Biaxial Or Transverse To Travel Direction Patents (Class 264/290.2)
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Patent number: 6726870Abstract: A method for making a bulky web. A web is fed in a first direction. The web is subjected to incremental stretching in a direction perpendicular to the first direction to provide a bulky web. The bulky web is then stabilized to provide a stabilized bulked web, Optionally, the bulky web may be gathered after it has been subjected to incremental stretching.Type: GrantFiled: July 17, 2000Date of Patent: April 27, 2004Assignee: The Procter & Gamble CompanyInventors: Douglas Herrin Benson, John Joseph Curro
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Patent number: 6726863Abstract: A method for producing a tube section from thermoplastic material, in which a tube section is extruded by means of an extruder which is provided with an extruder die having an inner core, which inner core defines an axial hollow space in the tube section, the tube section coming out of the extruder die downstream of the extruder die being internally cooled by means of an internal cooling member and externally cooled by means of an external cooling device. Immediately after the tube section leaves the extruder die, the internal cooling member brings about internal cooling of the tube. The external cooling device is positioned downstream of the internal cooling member, so that the external cooling of the tube section is brought about after the internal cooling.Type: GrantFiled: August 29, 2001Date of Patent: April 27, 2004Assignee: Wavin B.V.Inventors: Arjan Dirk van Lenthe, Jan Hendrik Prenger, Jan Visscher
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Patent number: 6719940Abstract: A method of controlling the gloss of a white biaxially oriented polyester film. The film will include at least one layer containing a cycloolefin copolymer at a concentration of about 4 to about 60% by weight of that layer. The method includes the step of stretching the film in a machine direction to a ratio of about 2.3 to about 3.4 to obtain desired gloss characteristics.Type: GrantFiled: March 13, 2001Date of Patent: April 13, 2004Assignee: Mitsubishi Polyester Film LLCInventor: Jeffrey R. Rounsley
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Patent number: 6713185Abstract: A method of forming a reinforced polymer film structure is disclosed that includes the steps of slitting a biaxially oriented polymer film web having a top face and a bottom face into a first portion and a second portion, identifying the first portion and the second portion, and placing the first portion atop the second portion, such that the bottom face of the first portion is adjacent the top face of the second portion. This structure provides an impact and tear resistant laminate. Also disclosed is a method of forming a polymer film structure by identifying a molecular orientation direction profile of two portions of biaxially oriented polymer film and layering the two portions such that a molecular orientation direction profile of one does not coincide with a molecular orientation direction profile of the other.Type: GrantFiled: February 13, 2001Date of Patent: March 30, 2004Assignee: Mitsubishi Polyester Film, LLCInventors: Charles David Carlson, Jr., Russell Scott Foxhall
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Publication number: 20040058093Abstract: The method of producing a film includes the steps of: casting a dope prepared by dissolving a macromolecular material in a solvent on a casting band; stripping the cast dope from the casting band to form a film; subjecting the stripped film to tentering to stretch or regulate the same in its width direction; and subjecting the tentered film to roll drying to dry the film while conveying the same in such a manner that it engages with a plurality of rolls, the method being characterized in that the solvent content in the film at the beginning of roll drying after tentering is kept within the range of 3 to 8% by weight, the surface temperature of the film during the roll drying is kept within the range of the film's Tg (glass transition temperature) −15° C. to the Tg, and the rate of the film expansion in the film conveying direction is kept within the range of −2% to 3%.Type: ApplicationFiled: September 16, 2003Publication date: March 25, 2004Inventor: Hiroshi Nakashima
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Patent number: 6709731Abstract: The invention relates to a sealable, UV-resistant and flame-retardant, coextruded, biaxially oriented polyester film with one matt side and composed of at least one base layer B and of, applied to the two sides of this base layer, a sealable outer layer A and matt outer layer C. The film also comprises at least one light stabilizer which is a UV stabilizer, and comprises a flame retardant. The invention also includes the use of the film and a process for its production.Type: GrantFiled: July 26, 2002Date of Patent: March 23, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
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Patent number: 6706228Abstract: Polyolefin/filler breathable films may be produced by machine or transverse direction orientation using interdigitating grooved rollers. Biaxial orientation to similarly produce breathable films may be accomplished by the same method. By heating the rollers, the breathability of the film is increased without increasing the depth of engagement of the interdigitating rollers.Type: GrantFiled: June 18, 2001Date of Patent: March 16, 2004Assignee: ExxonMobil Chemical CompanyInventor: John H. Mackay
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Patent number: 6703138Abstract: A laminated polyester film in which a coating layer whose main constituent component is a water-soluble or water-dispersible resin is provided on at least one side of a polyester film, wherein the water resistance value of the film is at least 90%, the discoloration after melt molding is no more than 10, and the haze value change after heating is no more than 20%. Adhesion, water resistance, recoverability, and whitening resistance after heating are all excellent.Type: GrantFiled: August 7, 2002Date of Patent: March 9, 2004Assignee: Toyo Boseki Kabushiki KaishaInventors: Hiroshi Taki, Chikao Morishige, Shinya Higashiura, Masayoshi Satoh
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Publication number: 20040043173Abstract: A method for producing a coated polymeric article by co-extruding polypropylene and a maleic anhydride modified polypropylene, corona-treating, and applying a polysilicate barrier is described. Also provided are films and bottles produced using this method.Type: ApplicationFiled: September 16, 2003Publication date: March 4, 2004Applicant: Hoechst Trespaphan GmbHInventor: Ravi Prasad
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Publication number: 20040044322Abstract: A method for making absorbent pads for various absorbent articles is provided. A strip of the absorbent web material is conveyed along a machine direction, the absorbent web material having a generally first constant cross-direction width and generally first uniform basis weight. Longitudinally defined portions of the web material are stretched in the cross direction so as to define longitudinal sections having a wider cross-direction width and decreased basis weight alternately spaced between longitudinally extending sections of the web material having a lesser cross-direction width and greater basis weight. The web is released eventually cut in a cross direction into individual absorbent pads such that each pad has a crotch section corresponding to the longitudinal section having the lesser cross-direction width and greater basis weight and at least one of a front section and back section corresponding to the wider cross-direction width and decreased basis weight.Type: ApplicationFiled: August 30, 2002Publication date: March 4, 2004Applicant: KIMBERLY-CLARK WORLDWIDE, INC.Inventor: Shannon Melius
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Patent number: 6699418Abstract: A method for producing a biaxially stretched film is provided, in which the method comprises, stretching a film made mainly of an ethylene-vinyl alcohol copolymer having an ethylene content of 15 to 70 mol % and a saponification degree of 80 mol % or more under heating; cooling the film; and subjecting the cooled film to a heat treatment; wherein a heating temperature during the stretching is 60 to 160° C., a cooling temperature is a temperature 30 to 100° C. lower than the heating temperature during the stretching, and a temperature for the heat treatment is 150 to 190° C. The thus obtained biaxially stretched film of the present invention has a small bowing coefficient.Type: GrantFiled: February 14, 2002Date of Patent: March 2, 2004Assignee: Kuraray Co., Ltd.Inventors: Kazuhisa Okada, Nariaki Fujii
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Patent number: 6696146Abstract: Mono- or biaxially-stretched polyester resin foamed sheets and films wherein the polyester resin has a melt strength of more than 1 centinewton at 280° C., a melt viscosity of at least 1500 Pa.s at 280° C. for a shear ratio which tends to zero and a crystallization rate such that for a 10-minute heating at 120° C. the crystallinity can reach values as high as 30-35%.Type: GrantFiled: March 20, 2000Date of Patent: February 24, 2004Assignee: Sinco Ricerche S.p.A.Inventors: Hussein Al Ghatta, Sandro Cobror, Tonino Severini
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Publication number: 20040026827Abstract: Precrystallizing an amorphous crystallizable thermoplastic article, such as an amorphous polyethylene terephthalate article, by heating to thermally induce crystallinity, then orienting at a temperature that is preferably greater than the crystallizing temperature, provides articles having substantially improved thermal dimensional stability together with high tensile modulus properties. The process is particularly useful in the production of containers suitable for use in hot-fill applications.Type: ApplicationFiled: June 12, 2003Publication date: February 12, 2004Inventors: Issam Dairanieh, Stefanos L. Sakellarides
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Patent number: 6689454Abstract: The invention relates to a white, flame-resistant, UV-stable, thermoformable, oriented film made from a crystallizable thermoplastic, the thickness of which lies in the range of from 10 &mgr;m to 350 &mgr;m. Said film comprises at least one white pigment, a flame-proofing agent and a UV absorber and is characterized by good stretchability and thermoformability, by good optical and mechanical properties and an economical production. The invention further relates to a method for the production of said film and the use thereof.Type: GrantFiled: July 19, 2002Date of Patent: February 10, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Guenther Crass, Ulrich Kern, Klaus Oberlaender
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Publication number: 20040021251Abstract: The present invention relates to improved processability of polyolefin films through the addition to the basic isotactic polypropylene (iPP) polymer of a resin or rosin modifier in an amount within the range of 1 to 30 weight percent. Alternatively, the composition could contain from about 5 to about 10 weight percent of a resin or rosin. Preferably the mixture should contain resin or rosin modifiers in an amount of about 10 percent by weight. The invention encompasses both the resulting polyolefin films and the process for producing such film. The improved processability of the film includes fewer web breaks and drawability at higher line speeds, resulting in fewer shut downs of the processing line and a decrease in manufacturing time. These improvements are measured in terms of variable machine direction orientation draw ratios and transverse direction orientation oven temperatures.Type: ApplicationFiled: July 29, 2003Publication date: February 5, 2004Inventors: William R. Wheat, Aiko Hanyu
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Patent number: 6685871Abstract: Toughened biaxially oriented polyamide films prepared by dry blending i) a polyamide homopolymer, copolymer, or blends thereof; and ii) a functionalized polyolefin terpolymer comprising maleic anhydride, ethyl acrylate, and an olefin, to thereby form a dry mixture. The dry mixture is melted to form a polymer blend, which is then formed into a polymer film. The edges of the film are pinned to a casting roll, and the film is plasticized in at least one water bath. The polymer film is subsequently biaxially oriented. The result is a toughened biaxially oriented film which is resistant to pinholes, cracks, and other structural defects. Such films are particularly suited for making packaging materials for various food products.Type: GrantFiled: May 15, 2001Date of Patent: February 3, 2004Assignee: Honeywell International Inc.Inventors: Jeffrey D. Moulton, Delroy G. Blissett, Gary M. Bardzak, Anthony B. Crochunis, Ann M. Majestic, Simon J. Porter, Thomas L. Staskowski
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Patent number: 6685865Abstract: The present invention is directed to a process for producing a biaxially oriented polyester film which comprises: subjecting a polyester film to simultaneous biaxial stretching in a stretching apparatus constructed to simultaneously stretch the film in the lengthwise and widthwise directions thereof; and subsequently subjecting the film to successive biaxial stretching in the lengthwise and widthwise directions thereof in the same apparatus as mentioned above. With this process, a film can be efficiently formed, without film breaking, which film is small in thickness and greatly strong in its lengthwise and widthwise directions.Type: GrantFiled: October 23, 2001Date of Patent: February 3, 2004Assignee: Toray Industries, Inc.Inventors: Katsuya Toyoda, Satoru Nishino, Toshiya Nishibayashi
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Patent number: 6677049Abstract: The invention relates to a multi-layered biaxially-oriented film, mainly made of a crystallizeable thermoplastic polyester and economically produceable with a high surface quality, i.e. without pinning bubbles and without electric arcing and film breaks, at production speeds of 340 m/min or higher. According to the invention the multi-layered polyester film has an average specific electrical melt resistance over its total thickness which lies within a range from 1.5×107 to 30×107 &OHgr;×cm. The invention also relates to a method of production of the film.Type: GrantFiled: August 24, 2001Date of Patent: January 13, 2004Assignee: Mitsubishi Polyester Film GmbHInventors: Harald Mueller, Ursula Murschall
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Patent number: 6676886Abstract: An improved pipe belling process is shown which features a mandrel having a specially designed backup or forming collar. The backup collar has an exposed lip portion which forms a complimentary angle with the outer sloped surface of the gasket which it abuts. The complimentary angles of the backup collar and gasket form a wedge shaped contact area which serves to retain the gasket in its initial circumferential position on the working surface of the mandrel as the heated pipe is forced over the mandrel and gasket.Type: GrantFiled: September 26, 2001Date of Patent: January 13, 2004Assignee: S&B Technical Products, Inc.Inventor: Bradford Corbett, Jr.
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Patent number: 6649247Abstract: The invention relates to a sealable, flame-retardant, coextruded, biaxially oriented polyester film with one matt side, and composed of at least one base layer B and of, applied to the two sides of this base layer, a sealable outer layer A and a matt outer layer C. The film also comprises at least one flame retardant. The invention further relates to the use of the film and to a process for its production.Type: GrantFiled: July 26, 2002Date of Patent: November 18, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
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Patent number: 6641924Abstract: The present invention relates to a white, biaxially oriented polyester film having at least a base layer, the characterizing features of which are that at least this base layer comprises a cycloolefin copolymer (COC) at a concentration of from 4 to 60% by weight, based on the base layer, where the glass transition temperature of cycloolefin copolymer (COC) is within the range from 70 to 270° C.Type: GrantFiled: October 19, 1999Date of Patent: November 4, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Patent number: 6638988Abstract: A porous thermoplastic resin film capable of functioning well as a separator of a cell is provided. The porous film is constituted with a thermoplastic resin and a filler, wherein XR defined by the following formula: XR=25×TGUR×d2/Y is smaller than 5, where Y(&mgr;m), TGUR (sec/100 cc), and d (&mgr;m) represent the thickness, the gurley value, and the average pore diameter of said film, respectively. The porous film constructed as shown above can reduce the internal resistance of a cell when used as a separator of the cell.Type: GrantFiled: October 23, 2001Date of Patent: October 28, 2003Assignee: Sumitomo Chemical Company, Ltd.Inventors: Atsuhiro Takata, Takeshi Yamada, Ryuma Kuroda
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Patent number: 6638465Abstract: A multilayer film is formed by coextruding and bistretching EVOH, binder and polyester followed by heat treating for less than 8 seconds at a temperature between 170° C. and 250° C.Type: GrantFiled: June 11, 2001Date of Patent: October 28, 2003Assignee: Dupont Teijin Films US Limited PartnershipInventors: Christine Andreis-Olinger, Gusty Feyder
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Patent number: 6630224Abstract: The invention relates to a matt, biaxially oriented polyester film having at least one matt base layer (B) which comprises at least 70% by weight of thermoplastic polyester, and also a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention has characteristic matt surfaces and has good suitability for use as a packaging film or for industrial applications.Type: GrantFiled: September 10, 2001Date of Patent: October 7, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Guenther Crass, Gottfried Hilkert
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Patent number: 6627295Abstract: The invention relates to a biaxially oriented polyester film having at least one matt side and composed of at least one base layer (B) and of, applied to this base layer, at least one matt outer layer (A) which comprises at least 70% by weight of thermoplastic polyester and also to a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention with the outer layer (A) has a characteristic matt surface and characteristic optical properties and has good suitability for use as a packaging film or for industrial applications.Type: GrantFiled: September 10, 2001Date of Patent: September 30, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Stefan Bartsch
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Patent number: 6617035Abstract: The invention relates to a hot-sterilizable, biaxially oriented polyester film with good metal adhesion, with a base layer B containing at least 80% by weight of thermoplastic polyester, and with at least one adhesive layer which contains a mixture or a blend of two components I and II, wherein component I of the mixture or the blend contains a polyethylene terephthalate copolymer, which contains a sulfomonomer and wherein component II of the mixture or the blend contains acrylic copolymer.Type: GrantFiled: December 11, 2001Date of Patent: September 9, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Stefan Bartsch, Richard Lee Davis
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Patent number: 6607808Abstract: The invention relates to a biaxially oriented polyester film having at least one matt side and composed of at least one base layer (B) made from a thermoplastic polyester and of, applied to this base layer (B), at least one matt outer layer (A) which comprises at least 70% by weight of thermoplastic polyester. The outer layer (A) has a characteristic matt surface and characteristic optical properties and has good suitability for use as a packaging film or for industrial application. The invention further relates to the use and to a process for its production.Type: GrantFiled: September 10, 2001Date of Patent: August 19, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Stefan Bartsch, Martin Mueller-Roosen
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Patent number: 6607815Abstract: The invention describes a biaxially oriented polyester film with at least one base layer B, with at least one metal-adherent outer layer A, and preferably with another outer layer C, the metal-adherent outer layer A having a metal adhesion of at least 4 N/25 mm wherein the metal adherent layer consists essentially of an amorphous copolyester comprising ethylene terephthalate and ethylene isophthalate units.Type: GrantFiled: July 18, 2001Date of Patent: August 19, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Stefan Bartsch, Herbert Peiffer
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Patent number: 6607834Abstract: Polyester-containing multilayer biaxially-oriented polypropylene films are provided. According to the invention, a two- or three-layer polyester-containing cap layer is bonded to a monoaxially oriented polypropylene core, followed by orientation of the resulting composite in a direction transverse to the direction of orientation of the core layer. At least one tie layer is interposed between the core and the polyester. Advantageously, the polyester contains silicone fluid as a processing aid.Type: GrantFiled: March 7, 2001Date of Patent: August 19, 2003Assignee: Applied Extrusion Technologies, Inc.Inventors: Alan M. Davis, John H. Lawrence, Tung-Yao Weng
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Publication number: 20030151162Abstract: A method of making a polypropylene product for use in making films and preferably biaxially oriented films and more preferably biaxially oriented films wherein a tenter-frame processing line is employed. The method includes the addition of low concentrations of a nucleating system in a mini-random polypropylene that allows for better processability and improved tensile properties. In one embodiment the nucleating system comprises a blend of a monocarboxylic acid nucleating agent and dicarboxylic acid nucleating agent. The nucleating system is combined with the polypropylene material and the resultant hot melt blend is further processed into biaxially oriented film. Alternately, the hot melt blend is formed into a convenient raw material for later use in a biaxial oriented film production facility. The resulting films possess superior processing and material characteristics.Type: ApplicationFiled: January 14, 2002Publication date: August 14, 2003Inventors: Victor M. DiNardo, Nicholas Z. Karnavas
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Publication number: 20030148131Abstract: The object of the present invention is to provide a method for producing a polyester film excellent in rigidity, toughness, dimensional stability, electric properties, etc. and less in thickness fluctuation and surface defects, hence very suitable as a film for various industrial materials such as magnetic recording media, capacitors, heat transfer ribbons and thermal mimeographic stencil paper. The first method of the present invention is a method for producing a polyester film, in which a film made of a resin mainly composed of a polyester is simultaneously biaxially stretched by a simultaneously biaxially stretching tenter oven, comprising the step of effecting small-ratio stretching at an area stretching ratio of 1.0005 to 3.Type: ApplicationFiled: September 23, 2002Publication date: August 7, 2003Applicant: Toray Industries, Inc.Inventors: Tetsuya Tsunekawa, Takuji Higashioji, Kenji Tsunashima
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Patent number: 6602585Abstract: A shrinkable iridescent film constitutes an oriented multilayer coextruded iridescent film having at least 10 generally parallel, very thin layers of substantially uniform thickness in which the contiguous adjacent layers are of heat shrinkable thermoplastic resinous material, each of which is heat shrinkable in at least one dimension in the plane of the film, the continuous adjacent layers being substantially uniformly shrinkable so as to have refractive indexes which differ by at least 0.03. The shrinkable film is made by selecting appropriate thermoplastic resinous materials, coextruding them into a thick film and then subjecting the film to orientation below the heat set temperature of the resinous materials.Type: GrantFiled: September 26, 2001Date of Patent: August 5, 2003Assignee: Engelhard CorporationInventor: Daniel J. Graney
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Publication number: 20030124280Abstract: Multilayer shaped articles, including films, preforms and containers, and method for forming the same, having at least one layer of poly(1,3-propylene 2,6-naphthalate) and at least one layer of poly(ethylene terephthalate). Poly(1,3-propylene 2,6-naphthalate) can be co-stretched with poly(ethylene terephthalate) to form oriented multilayer structures which have superior barrier properties. The poly(1,3-propylene 2,6-naphthalate) and poly(ethylene terephthalate) layers have good adhesion and do not require an adhesive tie layer.Type: ApplicationFiled: November 21, 2002Publication date: July 3, 2003Inventors: Pallatheri M. Subramanian, Howard Chung-Ho Ng, Ross A. Lee
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Patent number: 6586073Abstract: Fibers and microfibrillated articles are provided by imparting fluid energy to at least one surface of a highly oriented, voided, melt-processed polymeric film. The fibers and microfibrillated articles are useful as tape backings, filters, thermal and acoustical insulation and as reinforcement fibers for polymers or cast building materials such as concrete.Type: GrantFiled: September 20, 2001Date of Patent: July 1, 2003Assignee: 3M Innovative Properties CompanyInventors: Mario A. Perez, Sundaravel Damodaran, Michael D. Swan
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Patent number: 6585920Abstract: Embossed oriented thermoplastic films and a method of making same are described. The embossed oriented thermoplastic films have substantially the same mechanical properties as unembossed oriented thermoplastic films. The method includes providing an oriented thermoplastic film having first and second major surfaces, softening at least one of the first and second major surfaces to produce a softened surface, embossing the softened surface to produce an embossed oriented thermoplastic film, and cooling the embossed oriented thermoplastic film.Type: GrantFiled: April 27, 2001Date of Patent: July 1, 2003Assignee: 3M Innovative Properties CompanyInventors: Joan M. Strobel, Mark A. Strobel, Patrick J. Hager, Ronald S. Kapaun
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Patent number: 6582642Abstract: A running length of fastener product is formed of longitudinally pre-oriented synthetic resin. The product is characterized by a base web and an array of discrete fastener elements protruding from at least one side of the web, the web being in a laterally stretched molecular oriented condition. After forming a preform having discrete fastener elements integral with a base web in a stretchable state, the preform is stretched in a manner that substantially increases the fastener element spacing and reduces the thickness of the base web. A machine is shown that is capable of lengthwise orienting before forming and widthwise stretching after forming, which employs controlled heating to render the product widthwise stretchable while preserving or achieving a desired shape of the fastener elements.Type: GrantFiled: March 3, 2000Date of Patent: June 24, 2003Assignee: Velcro Industries, B.V.Inventors: Keith G. Buzzell, George A. Provost, Richard G. Maydra
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Publication number: 20030111764Abstract: Disclosed is a method of manufacturing a cellulose ester film according to a solution casting film manufacturing process comprising the steps of casting a cellulose ester dope on a support to form a film on the support, peeling the film from the support, drying the peeled film, and winding the dried film around a take-up spool, wherein the following relationship is satisfied:Type: ApplicationFiled: September 6, 2002Publication date: June 19, 2003Inventor: Katsusuke Nagashima
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Patent number: 6572806Abstract: A multilayered biaxially-oriented styrene based resin sheet comprises; a styrene based resin layer (A) as at least two outer layers formed by the polymerization of methacrylic acid in a weight proportion of 1˜3.5% and styrene, and a styrene based resin layer (B) formed from polystyrene which is sandwiched between the outer layers and for which the loss tangent (tan &dgr;) maximum peak value temperature for dynamic viscoelasticity measurement is 6.5˜25° C. lower than that for the resin of the resin layer (A). The sheet has excellent properties of transparency and external appearance, can be reused by recovering and moreover does not suffer from raindrop occurrence by secondary forming.Type: GrantFiled: September 29, 2000Date of Patent: June 3, 2003Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Satoshi Oya, Hidetsugu Sawada, Akio Toyoda, Kosuke Arai, Nobuyuki Konishi, Koji Adachi
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Patent number: 6565936Abstract: A film laminate is disclosed and comprises a biaxially oriented polyester film and another film laminated onto the polyester film, where the polyester film comprises a base layer at least 80% by weight of which is composed of a thermoplastic polyester, at least one cover layer and a metallic or ceramic layer located on the cover layer, where the cover layer is composed of a polymer or of a copolymer or of a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units, up to 40% by weight of ethylene terephthalate units and, if desired, up to 60% by weight of units of other aliphatic, cycloaliphatic or aromatic diols and/or carboxylic acids, with the proviso that the Tg2 value of the polyester film is greater than the Tg2 value of the base layer but smaller than the Tg2 value of the cover layer.Type: GrantFiled: November 2, 1999Date of Patent: May 20, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Richard Lee Davis
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Patent number: 6562274Abstract: A biaxially oriented polyester film that is 7.0 GPa or more in either the Young's modulus in the machine direction (YmMD) or in the transverse direction (YmTD), and in the range of 55° or more and 85° or less in the circumferential half-width of the diffraction line from the crystal plane in the direction of the polyester's backbone chain that is determined through crystal orientation analysis by wide angle X-ray diffractometry performed while rotating the polyester film around its normal. The film is high in rigidity in all directions within the film plane, high in tear resistance, high in dimensional stability, and resistant to deformation under load, and have very great industrial advantages as material for high-density magnetic recording media, with wide applicability as material for electrostatic capacitor, heat transfer ribbon, and base paper for thermosensitive stencil printing.Type: GrantFiled: October 27, 2000Date of Patent: May 13, 2003Assignee: Toray Industries, Inc.Inventors: Masayoshi Asakura, Kenichi Etou, Tetsuya Tsunekawa
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Patent number: 6558591Abstract: A microporous film of polyethylene having an intrinsic viscosity above 5 dl/g is prepared from a homogeneous solution in an evaporable solvent. The film is cooled and evaporable solvent is evaporated at a temperature below the dissolution temperature. The film is stretched to produce the micorporous film and is passed through a calender. The microporous films with a porosity of up to about 70% by volume and a battery separator quality factor (F) of at least 2.5 are described. Battery separators formed from the microporous films are also described.Type: GrantFiled: December 5, 2000Date of Patent: May 6, 2003Assignee: DSM N.V.Inventor: Gijsbertus H. M. Calis
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Publication number: 20030082976Abstract: A transversely stretched nonwoven fabric is manufactured by transversely stretching a nonwoven fabric. First, an original web comprising a plurality of un-oriented filaments is heated to a temperature higher than its stretch suitable temperature by 5° C. or more. Next, the heated original web is stretched at a rate of 1.2 to 3 in its transverse direction to stretch the filaments of the original web with almost no molecular orientation involved. Then, the original web stretched transversely at a rate of 1.2 to 3 is heated to the stretch suitable temperature and the original web is further stretched transversely at the stretch suitable temperature. With these steps, a transversely stretched nonwoven fabric in which the original web is stretched transversely at a rate of 7 times or more in total as compared with the state of the stretch thereof is manufactured with a high tensile strength of 132.5 mN/tex (1.5 g/d) in the transverse direction.Type: ApplicationFiled: December 4, 2002Publication date: May 1, 2003Inventors: Yuki Kuroiwa, Yoshiro Morino, Kazuhiko Kurihara, Shuichi Murakami
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Publication number: 20030082977Abstract: A transversely stretched nonwoven fabric is manufactured by transversely stretching a nonwoven fabric. First, an original web comprising a plurality of unoriented filaments is heated to a temperature higher than its stretch suitable temperature by 5° C. or more. Next, the heated original web is stretched at a rate of 1.2 to 3 in its transverse direction to stretch the filaments of the original web with almost no molecular orientation involved. Then, the original web stretched transversely at a rate of 1.2 to 3 is heated to the stretch suitable temperature and the original web is further stretched transversely at the stretch suitable temperature. With these steps, a transversely stretched nonwoven fabric in which the original web is stretched transversely at a rate of 7 times or more in total as compared with the state of the stretch thereof is manufactured with a high tensile strength of 132.5 mN/tex (1.5 g/d) in the transverse direction.Type: ApplicationFiled: December 4, 2002Publication date: May 1, 2003Inventors: Yuki Kuroiwa, Yoshiro Morino, Kazuhiko Kurihara, Shuichi Murakami
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Patent number: 6555190Abstract: The present invention provides coextruded or laminated multilayer films having at least one layer of a halopolymer such as poly(chlorotrifluoro ethylene) (PCTFE), at least one layer of a naphthalene containing polymer such as poly(ethylene naphthalate) (PEN), and an intermediate adhesive layer. The invention further provides methods of producing oriented, multilayer films which comprise either coextruding or laminating at least one layer of a halopolymer to a surface of at least one layer of a naphthalene containing polymer by an intermediate adhesive layer. The multilayer film may be uniaxially or biaxially stretched, and an optional thermoplastic polymer layer may be attached to another surface of either the halopolymer layer, the naphthalene containing polymer layer, or both, by another intermediate adhesive layer.Type: GrantFiled: August 24, 1998Date of Patent: April 29, 2003Assignee: Honeywell International Inc.Inventor: Mingliang Lawrence Tsai
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Publication number: 20030077968Abstract: A transversely stretched nonwoven fabric is manufactured by transversely stretching a nonwoven fabric. First, an original web comprising a plurality of un-oriented filaments is heated to a temperature higher than its stretch suitable temperature by 5° C. or more. Next, the heated original web is stretched at a rate of 1.2 to 3 in its transverse direction to stretch the filaments of the original web with almost no molecular orientation involved. Then, the original web stretched transversely at a rate of 1.2 to 3 is heated to the stretch suitable temperature and the original web is further stretched transversely at the stretch suitable temperature. With these steps, a transversely stretched nonwoven fabric in which the original web is stretched transversely at a rate of 7 times or more in total as compared with the state of the stretch thereof is manufactured with a high tensile strength of 132.5 mN/tex (1.5 g/d) in the transverse direction.Type: ApplicationFiled: December 4, 2002Publication date: April 24, 2003Inventors: Yuki Kuroiwa, Yoshiro Morino, Kazuhiko Kurihara, Shuichi Murakami
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Patent number: 6548628Abstract: The present invention relates to single- or multilayer films and one or more layers comprising at least one polyolefin molding composition containing at least one polyolefin derived from at least one olefin having at least 2 carbon atoms, of the formula Ra—CH═CH—Rb, in which Ra and Rb are identical or different and are a hydrogen atom or a straight-chain or branched C1-C15-alkyl radical, or Ra and Rb, together with the atoms connecting them, form a ring or ring system, and the polyolefin has been prepared by means of metallocene catalysts. The present invention furthermore relates to a process for the production of films and layers in which a polyolefin molding composition having a particle size of from 20 &mgr;m to 5000 &mgr;m is used or prepared. The shaped polyolefin molding composition is melt-mixed with at least one additive and shaped. The melt-mixed and shaped material is melted at a temperature of from 150° C. to 300° C.Type: GrantFiled: December 20, 1996Date of Patent: April 15, 2003Assignee: Basell Polyolefine GmbHInventors: Andreas Winter, Ernst Hofmann, Gerhard Wieners, Bernd Bachmann
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Patent number: 6540949Abstract: Methods of producing polyethylene films having a desired water vapor transmission rate (WVTR) are provided. The methods include casting a polyethylene sheet which has a base layer of a polyethylene and a cavitating agent, and at least one layer of a WVTR-controlling material, and subsequently biaxially orienting the sheet to yield a film having the desired WVTR. The base layer has a porous microstructure and a WVTR substantially higher than the desired WVTR.Type: GrantFiled: April 18, 2001Date of Patent: April 1, 2003Assignee: ExxonMobil Oil CorporationInventors: Hans Joachim Pip, Rhonda Rogers Agent
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Publication number: 20030059593Abstract: A composite film is provided by providing a polypropylene or other base resin layer, laminating a first covering layer of a resin composition (1) comprising the following components (A), (B), (C) and (D) to one side of the base resin layer and a second covering layer of a resin composition (2) comprising the components (A) and (D) to the other side of the base resin layer, which composite film is optionally stretched. The resin composition (2) may contain component (C).Type: ApplicationFiled: July 11, 2002Publication date: March 27, 2003Inventors: Takatoshi Sakaguchi, Junichi Kimura, Teruaki Yoshida
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Patent number: 6533987Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to electromagnetic radiation (EMR) energy. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.Type: GrantFiled: December 15, 2000Date of Patent: March 18, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Vasily A. Topolkaraev, Thomas Walter Odorzynski, Dave Allen Soerens, Michael J. Garvey, Duane Girard Uitenbroek
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Patent number: 6528144Abstract: The invention relates to a biaxially oriented polyester film which has very good optical properties and good processing behavior and which after it has been metallized or coated with oxidic materials exhibits a high oxygen barrier and which is built up from at least one base layer B and at least one layer A applied on top of this base layer, this layer A having a number N of elevations/protrusions per mm2 of film surface area which is related to their respective heights h and diameters d by the following equations: log N/mm2<Ah−Bh*log h/&mgr;m, 0.01 &mgr;m<h<10 &mgr;m (1) wherein Ah=1.4; Bh=2.5 log N/mm2<Ad−Bd*log d/&mgr;m, 0.4 &mgr;m<d<10 &mgr;m (2) wherein Ad=3.4; Bd=2.4.Type: GrantFiled: February 9, 2001Date of Patent: March 4, 2003Assignee: Hoechst Diafoil GmbHInventors: Herbert Peiffer, Gottfried Hilkert, Werner Roth