Biaxial Or Transverse To Travel Direction Patents (Class 264/290.2)
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Publication number: 20100055438Abstract: The present invention provides for concentrated aqueous silk fibroin solutions and an all-aqueous mode for preparation of concentrated aqueous fibroin solutions that avoids the use of organic solvents, direct additives, or harsh chemicals. The invention further provides for the use of these solutions in production of materials, e.g., fibers, films, foams, meshes, scaffolds and hydrogels.Type: ApplicationFiled: November 3, 2009Publication date: March 4, 2010Applicant: TRUSTEES OF TUFTS COLLEGEInventors: David L. Kaplan, Ung-Jin Kim, Jaehyung Park, Hyoung-Joon Jin
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Patent number: 7670687Abstract: The present invention relates to a biaxially oriented polyester film, which a) has a base layer B, which includes a yellow dye and a red dye, b) has, on each side of the base layer B, at least one layer (A or C) which includes, based on the weight of layer A or C, less than 0.01% by weight of the yellow dye and less than 0.01% by weight of the red dye, and c) the film has one absorption maximum lying at from 400 to 500 nm in the UV/visible spectrum from 400 to 800 nm. Preferred dyes are anthraquinone dyes and perinone dyes; the polyester is preferably PET. After metallization or lamination, the film has a gold appearance, and is a suitable packaging material.Type: GrantFiled: June 13, 2008Date of Patent: March 2, 2010Assignee: Mitsubishi Polyester Film GmbHInventors: Oliver Klein, Matthias Konrad, Holger Kliesch, Bodo Kuhmann
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Patent number: 7655291Abstract: A co-extruded film including talc and a method for preparing the film includes a polyester resin containing talc. The films may be single layer films or multi-layered structures such as ABA or AB structured films. Multi-layered films have talc in at least the A layer of the multi-layered film. If talc is present in the B layer, the A layer preferably includes a greater percentage of talc relative to the percentage of talc present in said B layer. The method uses readily available, low cost talc as an additive to achieve a co-extruded polyester film having simultaneously reduced transparency and reduced gloss to provide a translucent polyester film.Type: GrantFiled: October 14, 2003Date of Patent: February 2, 2010Assignee: Toray Plastics (America), Inc.Inventor: Yijun Ye
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Patent number: 7651653Abstract: A method for producing a machine direction and cross-machine direction elastic laminate includes the steps of providing a one direction elastic laminate material including at least one elastic layer and one facing layer and having a single direction of elasticity and coursing the one direction elastic laminate material through at least one stretching apparatus, such that the stretching apparatus stretches the laminate material in a direction perpendicular to the single direction of elasticity of the elastic laminate material, thereby producing a material that extends in a direction perpendicular to the direction of elasticity and also extends the elastic performance of the laminate in the single direction of elasticity.Type: GrantFiled: December 22, 2004Date of Patent: January 26, 2010Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Michael T. Morman, Paul Theodore Van Gompel, Jennifer Marvin, Thomas Harold Roessler, James M. Carr, Yung Hsiang Huang, Mary Jo Meyer, Eric Donald Johnson
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Publication number: 20100013121Abstract: The invention relates to the sequential biaxial stretching of a thin film made of a polylactic acid resin containing as large an amount of a plasticizer as 10 to 50 wt % and aims at solving the problematic grip failure in the widthwise stretching step which failure is caused by the lowering in film flatness occurring in gripping the film with clips continuously.Type: ApplicationFiled: September 21, 2007Publication date: January 21, 2010Applicant: ASAHI KASEI HOME PRODUCTS CORPORATIONInventors: Satoshi Hashimoto, Masaru Iriya
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Publication number: 20090302281Abstract: A dislocation-free sheet may be formed from a melt. A sheet of material with a first width is formed on a melt of the material using a cooling plate. This sheet has dislocations. The sheet is transported with respect to the cooling plate and the dislocations migrate to an edge of the sheet. The first width of the sheet is increased to a second width by the cooling plate. The sheet does not have dislocations at the second width. The cooling plate may have a shape with two different widths in one instance. The cooling plate may have segments that operate at different temperatures to increase the width of the sheet in another instance. The sheet may be pulled or flowed with respect to the cooling plate.Type: ApplicationFiled: June 4, 2009Publication date: December 10, 2009Applicant: VARIAN SEMICONDUCTOR EQUIPMENT ASSOCIATES, INC.Inventors: Peter L. Kellerman, Frank Sinclair, Frederick Carlson, Nicholas P.T. Bateman, Robert J. Mitchell
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Patent number: 7625194Abstract: A manufacturing apparatus is provided for manufacturing a tubular resin film of high quality and little thickness variations, which is stretched and given an orientation, and suitable as retardation film or the like. It comprises a stretching section (6) for stretching the tubular resin film (20), and a maintaining section (7) for maintaining a shape of said tubular resin film (20) stretched. Further, said stretching section (6) is arranged to apply a stretching force to said tubular resin film for longitudinally and/or circumferentially stretching said tubular resin film (20).Type: GrantFiled: December 24, 2003Date of Patent: December 1, 2009Assignee: Sumitomo Bakelite Company, Ltd.Inventors: Shingo Yoshida, Seigou Akazawa, Keiko Akazawa, legal representative, Toyotaro Maruyama, Takeshi Takeuchi, Shigeyoshi Furuhara, Masanori Ikenaga, Toshio Nakao
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Publication number: 20090227756Abstract: The present invention provides a method for producing a retardation film of a polypropylene resin, the method comprising subjecting a film of a polypropylene resin to longitudinal stretching and transverse stretching which are performed sequentially, wherein the transverse stretching comprises the following steps, and a polypropylene resin retardation film which is obtained by such a method and has both a high axial retardation and a uniform retardation: a step of preheating the film at a preheating temperature which is equal to or higher than the melting point of the polypropylene resin; a step of stretching the preheated film in the transverse direction at a stretching temperature which is lower than the preheating temperature; and a step of heat setting the film stretched in the transverse direction.Type: ApplicationFiled: March 23, 2007Publication date: September 10, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kyoko Hino, Toshihiko Suzuki, Hiroaki Takahata
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Patent number: 7575703Abstract: The present invention provides polymer gel-processing techniques and polymer articles of high modulus.Type: GrantFiled: February 25, 2004Date of Patent: August 18, 2009Assignee: Eidgenössische Technische Hochschule ZürichInventors: Magnus Kristiansen, Theo Tervoort, Paul Smith
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Patent number: 7550555Abstract: Ultrahigh molecular weight polyethylene compositions of highly beneficial sintering characteristics are disclosed and methods for making and processing same. Additionally, products comprising these compositions are described.Type: GrantFiled: January 24, 2003Date of Patent: June 23, 2009Assignee: Smith & Nephew Orthopaedics AGInventors: Paul Smith, Jeroen Visjager, Theo Tervoort
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Patent number: 7544408Abstract: Described are smooth biaxially oriented films and methods of making smooth biaxially oriented films for molding processes. The films may include an outer film layer A, and an outer film layer B that includes particles. Layer A has a SRa roughness of from 1 nm to 5 nm and a SRz roughness of from 10 nm to 100 nm. Layer B has a SRa roughness of from 5 nm to 50 nm and a SRz roughness of from 10 nm to 200 nm. The SRa and SRz of layer B is larger than the SRa and SRz of layer A.Type: GrantFiled: February 14, 2007Date of Patent: June 9, 2009Assignee: Toray Plastics (America), Inc.Inventors: Nao Yokota, Arron Carroll, Hiroshi Furuya, Hideo Yanase, Terufumi Takayama, Steven Sargeant
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Transparent, electrically conductive, coated polyester film, process for its production, and its use
Patent number: 7534487Abstract: The invention relates to a transparent, electrically conductive, biaxially oriented, single- or multilayer polyester film which includes a coating composed of (a) conductive (ITO) indium tin oxide particles or (ATO) antimony tin oxide particles, or of a mixture of these. The film further include other conductive components (b). The other conductive components (b) may be present either in the coating including ITO particles and/or ATO particles or in a layer in contact therewith. The conductive component (b) may also be a metal layer in contact with the ITO and/or ATO. The film is only oriented or relaxed prior to application of the ITO and/or ATO coating. The invention further relates to a process for the production of the film, and its use.Type: GrantFiled: March 18, 2005Date of Patent: May 19, 2009Assignee: Mitsubishi Polyester Film GmbHInventors: Dagmar Klein, Holger Kliesch, Thorsten Kiehne, Bodo Kuhmann, Franz Hora, Gottfried Hilkert, Manfred Wiederhold -
Patent number: 7524445Abstract: A method for making a vascular graft includes providing a PTFE green tube extrudate which is un-sintered, and then initially expanding the un-sintered extrudate to produce an initial node and fibril micro-structure therein. This is followed by heating the extrudate to raise the temperature thereof for a time period of sufficient duration such that the extrudate is partially sintered. The partially sintered extrudate is subsequently expanded to make the vascular graft. The subsequent expansion produces a subsequent node and fibril micro-structure in the vascular graft. An alternative method for making a vascular graft includes providing a PTFE green tube extrudate which is un-sintered, longitudinally expanding the un-sintered extrudate to form an ePTFE tube structure, and radially expanding the un-sintered ePTFE tube structure. ePTFE made according to the method is fabricated into various structures, such as tube structures, filament structures, and sheet structures.Type: GrantFiled: December 31, 2004Date of Patent: April 28, 2009Assignee: Boston Scientific Scimed, Inc.Inventors: Julio Duran, Krzysztof Sowinski
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Patent number: 7521010Abstract: A novel densified fluoropolymer article is described which has a water vapor permeation of about 0.015 g-mm/m2/day or less, and preferably has a matrix tensile strength of at least 10,000 psi in two orthogonal directions. The articles are made by compressing expanded porous PTFE at pressures, temperatures and times which result in elimination of the pores, and subsequent stretching above the crystalline melt temperature.Type: GrantFiled: November 6, 2007Date of Patent: April 21, 2009Assignee: Gore Enterprise Holdings, Inc.Inventors: Michael E. Kennedy, Donald L. Hollenbaugh, Jr.
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Patent number: 7514141Abstract: The invention relates to a biaxially oriented polyester film having a base layer (B) which comprises at least 80% by weight of a polyester comprised of from 55 to 90 mol % of units deriving from at least two aromatic dicarboxylic acids and of from 5 to 45 mol % of units deriving from at least one aliphatic dicarboxylic acid, where the total of the dicarboxylic-acid-derived molar percentages is 100. The film features ultimate tensile strength of ?100 N/mm2 and modulus of elasticity of ?3000 N/mm2.Type: GrantFiled: April 3, 2007Date of Patent: April 7, 2009Assignee: Mitsubishi Polyester Film GmbHInventors: Oliver Klein, Herbert Peiffer, Gottfried Hilkert
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Publication number: 20090085249Abstract: In a first zone of a tenter section, damp air is applied to side edge portions of a TAC film, thereby providing the TAC film with a water content profile in which water content decreases from the side edge portions toward a center portion. This water content profile causes the TAC film to have a birefringence profile in which a birefringence decreases from the side edge portions toward the center portion. The TAC film is stretched in a width direction while the side edge portions are being held with clips. Due to a low flexibility at the side edge portions during the stretching process, the birefringence of the TAC film increases such that an increase in the birefringence becomes larger from the side edge portions toward the center portion. A difference of the birefringence in the width direction before the stretching process compensates a difference of the increase in the birefringence in the width direction after the stretching process. The water content of the TAC film is then evaporated.Type: ApplicationFiled: September 26, 2008Publication date: April 2, 2009Applicant: FUJIFILM CorporationInventor: Toshinao Arai
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Patent number: 7491357Abstract: In solution casting, dope containing a polymer and a solvent is cast on to a support to form a cast film. The cast film is stripped from the support to obtain a polymer film of cellulose ester, for example, cellulose acetate propionate (CAP). The polymer film is stretched. While the polymer film is stretched, tension of 80 N/m or more is applied thereto in a stretching direction. Polymer film surface temperature thereof is set equal to or more than a glass transition temperature Tg thereof. Furthermore, before stretching the polymer film, the polymer film stripped from the support is dried. After stretching the polymer film, the polymer film is dried. Also, the solution casting process is according to multi casting of plural dopes at one time together for plural cast films in the polymer film.Type: GrantFiled: December 5, 2005Date of Patent: February 17, 2009Assignee: FUJIFILM CorporationInventor: Hidekazu Yamazaki
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Publication number: 20090035527Abstract: In a process of producing a stretch sheet, a strip-shaped laminate sheet 10A having an elastically stretchable elastic layer 1 and substantially inelastic, inelastic fiber layers 2 and 3 partially joined to each other at bonds 4 or a strip-shaped fibrous sheet containing an elastic component and a substantially inelastic component and having embossed regions formed by embossing in parts is stretched in directions starting from the bonds 4 or the embossed regions to obtain a stretch sheet 10. The stretch sheet has raised ridges and recessed grooves extending in the direction perpendicular to the stretch direction, and the bonds 4 or the embossed regions are present in the ridges.Type: ApplicationFiled: April 25, 2006Publication date: February 5, 2009Applicant: Kao CorporationInventors: Hideyuki Kobayashi, Koji Kanazawa, Akihiko Gunji, Tetsuya Masuki
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Patent number: 7479248Abstract: The invention relates to a vessel prosthesis or patch, made from a biocompatible polymer with microporous, finely-fibrillated structure and a method for improving the e-modulus of said vessel prostheses or patches. According to the invention, the vessel prostheses or patches are subjected to a full stretching (extension) with a degree of extension between 30% and 250% and subsequent restoration.Type: GrantFiled: September 17, 2003Date of Patent: January 20, 2009Assignee: Adiam Life Science AGInventors: Josef Jansen, Engin Kocaman
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Patent number: 7455801Abstract: The method of producing a film includes the steps of: casting a dope prepared by dissolving a macromolecular material in a solvent on a casting band; stripping the cast dope from the casting band to form a film; subjecting the stripped film to tentering to stretch or regulate the same in its width direction; and subjecting the tentered film to roll drying to dry the film while conveying the same in such a manner that it engages with a plurality of rolls, the method being characterized in that the solvent content in the film at the beginning of roll drying after tentering is kept within the range of 3 to 8% by weight, the surface temperature of the film during the roll drying is kept within the range of the film's Tg (glass transition temperature) ?15° C. to the Tg, and the rate of the film expansion in the film conveying direction is kept within the range of ?2% to 3%.Type: GrantFiled: September 16, 2003Date of Patent: November 25, 2008Assignee: Fujifilm CorporationInventor: Hiroshi Nakashima
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Patent number: 7442427Abstract: This invention relates to coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least APET, the heatsealable and peelable top layer (A) consisting of a) 80-98% by weight of polyester and b) 2-10% by weight of inorganic and/or organic particles having an average diameter d50 of from 2.5 to 8.0 ?m (based on the mass of the top layer (A)), wherein c) the polyester being composed of 12-89 mol % of units which derive from at least one aromatic dicarboxylic acid and 11-88 mol % of units which derive from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, d) the ratio of particle size d50 and layer thickness dA of the top layer (A) being greater than 1.2 and e) the layer thickness of the top layer (A) dA being from 1.0 to 5 ?m. The invention further relates to a process for producing the film and to its use.Type: GrantFiled: September 29, 2004Date of Patent: October 28, 2008Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Matthias Konrad, Harald Mueller, Paul Broemmel
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Publication number: 20080241769Abstract: A film consisting essentially of a continuous phase linear polyester matrix having dispersed therein a non-crosslinked random SAN-polymer and dispersed or dissolved therein at least one ingredient from the group of ingredients consisting of inorganic opacifying pigments, whitening agents, colorants, UV-absorbers, light stabilizers, antioxidants and flame retardants, wherein the film is white, microvoided, non-transparent and axially stretched; the linear polyester matrix has monomer units consisting essentially of at least one aromatic dicarboxylic acid, at least one aliphatic diol and optionally at least one aliphatic dicarboxylic acid; and the weight ratio of the linear polyester to the non-crosslinked SAN-polymer is in the range of 2.0:1 to 19.Type: ApplicationFiled: March 26, 2008Publication date: October 2, 2008Inventors: Dirk QUINTENS, Peter Bries
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Adhesion-promoted , heatsealable and peelable polyester film, process for its production and its use
Patent number: 7396578Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) includes a) from 60 to 99% by weight of polyester and b) from 1 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 2 to 8 ?m, and where c) the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and the non-sealable surface of the film has been rendered adhesion-promoting. The films of the invention are suitable as a packaging material for foods and other consumable items, and as a lid film for APET/CPET or CPET trays.Type: GrantFiled: November 9, 2004Date of Patent: July 8, 2008Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Bart Janssens, Matthias Konrad, Andreas Stopp -
Patent number: 7396498Abstract: The invention disclosed herein relates to a method of treating plastics material fibers, filaments or film to improve their resistance to degradation by UV radiation and/or increase their resistance to gas (oxygen) transmissivity and an improved plastics material so treated, the method including stretching the fiber, filament or film beyond its yield point and allowing the film to at least partially relax.Type: GrantFiled: June 23, 1999Date of Patent: July 8, 2008Assignee: Integrated Packaging Australia Pty. Ltd.Inventor: Peter Johnstone
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Patent number: 7378145Abstract: The present invention relates to a transparent, hot-embossable, biaxially oriented polyester film having a base layer (B), an amorphous outer layer (A) with a coating on this outer layer (A), and a crystalline outer layer (c). The invention further relates to the use of such film and to a process for its production.Type: GrantFiled: October 19, 2007Date of Patent: May 27, 2008Assignee: Mitsubishi Polyester Film GmbHInventors: Matthias Konrad, Bodo Kuhmann, Gottfried Hilkert
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Publication number: 20080102234Abstract: The present invention relates to a transparent, hot-embossable, biaxially oriented polyester film having a base layer (B), an amorphous outer layer (A) with a coating on this outer layer (A), and a crystalline outer layer (c). The invention further relates to the use of such film and to a process for its production.Type: ApplicationFiled: October 19, 2007Publication date: May 1, 2008Inventors: Matthias KONRAD, Bodo Kuhmann, Gottfried Hilkert
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Patent number: 7359017Abstract: A method for producing a roll of an optical compensation film, in the effective width of which an angle of the slow axis in the film face with the width direction of the film is within the range of ±1° and an angle of the fast axis in the film face with the length direction of the film is within the range of ±1°, wherein the angle of the fast axis in the film face with the length direction is cyclically varied by a cycle of from 1.5 m to 500 m in the length direction of the film and the minimum amplitude of the variation is within the range of from 0.1° to 1°.Type: GrantFiled: April 12, 2005Date of Patent: April 15, 2008Assignee: Konica Minolta Opto, Inc.Inventors: Hiroki Umeda, Katsusuke Nagashima, Noriyasu Kuzuhara, Minori Tamagawa
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Publication number: 20080081202Abstract: A method of producing a biaxially stretched, multi-layered polyamide film which includes a step of biaxially stretching a non-stretched laminate film composed of a layer mainly made of a polyamide resin and a layer mainly made of an aliphatic polyamide resin. The biaxial stretching is made by a roll/tenter successive biaxial stretching method. The polyamide resin is composed of a diamine constitutional unit mainly made of m-xylylenediamine units and a dicarboxylic acid constitutional unit mainly made of units derived from an ?,?-aliphatic dicarboxylic acid having 6 to 12 carbon atoms. The non-stretched laminate film is cooled by a cooling roll having a temperature within a limited range and then successively and biaxially stretched. With such a production method, the biaxially stretched, multi-layered polyamide film is excellent in the gas barrier properties, pinhole resistance, flexibility, and impact resistance.Type: ApplicationFiled: September 27, 2007Publication date: April 3, 2008Inventors: Hiroyuki NANBA, Kenji Kouno, Makoto Takahashi
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Patent number: 7329453Abstract: Coextruded, biaxially oriented polyester films which have a white base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) includes a) from 80 to 99% by weight of polyester and b) from 1 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 2.5 to 12 ?m, and where c) the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is greater than or equal to 1, and the base layer (B) comprises an inorganic white pigment and/or a polymer incompatible with polyester. The films of the invention are suitable as a packaging material for foods and other consumable goods or as a lid film for APET/CPET or CPET trays.Type: GrantFiled: November 9, 2004Date of Patent: February 12, 2008Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Paul Broemmel
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Patent number: 7306835Abstract: The present invention relates to a thermo-shrinkable polyester film with a superior thermal shrinkage, which has an orientation angle of a molecular chain in a range of from 0° to about ±10° relative to a main shrinkage direction, and a molecular orientation ratio (MOR) in a range of from 1.29 to about 2.5, thereby preventing a label made from the film from curling or waving.Type: GrantFiled: January 29, 2007Date of Patent: December 11, 2007Assignee: Kolon Industries, Inc.Inventors: Ki Il Hong, Gi Sang Song
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Patent number: 7300703Abstract: The use of a heat-stabilized, heat-set oriented film comprising poly(ethylene naphthalate) as a substrate in, or in the manufacture of, an electronic or opto-electronic device containing a conjugated conductive polymer, wherein said film has a shrinkage at 30 mins at 230° C. of less than 1%; and a composite film comprising such a substrate layer and on a surface thereof a barrier layer.Type: GrantFiled: August 14, 2006Date of Patent: November 27, 2007Assignee: Dupont Teijin Films U.S. Limited PartnershipInventors: William Alasdair MacDonald, Leigh Beckett Richardson
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Patent number: 7285322Abstract: The invention relates to an at least two-layer polyester film with a total thickness of from 5 to 200 ?m which comprises, alongside polyethylene terephthalate, from 2 to 20% by weight—based on the weight of the entire film—of polyethylene naphthalate (PEN), where at least one outer layer comprises less than 0.1% by weight of PEN (based on the weight of this outer layer).Type: GrantFiled: June 16, 2003Date of Patent: October 23, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Thorsten Kiehne, Bart Janssens, Christine Schmiedeskamp
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Patent number: 7261944Abstract: The invention relates to a single- or multilayer, oriented, film coated with an aminosilane compound and composed of polyester which comprises an additive which, on irradiation with electromagnetic radiation, forms metal nuclei on which further metal can be deposited in further steps of the process. The invention further relates to a process for producing this film and to its use in printed circuit boards, ribbon cables, smart cards, RFID labels, membrane keyboards, and film-based circuits of any type.Type: GrantFiled: September 15, 2004Date of Patent: August 28, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Thorsten Kiehne, Gottfried Hilkert, Ingo Fischer
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Patent number: 7247680Abstract: A homogeneous blend of a low density polyethylene with a metallocene-catalysed polyethylene having a density of from 0.906 g/cm3 and a Dow Rheology Index of at least 5/MI2,MI2 being the melt index measured according to ASTMD-1238 condition 190° C./2.16 kg and the Dow Rheology Index being determined by a dynamic rheological analysis performed at 190°.Type: GrantFiled: January 11, 2002Date of Patent: July 24, 2007Assignee: TOTAL Petrochemicals Research FeluyInventor: Philippe Marechal
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Patent number: 7241507Abstract: The invention relates to a hydrolysis-stable polyester whose thickness is preferably in the range from 0.4 to 500 ?m. The film comprises polyester and at least one hydrolysis stabilizer and is distinguished by its low hydrolysis rate. The invention furthermore relates to a process for the production of the film and its use.Type: GrantFiled: September 8, 2005Date of Patent: July 10, 2007Assignees: Mitsubishi Polyester Film GmbH, Schaefer Additivsysteme GmbHInventors: Holger Kliesch, Bodo Kuhmann, Thorsten Kiehne, Ingo Fischer, Gottfried Hilkert, Volker Schaefer
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Patent number: 7238419Abstract: The invention relates to a white opaque film formed from a crystallizable thermoplastic, preferably thermo-plastic polyester in the form of polyethylene terephthalate, barium sulfate and titanium dioxide as pigments, at least one optical brightener, and optionally at least one dye soluble in the thermoplastic. The film optionally includes, an additional functionality, e.g. in the form of an adhesive coating, of a coating with aminosilane or silicone, of UV resistance, of hydrolysis resistance, of flame retardancy, or of a sealable outer layer.Type: GrantFiled: May 31, 2006Date of Patent: July 3, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Ulrich Kern, Ursula Murschall, Bodo Kuhmann, Martin Jesberger
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Patent number: 7238417Abstract: The invention relates to a polyester film with a thickness of from about 4 to about 23 ?m, which comprises, alongside polyethylene terephthalate as main constituent, from about 2 to about 20% by weight of polyethylene naphthalate (based on the weight of the film), and has fewer than 30 pinholes per 100 m2. The invention further relates to a process for producing these films, and to the use of the films in packaging composites.Type: GrantFiled: June 16, 2003Date of Patent: July 3, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Ursula Murschall, Thorsten Kiehne, Gottfried Hilkert, Bart Janssens
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Patent number: 7238411Abstract: The present invention is a multilayer polyester film comprising a layer A and a layer B which are laminated alternately, the layer A constituting the outermost layer on both sides of the film, wherein (1) the layer A comprises a polyester A, and the layer B comprises a polyester B, (2) the melting point of the polyester A is higher than the melting point of the polyester B by at least 15° C., (3) the layer A is a layer having an oriented structure, and the layer B is a layer having a substantially unoriented structure, (4) the ratio (a/b) of the total thickness (a) of the layer A to the total thickness (b) of the layer B is 0.01 to 3, and (5) the in-plane tensile strength of the multilayer polyester film is 50 MPa or lower at a maximum, and the difference between its maximum value and minimum value is 20 MPa or smaller; and a method for producing the multilayer polyester film.Type: GrantFiled: February 10, 2003Date of Patent: July 3, 2007Assignee: Teijin LimitedInventors: Tetsuo Yoshida, Tetsuo Ichihashi
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Patent number: 7235203Abstract: Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a ?-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of ?-crystal orientation of less than 0.3 by the following method (I) and/or (II), optionally subjected to annealing treatment, and transversely stretched: method (I): melting the polypropylene-based resin composition containing needle crystals of a specific ?-crystal nucleating agent at a temperature not lower than m.p.Type: GrantFiled: February 15, 2002Date of Patent: June 26, 2007Assignee: New Japan Chemical Co., Ltd.Inventors: Kiyoshi Sadamitsu, Naoki Ikeda, Manabu Hoki, Kenichiro Nagata, Koichi Ogino
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Patent number: 7229697Abstract: The invention relates to a hydrolysis-stable polyester film comprising a polyester, whose thickness is preferably in the range from 0.4 to 500 ?m. The film comprises polyester and at least one hydrolysis stabilizer and is distinguished by its low hydrolysis rate. The invention furthermore relates to a process for the production of the film and its use.Type: GrantFiled: September 8, 2005Date of Patent: June 12, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Bodo Kuhmann, Thorsten Kiehne, Ingo Fischer, Gottfried Hilkert
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Patent number: 7229581Abstract: Invention relates to a process for producing a single-layer or multilayer film by extrusion or coextrusion, biaxial orientation, and heat setting based on crystallizable thermoplastics whose principal constituent is a crystallizable thermoplastic having a standard viscosity SV (DCA) of from 600 to 1000. The thermoplastic is mixed prior to extrusion or coextrusion with 50% by weight (based on the total weight of all thermoplastics) of a secondary thermoplastic having a standard viscosity SV (DCA) of more than 900 to 1500, the standard viscosity SV (DCA) of the two thermoplastics differing by at least 100 units. The secondary thermoplastic is a byproduct or waste product from the production of PET plastic bottles or originates from recycled PET bottles.Type: GrantFiled: November 5, 2003Date of Patent: June 12, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Ulrich Kern, Ursula Murschall, Holger Kliesch
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Patent number: 7229696Abstract: The invention relates to an at least two-layer polyester film with a total thickness of from about 5 to about 200 ?m which comprises polyethylene terephthalate and from about 2 to about 20% by weight—based on the weight of the entire film—of polyethylene naphthalate, and also at least one functional outer layer.Type: GrantFiled: June 16, 2003Date of Patent: June 12, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Ursula Murschall, Franz Hora, Guenther Crass, Herbert Peiffer, Bodo Kuhmann
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Patent number: 7223459Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least CPET, the heatsealable and peelable top layer (A) consisting of a) 80–98 % by weight of polyester and b) 2–10 % by weight of inorganic and/or organic particles having an average diameter d50 of from 2.5 to 12.0 ?m (based on the mass of the top layer (A)), wherein c) the polyester is composed of 12–89 mol % of units derived from at least one aromatic dicarboxylic acid and 11–88 mol % of units derived from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, d) the ratio of particle diameter d50 and layer thickness dA of the top layer (A) being greater than/equal to 1.0 and e) the layer thickness of the top layer (A) dA being from 2.3 to 10.0 ?m. The invention further relates to a process for producing the film and to its use.Type: GrantFiled: September 29, 2004Date of Patent: May 29, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
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Patent number: 7217379Abstract: A method for producing a tube section from thermoplastic material, in which a tube section is extruded by means of an extruder which is provided with an extruder die having an inner core, which inner core defines an axial hollow space in the tube section, the tube section coming out of the extruder die downstream of the extruder die being internally cooled by means of an internal cooling member and externally cooled by means of an external cooling device. Immediately after the tube section leaves the extruder die, the internal cooling member brings about internal cooling of the tube. The external cooling device is positioned downstream of the internal cooling member, so that the external cooling of the tube section is brought about after the internal cooling.Type: GrantFiled: February 20, 2004Date of Patent: May 15, 2007Assignee: Wavin B.V.Inventors: Arjan Dirk van Lenthe, Jan Hendrik Prenger, Jan Visscher
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Patent number: 7214339Abstract: The object of the present invention is to provide a method for producing a polyester film excellent in rigidity, toughness, dimensional stability, electric properties, etc. and less in thickness fluctuation and surface defects, hence very suitable as a film for various industrial materials such as magnetic recording media, capacitors, heat transfer ribbons and thermal mimeographic stencil paper. The first method of the present invention is a method for producing a polyester film, in which a film made of a resin mainly composed of a polyester is simultaneously biaxially stretched by a simultaneously biaxially stretching tenter oven, comprising the step of effecting small-ratio stretching at an area stretching ratio of 1.0005 to 3.Type: GrantFiled: September 23, 2002Date of Patent: May 8, 2007Assignee: Toray Industries, Inc.Inventors: Tetsuya Tsunekawa, Takuji Higashioji, Kenji Tsunashima
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Patent number: 7211306Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) includes a) from 80 to 98% by weight of polyester and b) from 2 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 3 to 12 ?m, and where c) the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is greater than or equal to 1.5, and the shrinkage of the films, at least in one direction, is more than 5%. The films of the invention are especially suitable, owing to their property of self-venting, as a lid film for APET/CPET or CPET trays.Type: GrantFiled: November 9, 2004Date of Patent: May 1, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
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Patent number: 7205040Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) comprises from 80 to 99% by weight of polyester and from 1 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 2.5 to 12 ?m, and where the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is ?1, and the base layer (B) comprises poly(-xyleneadipamide). The films of the invention are suitable, owing to their increased oxygen barrier, as a packaging material for foods and other consumable goods or as a lid film for APET/CPET or CPET trays.Type: GrantFiled: November 9, 2004Date of Patent: April 17, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
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Patent number: 7189452Abstract: Biaxially oriented polyester films formed from a crystallizable polyester having increased diethylene glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The films of the invention further include at least one IR-reflective pigment and one UV stabilizer. The inventive films feature adjustable mattness, diffuse scattering power for visible light, high light transmittance and IR reflectance and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.Type: GrantFiled: July 1, 2005Date of Patent: March 13, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
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Patent number: 7189347Abstract: A biaxially oriented polyamide laminate film having a layered structure of A/B, A/B/A or A/B/C, layer A having no projections with a height of 0.27 ?m or higher on the surface, or having a density of projections with a height of 0.27 ?m or higher on the surface of 200 projections/mm2, and the film exhibiting a maximum dimensional change of 4% or less during immersion in 95° C. hot water, a maximum dimensional change of 6% or less after withdrawal from the hot water, and a maximum dimensional change of 4% or less after heat treatment in dry hot air at 160° C.; and a process for producing the same. This film reduces the differences in physical properties in the width direction that occurs in a tenter and exhibits excellent adhesive properties, resistance to fatigue from flexing and operability, and can be provided economically.Type: GrantFiled: August 22, 2001Date of Patent: March 13, 2007Assignee: Toyo Boseki Kabushiki KaishaInventors: Shinji Fujita, Yukinobu Mukoyama, Katsuya Ito
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Patent number: RE40274Abstract: The present invention provides a heat shrinkable polyester film whose hot water shrinkage along its main shrinkage direction is equal to or greater than 20% when the film is put in hot water of 70° C. for 5 sec; 35% to 55% when put in hot water of 75° C. for 5 sec; and 50% to 60% when put in hot water of 80° C. for 5 sec, wherein the compressive strength of the label formed by the film satisfies a following expression (1): Y>X2.2??(1) where y denotes compressive strength (mN) and x denotes film thickness (?m).Type: GrantFiled: September 17, 2004Date of Patent: April 29, 2008Assignee: Toyo Boseki Kabushiki KaishaInventors: Hideki Ito, Norimi Tabota, Tsutomu Oko