During Or After Final Shape Change Patents (Class 264/210.4)
  • Patent number: 11804635
    Abstract: A separator comprising a crosslinked polyolefin substrate having a plurality of pores and an inorganic coating layer having internal pores formed on at least one surface of the crosslinked polyolefin substrate. The inorganic coating layer on the at least one surface of the crosslinked polyolefin substrate has internal pores formed by an immersion phase separation method, and a high power secondary battery including the same.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: October 31, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Su Rim Lee, Soon Hyung Choi, Seok Koo Kim
  • Patent number: 11769930
    Abstract: Provided is a separator for electricity storage devices, which comprises an active layer that contains a material (A) that is capable of absorbing lithium (Li), and which has an air permeability of 650 s/100 ml or less.
    Type: Grant
    Filed: November 20, 2018
    Date of Patent: September 26, 2023
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masanori Nakazawa, Hiroshi Hatayama
  • Patent number: 11196126
    Abstract: In accordance with at least selected embodiments, novel or improved separator membranes, separators, batteries including such separators, methods of making such membranes and/or separators, and/or methods of using such membranes and/or separators are disclosed or provided. In accordance with at least certain embodiments, an ionized radiation treated microporous polyolefin, polyethylene (PE), copolymer, and/or polymer blend (e.g., a copolymer or blend comprising PE and another polymer, such as polypropylene (PP)) battery separator for a secondary or rechargeable lithium battery and/or a method of making an ionized radiation treated microporous battery separator is disclosed.
    Type: Grant
    Filed: September 18, 2019
    Date of Patent: December 7, 2021
    Assignee: Celgard, LLC
    Inventors: Changqing Wang Adams, Michael Bielmann, Zhengming Zhang
  • Patent number: 10363701
    Abstract: The problem addressed by the invention lies in providing a method for producing an inorganic substance powder highly-oriented thin film sheet with which it is possible to produce a sheet of uniform thickness while preventing the generation of impurities, improving sheet surface properties, adjusting apparent specific gravity, and the like. The method for producing a thin film sheet comprises a step for preparing a predetermined inorganic substance powder, thermoplastic resin, and auxiliary agent, a step for exposing the starting materials mixed at a predetermined mixture ratio to high shear stress while kneading, a step for feeding the kneaded starting materials to a T die-type extrusion molding device and molding a sheet, and a step for adjusting the apparent gravity as desired by stretching under predetermined conditions.
    Type: Grant
    Filed: July 13, 2016
    Date of Patent: July 30, 2019
    Assignee: TBM CO., LTD.
    Inventors: Yuichiro Sumi, Naoyuki Kawamata
  • Patent number: 10000587
    Abstract: The present invention relates to a polymer fiber, in particular a polyethylene polymer fiber obtainable by melt-spinning of a polyethylene polymer, the use of the fiber and a process for the manufacture of the fiber. Further, the present invention relates to a heat sealable filter paper comprising said polymer fiber.
    Type: Grant
    Filed: July 29, 2013
    Date of Patent: June 19, 2018
    Assignee: Baumhueter Extrusion Gmbh
    Inventor: Ingo Knack
  • Publication number: 20140361457
    Abstract: In a method for manufacturing a polyolefin microporous film, non-uniformity in a film resulting from non-uniform drying during solvent extraction is minimized, high-speed drying and high-speed continuous productivity of the polyolefin microporous film are implemented. In the method for manufacturing a polyolefin microporous film, in which a composition composed of a polyolefin resin and a plasticizer is made into a film form using extrusion, the plasticize is extracted and removed using a solvent, and the film is thereafter dried. After the foregoing extraction and before the drying, the film is brought into close contact with a roll, or its width is mechanically restrained. A liquid (heating medium) having a temperature greater than r equal to the boiling point of the solvent is made to contact the film while the film is in close contact with the roll or while the width is restrained, whereby the film is heated and dried.
    Type: Application
    Filed: January 7, 2013
    Publication date: December 11, 2014
    Inventor: Tetsuro NOGATA
  • Patent number: 8840824
    Abstract: Single, continuous PTFE layers having lateral zones of varied characteristics are described. Some of the lateral zone embodiments may include PTFE material having little or no nodal and fibril microstructure. Methods of manufacturing PTFE layers allow for controllable permeability and porosity of the layers, in addition to other characteristics. The characteristics may vary from one lateral zone of a PTFE layer to a second lateral zone of a PTFE layer. In some embodiments, the PTFE layers may act as a barrier layer in an endovascular graft or other medical device.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: September 23, 2014
    Assignee: Trivascular, Inc.
    Inventors: Joseph W. Humphrey, Jeffry B. Skiba
  • Patent number: 8784710
    Abstract: A method of making an expanded polytetrafluoroethylene (ePTFE) membrane including the steps of: providing an unsintered or partially sintered ePTFE membrane; matting the unsintered or partially sintered ePTFE membrane; and immediately thereafter, sintering the matted ePTFE membrane. A method for making ePTFE tubes includes the steps of: providing an unsintered or partially sintered ePTFE membrane; wrapping the ePTFE membrane around a mandrel or form tool to form an ePTFE tube; matting the ePTFE tube; immediately thereafter, sintering the matted ePTFE tube; and removing the sintered ePTFE tube from the mandrel or form tool.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: July 22, 2014
    Assignee: Phillips Scientific Inc.
    Inventors: Douglas R. Hansen, James V. Phillips
  • Patent number: 8771582
    Abstract: The present invention is a bioactive, nanofibrous material construct which is manufactured using a unique electrospinning perfusion methodology. One embodiment provides a nanofibrous biocomposite material formed as a discrete textile fabric from a prepared liquid admixture of (i) a non-biodegradable durable synthetic polymer; (ii) a biologically active agent; and (iii) a liquid organic carrier. These biologically-active agents are chemical compounds which retain their recognized biological activity both before and after becoming non-permanently bound to the formed textile material; and will become subsequently released in-situ as discrete freely mobile agents from the fabric upon uptake of water from the ambient environment.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: July 8, 2014
    Assignees: BioScurfaces, Inc., Clemson University, Rhode Island Board of Education
    Inventors: Matthew D. Phaneuf, Philip J. Brown, Martin J. Bide
  • Patent number: 8728372
    Abstract: Thin PTFE layers are described having little or no node and fibril microstructure and methods of manufacturing PTFE layers are disclosed that allow for controllable permeability and porosity of the layers. In some embodiments, the PTFE layers may act as a barrier layer in an endovascular graft or other medical device.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: May 20, 2014
    Assignee: TriVascular, Inc.
    Inventors: Joseph W. Humphrey, Jeffrey B. Skiba
  • Patent number: 8394306
    Abstract: A method for producing a thermoplastic resin micro-porous film wherein a thermoplastic resin and a solvent (A) are melted and kneaded together to prepare a solution, the solution is extruded and cooled to prepare a formed product in a gel state, and the residual solvent (A) is removed from the formed product, characterized in that in the step of removing the solvent (A) use is made of a non-aqueous solvent (B) which is compatible with the solvent (A) and not compatible with the thermoplastic resin, and has a boiling point of 100° or higher and a flashing point of 0° or higher. The use of the non-aqueous solvent (B) provides a production method which allows the removal of a solvent with good efficiency and also with the reduction of a fear of environmental pollution and catching fire.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: March 12, 2013
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Mitsuhiro Nishida, Kohtaro Kimishima, Sadakatsu Suzuki
  • Patent number: 8377353
    Abstract: Conjugate fibers are prepared in which at least one segment is a mixture of a high-D PLA resin and a high-L PLA resin. These segments have crystallites having a crystalline melting temperature of at least 200° C. At least one other segment is a high-D PLA resin or a high-L PLA resin. The conjugate fibers may be, for example, bicomponent, multi-component, islands-in-the-sea or sheath-and-core types. Specialty fibers of various types can be made through further downstream processing of these conjugate fibers.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: February 19, 2013
    Assignee: NatureWorks LLC
    Inventors: Robert A. Green, Chad Henry Kamann, Jeffrey John Kolstad, Christopher M. Ryan
  • Patent number: 8287785
    Abstract: The present invention concerns a process for the manufacture of solid regenerated viscose fibers, comprising the steps of: —spinning a viscose spinning dope through a spinneret comprising spinning holes into a regenerating bath thereby forming filaments, —said viscose spinning dope having an alkali ratio immediately before spinning of from 0.7 to 1.0, preferably from 0.8 to 0.9, —at least part of said spinning holes having a circular orifice, —said regenerating bath containing—from 70 to 120 g/l, preferably 90 to 110 g/l sulfuric acid, —from 240 to 380 g/l, preferably 330 to 370 g/l sodium sulphate, —from 20 to 50 g/l, preferably 25 to 35 g/l zinc sulphate and said regenerating bath having a temperature of from 45 to 55° C., preferably 48 to 50° C.
    Type: Grant
    Filed: January 31, 2011
    Date of Patent: October 16, 2012
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Josef Schmidtbauer, Heinrich Schmidt, Susanna Schiemer
  • Publication number: 20120214946
    Abstract: A 10-50 g/d high strength polyethylene fiber and preparation method thereof are provided, which are in the high molecular material field. Said fiber is obtained by cross blend melt spinning method, and its strength is 10-50 g/d, its modulus is 400-2000 g/d. The material used by said cross blend melt spinning method is obtained by mixing low density polyethylene with molecular weight of 2/5-500,000 and super molecule weight polyethylene with molecular weight of 120-7000,000 in the proportion of 2-10:1. Flow modifier or diluent is not additionally added in the present invention, raw material consumption is low, extra high pressure is avoided, energy consumption and cost of production are low, technological process is simple, single line capacity is easily raised, and large scale industrial production can be realized.
    Type: Application
    Filed: April 27, 2012
    Publication date: August 23, 2012
    Applicant: SHANDONG ICD HIGH PERFORMANCE FIBRES CO., LTD.
    Inventor: Yi REN
  • Patent number: 8246886
    Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: August 21, 2012
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
  • Patent number: 7820083
    Abstract: Reflective pellets (16) are formed by extrusion of reflective micro beads (26) in a thermoplastic (20), removal of the surface layer of the pellets so as to expose the reflective beads at the surface of the pellets and applying the reflective pellets to the base line (14) of the striping applied to a paved road.
    Type: Grant
    Filed: February 11, 2008
    Date of Patent: October 26, 2010
    Assignee: Fortson-Peek Company, Inc.
    Inventor: Mark S. Bjorklund
  • Patent number: 7815825
    Abstract: The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: October 19, 2010
    Assignee: Tonen Chemical Corporation
    Inventors: Hidehiko Funaoka, Kotaro Takita, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 7700025
    Abstract: A microporous polyolefin film which comprises 5 to 95 wt. % polyethylene (A) having a viscosity-average molecular weight (Mv) of 2,000,000 or higher, a first-melting-peak signal height as determined by DSC (differential scanning calorimetry) of 3.0 mW/mg or higher, a specific surface area of 0.7 m2/g or larger, and an average particle diameter of 1 to 150 ?m and 95 to 5 wt. % polyethylene (B) having an Mw of 10,000 to 200,000, excluding 10,000 and 200,000, wherein the ratio of the Mv of the compound (A) to that of the compound (B), (A)/(B), is 10 or higher, the film as a whole has a molecular weight of 300,000 to 1,500,000, and the film has a fuse temperature of 120 to 140° C., a breaking temperature of 150° C. or higher, and a ratio of the piercing strength at 25° C. to the piercing strength at 140° C. of from 0.01 to 0.25.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: April 20, 2010
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Daisuke Inagaki, Takahiko Kondo
  • Patent number: 7674524
    Abstract: A major object of the invention is to provide a thermoadhesive conjugate fiber with low heat shrinkability and high adhesion having low orientation and high elongation and having extremely satisfactory card-passing properties. The object of the invention can be achieved by a thermoadhesive conjugate fiber made of a fiber forming resin component and a crystalline thermoplastic resin having a melting point of at least 20° C. lower than that of the fiber forming resin component and having a breaking elongation of from 60 to 600%, a dry heat shrinkage percentage at 120° C. of from ?10.0 to 5.0%, and more preferably a percentage of crimp/number of crimps of 0.8 or more; and a manufacturing method of a thermoadhesive conjugate fiber, which includes drawing an undrawn yarn of a conjugate fiber taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.
    Type: Grant
    Filed: February 2, 2007
    Date of Patent: March 9, 2010
    Assignee: Teijin Fibers Limited
    Inventor: Hironori Goda
  • Patent number: 7479243
    Abstract: The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: January 20, 2009
    Assignee: Tonen Chemical Corporation
    Inventors: Hidehiko Funaoka, Kotaro Takita, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 6858057
    Abstract: A filter media comprising a synthetic microfiber polymer fine fiber web wherein the diameter of the fibers is between about 0.8 to about 1.5 microns. The filter media is acceptable for use in ASHRAE applications. Constructions with a low DP backing, support or prefilter layers of coarse fiber provide large area filter webs of high efficiency and a stable and high threshold value of alpha above eleven.
    Type: Grant
    Filed: March 12, 2003
    Date of Patent: February 22, 2005
    Assignee: Hollingsworth & Vosa Company
    Inventor: David Thomas Healey
  • Patent number: 6793854
    Abstract: A method and an apparatus for making a plastic film, and to a plastic film wherein the method includes extruding a film from plastic material by an extruder and orientating the film after extrusion. Material is mixed into the plastic so that when the plastic film is stretched, cavitation bubbles are formed in the material particles mixed into the plastic. After orientation, gas is arranged to act on the plastic film under high pressure so that the gas diffuses in the cavitation bubbles and causes overpressure in them. Thus it is possible to make a thin foamed film with a foaming degree of over 70%.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: September 21, 2004
    Assignee: Conenor Oy
    Inventor: Kari Kirjavainen
  • Patent number: 6660211
    Abstract: The present invention is directed to methods of making biodegradable films and biodegradable precursor films having enhanced breathability and ductility. The method includes blending a water soluble polymer and a biodegradable polymer to form a blended polymer mixture. The biodegradable polymer is preferably a biodegradable aliphatic polyester, and the water-soluble polymer is preferably polyethylene oxide and/or polyethylene glycol. The blended polymer mixture is formed into a precursor film. The precursor film is further processed to form a breathable biodegradable film.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: December 9, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Dave A. Soerens
  • Patent number: 6569987
    Abstract: To produce meta aramid filaments having a good quality from a polymer solution of a meta aramid produced by a solution polymerization method, with high efficiency, (1) a meta aramid is prepared by polymerization-reacting a aromatic meta-diamine with a aromatic meta-dicarboxylic acid chloride in a polar organic solvent; (2) hydrogen chloride contained in the resultant polymer solution is neutralized with a neutralizing agent containing an alkali metal hydroxide which can react with hydrogen chloride to produce a salt thereof insoluble in the polymerization solvent; (3) the salt deposited from the polymer solution is removed by filtration; (4) the resultant polymer solution is mixed with water and a polar organic amide solvent to prepare a spinning solution; (5) the resultant meta aramid spinning solution is directly extruded in the form of filamentary streams into an aqueous coagulation liquid, to coagulate the extruded filamentary streams of the polymer solution into the form of filaments; (6) the coagulated
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: May 27, 2003
    Assignee: Teijin Limited
    Inventors: Akihiro Ohba, Takashi Yoshitomi, Hirozumi Iwasaki, Kotaro Takiue
  • Patent number: 6566012
    Abstract: It is an object of the present invention to provide a microporous polyolefin membrane, high in pin puncture strength, adequate in pore diameter and high in porosity, comprising (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and having a porosity of 30 to 95%, bubble point exceeding 980 KPa and pin puncture strength of 4,900 mN/25 &mgr;m or more. The membrane can be used as a filter or as a separator for a battery.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: May 20, 2003
    Assignee: Tonen Chemical Corporation
    Inventors: Kotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 6558591
    Abstract: A microporous film of polyethylene having an intrinsic viscosity above 5 dl/g is prepared from a homogeneous solution in an evaporable solvent. The film is cooled and evaporable solvent is evaporated at a temperature below the dissolution temperature. The film is stretched to produce the micorporous film and is passed through a calender. The microporous films with a porosity of up to about 70% by volume and a battery separator quality factor (F) of at least 2.5 are described. Battery separators formed from the microporous films are also described.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: May 6, 2003
    Assignee: DSM N.V.
    Inventor: Gijsbertus H. M. Calis
  • Patent number: 6540953
    Abstract: A method of producing a microporous membrane comprising the steps of: extruding a polymer at a temperature of from (polymer melting point +10° C.) to (polymer melting point +100° C.); drawing the extruded polymer at a rate of 5˜120 m/min in 10˜150° C. to obtain a polymer film; annealing the polymer film at a temperature of from (polymer melting point −100° C.) to (polymer melting point −5° C.) for 10 seconds to 1 hour; irradiating both surfaces of the annealed polymer film with an ion-particle amount of 102˜1020 ion/cm2 energized at 10−2˜107 KeV, at an irradiating distance of 5˜100 cm under a vacuum of 10−2˜10−[torr; cold stretching the irradiated polymer film at a temperature of from −20° C. to (polymer melting point −40° C.); hot stretching the cold stretched polymer film at a temperature of from (polymer melting point −40° C.) to (polymer melting point −5° C.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: April 1, 2003
    Assignee: LG Chemical Ltd.
    Inventors: Sang-Young Lee, Myung-Man Kim, Heon-Sik Song
  • Patent number: 6524360
    Abstract: An electret filter media includes an additive or mixtures thereof that enhance the charge stability of the media. The filter media achieves acceptable alpha values for a range of filtration challenges without significant decay in alpha values over time. Preferred charge additives include fatty acid amides and mixtures thereof.
    Type: Grant
    Filed: February 14, 2001
    Date of Patent: February 25, 2003
    Assignee: Hollingsworth & Vose Company
    Inventors: Stephen T. Cox, David T. Healey
  • Publication number: 20030015826
    Abstract: The present invention is directed to methods of making biodegradable films and biodegradable precursor films having enhanced breathability and ductility. The method includes blending a water soluble polymer and a biodegradable polymer to form a blended polymer mixture. The biodegradable polymer is preferably a biodegradable aliphatic polyester, and the water-soluble polymer is preferably polyethylene oxide and/or polyethylene glycol. The blended polymer mixture is formed into a precursor film. The precursor film is further processed to form a breathable biodegradable film.
    Type: Application
    Filed: April 23, 2001
    Publication date: January 23, 2003
    Inventors: Vasily A. Topolkaraev, Dave A. Soerens
  • Patent number: 6245272
    Abstract: It is an object of the present invention to provide a microporous polyolefin membrane, high in elongation and porosity, low in shrinkage, and capable of improving battery characteristics, safety and productivity, when used for battery separators. The microporous polyolefin membrane of the present invention comprises (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and having a porosity of 45 to 95%, elongation at break of 300% or more, bubble point exceeding 980 KPa and thermal shrinkage in the TD direction of 3% or less. The present invention also provides a method for producing the above microporous polyolefin membrane.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: June 12, 2001
    Assignee: Tonen Chemical Corporation
    Inventors: Kotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 6177035
    Abstract: The invention relates to a process for the manufacture of cellulosic flat films and of cellulosic membranes in the form of flat membranes whereby a solution of cellulose in an aqueous tertiary amine oxide is extruded by means of an extrusion nozzle, which has an extrusion gap, whereby the solution is shaped in the form of a film and the solution is led into a precipitation bath via an air gap and is characterized in that an extrusion nozzle is used which has an extrusion gap with a minimum length of 40 cm.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: January 23, 2001
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Christian Schlossnikl, Siegfried Ambrosch, Heinrich Firgo, Peter Gspaltl
  • Patent number: RE38583
    Abstract: The invention relates to a process for the manufacture of cellulosic flat films and cellulosic membranes in the form of flat membranes whereby a solution of cellulose in an aqueous tertiary amine oxide is moulded in film form using an extrusion nozzle which has an oblong extrusion gap and is led into a precipitation bath via an air gap whereby the cellulosic flat film is formed in the precipitation bath, characterized in that the cellulosic flat film is stretched in the transverse direction after entering the precipitation bath.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: September 14, 2004
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Christian Schlossnikl, Peter Gspaltl, Johann Kalleitner, Gerold Riedl, Andreas Schweigart