Utilizing Added Agent (e.g., Flux, Plasticizer, Dispersing Agent, Etc.) Patents (Class 264/211)
  • Patent number: 5316717
    Abstract: A process for making gelatine films, in particular sheet gelatine, from powdered gelatine includes the following steps: The powdered gelatine with the addition of water is plasticized by the application of shearing forces at an elevated pressure and an elevated temperature, the plasticized mass is pressed in the form of a film through a slotted die, the film is drawn off the slotted die under tension and the taut film is dried.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: May 31, 1994
    Assignee: Deutsche Gelatine-Fabriken Stoess AG
    Inventors: Peter Koepff, Klaus Braumer, Helmuth Stahl, Eberhard Dick
  • Patent number: 5316578
    Abstract: A process for the production of a homogeneous, thermoplastically processible melt. The process includes a. introduction of chemically modified starch into an intake zone of an extruder and conveyance thereof to a receiving zone, b. addition of a prehomogenized liquid mixture of plasticizer, emulsifier, and additives, followed by mixing and further conveyance of the starch liquid mixture through the receiving zone at elevated temperature, c. destructurization of the modified starch without adding any water and conveyance of the starch and mixture at elevated temperature to form a homogeneous, thermoplastically processible melt, d. degassing of the melt at elevated temperature and under reduced pressure, and e. extrusion thereof through a die at elevated temperature and pressure.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: May 31, 1994
    Assignee: Ems-Inventa AG
    Inventors: Friedrich S. Buehler, Josef Casanova, Hansjorg Ernst, Hans-Joachim Schultze
  • Patent number: 5316714
    Abstract: A monodispersed glycol suspension having excellent dispersion stability, including a monodispersed suspension in a glycol of spherical fine particles of an amorphous inorganic oxide having an average particle diameter of 0.05 to 5 micrometers and a relative particle size standard deviation of 1.0 to 1.5 and containing glycol bonded to its surface. This monodispersed suspension is useful as a raw material for the production of a polyester film having improved slipperiness.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: May 31, 1994
    Assignee: Nippon Shokujai Kagaku Kogyo Co., Ltd.
    Inventors: Tadahiro Yoneda, Saburo Nakahara, Mitsuo Takeda, Midori Kamo
  • Patent number: 5314754
    Abstract: This invention relates to a method of producing starch derived shaped articles and in particular, a method of producing films derived from high amylose starch. In the method, a hot melt is prepared by heating under pressure a composition comprising a high amylosic material, or a derivative thereof, and sufficient water to provide a homogeneous melt for subsequent extrusion as a shaped article. The hot melt is subjected to an atmospheric or subatmospheric pressure immediately prior to or during extrusion so as to remove water from the hot melt prior to the formation of the shaped article. Preferably, the high amylosic material is derived from Goodman Fielder Mills Pty. Limited maize hybrids 55/77 or 65/88. The starch derived films produced by the method are particularly suitable for use in oxygen barrier laminates and as biodegradable mulch films.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: May 24, 1994
    Assignee: Goodman Fielder Wattie Australia Limited
    Inventor: Adrian T. Knight
  • Patent number: 5306456
    Abstract: Thermoplastic articles, preferably of polycarbonate, are advantageously stabilized by selected bisbenzophenone UV absorbers concentrated in the outer surface or coating layers of the article prepared by coextrusion techniques.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: April 26, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Suhadolnik, James H. Botkin, Carmen Hendricks
  • Patent number: 5306745
    Abstract: A composition includes a blend of an additive, such as a fungicide, encapsulated in a first thermoplastic resin and a second thermoplastic resin which has a lower melting point than the first resin. During extrusion of the blend, the second resin melts and surrounds the encapsulated additive before the first resin melts. Thus composition is especially useful in combination with a multilayer film including a core layer made up of the composition, and respective further layers laminated to each side of the core layer. These films are useful in packaging articles such as fruits and vegetables to protect them from fungal infections.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: April 26, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Vincent W. Herran, Livio Buongiorno
  • Patent number: 5304590
    Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: April 19, 1994
    Assignee: Solcas Polymer, Inc.
    Inventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
  • Patent number: 5298210
    Abstract: The invention involves the use of about 1 to 4 %wt cured elastomer irregularly-shaped particles having a sieve size of about 0.7 mm +/-0.1 mm in uncured elastomer to suppress bubble formation without substantial loss of tensile strength, in calendered, cured elastomer products, such as, decorative or sealing sheet materials.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: March 29, 1994
    Assignee: Firma Carl Freudenberg
    Inventors: Klaus Heckel, Herbert Arnold, Gerhard Graab
  • Patent number: 5290850
    Abstract: An improved process for melt spinning a pigmented hexamethylene adipamide fiber from a melt blend of a polymer and a colored pigment wherein the polymer is a random interpolyamide or a block polymer having two different difunctional recurring amide-forming moieties other than those which form hexamethylene adipamide is disclosed along with pigmented hexamethylene adipamide polymer fibers having tenacities greater than 7.5 or even 8 grams per denier.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: March 1, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ketan G. Shridharani, Peter R. Witt, Perry H. C. Lin, Sundar M. Rao
  • Patent number: 5288318
    Abstract: A method and composition are provided for making biodegradable injection ded parts from 30% to 70% cellulose acetate, 10% to 60% unmodified raw (whole) starch and 5% to 35% plasticizer including glycerols and glycerol acetates. Other ingredients that can be used include: starch, flour and paper acetates; gelatin; boric acid; and agricultural fillers. The solid ingredients are combined and fed to an extruder used to make pellets or to feed injection molding equipment. The resulting parts are clear to white or colorful depending upon the added filler materials. The plastics formed are water resistant, high strength and biodegradable.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: February 22, 1994
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Jean M. Mayer, Glenn R. Elion
  • Patent number: 5288446
    Abstract: The present invention provides a novel process which imparts anisotropy strength to a rubber article. The process of the present invention includes mixing a rubber composition under a shearing force in a certain direction and then vulcanizing it in a mold, wherein said rubber composition comprises a base rubber, 3 to 100 parts by weight of a metal salt of an alpha, beta-unsaturated fatty acid, and 0.5 to 5.0 parts by weight of an organic peroxide; parts by weight being based on 100 parts by weight of base rubber.
    Type: Grant
    Filed: September 11, 1992
    Date of Patent: February 22, 1994
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Tomoko Noyama, Akihiro Nakahara
  • Patent number: 5286437
    Abstract: A method is disclosed for the production of extruded plastic products by using an extruder (1) which has an extruder hopper (2) which is supplied with a hot mixture obtained by discontinuous mixing of PVC powder and aditives in a hot mixing zone, with the supply of frictional heat, wherein a first amount of PVC powder is mixed with an excess of additives with the supply of frictional heat, after which the mixture thus obtained is homogenised in the same mixing zone with a supplementary amount of PVC powder, in such a way that the final mixture has the desired concentration of additives, after which the hot mixture obtained after homogenisation is fed directly to the extruder hopper (2). An installation for the production of plastic products by extrusion, comprising a discontinuously operating hot mixer is also disclosed, as well as said hot mixer (3).
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: February 15, 1994
    Assignee: Wavin B.V.
    Inventor: Hendrik Severiens
  • Patent number: 5286422
    Abstract: A halogen group solvent comprising a mixed solvent consisting essentially of bromochloromethane and/or 1,2-dichloroethylene and a co-solvent, wherein the co-solvent is at least one member selected from the group consisting of carbon dioxide, sulfur hexafluoride, difluorochloromethane, 1,1,1,2-tetrafluoroethane, etc., and the content of said co-solvent in the mixed solvent is 3 to 65% by weight; a polyolefin solution using the solvent; and a process for producing a three-dimensional fiber of a polyolefin using the solution.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: February 15, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Jinichiro Kato, Toshio Yoneyama, Kazuhiko Shimura, Yoshiaki Nakayama, Kenji Kanekiyo
  • Patent number: 5283023
    Abstract: A method of forming a nonwoven web having delayed wettability, in that the web is not wettable by water upon its formation but becomes wettable within from about three hours to about 30 days thereafter without any post-formation treatment, which method involves the steps of (1) melting a mixture consisting of a thermoplastic polyolefin, and additive, and a retardant coadditive; (2) forming fibers by extruding the resulting melt through under defined conditions of shear and throughput; (3) drawing the fibers; and (4) collecting the fibers on a moving foraminous surface as a web of entangled fibers. The additive is a defined polysiloxane polyether having a molecular weight of from about 700 to about 1,300 and a polydispersity of from about 1.3 to about 3.0. The additive is present in an amount of from about 1.8 to about 3.0 percent by weight, based on the amount of thermoplastic polyolefin.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: February 1, 1994
    Assignee: Kimberly-Clark Corporation
    Inventors: Ronald S. Nohr, John G. MacDonald
  • Patent number: 5281378
    Abstract: High strength spun melt fiber is prepared by utilizing threadline oxidative chain scission degradation of hot fiber spun from polymer component(s) having a broad molecular weight distribution in conjunction with a delayed quench step.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: January 25, 1994
    Assignee: Hercules Incorporated
    Inventor: Randall E. Kozulla
  • Patent number: 5279769
    Abstract: The invention relates to a method for preparing a conductive polymer product by doping a conductor polymer. The conductor polymer or a mixture of the conductor polymer and a matrix polymer is in a molten state brought into contact with a doping agent, whereafter the mixture is treated into a product.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: January 18, 1994
    Assignee: Neste Oy
    Inventors: Timo Kokkonen, Toivo Karna, Jukka Laakso, Per Nyholm, Jan-Erik sterholm, Henrik Stubb
  • Patent number: 5277855
    Abstract: The present invention is directed to a process for forming a yarn having at least one conductive filament wherein the conductive and nonconductive filaments which make up the yarn are simultaneously co-spun. The present process can be performed at spinning speeds of above about 3500 meters per minute to produce a yarn useful in antistatic carpet production.
    Type: Grant
    Filed: October 5, 1992
    Date of Patent: January 11, 1994
    Inventors: Lawrence E. Blackmon, John D. Forster, Walter J. Nunning
  • Patent number: 5277851
    Abstract: A method of making a porous polymeric material by heating a mixture of a thermoplastic polymer and a cationic or non-ionic surfactant having a hydrophilic-lipophilic balance range of 4.0 to 6.0 to a temperature and for a time sufficient for the polymer and surfactant to mutually dissolve. The mixture is then cooled to a temperature so that non-equilibrium liquid-liquid phase separation takes place to form a bi-continuous matrix of the polymer and surfactant so that the polymer and surfactant form two intermingled separate phases of large interfacial surface area. The surfactant is then removed from the polymer. The porous polymeric material produced by the above method has a lacey or filamentous structure consisting of a plurality of polymer strands connected together at spaced apart locations along each strand.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: January 11, 1994
    Inventors: Douglas L. Ford, Clinton V. Kopp, Robert J. W. Streeton
  • Patent number: 5275774
    Abstract: In a process for extruding or injection moulding starch-containing composition, a substantially transparent product is produced by providing that the starch used contains less than 8% by weight of water, that the water content of the starch in the barrel of the extruder or injection moulding machine is controlled so as to be within the range of from 5 to 20% by weight (based on the weight of the starch) and that water is removed from the composition immediately before the composition leaves the barrel of the extruder or the injection moulding machine so that the water content of the composition passing through the die and/or entering the mould is less than 3% by weight of the starch.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: January 4, 1994
    Assignee: Cerestar Holdings, B.V.
    Inventors: Kark-Heinz Bahr, Michael G. Fitton, Helmut Koch
  • Patent number: 5275854
    Abstract: Disclosed is a shaped article comprising a continuous oriented thermoplastic polymer matrix having dispersed therein microbeads of a polymer which are at least partially bordered by void space, the microbeads being present in an amount of about 5-50% weight based on the weight of said oriented thermoplastic, said void space occupying about 2-60% by volume of said shaped article. Preferably, the microbeads are cross-linked to an extent they will be resilient and elastic at the orientation temperature, and are coated with a slip agent. The shaped article is preferably in the form of a sheet, fibers, or other molded article, and preferably has a relatively low specific gravity and whiteness.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: January 4, 1994
    Assignee: Eastman Kodak Company
    Inventors: Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glenn C. Smith
  • Patent number: 5271883
    Abstract: There is disclosed a nonwoven web for use as a barrier layer in an SMS fabric laminate. The web is formed at commercially acceptable polymer melt throughputs (greater than 3 PIH) by using a reactor granule polyolefin, preferably polypropylene, that has been modified by the addition of peroxide in amounts ranging from up to 3000 ppm to reduce the molecular weight distribution from an initial molecular weight distribution of from 4.0 to 4.5 Mw/Mn to a range of from 2.2 to 3.5 Mw/Mn. Also the addition of peroxide increases the melt flow rate (lowers viscosity) to a range between 800 up to 5000 gms/10 min at 230.degree. C. The resulting web has an average fiber size of from 1 to 3 microns and pore sizes distributed predominantly in the range from 7 to 12 microns, with a lesser amount of pores from 12 to 25 microns, with virtually no pores greater than 25 microns, and with the peak of the pore size distribution less than 10 microns.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: December 21, 1993
    Assignee: Kimberly-Clark Corporation
    Inventors: Terry K. Timmons, Peter Kobylivker, Lin-Sun Woon
  • Patent number: 5269996
    Abstract: A method for producing ultra fine denier cellulose acetate fibers that entails spinning a spinning solution containing adequately high amounts of cellulose acetate in acetone wherein the cellulose acetate has a falling ball viscosity of 15 to 70 seconds wherein the spinning is conducted through spinnerettes having holes that have a diameter of less than 36 microns followed by drying at a temperature of about 50.degree. to 80.degree. C. at a draw ratio of 0.9 to 1.7.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: December 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Benedict M. Lee, Charles S. Winebarger
  • Patent number: 5269995
    Abstract: A process and apparatus for the coextrusion of a multilayer polymeric body is provided which incorporates protective boundary layers into the body, protecting the layers from instability and breakup during layer formation and multiplication. The process includes the steps of providing at least first and second streams of heat plastified extrudable thermoplastic material which are combined to form a composite stream having the first substreams and second substreams interdigitated. A third stream of heat plastified thermoplastic material is supplied to the exterior surfaces of the composite stream to form protective boundary layers adjacent the walls of the coextrusion apparatus through which the heat plastified polymer streams pass. Layer instability and breakup are avoided using process conditions which would otherwise adversely affect the optical and/or mechanical properties of the articles which are formed.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: December 14, 1993
    Assignee: The Dow Chemical Company
    Inventors: Ravi Ramanathan, Walter J. Schrenk, John A. Wheatley
  • Patent number: 5264174
    Abstract: According to the present invention, there is provided a process for stably producing a compositely reinforced polypropylene composition having less warpage deformation and good moldability which includes the steps of using an extruder having at least three feed inlets, feeding an organic peroxide and a polypropylene resin selected from (a) a polypropylene modified by grafting an unsaturated organic acid thereonto, (b) a mixture of the resulting modified polypropylene and an unmodified polypropylene, (c) a mixture of an unsaturated organic acid and an unmodified polypropylene or (d) mixtures of the foregoing to the extruder through the first feed inlet of the extruder, feeding the lamellar inorganic filler thereto through the second feed inlet disposed at a position where the resin mixture is sufficiently melted and kneaded, feeding the glass fiber through the third feed inlet, and then melting and kneading these materials.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: November 23, 1993
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Hiroshi Takei, Rikio Yonaiyama, Minoru Yoshimitsu, Nobukazu Atsumi
  • Patent number: 5258149
    Abstract: The present invention relates to the efficient removal of low density lipoprotein cholesterol complex (LDL-C) from whole blood. More specifically, it relates to a process for making a microporous plasmapheresis membrane having an immobilized affinity agent. The immobilized affinity agent is polyacrylic acid bound directly and/or through an interaction with silica and/or calcium chloride to a microporous hollow fiber membrane.
    Type: Grant
    Filed: May 5, 1992
    Date of Patent: November 2, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marc E. Parham, Richard L. Duffy, Donald T. Nicholson
  • Patent number: 5250240
    Abstract: A process is provided which allows economical production of polyolefin separation membranes having various structures, porosities and pore sizes. The process involves using a melt blend solution consisting of a polyolefin such as polypropylene or polyethylene and a diluent selected from the group consisting of natural soybean oil, pure linoleic acid, or a mixtures of oleic acid, linoleic acid and palmitic acid.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: October 5, 1993
    Assignee: Korea Institute of Science and Technology
    Inventors: Jae-Jin Kim, Sung-Soo Kim, Jeong-Rim Hwang, Sang-Bong Suh
  • Patent number: 5250237
    Abstract: A process is provided for flash-spinning plexifilamentary film-fibril strands of a fiber-forming polyolefin from a C.sub.1-4 alcohol or a C.sub.1-4 alcohol/co-solvent spin liquid that, if released to the atmosphere, presents no or a greatly reduced ozone depletion hazard, as compared to the halocarbon spin liquids currently-used commercially for making such strands. The resulting flash-spun plexifilamentary film-fibril strands are well fibrillated and are of a quality equivalent to commercially available strands. The invention also covers the spin liquids useful in the inventive process.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: October 5, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hyunkook Shin
  • Patent number: 5246657
    Abstract: A polyolefin fiber having improved initial elongation and two characteristic melting point peaks, average creep rate, modulus and tensile strength is obtained by milk-kneading a composition containing two different ultra-high-molecular-weight polyolefins each having an intrinsic viscosity of at least 5 dl/g. The first polyolefin is polyethylene. The second polyolefin is an ethylene/.alpha.-olefin copolymer, e.g., ethylene/propylene, wherein the content of the .alpha.-olefin is such that the number of side chains of the .alpha.-olefin per 1000 carbon atoms in the copolymer is from 0.5 to 10, on average. The weight ratio of the ethylene polymer to the ethylene copolymer is from 10/90 to 90/10. The mixture of the two ultra-high-molecular-weight polyolefins is melt-kneaded in the presence of a diluent, such as wax, and the kneaded mixture is spun and drawn to a draw ratio of at least 10.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: September 21, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kazuo Yagi, Hiroyuki Takeda
  • Patent number: 5240665
    Abstract: An improved extrudable solution such as a cellulose acetate/acetone spinning solution is provided containing cellulose ester, solvent, metal oxide precursor, acid, and water. The solution is extruded such as by spinning and produces a shaped article such as a cellulose acetate fiber containing metal oxide interpenetrating networks.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: August 31, 1993
    Assignee: Eastman Kodak Company
    Inventors: Kab S. Seo, Christine J. Landry, Bradley K. Coltrain, James D. Cloyd
  • Patent number: 5240983
    Abstract: A process for producing a polyolefin thermoplastic elastomer composition having superior rubbery elasticity, mechanical properties, etc. and also having improved processing fluidity, workability, etc. is provided, which process comprises blending(A) 40 to 80% by weight of an ethylene-propylene copolymer rubber and/or an ethylene-propylene-diene terpolymer, as a soft segment component,(B) 60 to 20% by weight of a crystalline ethylene-propylene block copolymer having an ethylene content of at least 5% by weight and a melt flow index of 0.5 to 30 g/10 minutes or a crystalline ethylene-propylene random copolymer having an ethylene content of at least 1.5% by weight and a melt flow index of 0.5 to 30 g/10 minutes, each as a hard segment, and based upon 100 parts by weight of the total of (A) and (B),(C) 0.3 to 5 parts by weight of an organosilane,(D) 0.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: August 31, 1993
    Assignee: Chisso Corporation
    Inventors: Nobuchika Tabata, Fumikazu Saito, Hisao Iizuka, Yutaka Nozokido
  • Patent number: 5238982
    Abstract: Disclosed is a method for producing polyamide fibers with reduced flammability by melt mixing a polyamide with a phosphate ester of the general formula: ##STR1## wherein n is a number of from 1 to 10;m is a number of from 0 to 3;x is a number of from 0 to 3;R is linear or branched C.sub.1 - to C.sub.18 - alkyl radical;at a temperature of from about 180.degree. to about 280.degree. C., and melt spinning fibers.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: August 24, 1993
    Assignee: BASF Corporation
    Inventors: Atish Adhya, Robert L. Lilly
  • Patent number: 5238637
    Abstract: Process for improving the output efficiency during the spinning of a polyamide-based preoriented yarn at a speed of at least 4000 m/min by introduction, before the spinning, of a quantity of 0.05 to 1% by weight of pyrogenic silica of particle size of between 5 and 15 nm into the molten polymer in the form of dispersion in a master mix of the same polyamide as than intended to be processed, the filaments after spinning being then cooled by means of a gas stream at room temperature and then sized and wound at a speed of between 4200 and 5800 m/min.The preoriented yarns thus prepared exhibit a delay in the orientation and are obtained with a gain in output efficiency of at least 10%, generally at least 15%.
    Type: Grant
    Filed: May 21, 1992
    Date of Patent: August 24, 1993
    Assignee: Rhone-Poulenc Fibres
    Inventors: Olivier Chaubet, Walter Roggenstein, Noel Witmeyer
  • Patent number: 5238635
    Abstract: Disclosed is a process for treating olefin polymer particles with phosphite- and phosphonite-free compositions consisting essentially of:A. a polyhydric alcohol ester of a hindered phenol derivative of propionic acid having a melting point or melting range below about 130.degree. C.,B. about 20 to 35 parts based on 100 parts by weight of component A of a mono-ester of a hindered phenol derivative of propionic acid having a melting point or melting range below about 130.degree. C.,C. about 20-75 pph of a viscosity-reducing agent having a viscosity of about 180 to 55,000 Saybolt Universal Seconds at 100.degree. F. (38.degree. C.),D. up to 1000 pph each of an antistatic agent, a slip agent or mixture thereof andE. up to 1000 pph each of a light stabilizer, a thioether, an organic polysulfide, an acid scavenger or neutralizer, a nucleating agent, or a mixture thereof. The resulting surface-treated polymer particles and end uses therefor are also disclosed.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: August 24, 1993
    Assignee: Himont Incorporated
    Inventors: Bryan J. Launchbury, Alain Lerou
  • Patent number: 5238631
    Abstract: Process for making wireless twist ties including extruding and quenching molten polymeric materials to form ribbon or perforated sheets. Wireless twist ties include polymeric material, such as polyethylene terephthalate, polyvinylchloride, styrene-acrylonitrile copolymer and polystyrene and particulate rubber impact modifier. Wireless twist ties, when elongated, exhibit deformation before failure of at least 50%.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: August 24, 1993
    Assignee: Kyowa Limited
    Inventors: Richard D. Stolk, Vladimir O. Bekker
  • Patent number: 5238630
    Abstract: Extrudable labelstock for in-mold labeling purposes which has a tensile ultimate elongation per ASTM D-882 of at least about 10% in one or both of the machine and transverse directions, and which contains a sufficient amount of one or more slip additives to prevent a significant degree of edge-welding between adjacent stacked sheets of the labelstock on a high type die cutter in an in-mold labeling process, and the improved in-mold labeling process employing such labelstock.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: August 24, 1993
    Assignee: The Dow Chemical Company
    Inventor: Harvey C. Tung
  • Patent number: 5236644
    Abstract: The present invention relates to the efficient removal of low density lipoprotein cholesterol complex (LDL-C) from whole blood. More specifically, it relates to the use of an immobilized affinity agent on a microporous plasmapheresis membrane. The immobilized affinity agent is polyacrylic acid bound directly and/or through an interaction with silica and/or calcium chloride to a microporous hollow fiber membrane.
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: August 17, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marc E. Parham, Richard L. Duffy, Donald T. Nicholson
  • Patent number: 5236645
    Abstract: Additives are introduced into a thermoplastic melt by feeding at least one additive in an aqueous vehicle containing a dispersant to form an aqueous additive stream to a vented extruder which is extruding a thermoplastic followed by volatilizing an aqueous portion of the aqueous additive stream and removing substantially all the volatilized aqueous portion through the extruder vent to achieve a substantially homogeneous system containing the thermoplastic and at least one additive and forming a fiber from the homogeneous system by extrusion of the system through a spinneret.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: August 17, 1993
    Assignee: BASF Corporation
    Inventor: Frank R. Jones
  • Patent number: 5236649
    Abstract: The present invention is a coated particulate in the form of a powder or in the form of a pellet, the particulate comprising a vinylidene chloride interpolymer and being coated with at least one processing aid at a level effective to improve the extrudability of the vinylidene chloride interpolymer. The processing aid beneficially is selected from the group consisting of fatty esters; wax esters; glycerol esters; glycol esters; fatty alcohol esters, fatty alcohols; fatty amides; metallic salts of fatty acids; olefin polymers and polyolefin waxes.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: August 17, 1993
    Assignee: The Dow Chemical
    Inventors: Mark J. Hall, Stephen R. Betso, Duane F. Foye, Kun S. Hyun, Steven R. Jenkins, Donald E. Kirkpatrick, Paul T. Louks, James A. Stevenson
  • Patent number: 5236652
    Abstract: The invention provides a process for making polyamide fiber with high molecular weight and/or chemical and thermal resistance using conventional single or twin screw extruders. The process includes melt-blending polyamide polymer comprising at least about 75% by weight of poly(hexamethylene adipamide) or poly(.epsilon.-caproamide) and having a formic acid relative viscosity of about 20 to about 50 with a polyamide additive concentrate comprising polyamide polymer and an additive selected from the class consisting of stabilizers, catalysts and mixtures thereof to form a molten polymer which contains about 0.05 to about 2 weight % of the additive and extruding the molten polymer from a spinneret and forming a fiber having a denier per filament of 1 to 40. Fibers made by this process have great utility in the batt of papermaking machine felts where they provide improved resistance to wear and/or chemical attack.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: August 17, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: David R. Kidder
  • Patent number: 5234648
    Abstract: The invention relates to a method for the coextrusion of a plate-shaped product. In the method according to the invention at least one coating layer is provided by means of coextrusion which is composed of a special polymer mixture. This mixture enables obtaining of a matt surface and can be provided very uniformly on the major layer of polycarbonate by coextrusion. The polymer mixture comprises 84-92% by weight of polycarbonate, 4-8% by weight of talcum and 4-8% by weight of a mattifying agent based on acrylate copolymers.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: August 10, 1993
    Assignee: General Electric Company
    Inventors: Peter W. van Es, Petrus J. Plompen
  • Patent number: 5225137
    Abstract: In general, used thermoplastic liquid containers such as oil and solvent bottles are discarded. When recycling oil bottles, the usual practice is to wash the bottles with a solvent to remove oil therefrom. Washing of the bottles results in large quantities of used, oil-containing solvent, which present a disposal problem. A simple solution to the problem of recycling liquid containers with no preliminary washing or cleaning operation includes the steps of tumbling the bottles to promote liquid separation, shredding the bottles into small pieces and draining the liquid therefrom, grinding the pieces of plastic to yield a particulate thermoplastic, and mixing the particulate thermoplastic and any liquid remaining therein with an additive, e.g. an oil absorbent and a filler such as calcium carbonate, glass, mica or talc, and when the liquid is an oil, an absorbent to produce an extrudable mixture which can be used to form new containers.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: July 6, 1993
    Assignee: ABC Group
    Inventor: Changize Sadr
  • Patent number: 5225263
    Abstract: Nonwovens of synthetic continuous filaments obtained by melt extrusion, in which at least 50% of the filaments contain at least from 0,5 to 3%, preferably from 0.6 to 1.5%, of a polyorganosiloxane introduced into the said filaments during their manufacture.Process for the manufacture of these nonwovens, in which, before extrusion of the polymer melt to produce the filaments by flowing through orifices of a die, a silicone oil of polyorganosiloxane type is introduced in the proportion at least of 0,5 to 3%, preferably from 0.6 to 1.5% relative to the polymer, into the melt of the latter.The polyorganosiloxane product employed is of the polydiorganosiloxane type with a molecular weight of between 1,000 and 250,000, preferably between 7,500 and 70,000, corresponding to dynamic viscosities of 50 to 10,000 mPa s; stable under extrusion conditions.Use of the nonwovens, chiefly as a support for floor coverings with stitched pile.
    Type: Grant
    Filed: February 13, 1991
    Date of Patent: July 6, 1993
    Assignee: Frudenberg Spunweb S.A. Societe Anonyme A. Directoire
    Inventors: Jean Baravian, Olivier Chaubet, Georges Riboulet
  • Patent number: 5223196
    Abstract: An improved process for melt-spinning a pigmented hexamethylene adipamide fiber from a melt blend of a polymer and a colored pigment wherein the polymer is a random interpolyamide or a block polymer having two different difunctional recurring amide-forming moieties other than those which form hexamethylene adipamide is disclosed along with pigmented hexamethylene adipamide polymer fibers having tenacities greater than 7.5 or even 8 grams per denier.
    Type: Grant
    Filed: November 20, 1990
    Date of Patent: June 29, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ketan G. Shridharani, Peter R. Witt, Perry H. Lin, Sundar M. Rao
  • Patent number: 5221502
    Abstract: In one embodiment this invention provides a cigarette product which contains a novel type of encapsulated flavorant-release filament. The flavorant is released under normal smoking conditions.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: June 22, 1993
    Assignees: Philip Morris Incorporated, Philip Morris Products Inc.
    Inventor: James M. Washington
  • Patent number: 5219510
    Abstract: A cellulose ester film which can be melt cast is manufactured by esterfying cellulose to form a cellulose acetate or cellulose acetate propionate having degrees of substitution of DSac=1.9 to 2.6, DSpr=0 to 0.9 and DS.sub.OH =0 to 0.55 and melt compounding the resulting polymer with a non-volatile phosphoric acid ester. A film is formed by melt extruding the compounded polymer onto a cooling surface to form a solid film. The film is then biaxially oriented at 130.degree. to 200.degree. C. and a stretch ratio of 1.25.times. to 2.5.times. in both directions. The resulting product is a film of excellent properties such as surface smoothness, light transmission, low haze, low color, high elastic modulus and curl relaxation after aqueous processing. The melt cast film is useful as a photographic roll film to replace solvent cast cellulose triacetate.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: June 15, 1993
    Assignee: Eastman Kodak Company
    Inventors: Julie S. Machell, I. Daniel Sand
  • Patent number: 5215695
    Abstract: A process for reclaiming residuals produced from the manufacture of decorative high pressure laminates (HPLs), and composite materials obtained by the process. Such residuals which include cellulose impregnated with thermosetting resins which are partially condensed, are ground to a predetermined particle size and mixed with a melted mass of thermoplastic resin under controlled pressure and temperature conditions. The mixing time is sufficiently long for completion of the reaction during which physical and chemical interactions occur between the partially polycondensed thermosetting resin and the thermoplastic resin. The material so produced can be converted into granules for subsequent injection molding. There is provided an effective solution to pollution problems and excessive expense problems associated with the disposal of scraps and residuals from the manufacture of decorative HPLs.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: June 1, 1993
    Assignee: Abet Laminati S.p.A.
    Inventors: Claudio Bortoluzzi, Raffaele Bogana
  • Patent number: 5213733
    Abstract: Synthetic textiles containing a photochromic pigment. The pigments are prepared by encapsulating a photochromic pigment in a thermoplastic polymer having a high melt flow index, mixed with a primary thermoplastic resin, and extruded at a temperature of less than 250.degree. C. through a spinnerette having a diameter of at least 0.3 ml.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: May 25, 1993
    Assignee: Industrial Technology Research Institute
    Inventors: Yean-Rong Hwu, Chi-Chung Bai, Li-Chang Tao, Der-Guey Luo, Andrew T. Hu
  • Patent number: 5213740
    Abstract: A process for the preparation of particles which includes adding to a melt mixing apparatus at least two polymers, at least one of which is insoluble, incompatible or immiscible in the other polymer or polymers, and separating the incompatible polymer from the melt mixture. Also, a process for the preparation of toner particles which includes adding to a melt mixing apparatus, or to an extrusion apparatus at least two polymers, one of which is insoluble in the other polymer, and pigment particles, melt mixing or melt extruding the aforementioned polymers and pigments, and separating the incompatible polymer domains from the resulting mixture.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: May 25, 1993
    Assignee: Xerox Corporation
    Inventor: Timothy J. Fuller
  • Patent number: 5207959
    Abstract: Process for improving the production efficiency of the spinning of an undrawn, preoriented yarn based on polyethylene terephthalate (PET) by the introduction, before the spinning, of 0.03 to 0.1% by weight of fumed silica with a particle size of between 5 and 15 nm into the molten polymer in the form of dispersion in a masterbatch of the same polymer as that to be processed, then spinning the PET containing the silica in the finely dispersed state, the filaments being next cooled by means of a gas stream at temperature between 17.degree. to 22.degree. C. and then sized and wound at a velocity of between 3500 and 5000 m/min.The gain in production efficiency, evaluated in relation to the shrinkage of the filaments in dry air at 180.degree. C., is at least 7%, generally at least 10-15%.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: May 4, 1993
    Assignee: Rhone Poulenc Fibres
    Inventors: Paul Antikow, Francois Pinaud
  • Patent number: 5205973
    Abstract: Incorporation of fibrous filler into a styrene-butadiene rubber (SBR) by mixing a fibrous filler, SBR latex and a coagulant, feeding the resulting coagulated fiber-filled SBR latex to a dewatering extruder and through a flow restriction that applies back pressure sufficient that water present in the SBR is forced out of a vent upstream from the flow restriction and discharging the fiber-filled SBR from the extruder.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: April 27, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Fred Y. Kafka