeration and air conditioning systems. The compositions may be in combination with fluoroethers. The compositions may be azeotropic or near azeotropic.
    Type: Application
    Filed: May 22, 2008
    Publication date: September 18, 2008
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Barbara Haviland Minor, Mario J. Nappa, Allen C. Sievert, Thomas J. Leck
  • Patent number: 7422699
    Abstract: Disclosed herein are 1,1,1,3,3-pentafluorobutane refrigerant or heat transfer fluid compositions further comprising hydrofluorocarbon, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane r mixtures thereof, which are useful in refrigerain or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab.single pass heat exchangers.
    Type: Grant
    Filed: June 5, 2007
    Date of Patent: September 9, 2008
    Assignee: E.I. Du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Mario J. Nappa
  • Patent number: 7422698
    Abstract: The present invention relates to compositions for use in refrigeration and air-conditioning systems comprising 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. Further, the present invention relates to compositions for use in refrigeration and air-conditioning systems employing a centrifugal compressor comprising 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. The compositions of the present invention may be azeotropic or near-azeotropic and are useful in processes for producing cooling or heat or as heat transfer fluids.
    Type: Grant
    Filed: February 1, 2007
    Date of Patent: September 9, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Publication number: 20080203349
    Abstract: Mixtures of tetrafluoropropenes with bromofluoropropenes provide compositions that have boiling points within an acceptable range, have good chemical stability, low GWP and are essentially non-flammable.
    Type: Application
    Filed: February 27, 2007
    Publication date: August 28, 2008
    Inventors: Rajiv R. Singh, David P. Wilson, Ian Shankland, Hang T. Pham
  • Publication number: 20080207788
    Abstract: Various uses of chloro,fluoroalkenes, particularly (HFCO-1233) in a variety of applications, including as blowing agents are disclosed.
    Type: Application
    Filed: September 26, 2007
    Publication date: August 28, 2008
    Applicant: Honeywell International Inc.
    Inventors: James M. Bowman, David J. Williams, Rajiv R. Singh, Ian Shankland
  • Publication number: 20080197317
    Abstract: Working fluid for the heat transfer, in particular for the heat transfer by heat pipes, containing or consisting of partially fluorinated and/or perfluorinated hydrocarbons and/or perfluorinated polyethers. Preferably, a mixture of pentafluorobutane and perfluorinated polyether is used as a working fluid.
    Type: Application
    Filed: October 20, 2005
    Publication date: August 21, 2008
    Applicant: Solvay Fluor GmbH
    Inventor: Martin Schwiegel
  • Patent number: 7413676
    Abstract: The present invention relates to Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with fluoroethers, which are azeotropic or near azeotropic.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: August 19, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Mario Joseph Nappa, Barbara Haviland Minor, Allen Capron Sievert, Velliyur Nott Mallikarjuna Rao
  • Patent number: 7413675
    Abstract: The present invention relates to compositions for use in refrigeration and air-conditioning systems comprising at least one hydrocarbon, and which are also useful in systems employing a centrifugal compressor The are useful in processes for producing cooling or heat or as heat transfer fluids.
    Type: Grant
    Filed: June 13, 2005
    Date of Patent: August 19, 2008
    Assignee: E.I. duPont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 7413674
    Abstract: Provided are azeotrope-like compositions comprising difluoroethane and trifluoroiodomethane, azeotrope-like compositions comprising difluoroethane, tetrafluoropropene and trifluoroiodomethane, and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: August 19, 2008
    Assignee: Honeywell International Inc.
    Inventors: Rajiv R. Singh, David P. Wilson, Hang T. Pham
  • Publication number: 20080191162
    Abstract: Disclosed herein are 1,1,1,3,3-pentafluorobutane refrigerant or heat transfer fluid compositions further comprising hydrofluorocarbon, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof, which are useful in refrigerain or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab.single pass heat exchangers.
    Type: Application
    Filed: March 18, 2008
    Publication date: August 14, 2008
    Applicant: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Mario J. Nappa, Allen C. Sievert
  • Patent number: 7407600
    Abstract: An improved system for transferring heat, utilizing diols, specifically 1,3-propanediol (PDO). The system reduces the energy consumption, maintenance costs, corrosion, toxicity, and the risk of fire associated with such heat-dependent processes. Unlike traditional hydrocarbon heating fluids, diols do not require draining and replacement if a purifier is installed in the system. Business methods are also disclosed.
    Type: Grant
    Filed: July 6, 2004
    Date of Patent: August 5, 2008
    Assignee: Dupont Tale + Lyle Bio Products Company, LLC
    Inventors: Edward Eaton, Scot D. Kudcey
  • Publication number: 20080169446
    Abstract: The present invention relates to compositions for use in refrigeration and air-conditioning systems comprising 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane and at least one chlorocarbon, alcohol, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. Further, the present invention relates to compositions for use in refrigeration and air-conditioning systems employing a centrifugal compressor comprising 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane and at least one chlorocarbon, alcohol, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. The compositions of the present invention may be azeotropic or near-azeotropic and are useful in processes for producing cooling or heat or as heat transfer fluids.
    Type: Application
    Filed: February 6, 2008
    Publication date: July 17, 2008
    Applicant: E.I. du Pont de Nemours and Company
    Inventor: BARBARA HAVILAND MINOR
  • Patent number: 7396485
    Abstract: The invention relates to azeotropic and azeotrope-like mixtures of HFC-32, HCl, and Cl2, and processes for separating the azeotrope-like mixtures of HFC-32 and HCL and HFC-32, HCL and Cl2.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: July 8, 2008
    Assignee: Honeywell International Inc.
    Inventors: Hang T. Pham, Rajiv R. Singh, Hsueh Sung Tung, Franklin S. Wong
  • Publication number: 20080157022
    Abstract: Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent comprising a diene-based compound. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
    Type: Application
    Filed: December 21, 2005
    Publication date: July 3, 2008
    Inventors: Rajiv R. Singh, Haridasan K. Nair, Raymond H. Thomas, Lawrence A. Ford, David P. Wilson
  • Publication number: 20080142754
    Abstract: The present invention relates to compositions for use in refrigeration and air conditioning systems comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof, and which are also useful in systems employing a centrifugal compressor The compositions of the present invention may be azeotropic or near azeotropic and are useful in processes for producing refrigeration or heat or as heat transfer fluids.
    Type: Application
    Filed: December 20, 2007
    Publication date: June 19, 2008
    Inventors: BARBARA HAVILAND MINOR, THOMAS J. LECK
  • Publication number: 20080135800
    Abstract: Various uses of fluoroalkenes, including tetrafluoropropenes, particularly (HFO-1234) in a variety of applications, including as blowing agents are disclosed.
    Type: Application
    Filed: September 27, 2007
    Publication date: June 12, 2008
    Applicant: Honeywell International Inc.
    Inventors: James M. Bowman, David J. Williams, Rajiv R. Singh
  • Patent number: 7385089
    Abstract: A fluorochemical ketone compound consists of two terminal, branched, independently fluoroalkylcarbonyl or perfluoroalkylcarbonyl groups and an intervening linear perfluoropolyether segment, each of the terminal groups optionally comprising at least one catenated heteroatom, and the perfluoropolyether segment consisting essentially of at least one tetrafluoroethyleneoxy moiety and, optionally, at least one difluoromethyleneoxy moiety, the moieties being randomly or non-randomly distributed within the perfluoropolyether segment.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: June 10, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Michael G. Costello, Richard M. Flynn, Jay F. Schulz, George G. I. Moore
  • Patent number: 7384572
    Abstract: The present invention relates to the discovery of compositions which include fluoroethane, 2-fluoropropane or tert-butylfluoride. These compositions are useful as pure components or with at least one of tetrafluoroethane, difluoroethane, hexafluoropropane, a hydrocarbon or dimethylether. These compositions are useful as aerosol propellants, refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: October 24, 2006
    Date of Patent: June 10, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Vinci Martinez Felix, Allen Capron Sievert
  • Publication number: 20080128650
    Abstract: Refrigerant compositions are provided which include: (a) pentafluoroethane or trifluoromethoxydifluoromethane or hexafluorocyclopropane or mixtures thereof, in an amount from about 60 to about 70% by weight based on the weight of the composition; (b) 1,1,1,2- or 1,1,2,2-tetrafluoroethane or trifluoromethoxypentafluoroethane or 1,1,1,2,3,3-heptafluoropropane or mixtures thereof, in an amount from about 26 to 36% by weight based on the weight of the composition; and (c) an ethylenically unsaturated or saturated hydrocarbon, optionally containing one or more oxygen atoms, having a boiling point from ?12° C. to +10° C., or a mixture thereof, or a mixture of one or more of the hydrocarbons with one or more other hydrocarbons or ethers, said mixture having a bubble point from ?12° C. to +10° C., in an amount from about 1% to 4% by weight based on the weight of the composition.
    Type: Application
    Filed: February 15, 2008
    Publication date: June 5, 2008
    Applicant: E. I. du Pont de Nemours and Company
    Inventors: Neil A. Roberts, Owen R. Chambers
  • Publication number: 20080127659
    Abstract: Disclosed herein are refrigerant or heat transfer fluid compositions further comprising fluoroether, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane, and hydrofluorocarbon, which are useful in refrigeration or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab/single pass heat exchangers.
    Type: Application
    Filed: February 6, 2008
    Publication date: June 5, 2008
    Applicant: E. I. du Pont de Nemours and Company
    Inventors: BARBARA HAVILAND MINOR, MARIO J. NAPPA, ALLEN C. SIEVERT
  • Publication number: 20080125505
    Abstract: Various uses of fluoroalkenes, including tetrafluoropropenes, particularly HFO-1234ze, in a variety of applications, including as blowing agents are disclosed.
    Type: Application
    Filed: September 26, 2007
    Publication date: May 29, 2008
    Applicant: Honeywell International Inc.
    Inventors: James M Bowman, David J. Williams, Rajiv R. Singh
  • Publication number: 20080121837
    Abstract: Disclosed are heat transfer compositions, and methods of using and selecting heat transfer compositions, in which the composition comprises a first component comprising difluoromethane (R-32), and at least one second component selected from group consisting of CF3I, 1,2,3,3,3-pentafluoropropene (HFO 1225ye), and combinations of these, and optionally, but preferably, at least one third component selected from the group consisting of fluorinated C2-C3 compounds, including any combination of two or more fluorinated C2-C3 compounds.
    Type: Application
    Filed: July 6, 2007
    Publication date: May 29, 2008
    Applicant: Honeywell International, Inc.
    Inventors: Rajiv R. Singh, Ian Shankland, Ryan Hulse
  • Publication number: 20080125506
    Abstract: Various uses of fluoroalkenes, including pentafluoropropenes, particularly (HFO-1225yez) in a variety of applications, including as blowing agents are disclosed.
    Type: Application
    Filed: September 27, 2007
    Publication date: May 29, 2008
    Applicant: Honeywell International Inc.
    Inventors: James M. Bowman, David J. Williams, Rajiv R. Singh
  • Publication number: 20080116417
    Abstract: A method for removing iodine and iodide ions from heat transfer compositions which contain a hydrofluoroalkene, an iodocarbon, and iodine and iodide ions. Iodine and iodide ions from such heat transfer compositions by contacting the composition with a molecular sieve, ion exchange resin, clay or alumina, metal impregnated with a metal which is capable of reacting with iodine and iodide ions.
    Type: Application
    Filed: November 8, 2007
    Publication date: May 22, 2008
    Inventors: George J. Samuels, Samuel F. Yana Motta, Gregory J. Shafer, Rajiv R. Singh, Mark W. Spatz, Raymond H. Thomas, Michael Van Der Puy, John L. Welch, Gary Zyhowski, David P. Wilson
  • Publication number: 20080111099
    Abstract: The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, a polyol ester and at least one compound comprising trifluoromethane, methyl iodide, heptafluorobutane or propene.
    Type: Application
    Filed: November 8, 2007
    Publication date: May 15, 2008
    Inventors: Rajiv R. Singh, Raymond H. Thomas, George J. Samuels, David P. Wilson, Michael Van Der Puy, John L. Welch, Gregory J. Shafer, Mark W. Spatz
  • Publication number: 20080104967
    Abstract: A regenerator material is comprised of a granular body made of bismuth or an alloy of bismuth and antimony. A rate of the granular body having a grain size of 0.14 mm to 1.6 mm is 70% by weight or more with respect to the entire granular body, and a rate of the granular body in which a ratio of a major axis to a minor axis is 5 or more is 70% by weight or more with respect to the entire granular body. Thereby, there is provided a regenerator material, more friendly to the environment, easily turned into a spherical shape, having sufficient mechanical strength for use, low cost, and having a superior thermal property when used for a cryocooler.
    Type: Application
    Filed: May 27, 2005
    Publication date: May 8, 2008
    Applicant: SUMITOMO HEAVY INDUSTRIES, LTD.
    Inventor: Toshimi Satoh
  • Publication number: 20080105848
    Abstract: The present invention relates to compositions which can be used as expanding agent in the manufacture of thermosetting polymers. A more particular subject-matter of the invention is compositions comprising 1,1,1,3,3-pentafluorobutane (365 mfc), 1,1,1,3,3-pentafluoropropane (245 fa) and a hydrochlorocarbon compound.
    Type: Application
    Filed: March 16, 2005
    Publication date: May 8, 2008
    Inventor: Laurent Caron
  • Patent number: 7354529
    Abstract: Disclosed herein are refrigerant or heat transfer fluid compositions further comprising fluoroether, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane, and hydrofluorocarbon, which are useful in refrigeration or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab/single pass heat exchangers.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: April 8, 2008
    Assignee: E. I. du Pont deNemours and Company
    Inventors: Barbara Haviland Minor, Mario J. Nappa, Allen C. Sievert
  • Patent number: 7351352
    Abstract: Disclosed herein are 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane refrigerant or heat transfer fluid compositions further comprising and a fluoroether compound, which are useful in refrigeration or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab/single pass heat exchangers.
    Type: Grant
    Filed: April 17, 2007
    Date of Patent: April 1, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Mario J. Nappa, Allen C. Sievert
  • Patent number: 7351351
    Abstract: The present invention relates to compositions for use in refrigeration and air-conditioning systems comprising 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane and at least one chlorocarbon, alcohol, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. Further, the present invention relates to compositions for use in refrigeration and air-conditioning systems employing a centrifugal compressor comprising 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane and at least one chlorocarbon, alcohol, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof. The compositions of the present invention may be azeotropic or near-azeotropic and are useful in processes for producing cooling or heat or as heat transfer fluids.
    Type: Grant
    Filed: January 16, 2007
    Date of Patent: April 1, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 7338616
    Abstract: Disclosed herein are refrigerant and heat transfer fluid compositions comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one hydrocarbon. These compositions are useful in refrigeration and air conditioning systems that employ a centrifugal compressor. Also disclosed herein are azeotropic or near azeotropic refrigerant and heat transfer fluid compositions comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one hydrocarbon.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: March 4, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Thomas J. Leck
  • Patent number: 7332102
    Abstract: An apparatus and method wherein potential ozone layer-damaging dichlorodifluoromethane (Refrigerant R-12) is substituted with a mix of less environmentally damaging refrigerants Chlorodifluoroethane and Tetrafluoroethane in dichlorodifluoromethane-based air-cooling systems, in particular HVAC and refrigeration applications. While less environmentally damaging than dichlorodifluoromethane, the substitute refrigerant is less flammable than presently available refrigerants, yet still has a temperature-pressure relationship close enough to that of dichlorodifluoromethane, making the substitute refrigerant suitable for use with dichlorodifluoromethane-based air-cooling systems. In this event, it is mixed with a lubricating oil that is compatible with both the unit refrigerant and typical R-12 system design.
    Type: Grant
    Filed: July 6, 2005
    Date of Patent: February 19, 2008
    Assignee: Stefko Properties, LLC
    Inventors: Kenneth M Ponder, Steffan Thomas, Jr.
  • Patent number: 7332103
    Abstract: The present invention relates to compositions for use in refrigeration and air conditioning systems comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof, and which are also useful in systems employing a centrifugal compressor. The compositions of the present invention may be azeotropic or near azeotropic and are useful in processes for producing refrigeration or heat or as heat transfer fluids.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: February 19, 2008
    Assignee: E.I. duPont deNemours and Company
    Inventors: Barbara Haviland Minor, Thomas J. Leck
  • Publication number: 20080028782
    Abstract: An azeotrope spray cooling system for utilizing an azeotrope coolant for improving the performance of a spray cooling system. An azeotrope coolant is utilized within a two-phase thermal management system for thermally managing one or more heat producing devices. The characteristics of the azeotrope coolant may be adjusted for various types of thermal management applications by altering the components of the azeotrope coolant.
    Type: Application
    Filed: July 16, 2005
    Publication date: February 7, 2008
    Inventors: Charles L. Tilton, Donald E. Tilton, Bruce A. Smetana, Angela R. Maehren, Philip W. Appel, Randall T. Palmer
  • Patent number: 7326362
    Abstract: In the present invention, a rigid polyurethane foam or polyisocyanurate foam is prepared by mixing an isocyanate with a premix of a polyol, a blowing agent, a reaction catalyst, a foam stabilizer and other additives, in which 1,1,1,3,3-pentafluoropropane is used as the blowing agent in combination with a vapor pressure depressant therefor that includes at least one compound compatible with 1,1,1,3,3-pentafluoropropane.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: February 5, 2008
    Assignee: Central Glass Company, Limited
    Inventors: Yasuo Hibino, Toshio Hesaka, Naoto Takada
  • Patent number: 7314576
    Abstract: Disclosed herein are refrigerant and heat transfer fluid compositions comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one hydrofluorocarbon for use in refrigeration and air conditioning systems employing a centrifugal compressor. The compositions may be azeotropic or near-azeotropic.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: January 1, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Mario Joseph Nappa, Allen Capron Sievert, Thomas J. Leck
  • Patent number: 7309459
    Abstract: This invention relates to compositions of cyclopentane, and a compound selected from the group consisting of hydrofluorocarbons, hydrofluoroethers, or fluorinated sulfur compounds. Specifically these compounds may be selected from the group consisting of tetrafluoroethane, hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, octafluorobutane, hexafluorobutane, pentafluorobutane, nonafluorobutane, difluorobutane, trifluoro-2-methoxyethane and bis(pentafluoroethyl)sulfide. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: October 3, 2006
    Date of Patent: December 18, 2007
    Assignee: E. I. duPont deNemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 7288211
    Abstract: The invention relates to the addition of ?-methyl styrene, isobutanol and/or isopropanol to reduce vapor pressure, improve k-factor, enhance the solubility of the blowing agent in the premix and/or improve the processing characteristics of polyurethane and polyisocyanurate closed-cell foams prepared with a blowing agent comprising a hydrofluorocarbon selected from the group consisting of 1,1,1,3,3-pentafluoropropane, 1,1,1,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, and mixtures thereof.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: October 30, 2007
    Assignee: Honeywell International Inc.
    Inventors: Mary Charlotte Bogdan, Leslie Bruce Bement, Barbara Ruth Decaire, Dennis Paul Konopa, Harold John Kieta, Rajiv Ratna Singh
  • Patent number: 7276471
    Abstract: Provided are azeotrope-like compositions comprising pentafluoropropane, methanol, and dichloroethylene, and uses thereof, including use in aerosols, refrigerant compositions, refrigeration systems, and blowing agent compositions.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: October 2, 2007
    Assignee: Honeywell International Inc.
    Inventors: Guillermo J. Hitters, Gary Knopeck, Ian R. Shankland, Rajiv R. Singh
  • Patent number: 7276176
    Abstract: Refrigerant composition is disclosed which comprises: (a) pentafluoroethane, trifluoromethoxydifluoromethane or hexafluorocyclopropane, or a mixture of two or more thereof, in an amount of at least 75% based on the weight of the composition, (b) 1,1,1,2- or 1,1,2,2-tetrafluoroethane, trifluoromethoxypentafluoroethane, 1,1,1,2,3,3-heptafluoropropane or a mixture of two or more thereof, in an amount of from 10 to 20% by weight based on the weight of the composition and (c) and ethylenically unsaturated or saturated hydrocarbon, optionally containing one or more oxygen atoms, with a boiling point from ?50° C. to +35° C., or a mixture thereof in an amount from 1% to 4% by weight based on the weight of the composition, the weight ratio of component (a): component (b) being at least 4:1.
    Type: Grant
    Filed: October 13, 2003
    Date of Patent: October 2, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Neil André Roberts, Owen Chambers
  • Patent number: 7276177
    Abstract: Disclosed herein are hydrofluorocarbon refrigerant or heat transfer fluid compositions that are useful in refrigerain or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab.single pass heat exchangers.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: October 2, 2007
    Assignee: E.I. duPont de Nemours and Company
    Inventors: Barbara Haviland Minor, Mario J. Nappa
  • Patent number: 7273835
    Abstract: The invention relates to azeotropic and azeotrope-like mixtures of HFC-32 and HCl or a mixture of HCl and Cl2, and a process for separating the azeotrope-like mixtures.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: September 25, 2007
    Assignee: Honeywell International Inc.
    Inventors: Hang T. Pham, Rajiv R. Singh, Hsueh Sung Tung, Franklin S. Wong
  • Patent number: 7270766
    Abstract: “Disclosed is a feed water composition for boilers whose main ingredient is a purified ethylene glycol aqueous solution that is a mixture of purified ethylene glycol and pure water in a weight ratio of 70-90 : 10-30 wt %. The feed water composition comprises 92.1 to 98.8 wt % of the purified ethylene glycol aqueous solution, 0.1 to 2.0 wt % of sodium benrzoate, 0.1 to 1.5 wt % of tolyltriazole, 0.1 to 0.7 wt % of triethanol amine, 0.5 to 1.5 wt % of sodium nitrate, 0.3 to 1.2 wt % of sodium molybdate, and 0.1 to 1.0 wt % of potassium hydroxide.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: September 18, 2007
    Inventor: Young Nam Kim
  • Patent number: 7270717
    Abstract: Disclosed are compositions and methods for cleaning contaminated articles based on the provision of a zeotropic composition comprising (a) at least one flammable solvent having a boiling point at a first pressure; (b) at least one first nonflammable solvent having a boiling point at said first pressure which is less than about said first pressure boiling point of said flammable solvent; and (c) at least one second nonflammable solvent having a boiling point at said first pressure which is greater than about the first pressure boiling point of said flammable solvent.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: September 18, 2007
    Assignee: Honeywell International Inc.
    Inventors: Gary Knopeck, Rajiv R. Singh, Kane Cook, Ian Shankland, Harold Kieta
  • Patent number: 7264745
    Abstract: The present invention relates to Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with hydrofluorocarbons, which are azeotropic or near azeotropic.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: September 4, 2007
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Mario Joseph Nappa, Barbara Haviland Minor, Allen Capron Sievert, Velliyur Nott Mallikarjuna Rao