Curing Or Polymerization In The Extruder (includes Incomplete Polymerization Or Curing, Or Coagulating Rubber) Patents (Class 264/211.24)
  • Patent number: 11371503
    Abstract: A drilling motor system for drilling a subterranean well includes a stator tube, the stator tube being an elongated tubular member with a central stator bore. A stator elastomer layer is located within the central stator bore, lining a wall of the central stator bore. The stator elastomer layer has an elastomer bore that includes a plurality of stator lobes extending in a helical pattern along an axial length of the central bore. A rotor is located within the elastomer bore, the rotor being an elongated member that includes a plurality of rotor lobes extending in a helical pattern along an axial length of the rotor. The stator elastomer layer includes a failure detection system, the failure detection system operable to identify a region of damaged stator elastomer layer.
    Type: Grant
    Filed: December 16, 2019
    Date of Patent: June 28, 2022
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventor: Victor Carlos Costa De Oliveira
  • Patent number: 10654996
    Abstract: The present disclosure provides a method for crosslinking polyolefins through using a substantially-miscible, polyolefin-based, silane-crosslinking-agent carrier and related moisture-crosslinkable polyolefin-based compositions. The method is for crosslinking a first polyolefin includes the steps of: (A) selecting a second polyolefin being substantially-miscible with the first polyolefin and having particles of a morphology selected from the group consisting of powder and substantially spherical; (B) admixing the second polyolefin to the first polyolefin; (C) adsorbing a silane-crosslinking agent onto the second polyolefin, thereby rendering a substantially-miscible, polyolefin-based, silane-crosslinking-agent carrier; (D) melt blending the first polyolefin and the substantially-miscible, polyolefin-based, silane-crosslinking-agent carrier, thereby yielding a moisture-crosslinkable polyolefin-based composition; and (E) crosslinking the moisture-crosslinkable polyolefin-based composition.
    Type: Grant
    Filed: May 30, 2018
    Date of Patent: May 19, 2020
    Assignee: Equistar Chemicals, LP
    Inventors: Cindy L. Flenniken, Chun D. Lee
  • Patent number: 9822203
    Abstract: A process for producing water-absorbing polymer particles having high free swell rate and high centrifuge retention capacity with simultaneously high permeability of the swollen gel bed by polymerization of an aqueous monomer solution in a polymerization reactor having at least two shafts (kneaders) which rotate in an axially parallel manner, subsequent extrusion at high temperatures and thermal surface postcrosslinking.
    Type: Grant
    Filed: January 20, 2014
    Date of Patent: November 21, 2017
    Assignee: BASF SE
    Inventors: Monica Haag, Roland Krauss, Thomas Gieger, Volker Klock, Matthias Weismantel
  • Patent number: 9186835
    Abstract: A method for solid-state/melt extrusion, as can be accomplished using a unitary extruder apparatus comprising a solid-state shearing zone and a melt-state extrusion zone.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: November 17, 2015
    Assignee: Bucknell University
    Inventors: Katsuyuki Wakabayashi, Stephen M. Brouse, Michael D. Boches
  • Publication number: 20150084232
    Abstract: Extrudable hydrogel compositions for printing 3D objects, such as cell growth scaffolds, are provided. Also provided are methods for making the crosslinked hydrogel compositions and the printed objects and methods for culturing cells using the cell growth scaffolds. The hydrogel precursor solutions are aqueous solutions comprising a biocompatible polymer, functionalized polyethylene glycol as a crosslinker and, optionally, cells and/or bioactive factors.
    Type: Application
    Filed: September 25, 2014
    Publication date: March 26, 2015
    Inventors: Alexandra L. Rutz, Ramille N. Shah
  • Patent number: 8946375
    Abstract: A method for making over-indexed thermoplastic polyurethane elastomer precursor. The precursor may be cross-linked.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: February 3, 2015
    Assignee: NIKE, Inc.
    Inventors: Yasushi Ichikawa, Thomas J. Kennedy, III, Chien-Hsin Chou, Hui-Kai Liao
  • Patent number: 8945447
    Abstract: A method of preparing a green tire innerliner, the method comprising mixing one or more vulcanizable rubbery polymers, less than 0.75 parts by weight zinc oxide, less than 0.75 parts by weight magnesium oxide, and less than 0.75 parts by weight sulfur, per 100 parts by weight rubber, to form a vulcanizable mixture and extruding the mixture to form a green tire innerliner.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: February 3, 2015
    Assignee: Bridgestone Americas Tire Operations, LLC
    Inventors: James D. Ulmer, Robert Gibbons Barned, Lisa Marie Dinger, Joseph Lanzarotta
  • Patent number: 8877105
    Abstract: A process for manufacturing an elastomeric tire component includes the steps of a) preparing an elongated element including a cross-linkable elastomeric material by feeding it to an extruding device having a plurality of units, each having a respective thermal inertia, and b) delivering the elongated element onto a building support, and further includes at least one non-productive step of c) submitting at least one of the units of the extruding device to a thermal transition selected from heating or cooling, substantially reducing the risk of scorching during the thermal transition from and to the non-productive step ranking the units according to their thermal inertia and heating the units starting with the top-ranked unit sequentially to the bottom-ranked unit to reach the respective working temperature or cooling the units starting from the maximum working temperature unit sequentially to the minimum working temperature unit to reach the respective non-working temperature.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: November 4, 2014
    Assignee: Pirelli Tyre S.p.A.
    Inventors: Francesco D'Oria, Enrico Sabbatani, Maurizio Marchini
  • Patent number: 8871125
    Abstract: A process to produce a laminate comprising coextruding a dynamically vulcanized alloy (DVA) film with an adhesive layer comprising a vulcanizable elastomeric composition through a die to produce the laminate. The process provides a residence time of the vulcanizable elastomeric composition in the melt to partially scorch the vulcanizable elastomeric composition. A melt of the DVA is in contact with the melt of the vulcanizable elastomeric composition in the die for at least 5 seconds, optionally also with a change in the area of the contact between the DVA film and the adhesive layer as it passes through the die, to increase the adhesion between the adhesive layer and the DVA layer relative to a shorter co-residence time. A laminate and a pneumatic tire comprising the laminate are also disclosed.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: October 28, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Porter C. Shannon, Michael J. Vinck
  • Publication number: 20140289986
    Abstract: A cotton bud with a rod-like grip body and with a bud body that is arranged at least at one free end of the grip body. The rod-like grip body is a biologically degradable extrusion body, and includes natural fibres embedded into a material matrix.
    Type: Application
    Filed: June 20, 2012
    Publication date: October 2, 2014
    Applicant: ROWEG HOLDING AG
    Inventors: Beat Hani, Christian Rytka, Guy Petignat
  • Patent number: 8845840
    Abstract: The present disclosure is directed to a process for recycling film materials, and is particularly directed to collecting spent release liners for labels and constructing new release liner stock from the spent materials. In order to use the waste film, the film is subjected to a process for increasing the intrinsic viscosity. In addition, a coloring agent may be incorporated into the film in order to mask yellowing. In one embodiment, a multilayered composite film is formed.
    Type: Grant
    Filed: June 14, 2013
    Date of Patent: September 30, 2014
    Assignee: Mitsubishi Polyester Film, Inc.
    Inventors: Marshall Dean Ledbetter, Kathy L. Trojan
  • Patent number: 8834971
    Abstract: Process for the continuous preparation of prepolymers based on phenolic resin, an oxazoline component and an epoxide in the presence of a catalyst, including supplying the phenolic resin and the oxazoline component to an extruder in a stream A; a Lewis adduct of boron trifluoride or of aluminum trichloride, or arylsulphonic acids or alkylsulphonic acids, or latent arylsulphonic acids or latent alkylsulphonic acids, in a stream B, and the epoxide in a stream C, the infeed of stream A being situated, as seen in extrusion direction, before the infeed of stream C, these reactants are mixed at a reaction temperature of 120 to 200° C. with a residence time in the extruder of 3 seconds to 15 minutes, and then the product discharge of the extruder is cooled to a temperature of less than 45° C. within from 30 to 60 seconds.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: September 16, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Marianne Omeis, Franz-Albert von Itter, Thomas Weihrauch
  • Patent number: 8834763
    Abstract: The present disclosure relates to a method of forming fibers. First and second precursors, each possessing a core and at least one functional group known to have click reactivity, are mixed in a hopper. The mixed precursors are then extruded through an extrusion die to crosslink and produce a filament. Polymerization of the first and second precursors is catalyzed by transition metal ions.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: September 16, 2014
    Assignees: Covidien LP, Sofradim Production
    Inventors: Ahmad Robert Hadba, Sebastien Ladet
  • Patent number: 8784712
    Abstract: A process for making a polyurethane, comprising reacting a multifunctional isocyanate, a polyol and, optionally, a chain extender, wherein at least two reagents selected from the isocyanate, the polyol, the chain extender, any mixture thereof and any pre-polymer formed therefrom, are intensively mixed prior to being reactively extruded, to form a polyurethane having a predetermined stoichiometry and thermal history. The polyurethanes obtained by such a process are of highly consistent composition and are, thus, especially suitable for use in the medical device industry.
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: July 22, 2014
    Assignee: Ranier Limited
    Inventors: Geoffrey Thomas Andrews, Anthony Francis Johnson
  • Publication number: 20140175697
    Abstract: A modified long chain polyamide is provided. The modified long chain polyamide is polymerized by monomers comprising a long-aliphatic-chain monomer, and equimolar of an aromatic diacid and polyethyleneoxy diamine. A fiber made from the modified long chain polyamide is also provided.
    Type: Application
    Filed: December 26, 2012
    Publication date: June 26, 2014
    Applicant: TAIWAN TEXTILE RESEARCH INSTITUTE
    Inventors: Wei-Hung Chen, Ta-Yo Chen, Tsai-Wen Chen, Wei-Hsiang Lin
  • Patent number: 8734609
    Abstract: A process for continuous manufacturing of moisture-curable polyurethane formulations used as sealants and adhesives. The process is characterized by the fact that the reactive components are introduced independently, and without the need for a prepolymer, to a mixer. Solid or liquid raw materials can be either pre-blended or fed directly to the mixer, a twin-screw extruder, which provides the requisite energy to homogenously mix the raw materials and drive the chemical reaction. The process is designed so that the extruder barrel and screw allow variable feed addition and heat exchange down the length of the machine. This allows various operations to be performed at different points in the extruder, including reaction, dispersive mixing, distributive mixing and devolitization.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: May 27, 2014
    Assignee: Bostik, Inc.
    Inventor: Sean G. Duffy
  • Publication number: 20140142626
    Abstract: The present disclosure relates to a method of forming fibers. First and second precursors, each possessing a core and at least one functional group known to have click reactivity, are mixed. The mixed precursors are then extruded under heat to cross-link during fiber production.
    Type: Application
    Filed: January 23, 2014
    Publication date: May 22, 2014
    Applicants: COVIDIEN LP, SOFRADIM PRODUCTION
    Inventors: Ahmad Robert HADBA, Sebastien LADET
  • Patent number: 8668657
    Abstract: A method of manufacturing a guidewire having a discrete length. The method includes the steps of feeding a first end of a corewire into an extrusion device, gripping the first end of the corewire with a gripping apparatus, and extruding a first extrusion material onto an outer surface of the corewire while the gripping apparatus pulls the corewire through the extrusion device to form an extrusion jacket on the outer surface of the corewire. The corewire has a predetermined length corresponding to a length of the guidewire.
    Type: Grant
    Filed: August 30, 2013
    Date of Patent: March 11, 2014
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Matthew S. Solar, Richard Acevedo, Eric Welch, Scott Jones
  • Patent number: 8658077
    Abstract: Oligoamines, such as a compound of the formula H2N(CH2CH2NH)nH in which n is an integer of 2-10, crosslink polymers containing carboxyl functionality unexpectedly faster than conventional diamines such as 1,6-diaminohexane. The combination of an ethylene-acrylic acid copolymer with an oligoamine of this type is useful for, among other things, the production of crosslinked wire and cable insulation.
    Type: Grant
    Filed: August 5, 2009
    Date of Patent: February 25, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Bharat I. Chaudhary, Eric P. Wasserman
  • Publication number: 20140051315
    Abstract: The present invention relates to fibers comprising at least 98 wt % of a propylene polymer having, in particular, a specific molecular weight distribution Mw/Mn and xylene solubles content. The present invention also relates to nonwovens, laminates and composites comprising such fibers. Furthermore, the present invention relates to a process for producing such fibers, nonwovens, laminates and composites.
    Type: Application
    Filed: December 12, 2008
    Publication date: February 20, 2014
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Alain Standaert, Hugues Haubruge, GuilLaume Pavy, Jerome Gromada
  • Patent number: 8647551
    Abstract: A process for producing moldings with condensing-up of a polyamide molding composition whose polyamide component contains, as a result of the method of preparation, at least 5 ppm of phosphorus in the form of an acidic compound by means of a compound having at least two carbonate units, wherein a) from 0.001 to 10% by weight, based on the polyamide, of a salt of a weak acid is added to the polyamide molding composition prior to compounding or during compounding, b) a mixture of the finished composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, effects a significant increase in the melt stiffness combined with moderate processing pressures, which considerably simplifies, in particular, the production of hollow bodies and hollow profiles having large diameters.
    Type: Grant
    Filed: February 15, 2006
    Date of Patent: February 11, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Andreas Dowe, Rainer Goering, Martin Himmelmann, Sonja Bollmann, Franz-Erich Baumann, Roland Wursche
  • Patent number: 8642701
    Abstract: Injection stretch blow molded (ISBM) articles containing a bio-based polymers and methods of forming the same are described herein. The method generally includes providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid to form a polymeric blend; injection molding the blend into a preform; and stretch-blowing the preform into an article.
    Type: Grant
    Filed: February 8, 2011
    Date of Patent: February 4, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Luyi Sun, John Ashbaugh, David Rauscher, Leland Daniels, Robert Dotter
  • Patent number: 8618224
    Abstract: Disclosed is a method for viscosity breaking of a polypropylene polymer, a polypropylene copolymer or a polypropylene polymer blend, which process comprises adding a chain transfer agent and an initiator to a polypropylene polymer, polypropylene copolymer or polypropylene polymer blend and heating the resultant composition. The chain transfer agent has a Cs value of greater than or equal to about 0.04 as measured in ethylene polymerization at 130° C. The initiator is for example an organic or inorganic peroxide, a carbon based radical generator, a bis azo compound, a stable nitroxyl compound, a sterically hindered NO-acyl compound or a sterically hindered alkoxyamine compound.
    Type: Grant
    Filed: May 14, 2013
    Date of Patent: December 31, 2013
    Assignee: BASF SE
    Inventors: David E. Horst, Michael Roth, Peter Nesvadba
  • Publication number: 20130276967
    Abstract: The present disclosure is directed to a process for recycling film materials, and is particularly directed to collecting spent release liners for labels and constructing new release liner stock from the spent materials. In order to use the waste film, the film is subjected to a process for increasing the intrinsic viscosity. In addition, a coloring agent may be incorporated into the film in order to mask yellowing. In one embodiment, a multilayered composite film is formed.
    Type: Application
    Filed: June 14, 2013
    Publication date: October 24, 2013
    Inventors: Marshall Dean Ledbetter, Kathy L. Trojan
  • Patent number: 8535242
    Abstract: A method of manufacturing a guidewire having a discrete length. The method includes the steps of feeding a first end of a corewire into an extrusion device, gripping the first end of the corewire with a gripping apparatus, and extruding a first extrusion material onto an outer surface of the corewire while the gripping apparatus pulls the corewire through the extrusion device to form an extrusion jacket on the outer surface of the corewire. The corewire has a predetermined length corresponding to a length of the guidewire.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: September 17, 2013
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Matthew Solar, Richard Acevedo, Eric Welch, Scott Jones
  • Patent number: 8535586
    Abstract: A family of functionalized polymers is provided capable of forming membranes having exceptional OH? ionic conductivity as well as advantageous mechanical properties, which may be applied to membranes including such polymers for use in, e.g., AEMFC/HEMFC fuel cells. Preferred functional groups include a quaternary phosphonium, and the polymer may specifically be (tris(2,4,6-trimethoxyphenyl) phosphine)3 functionalized phosphonium polysulfone hydroxide, ECL-PVBC-QPOH, or QPOH based on any of the commercial polumers including polycarbonate (PC), poly(2,6-dimethyl-1,4-phenylene oxide) (PPO), polyetherimine (PEI), poly(ether sulfone) (PES), poly(phenylene sulfoxide) PPS, poly(ether ether ketone) (PEEK), or polybenzimidazole (PBI), polyvinyl chloride (PVC). An ionomer membrane may include polysulfone based TPQPOH, ECL-PVBC-QPOH, and/or PPO.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: September 17, 2013
    Assignee: The Regents of the University of California
    Inventors: Yushan Yan, Shuang Gu, Feng Wang
  • Patent number: 8501066
    Abstract: A method and an apparatus are provided for the production of heat-activable adhesive pellets that can be formed into elements for holding an article to a surface such as a glass surface. The apparatus and method for the manufacture of the heat-activable pellets include the steps of introducing at least a first component comprising at least one difunctional polymer with at least one multifunctional polymer into an extruder, heating the first component, introducing a second component comprising isocyanate and a powder flow enhancer (such as fumed silica) at a point downstream of the introduction of the first component, combining the first and second components in the extruder to form a flowable compound, pelletizing the extruded compound exiting the extruder by cutting to form heat-activable adhesive pellets, and drying the pellets. In one embodiment of the disclosed invention a catalyst is applied to the pellets to form catalyst-coated heat-activable adhesive pellets.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: August 6, 2013
    Assignee: A. Raybond Et Cie
    Inventors: Michel Bremont, Michel Awkal
  • Patent number: 8470224
    Abstract: This invention relates to a method of manufacturing sheet for food containers, which comprises: adding a chain extender to moist flakes of recovered PET; charging the flakes of recovered PET containing the chain extender into an extruder having two or more vent holes, melting and kneading the flakes of recovered PET with sucking to degas through the vent holes, while molecular chains of the recovered PET of which the molecular weight has been lowered are bonded to each other by the chain extender to render the molecular weight higher, and simultaneously, ethylene glycol and acetaldehyde, produced during depolymerization by water and heat, are trapped by the chain extender to remove residual aldehydes; and extruding the recovered PET from the extruder into sheet.
    Type: Grant
    Filed: March 8, 2011
    Date of Patent: June 25, 2013
    Assignee: Nakamoto Packs Co., Ltd.
    Inventors: Katsuro Sasauchi, Reiichi Konishi
  • Patent number: 8460590
    Abstract: A process for continuously producing an elastomeric composition includes providing at least one extruder, metering and feeding at least one elastomer, at least one filler, and ingredients different from elastomers and fillers into the at least one extruder, mixing and dispersing the at least one filler and the ingredients different from elastomers and fillers into the at least one elastomer using the at least one extruder, and extruding a resulting elastomeric composition. The at least one extruder includes the housing and at least one screw rotatably mounted in the housing. The housing includes at least one feed opening and a discharge opening. At least one of the ingredients different from elastomers and fillers includes a subdivided product including one or more minor ingredients dispersed in at least one thermoplastic binding agent. An apparatus for continuously producing the elastomeric composition is also disclosed.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: June 11, 2013
    Assignee: Pirelli Pneumatici S.p.A.
    Inventors: Renato Caretta, Maurizio Galimberti, Cesare Amurri, Cristiano Puppi, Giuseppe Ducoli, Enrico Albizzati
  • Publication number: 20130113135
    Abstract: A method for solid-state/melt extrusion, as can be accomplished using a unitary extruder apparatus comprising a solid-state shearing zone and a melt-state extrusion zone.
    Type: Application
    Filed: October 17, 2012
    Publication date: May 9, 2013
    Applicant: Bucknell University
    Inventor: Bucknell University
  • Publication number: 20130026673
    Abstract: A method of continuous curing and post-curing of a plurality of extruded strands is provided. A plurality of extruded strands is wrapped through a plurality of spindle units rotatably connected to a rigid frame structure. A plurality of dual spindles are provided in a plurality of upper and lower spindle units, wherein each dual spindle comprises a free spinning roller and a driven roller. A chamber that comprises a dual function chamber configured for heating and cooling is supported on the rigid frame structure. The plurality of extruded strands is continuously transferred between the upper spindle units and the lower spindle units such that the plurality of extruded strands runs in a vertical fashion that continuously alternates between the lower spindle units and the upper spindle units. Each of the plurality of strands is transferred independently of each other and continuously passed through the chamber for continuous curing and post-curing.
    Type: Application
    Filed: October 8, 2012
    Publication date: January 31, 2013
    Inventor: Michael R. Thomas
  • Patent number: 8362145
    Abstract: A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: January 29, 2013
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
  • Publication number: 20130005883
    Abstract: Disclosed is a novel packing for a solar cell module laminator. An object is to solve the problem of durability involved in conventional packings and to stably manufacture a high-quality module over a long period of time. The packing is composed of an olefin based rubber crosslinked with an organic peroxide and allowed to have a Shore A hardness, a dimensional stability, and a compression set each falling within a certain range. The olefin based rubber is suitably an EPDM rubber and/or an EPM rubber and is made possible for achieving extrusion molding.
    Type: Application
    Filed: March 9, 2011
    Publication date: January 3, 2013
    Inventors: Hidenari Nakahama, Shuji Maeda, Hiroshi Nakano
  • Patent number: 8293157
    Abstract: A method of manufacturing a cellulose/gelatin composite viscose rayon filament that is characterized by including a process in which a spinning process is carried out while a viscose spinning solution is mixed with a gelatin crosslinking solution, which makes it possible to produce a cellulose/gelatin composite viscose rayon having uniform strength and elongation without yarn disconnection.
    Type: Grant
    Filed: May 10, 2006
    Date of Patent: October 23, 2012
    Assignee: Kurashiki Boseki Kabushiki Kaisha
    Inventors: Masaru Yamada, Kunihiro Ohshima
  • Patent number: 8287788
    Abstract: The present invention relates to a process for the continuous production of thermoplastically processable polyurethane elastomers, by metering a polyisocyanate (A), a proportion of 1-80 equivalent%, based on the isocyanate group content of the polyisocyanate (A), of a compound (B) having an average of at 1.8-3.0 hydrogen atoms having Zerewitinoff activity, with an average molar mass of 450-5000 g/mol, and a proportion of 12-99 equivalent%, based on the isocyanate group content of the polyisocyanate (A), of a chain extender (C), into a self-cleaning twin-screw extruder whose diameter is 32-62 mm, which is operated at shear rates above 6000 s?1 and residence times of 1-20 seconds, and then bringing the mixture from the self-cleaning twin-screw extruder into a second apparatus in order to complete the reaction.
    Type: Grant
    Filed: January 31, 2006
    Date of Patent: October 16, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Scholz, Marian Mours, Sven Lawrenz, Horst Papenfuss, Christoph Bahr, Ruediger Krech
  • Publication number: 20120252973
    Abstract: The present invention relates to a pultrusion resin system, comprising (a) di- or polyisocyanates, (b) compounds having at least two groups reactive toward isocyanates, (c) catalyst, (d) polybasic acid with functionality greater than or equal to 2 and, optionally, (e) further auxiliaries and additives, where the boiling point of the polybasic acid is at least 200° C. at standard pressure and it is soluble in the compound having at least two groups reactive toward isocyanates. The invention further relates to a process for producing a pultrudate, and also to this pultrudate.
    Type: Application
    Filed: November 30, 2010
    Publication date: October 4, 2012
    Applicant: BASF SE
    Inventors: Katrin Nienkemper, Bert Neuhaus, Daniela Fisser-Schmalkuche
  • Patent number: 8241545
    Abstract: The present disclosure provides a method for preparing polylactic acid and its products using a twin-screw extruder, comprising the step of mixing carbon dioxide adducts of carbene and lactide, and obtaining polylactic acid and its products via reactive extrusion using a twin-screw extruder.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: August 14, 2012
    Assignee: Nanjing Universty of Technology
    Inventors: Zhenjiang Li, Pingkai Ouyang, He Huang
  • Publication number: 20120128916
    Abstract: There are provided a molded object, a method of producing the same, a sealed molded object, a polymer, and an optical information recording medium, in each of which curing may be achieved at around room temperature in a short time without addition of an accelerator, and volumetric shrinkage accompanying the curing may be suppressed. The molded object is obtained by curing a curable composition containing a silicon analogue having one or more epoxy groups and an ?-hydroxy acid.
    Type: Application
    Filed: November 3, 2011
    Publication date: May 24, 2012
    Applicant: Sony Corporation
    Inventor: Noriyuki Saito
  • Patent number: 8105540
    Abstract: A method of treating a polymer compound has the steps of: mixing and agitating the polymer compound and a chemical agent in an extruder while controlling the inside of the extruder to be kept at a high temperature and a high pressure to have a reaction mixture containing a polymer treated product; supplying the reaction mixture continuously into a high-pressure container disposed following the extruder and retaining the reaction mixture at the high temperature and high pressure for a predetermined time; then supplying the reaction mixture continuously to a chemical agent separator to separate the polymer treated product; and supplying the separated polymer treated product continuously to a molding means to form it into a molded material.
    Type: Grant
    Filed: June 23, 2010
    Date of Patent: January 31, 2012
    Assignees: Hitachi Cable, Ltd., The Japan Steel Works, Ltd.
    Inventors: Toshiharu Goto, Takanori Yamazaki, Yoshihiko Iwamoto, Jun Kakizaki
  • Publication number: 20120001362
    Abstract: A spin pack assembly for use in melt spinning elastic fibers. The spin pack assembly includes a circular breaker plate having a center aperture and several circular patterns of apertures with each circular pattern having a plurality of apertures. Each circular pattern is located concentrically about an axis of the center aperture. The apertures in the outer circular patterns have a greater diameter than the apertures in the inner circular patterns. The spin pack assembly also has a spinneret plate where the exit aperture of the spinneret plate is recessed in the body of the spin pack assembly.
    Type: Application
    Filed: September 17, 2010
    Publication date: January 5, 2012
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Ravi R. Vedula, James E. Bryson, JR.
  • Patent number: 8021586
    Abstract: A curable resin composition and powder coating compositions made therefrom including (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure provided that the polyether structure of said immiscible block segment contains at least one or more alkylene oxide monomer units having at least four carbon atoms; such that when the epoxy resin composition is cured, the toughness of the resulting cured epoxy resin composition is increased; and (c) at least one curing agent required for the manufacturing, application and proper performance of the powder coating. The amphiphilic block copolymer is preferably an all polyether block copolymer such as a PEO-PBO diblock copolymer or a PEO-PBO-PEO triblock copolymer.
    Type: Grant
    Filed: November 2, 2005
    Date of Patent: September 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Kandathil E. Verghese, Marcos P. Franca
  • Publication number: 20110207907
    Abstract: The invention relates to a gel-spinning process for producing UHMWPE fibers, said process comprising the steps of a) feeding a slurry containing UHMWPE and a spinning solvent to an extruder; b) converting the slurry in the extruder into a solution of UHMWPE in the spinning solvent; c) spinning fluid UHMWPE fibers by passing the solution of step b) through a spinning plate containing a plurality of spin holes; d) cooling the fluid UHMWPE fibers to form gel UHMWPE fibers; e) removing at least partly the spinning solvent from the gel UHMWPE fibers; and f) drawing the UHMWPE fibers in at least one drawing step before, during and/or after removing the spin solvent characterised in that the spinning plate having at most 6 spin holes per cm2.
    Type: Application
    Filed: November 20, 2009
    Publication date: August 25, 2011
    Inventor: Joseph Arnold Paul Maria Simmelink
  • Patent number: 7993569
    Abstract: The present invention provides a method of manufacturing high-melting-tension heat-resistant transparent or opaque sheets, boards, and molds from polyethylene terephthalate (PET). The method is characterized in that a mixture of: (1) PET polyester whose melt flow rate (MFR) is 45-130 g/10 minutes (a); (2) coupling agent master batch (f) comprising coupling agent (d) and substrate (e), wherein coupling agent (d) is a mixture of compounds containing 2 epoxy groups (b) and compounds containing 3 or more epoxy groups (c); and (3) catalyst master batch (i) comprising coupling reaction catalyst (g) and substrate (h); is melted in a reaction-extruder to give PET polyester whose MFR is 40 g/10 minutes or less.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: August 9, 2011
    Assignees: FTEX, Incorporated, Nakamoto Packs Co., Ltd.
    Inventors: Yukio Kobayashi, Takashi Fujimaki, Takashi Nakamoto
  • Publication number: 20110180957
    Abstract: The invention relates to products and processes employing coupling activator compounds represented by the following formula I: S—X-A??(I) wherein S represents a silane coupling moiety capable of bonding with the surface of an inorganic substrate, A represents a ring-opening polymerization activator moiety, or blocked precursor thereof, and X represents a linking moiety. Substrates containing the coupling activator compounds are useful in preparing reinforced resins.
    Type: Application
    Filed: April 8, 2011
    Publication date: July 28, 2011
    Inventors: Thomas Burghardt, Jawed Asrar, Klaus Friedrich Gleich
  • Publication number: 20110086568
    Abstract: The present invention relates to fibers comprising at least 98 wt % of a propylene polymer having, in particular, a specific molecular weight distribution Mw/Mn and xylene solubles content. The present invention also relates to nonwovens, laminates and composites comprising such fibers. Furthermore, the present invention relates to a process for producing such fibers, nonwovens, laminates and composites.
    Type: Application
    Filed: December 12, 2008
    Publication date: April 14, 2011
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Alain Standaert, Hugues Haubruge, GuilLaume Pavy, Jerome Gromada
  • Publication number: 20110062636
    Abstract: Methods and apparatus are disclosed for binding of particulate materials to manufacture articles including continuous panels or sheets (22). Particulate feed materials are mixed with a heat curable binder and the mixture (21) is fed to and compressed in a die (25). A radio frequency (RF) field is applied across electrodes (28, 29) between which the mixture is held compressed to inductively or dielectrically heat and cure the binder. Prior to entering the die (25) the mixture is first fed to an intake zone (32) where the mixture is shaped into substantially the same shape as the shape of the mixture in the die so that any curing of the binder due to heating of the mixture in the intake zone (32) occurs while the mixture is in the desired final shape. Operating parameters including shape and dimensions of the intake zone, mixture advancement lengths, are disclosed.
    Type: Application
    Filed: May 25, 2009
    Publication date: March 17, 2011
    Applicant: PANEL BOARD HOLDING B.V.
    Inventor: Richard Laurance Lewellin
  • Patent number: 7767124
    Abstract: A method of treating a polymer compound has the steps of: mixing and agitating the polymer compound and a chemical agent in an extruder while controlling the inside of the extruder to be kept at a high temperature and a high pressure to have a reaction mixture containing a polymer treated product; supplying the reaction mixture continuously into a high-pressure container disposed following the extruder and retaining the reaction mixture at the high temperature and high pressure for a predetermined time; then supplying the reaction mixture continuously to a chemical agent separator to separate the polymer treated product; and supplying the separated polymer treated product continuously to a molding means to form it into a molded material.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: August 3, 2010
    Assignees: Hitachi Cable, Ltd., The Japan Steel Works, Ltd.
    Inventors: Toshiharu Goto, Takanori Yamazaki, Yoshihiko Iwamoto, Jun Kakizaki
  • Publication number: 20100181697
    Abstract: A method for producing a proton-conducting, polyazole-containing membrane, in which A) a composition containing polyphosphoric acid and at least one polyazole and exhibiting a solution viscosity in the range from 10 Pa·s to 1000 Pa·s, measured to DIN 53018 at the temperature at the orifice during production of the membrane, is pressed through an orifice at a temperature in the range from 25° C. to 300° C., and B) the composition is then solidified.
    Type: Application
    Filed: September 11, 2007
    Publication date: July 22, 2010
    Applicant: BASF FUEL CELL GHBH
    Inventors: Oemer Uensal, Mathias Weber, Gunter Christ, Christian Dörr, Daniel Walczyk, Tequila Harris
  • Patent number: 7731879
    Abstract: A process for the extrusion of peroxide crosslinked polymer parts, mainly tubes, in which the crosslinkable polymer is heated in an extruder in a controlled manner to a value above the crystallite melting point of the polymer, but below the crosslinking temperature, and fed continuously to an extrusion die to create the part and in which at least a partial crosslinking of the polymer is achieved in the extrusion die by heating of the polymer above a crosslinking temperature provision.
    Type: Grant
    Filed: October 23, 2003
    Date of Patent: June 8, 2010
    Assignee: Rehau AG & Co.
    Inventors: Karlheinz Winter, Gerhard Dunkel, Günther Seewald, Hermann Zwilling
  • Publication number: 20100087602
    Abstract: A method comprising contacting a polypropylene, an acrylate-containing compound, and an initiator to form a composition, and reactive extruding the composition to form a polymer blend. A method comprising contacting a polypropylene, a multi-functional acrylate monomer, and an initiator to form a composition, reactive extruding the composition to form a reactive extruded composition, and forming the reactive extruded composition into a film wherein the reactive extruded composition has a melt flow rate that is reduced by equal to or greater than 5% when compared to neat polypropylene.
    Type: Application
    Filed: October 8, 2008
    Publication date: April 8, 2010
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Fengkui Li, Ryan L. Albores, John Bieser