Plural Step Coagulating Or Regenerating Patents (Class 264/196)
  • Patent number: 8741197
    Abstract: The invention provides an antimicrobial, antifungal and antiviral polymeric material, comprising rayon fibers and a single antimicrobial, antifungal and antiviral component consisting essentially of microscopic water insoluble particles of copper oxide incorporated in said fibers wherein a portion of said particles in said fibers are exposed and protruding from the surface of the fibers and wherein said particles release Cu++ when exposed to water or water vapor.
    Type: Grant
    Filed: March 28, 2007
    Date of Patent: June 3, 2014
    Assignee: Cupron Inc.
    Inventor: Jeffrey Gabbay
  • Publication number: 20040238996
    Abstract: A filling material for use with pillows, comforters and other products includes a blend of down and Lyocell fiber. Various preparation, washing, drying, dedusting, and blending steps achieve the blended product. The filling material has various advantageous characteristics such as improved moisture management, improved support while maintaining softness and comfort, and all-natural and enhanced hypoallergenic performance.
    Type: Application
    Filed: January 16, 2004
    Publication date: December 2, 2004
    Inventor: Brandon Palmer
  • Patent number: 6720057
    Abstract: The invention described here concerns a process to permit the manufacture of a cellulose fibre from hydrate cellulose with an extremely large surface area which may be used for the preparation of a fabric characterized by a high absorptive power, good liquid-retention properties, high grease-solvent properties as well as particle-absorbing properties, which is suitable for making products that are themselves easy to clean, which can be used for cleaning and decontamination as well as to reduce the surface tension of water and which can be disposed of without damage to the environment.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: April 13, 2004
    Inventors: Achim Neumayr, Herbert Hasl
  • Patent number: 6596033
    Abstract: The invention is lyocell fiber characterized by a pebbled surface as seen at high magnification and having a variable cross section and diameter along and between fibers. The fiber is produced by centrifugal spinning, melt blowing or its spunbonding variation. The fibers can be made in the microdenier range with average weights as low as one denier or less. The fibers have inherently low gloss and can be formed into tight yarns for making fabrics of very soft hand. Alternatively, the fibers can be formed into self bonded nonwoven fabrics.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: July 22, 2003
    Assignee: Weyerhaeuser Company
    Inventors: Mengkui Luo, Vincent A. Roscelli, Amar N. Neogi, Richard A. Jewell
  • Patent number: 5795523
    Abstract: The present invention relates to an improved method for producing tubular sausage casings of regenerated cellulose wherein viscose is extruded through an annular extrusion die submerged in an aquarium to form a tubular product and coagulation and regeneration of the tubular product is initiated in said aquarium, continued by spray application of an intermediate regenerating solution in an intermediate regeneration zone after the tubular product has exited the aquarium, and completed in one or more coagulation/regeneration baths which includes the step of heating the tubular product to a temperature above the boiling point of carbon bisulphide in the intermediate reaction zone.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: August 18, 1998
    Assignee: Alfacel s.a.
    Inventor: Alexander Rozenberg
  • Patent number: 5783131
    Abstract: The present invention relates to an improved method for regenerating cellulosic sausage casings which includes the steps of extruding viscose through an annular extrusion die submerged in an aquarium to form a tubular product and partially gelling and coagulating the gel tubing in the aquarium, supporting the partially gelled and coagulated tubing on at least two upwardly moving inclined belt such that different sides of the casing are disposed in an upward facing orientation on the different belts and applying an intermediate regenerating solution to the tubing supported by the belts until it is partially cured, and conveying the partially cured tubing into at least one coagulation/regeneration bath which completes regeneration of the tubing.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: July 21, 1998
    Assignee: Alfacel s.a.
    Inventors: Alan David Stall, Luis Michelena Garcia
  • Patent number: 5776398
    Abstract: The invention provides methods for producing tubular sausage casings wherein regeneration of the interior portion of the viscose casing is initiated prior to regeneration of the exterior portion of the casing.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: July 7, 1998
    Assignee: Alfacel s.a.
    Inventors: Alan David Stall, Antonio Vitorero Miguelez
  • Patent number: 5741529
    Abstract: An adjustable reaction tub for making tubular cellulosic casings from viscose, the tub having upper rollers mounted to a frame and lower rollers on a roll support mounted to the same frame for adjustable positioning of the lower rollers at any of a range of depths within the tub.
    Type: Grant
    Filed: July 31, 1996
    Date of Patent: April 21, 1998
    Assignee: Alfacel s.a.
    Inventor: Alan D. Stall
  • Patent number: 5470519
    Abstract: A method of manufacturing a cellulosic article of cellulose or a cellulose derivative that has incorporated a polyethylene oxide composition having a molecular weight of at least 70,000.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: November 28, 1995
    Assignee: Viskase Corporation
    Inventor: John Markulin
  • Patent number: 5443776
    Abstract: The absorbency of regenerated viscose filaments is improved by overfeeding a continuous tow of partially regenerated filaments onto a moving foraminous support so that regeneration occurs prior to and after the filament tow is overfed onto the moving support.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: August 22, 1995
    Assignee: Courtaulds plc
    Inventors: Alan J. Bartholomew, Paul L. Probert, Michael Richardson, Andrew G. Wilkes
  • Patent number: 5422050
    Abstract: This invention provides reinforced composite structures consisting essentially of a matrix and a dispersed phase, where the matrix is a hydrogel containing water and a solubilized vinyl alcohol homopolymer, the dispersed phase contains a plurality of uniformly distributed acicular regions consisting of fibrils formed from a highly oriented crystalline vinyl alcohol polymer, where the diameter of the said fibrils is less than 1 millimeter, the aspect ratio of the fibrils is from 2:1 to 1000:1, and where the composite is characterized by a gradual transition in the degree of crystallinity at the interfaces between the matrix and the fibrils.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: June 6, 1995
    Assignee: Mizu Systems Inc.
    Inventors: Daniel Graiver, Arnold W. Lomas
  • Patent number: 5175196
    Abstract: A hollow fiber of amorphous, hydroxy-ethylated poly-(2,6-dimethyl-p-oxyphenylene) (PPO-OH) with a glass transition temperature (Tg) of from 180.degree. to 200.degree. C. is disclosed, which is formed by a high-density, microporous layer on a macroporous backing, and having an outer diameter comprised within the range of from 450 to 550 .mu.m and an inner diameter comprised within the range of from 250 to 400 .mu.m.The process for preparing the hollow fibre and the use of said fibre in the processes of separation of gas mixtures are disclosed as well.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: December 29, 1992
    Assignee: Eniricerche S.p.A.
    Inventors: Alessandro Stopponi, Claudio Demofonti, Claudio Valentini, Raffaello Sisto, Ugo Pedretti
  • Patent number: 4575376
    Abstract: Method for increasing the absorbency of cellulosic fibers by a high temperature wet treatment comprising heating the fibers in a water bath at temperatures within the range of about 95.degree. C. to 100.degree. C. for periods ranging from about one to sixty minutes. Absorbency of the treated fibers is thus increased by more than 2% of the corresponding untreated fibers as measured by the Syngyna Test Method. By employing such materials in catamenial tampons, sanitary napkins or the like, the amount of absorbent material may be decreased by 10% or more relative to the corresponding, untreated absorbent material, without adversely affecting the absorbent characteristics thereof.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: March 11, 1986
    Assignee: International Playtex
    Inventors: Shailesh Shah, David R. King, Nathan D. Field
  • Patent number: 4404157
    Abstract: Process for the continuous production of viscose rayon yarns having a high egree of whiteness, comprising extruding a viscose solution into a coagulating bath, drawing and coagulating the extruded filaments, advancing said filaments in a substantially helical path while they undergo all the treatments required for the production of the finished yarn, which process is characterized by, after the exit of the filaments from the spinning bath, completion of the coagulation to a coagulation index not higher than 1 and a treatment with water having a non-alkaline pH.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: September 13, 1983
    Assignee: SNIA VISCOSA Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Gianfranco Angelini, Novello Leoncini, Bice Pallesi, Ugo Paoletti
  • Patent number: 4383962
    Abstract: A viscose rayon filament yarn excellent in resistance to deterioration with time and uniform in boiling water shrinkage factor in the longitudinal direction of yarn which has been produced by a continuous spinning process characterized by spinning a viscose having a sulfur content of sulfur oxides and polysulfides of 0.55% by weight or less based on the weight of cellulose, then allowing the yarn to stand for a time period defined by the following equation and then washing it with water and drying it:7.5D.sub.M +15.ltoreq.T.sub.s .ltoreq.10D.sub.M +25wherein D.sub.M is denier of the monofilament constituting the rayon filament yarn to be spun and T.sub.s, expressed in second, is the standing time of the viscose filament spun.
    Type: Grant
    Filed: September 17, 1980
    Date of Patent: May 17, 1983
    Assignees: Asahi Kasei Kogyo Kabushiki Kaisha, Snia Viscosa S.p.A.
    Inventors: Yasuo Isome, Toshio Minami, Tadahiko Takahashi
  • Patent number: 4371491
    Abstract: A process is described for the continuous spinning of viscose rayon. Said ocess is characterized by the fact that after the coagulation and drawing of the yarn, a two-stage setting is carried out, the first stage being at higher temperature and acidity than the second stage. The two-stage setting permits one to obtain a yarn which is not only perfectly set but is also substantially desulphurated and the classic desulphuration operation is thus eliminated. The setting is followed by at least one washing and by the other conventional treatments, with the exception of the desulphuration. The viscose rayon continuous spinning process is carried out while the yarn travels in a substantially helical path.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: February 1, 1983
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Tommaso Benai, Novello Leoncini, Ugo Paoletti
  • Patent number: 4361532
    Abstract: A process is provided herein for continuously spinning viscose yarns by euding viscose into a coagulating bath to form filaments and partially coagulating these filaments to a coagulation index of between 15 and 18, while concurrently stretching said filaments to the desired stretch ratio and then subjecting the filaments to a 2-stage coagulation treatment in which (1) the filaments are advanced without further chemical treatment onto e.g. a first advancing roller where partial spontaneous coagulation occurs such that the coagulation index is between 5 and 8 and (2) a second stage coagulation which comprises contacting the filaments with an acid bath at a temperature between 50.degree. and 100.degree. C. until complete coagulation occurs such that the coagulation index is between 0 and 1.The aforementioned process permits the spinning operation to occur at a much greater speed than was hitherto possible without increasing dimensions of the treatment zones or apparatus.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: November 30, 1982
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Tommaso Benai, Ugo Paoletti, Novello Leoncini
  • Patent number: 4314959
    Abstract: A process for the preparation of regenerated cellulose shaped bodies from inning dopes comprising solutions of methylol derivatives of cellulose in organic solvent selected from dimethylformamide, dimethylacetamide, dimethylsulphoxide and N-methyl-pyrrolidone is described. The cellulose derivative is coagulated from the spinning dope in a coagulating bath, the main component of which is a high-boiling alcohol capable of reacting with the free (para)formaldehyde and with the bound (para)formaldehyde of the methylol derivative to a degree varying with the temperature. It is possible to prepare filaments and yarns having excellent characteristics by starting from solutions having high CH.sub.2 O and cellulose concentrations and high MS ratios.
    Type: Grant
    Filed: April 21, 1980
    Date of Patent: February 9, 1982
    Assignee: SNIA Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Roberto Leoni, Alberto Baldini, Angelo Calloni, Gianfranco Angelini
  • Patent number: 4255101
    Abstract: A device for the continuous spinning of viscose rayon includes a main or cessing roller and a plurality of secondary or advancing rollers set askew with respect to the processing roller. The processing and advancing rollers are carried bracket-like by a support arm in which they are rotatively supported. The actuating structures are located in the vicinity of the supports of the respective rollers. The support arm is hollow and contains the roller supports and the actuating structures, and is located at the end of the unit at which the yarns leave the same after being processed. A plurality of spinning units are arranged in rows and the rows are born by a frame carrying all the necessary accessory devices. Means are provided for preventing the escape of fumes from the treatment liquors into the surrounding room.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: March 10, 1981
    Assignee: SNIA Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Ugo Paoletti, Alessandro Volterra
  • Patent number: 4045532
    Abstract: A continuous process for producing viscose yarn including feeding a viscose solution through spinneret dies into a spinning bath to spin viscose yarn, and finally regenerating and concurrently cooling the spun yarn, now carrying entrapped carbon bisulfide in the form of an emulsion, from said spinning bath at a temperature below the boiling point of the carbon bisulfide. Thereafter, while maintaining the finally regenerated yarn in a cooled condition, washing the yarn with water whereby some water, in addition to the carbon bisulfide, becomes entrapped in the yarn, subjecting the washed yarn to avivage treatment, and finally drying the resulting yarn at an elevated temperature sufficient to concurrently remove both the entrapped water and the carbon bisulfide from the yarn. Thereafter, the resulting dried and carbon bisulfide-free yarn is wound into a package.
    Type: Grant
    Filed: October 29, 1974
    Date of Patent: August 30, 1977
    Inventors: Arkady Trofimovich Serkov, Gennady Alfeevich Budnitsky, Boris Matveevich Sokolovsky, Vyacheslav Kapitonovich Lezhnev
  • Patent number: 4018681
    Abstract: Cellulosic solutions are filtered by a process enabling virtual complete recovery and recycling of the undissolved cellulosic components of the solutions. The process comprises filtering the solution through a bed of particulate material until the build-up of undissolved material impedes the further flow of solution through the bed, mixing the undissolved material and particulate bed with a solvent to partially dissolve the undissolved material, which is highly concentrated relative to its original concentration before filtration, adding a solubilizing reactant to said concentrated partial solution of undissolved material to complete the solution of the cellulosic residues, and separating and recycling the resulting solution.
    Type: Grant
    Filed: November 12, 1975
    Date of Patent: April 19, 1977
    Assignee: International Telephone and Telegraph Corporation
    Inventors: Edmund M. LaPolla, Charles F. Murphy, Arthur Sarkisian