Liquid Is Solvent Extractive Patents (Class 264/203)
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Patent number: 11958790Abstract: The invention is directed to a co-layered propellant grain having an exposed outer surface, wherein said propellant grain comprises an outer layer comprising a slow burning propellant composition located on essentially the entire outer surface of the grain, and an inner layer comprising a fast burning propellant composition having a higher linear burn rate than said slow burning propellant composition; wherein said propellant grain has a structure such that after ignition, the inner layer becomes increasingly exposed at the outer surface.Type: GrantFiled: August 20, 2018Date of Patent: April 16, 2024Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNOInventors: Christoffel Adrianus Van Driel, Martijn Zebregs, Dinesh Ravindre Ramlal, Michiel Hannes Straathof
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Patent number: 11946165Abstract: A method for producing solid cellulose filaments from a fluid of the cellulose by extruding the fluid through a plurality of extrusion openings, whereby fluid filaments are produced, and solidifying the filaments in a coagulation bath, the filaments being bundled in the coagulation bath and being deflected as a bundle in order to be drawn from the coagulation bath above the coagulation bath level, the bundle of filaments assuming a deflection width on a deflecting device, which deflection width is defined in accordance with a formula. A device therefor is also provided.Type: GrantFiled: August 30, 2019Date of Patent: April 2, 2024Assignee: AUROTEC GMBHInventors: Stefan Zikeli, Friedrich Ecker
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Patent number: 11873580Abstract: The present invention provides a process for the viable removal of liquid from lyocell cellulose continuous filament yarns at very high production speeds.Type: GrantFiled: December 20, 2019Date of Patent: January 16, 2024Assignee: LENZING AKTIENGESELLSCHAFTInventors: Johann Pillichshammer, Christoph Schrempf, Andreas Gressenbauer, Ernst Reiter, Martin Neunteufel
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Patent number: 11867491Abstract: Ammunition cartridge comprising a rigid casing including a tubular sleeve and a base closing an end of the casing, a projectile mounted at another end of the casing, a propellant charge contained inside the casing, and an ignition device. The ignition device comprises an ignition charge arranged to ignite the propellant charge at a point of ignition distal from the base and proximal the projectile.Type: GrantFiled: September 14, 2021Date of Patent: January 9, 2024Inventor: Albert Gaide
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Patent number: 11585015Abstract: The invention relates to a process for the production of polymer fibers from polymers dissolved in ionic liquids by means of an air gap spinning process, characterized in that a) a spinning solution that contains an ionic liquid and a dissolved polymer is produced; b) said spinning solution is guided through an extruder before it is divided into fibers via a die; and c) the obtained fibers are guided via an air gap through a coagulation bath.Type: GrantFiled: February 1, 2017Date of Patent: February 21, 2023Assignee: DEUTSCHE INSTITUTE FUR TEXTIL-UND FASERFORSCHUNG DENKENDORFInventors: Falko Abels, Tomasz Cwik, Ronald Beyer, Frank Hermanutz
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Patent number: 11519101Abstract: Method of manufacturing a regenerated cellulosic molded body, wherein the method comprises supplying a starting material which comprises cellulose and at least one foreign matter, transferring at least a part of the starting material with at least a part of the at least one foreign matter into a spinning mass which additionally contains a solvent for solving at least a part of the cellulose of the starting material in the solvent, and extruding the spinning mass to the molded body, and subsequently precipitating in a spinning bath, wherein thereby the molded body is obtained, wherein the molded body comprises cellulose and at least a part of the at least one foreign matter.Type: GrantFiled: January 14, 2019Date of Patent: December 6, 2022Assignee: LENZING AKTIENGESELLSCHAFTInventors: Christoph Klaus-Nietrost, Richard Herchl, Christian Weilach
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Patent number: 11406172Abstract: A toothbrush head, including at least one two-component cleaning element and at least one bristle tuft element, is produced by injection molding. To achieve high design flexibility regarding the arrangement of the two-component cleaning elements and regarding the material choice, the two-component cleaning elements are manufactured separately or in an upstream molding step. Then the two-component cleaning elements, together with the bristle tufts, are over-molded with plastic material, to form the brush head or a part thereof.Type: GrantFiled: June 27, 2017Date of Patent: August 9, 2022Assignee: The Procter & Gamble CompanyInventors: Stefan Scheurich, Uwe Tretrop, Ulrich Stoerkel
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Patent number: 10800080Abstract: A tape-shaped product and a belt for a ball chain are provided. A tape-shaped product of synthetic resin includes a tape of a thermoplastic resin, and a preliminarily stretched fibrous member of a thermoplastic resin contained therein along longitudinally parallel edges or in proximity thereto of the tape. A belt for a ball chain, includes a tape-shaped product of synthetic resin formed by injection molding, together with a fibrous member as an insert of a resin of the same kind as that of the fibrous member so that the fibrous member is disposed along the longitudinal edges or in proximity thereto, ball-insetting holes are disposed at equal intervals, and ball-retaining projections are disposed around the holes.Type: GrantFiled: March 17, 2016Date of Patent: October 13, 2020Assignee: THK CO., LTD.Inventors: Nobuyuki Masumura, Kazuki Tomita, Akira Tochigi, Yuji Kokuno, Seiichi Ohira, Hidekazu Michioka, Katsuya Iida
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Patent number: 10767279Abstract: The present invention relates to a method of preparing wear and cut resistant UHMWPE fibers. In the method, a resin material is added into a ball grinder, and the temperature is controlled, and then a mother liquor is added slowly into the ball grinder and mixed uniformly, and the mixed solution is vacuumed in a sealed container for several hours and extruded by a twin screw extruder, a metering pump, and a spin beam, and finally processed with drafting and hot drawing and winding formation. The fiber so manufactured has the features of soft touch and comfortable wearing.Type: GrantFiled: February 8, 2018Date of Patent: September 8, 2020Assignee: ZHEJIANG JINHAO NEW MATERIALS CO., LTD.Inventors: Jianfang Zhang, Xinwei Wang, Yongfei Sun, Shuiyao Liu, Wenlan Gong, Wenjun Wen
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Patent number: 10655245Abstract: A metal oxide macroscopic fiber and a preparation method thereof, the method including: adding, as a spinning dope, an anionic metal oxide aqueous colloidal solution into wet spinning equipment, extruding the spinning dope from the spinning equipment into a thread, injecting the extruded thread into a coagulating bath containing a flocculating agent to obtain as-spun fiber, and repeatedly washing the resulted as-spun fiber with deionized water and drying same, thereby obtaining a metal oxide fiber. Said method makes the process simple and controllable, being adaptable to production on a large scale. The prepared metal oxide fiber having special physical and chemical properties is widely applicable in terms of intelligent spinning, biomedicine, energy recycling and conversion, and the field of microelectronic devices and the like.Type: GrantFiled: September 16, 2015Date of Patent: May 19, 2020Assignee: SOOCHOW UNIVERSITYInventors: Fengxia Geng, Junyu Hou, Yuanchuan Zheng
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Patent number: 10604897Abstract: This invention relates to the use of Lyocell fibers with a tendency to fibrillate for the manufacture of a nonwoven fibrous web material, in particular for the use in a wipe, by using a foam technique.Type: GrantFiled: February 29, 2016Date of Patent: March 31, 2020Assignee: Lenzing AktiengesellschaftInventors: Gisela Goldhalm, Thomas Maier, Gert Kroner
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Patent number: 10570565Abstract: The present invention relates to fibrillated lyocell fibers which have a fibrillation quotient Q of 20 or more and whose content of microfibers with a fineness of less than 14 mesh and a diameter of less than 2 ?m is at least 50%, as well as the use thereof for producing a wipe, which contains pulp and 5 to 20 wt. % of fibrillated lyocell fibers.Type: GrantFiled: May 29, 2015Date of Patent: February 25, 2020Assignee: Lenzing AktiengesellschaftInventors: Johann Männer, Rudolf Aigner, Jim Gannon, Matt Riley
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Patent number: 10519605Abstract: Methods for marking cellulosic products, including cellulosic fibers such as lyocell and cellulosic films, including methods for marking such products with a detectable nucleic acid marker to identify and validate the origin or authenticity of the products or items manufactured using such products. Detectably-marked cellulosic products marked with nucleic acid markers for authentication, validation and tracking are also provided.Type: GrantFiled: March 22, 2017Date of Patent: December 31, 2019Assignee: APDN (B.V.I.), Inc.Inventors: Lawrence Jung, Michael E. Hogan, Ming Hwa Benjamin Liang
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Patent number: 9963820Abstract: The invention concerns a cellulose fiber of the genus Lyocell which is treated with a cross-linking agent, with the cross-linking agent inducing a protection from fibrillation on the fiber and exhibiting the following properties: the protection from fibrillation induced by the cross-linking agent changes if the fiber is stored within a pH range from 4.0 to 10.0, in particular under the influence of moisture and/or heat, within the pH range from 4.0 to 10.0, an optimum value exists at which the stability of the protection from fibrillation induced by the cross-linking agent during storage is highest a suitable range exists around the optimum value in which the stability is reduced by 20% at the most, compared to the stability at the optimum value, within the pH range from 4.0 to 10.Type: GrantFiled: June 18, 2009Date of Patent: May 8, 2018Assignee: Lenzing AktiengesellschaftInventors: Heidrun Fuchs, Peter Dobson
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Patent number: 9833509Abstract: The subject matter described herein is directed to articles, compositions, systems, and methods of using and preparing bioceramic compositions and to the bioceramic compositions. A bioceramic composition of the disclosure radiates infrared energy or rays and can be used in the treatment of various conditions.Type: GrantFiled: May 1, 2015Date of Patent: December 5, 2017Assignee: MULTIPLE ENERGY TECHNOLOGIES LLCInventors: Shannon Vissman, Francisco Jose Cidral-Filho, Francisco de Paula Moreira, Steven Midttun
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Patent number: 9765447Abstract: Processes for preparing ultra-high molecular weight polyethylene (“UHMW PE”) filaments and multi-filament yarns, and the yarns and articles produced therefrom. Each process produces UHMW PE yarns having tenacities of 45 g/denier to 60 g/denier or more at commercially viable throughput rates.Type: GrantFiled: October 26, 2015Date of Patent: September 19, 2017Assignee: HONEYWELL INTERNATIONAL INC.Inventors: Thomas Tam, John Armstrong Young, Ralf Klein, Mark Tallent, Henry Gerard Ardiff
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Patent number: 9655491Abstract: A method of cleaning residue from a surface. A disposable cellulosic wiper is provided that includes a percentage by weight of pulp-derived papermaking fibers, and from about 10% to about 75% by weight of fibrillated regenerated independent cellulosic microfibers having a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml and having a weight average diameter of less than about 2 microns. The wiper is applied, with a predetermined amount of pressure, to a residue-bearing surface. The surface is wiped with the applied wiper, while applying the predetermined amount of pressure, to remove residue from the surface, such that the surface has less than 1 g/m2 of residue after being wiped under the predetermined amount of pressure with the applied wiper.Type: GrantFiled: April 13, 2016Date of Patent: May 23, 2017Assignee: Georgia-Pacific Consumer Products LPInventors: Daniel W. Sumnicht, Joseph H. Miller
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Patent number: 9586341Abstract: Methods are provided for reducing one or more dimensions of individual pieces of biomass; treating biomass, such as size-reduced biomass; changing a molecular structure of a biomass material; and, optionally, subjecting the biomass to a primary process to form a product. The methods include processing biomass materials using a screw extrusion process, and treating the biomass material with a screw extrusion process in size-reduction and treating steps.Type: GrantFiled: March 1, 2016Date of Patent: March 7, 2017Assignee: XYLECO, INC.Inventor: Marshall Medoff
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Patent number: 9334592Abstract: The present invention relates to a process for the production of a hydroentangled product comprising cellulose fibers, wherein a Lyocell melt-blown web is subjected to a treatment by fine high-pressure jets of water, characterized in that the web is subjected to said fine high-pressure jets in at least three treatment steps the pressure of said high-pressure jets is 75 bar or less in each of said treatment steps. Furthermore, the invention relates to products obtainable by said products, and uses thereof.Type: GrantFiled: October 10, 2008Date of Patent: May 10, 2016Assignee: Lenzing AktiengesellschaftInventors: Pat White, Haio Harms, Malcolm Hayhurst
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Patent number: 9103069Abstract: The present invention is directed towards a method for spinning neutral or anionically modified cellulose comprising the steps of: (a) preparing a suspension of the neutral or anionically modified cellulose in a continuous phase; (b) subjecting the suspension to high shear rate; (c) performing spinning by extruding the cellulose suspension into an airgap region comprising at least one heated zone to obtain spun fibers, (d) subjecting the spun fibers to at least one washing stages and (e) isolating the spun fibers from the at least one washing stages; as well as fibers obtained based on the method of the invention and paper or board products derived from such fibers.Type: GrantFiled: March 8, 2012Date of Patent: August 11, 2015Assignee: SAPPI Netherlands Services B.V.Inventors: Ian Graveson, Philip Turner
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Publication number: 20150119545Abstract: Provided is a method of fabricating a thermal conductive polymer, including: a) fabricating a gel filament by primarily elongating a solution filament formed by spinning a mixed solution containing an ultra high molecular weight polyolefin (UHMWPO) resin and a first solvent, followed by cooling; b) secondarily elongating the gel filament; c) fabricating a dry filament by removing the solvent from the gel filament, followed by tertiary elongation; and d) converting the dry filament into the gel filament by adding the first solvent to the dry filament; e) removing the first solvent from the converted gel filament; and f) quaternarily elongating the gel filament from which the first solvent is removed.Type: ApplicationFiled: October 29, 2014Publication date: April 30, 2015Inventors: Yongrak MOON, Kangmin JUNG
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Patent number: 9011739Abstract: Methods for making high quality polyimide fibers suitable for continuous industrial production are described. Polyimide fibers are continuously prepared from a polyamic acid solution through sequentially spinning the polyamic acid solution by either a wet or a dry-wet process, coagulating, drying or drying after washing, thermally treating and stretching the resulting polyamic acid fibers to obtain polyimide fibers, and winding polyimide fibers as prepared into rolls.Type: GrantFiled: February 17, 2012Date of Patent: April 21, 2015Assignee: Beijing University of TechnologyInventors: Dezhen Wu, Hongqing Niu, Shengli Qi, Enlin Han, Xiaona Yan, Guofeng Tian, Xiaodong Wang
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Patent number: 8926712Abstract: A solvent spun bamboo fiber with a high wet modulus and a producing method thereof are disclosed. The producing method includes: activating by adding a bamboo pulp into de-ionized water, adjusting the pH value, adding cellulase and adjusting the pH value by adding alkali; squeezing by vacuum dehydration; pre-dissolving by adding an aqueous solution containing 50-88% by mass of N-methylmorpholine-N-oxide; then dissolving by putting the above pre-dissolved mixture into a dissolver, heating, vacuumizing, dehydrating, dissolving, homogenizing and defoaming; spinning by spraying through a spinneret and forming a bamboo fiber by dry-wet spinning; water washing; bleaching; oiling; and drying. The present method is simple to operate, free of industrial pollution, low energy consuming, and highly safe. The bamboo fiber produced by the present method not only keeps the natural physical and chemical properties of bamboo fiber, but also has a high wet modulus without harmful chemical residues.Type: GrantFiled: September 7, 2010Date of Patent: January 6, 2015Assignee: Shanghai Lyocell Fibre Development Co., Ltd.Inventors: Kun Jiang, Xiaoliang Wang, Changli Zhu, Xin Wang, Dianhai Zheng
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Patent number: 8889049Abstract: An improved process for solution spinning of ultra-high molecular weight polyethylene (UHMW PE) filaments, wherein the 10 wt % solution of the UHMW PE in mineral oil at 250° C. has a Cogswell extensional viscosity and a shear viscosity within select ranges.Type: GrantFiled: April 30, 2010Date of Patent: November 18, 2014Assignee: Honeywell International IncInventors: Thomas Y. Tam, John A. Young, Qiang Zhou, Conor J. Twomey, Charles Arnett
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Patent number: 8858851Abstract: The present invention discloses a process for producing low-titer, high-strength and high-modulus polyethylene fibers, comprising the following steps: dissolving the ultra-high molecular weight polyethylene into paraffin oil with a low viscosity to form a spinning solution with a concentration of 3˜15%; extruding the spinning solution through a thin spinneret with at least 10 orifices having a diameter ? of 0.7˜0.8 mm and a length/diameter ratio of 10˜12, by applying a high pressure in the range of 2.5±1.0 MPa to the spinning solution, such that the fluid in the orifices is extruded at a shear rate of 200˜3 500 sec?1; and then performing a jet stretch at a deformation rate of 200˜5 000 min?1 within an air-gap of 10˜15 mm between the spinneret and the quench bath surface; feeding the jet-stretched fluid into the quench bath to form gel filaments; extracting and drying the gel filaments; and performing a multistage ultrahigh post stretch on the dried gel filaments with a stretch ratio of 15 or less.Type: GrantFiled: September 11, 2008Date of Patent: October 14, 2014Assignee: Hunan Zhongtai Special Equipment Co., Ltd.Inventors: Nianci Yang, Yuanjun Zhang, Bo Gao, Zhiquan Wu, Mingqing Lin, Chuanqing Wu, Yong Guo, Yunbo Zhou, Haijun Lin
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Publication number: 20140291887Abstract: A polymeric fiber for use in gas separation is formed from a spin dope which includes solvent and non-solvent materials. The fiber is passed through a quench bath, and then a leach bath, in which the solvent and non-solvent are removed. The quench bath and the leach bath include sets of rollers which transport the fiber through the system. Each set of rollers in the leach bath operates at a speed which is greater than or equal to the speed of the rollers which are immediately upstream. Thus, the fiber is stretched, in different amounts, at the same time that the solvent and non-solvent are being removed, and while the fiber is still wet. The resulting fiber has been found to exhibit superior flux and selectivity properties.Type: ApplicationFiled: March 28, 2014Publication date: October 2, 2014Applicant: Generon IGS, Inc.Inventors: Frederick L. Coan, Arthur J. Barajas, Jeff C. Schletz
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Patent number: 8790556Abstract: A spinneret having tri-arc holes may be used to produce tri-arc filaments. In some instances, tri-arc holes have a Y-shape with three prongs and each prong having an arc at the end of the prong that tapers from the end of the arc to a connection point of an adjacent arc, and tri-arc filaments have a generally-Y shape cross-section with bulbous or arcing tips. Further, tri-arc filaments may be useful in a plurality of applications including, but not limited to, filters, filters comprising particulate additives, and smoking device filters.Type: GrantFiled: July 25, 2012Date of Patent: July 29, 2014Assignee: Celanese Acetate LLCInventors: Christopher M. Bundren, Lawton E. Kizer, Denis G. Fallon, Lixin Xue
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Publication number: 20140186715Abstract: A method for manufacturing a polyolefin-based porous separator includes forming a sheet containing a polyolefin-based resin and a diluent, extracting the diluent from the sheet by using an extracting apparatus, and forming a separator by drying the extracted sheet using a drying apparatus provided with an inlet. The shortest distance between an outlet of the extracting apparatus and an inlet of the drying apparatus may be 100 mm or less.Type: ApplicationFiled: December 28, 2013Publication date: July 3, 2014Inventors: Jung Seong LEE, Kee Wook KIM, Sang Ho LEE, Yong Bae LEE, Jung Sue JANG, Jun Ho CHUNG, Jae Hyun CHO
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Patent number: 8734567Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: GrantFiled: April 29, 2013Date of Patent: May 27, 2014Assignee: Chevron U.S.A. Inc.Inventor: Shabbir Husain
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Patent number: 8623245Abstract: A colored high strength polyethylene fiber, preparation method and use thereof are provided, which are in the high molecular material field. The surface of said high strength polyethylene fiber is chromatic, grey or black. The strength of said high strength polyethylene fiber is 15-50 g/d, its modulus is 400-2000 g/d. The product of the present invention is colored, so it can be well applied to civil and military field. The preparation method of present invention has some advantages that technological process is simple, production efficiency is high, cost of production is low, performance of made fiber is excellent, and use-cost is reduced, compared with the prior art.Type: GrantFiled: July 14, 2008Date of Patent: January 7, 2014Assignee: Shandong ICD High Performance Fibres Co., Ltd.Inventor: Yi Ren
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Patent number: 8617354Abstract: Provided is a process for manufacturing shaped cellulose materials from lignocellulose where a dissolving grade pulp is manufactured and dissolved in an aqueous alkaline or acidic solvent system forming a solution suitable for shaping new cellulose structures including fibers, films and cellulose derivatives. At least a part of the spent cellulose dissolving or cellulose shaping chemicals are recovered in one or more unit operations in a pulp mill chemical recovery cycle.Type: GrantFiled: March 8, 2010Date of Patent: December 31, 2013Assignee: Kiram ABInventor: Lars Stigsson
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Patent number: 8608998Abstract: A process for stripping chemically bonded spinning solvent from a solution-spun nonwoven web comprising the steps of providing a nonwoven web comprising solvent-laden polymeric fibers having average fiber diameters of less than about 1 micrometer, and transporting the nonwoven web through at least one infrared solvent stripping station wherein infrared radiation irradiates the nonwoven web in the absence of a solvent stripping fluid impinging on the nonwoven web in order to reduce the solvent concentration of the fibers to less than about 10,000 ppmw.Type: GrantFiled: July 9, 2008Date of Patent: December 17, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Christel Berta Laxton, B. Lynne Wiseman, Christopher William Newton, Simon Frisk
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Patent number: 8512627Abstract: The present invention provides a method for the production of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) asymmetric hollow fiber membrane. The invention comprises preparing a dope solution of PVDF-HFP with an additive of lithium chloride or glycerol dissolved in a solvent such as N-methylpyrollidone (NMP). The dope solution is spun to form a PVDF-HFP asymmetric hollow fiber membrane.Type: GrantFiled: February 4, 2009Date of Patent: August 20, 2013Assignee: Nanyang Technological UniversityInventors: Rong Wang, David Tee Liang, Joo Hwa Tay
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Patent number: 8449651Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: GrantFiled: August 25, 2010Date of Patent: May 28, 2013Assignee: Chevron U.S.A. Inc.Inventor: Shabbir Husain
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Patent number: 8420005Abstract: The present invention provides a meltblown wetlaid method for producing non-woven fabrics with anti-mildew, anti-bacteria and deodorizing capabilities from natural cellulose. The method comprises selecting wood pulp as raw material and using N-methylmorpholine N-oxide (NMMO) as dissolving solvent and 1,3-phenylene-bis 2-oxazoline (BOX) as stabilizer to form mixed cellulose mucilage as well as using modified and nano-miniaturized natural chitosan as additive for blending and dissolution to form cellulose dope. By meltblown method, the dope is extruded out of spinnerets to form filament bundle, then by ejecting mist aerosol of water, the filament bundle is coagulated with regeneration. After post treatments of water rinsing, hydro-entangled needle punching, drying, winding-up and the like having been orderly applied, then final product for nonwoven fabric of continuous filament with anti-mildew, anti-bacteria and deodorizing capabilities is produced.Type: GrantFiled: September 10, 2010Date of Patent: April 16, 2013Assignee: Acelon Chemical and Fiber CorporationInventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
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Patent number: 8420004Abstract: The present invention provides a meltblown wetlaid method for producing non-woven fabrics from natural cellulose using pulp as raw material and N-methylmorpholine N-oxide (NMMO) as solvent for dissolving into dope. The dope is then extruded out of a spinneret to form filament bundle by meltblown method. Subsequently, by means of ejecting mist aerosol of water, the filament bundle is coagulated with regeneration. Via post treatments of water rinsing, hydro-entangled needle punching, drying, winding-up and the like have been orderly applied, then final product of nonwoven fabrics with continuous filament are produced from natural cellulose.Type: GrantFiled: August 27, 2010Date of Patent: April 16, 2013Assignee: Acelon Chemical and Fiber CorporationInventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
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Patent number: 8394306Abstract: A method for producing a thermoplastic resin micro-porous film wherein a thermoplastic resin and a solvent (A) are melted and kneaded together to prepare a solution, the solution is extruded and cooled to prepare a formed product in a gel state, and the residual solvent (A) is removed from the formed product, characterized in that in the step of removing the solvent (A) use is made of a non-aqueous solvent (B) which is compatible with the solvent (A) and not compatible with the thermoplastic resin, and has a boiling point of 100° or higher and a flashing point of 0° or higher. The use of the non-aqueous solvent (B) provides a production method which allows the removal of a solvent with good efficiency and also with the reduction of a fear of environmental pollution and catching fire.Type: GrantFiled: June 28, 2001Date of Patent: March 12, 2013Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Mitsuhiro Nishida, Kohtaro Kimishima, Sadakatsu Suzuki
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Patent number: 8383026Abstract: One or more embodiments relates to the production of a fabricated fiber having an asymmetric polymer network and having an immobilized liquid such as an ionic liquid within the pores of the polymer network. The process produces the fabricated fiber in a dry-wet spinning process using a homogenous dope solution, providing significant advantage over current fabrication methods for liquid-supporting polymers. The fabricated fibers may be effectively utilized for the separation of a chemical species from a mixture based on the selection of the polymer, the liquid, and the solvent utilized in the dope.Type: GrantFiled: October 21, 2010Date of Patent: February 26, 2013Assignee: U.S Department of EnergyInventors: David R. Luebke, Shan Wickramanayake
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Patent number: 8372323Abstract: A process for preparing a PANOX fiber comprising: obtaining an acrylonitrile copolymer, wherein the copolymer contains at least about 2% by weight itaconic acid comonomer; forming a spin dope from the copolymer; wet spinning the spin dope to obtain gelled filaments; contacting the gelled filaments with ammonia activator in an aqueous imbibation bath; bundling the gelled filaments to obtain a fiber; removing solvent from the fiber; drawing the fiber; densifying the fiber by heating the fiber up to about 400 degrees C. for a time of about 15 minutes in a rapid densification zone; and withdrawing a PANOX fiber from the densification zone.Type: GrantFiled: September 10, 2009Date of Patent: February 12, 2013Assignee: International Fibers, Ltd.Inventor: W. Kenneth Wilkinson
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Patent number: 8366988Abstract: The present invention provides a “spunbond wetlaid method for producing non-woven fabrics from natural cellulose” using pulp as raw material and N-methylmorpholine N-oxide (NMMO) as solvent for dissolving into dope. Then, the dope is extruded out of a spinneret to form filament bundle by spunbond method. The dope is extruded out of a spinneret bank of grouped spinnerets to form filament bundle for further stretching process under quench condition. The filament bundle is coagulated with regeneration in a coagulating solution. The coagulated filament bundle is rapidly stretched under high pressure by an air draw-off machine. The stretched filament bundle is collected and stacked on a collecting net as web nonwoven. After post treatments of water rinsing, hydro-entangled needle punching, drying, winding-up and the like have been orderly applied then final product of nonwoven fabrics with continuous filament are produced from natural cellulose.Type: GrantFiled: September 1, 2010Date of Patent: February 5, 2013Assignee: Acelon Chemical and Fiber CorporationInventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
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Patent number: 8337730Abstract: The present invention relates to a continuous, multicellular, hollow carbon fiber wherein the fiber structure includes a substantially hollow fiber and multiple internal walls defining multiple integral internal hollow fibers such that the fiber structure comprises a honeycomb-like cross section.Type: GrantFiled: January 5, 2009Date of Patent: December 25, 2012Assignees: The Boeing Company, Hill, Inc.Inventors: Thomas K. Tsotsis, Jeff Haggard
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Patent number: 8303888Abstract: A process is disclosed of forming cellulose fibers. The process includes extruding an aqueous solution of cellulose and a solvent through a first member to form filaments. The first member has multiple rows of first and second openings with a nozzle positioned in each of the first openings. At least one of the nozzles in one row is staggered from at least one of the nozzles in an adjacent row. At least a portion of each of the filaments is shrouded in a pressurized gas emitted through each of the first openings. Each of the filaments is contacted with a liquid to remove some of the solvent and transform each of the filaments into a continuous solid fiber. The continuous solid fibers are then collected on a moving surface to form a non-woven cellulose web.Type: GrantFiled: April 11, 2008Date of Patent: November 6, 2012Assignee: Reifenhauser GmbH & Co. KGInventors: Douglas B. Brown, Jeffrey D. Stark, Carmen A. Granato, Sr., Duane K. Zacharias
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Patent number: 8282877Abstract: The present invention relates to a process for the production of a hydroentangled product comprising cellulose fibers, which includes the steps of (a) extruding a solution comprising cellulose dissolved in an aqueous tertiary amine-oxide through a spinneret into an air gap, thereby forming filaments (b) drawing said filaments by means of a gaseous stream (c) collecting and precipitating said filaments in order to form a web (d) bonding said web by means of a hydroentanglement process (e) contacting said filaments in the air gap with a medium which at least partially coagulates the filaments. Furthermore, the invention relates to products obtainable by said products, and uses thereof.Type: GrantFiled: April 26, 2007Date of Patent: October 9, 2012Assignee: Lenzing AktiengesellschaftInventors: Pat White, Haio Harms, Malcolm Hayhurst
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Patent number: 8273278Abstract: A water-insoluble polyglutamic acid (PGA) fiber and a preparation method thereof are provided. In the preparation method, the PGA is cross-linked by a cross-linking agent and then passes through a spinning nozzle to form PGA fibers. Therefore, the highly water-absorbing PGA, which cannot be spun by conventional methods, can be spun to form PGA fibers and maintain the high water-absorption ability.Type: GrantFiled: April 9, 2010Date of Patent: September 25, 2012Assignee: Far East New Century CorporationInventors: Jo-Wei Huang, Mei-Ting Fan Chiang, Ken-Yuan Chang
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Publication number: 20120067208Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.Type: ApplicationFiled: November 28, 2011Publication date: March 22, 2012Applicants: Georgia Tech Research Corporation, Chevron U.S.A. Inc.Inventors: Stephen J. MILLER, Imona C. Omole, William J. Koros
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Publication number: 20120048107Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: ApplicationFiled: August 25, 2010Publication date: March 1, 2012Inventor: Shabbir Husain
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Patent number: 8052905Abstract: A process for the preparation of polymer yarns from ultra high molecular weight homopolymers or copolymers, wherein the process includes the following steps: (a) preparing a suspension of a homopolymer or copolymer and a spinning or gelling solvent of a non polar nature at a weight of homopolymer or copolymer to solvent ratio from 2/98 to 30/70, wherein said ultra high molecular weight homopolymer or copolymer is reactor bimodal or multimodal; (b) feeding said homopolymer or copolymer suspension to an extruder; (c) extruding said suspension under gel forming conditions, at a temperature in excess of 150° C., and under inert conditions; (d) spinning the gel obtained from the extrusion so as to obtain non-stretched filaments with diameters of at least 1 mm, at a temperature in excess of 150° C.Type: GrantFiled: November 9, 2007Date of Patent: November 8, 2011Assignee: Braskem S.A.Inventors: Fernanda Oliveira Vieira Da Cunha, Alan Kardec Do Nascimento, Breno De La Rue, Martha de La Rue Beckedorf
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Patent number: 8003027Abstract: A process for the preparation of polymer yarns from ultra high molecular weight homopolymers or copolymers which includes the steps of preparing a suspension of a homopolymer or copolymer and a spinning or gelling solvent, extruding the suspension with the formation of a gel, spinning the gel to obtain non-stretched filaments or yarns, cooling the non-stretched filaments or yarns, feeding the non-stretched filaments or yarns, to an extractor together with the feed of an organic extraction solvent, extracting the non-polar long chain solvent impregnated in the yarns, drying the non-stretched filament bundles or yarns, and stretching said dry yarns at a temperature in excess of 80° C.Type: GrantFiled: November 9, 2007Date of Patent: August 23, 2011Assignees: Braskem S.A., Profil Ind E Com de Fios Ltda.Inventors: Fernanda Oliveira Vieira Da Cunha, Alan Kardec do Nascimento, Breno de La Rue, Martha De La Rue Beckerdorf
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Patent number: 7981337Abstract: The present invention relates to the use of an aqueous sodium hydroxide/thiourea solution, specifically to the use of an aqueous sodium hydroxide/thiourea solution for pilot-scale production of cellulose products, wherein sodium hydroxide constitutes 8.1%-12.0% of the total weight of the aqueous solution, thiourea constitutes 3.0%-6.0% of the total weight of the aqueous solution, and said cellulose products include regenerated cellulose filaments, films, nonwovens, as well as composite fibers and/or functional materials of protein/cellulose, chitin/cellulose, Konjac Glucomannan/cellulose, nano-crystal particle/cellulose, etc.Type: GrantFiled: April 21, 2006Date of Patent: July 19, 2011Assignees: Wuhan University, Jiangsu Long-Ma Green Fibers Co., Ltd.Inventors: Lina Zhang, Dong Ruan, Jinping Zhou, Ang Lv
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Publication number: 20110168980Abstract: A nanofiber composite including a nanofiber formed of a hydrophobic polymer, a nanowire formed of a conductive or semiconductive organic material that is oriented in the nanofiber in the longitudinal direction of the nanofiber, and an ionic active material.Type: ApplicationFiled: June 30, 2010Publication date: July 14, 2011Inventors: Jae-hyun Hur, Jong-jin Park, Seung-nam Cha, Jong-min Kim, Chi-yul Yoon