Gate Conductor Material Being Compound Or Alloy Material (e.g., Organic Material, Tin, Mosi 2 ) (epo) Patents (Class 257/E29.16)
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Patent number: 11037728Abstract: A dielectric including a composite including a metal oxide having a rocksalt crystal structure and a beryllium oxide, and a capacitor, a transistor, and an electronic device including the same.Type: GrantFiled: December 18, 2018Date of Patent: June 15, 2021Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jinhong Kim, Se Yun Kim
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Patent number: 10529826Abstract: A method includes forming an active layer, forming a gate structure above a channel region of the active layer, forming a sidewall spacer adjacent the gate structure, forming a first dielectric layer adjacent the sidewall spacer, recessing the gate structure to define a gate cavity, forming an inner spacer in the gate cavity, forming a cap layer in the gate cavity, recessing the first dielectric layer and the sidewall spacer to expose sidewall surfaces of the cap layer, removing the inner spacer to define a first spacer cavity, forming an upper spacer in the spacer cavity and contacting sidewall surfaces of the cap layer, forming a second dielectric layer above the upper spacer and the cap layer, and forming a first contact structure at least partially embedded in the second dielectric layer and contacting a surface of the upper spacer.Type: GrantFiled: August 13, 2018Date of Patent: January 7, 2020Assignee: GLOBALFOUNDRIES Inc.Inventors: Julien Frougier, Ruilong Xie, Chanro Park, Kangguo Cheng
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Patent number: 10193063Abstract: Subject matter disclosed herein may relate to fabrication of a correlated electron material (CEM) switch. In embodiments, processes are described in which conductive traces may be formed on or over an insulating material. Responsive to forming voids in the insulating material, localized portions of the conductive traces in contact with the voids may be exposed to gaseous oxidizing agents, which may convert the localized portions of the conductive traces to a CEM. In embodiments, an electrode material may be deposited within the voids to contact the localized portion of conductive trace converted to the CEM.Type: GrantFiled: December 1, 2016Date of Patent: January 29, 2019Assignee: ARM Ltd.Inventors: Carlos Alberto Paz de Araujo, Jolanta Bozena Celinska, Kimberly Gay Reid, Lucian Shifren
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Patent number: 10178309Abstract: A semiconductor structure and a method for manufacturing the same are provided. The semiconductor structure comprises a substrate, a gate structure, a first dielectric layer and two air gaps. The gate structure is disposed on the substrate. The gate structure has two opposite side walls. The gate structure comprises a U-shaped structure and a metal gate electrode. The U-shaped structure defines an opening toward upside, and comprises a work function layer. The metal gate electrode is disposed in the opening defined by the U-shaped structure. A level of a top surface of the U-shaped structure is lower than a level of a top surface of the metal gate electrode. The first dielectric layer is disposed on the substrate adjacent to the gate structure. Each of the two air gaps is formed between the first dielectric layer and one of the two opposite side walls of the gate structure.Type: GrantFiled: June 6, 2018Date of Patent: January 8, 2019Assignee: UNITED MICROELECTRONICS CORP.Inventor: Chien-Ting Lin
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Patent number: 10109641Abstract: According to one embodiment, the electrode films are stacked with gaps interposed between the electrode films. The first insulating film is provided between a lowermost electrode film of the electrode films and the substrate and being a metal oxide film, a silicon carbide film, or a silicon carbonitride film. The second insulating film is provided on an uppermost electrode film of the electrode films and being a metal oxide film, a silicon carbide film, or a silicon carbonitride film. The stacked film includes a semiconductor film extending in a stacking direction of the stacked body in the stacked body, and a charge storage film provided between the semiconductor film and the electrode films.Type: GrantFiled: January 22, 2016Date of Patent: October 23, 2018Assignee: TOSHIBA MEMORY CORPORATIONInventor: Shinya Arai
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Patent number: 10062604Abstract: A semiconductor device includes: a substrate, a gate structure on the substrate, and a spacer adjacent to the gate structure, in which the spacer extends to a top surface of the gate structure, a top surface of the spacer includes a planar surface, the spacer encloses an air gap, and the spacer is composed of a single material. The gate structure includes a high-k dielectric layer, a work function metal layer, and a low resistance metal layer, in which the high-k dielectric layer is U-shaped. The semiconductor device also includes an interlayer dielectric (ILD) layer around the gate structure and a hard mask on the spacer, in which the top surface of the hard mask is even with the top surface of the ILD layer.Type: GrantFiled: July 7, 2017Date of Patent: August 28, 2018Assignee: UNITED MICROELECTRONICS CORP.Inventors: Ching-Yu Chang, Ssu-I Fu, Yu-Hsiang Hung, Chih-Kai Hsu, Wei-Chi Cheng, Jyh-Shyang Jenq
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Patent number: 10021298Abstract: A semiconductor structure and a method for manufacturing the same are provided. The semiconductor structure comprises a substrate, a gate structure, a first dielectric layer and two air gaps. The gate structure is disposed on the substrate. The gate structure has two opposite side walls. The gate structure comprises a U-shaped structure and a metal gate electrode. The U-shaped structure defines an opening toward upside, and comprises a work function layer. The metal gate electrode is disposed in the opening defined by the U-shaped structure. A level of a top surface of the U-shaped structure is lower than a level of a top surface of the metal gate electrode. The first dielectric layer is disposed on the substrate adjacent to the gate structure. Each of the two air gaps is formed between the first dielectric layer and one of the two opposite side walls of the gate structure.Type: GrantFiled: February 1, 2016Date of Patent: July 10, 2018Assignee: UNITED MICROELECTRONICS CORP.Inventor: Chien-Ting Lin
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Patent number: 9799523Abstract: The present disclosure relates to methods for forming a high-k gate dielectric, the methods comprising the steps of providing a semiconductor substrate, cleaning the substrate, performing a thermal treatment, and performing a high-k dielectric material deposition, wherein said thermal treatment step is performed in a non-oxidizing ambient, leading to the formation of a thin interfacial layer between said semiconductor substrate and said high-k dielectric material and wherein the thickness of said thin interfacial layer is less than 10 ?.Type: GrantFiled: October 12, 2015Date of Patent: October 24, 2017Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Hui OuYang, Jean-Luc Everaert, Laura Nyns, Rita Vos
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Patent number: 9024393Abstract: A manufacturing method for semiconductor device having metal gate includes providing a substrate having a first semiconductor device and a second semiconductor device formed thereon, the first semiconductor device having a first gate trench and the second semiconductor device having a second gate trench; sequentially forming a high dielectric constant (high-k) gate dielectric layer and a multiple metal layer on the substrate; forming a first work function metal layer in the first gate trench; performing a first pull back step to remove a portion of the first work function metal layer from the first gate trench; forming a second work function metal layer in the first gate trench and the second gate trench; and performing a second pull back step to remove a portion of the second work function metal layer from the first gate trench and the second gate trench.Type: GrantFiled: December 26, 2013Date of Patent: May 5, 2015Assignee: United Microelectronics Corp.Inventors: Ssu-I Fu, Wen-Tai Chiang, Ying-Tsung Chen, Shih-Hung Tsai, Chien-Ting Lin, Chi-Mao Hsu, Chin-Fu Lin
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Patent number: 9000596Abstract: A MOS transistor having a gate insulator including a dielectric of high permittivity and a conductive layer including a TiN layer, wherein the nitrogen composition in the TiN layer is sub-stoichiometric in its lower portion and progressively increases to a stoichiometric composition in its upper portion.Type: GrantFiled: June 22, 2012Date of Patent: April 7, 2015Assignee: STMicroelectronics (Crolles 2) SASInventors: Pierre Caubet, Sylvain Baudot
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Patent number: 8901670Abstract: A method of forming a semiconductor device is provided that in some embodiments encapsulates a gate silicide in a continuous encapsulating material. By encapsulating the gate silicide in the encapsulating material, the present disclosure substantially eliminates shorting between the gate structure and the interconnects to the source and drain regions of the semiconductor device.Type: GrantFiled: September 5, 2012Date of Patent: December 2, 2014Assignee: International Business Machines CorporationInventors: Sivananda K. Kanakasabapathy, Hemanth Jagannathan, Soon-Cheon Seo
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Patent number: 8901674Abstract: A method of forming a p-type semiconductor device is provided, which in one embodiment employs an aluminum containing threshold voltage shift layer to produce a threshold voltage shift towards the valence band of the p-type semiconductor device. The method of forming the p-type semiconductor device may include forming a gate structure on a substrate, in which the gate structure includes a gate dielectric layer in contact with the substrate, an aluminum containing threshold voltage shift layer present on the gate dielectric layer, and a metal containing layer in contact with at least one of the aluminum containing threshold voltage shift layer and the gate dielectric layer. P-type source and drain regions may be formed in the substrate adjacent to the portion of the substrate on which the gate structure is present. A p-type semiconductor device provided by the above-described method is also provided.Type: GrantFiled: February 25, 2013Date of Patent: December 2, 2014Assignee: International Business Machines CorporationInventors: Keith Kwong Hon Wong, Dechao Guo, Unoh Kwon, Christopher Carr Parks, Yun-Yu Wang
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Patent number: 8836049Abstract: A semiconductor structure includes a work function metal layer, a (work function) metal oxide layer and a main electrode. The work function metal layer is located on a substrate. The (work function) metal oxide layer is located on the work function metal layer. The main electrode is located on the (work function) metal oxide layer. Moreover a semiconductor process forming said semiconductor structure is also provided.Type: GrantFiled: June 13, 2012Date of Patent: September 16, 2014Assignee: United Microelectronics Corp.Inventors: Min-Chuan Tsai, Hsin-Fu Huang, Chi-Mao Hsu, Chin-Fu Lin, Chien-Hao Chen, Wei-Yu Chen, Chi-Yuan Sun, Ya-Hsueh Hsieh, Tsun-Min Cheng
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Patent number: 8829622Abstract: An integrated circuit including at least one isolating trench that delimits an active area made of a monocrystalline semiconductor material, the or each trench comprising an upper portion including an insulating layer that encapsulates a lower portion of the trench, the lower portion being at least partly buried in the active area and the encapsulation layer comprising nitrogen or carbon.Type: GrantFiled: June 13, 2012Date of Patent: September 9, 2014Assignee: STMicroelectronics (Crolles 2) SASInventors: Grégory Bidal, Laurent Favennec, Raul Andres Bianchi
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Patent number: 8796751Abstract: Some embodiments include a semiconductor construction having a gate extending into a semiconductor base. Conductively-doped source and drain regions are within the base adjacent the gate. A gate dielectric has a first segment between the source region and the gate, a second segment between the drain region and the gate, and a third segment between the first and second segments. At least a portion of the gate dielectric comprises ferroelectric material. In some embodiments the ferroelectric material is within each of the first, second and third segments. In some embodiments, the ferroelectric material is within the first segment or the third segment. In some embodiments, a transistor has a gate, a source region and a drain region; and has a channel region between the source and drain regions. The transistor has a gate dielectric which contains ferroelectric material between the source region and the gate.Type: GrantFiled: November 20, 2012Date of Patent: August 5, 2014Assignee: Micron Technology, Inc.Inventors: Nirmal Ramaswamy, Kirk D. Prall, Wayne Kinney
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Patent number: 8735983Abstract: Metal-oxide-semiconductor transistors are provided. A metal-oxide-semiconductor transistor may be formed on a semiconductor substrate. Source and drain regions may be formed in the substrate. A gate insulator such as a high-K dielectric may be formed between the source and drain regions. A gate may be formed from multiple gate conductors. The gate conductors may be metals with different workfunctions. A first of the gate conductors may form a pair of edge gate conductors that are adjacent to dielectric spacers. An opening between the edge gate conductors may be filled with the second gate conductor to form a center gate conductor. A self-aligned gate formation process may be used in fabricating the metal-oxide-semiconductor transistor.Type: GrantFiled: November 26, 2008Date of Patent: May 27, 2014Assignee: Altera CorporationInventors: Jun Liu, Albert Ratnakumar, Qi Xiang, Jeffrey Xiaoqi Tung
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Patent number: 8716813Abstract: A field effect transistor device includes a first gate stack portion including a dielectric layer disposed on a substrate, a first TiN layer disposed on the dielectric layer, a metallic layer disposed on the dielectric layer, and a second TiN layer disposed on the metallic layer, a first source region disposed adjacent to the first gate stack portion, and a first drain region disposed adjacent to the first gate stack portion.Type: GrantFiled: July 24, 2012Date of Patent: May 6, 2014Assignee: International Business Machines CorporationInventors: Takashi Ando, Changhwan Choi, Unoh Kwon, Vijay Narayanan
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Patent number: 8691638Abstract: A method of forming a semiconductor device is presented. The method includes providing a substrate. The method further includes forming a gate stack having a gate electrode on the substrate, which includes forming a metal gate electrode layer. A buffer gate electrode layer is formed on top of the metal gate electrode layer and a top gate electrode layer having a poly-silicon alloy is formed over the metal gate electrode layer.Type: GrantFiled: December 10, 2010Date of Patent: April 8, 2014Assignee: GLOBALFOUNDRIES Singapore Pte. Ltd.Inventors: Shyue Seng Tan, Chunshan Yin
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Patent number: 8669624Abstract: Provided are a semiconductor device which enables reduction of diffusion of Si in the manufacturing process of an MIPS element and suppression of an increase in EOT, and a method of manufacturing the same. An embodiment of the present invention is a semiconductor device including a field effect transistor having a gate insulating film provided on a silicon substrate and a gate electrode provided on the gate insulating film. The gate electrode is a stack-type electrode including a conductive layer containing at least Ti, N, and O (oxygen) and a silicon layer provided on the conductive layer, and the concentration of oxygen in the conductive layer is highest in the side of the silicon layer.Type: GrantFiled: July 26, 2012Date of Patent: March 11, 2014Assignee: Canon Anelva CorporationInventors: Naomu Kitano, Takashi Minami, Nobuo Yamaguchi, Takuya Seino, Takashi Nakagawa, Heiji Watanabe, Takayoshi Shimura, Takuji Hosoi
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Patent number: 8643121Abstract: A semiconductor device and a method of manufacturing a gate stack for such a semiconductor device. The device includes a gate stack that has a gate insulation layer provided over a channel region of the device, and a metal layer that is insulated from the channel region by the gate insulation layer. The metal layer contains work function modulating impurities which have a concentration profile that varies along a length of the metal layer from the source region to the drain region. The gate stack has a first effective work function in the vicinity of a source region and/or the drain region of the device and a second, different effective work function toward a center of the channel region.Type: GrantFiled: November 23, 2009Date of Patent: February 4, 2014Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Markus Mueller, Raghunath Singanamalla
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Patent number: 8592924Abstract: A semiconductor device includes a semiconductor substrate having a semiconductor layer, a gate electrode, a source region, a drain region, an element separation insulating film layer and a wiring. The gate electrode include a laminated structure having a gate insulating film formed on the semiconductor layer, a metal or a metallic compound formed on the gate insulating film and a polycrystalline silicon layer formed on the metal or metallic compound. The source region and drain region are formed on a surface portion of the semiconductor substrate and sandwich the gate electrode therebetween. The element separation insulating film layer surrounds the semiconductor layer. The wiring is in contact with the metal or metallic compound of the gate electrode.Type: GrantFiled: May 14, 2012Date of Patent: November 26, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yoshinori Tsuchiya, Masato Koyama
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Patent number: 8581353Abstract: A transistor gate dielectric including a first dielectric material having a first dielectric constant and a second dielectric material having a second dielectric constant different from the first dielectric constant.Type: GrantFiled: December 22, 2010Date of Patent: November 12, 2013Assignee: Intel CorporationInventor: Gang Bai
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Patent number: 8575709Abstract: Methods for fabricating gate electrode/high-k dielectric gate structures having an improved resistance to the growth of silicon dioxide (oxide) at the dielectric/silicon-based substrate interface. In an embodiment, a method of forming a transistor gate structure comprises: incorporating nitrogen into a silicon-based substrate proximate a surface of the substrate; depositing a high-k gate dielectric across the silicon-based substrate; and depositing a gate electrode across the high-k dielectric to form the gate structure. In one embodiment, the gate electrode comprises titanium nitride rich in titanium for inhibiting diffusion of oxygen.Type: GrantFiled: July 24, 2012Date of Patent: November 5, 2013Assignee: International Business Machines CorporationInventors: Huiming Bu, Michael P. Chudzik, Wei He, William K. Henson, Siddarth A. Krishnan, Unoh Kwon, Naim Moumen, Wesley C. Natzle
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Patent number: 8558325Abstract: A gate containing ruthenium for a dielectric having an oxide containing a lanthanide and a method of fabricating such a combination gate and dielectric produce a reliable structure for use in a variety of electronic devices. A ruthenium or a conductive ruthenium oxide gate may be formed on a lanthanide oxide. A ruthenium-based gate on a lanthanide oxide provides a gate structure that can effectively prevent a reaction between the gate and the lanthanide oxide.Type: GrantFiled: May 17, 2010Date of Patent: October 15, 2013Assignee: Micron Technology, Inc.Inventors: Kie Y. Ahn, Leonard Forbes
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Patent number: 8487382Abstract: The present disclosure provides a method for making metal gate stacks of a semiconductor device. The method includes forming a high k dielectric material layer on a semiconductor substrate; forming a conductive material layer on the high k dielectric material layer; forming a dummy gate in a n-type field-effect transistor (nFET) region and a second dummy gate in a pFET region employing polysilicon; forming an inter-level dielectric (ILD) material on the semiconductor substrate; applying a first chemical mechanical polishing (CMP) process to the semiconductor substrate; removing the polysilicon from the first dummy gate, resulting in a first gate trench; forming a n-type metal to the first gate trench; applying a second CMP process to the semiconductor substrate; removing the polysilicon from the second dummy gate, resulting in a second gate trench; forming a p-type metal to the second gate trench; and applying a third CMP process to the semiconductor substrate.Type: GrantFiled: November 9, 2011Date of Patent: July 16, 2013Assignee: Taiwan Semiconductor Maufacturing Company, Ltd.Inventors: Sheng-Chen Chung, Kong-Beng Thei, Harry Chuang
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Patent number: 8450813Abstract: There is provided a fin transistor structure and a method of fabricating the same. The fin transistor structure comprises a fin formed on a semiconductor substrate, wherein a bulk semiconductor material is formed between a portion of the fin serving as the channel region of the transistor structure and the substrate, and an insulation material is formed between remaining portions of the fin and the substrate. Thereby, it is possible to reduce the current leakage while maintaining the advantages of body-tied structures.Type: GrantFiled: June 25, 2010Date of Patent: May 28, 2013Assignee: Institute of Microelectronics, Chinese Academy of SciencesInventors: Zhijiong Luo, Haizhou Yin, Huilong Zhu
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Patent number: 8445973Abstract: There is provided a fin transistor structure and a method of fabricating the same. The fin transistor structure comprises a fin formed on a semiconductor substrate, wherein an insulation material is formed between a portion of the fin serving as the channel region of the transistor structure and the substrate, and a bulk semiconductor material is formed between remaining portions of the fin and the substrate. Thereby, it is possible to reduce the current leakage while maintaining the advantages such as low cost and high heat transfer.Type: GrantFiled: June 24, 2010Date of Patent: May 21, 2013Assignee: Institute of Microelectronics, Chinese Academy of SciencesInventors: Zhijiong Luo, Huilong Zhu, Haizhou Yin
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Patent number: 8415753Abstract: This invention provides a semiconductor device having a field effect transistor comprising a gate electrode comprising a metal nitride layer and a polycrystalline silicon layer, and the gate electrode is excellent in thermal stability and realizes a desired work function. In the semiconductor device, a gate insulating film 6 on a silicon substrate 5 has a high-permittivity insulating film formed of a metal oxide, a metal silicate, a metal oxide introduced with nitrogen, or a metal silicate introduced with nitrogen, the gate electrode has a first metal nitride layer 7 provided on the gate insulating film 6 and containing Ti and N, a second metal nitride layer 8 containing Ti and N, and a polycrystalline silicon layer 9, in the first metal nitride layer 7, a molar ratio between Ti and N (N/Ti) is not less than 1.1, and a crystalline orientation X1 is 1.1<X1 <1.8, and in the second metal nitride layer 8, the molar ratio between Ti and N (N/Ti) is not less than 1.1, and a crystalline orientation X2 is 1.Type: GrantFiled: April 28, 2010Date of Patent: April 9, 2013Assignee: Canon Anelva CorporationInventors: Takashi Nakagawa, Naomu Kitano, Kazuaki Matsuo, Motomu Kosuda, Toru Tatsumi
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Patent number: 8410556Abstract: A semiconductor device includes pMISFET and nMIS formed on the semiconductor substrate. The pMISFET includes, on the semiconductor substrate, first source/drain regions, a first gate dielectric formed therebetween, first lower and upper metal layers stacked on the first gate dielectric, a first upper metal layer containing at least one metallic element belonging to groups IIA and IIIA. The nMISFET includes, on the semiconductor substrate, second source/drain regions, second gate dielectric formed therebetween, a second lower and upper metal layers stacked on the second gate dielectric and the second upper metal layer substantially having the same composition as the first upper metal layer. The first lower metal layer is thicker than the second lower metal layer, and the atomic density of the metallic element contained in the first gate dielectric is lower than the atomic density of the metallic element contained in the second gate dielectric.Type: GrantFiled: November 7, 2011Date of Patent: April 2, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Reika Ichihara, Masato Koyama
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Patent number: 8390042Abstract: Improved semiconductor devices including metal gate electrodes are formed with reduced performance variability by reducing the initial high dopant concentration at the top portion of the silicon layer overlying the metal layer. Embodiments include reducing the dopant concentration in the upper portion of the silicon layer, by implanting a counter-dopant into the upper portion of the silicon layer, removing the high dopant concentration portion and replacing it with undoped or lightly doped silicon, and applying a gettering agent to the upper surface of the silicon layer to form a thin layer with the gettered dopant, which layer can be removed or retained.Type: GrantFiled: January 18, 2012Date of Patent: March 5, 2013Assignee: Globalfoundries Inc.Inventors: Man Fai Ng, Rohit Pal
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Publication number: 20130049141Abstract: A metal gate structure located on a substrate includes a gate dielectric layer, a metal layer and a titanium aluminum nitride metal layer. The gate dielectric layer is located on the substrate. The metal layer is located on the gate dielectric layer. The titanium aluminum nitride metal layer is located on the metal layer.Type: ApplicationFiled: August 22, 2011Publication date: February 28, 2013Inventors: Tsun-Min Cheng, Min-Chuan Tsai, Chih-Chien Liu, Jen-Chieh Lin, Pei-Ying Li, Shao-Wei Wang, Mon-Sen Lin, Ching-Ling Lin
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Patent number: 8330234Abstract: In a semiconductor device, a gate electrode having a uniform composition prevents deviation in a work function. Controlling a Vth provides excellent operation properties. The semiconductor device includes an NMOS transistor and a PMOS transistor with a common line electrode. The line electrode includes electrode sections (A) and (B) and a diffusion barrier region formed over an isolation region so that (A) and (B) are kept out of contact. The diffusion barrier region meets at least one of: (1) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (A) is lower than the interdiffusion coefficient of the constituent element between electrode section (A) materials; and (2) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (B) is lower than the interdiffusion coefficient of the constituent element between electrode section (B) materials.Type: GrantFiled: November 21, 2006Date of Patent: December 11, 2012Assignee: NEC CorporationInventor: Takashi Hase
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Patent number: 8294223Abstract: A method of manufacturing a metal gate structure includes providing a substrate (110) having formed thereon a gate dielectric (120), a work function metal (130) adjacent to the gate dielectric, and a gate metal (140) adjacent to the work function metal; selectively forming a sacrificial capping layer (310) centered over the gate metal; forming an electrically insulating layer (161) over the sacrificial capping layer such that the electrically insulating layer at least partially surrounds the sacrificial capping layer; selectively removing the sacrificial capping layer in order to form a trench (410) aligned to the gate metal in the electrically insulating layer; and filling the trench with an electrically insulating material in order to form an electrically insulating cap (150) centered on the gate metal.Type: GrantFiled: December 13, 2010Date of Patent: October 23, 2012Assignee: Intel CorporationInventors: Willy Rachmady, Soley Ozer, Jason Klaus
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Patent number: 8242599Abstract: An electronic component is described that includes a metallic layer on a substrate that is made of a semiconductor material and a diffusion barrier layer that is made of a material that has a small diffusion coefficient for the metal of the metallic layer which is formed between the metallic layer and the substrate.Type: GrantFiled: January 9, 2008Date of Patent: August 14, 2012Assignee: Robert Bosch GmbHInventors: Richard Fix, Oliver Wolst, Alexander Martin
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Patent number: 8193641Abstract: A transistor gate comprises a substrate having a pair of spacers disposed on a surface, a high-k dielectric conformally deposited on the substrate between the spacers, a recessed workfunction metal conformally deposited on the high-k dielectric and along a portion of the spacer sidewalls, a second workfunction metal conformally deposited on the recessed workfunction metal, and an electrode metal deposited on the second workfunction metal. The transistor gate may be formed by conformally depositing the high-k dielectric into a trench between the spacers on the substrate, conformally depositing a workfunction metal atop the high-k dielectric, depositing a sacrificial mask atop the workfunction metal, etching a portion of the sacrificial mask to expose a portion of the workfunction metal, and etching the exposed portion of the workfunction metal to form the recessed workfunction metal. The second workfunction metal and the electrode metal may be deposited atop the recessed workfunction metal.Type: GrantFiled: May 9, 2006Date of Patent: June 5, 2012Assignee: Intel CorporationInventors: Willy Rachmady, Brian McIntyre, Michael K. Harper, Subhash M. Joshi
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Patent number: 8193593Abstract: A transistor gate dielectric including a first dielectric material having a first dielectric constant and a second dielectric material having a second dielectric constant different from the first dielectric constant.Type: GrantFiled: November 10, 2009Date of Patent: June 5, 2012Assignee: Intel CorporationInventor: Gang Bai
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Patent number: 8169040Abstract: A semiconductor device includes: an n-channel MIS transistor and a p-channel MIS transistor. An n-channel MIS transistor includes: a first gate insulating film having an amorphous layer or an epitaxial layer formed on a p-type semiconductor region between a first source/drain regions; and a first gate electrode having a stack structure formed with a first metal layer and a first compound layer. The first metal layer is formed on the first gate insulating film and made of a first metal having a work function of 4.3 eV or smaller, and the first compound layer is formed on the first metal layer and contains a compound of a second metal and a IV-group semiconductor. The second metal is different from the first metal. A p-channel MIS transistor includes a second gate electrode having a second compound layer containing a compound of the same composition as the first compound layer.Type: GrantFiled: June 28, 2010Date of Patent: May 1, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Yoshinori Tsuchiya, Masato Koyama, Masahiko Yoshiki
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Patent number: 8120114Abstract: In one aspect, an apparatus may include a metal gate of a transistor. An etch stop layer may be selectively formed over the metal gate. The etch stop layer may include a metal compound. An insulating layer may be over the etch stop layer. A conductive structure may be included through the insulating layer to the metal gate. Methods of making such transistors are also disclosed.Type: GrantFiled: December 27, 2006Date of Patent: February 21, 2012Assignee: Intel CorporationInventors: Andrew Ott, Sean King, Ajay Sharma
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Patent number: 8115264Abstract: Provided is a semiconductor device that comprises a metal gate having a low sheet resistance characteristic and a high diffusion barrier characteristic and a method of fabricating the metal gate of the semiconductor device. The semiconductor device includes a metal gate formed on a gate insulating film, wherein the metal gate is formed of a metal nitride that contains Al or Si and includes upper and lower portions where the content of Al or Si is relatively high and a central portion where the content of Al or Si is relatively low.Type: GrantFiled: January 10, 2008Date of Patent: February 14, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Sung-ho Park, Jin-seo Noh, Joong S. Jeon
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Patent number: 8089117Abstract: A desired property for a metal gate electrode layer is that it can cover a three-dimensional semiconductor structure having a microstructure with high step coverage. Another desired property for the metal gate electrode layer is that the surface of a deposited electrode layer is flat on a nanometer scale, enables a dielectric layer for electrical insulation to be coated without performing special planization after deposition of the electrode layer. Furthermore, another desired property for the metal gate electrode layer is that it has the similar etching workability to materials used in an ordinary semiconductor manufacturing process. Furthermore, another desired property for the metal gate electrode layer is that it has a structure in which diffusion of impurity is suppressed due to homogeneity thereof and the absence of grain boundaries.Type: GrantFiled: August 22, 2006Date of Patent: January 3, 2012Assignee: National Institute of Advanced Industrial Science and TechnologyInventor: Takashi Shimizu
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Patent number: 8076735Abstract: A semiconductor device and a method for fabricating the same are described. A polysilicon layer is formed on a substrate. The polysilicon layer is doped with an N-type dopant. A portion of the polysilicon layer is then removed to form a plurality of dummy patterns. Each dummy pattern has a top, a bottom, and a neck arranged between the top and the bottom, where the width of the neck is narrower than that of the top. A dielectric layer is formed on the substrate to cover the substrate disposed between adjacent dummy patterns, and the top of each dummy pattern is exposed. Thereafter, the dummy patterns are removed to form a plurality of trenches in the dielectric layer. A plurality of gate structures is formed in the trenches, respectively.Type: GrantFiled: October 2, 2009Date of Patent: December 13, 2011Assignee: United Microelectronics Corp.Inventor: Chun-Hsien Lin
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Patent number: 8053849Abstract: Thin effective gate oxide thickness with reduced leakage for replacement metal gate transistors is achieved by forming a protective layer between the gate oxide layer and metal gate electrode, thereby reducing stress. Embodiments include forming a protective layer of amorphous carbon containing metal carbides decreasing in concentration from the metal gate electrode toward the gate oxide layer across the protective layer. Embodiments of methodology include removing the removable gate, depositing a layer of amorphous carbon on the gate oxide layer, forming the metal gate electrode and then heating at an elevated temperature to diffuse metal from the metal gate electrode into the amorphous carbon layer, thereby forming the metal carbides. Embodiments also include metal gate transistors with a gate oxide layer having a high dielectric constant and silicon concentrated at the interfaces with the metal gate electrode and substrate.Type: GrantFiled: November 9, 2005Date of Patent: November 8, 2011Assignee: Advanced Micro Devices, Inc.Inventors: James Pan, John Pellerin
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Patent number: 8039887Abstract: A non-volatile semiconductor storage device includes: a semiconductor substrate; a source region and a drain region formed in the semiconductor substrate so as to be separated from each other; a first insulating film formed between the source region and the drain region, on the semiconductor substrate; a floating electrode formed on the first insulating film and including a semiconductor conductive material layer having extension strain; a second insulating film formed on the floating electrode; and a control electrode formed on the second insulating film. The extension strain of the floating electrode becomes gradually small as the location advances from the second insulating film toward the first insulating film, and the floating electrode has extension strain of 0.01% or more at an interface between the floating electrode and the second insulating film, and has extension strain less than 0.01% at an interface between the floating electrode and the first insulating film.Type: GrantFiled: May 5, 2010Date of Patent: October 18, 2011Assignee: Kabushiki Kaisha ToshibaInventors: Masumi Saitoh, Ken Uchida
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Publication number: 20110210405Abstract: The present invention provides a metal nitride film that realizes an intended effective work function (for example, a high effective work function) and has EOT exhibiting no change or a reduced change, a semiconductor device using the metal nitride film, and a manufacturing method of the semiconductor device. The metal nitride film according to an embodiment of the present invention contains Ti, Al and N, wherein the metal nitride film has such molar fractions of Ti, Al and N as (N/(Ti+Al+N)) of 0.53 or more, (Ti/(Ti+Al+N)) of 0.32 or less, and (Al/(Ti+Al+N)) of 0.15 or less.Type: ApplicationFiled: February 28, 2011Publication date: September 1, 2011Applicant: CANON ANELVA CORPORATIONInventors: Takashi Nakagawa, Naomu Kitano
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Patent number: 8003503Abstract: A method of forming a semiconductor device includes providing a dielectric film on a substrate, depositing a metal-containing gate electrode film over the dielectric film, and modifying a surface layer of the metal-containing gate electrode film by exposing the metal-containing gate electrode film to a process gas containing an oxygen-containing gas, a nitrogen-containing gas, or an oxygen- and nitrogen-containing gas, where a thickness of the modified surface layer is less than a thickness of the metal-containing gate electrode film. The method further includes, heat-treating the modified metal-containing gate electrode film to form a stressed metal-containing gate electrode film that exhibits stress over the substrate.Type: GrantFiled: September 30, 2010Date of Patent: August 23, 2011Assignee: Tokyo Electron LimitedInventor: Robert D Clark
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Patent number: 7968956Abstract: A semiconductor device includes a semiconductor substrate, a p-channel MIS transistor formed on the substrate, the p-channel transistor having a first gate dielectric formed on the substrate and a first gate electrode layer formed on the first dielectric, and an n-channel MIS transistor formed on the substrate, the n-channel transistor having a second gate dielectric formed on the substrate and a second gate electrode layer formed on the second dielectric. A bottom layer of the first gate electrode layer in contact with the first gate dielectric and a bottom layer of the second gate electrode layer in contact with the second gate dielectric have the same orientation and the same composition including Ta and C, and a mole ratio of Ta to a total of C and Ta, (Ta/(Ta+C)), is larger than 0.5.Type: GrantFiled: February 19, 2009Date of Patent: June 28, 2011Assignee: Kabushiki Kaisha ToshibaInventors: Kosuke Tatsumura, Masakazu Goto, Reika Ichihara, Masato Koyama, Shigeru Kawanaka, Kazuaki Nakajima
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Publication number: 20110147858Abstract: The invention relates to integrated circuit fabrication, and more particularly to a Field Effect Transistor with a low resistance metal gate electrode. An exemplary structure for a gate electrode for a Field Effect Transistor comprises a lower portion formed of a first metal material having a recess and a first resistance; and an upper portion formed of a second metal material having a protrusion and a second resistance, wherein the protrusion extends into the recess, wherein the second resistance is lower than the first resistance.Type: ApplicationFiled: December 21, 2009Publication date: June 23, 2011Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Peng-Soon LIM, Da-Yuan Lee, Kuang-Yuan Hsu
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Patent number: 7919795Abstract: Provided are a wire structure, a method for fabricating a wire, a thin film transistor (TFT) substrate and a method for fabricating a TFT substrate. The wire structure includes a barrier layer formed on a substrate and including copper, copper solid solution layer.Type: GrantFiled: December 20, 2007Date of Patent: April 5, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Je-Hun Lee, Chang-Oh Jeong, Eun-Guk Lee, Do-Hyun Kim
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Patent number: 7880243Abstract: FET device structures are disclosed with the PFET and NFET devices having high-k dielectric gate insulators and metal containing gates. The metal layers of the gates in both the NFET and PFET devices have been fabricated from a single common metal layer. Due to the single common metal, device fabrication is simplified, requiring a reduced number of masks. Also, as a further consequence of using a single layer of metal for the gates of both type of devices, the terminal electrodes of NFETs and PFETs can be butted to each other in direct physical contact. Device thresholds are adjusted by the choice of the common metal material and oxygen exposure of the high-k dielectric. Threshold values are aimed for low power consumption device operation.Type: GrantFiled: August 7, 2007Date of Patent: February 1, 2011Assignee: International Business Machines CorporationInventors: Bruce B. Doris, Eduard Albert Cartier, Barry Paul Linder, Vijay Narayanan, Vamsi Paruchuri
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Publication number: 20110012205Abstract: A metal gate structure is disclosed. The metal gate structure includes: a semiconductor substrate having an active region and an isolation region; an isolation structure disposed in the isolation region; a first gate structure disposed on the active region; and a second gate structure disposed on the isolation structure, wherein the height of the second gate structure is different from the height of the first gate structure.Type: ApplicationFiled: September 24, 2010Publication date: January 20, 2011Inventors: Chien-Ting Lin, Che-Hua Hsu, Li-Wei Cheng