Alkali Metal Hydroxide Containing Patents (Class 252/79.5)
  • Patent number: 11851772
    Abstract: Compositions and methods for etching a surface of an implantable device are disclosed. The compositions generally include one or more alkali components, such as a metal hydroxide and an amine, one or more chelating agents, and optionally iron (Fe) and/or certain component metals of the metal or alloy to be etched. For example, when etching a titanium device, the metals may include titanium (Ti). Alternatively, the composition may be an electrolyte composition useful for electrochemical etching of the implantable device. These compositions and methods may generate nanoscale geometry on the surface of the implantable device to provide implants with accelerate osseointegration and healing after surgery.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: December 26, 2023
    Assignee: Tech Met, Inc.
    Inventors: Michael Vidra, Edward Palanko, Robert Vaccaro, Jordan Incerpi
  • Patent number: 11764067
    Abstract: The present disclosure provides an etching solution, including an ionic strength enhancer having an ionic strength greater than 10?3 M in the etching solution, wherein the ionic strength enhancer includes Li+, Na+, K+, Mg2+, Ca2+, N(CH3)+, or N(C2H5)4+, a solvent, and an etchant.
    Type: Grant
    Filed: June 9, 2021
    Date of Patent: September 19, 2023
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY LTD.
    Inventor: Chung-Chieh Lee
  • Patent number: 11361454
    Abstract: Wafer images and related alignment methods for crystalline wafers are disclosed. Certain aspects relate to accessing and aligning images of a same or similar crystalline wafer captured from different imaging sources. Alignment may include determining spatial differences between shared crystalline features in various wafer images of the same or similar crystalline wafer and transforming at least one of the images according to the determined spatial differences. With sufficient alignment, information may be associated and/or transferred between the various images, thereby providing the capability of forming a combined wafer image and sub-images thereof with high resolution and spatial coordination between different image sources. Certain aspects relate to development of nondestructive, high fidelity defect characterization and/or dislocation counting methods in crystalline materials based on modern deep convolutional neural networks (DCNN).
    Type: Grant
    Filed: February 28, 2020
    Date of Patent: June 14, 2022
    Assignee: WOLFSPEED, INC.
    Inventors: Robert Tyler Leonard, Matthew David Conrad, Edward Robert Van Brunt
  • Patent number: 11233208
    Abstract: A flexible display screen and a flexible display apparatus are provided. The flexible display screen includes a display device, a flexible substrate, a support structure and a drive chip. The display device is positioned on the flexible substrate, and the flexible substrate is positioned on the support structure. The support structure further defines a groove thereon to accommodate the drive chip.
    Type: Grant
    Filed: March 8, 2018
    Date of Patent: January 25, 2022
    Assignees: Kunshan New Flat Panel Display Technology Center Co., Ltd., Kunshan Go-Visionox Opto-Electronics Co., Ltd.
    Inventors: Pengle Dang, Ji Cheng, Xiuyu Zhang, Meiling Gao
  • Patent number: 11070023
    Abstract: In various embodiments, laser systems feature beam emitters thermally coupled to heat sinks comprising, consisting essentially of, or consisting of a metal-matrix composite of a thermally conductive metal and a refractory metal. At least a portion of the surface of the heat sink is treated to form a depleted region, and a diamond coating is deposited within and/or over the depleted region. The depleted region is substantially free of the thermally conductive metal or contains the thermally conductive metal at a concentration less than that of the body of the heat sink.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: July 20, 2021
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Parviz Tayebati, Myrna Reyes, Xiuying Wu
  • Patent number: 10961185
    Abstract: The invention relates to a stabilizer for L-012 or a salt thereof, a stabilization method for L-012 or a salt thereof, coexisting with the stabilizer and L-012 or a salt thereof, and the like. The stabilizer is represented by Formula [1]: wherein p pieces of M1 each independently represent a hydrogen atom or an alkali metal atom, q pieces of R1 each independently represent a hydroxy group or a sulfonic acid group, m represents 0 or 1, p represents an integer of 1 to 3, q represents an integer of 0 to 4, Y represents a nitrogen atom or a CH group (a methine group), and Z represents an aryl group having a specific structure or a pyrazolyl group having a specific structure.
    Type: Grant
    Filed: October 20, 2016
    Date of Patent: March 30, 2021
    Assignee: FUJIFILM WAKO PURE CHEMICAL CHEMICAL CORPORATION
    Inventors: Shinya Kaji, Toshinari Ohashi, Naoyuki Yamamoto
  • Patent number: 10081541
    Abstract: A multiple silicon trenches forming method and an etching mask structure, the method comprises: step S11, providing a MEMS sealing cap silicon substrate (100); step S12, forming n stacked mask layers (101, 102, 103) on the MEMS sealing cap silicon substrate (100), after forming each mask layer, photolithographing and etching the mask layer and all other mask layers beneath the same to form a plurality of etching windows (D1, D2, D3); step S13, etching the MEMS sealing cap silicon substrate by using the current uppermost mask layer and a layer of mask material beneath the same as a mask; step S14, removing the current uppermost mask layer; step S15, repeating the step S13 and the step S14 until all the n mask layers are removed.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: September 25, 2018
    Assignee: HANGZHOU SILAN INTEGRATED CIRCUIT CO., LTD
    Inventors: Yongxiang Wen, Chen Liu, Feng Ji, Liwen Li
  • Patent number: 10002783
    Abstract: A method for manufacturing a memory device may include the following steps: preparing a first semiconductor, a second semiconductor, a first conductor, and a second conductor, wherein the second semiconductor is spaced from the first semiconductor, wherein the first conductor directly contacts the first semiconductor, and wherein the second conductor is spaced from the first conducive member and directly contacts the second semiconductor; preparing a dielectric material member, which is positioned between the first semiconductor and the second semiconductor and directly contacts each of the first semiconductor, the second semiconductor, the first conductor, and the second conductor; performing ion implantation on the dielectric material member to form an implanted member and a dielectric member; and removing the implanted member.
    Type: Grant
    Filed: November 16, 2016
    Date of Patent: June 19, 2018
    Assignees: SEMICONDUCTOR MANUFACTURING INTERNATIONAL (SHANGHAI) CORPORATION, SEMICONDUCTOR MANUFACTURING INTERNATIONAL (BEIJING) CORPORATION
    Inventor: Liang Chen
  • Patent number: 9039925
    Abstract: Provided is a polishing slurry composition, including a non-ionic surfactant represented by the following formula (1) R—(OCH2CH2)x—OH??formula (1) wherein x is an integer from 1 to 50, and R is selected from a group consisting of a C3-C50 alkyl group, a C6-C55 benzylalkyl group and a C6-C55 phenylalkyl group.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: May 26, 2015
    Assignee: UWIZ Technology Co., Ltd.
    Inventors: Wei-Jung Chen, Wen-Tsai Tsai, Ho-Ying Wu, Song-Yuan Chang, Ming-Hui Lu
  • Publication number: 20150129539
    Abstract: A passivation composition and use of the composition in a method of forming a conductive pattern are provided. The passivation composition includes an oxidizing agent, an inorganic base with a general formula M(OH)n and a solvent, wherein M is a metal ion and n is the valence number of the metal ion. The method includes the following steps: (a) forming a polymer conductive layer on a substrate, wherein the polymer conductive layer is consisting of a first area and a second area. The first area is corresponding to a conductive area to be formed; and (b) passivating the second area by using the passivation composition to reduce the conductivity of the second area and form the conductive pattern on the substrate.
    Type: Application
    Filed: March 28, 2014
    Publication date: May 14, 2015
    Applicant: ETERNAL CHEMICAL CO., LTD.
    Inventors: Wei-Kai Chen, Tu-Yi Wu
  • Publication number: 20150132958
    Abstract: The invention relates to a contact release capsule comprising a particle, a chemical payload, and a polymer coating, wherein the particle is impregnated with the chemical payload, and the chemical payload is held inside the particle by the polymer coating until the contact release capsule contacts a surface and a shearing force removes the polymer coating allowing the chemical payload to release outside the particle. The contact release capsule is useful in chemical mechanical planarization slurries. Particularly, the contact release capsule may comprise a glycine impregnated silica nanoparticle coated with a polymer, wherein the contact release capsule is dispersed in an aqueous solution and used in the copper chemical mechanical planarization process. Use of the contact release capsule in a slurry for copper chemical mechanical planarization may significantly improve planarization efficiency, decrease unwanted etching and corrosion, and improve dispersion stability.
    Type: Application
    Filed: January 20, 2015
    Publication date: May 14, 2015
    Inventor: Robin Ihnfeldt
  • Publication number: 20150125985
    Abstract: It is the object of the present invention to provide an alkali etching solution for solar cell manufacturing, which is capable of forming uniformly a fine hubbly structure throughout a whole wafer on the surface of a wafer having a silicon as a main component, and still more is applicable to various wafers; and a method for manufacturing a silicon-based substrate for solar cell manufacturing, using the etching solution.
    Type: Application
    Filed: May 10, 2013
    Publication date: May 7, 2015
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Naoko Ohuchi, Masahiko Kakizawa, Hiroyuki Tsurumoto, Terumi Watanabe, Shinshi Kawara
  • Patent number: 9017571
    Abstract: A dry etching agent according to the present invention preferably contains: (A) 1,3,3,3-tetrafluoropropene; (B) at least one kind of additive gas selected from the group consisting of H2, O2, O3, CO, CO2, COCl2, COF2, CF3OF, NO2, F2, NF3, Cl2, Br2, I2, CH4, C2H2, C2H4, C2H6, C3H4, C3H6, C3H8, HF, HI, HBr, HCl, NO, NH3 and YFn (where Y represents Cl, Br or I; and n represents an integer satisfying 1?n?7); and (C) an inert gas. This dry etching agent has less effect on the global environment and can obtain a significant improvement in process window and address processing requirements such as low side etching ratio and high aspect ratio even without any special substrate excitation operation.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: April 28, 2015
    Assignee: Central Glass Company, Limited
    Inventors: Tomonori Umezaki, Yasuo Hibino, Isamu Mori, Satoru Okamoto, Akiou Kikuchi
  • Publication number: 20150111382
    Abstract: Provided is a polishing composition used for polishing a semiconductor substrate having a through-silicon via structure, comprising an oxidizing agent having a standard electrode potential of 350 mV or more and 740 mV or less, a silicon polishing accelerating agent, a through-silicon via material polishing speed increasing agent, a silicon contamination preventing agent, and water.
    Type: Application
    Filed: April 10, 2013
    Publication date: April 23, 2015
    Applicant: FUJIMI INCORPORATED
    Inventor: Toshio Shinoda
  • Publication number: 20150104941
    Abstract: A barrier chemical mechanical planarization polishing composition is provided that includes suitable chemical additives. The suitable chemical additives are organic polymer molecules containing ethylene oxide repeating units having the general molecular structure of where n refers to the total numbers of the repeating unit ranging from 6,818 to 181,817; and the molecular weights of polyethylene oxide ranging from 100,000 to 8,000,000. There is also provided a chemical mechanical polishing method using the barrier chemical mechanical planarization polishing composition.
    Type: Application
    Filed: September 30, 2014
    Publication date: April 16, 2015
    Inventors: Maitland Gary Graham, JAMES ALLEN SCHLUETER, XIAOBO SHI
  • Patent number: 8999186
    Abstract: The present invention relates to a method for selectively etching and patterning with high resolution of flexible polymer matrices, which may comprise Ag nano tubes.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: April 7, 2015
    Assignee: Merck Patent GmbH
    Inventors: Arjan Meijer, Werner Stockum, Ingo Koehler
  • Patent number: 8974691
    Abstract: A polishing composition for a silicon wafer and a rinsing composition for a silicon wafer according to the present invention contain a nonionic surfactant of a polyoxyethylene adduct. The HLB value of the polyoxyethylene adduct is 8 to 15. The weight-average molecular weight of the polyoxyethylene adduct is 1400 or less. The average number of moles of oxyethylene added in the polyoxyethylene adduct is 13 or less. The content of the polyoxyethylene adduct in each of the polishing composition and the rinsing composition is 0.00001 to 0.1% by mass.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: March 10, 2015
    Assignee: Fujimi Incorporated
    Inventors: Kohsuke Tsuchiya, Shuhei Takahashi
  • Patent number: 8961814
    Abstract: Methods and formulations for the selective etching of etch stop layers deposited above metal-based semiconductor layers used in the manufacture of TFT-based display devices are presented. The formulations are based on an alkaline solution. Methods and formulations for the selective etching of molybdenum-based and/or copper-based source/drain electrode layers deposited above metal-based semiconductor layers used in the manufacture of TFT-based display devices are presented. The formulations are based on an alkaline solution.
    Type: Grant
    Filed: December 18, 2013
    Date of Patent: February 24, 2015
    Assignee: Intermolecular, Inc.
    Inventors: Jeroen Van Duren, Zhi-Wen Wen Sun
  • Publication number: 20150048053
    Abstract: A layer of a metal selected from titanium, niobium, tungsten, molybdenum, ruthenium, rhodium, arsenic, aluminum and gallium, an oxide of the metal, a nitride of the metal, silicon nitride, hafnium nitride, tantalum nitride, or an alloy of these metals, the layer being provided on an underlying base material selected from glass, silicon, copper and nickel, is selectively etched with an alkaline etching solution containing a predefined complexing agent.
    Type: Application
    Filed: September 3, 2012
    Publication date: February 19, 2015
    Applicant: JCU CORPORATION
    Inventors: Christopher Cordonier, Mitsuhiro Nabeshima, Shingo Kumagai, Naoki Takahashi
  • Publication number: 20150037614
    Abstract: The present disclosure relates to a planarized bit-patterned magnetic medium that has a magnetic layer, including island regions and trench regions, a first carbon layer applied over the magnetic layer, and a second carbon layer applied over the first carbon layer, wherein the second carbon layer has been removed in the island regions. The first carbon layer may have a lower material removal rate when exposed to chemical-mechanical polishing than the second carbon layer. The present disclosure also relates to a method for planarizing a bit-patterned magnetic medium and a slurry composition for the chemical-mechanical polishing of carbon layers, the slurry composition including an oxidizer component, a catalyst component, a particulate component, and a reaction control component.
    Type: Application
    Filed: August 2, 2013
    Publication date: February 5, 2015
    Applicant: HGST Netherlands B.V.
    Inventors: Kurt A. Rubin, Richard L. White, Xiaoping Bian
  • Publication number: 20150014580
    Abstract: In the present invention, by using an etching liquid for silicon wafers, which comprises an aqueous solution containing (A) an alkali component and (B) a phosphonic acid derivative or a salt thereof, a good texture can be stably and uniformly formed on a wafer surface. The present invention provides a texture-forming etching liquid for silicon wafers, which is applicable to both wafers cut by a loose abrasive grain system and wafers cut by a fixed abrasive grain system with no vaporization of additive components in the region of working temperatures of from 60° C. to 95° C.
    Type: Application
    Filed: February 6, 2013
    Publication date: January 15, 2015
    Applicant: DAI-ICHI KOGYO SEIYAKU CO., LTD.
    Inventors: Kazunori Nakagawa, Shigeru Kigasawa, Toshikazu Nabeshima
  • Publication number: 20150014579
    Abstract: A polishing composition contains: silicon dioxide having an average primary particle diameter of 40 nm or more as calculated from the specific surface area determined by the BET method; a nitrogen-containing water-soluble polymer; and a basic compound. The value of B/A is 1 or more and less than 7,000 and the value of C/A is 5,000 or more and less than 1,500,000 when in one liter of the polishing composition, A is defined as the number of silicon dioxide, B is defined as the number of monomer units of the nitrogen-containing water-soluble polymer, and C is defined as the number of molecules of the basic compound. Alternatively, the value of B/A is 1 or more and less than 7,000 and the value of C/A is 5,000 or more and less than 100,000. The polishing composition is used, for example, for polishing a semiconductor substrate.
    Type: Application
    Filed: February 5, 2013
    Publication date: January 15, 2015
    Inventors: Toshihiro Miwa, Hiroyuki Oda, Shinichiro Takami, Shuhei Takahashi, Yutaka Inoue
  • Patent number: 8932719
    Abstract: The object of the present invention is to strongly join an aluminum alloy part with an FRP prepreg. An object obtained by subjecting an aluminum alloy to a suitable liquid treatment so as to form a surface having large, micron-order irregularities and also fine irregularities with a period of several tens of nanometers, eliminating the presence of sodium ions from the surface and additionally forming a surface film of aluminum oxide, which is thicker than a natural oxide layer, has been found to have a powerful adhesive strength with epoxy-based adhesives. By simultaneously curing an FRP prepreg which uses the same epoxy-based adhesive in the matrix, an integral composite or structure in which FRP and aluminum alloy have been united at a joining strength of unprecedented magnitude is produced.
    Type: Grant
    Filed: March 12, 2008
    Date of Patent: January 13, 2015
    Assignee: Taisei Plas Co., Ltd.
    Inventors: Masanori Naritomi, Naoki Andoh
  • Patent number: 8900472
    Abstract: A liquid agent for the surface treatment of monocrystalline wafers, which contains an alkaline etching agent and also at least one low-volatile organic compound. Systems of this type can be used both for the cleaning, damage etch and texturing of wafer surfaces in a single etching step and exclusively for the texturing of silicon wafers with different surface quality, whether it now be wire-sawn wafers with high surface damage or chemically polished surfaces with minimum damage density.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: December 2, 2014
    Assignee: Fraunhofer-Gesellschaft zur Föerderung der angewandten Forschung E.V.
    Inventors: Kuno Mayer, Mark Schumann, Daniel Kray, Teresa Orellana Peres, Jochen Rentsch, Martin Zimmer, Elias Kirchgässner, Eva Zimmer, Daniel Biro, Arpad Mihai Rostas, Filip Granek
  • Publication number: 20140339463
    Abstract: The present invention provides a desmear solution and a desmear method using said desmear solution, the desmear solution being capable of certainly removing a smear inside a non-through hole formed in a resin substrate and also capable of forming a plating film excellent in adhesion without excessive roughening of a surface of the resin substrate. The present invention uses the desmear solution containing a permanganate having a concentration of 0.2 to 0.4 mol/L and an alkali metal hydroxide and having a molar concentration ratio of said permanganate to said alkali metal hydroxide of 1:5 to 1:20.
    Type: Application
    Filed: September 11, 2012
    Publication date: November 20, 2014
    Applicant: C. UYEMURA & CO., LTD.
    Inventors: Yoshikazu Saijo, Hisamitsu Yamamoto, Masayuki Utsumi
  • Patent number: 8889555
    Abstract: A polishing agent for copper polishing, comprising (A) an inorganic acid with divalent or greater valence, (B) an amino acid, (C) a protective film-forming agent, (D) an abrasive, (E) an oxidizing agent and (F) water, wherein the content of the component (A) is at least 0.08 mol/kg, the content of the component (B) is at least 0.20 mol/kg, the content of the component (C) is at least 0.02 mol/kg, and either or both of the following conditions (i) and (ii) are satisfied. (i): The proportion of the content of the component (A) with respect to the content of the component (C) is 2.00 or greater. (ii): It further comprises (G) at least one kind selected from among organic acids and their acid anhydrides.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: November 18, 2014
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hiroshi Ono, Takashi Shinoda, Yuuhei Okada
  • Patent number: 8883034
    Abstract: The invention provides a polishing composition comprising (a) silica, (b) one or more compounds that increases the removal rate of silicon, (c) one or more tetraalkylammonium salts, and (d) water, wherein the polishing composition has a pH of about 7 to about 11. The invention further provides a method of polishing a substrate with the polishing composition.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: November 11, 2014
    Inventors: Brian Reiss, John Clark, Lamon Jones, Jeffrey Gilliland, Michael White
  • Patent number: 8865017
    Abstract: A method of texturing a surface of a crystalline silicon substrate is provided. The method includes immersing a crystalline silicon substrate into an aqueous alkaline etchant solution to form a pyramid shaped textured surface, with (111) faces exposed, on the crystalline silicon substrate. The aqueous alkaline etchant solution employed in the method of the present disclosure includes an alkaline component and a nanoparticle slurry component. Specifically, the aqueous alkaline etchant solution of the present disclosure includes 0.5 weight percent to 5 weight percent of an alkaline component and from 0.1 weight percent to 5 weight percent of a nanoparticle slurry on a dry basis.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: October 21, 2014
    Assignee: International Business Machines Corporation
    Inventors: Mahadevaiyer Krishnan, Jun Liu, Satyavolu S. Papa Rao, George G. Totir
  • Patent number: 8859429
    Abstract: A polishing agent for copper polishing, comprising (A) an inorganic acid with divalent or greater valence, (B) an amino acid, (C) a protective film-forming agent, (D) an abrasive, (E) an oxidizing agent and (F) water, wherein the content of the component (A) is at least 0.08 mol/kg, the content of the component (B) is at least 0.20 mol/kg, the content of the component (C) is at least 0.02 mol/kg, and either or both of the following conditions (i) and (ii) are satisfied. (i): The proportion of the content of the component (A) with respect to the content of the component (C) is 2.00 or greater. (ii): It further comprises (G) at least one kind selected from among organic acids and their acid anhydrides.
    Type: Grant
    Filed: March 6, 2012
    Date of Patent: October 14, 2014
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hiroshi Ono, Takashi Shinoda, Yuuhei Okada
  • Patent number: 8846533
    Abstract: A cleaning solution of the present invention contains a sodium ion, a potassium ion, an iron ion, an ammonium salt of a sulfuric ester represented by General Formula (1), and water, and each content of the sodium ion, the potassium ion, and the iron ion is 1 ppb to 500 ppb. ROSO3—(X)+ (1) where R is an alkyl group with a carbon number of 8-22 or an alkenyl group with a carbon number of 8-22, and (X)+ is an ammonium ion.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: September 30, 2014
    Assignee: Kao Corporation
    Inventor: Youichi Ishibashi
  • Patent number: 8821751
    Abstract: A CMP composition and associated method are provided that afford good corrosion protection and low defectivity levels both during and subsequent to CMP processing. This composition and method are useful in CMP (chemical mechanical planarization) processing in semiconductor manufacture involving removal of metal(s) and/or barrier layer material(s) and especially for CMP processing in low technology node applications.
    Type: Grant
    Filed: June 7, 2011
    Date of Patent: September 2, 2014
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Xiaobo Shi, Ronald Martin Pearlstein
  • Patent number: 8821747
    Abstract: A method for manufacturing a glass substrate for a magnetic disk comprises a surface grinding step of processing a mirror-surface plate glass, having a main surface in the form of a mirror surface, to a required flatness and surface roughness using fixed abrasive particles. The method comprises, before the surface grinding step using the fixed abrasive particles, a surface roughening step of roughening the surface of the mirror-surface plate glass by frosting.
    Type: Grant
    Filed: October 5, 2009
    Date of Patent: September 2, 2014
    Assignee: Hoya Corporation
    Inventors: Takanori Mizuno, Yosuke Suzuki
  • Patent number: 8815110
    Abstract: The invention provides a polishing composition comprising (a) silica, (b) one or more compounds that increase the removal rate of silicon, (c) one or more tetraalkylammonium salts, and (d) water, wherein the polishing composition has a pH of about 7 to about 11. The invention further provides a method of polishing a substrate with the polishing composition.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: August 26, 2014
    Assignee: Cabot Microelectronics Corporation
    Inventors: Brian Reiss, Michael White, Lamon Jones, John Clark
  • Publication number: 20140231704
    Abstract: The present disclosure includes a texture formulation that includes an aliphatic diol, an alkaline compound and water which provides a consistent textured region across a silicon surface suitable for solar cell applications. The current invention describes silicon texturing formulations that include at least one high boiling point additive. The high boiling point additive may be a derivative compound of propylene glycol or a derivative compound of ethylene glycol. Processes for texturing a crystalline silicon substrate using these formulations are also described. Additionally, a combinatorial method of optimizing the textured surface of a crystalline silicon substrate is described.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: Intermolecular, Inc.
    Inventors: Zhi-Wen Sun, Nikhil Kalyankar, Nitin Kumar, Minh Anh Nguyen, Sagar Vijay
  • Patent number: 8801958
    Abstract: A titanium etchant composition and a method of forming a semiconductor device using the same, the titanium etchant composition including a titanium remover; a corrosion inhibitor; and a deionized water; wherein the corrosion inhibitor includes 5-aminotetrazole.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: August 12, 2014
    Assignees: Samsung Electronics Co., Ltd., Samyoung Pure Chemicals Co., Ltd.
    Inventors: Dong-Min Kang, Heon jin Park, Kyoochul Cho, Baiksoon Choi, Seunghyun Ahn, Jeong Kwon, JungIg Jeon
  • Publication number: 20140191155
    Abstract: The invention provides a polishing composition comprising silica, an aminophosphonic acid, a polysaccharide, a tetraalkylammonium salt, a bicarbonate salt, an azole ring, and water, wherein the polishing composition has a pH of about 7 to about 11. The invention further provides a method of polishing a substrate with the polishing composition.
    Type: Application
    Filed: March 13, 2014
    Publication date: July 10, 2014
    Inventors: Brian REISS, Timothy JOHNS, Michael WHITE, Lamon JONES, John CLARK
  • Publication number: 20140193945
    Abstract: Disclosed herein is an aqueous alkaline etching solution comprising water and an alkaline material being selected from the group consisting of ammonium hydroxide, ammonium phosphate, ammonium carbonate, quaternary ammonium hydroxide, quaternary ammonium phosphate, quaternary ammonium carbonate, an alkali metal hydroxide, an alkaline earth metal hydroxide, or a combination comprising at least one of the foregoing alkaline materials; the aqueous alkaline solution being operative to etch aluminum oxide at a rate greater than or equal to about 2:1 over a rate at which it etches a metal oxide semiconductor to be protected; wherein the aqueous etching solution has a pH of 8 to 13.
    Type: Application
    Filed: December 31, 2012
    Publication date: July 10, 2014
    Inventors: Yuanyuan Li, Kaige Sun, Thomas N. Jackson
  • Patent number: 8771531
    Abstract: A substrate for a liquid ejection head, including: forming a sacrifice layer on a first surface of a silicon substrate in a region in which a liquid supply port is to open, the sacrifice layer containing aluminum which is selectively etched with respect to the silicon substrate; forming an etching mask on a second surface which is a rear surface of the first surface of the silicon substrate, the etching mask having an opening corresponding to the sacrifice layer; a first etching step of etching the silicon substrate by using the etching mask as a mask and by using a first etchant containing 8 mass % or more and less than 15 mass % of tetramethylammonium hydroxide; and after the first etching step, a second etching step of removing the sacrifice layer by using a second etchant containing 15 mass % or more and 25 mass % or less of tetramethylammonium hydroxide.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: July 8, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenta Furusawa, Shuji Koyama, Hiroyuki Abo, Taichi Yonemoto
  • Publication number: 20140162456
    Abstract: The present invention is directed to a method for polishing a silicon wafer, the method comprising: polishing the silicon wafer by bringing the silicon wafer into sliding contact with a polishing pad attached to a turn table while supplying a polishing agent stored in a tank to the polishing pad; and circulating the polishing agent to recover the supplied polishing agent in the tank, wherein the silicon wafer is polished while adjusting a concentration of silicate ions contained in the polishing agent in the tank to be within a predetermined range. The present invention provides a polishing agent having a high polishing rate that enables the polishing rate to be kept constant among polishing batches, and a method for polishing a silicon wafer accurately with a target polishing stock removal or a target finishing thickness by using the polishing agent.
    Type: Application
    Filed: August 13, 2012
    Publication date: June 12, 2014
    Applicant: SHIN-ETSU HANDOTAI CO., LTD.
    Inventors: Shigeru Oba, Takao Kawamata
  • Patent number: 8747693
    Abstract: A silica having metal ions absorbed thereon and a fabricating method thereof are provided. The silica having metal ions absorbed thereon is a silica having metal ions absorbed thereon and being modified with persulfate salt. The method includes following steps. A solution is provided, and the solution includes silica and persulfate salt therein. The solution is heated to react the silica with the persulfate salt, so as to obtain silica modified with persulfate salt. Metal ion source is added in the solution, the metal ion source dissociates metal ions, and the silica modified with persulfate salt absorbs the metal ions to obtain the silica having metal ions absorbed thereon.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: June 10, 2014
    Assignee: UWIZ Technology Co., Ltd.
    Inventors: Yun-Lung Ho, Song-Yuan Chang, Ming-Hui Lu, Chung-Wei Chiang
  • Patent number: 8735293
    Abstract: A method for chemical mechanical polishing of a substrate comprising a germanium-antimony-tellurium chalcogenide phase change alloy using a chemical mechanical polishing composition comprising water; 1 to 40 wt % colloidal silica abrasive particles having an average particle size of ?50 nm; and 0 to 5 wt % quarternary ammonium compound; wherein the chemical mechanical polishing composition is oxidizer free and chelating agent free; and, wherein the chemical mechanical polishing composition has a pH >6 to 12.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: May 27, 2014
    Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.
    Inventor: Zhendong Liu
  • Patent number: 8728341
    Abstract: A polishing agent of the invention comprises tetravalent metal hydroxide particles, a cationized polyvinyl alcohol, at least one type of saccharide selected from the group consisting of an amino sugar, a derivative of the amino sugar, a polysaccharide containing an amino sugar and a derivative of the polysaccharide, and water. The method for polishing a substrate of the invention comprises a step of polishing the silicon oxide film 1 (film to be polished), formed on the silicon substrate 2 having the silicon oxide film 1, by relatively moving the silicon substrate 2 and a polishing platen, in a state that the silicon oxide film 1 is pressed against a polishing pad on the polishing platen, while supplying the polishing agent of the invention between the silicon oxide film 1 and the polishing pad.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: May 20, 2014
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Daisuke Ryuzaki, Takenori Narita, Yousuke Hoshi, Tomohiro Iwano
  • Patent number: 8715524
    Abstract: The invention provides a polishing liquid for polishing a barrier layer of a semiconductor integrated circuit, the polishing liquid comprising: a diquaternary ammonium cation; a corrosion inhibiting agent; and a colloidal silica, wherein the pH of the polishing liquid is in the range of 2.5 to 5.0. According to the invention, a polishing liquid capable of achieving a superior barrier layer polishing rate, as well as suppressing the occurrence of scratching due to the agglomeration of solid abrasive grains can be provided.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: May 6, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Tetsuya Kamimura, Toshiyuki Saie, Masaru Yoshikawa
  • Patent number: 8709278
    Abstract: A polishing composition that allows polishing speed to be increased and surface roughness to be reduced is provided. The polishing composition according to the present invention includes a compound including at least an oxyethylene group or an oxypropylene group in a block polyether represented by the following general formula (1), a basic compound, and abrasives: >N—R—N< (1) where R represents an alkylene group expressed as CnH2n and “n” is an integer not less than 1.
    Type: Grant
    Filed: July 13, 2009
    Date of Patent: April 29, 2014
    Assignee: Nitta Haas Incorporated
    Inventors: Takayuki Matsushita, Noriaki Sugita
  • Publication number: 20140106566
    Abstract: A method for etching an ultra thin film is provided which includes providing a substrate having the ultra thin film formed thereon, patterning a photosensitive layer formed over the ultra thin film, etching the ultra thin film using the patterned photosensitive layer, and removing the patterned photosensitive layer. The etching process includes utilizing an etch material with a diffusion resistant carrier such that the etch material is prevented from diffusing to a region underneath the photosensitive layer and removing portions of the ultra thin film underneath the photosensitive layer.
    Type: Application
    Filed: January 6, 2014
    Publication date: April 17, 2014
    Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chia-Chu LIU, Kuei-Shun Chen, Shang-Wern Chang, Chih-Yang Yeh
  • Patent number: 8697576
    Abstract: The invention provides a polishing composition comprising silica, an aminophosphonic acid, a polysaccharide, a tetraalkylammonium salt, a bicarbonate salt, an azole ring, and water, wherein the polishing composition has a pH of about 7 to about 11. The invention further provides a method of polishing a substrate with the polishing composition.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: April 15, 2014
    Assignee: Cabot Microelectronics Corporation
    Inventors: Brian Reiss, Timothy Johns, Michael White, Lamon Jones, John Clark
  • Publication number: 20140042360
    Abstract: A method of texturing a surface of a crystalline silicon substrate is provided. The method includes immersing a crystalline silicon substrate into an aqueous alkaline etchant solution to form a pyramid shaped textured surface, with (111) faces exposed, on the crystalline silicon substrate. The aqueous alkaline etchant solution employed in the method of the present disclosure includes an alkaline component and a nanoparticle slurry component. Specifically, the aqueous alkaline etchant solution of the present disclosure includes 0.5 weight percent to 5 weight percent of an alkaline component and from 0.1 weight percent to 5 weight percent of a nanoparticle slurry on a dry basis.
    Type: Application
    Filed: October 22, 2013
    Publication date: February 13, 2014
    Applicant: International Business Machines Corporation
    Inventors: Mahadevaiyer Krishnan, Jun Liu, Satyavolu S. Papa Rao, George G. Totir
  • Patent number: 8647527
    Abstract: A polishing composition contains a vanadate such as ammonium vanadate, sodium vanadate, and potassium vanadate and an oxygen donor such as hydrogen peroxide and ozone. It is preferable that the polishing composition further contains at least either one of abrasive grains and a pH adjusting agent. The polishing composition can be suitably used for polishing a silicon carbide wafer such as a hexagonal silicon carbide single crystal wafer.
    Type: Grant
    Filed: January 23, 2008
    Date of Patent: February 11, 2014
    Assignee: Fujimi Incorporated
    Inventors: Kazutoshi Hotta, Kanji Kawata
  • Publication number: 20140004701
    Abstract: Monocrystalline semiconductor substrates are textured with alkaline solutions to form pyramid structures on their surfaces to reduce incident light reflectance and improve light absorption of the wafers. The alkaline baths include compounds which inhibit the formation of flat areas between pyramid structures to improve the light adsorption.
    Type: Application
    Filed: June 27, 2012
    Publication date: January 2, 2014
    Applicant: Rohm and Haas Electronic Materials LLC
    Inventors: Robert K. Barr, Corey O'Connor, Peter W. Hinkley, George R. Allardyce
  • Publication number: 20140001145
    Abstract: A method of forming a capacitor structure, which comprises: applying a silicon etching liquid which contains an alkali compound and a hydroxylamine compound in combination, with the pH adjusted to 11 or more, to a polycrystalline silicon film or an amorphous silicon film, removing a part or all of the polycrystalline silicon film or amorphous silicon film, and forming concave and convex shapes that constitute a capacitor.
    Type: Application
    Filed: September 3, 2013
    Publication date: January 2, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Atsushi MIZUTANI, Tadashi INABA, Akiko KOYAMA