Stretching By Applying Tension Patents (Class 264/288.4)
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Patent number: 8647553Abstract: In a process of producing a stretch sheet, a strip-shaped laminate sheet 10A having an elastically stretchable elastic layer 1 and substantially inelastic, inelastic fiber layers 2 and 3 partially joined to each other at bonds 4 or a strip-shaped fibrous sheet containing an elastic component and a substantially inelastic component and having embossed regions formed by embossing in parts is stretched in directions starting from the bonds 4 or the embossed regions to obtain a stretch sheet 10. The stretch sheet has raised ridges and recessed grooves extending in the direction perpendicular to the stretch direction, and the bonds 4 or the embossed regions are present in the ridges.Type: GrantFiled: April 25, 2006Date of Patent: February 11, 2014Assignee: Kao CorporationInventors: Hideyuki Kobayashi, Koji Kanazawa, Akihiko Gunji, Tetsuya Masuki
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Patent number: 8632706Abstract: A single-sided, slip resistant, self-adhesive material is produced using a blown film process which produces a film having an interior layer capable of being treated or coated to accept a pressure sensitive adhesive, a middle layer of flexible polyolefin and an exterior polyolefin elastomer layer in combination with a blowing agent to produce a single-sided slip resistant material. A number of in-line rollers are provided after a pair of rollers, which form part of a machine direction orienter (MDO) that is used in line in the manufacturing process to heat, and then cool and condition (anneal and relieve any stresses and/or thickness inconsistencies) the film prior to the film being coated on one side with a pressure sensitive adhesive.Type: GrantFiled: August 15, 2011Date of Patent: January 21, 2014Assignee: Multi Technologies Instustrial L.L.C.Inventors: George M. Orlych, Michael C. Sullivan, Thomas Zickell
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Patent number: 8623256Abstract: A process for simultaneously activating two or more portions of a web in different directions. The process involves feeding a web into an apparatus that includes a pair of intermeshing activation rolls having three dimensional surface features configured to simultaneously activate different portions a web in different directions. The three dimensional surface features are arranged in discrete regions on the rolls such that at least two of the regions provide different directions of activation. The rolls include one or more buffer regions positioned between the discrete regions on the roll that provide different directions of activation.Type: GrantFiled: October 18, 2011Date of Patent: January 7, 2014Assignee: The Procter & Gamble CompanyInventors: Khalid Qureshi, Fred Naval Desai
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Patent number: 8617445Abstract: The present invention provides a process for producing an oriented thermoplastic polyester resin sheet which is excellent in tensile strength, tencile modulas and heat resistance, and a light laminate-molded body using the same, which has a low linear expansion coefficient and is excellent in impact resistance, durability, easiness of handling, productivity, and others. A process for producing an oriented thermoplastic polyester resin sheet, which includes: pultrusion-drawing a thermoplastic polyester resin sheet in an amorphous state at a temperature from the glass transition temperature of the thermoplastic polyester resin ?20° C. to the glass transition temperature of the thermoplastic polyester resin +20° C.; and then drawing the resultant uniaxially at a temperature higher than the temperature for the pultrusion-drawing. A laminate-molded body, wherein a thermoplastic resin layer is laminated on each of the surfaces of the resultant oriented thermoplastic polyester resin sheet.Type: GrantFiled: February 17, 2006Date of Patent: December 31, 2013Assignee: Sekisui Chemical Co., Ltd.Inventors: Shigeru Ogasawara, Hirotsugu Yoshida, Hisashi Eguchi, Ryuichi Matsuo
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Patent number: 8591998Abstract: A process in which a wound roll of biaxially oriented polyester film having a glass transition temperature (Tg (° C.)) is annealed at a temperature Ta (° C.) above Tg where Tg<Ta?Tg+100 (° C.) for a time t after thermal equilibrium where 1 hour?t?72 hours and cooled, for the purpose of improving the shrinkage of said polyester film.Type: GrantFiled: February 9, 2007Date of Patent: November 26, 2013Assignee: DuPont Teijin Films U.S. Limited PartnershipInventors: Duncan Henry MacKerron, Katsuyuki Hashimoto
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Patent number: 8579621Abstract: Provided is a method for manufacturing a high-quality porous film. Here, while the porous film is being manufactured through forming micropores by stretching, a raw film is prevented from slipping on the surfaces of the respective rolls as much as possible even though the raw film includes oil or liquid paraffin as a solvent. The method is for manufacturing a porous film through forming micropores by successive biaxial stretching. A tensile force applied to the raw film F transferring from the longitudinal stretching machine (10) to the transverse stretching machine (50) is set not less than a stretching force necessary for the longitudinal stretching, and thus the raw film is prevented from slipping on a contact surface between the raw film and each roll of the longitudinal stretching machine (10).Type: GrantFiled: July 23, 2012Date of Patent: November 12, 2013Assignee: Toshiba Kikai Kabushiki KaishaInventors: Takayoshi Sano, Satoru Nitta
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Patent number: 8568892Abstract: A coated article includes a substrate having on its surface a coating that includes a polymer selected from the group consisting of hydroxypropylcellulose, poly(2-ethyl-2-oxazoline) and mixtures of these, a surfactant, colloidal silica, and a crosslinker selected from the group consisting of water-soluble titanium salts and water-soluble or water-dispersible organic crosslinkers. The coating may be formed by applying a dispersion of the coating composition in a diluent to the substrate and subsequently drying the coated substrate to evaporate the diluent.Type: GrantFiled: October 29, 2008Date of Patent: October 29, 2013Assignee: DuPont Teijin Films U.S. Limited PartnershipInventors: Chen Zhao, David Volsin, Cornell Chappell, Jr.
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Patent number: 8568636Abstract: The present invention relates to a multilayer film coextruded from an aliphatic polycarbonate and polylactic acid-based polymer and a method for producing the same. According to the present invention, a multilayer film having excellent adhesive property can be manufactured even without a separate adhesive layer.Type: GrantFiled: August 25, 2011Date of Patent: October 29, 2013Assignee: SK Innovation Co., Ltd.Inventors: Min Ho Jeon, Ji Eun Yoo, Moon Jung Choi, Kwang Jin Chung, Myung Ahn Ok
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Publication number: 20130271833Abstract: A resin composition including a polyphenylene ether (A) and a copolymer (B) containing a repeating unit derived from a styrene compound and a repeating unit derived from maleic acid anhydride, wherein an amount of the repeating unit derived from maleic acid anhydride in the copolymer (B) is equal to or larger than 5% by weight and equal to or smaller than 20% by weight, and an amount of the polyphenylene ether (A) is equal to or more than 25 parts by weight and equal to or less than 35 parts by weight with respect to 100 parts by weight of the repeating unit derived from the styrene compound.Type: ApplicationFiled: December 27, 2011Publication date: October 17, 2013Applicant: ZEON CORPORATIONInventor: Taku Hatano
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Patent number: 8557162Abstract: A mechanical activation system has a first activation member, a second activation member, an activation zone, and a non-slip zone. The first activation member has a first plurality of teeth, and the second activation member has a second plurality of teeth. The first plurality of teeth is capable of intermeshing with the second plurality of teeth. The activation zone includes a first portion of the first plurality of teeth and a first portion of the second plurality of teeth. The first portion of the first plurality of teeth and the first portion of the second plurality of teeth include teeth having continuous tips. The first non-slip zone includes a second portion of the first plurality of teeth or a second portion of the second plurality of teeth. The second portion includes a tooth having a discontinuous tip.Type: GrantFiled: October 29, 2012Date of Patent: October 15, 2013Assignee: The Procter & Gamble CompanyInventor: Uwe Schneider
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Publication number: 20130259408Abstract: Methods of increasing the perceived thickness and strength of a thermoplastic film include incrementally stretching thermoplastic films in the machine direction. In one or more implementations, methods of incrementally stretching thermoplastic films include reducing the gauge of the films while increasing a loft of at least a portion of the film. The methods can involve cold stretching the films and imparting rib patterns and alternating peaks and valleys into the film. The linear ribs can have alternating thick and thin gauges.Type: ApplicationFiled: March 28, 2012Publication date: October 3, 2013Inventors: Michael G. Borchardt, Robert T. Dorsey
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Patent number: 8545745Abstract: A method for using a Poisson's ratio material includes a carbon nanotube film structure is provided. The carbon nanotube film structure includes a plurality of carbon nanotubes. A first part of the carbon nanotubes are aligned a first direction, a second part of the carbon nanotubes are aligned a second direction. The first direction is substantially perpendicular to second direction. When the Poisson's ratio material is stretched or compressed substantially along the first or second direction, a Poisson's ratio value is negative. When the Poisson's ratio material is stretched or compressed in a direction having an angle of about 45 degrees with the first direction, the Poisson's ratio value is positive.Type: GrantFiled: October 1, 2012Date of Patent: October 1, 2013Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Lu-Zhuo Chen, Chang-Hong Liu, Jia-Ping Wang, Shou-Shan Fan
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Patent number: 8540911Abstract: A method of generating a plurality of pipettes. The method comprises providing a tubular element, cutting the tubular element to form a plurality of two pipettes length components each having a length of about two target pipettes, simultaneously rotating the plurality of two pipettes length components, heating a central portion of each one of the rotated two pipettes length components, stretching each two pipettes length component to extend the respective central portion, and dividing each two pipettes length component at the extended central portion to form the two target pipettes.Type: GrantFiled: November 14, 2011Date of Patent: September 24, 2013Assignee: Miniplast Ein-Shemer ACS Ltd.Inventors: Eitan Ochman, Omri Shoham
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Patent number: 8535032Abstract: A film stretcher that transports a film material in a predetermined transport direction while holding an end of the film material in a width direction of the film material to stretch the film material in the width direction includes a holding unit that includes a stretching roll having an annular groove formed on an outer periphery of the stretching roll and an endless wire fitted in the annular groove over a predetermined rotation angle range of the annular groove in a circular arc shape so that the end of the film material in the width direction of the film material is pinched. The stretching roll is inclined so as to open toward a downstream side in the transport direction of the film material. The holding unit transports the film material in the transport direction while pinching the film material using the stretching roll and the endless wire, whereby the film material is stretched in the width direction.Type: GrantFiled: August 13, 2009Date of Patent: September 17, 2013Assignees: Toyota Jidosha Kabushiki Kaisha, Tokiwa Seisakusho Co., Ltd.Inventors: Hiroshi Harada, Hiroshi Suzuki, Toshiaki Kenmotsu
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Patent number: 8535588Abstract: Clipping both right and left side edge parts of a sheet or film by right and left pitch-variable clips having flow-directional clip pitches variable along with travel movements, respectively, having positions (AR, AL) for initiation of enlargements of flow-directional clip pitches changed between right clips and left clips, and enlarging flow-directional clip pitches along with travel movements of clips to thereby make an oblique stretch.Type: GrantFiled: July 17, 2007Date of Patent: September 17, 2013Assignee: Toshiba Kikai Kabushiki KaishaInventors: Takayoshi Sano, Satoru Nitta, Hiromu Saijyo
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Patent number: 8512833Abstract: The present invention relates to a heat-shrinkable polyester film, which has a heat-shrinkage of 20% or more in both the longitudinal and transverse directions when treated with 80° C. water for 30 seconds and a bidirectional balance parameter in the range of 0.25 to 2.5 and exhibits an excellent properties in die-cutting and removing from a container such as a glass bottle for recycling by washing with hot water.Type: GrantFiled: May 15, 2009Date of Patent: August 20, 2013Assignee: SKC Co., LtdInventors: Tae-Byoung Oh, Tae-Hyoung Jung, Nam Ill Kim
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Patent number: 8507057Abstract: A heat-shrinkable polyester film having a thermal shrinkage ratio of 15% or more in the longitudinal direction when treated at 100° C. for 10 seconds, a tensile strength at rupture in the longitudinal direction of 7 kgf/mm2 or more, and a difference between elongations at the hardening and yield points in the longitudinal direction of 15% or more exhibits superior properties, such as high tensile strength and crack-resistance in the longitudinal direction, suitable for labeling or shrink-wrapping containers.Type: GrantFiled: March 19, 2009Date of Patent: August 13, 2013Assignee: SKC Co., LtdInventors: Seong-Do Kim, Taehoung Jeong, Tae-Byoung Oh
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Patent number: 8501300Abstract: A method of manufacture of a coated polymeric film which comprises performing in sequence the steps of: (i) forming a substrate layer comprising poly(ethylene naphthalate) having a thickness in a range from 50 ?m to 250 ?m; (ii) stretching the substrate layer in at least one direction; (iii) heat-setting the substrate layer under dimensional restraint at a tension in the range of about 19 to about 75 kg/m of film width, at a temperature above the glass transition temperature of the poly(ethylene naphthalate) but below the melting temperature thereof; (iv) heat-stabilizing the substrate layer under a tension of less than 5 kg/m of film width, and at a temperature above the glass transition temperature of the poly(ethylene naphthalate) but below the melting temperature thereof; and (v) disposing a coating layer on a surface of the substrate layer by a process comprising applying a planarizing coating composition thereto such that a surface of said coating layer exhibits an Ra value of less than 0.Type: GrantFiled: December 17, 2009Date of Patent: August 6, 2013Assignee: DuPont Teijin Films U.S. Limited PartnershipInventors: Julian Neal Robinson, Robert William Eveson, Karl Rakos
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Patent number: 8480836Abstract: A double-sided, slip resistant material is produced using a blown film process which produces a film having an interior heat sealable layer, a core layer of flexible polyolefin and an exterior polyolefin elastomer layer in combination with a blowing agent and optionally grit to produce a double-sided slip resistant material. A number of rollers are provided after nip rollers have fused the film together, and which form part of a machine direction orienter (MDO) that is used in line in the manufacturing process to heat, and then cool and condition (anneal and relieve any stresses and/or thickness inconsistencies in the film) prior to the film being wound onto a roll for storage.Type: GrantFiled: January 18, 2010Date of Patent: July 9, 2013Assignee: Multi Technologies Industrial L.L.C.Inventors: George M. Orlych, Mike C. Sullivan
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Patent number: 8475700Abstract: Prepare an oriented polymer composition that is cavitated, has cross sectional dimensions all at least three millimeters and at least one de-oriented surface layer having a thickness of at least 80 microns and at least 50 microns less than half the thickness of the oriented polymer composition, the de-oriented surface layer having a lower degree of polymer orientation than a 100 micron thick portion of the oriented polymer composition adjacent to and below the de-oriented surface layer by sufficiently heat treating a surface of a cavitated oriented polymer composition.Type: GrantFiled: October 4, 2010Date of Patent: July 2, 2013Assignee: Eovations, LLCInventors: James J. O'Brien, Timothy O. Kirch, Kevin L. Nichols, Brett M. Birchmeier
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Patent number: 8465842Abstract: The present invention relates to a biaxial oriented polyester film and process for preparing the same, the said film is having an average ellipticity of not more than 0.6, Poisson ratio of not more than 0.7 (at elongation greater than 25%) all along the width of web and residual enthalpy in the range of 12% to 20%, a continuous reduction in residual film area up to an elongation of 100%.Type: GrantFiled: December 17, 2008Date of Patent: June 18, 2013Assignee: Polyplex Corporation LimitedInventors: Bidhan Krushna Mohanty, Krishna Reddy
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Patent number: 8440125Abstract: Disclosed is a method for producing polyethylene films which have high resistance to deformation or elongation under loading in tension. The method comprises orienting in the machine direction (MD) a high density polyethylene film at a draw-down ratio effective to give the film an MD tensile strength at yield greater than or equal to 50,000 psi, wherein the HDPE has a density greater than 0.940 g/cm3.Type: GrantFiled: June 28, 2004Date of Patent: May 14, 2013Assignee: Equistar Chemicals, LPInventor: D. Ryan Breese
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Publication number: 20130115415Abstract: A one-piece plastics material mesh structure, particularly a geogrid, is produced by stretching a plastics sheet starting material formed with an array of holes and comprises a plurality of generally parallel rib structures extending longitudinally in a first direction parallel to the stretch direction and a plurality of generally parallel bar structures extending in a second direction transverse to the rib structures. The rib structures and said bar structures are interconnected by junctions. The rib structures have rib segments oriented in the first direction along their lengths and orientation in this direction extends across the junctions connecting two such oriented rib segments. The bar structures are such that their overall stretch ratio in the second direction is a maximum of 1 and all locations along the length of the bar structures have a maximum orientation of 1.5 in the second direction.Type: ApplicationFiled: October 26, 2012Publication date: May 9, 2013Applicant: Tensar Technologies LimitedInventor: Tensar Technologies Limited
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Publication number: 20130115396Abstract: Methods of increasing the haze of a thermoplastic film include incrementally stretching thermoplastic films in the machine direction. In one or more implementations, methods of incrementally stretching thermoplastic films include reducing the gauge of the films without reducing the films' haze. The methods can involve cold stretching the films and imparting rib patterns into the film. The linear ribs can have alternating thick and thin gauges. Incrementally stretched thermoplastic films can have a haze that is approximately equal to or greater than the haze of the film prior to stretching.Type: ApplicationFiled: November 4, 2011Publication date: May 9, 2013Inventor: Michael G. Borchardt
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Patent number: 8435432Abstract: Retardation expressibility of a transparent polymer film can be easily controlled by heat treatment of the film at a temperature T (unit, ° C.) satisfying a condition of the following formula (1): Tc?T<Tm0??Formula (1) wherein Tc represents the crystallization temperature (unit, ° C.) of the film before the heat treatment; and Tm0 represents the melting point (unit, ° C.) of the film before the heat treatment.Type: GrantFiled: February 21, 2007Date of Patent: May 7, 2013Assignee: FUJIFILM CorporationInventor: Yasuyuki Sasada
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Publication number: 20130082418Abstract: A method and apparatus is provided which uses activation members for incrementally stretching a web at a low strain rate. The activation members include an activation belt and a single activation member wherein the activation belt and single activation member comprise a plurality of teeth and grooves that complement and engage one another at a depth of engagement in a deformation zone. The depth of engagement can be controlled to increase linearly over at least a portion of the deformation zone such that a web interposed between the activation belt and the single activation member in the deformation zone is incrementally stretched at a low rate of strain.Type: ApplicationFiled: November 2, 2012Publication date: April 4, 2013Applicant: THE PROCTER & GAMBLE COMPANYInventor: THE PROCTER & GAMBLE COMPANY
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Publication number: 20130029066Abstract: Methods of incrementally stretching thermoplastic films in the machine direction include elongating the films in the machine direction without reducing the films' machine-direction tear resistance. In one or more implementations, methods of incrementally stretching thermoplastic films include reducing the gauge of the films without reducing the films' machine-direction tear resistance. The methods can involve cold stretching the films and imparting transverse-direction extending linear rib pattern into the film. The linear ribs can have alternating thick and thin gauges. Incrementally stretched thermoplastic films can have a machine-direction tear resistance that is approximately equal to or greater than the machine-direction tear resistance of the film prior to stretching.Type: ApplicationFiled: July 25, 2011Publication date: January 31, 2013Inventor: Michael G. Borchardt
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Patent number: 8357321Abstract: A casting dope (11) prepared from CAP, additive and solvent is cast onto a casting belt (35), peeled and dried to be a primary film (14), and wound to a primary film roll (16). After the storage, the primary film (14) is unwound and fed into a tenter device (18). In the tenter device (18), while the stretch in the widthwise direction is performed, a relaxation of the primary film (14) in the longitudinal direction is made. If an extent percentage of the stretch is less than 70% to the predetermined value, the relation is started. The primary film (14) is fed out as a produced polymer film (22) from the tenter device (18), and the polymer film (22) is wound up to a product film roll (24). On the produced polymer film (22), the in-plane retardation increases and the thickness retardation decreases. Thus the optical properties become preferable.Type: GrantFiled: September 20, 2006Date of Patent: January 22, 2013Assignee: FUJIFILM CorporationInventor: Kouji Tonohara
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Patent number: 8337739Abstract: Methods of fabricating a polymeric implantable device from a PLLA/PDLA blend such as a stent with improved fracture toughness are disclosed. The blend is melt processed to allow formation of stereocomplex crystallites, which are nucleation sites for crystal growth. A polymer construct is formed from the melt processed blend and device is formed from the polymer construct. The stereocomplex crystallites result in an in increase in nucleation density and reduced crystal size, which increases fracture toughness of the formed device.Type: GrantFiled: August 12, 2008Date of Patent: December 25, 2012Assignee: Abbott Cardiovascular Systems Inc.Inventors: Yunbing Wang, James Oberhauser
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Patent number: 8328968Abstract: Disclosed herein are methods of preparing a composite sheet material having strength and barrier properties suitable for use as a housewrap, the methods comprising extrusion coating a polyolefin film layer onto a surface of an area-bonded, spunbond nonwoven substrate to form a composite sheet material, the composite sheet material having a grab tensile strength of at least 178 Newtons in at least one of the machine direction (MD) or the cross-machine direction (CD), and stretching the composite sheet material to impart to the composite sheet material a hydrostatic head of at least 100 cm, and a moisture vapor transmission rate (MVTR) of at least 35 g/m2/24 hr at 50% relative humidity and 23° C.Type: GrantFiled: April 16, 2012Date of Patent: December 11, 2012Assignee: Fiberweb, Inc.Inventors: Gary W. Anderson, Susannah D. Gelotte
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Patent number: 8318073Abstract: A mechanical activation system has a first activation member, a second activation member, an activation zone, and a non-slip zone. The first activation member has a first plurality of teeth, and the second activation member has a second plurality of teeth. The first plurality of teeth is capable of intermeshing with the second plurality of teeth. The activation zone includes a first portion of the first plurality of teeth and a first portion of the second plurality of teeth. The first portion of the first plurality of teeth and the first portion of the second plurality of teeth include teeth having continuous tips. The first non-slip zone includes a second portion of the first plurality of teeth or a second portion of the second plurality of teeth. The second portion includes a tooth having a discontinuous tip.Type: GrantFiled: November 22, 2010Date of Patent: November 27, 2012Assignee: The Procter & Gamble CompanyInventor: Uwe Schneider
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Patent number: 8318072Abstract: One embodiment of the present invention provides a method for producing a stretched cellulose acylate film with an in-plane retardation, Re, of 100 nm or more and a relationship between the thickness direction retardation, Rth, and Re which satisfies Rth<(Re/2), by longitudinally stretching an unstretched cellulose acylate film in a longitudinal direction by pulling by means of a difference in circumferential velocity between a pair of rollers, wherein the method is characterized in that the cellulose acylate film is subjected to free-end uniaxial stretching to a longitudinal stretch ratio of 1 to 2 while the film is being heated in a heating oven installed between the pair of rollers at a stretching temperature in the range of Tc?10° C. to Tc+70° C., Tc being the crystallization temperature of the film, and with the temperature difference in the film width direction maintained within 10° C.Type: GrantFiled: May 9, 2008Date of Patent: November 27, 2012Assignee: FUJIFILM CorporationInventor: Masaaki Otoshi
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Patent number: 8309217Abstract: Disclosed is an easy adhesion film which attains sufficient adhesiveness in various processings without using any crosslinking agent such as a melamine resin to possibly pollute the environment and has a primer layer excellent in high-temperature hot water resistance. In the easy adhesion film, a coating film including a polyester resin and a crosslinking agent component in a content of 0.1% by mass or less, inclusive of 0% by mass, is formed on at least one side of a substrate film. The sum of the acid number and the hydroxyl number of the polyester resin is 50 to 200 mg KOH/g, wherein the acid number is 20 to 60 mg KOH/g and the hydroxyl number is 30 to 150 mg KOH/g. The amount of the oligomers contained in the polyester is 2.0% by mass or less. The thickness of the coating film is 0.001 to 0.5 ?m.Type: GrantFiled: February 12, 2008Date of Patent: November 13, 2012Assignee: Unitika Ltd.Inventors: Takayoshi Okuzu, Hideki Kuwata
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Patent number: 8308862Abstract: An optical cellulose acylate film comprising a polymer component which is a cellulose acylate obtained by substituting hydroxyl groups of a cellulose by an acetyl group and an acyl group having 3 or more carbon atoms, wherein a substitution degree A of the acetyl group and a substitution degree B of the acyl group having 3 or more carbon atoms satisfy the following formulae (I) and (II): 2.0?A+B?3.0 (I), 0<B (II), and the optical cellulose acylate film comprises a retardation-expressing agent which is at least one of a rod-like compound and a discotic compound or an elastic modulus E(MD) in a casting direction and an elastic modulus E(TD) in a casting width direction satisfy the following formulae (III) and (IV): 1,500 MPa?E(MD)?3,400 Mpa (III) and 1,200 MPa?E(TD)?3,400 Mpa (IV).Type: GrantFiled: May 13, 2005Date of Patent: November 13, 2012Assignee: FUJIFILM CorporationInventors: Hiroyuki Kawanishi, Yosuke Nishiura, Takako Nishiura, legal representative
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Patent number: 8298462Abstract: This invention relates to a method of uniaxially expanding a fluoropolymer product including the steps of expanding a green fluoropolymer product in a first direction to create a first-expanded fluoropolymer product, and expanding the first-expanded fluoropolymer product in the same first direction. As a result with the subject invention, it has been found that ultra-high expansion and a variety of different porous/fibril structures can be achieved by using subsequent expansion steps in the same direction. Various considerations exist with such methodology, including the selection of rates of expansion of both steps, the amount of expansion of both steps, pre-heating and cutting the product between expansion steps. Although the present invention can be used with various fluoropolymer products, it is particularly well-suited for use with PTFE.Type: GrantFiled: December 30, 2004Date of Patent: October 30, 2012Assignee: Boston Scientific Scimed, Inc.Inventors: Michael Luk, Jeff Sewell, Jason Hill
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Patent number: 8293160Abstract: At an optional stage in the production step of a biaxially stretched film using a polyamide resin including, as a first component, nylon 6, and as a second component, a polyamide including xylylenediamine and an aliphatic dicarboxylic acid having 4 to 12 carbon atoms, the film is brought into contact with water set at 40° C. or higher and lower than 70° C. for 1 to 10 minutes and further with water set at 70° C. or higher for 1 to 10 minutes. In the film thus obtained, the content of low molecular weight compounds is 0% by mass to 0.2% by mass.Type: GrantFiled: April 15, 2009Date of Patent: October 23, 2012Assignee: Unitika Ltd.Inventors: Kiwamu Yuki, Makoto Nakai, Atsuko Noda
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Patent number: 8273839Abstract: Antiballistic or composite products include high strength polyethylene films or tapes produced in a process including the steps of providing a quantity of disentangled polyethylene, applying a pressure of at least 20 bar to the quantity of disentangled polyethylene and a temperature between the ?-relaxation temperature and the melting temperature of the disentangled polyethylene Tm PE resulting in a block of disentangled polyethylene, skiving a film or tape off the block of disentangled polyethylene and drawing the film or tape in a single or multi stage drawing step at a total draw ratio of at least 1:20.Type: GrantFiled: March 14, 2012Date of Patent: September 25, 2012Assignee: Novameer B.V.Inventors: Jan Adolph Dam Backer, Bart Clemens Kranz, Benjamin Slager
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Patent number: 8273447Abstract: A multilayer oriented film comprising at least one layer (a) comprising one or more polyesters and/or copolyesters characterized by a % of crystallinity higher than 15, an adjacent layer (b) comprising one or more polyolefin-based adhesive resins, and a layer (c) comprising one or more co-polyesters characterized by a % of crystallinity lower than 15, is positioned between said two layers (a) and (b) in such a way that one of the two principal surfaces of layer (c) is directly adhered to layer (a) and the other is directly adhered to layer (b). The presence of a co-polyester layer (c) of relatively low % crystallinity positioned between (co)polyester layer (a) and adhesive layer (b) remarkably increases the bond between the two layers (a) and (b) and prevents delamination problems in the oriented structure.Type: GrantFiled: January 19, 2007Date of Patent: September 25, 2012Assignee: Cryovac, Inc.Inventor: Roberto Forloni
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Patent number: 8268215Abstract: A laminated film for a reflecting plate is provided that comprises a layer A and a layer B, the layer A comprising a polyester that comprises substantially no antimony element and preferably comprises 1 to 25 wt % of inert particles having an average particle diameter of 0.3 to 3.0 ?m and the layer B being in contact with the layer A and comprising a polyester which preferably comprises 31 to 80 wt % of inert particles having an average particle diameter of 0.3 to 3.0 ?m. This laminated film has a practically satisfactory capability of reflecting visible light, can be produced stably even if inert particles are added in high concentration, hardly has streak-like defects, and can be suitably used as a substrate for a reflecting plate for a liquid crystal display or an internally illuminating electrical billboard.Type: GrantFiled: June 16, 2005Date of Patent: September 18, 2012Assignee: Teijin Dupont Films Japan LimitedInventors: Hiroshi Kusume, Atsushi Oyamatsu
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Patent number: 8257621Abstract: A transparent polymer film satisfying Rth/Re??0.39, Re>0 and Rth<0 and having a moisture permeability of 100-2000 g/(m2·day) at 40° C. and a relative humidity of 90%, and not containing an additive composition that raises Rth by at least 8 nm.Type: GrantFiled: February 22, 2007Date of Patent: September 4, 2012Assignee: FUJIFILM CorporationInventor: Yasuyuki Sasada
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Patent number: 8252218Abstract: Provided is a method for manufacturing a high-quality porous film. Here, while the porous film is being manufactured through forming micropores by stretching, a raw film is prevented from slipping on the surfaces of the respective rolls as much as possible even though the raw film includes oil or liquid paraffin as a solvent. The method is for manufacturing a porous film through forming micropores by successive biaxial stretching. A tensile force applied to the raw film F transferring from the longitudinal stretching machine (10) to the transverse stretching machine (50) is set not less than a stretching force necessary for the longitudinal stretching, and thus the raw film is prevented from slipping on a contact surface between the raw film and each roll of the longitudinal stretching machine (10).Type: GrantFiled: April 3, 2009Date of Patent: August 28, 2012Assignee: Toshiba Kikai Kabushiki KaishaInventors: Takayoshi Sano, Satoru Nitta
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Patent number: 8246878Abstract: A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction.Type: GrantFiled: April 30, 2008Date of Patent: August 21, 2012Assignee: Fina Technology, Inc.Inventors: Luyi Sun, Jose Sosa
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Patent number: 8246886Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.Type: GrantFiled: July 9, 2008Date of Patent: August 21, 2012Assignee: Nanocomp Technologies, Inc.Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
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Patent number: 8226860Abstract: A method for controlling positive birefringence in an optical compensation film (positive C-plate) having high positive birefringence throughout the wavelength range 400 nm<?<800 nm is provided. The method includes selecting polymers with optically anisotropic subunits (OASUs) that exhibit the buttressing effect, wherein the OASUs may be disks, mesogens or aromatic rings substituted with birefringence enhancing substituents. The method further includes processing the polymer by solution casting to yield a polymer film with high birefringence without the need for stretching, photopolymerization, or other processes. These optical compensation films may be used in LCDs, particularly IPS-LCDs.Type: GrantFiled: March 29, 2007Date of Patent: July 24, 2012Assignee: Akron Polymer SystemsInventors: Xiaoliang Joe Zheng, Frank W. Harris, Ted Calvin Germroth, Jiaokai Alexander Jing, Dong Zhang, Thauming Kuo, Brian Michael King
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Publication number: 20120181727Abstract: A device for expanding a hollow body includes a plurality of sector-shaped expandable jaws disposed in a holder and distributed about a central axis: The expandable jaws extend along the axis to a free end and are radially movable with respect to the axis. Each of the expandable jaws includes: a cylindrical surface having a radius corresponding to a radius of the expanded hollow body and an inward radial taper at an area of the free end; and a plurality of projections and recesses disposed in a joint region and arranged in an alternating manner with each other along the axis and at least partially extending into the area of the free end. The cylindrical surfaces are rounded off to transition to respective outer surfaces of the projections. The outer surfaces of the projections extend, at least at ends of the projections, radially inward with respect the cylindrical surfaces.Type: ApplicationFiled: August 28, 2010Publication date: July 19, 2012Applicant: ROTHENBERGER AGInventors: Knut Lindner, Thoralf Krause, Arnd Greding
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Patent number: 8211342Abstract: A process for the production of a non-fibrous ultra high molecular weight polyethylene tape having a width of 1-inch or greater and a modulus of 1,400 grams per denier or greater. The non-fibrous UHMWPE tape is obtained by compression molding ultrahigh molecular weight polyethylene powder at a temperature below its melting point and then drawing and stretching the entire resultant compression molded UHMWPE sheet, with no slitting or splitting of the sheet, at a draw ratio of at least 100:1. The UHMWPE tape can be produced in weights of 6,000 to 90,000 denier or greater. The UHMWPE tape of the present invention minimizes the effect of stress concentrators that are prevalent with fibers and thereby enables the tape to be drawn at much higher draw ratios than is possible with fibrous UHMWPE. When used in ballistics panels, the high modulus high molecular weight polyethylene tape of the present invention improves ballistic performance by providing enhanced dissipation of the impact energy of a projectile.Type: GrantFiled: July 8, 2011Date of Patent: July 3, 2012Assignee: Bae Systems Tensylon H.P.M., Inc.Inventors: Gene C. Weedon, Kenneth C. Harding, Lisa Owen
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Patent number: 8197726Abstract: A cellulose acylate film in which the number of V-shaped thickness-uneven portions having a variation width in the thickness direction of 0.1 to 10% of a film thickness and a width in the in-plane direction of 1 to 20 mm is in the range of 0 to 10 per 100 m in the length direction of the film. A display unevenness is solved in a liquid crystal display device having the cellulose acylate film.Type: GrantFiled: December 22, 2005Date of Patent: June 12, 2012Assignee: FUJIFILM CorporationInventors: Kiyokazu Hashimoto, Zemin Shi
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Patent number: 8197931Abstract: A white polyester film containing voids, wherein a resin constituting the film has a layer (layer A) formed by using a polyester resin and a cyclic olefin copolymerized resin, and wherein a void ratio taken in a cross-section of the layer is more than 25% and 75% or less and the average particle size of the cyclic olefin copolymerized resin in the film is 0.1 ?m or more and 3 ?m or less.Type: GrantFiled: January 28, 2008Date of Patent: June 12, 2012Assignee: Toray Industries, Inc.Inventors: Takashi Ueda, Hideki Fujii, Tatsuo Yoshida, Kozo Takahashi, Masahiro Okuda, Kazunori Tanaka, Toshihiko Hiraoka
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Patent number: 8188207Abstract: Process for producing high strength polyethylene films or tapes comprising the steps of: providing a quantity of disentangled polyethylene, applying a pressure of at least 20 bar to the quantity of disentangled polyethylene and a temperature between the ?-relaxation temperature and the melting temperature of the disentangled polyethylene Tm PE resulting in a block of disentangled polyethylene, skiving a film or tape off the block of disentangled polyethylene and, drawing said film or tape in a single or multi stage drawing step at a total draw ratio of at least 1:20.Type: GrantFiled: April 21, 2009Date of Patent: May 29, 2012Assignee: Novameer B.V.Inventors: Jan Adolph Dam Backer, Bart Clemens Kranz, Benjamin Slager
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Patent number: 8182732Abstract: Here is disclosed a composite sheet comprising substantially non-stretchable nonwoven fabric sheets and a plurality of elastic members extending in a transverse direction and spaced one from another in a longitudinal direction by a given spacing wherein the elastic members are secured in a stretched state to the nonwoven fabric sheets. The composite sheet has a plurality of gathers formed by slightly undulated surface of the nonwoven fabric sheets and the elastic members and these gathers are substantially continuous in the longitudinal direction and arranged at substantially regular intervals in the transverse direction.Type: GrantFiled: October 21, 2004Date of Patent: May 22, 2012Assignee: Uni-Charm CorporationInventors: Kazuo Ukegawa, Masato Isono, Hiroaki Kamio, Toru Oba