Extractive Fluid Or Effects Reaction Patents (Class 264/211.16)
  • Publication number: 20150104642
    Abstract: A graphene composite fiber includes graphene sheets and a polymer for aggregating the graphene sheets together. The polymer includes either or both of a hyperbranched polymer and polyvinyl alcohol. The graphene sheets and the polymer are stacked on each other to form a layered structure, and the graphene sheets are regularly arranged along an axial direction of the graphene composite fiber. In a production method of the graphene composite fiber, a graphene oxide is used as a raw material, which significantly improves tensile strength of the graphene composite fiber. Addition of the polymer provides good tenacity for the composite fiber. In a spinning process, rotated coagulant is used to increase a tensile force of a gelatinous fiber, so that the gelatinous fiber has high orientation and tacticity, thereby significantly improving strength of an obtained solid fiber. The final reduction process restores electrical conductivity of a graphene fairly well.
    Type: Application
    Filed: December 19, 2014
    Publication date: April 16, 2015
    Inventors: Chao GAO, Xiaozhen HU, Xiaosong ZHOU, Yan XU
  • Patent number: 8999211
    Abstract: A process for producing porous structures from polyamide by dissolving the polyamide in an ionic liquid and precipitating or coagulating the dissolved polyamide by contacting the solution with a liquid precipitant medium. Fibers are produced from the dissolved polyamide in a wet-spinning process by precipitation in protic solvents, in particular water, a C1-4-alkanol or mixtures thereof, and subsequent freeze-drying. Foils, films or coatings are produced by blade coating the dissolved polyamide onto a substrate surface, optionally spraying with protic solvent, in particular water, a C1-4-alcohol or mixtures thereof, dipping into a precipitation or coagulation bath, freeze-drying of the resulting foil, of the film or of the coated substrate. Molded parts are prepared by extracting the dissolved polyamide with protic solvents, preferably water, a C1-4-alcohol or mixtures thereof, wherein the dissolved polymer is transformed to a solid or wax-like state by cooling and extracted after subsequent molding.
    Type: Grant
    Filed: February 11, 2009
    Date of Patent: April 7, 2015
    Assignee: BASF SE
    Inventors: Stefan Schwiegk, Axel Wilms, Ronald Frans Maria Lange, Michael Siemer, Giovanni D'Andola, Volker Rauschenberger, Frank Hermanutz, Frank Gaehr, Julien Courtois, Dirk Gerhard
  • Patent number: 8999212
    Abstract: A graphene ribbon fiber manufacturing process, where a coagulation medium flows in the same direction as the graphene ribbon fibers. The process for spinning graphene ribbon fibers starts with unzipping carbon nanotubes to form graphene ribbons, purifying and drying the graphene ribbons and subsequent dissolving of the graphene ribbons in a suitable solvent, preferably a super acid to form a spin-dope. The spin-dope is spun such that the accrued fibers are guided into a coagulation medium, also known as anti-solvent, where the spun or accrued fibers are coagulated. The coagulated graphene ribbon fibers are stripped, neutralized and washed and wound on bobbins.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: April 7, 2015
    Assignee: Teijin Aramid B.V.
    Inventors: Bernardus Maria Koenders, Jacobus Johannes Meerman, Stephanus Maria Kamperman, Ron Folkert Waarbeek Ter, Jorrit Jong De, Angelique Antonia Theresia Hendrikus Radier, Marcin Jan Otto
  • Patent number: 8932513
    Abstract: A method of synthesizing mechanically resilient titanium carbide (TiC) nanofibrous felts comprising continuous nanofibers or nano-ribbons with TiC crystallites embedded in carbon matrix, comprising: (a) electrospinning a spin dope for making precursor nanofibers with diameters less than 0.5 J.Lm; (b) overlaying the nanofibers to produce a nanofibrous mat (felt); and then (c) heating the nano-felts first at a low temperature, and then at a high temperature for making electrospun continuous nanofibers or nano-ribbons with TiC crystallites embedded in carbon matrix; and (d) chlorinating the above electrospun nano-felts at an elevated temperature to remove titanium for producing carbide derived carbon (CDC) nano-fibrous felt with high specific surface areas.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: January 13, 2015
    Assignee: South Dakota Board of Regents
    Inventors: Hao Fong, Lifeng Zhang, Yong Zhao, Zhengtao Zhu
  • Patent number: 8858851
    Abstract: The present invention discloses a process for producing low-titer, high-strength and high-modulus polyethylene fibers, comprising the following steps: dissolving the ultra-high molecular weight polyethylene into paraffin oil with a low viscosity to form a spinning solution with a concentration of 3˜15%; extruding the spinning solution through a thin spinneret with at least 10 orifices having a diameter ? of 0.7˜0.8 mm and a length/diameter ratio of 10˜12, by applying a high pressure in the range of 2.5±1.0 MPa to the spinning solution, such that the fluid in the orifices is extruded at a shear rate of 200˜3 500 sec?1; and then performing a jet stretch at a deformation rate of 200˜5 000 min?1 within an air-gap of 10˜15 mm between the spinneret and the quench bath surface; feeding the jet-stretched fluid into the quench bath to form gel filaments; extracting and drying the gel filaments; and performing a multistage ultrahigh post stretch on the dried gel filaments with a stretch ratio of 15 or less.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: October 14, 2014
    Assignee: Hunan Zhongtai Special Equipment Co., Ltd.
    Inventors: Nianci Yang, Yuanjun Zhang, Bo Gao, Zhiquan Wu, Mingqing Lin, Chuanqing Wu, Yong Guo, Yunbo Zhou, Haijun Lin
  • Patent number: 8795561
    Abstract: A process for forming a nanofiber non-woven includes mixing a first and second thermoplastic polymer and a plurality of particles, then subjecting the mixture to elongational forces when the first and second polymers are in a softened condition forming nanofibers of the first polymer. Next, the mixture is brought to a condition where the temperature is below the softening temperature of the first polymer forming a first intermediate. The first intermediate is consolidated forming the second intermediate where at least 70% of the nanofibers are fused to other nanofibers. Next, at least a portion of the second polymer is removed and at least 50% of the particles are positioned adjacent a surface of the nanofibers.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: August 5, 2014
    Assignee: Milliken & Company
    Inventors: Walter A. Scrivens, Hao Zhou
  • Patent number: 8771582
    Abstract: The present invention is a bioactive, nanofibrous material construct which is manufactured using a unique electrospinning perfusion methodology. One embodiment provides a nanofibrous biocomposite material formed as a discrete textile fabric from a prepared liquid admixture of (i) a non-biodegradable durable synthetic polymer; (ii) a biologically active agent; and (iii) a liquid organic carrier. These biologically-active agents are chemical compounds which retain their recognized biological activity both before and after becoming non-permanently bound to the formed textile material; and will become subsequently released in-situ as discrete freely mobile agents from the fabric upon uptake of water from the ambient environment.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: July 8, 2014
    Assignees: BioScurfaces, Inc., Clemson University, Rhode Island Board of Education
    Inventors: Matthew D. Phaneuf, Philip J. Brown, Martin J. Bide
  • Patent number: 8691130
    Abstract: Disclosed are multicomponent fibers derived from a blend of a sulfopolyester with a water non-dispersible polymer wherein the as-spun denier is less than about 6 and wherein the water dispersible sulfopolyester exhibits a melt viscosity of less than 12,000 poise measured at 240° C. at a strain rate of 1 rad/sec, and wherein the sulfopolyester comprising less than about 25 mole % of residues of at least one sulfomonomer, based on the total moles of diacid or diol residues. The multicomponent fiber is capable of being drawn at a relatively high fiber speed, particularly at least about 2000 m/min, and may be used to produce microdenier fibers. Fibrous articles may be produced from the multicomponent fibers and microdenier fibers. Also disclosed is a process for multicomponent fibers, nonwoven fabrics, and microdenier webs.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: April 8, 2014
    Assignee: Eastman Chemical Company
    Inventors: Rakesh Kumar Gupta, Scott Ellery George, Daniel William Klosiewicz, Kab Sik Seo, Coralie McKenna Fleenor, Allen Lynn Crain
  • Patent number: 8623245
    Abstract: A colored high strength polyethylene fiber, preparation method and use thereof are provided, which are in the high molecular material field. The surface of said high strength polyethylene fiber is chromatic, grey or black. The strength of said high strength polyethylene fiber is 15-50 g/d, its modulus is 400-2000 g/d. The product of the present invention is colored, so it can be well applied to civil and military field. The preparation method of present invention has some advantages that technological process is simple, production efficiency is high, cost of production is low, performance of made fiber is excellent, and use-cost is reduced, compared with the prior art.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: January 7, 2014
    Assignee: Shandong ICD High Performance Fibres Co., Ltd.
    Inventor: Yi Ren
  • Patent number: 8419989
    Abstract: The present invention concerns a process and apparatus for spinning polymer filaments comprising extruding a polymer solution to form one or more filaments into an air gap above a coagulation liquid, where the filaments are subject to strain; forming a downward stream of liquid and filaments by contacting the polymer solution with a coagulation liquid; passing the filaments and liquid through a quench tube; contacting the liquid with a surface such that the downward force of gravity on the liquid does not increase the strain of the filaments in the air gap; and separating the liquid from the filaments.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: April 16, 2013
    Assignees: Magellan Systems International LLC, E I du Pont de Nemours and Company
    Inventor: Christopher William Newton
  • Patent number: 8420005
    Abstract: The present invention provides a meltblown wetlaid method for producing non-woven fabrics with anti-mildew, anti-bacteria and deodorizing capabilities from natural cellulose. The method comprises selecting wood pulp as raw material and using N-methylmorpholine N-oxide (NMMO) as dissolving solvent and 1,3-phenylene-bis 2-oxazoline (BOX) as stabilizer to form mixed cellulose mucilage as well as using modified and nano-miniaturized natural chitosan as additive for blending and dissolution to form cellulose dope. By meltblown method, the dope is extruded out of spinnerets to form filament bundle, then by ejecting mist aerosol of water, the filament bundle is coagulated with regeneration. After post treatments of water rinsing, hydro-entangled needle punching, drying, winding-up and the like having been orderly applied, then final product for nonwoven fabric of continuous filament with anti-mildew, anti-bacteria and deodorizing capabilities is produced.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: April 16, 2013
    Assignee: Acelon Chemical and Fiber Corporation
    Inventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
  • Patent number: 8420004
    Abstract: The present invention provides a meltblown wetlaid method for producing non-woven fabrics from natural cellulose using pulp as raw material and N-methylmorpholine N-oxide (NMMO) as solvent for dissolving into dope. The dope is then extruded out of a spinneret to form filament bundle by meltblown method. Subsequently, by means of ejecting mist aerosol of water, the filament bundle is coagulated with regeneration. Via post treatments of water rinsing, hydro-entangled needle punching, drying, winding-up and the like have been orderly applied, then final product of nonwoven fabrics with continuous filament are produced from natural cellulose.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: April 16, 2013
    Assignee: Acelon Chemical and Fiber Corporation
    Inventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
  • Patent number: 8377353
    Abstract: Conjugate fibers are prepared in which at least one segment is a mixture of a high-D PLA resin and a high-L PLA resin. These segments have crystallites having a crystalline melting temperature of at least 200° C. At least one other segment is a high-D PLA resin or a high-L PLA resin. The conjugate fibers may be, for example, bicomponent, multi-component, islands-in-the-sea or sheath-and-core types. Specialty fibers of various types can be made through further downstream processing of these conjugate fibers.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: February 19, 2013
    Assignee: NatureWorks LLC
    Inventors: Robert A. Green, Chad Henry Kamann, Jeffrey John Kolstad, Christopher M. Ryan
  • Patent number: 8372323
    Abstract: A process for preparing a PANOX fiber comprising: obtaining an acrylonitrile copolymer, wherein the copolymer contains at least about 2% by weight itaconic acid comonomer; forming a spin dope from the copolymer; wet spinning the spin dope to obtain gelled filaments; contacting the gelled filaments with ammonia activator in an aqueous imbibation bath; bundling the gelled filaments to obtain a fiber; removing solvent from the fiber; drawing the fiber; densifying the fiber by heating the fiber up to about 400 degrees C. for a time of about 15 minutes in a rapid densification zone; and withdrawing a PANOX fiber from the densification zone.
    Type: Grant
    Filed: September 10, 2009
    Date of Patent: February 12, 2013
    Assignee: International Fibers, Ltd.
    Inventor: W. Kenneth Wilkinson
  • Patent number: 8349232
    Abstract: The invention provides methods for the preparation of nonwoven spunbonded fabrics and various materials prepared using such spunbonded fabrics. The method generally comprises extruding multicomponent fibers having an islands in the sea configuration such that upon removal of the sea component, the island components remain as micro- and nanofibers. The method further comprises mechanically entangling the multicomponent fibers to provide a nonwoven spunbonded fabric exhibiting superior strength and durability without the need for thermal bonding.
    Type: Grant
    Filed: March 28, 2007
    Date of Patent: January 8, 2013
    Assignee: North Carolina State University
    Inventors: Behnam Pourdeyhimi, Nataliya V. Fedorova, Stephen R. Sharp
  • Patent number: 8337730
    Abstract: The present invention relates to a continuous, multicellular, hollow carbon fiber wherein the fiber structure includes a substantially hollow fiber and multiple internal walls defining multiple integral internal hollow fibers such that the fiber structure comprises a honeycomb-like cross section.
    Type: Grant
    Filed: January 5, 2009
    Date of Patent: December 25, 2012
    Assignees: The Boeing Company, Hill, Inc.
    Inventors: Thomas K. Tsotsis, Jeff Haggard
  • Patent number: 8298466
    Abstract: Medical articles with porous polymeric structures and methods of forming thereof are disclosed. The porous structure can have pores sizes that are nanoporous or greater than nanoporous. The porous structure can be a coating or layer of a medical device such as a stent, stent graft, catheter, or lead for pacemakers or implantable cardioverter defibrillators. Additionally, the body of the medical device can be a porous polymeric structure. The porous structure can be made from bioabsorbable polymers. The porous structures can be formed by contacting a polymer with a supercritical fluid.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: October 30, 2012
    Assignee: Abbott Cardiovascular Systems Inc.
    Inventors: Kumin Yang, Neftali Fernandez
  • Patent number: 8262958
    Abstract: Disclosed are water-dispersible fibers derived from sulfopolyesters having a Tg of at least 25° C. The fibers may contain a single sulfopolyester or a blend of a sulfopolyester with a water-dispersible or water-nondispersible polymer. Also disclosed are multicomponent fibers comprising a water dispersible sulfopolyester having a Tg of at least 57° C. and a water non-dispersible polymer. The multicomponent fibers may be used to produce microdenier fibers. Fibrous articles may be produced from the water-dispersible fibers, multicomponent fibers, and microdenier fibers. The fibrous articles include water-dispersible and microdenier nonwoven webs, fabrics, and multilayered articles such as wipes, gauze, tissue, diapers, panty liners, sanitary napkins, bandages, and surgical dressings. Also disclosed is a process for water-dispersible fibers, nonwoven fabrics, and microdenier webs.
    Type: Grant
    Filed: December 30, 2010
    Date of Patent: September 11, 2012
    Assignee: Eastman Chemical Company
    Inventors: William Alston Haile, Scott Ellery George, Wesley Raymond Hale, Waylon Lewellyn Jenkins
  • Publication number: 20120148841
    Abstract: The present invention is directed to a high surface area fiber and method for making the same. The fiber includes a co-extruded internal fiber and an external sheath that is washed with a solvent to remove the dissolvable external sheath, the resulting fiber having a longitudinal axis and a cross-section, the cross-section having a middle region and projections extending from the middle region.
    Type: Application
    Filed: January 27, 2012
    Publication date: June 14, 2012
    Applicants: ALLASSO INDUSTRIES, NORTH CAROLINA STATE UNIVERSITY
    Inventors: Behnam Pourdeyhimi, Walter Chappas
  • Patent number: 8092732
    Abstract: The present invention provides a processing method of the natural cellulose fiber with feature for enhancing the capability of antifungi, antibacteria and deodorization. The procedure is that firstly modify and reduce the properties of the natural chitosan of high polymer material to nanometer scale; secondly dunk the chitosan into the syrup-like mixture of wood pulp and NMMO solvent to yield quasi-dope; thirdly dehydrate the quasi-dope of paste mixture to form the mud-like dope; fourthly spin the dope by dryjet wet spinning method; fifthly regenerate the filament in coagulation bath, water rinse and dry; finally water rinse, dry, apply the lubricant to finish. The water soluble chitosan, which has been treated by property modification and reduced to nanometer scale, can effectively and completely solve in the cellulose of low DP to offer wider extent of selection in the DP and better flexibility of adding percentage in content of modified chitosan.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: January 10, 2012
    Assignee: Acelon Chemical and Fiber Corporation
    Inventors: Wen-Tung Chou, Ming-Yi Lai, Kun-Shan Huang
  • Patent number: 8052905
    Abstract: A process for the preparation of polymer yarns from ultra high molecular weight homopolymers or copolymers, wherein the process includes the following steps: (a) preparing a suspension of a homopolymer or copolymer and a spinning or gelling solvent of a non polar nature at a weight of homopolymer or copolymer to solvent ratio from 2/98 to 30/70, wherein said ultra high molecular weight homopolymer or copolymer is reactor bimodal or multimodal; (b) feeding said homopolymer or copolymer suspension to an extruder; (c) extruding said suspension under gel forming conditions, at a temperature in excess of 150° C., and under inert conditions; (d) spinning the gel obtained from the extrusion so as to obtain non-stretched filaments with diameters of at least 1 mm, at a temperature in excess of 150° C.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: November 8, 2011
    Assignee: Braskem S.A.
    Inventors: Fernanda Oliveira Vieira Da Cunha, Alan Kardec Do Nascimento, Breno De La Rue, Martha de La Rue Beckedorf
  • Patent number: 8051991
    Abstract: A process for manufacturing of an asymmetric hollow fiber membrane, comprising the steps of extruding a polymer solution through the outer ring slit of a hollow fiber spinning nozzle, simultaneously extruding a center fluid through the inner bore of the hollow fiber spinning nozzle, into a precipitation bath, whereby the polymer solution contains 10 to 26 wt-% of polysulfone (PSU), polyethersulfone (PES) or polyarylethersulfone (PAES), 8 to 15 wt-% polyvinylpyrrolidone (PVP), 55 to 75 wt-% N-alkyl-2-pyrrolidone (NAP) and 3 to 9 wt-% water the centre fluid contains 70 to 90 wt-% N-alkyl-2-pyrrolidone (NAP) and 10 to 30 wt-% water, and the precipitation bath contains 0 to 20 wt-% N-alkyl-2-pyrrolidone (NAP) and 80 to 100 wt-% water.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: November 8, 2011
    Assignee: Gambro Lundia AB
    Inventors: Bernd Krause, Markus Hornung, Herman Goehl
  • Patent number: 8003027
    Abstract: A process for the preparation of polymer yarns from ultra high molecular weight homopolymers or copolymers which includes the steps of preparing a suspension of a homopolymer or copolymer and a spinning or gelling solvent, extruding the suspension with the formation of a gel, spinning the gel to obtain non-stretched filaments or yarns, cooling the non-stretched filaments or yarns, feeding the non-stretched filaments or yarns, to an extractor together with the feed of an organic extraction solvent, extracting the non-polar long chain solvent impregnated in the yarns, drying the non-stretched filament bundles or yarns, and stretching said dry yarns at a temperature in excess of 80° C.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: August 23, 2011
    Assignees: Braskem S.A., Profil Ind E Com de Fios Ltda.
    Inventors: Fernanda Oliveira Vieira Da Cunha, Alan Kardec do Nascimento, Breno de La Rue, Martha De La Rue Beckerdorf
  • Patent number: 7981336
    Abstract: The subject matter disclosed herein relates generally to the production of a predetermined ratio of multicomponent fibers in combination with monocomponent fibers or other multicomponent fibers, preferably through a spunbonding process. After extrusion, these fibers can produce a fiber network that is subsequently bonded to produce a nonwoven fabric comprising multiple types of fibers. The multicomponent fibers within the network may be processed to remove one component by dissolution or to split the individual components into separate fibers. As a result, the fabric will be comprised of fibers with a range of diameters (micro- or nano-denier fibers as well as higher denier fibers) such that the fibers will not pack as tightly as in a homogeneous nonwoven fabric produced from one type of monocomponent or multicomponent fiber. The present invention additionally relates to methods for producing nonwoven fabrics with increased loft, breathability, strength, compressive properties, and filtration efficiency.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: July 19, 2011
    Assignee: North Carolina State University
    Inventor: Behnam Pourdeyhimi
  • Patent number: 7968029
    Abstract: The present invention relates to processes for hydrolyzing polyphosphoric acid in polyareneazole filaments.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: June 28, 2011
    Assignees: E. I. du Pont de Nemours and Company, Magellan Systems International, LLC
    Inventor: Christopher William Newton
  • Patent number: 7968030
    Abstract: The present invention relates to processes for hydrolyzing polyphosphoric acid in spun multifilament yarns.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: June 28, 2011
    Assignees: E.I. du Pont de Nemours and Company, Magellan Systems International, LLC
    Inventors: Christopher W Newton, Steven R Allen, Steven D Moore
  • Patent number: 7959762
    Abstract: A method for making mixed polymer composite fibers in which a carboxyalkyl cellulose and a starch are blended in water to provide an aqueous gel; the aqueous gel treated with a first crosslinking agent to provide a crosslinked gel; the crosslinked gel mixed with a water-miscible solvent to provide fibers; and the fibers treated with a second crosslinking agent to provide crosslinked mixed polymer composite fibers.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: June 14, 2011
    Assignee: Weyerhaeuser NR Company
    Inventor: S Ananda Weerawarna
  • Patent number: 7935298
    Abstract: A process of making fibers by electrostatic spinning includes the use of a mixing vessel (10), a piston (15) for pressurizing the polymer, carbon dioxide sources (20) for lowering the viscosity of the polymer or pressurizing the collection vessel (35), a pressure generator (25), view ports (30), a target (36), a spinning needle (40), a camera/TV recorder (45) and a voltage source (50).
    Type: Grant
    Filed: December 23, 2004
    Date of Patent: May 3, 2011
    Assignee: Virginia Commonwealth University
    Inventors: Mark McHugh, Zhihao Shen, Diane Gee, Georgios Karles, Jose Nepomuceno, Gary Huvard
  • Patent number: 7901606
    Abstract: The present invention provides a method of producing porous structures, particles or matrixes, which may be comprised of one or a plurality of components, an apparatus for carrying out the method and particles formed in accordance with the method. The method is particularly suitable for producing porous composite or pure particles for pharmaceutical applications. In accordance with the method, a composite comprising a material such as a pharmaceutical, a biodegradable polymers and/or a biological agent is formed. The composite must further comprise a material that is soluble in supercritical fluid. Extraction of the supercritical fluid soluble material produces porous structures, which may be in the form of particles or matrixes.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 8, 2011
    Assignee: Ferro Corporation
    Inventors: Pratibhash Chattopadhyay, Boris Y. Shekunov, Jeffrey S. Seitzinger
  • Patent number: 7867421
    Abstract: The invention relates to a method for the production of composite fibers with an increased content of colloidal particles, made from a pre-fiber, comprising a polymeric binder and colloidal particles, during which the chemical structure of the polymeric binder is degraded at a temperature of the order of ambient temperature such as to at least partially eliminate the above. The invention further relates to a fiber comprising a polymeric binder and colloidal particles, combining an excellent mechanical strength and a content of colloidal particles greater than 70% by mass.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: January 11, 2011
    Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Universite des Sciences Et Technologies (Bordeaux 1)
    Inventors: Philippe Poulin, Stephane Badaire, Cecile Zakri, Maryse-Marie-Therese Maugey
  • Publication number: 20100324221
    Abstract: The present invention is an antistatic acrylic fiber which comprises 90 to 99% by weight of acrylonitrile polymer containing 80 to 100% by weight of acrylonitrile as a constituting component and 10 to 1% by weight of acrylic antistatic resin containing 10 to 70% by weight of acrylonitrile as a constituting component, characterized in that alkali metal ion is contained in an amount of not less than 150 ppm to the fiber. The acrylic fiber of the present invention has antistatic property which does not lower so much even if the fiber is subjected to a spinning and dyeing step.
    Type: Application
    Filed: June 19, 2009
    Publication date: December 23, 2010
    Inventors: Yoshiki Yamato, Yoshihiro Watanabe
  • Patent number: 7793357
    Abstract: This invention provides a method of producing chitosan non-woven fabrics and an apparatus thereof. At first, a chitosan acidic solution is extruded to form a chitosan fibrous stream. Then, a solidifying agent is ejected to form a solidifying agent stream. The solidifying agent stream and the chitosan fibrous stream are combined to form a pre-solidified chitosan fiber. Then, high-pressure air is ejected on the pre-solidified chitosan fiber to stretch the pre-solidified chitosan fiber. Finally, the chitosan fibers are collected to form chitosan non-woven fabrics.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: September 7, 2010
    Assignee: Taiwan Textile Research Institute
    Inventors: Chao-Chun Peng, Tzu-Hsiang Huang, Jian-Min Lin, Jen-Hsiung Lee
  • Patent number: 7776246
    Abstract: The present invention concerns a process for making a polyareneazole multifilament yarn comprising: a) extruding a solution comprising polyareneazole polymer and polyphosphoric acid through a plurality of orifices to produce filaments; b) forming a multifilament yarn from said filaments; c) hydrolyzing at least some of the polyphosphoric acid in the yarn by heating the yarn to a temperature above about 120° C. for up to about two minutes; d) washing at least some of the hydrolyzed polyphosphoric acid from the yarn; e) drying the washed yarn; f) optionally, heating the yarn above about 300° C., and g) collecting the yarn at a speed of at least about 50 meters per minute.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: August 17, 2010
    Assignees: E. I. du Pont de Nemours and Company, Magellan Systems International, LLC
    Inventors: Steven R Allen, Steven D Moore, Christopher William Newton, David J Rodini, Doetze Jakob Sikkema
  • Patent number: 7704900
    Abstract: Provided is an artificial leather sheet that comprises microfine fibers of an inelastic polymer having a mean fiber diameter of at most 5 ?m and an elastic polymer, in which the major portion of the elastic polymer forms a fibrous structure of the entangled nonwoven fabric with the microfine fibers of inelastic polymer throughout the entire layer of the artificial leather sheet in the thickness direction thereof, and a part of the elastic polymer forms a porous layer integrated with the entangled nonwoven fabric structure on at least one face of the artificial leather sheet. The artificial leather sheet does not substantially undergo structure deformation even when repeatedly elongated and deformed. It has good elastic stretchability, and has a soft and dense feel, and its appearance is good not detracting from the drapability of the sheet.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: April 27, 2010
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinichi Yoshimoto, Tetsuya Ashida, Hisao Yoneda
  • Patent number: 7575707
    Abstract: A method for electrospinning nanofibers having a core-sheath, tubular, or composite structure is disclosed. The process uses a spinneret having first and second capillaries that channel first and second fluids in the spinneret, the second capillary surrounding the first. A high voltage is applied between the spinneret and a spaced conductive collector. In one embodiment, the first fluid is a mineral oil and the second fluid is a polymeric solution that may include a polymer, a catalyst, a solvent, and a sol-gel precursor. The as-spun nanofiber includes an oil core and a composite sheath. The oil may be removed to produce a composite tubular fiber or the polymer and oil may be removed by calcination to produce a ceramic tubular fiber. In other embodiments, miscible fluids are used to produce porous nanofibers, selected additives functionalize the surfaces of the nanofibers and/or conjugated polymers are used.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: August 18, 2009
    Assignee: University of Washington
    Inventors: Younan Xia, Dan Li
  • Patent number: 7431869
    Abstract: A nonwoven web product including ultra-fine fibers is formed utilizing a spunbond apparatus that forms multicomponent fibers by delivering first and second polymer components in a molten state from a spin pack to a spinneret, extruding multicomponent fibers including the first and second polymer components from the spinneret, attenuating the mulicomponent fibers in an aspirator, laying down the multicomponent fibers on an elongated forming surface disposed downstream from the aspirator to form a nonwoven web, and bonding portions of at least some of the fibers in the nonwoven web together to form a bonded, nonwoven web product. The multicomponent fibers can include separable segments such as islands-in-the-sea fibers, where certain separated segments become the ultra-fine fibers in the web product.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: October 7, 2008
    Assignee: Hills, Inc.
    Inventors: Jeff Haggard, Arnold Wilkie, James Brang, Jerry Taylor
  • Patent number: 7270779
    Abstract: The present invention relates to a method and an apparatus for extruding continuously molded bodies, wherein an extrusion solution, in particular an extrusion solution containing water, cellulose and a tertiary amine oxide, is extruded through an extrusion orifice into a continuously molded body and is then deflected by means of a deflector (7). To improve the quality of the continuously molded bodies produced by the method or apparatus of the invention, the extrusion orifices are arranged in a row such that the individual, continuously molded bodies exit in the form of a curtain (3) form the extrusion head. This curtain is then deflected by the deflector.
    Type: Grant
    Filed: April 25, 2001
    Date of Patent: September 18, 2007
    Assignee: Zimmer A.G.
    Inventors: Stefan Zikeli, Friedrich Ecker
  • Patent number: 7226541
    Abstract: The invention relates to a terpolymer of tetrafluoroethylene (TFE) monomer, polyvinylidene fluoride (PVDF) monomer and hexafluoropropylene (HFP) monomer for forming an ultrafiltration or microfiltration membrane, method of forming said membranes, and to the ultrafiltration or microfiltration membranes themselves. The invention also relates to a method of forming a polymeric ultrafiltration or microfiltration membrane including preparing a leachant resistant membrane dope which incorporates a leachable pore forming agent, casting a membrane from the dope and leaching the pore forming agent from the membrane. The invention also relates to a method of preparing a polymeric ultrafiltration or microfiltration membrane of improved structure including the step of adding a nucleating agent to the membrane dope before casting.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: June 5, 2007
    Assignee: Siemens Water Technology Corp.
    Inventors: Heinz-Joachim Muller, Daniel Mullette
  • Patent number: 7189346
    Abstract: The present invention relates to polybenzazaole (PBZ) fibers and processes for the preparation of such fibers. The invention further relates to yarns, fabrics, and articles incorporating fibers of this invention, and processes for making such yarns, fabrics, and articles.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: March 13, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 7025915
    Abstract: A method for producing an artificial leather includes mixed spinning an island polymer and a sea polymer having a different dissolving property from that of the island polymer at a predetermined temperature, producing a non-woven substrate from the fiber obtained, immersing the non-woven substrate into a polymer, dissolving and removing the sea polymer in the non-woven substrate to obtain an artificial leather as a semi-finished product, and polishing the surface of the artificial leather to obtain an artificial leather having excellent dyeability and advanced fluff-like property. The ratio of melt flow index of the sea polymer to relative viscosity of the island polymer is about 20 to about 55, in which the relative viscosity of the island polymer is about 2.7 to about 3.5 and the weight percentage of the sea polymer relative to the sum of the sea polymer and the island polymer is about 30% to about 70%.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: April 11, 2006
    Assignee: San Fang Chemical Industry Co., Ltd.
    Inventors: Ching-Tang Wang, Mong-Ching Lin, Chung-Chin Feng, Kuo-Kuang Cheng, Chin-Yi Lin
  • Patent number: 6884378
    Abstract: This invention relates to methods for manufacturing super-micro fibers to produce fibers having dimensions of between 0.003-0.0003 denier per filament. The manufacturing methods include the following steps: blending polyamide-polyester mixtures; passing said polyamide-polyester mixtures through single-path and twin-screw extrusion processes; spinning said polyamide-polyester mixtures; melting and dissolving said polyamide-polyester mixtures; and separating polyester compounds from said polyester-polyamide mixtures to form polyamide compound or super-micro fibers.
    Type: Grant
    Filed: July 5, 2002
    Date of Patent: April 26, 2005
    Assignee: Nan Ya Plastics Corporation
    Inventor: Zo-Chun Jen
  • Publication number: 20040183238
    Abstract: A process for making non-thermoplastic starch fibers comprises the steps of: (a) providing a non-thermoplastic starch composition comprising from about 50% to about 75% by weight of modified starch and from about 25% to about 50% of water and having a shear viscosity within the at least one nozzle from about 1 to about 80 Pascals·second at the processing temperature and at a shear rate of 3,000 sec−1; (b) extruding the non-thermoplastic starch composition through at least one extrusion nozzle terminating with a nozzle tip, thereby forming at least one embryonic starch fiber; (c) attenuating the at least one embryonic starch fiber with an attenuating air having an average velocity at the nozzle tip greater than about 30 meters per second, to cause the fiber to form an average equivalent diameter of less than about 20 microns; (d) dewatering the at least one embryonic starch fiber to a consistency of from about 70% to about 99% by weight, thereby producing at least one non-thermoplastic starch fibe
    Type: Application
    Filed: March 18, 2004
    Publication date: September 23, 2004
    Inventors: Michael David James, Larry Neil Mackey, Donald Eugene Ensign, Savas Aydore
  • Patent number: 6780361
    Abstract: A method including forming a pseudo-gel of a semi-crystalline polymer material and a solvent. The pseudo-gel is shaped into a first form and stretched. A portion of the solvent is removed to create a second form. The second form is stretched into a microstructure including nodes interconnected by fibrils. A method including forming a first form of a pseudo-gel including an ultra-high molecular weight polyethylene material and a solvent; stretching the first form; removing the solvent to form a second form; stretching the second form into a microstructure including nodes interconnected by fibrils; and annealing the stretched second form. An apparatus including a body portion formed of a dimension suitable for a medical device application and including a polyolefin polymer including a node and a fibril microstructure. An apparatus including a body portion including an ultra-high molecular weight polyolefin material including a node and a fibril microstructure.
    Type: Grant
    Filed: June 17, 2002
    Date of Patent: August 24, 2004
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Srinivasan Sridharan, Murthy V. Simhambhatla
  • Patent number: 6723267
    Abstract: The invention relates to a highly oriented polyolefin fiber containing polyolefin with an intrinsic viscosity of at least 5 dl/g, which fiber has a tensile strength of at least 26 cN/dtex and a modulus of tension of at least 700 cN/dtex, a process for the preparation thereof and the use in ropes or anti-ballistic shaped articles. The invention also relates to improved ropes and anti-ballistic shaped articles. The highly oriented polyolefin fiber according to the invention has improved properties in applications such as, in particular, anti-ballistic shaped articles since the fiber contains 0.05-5 wt. % of a solvent for the polyolefin (relative to the total fiber weight).
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: April 20, 2004
    Assignee: DSM N.V.
    Inventors: Joseph A. P. M. Simmelink, Jacobus J. Mencke
  • Publication number: 20040070101
    Abstract: A method for producing a ultrafine fiber includes spinning an island polymer and a sea polymer to a ultrafine fiber. The island polymer is an olefin polymer and the sea polymer has a different dissolving property from that of the island polymer. A method for producing a ultrafine fiber substrate, which includes obtaining a substrate from the ultrafine fiber from the above-mentioned method, dissolving and removing the sea polymer in the substrate to obtain the ultrafine fiber substrate.
    Type: Application
    Filed: October 8, 2003
    Publication date: April 15, 2004
    Inventors: Ching-Tang Wang, Mong-Ching Lin, Chung-Chih Feng, Kuo-Kuang Cheng, Chih-Yi Lin
  • Patent number: 6706224
    Abstract: The invention relates to a process for the production of a spunlaid fabric containing solvent-spun cellulosic fibers.
    Type: Grant
    Filed: January 24, 2001
    Date of Patent: March 16, 2004
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Heinrich Firgo, Rudolf Kraft, Harmut Rüf, Christian Schlossnikl
  • Publication number: 20040041298
    Abstract: Methods for manufacturing super micro fibers to produce fibers having dimensions of between 0.003-0.003 denier per filament. The manufacturing methods include the following steps: blending polyamide and polyester compounds; passing the polyamide-polyester mixture through twin-screw extrusion; spinning the mixture and; melting, dissolving and removing the polyester compounds with alkaline solvents.
    Type: Application
    Filed: July 5, 2002
    Publication date: March 4, 2004
    Inventor: Zo-Chun Jen
  • Publication number: 20030165648
    Abstract: Fiber spinning of two polymer compositions wherein one of the compositions contains carbon nanotubes produces structures such as fibers, ribbons, yarns and films of carbon nanotubes. The polymers are removed and stabilization of the carbon nanotube material is achieved by post-spinning processes. The advances disclosed herein enable the carbon nanotube composites to be used in actuators, supercapacitors, friction materials and in devices for electrical energy harvesting.
    Type: Application
    Filed: March 4, 2002
    Publication date: September 4, 2003
    Inventors: Alex Lobovsky, James Matrunich, Ray H. Baughman, Igor Palley, Gary A. West, Ilan Golecki
  • Publication number: 20030116293
    Abstract: Fibers are produced from an acetone solution of cellulose acetate by pulling or extruding such material through a spinneret in a dry spinning process. A vacuum is applied to the thus formed fibers after a certain degree of drying. A dried outer skin is formed, and the vacuum causes the solvent inside the skin to explode or pop and exit the fiber along micro-porous paths thereby producing high surface area fibers with micro-porous cavities and internal void volume. Such micro-cavities are particularly useful for retaining solid and/or liquid reagents in a cigarette filter for selective filtration of various smoke components.
    Type: Application
    Filed: April 16, 2002
    Publication date: June 26, 2003
    Inventors: Lixin Xue, Kent B. Koller, Qiong Gao
  • Patent number: 6569987
    Abstract: To produce meta aramid filaments having a good quality from a polymer solution of a meta aramid produced by a solution polymerization method, with high efficiency, (1) a meta aramid is prepared by polymerization-reacting a aromatic meta-diamine with a aromatic meta-dicarboxylic acid chloride in a polar organic solvent; (2) hydrogen chloride contained in the resultant polymer solution is neutralized with a neutralizing agent containing an alkali metal hydroxide which can react with hydrogen chloride to produce a salt thereof insoluble in the polymerization solvent; (3) the salt deposited from the polymer solution is removed by filtration; (4) the resultant polymer solution is mixed with water and a polar organic amide solvent to prepare a spinning solution; (5) the resultant meta aramid spinning solution is directly extruded in the form of filamentary streams into an aqueous coagulation liquid, to coagulate the extruded filamentary streams of the polymer solution into the form of filaments; (6) the coagulated
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: May 27, 2003
    Assignee: Teijin Limited
    Inventors: Akihiro Ohba, Takashi Yoshitomi, Hirozumi Iwasaki, Kotaro Takiue