Abstract: The present disclosure provides a negative electrode active material that can realize excellent low temperature characteristics. An negative electrode active material for a lithium ion secondary battery disclosed herein includes a carbon material that is able to reversibly occlude and release lithium ions and a carbon coating layer that is formed on a surface of the carbon material, and the carbon coating layer contains carbon atoms and phosphorus atoms. In addition, in the carbon coating layer, when a peak of a P2p spectrum measured through X-ray photoelectron spectroscopy (XPS) is subjected to waveform separation, it has a peak at a position at which the binding energy is 131 eV.

Abstract: A secondary battery is provided for cycling between a charged and a discharged state, the secondary battery including a battery enclosure, an electrode assembly, carrier ions, a non-aqueous liquid electrolyte within the battery enclosure, and a set of electrode constraints. The set of electrode constraints includes a primary constraint system having first and second primary growth constraints and at least one primary connecting member, the first and second primary growth constraints separated from each other in the longitudinal direction, wherein the primary constraint array restrains growth of the electrode assembly in the longitudinal direction such that any increase in the Feret diameter of the electrode assembly in the longitudinal direction over 20 consecutive cycles of the secondary battery is less than 20%.

Abstract: A pre-lithiated silicon-based anode includes a silicon-based anode, lithium disposed on a surface or in an interior of the silicon-based anode, and a protective coating on the surface of the silicon-based anode. The pre-lithiated silicon-based anode allows subsequent processing to be performed safely in the atmosphere.

Abstract: An all solid battery includes: a solid electrolyte layer including a glass component, a main component of the solid electrolyte layer being phosphoric acid salt-based solid electrolyte; and electrode layers that are provided on both main faces of the solid electrolyte layer, wherein the electrode layers include a carbon material having an average particle diameter of 40 nm or more and 120 nm or less, wherein a DBP oil absorption of the carbon material is 200 mL/100 g or less.

Abstract: A energy storage device for cycling between a charged state and a discharged state, the energy storage device including an enclosure, an electrode assembly and a non-aqueous liquid electrolyte within the enclosure, and a constraint that maintains a pressure on the electrode assembly as the energy storage device is cycled between the charged and the discharged states.

Abstract: Electrolytes and electrolyte additives for energy storage devices comprising alkoxyethane based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises an alkoxyethane based compound.

Abstract: A lithium secondary battery includes a cathode, a separator, and an anode including an anode current collector and an anode active material layer formed on the anode current collector and facing the cathode with the separator interposed therebetween. The anode active material layer includes a first anode active material layer formed on the anode current collector and including a first anode active material and a first anode binder containing a styrene-butadiene-based rubber (SBR) binder and a second anode active material layer formed on the first anode active material layer and including a second anode active material and a second anode binder containing a acryl-based binder. Each of the first anode active material and the second anode active material includes a silicon-based active material and a graphite-based material and contains 2 to 9.5 parts by weight of silicon with respect to the 100 part by weight of the graphite-based active material.

Abstract: Provided are methods of preparing a separator/anode assembly for use in an electric current producing cell, wherein the assembly comprises an anode current collector layer interposed between a first anode layer and a second anode layer and a porous separator layer on the side of the first anode layer opposite to the anode current collector layer, wherein the first anode layer is coated directly on the separator layer.

Abstract: Zinc electrolytic manganese dioxide (EMD) batteries including a high performing flexible chitosan-based gel electrolyte with poly-vinyl alcohol (PVA) and potassium hydroxide (KOH) additives were prepared. The Zn-EMD batteries were constructed using an optimized assembly technique employed to achieve good interfacial contact between the layers. Attaining energy densities between 150-250 Wh/kg (w.r.t cathode mass) is possible for these batteries, encouraging their use in wearable or flexible electronics. Using the chitosan-based gel electrolyte and limited voltage window testing, the prepared Zn-EMD alkaline batteries are among the best reported polymer-based alkaline electrolyte Zn rechargeable batteries.

Abstract: The embodiments of the present application provide a winding type electrode assembly including a positive electrode plate and a negative electrode plate; the positive electrode plate includes a first positive winding end portion and a positive winding middle section; the negative electrode plate includes a first portion and a second portion; and an active material layer of the negative electrode plate exceeds an active material layer of the positive electrode plate, and a difference between a maximum width of a negative active material layer of the first portion and a minimum width of a positive active material layer of the first positive winding end portion is larger than a difference between a maximum width of a negative active material layer of the second portion and a minimum width of a positive active material layer of the positive winding middle section.

Abstract: Provided are a composite separator, a lithium battery including the same, and a method of manufacturing the composite separator. The composite separator includes: a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a water-soluble binder and inorganic particles, and the water-soluble binder includes a polyacrylic acid metal salt.

Abstract: A method for producing a battery, the method includes a liquid injecting process. In this liquid injecting process includes: a first liquid-injecting step of injecting an electrolytic solution of a first injection amount (V1) determined so that a liquid-level height of the electrolytic solution falls within an intermediate liquid-level range in which the liquid-level height is equal to or higher than a first reference height but is lower than a second reference height while an air pressure in a metal battery case is regulated to a first air pressure; and a second liquid-injecting step of injecting the electrolytic solution in a remaining second injection amount up to a specified amount while increasing the air pressure in the metal battery case to a second air pressure higher than the first air pressure and maintaining the liquid-level height of the electrolytic solution within the intermediate liquid-level range.

Abstract: Described herein are electrochemical cells fabricated with current collectors comprising polymer bases and metal layers and methods of interconnecting these current collectors or, more specifically, interconnecting their metal layers. For example, a current collector, positioned between two other current collectors, can have an opening allowing these two other current collectors to form a direct interface. This interface not only directly interconnects the metal layers on these two current collectors but also indirectly interconnects the two metal layers of the middle current collector, which are positioned on the opposite sides of the polymer base of this current collector. In some examples, the metal layers of current collectors are reinforced by external metal foils that help to maintain continuity and/or repair any discontinuities in the metal layers when these metal layers are welded together. For example, welding may push portions of the polymer bases away from the weld zone.

Abstract: A negative active material for a rechargeable lithium battery includes a core including a SiO2 matrix and a Si grain, and a coating layer continuously or discontinuously coated on the core. The coating layer includes SiC and C, and the peak area ratio of the SiC (111) plane to the Si (111) plane as measured by X-ray diffraction analysis (XRD) using a CuK? ray ranges from about 0.01 to about 0.5.

Abstract: A conductive material dispersion includes a carbon-based conductive material, a main dispersant, an auxiliary dispersant, and a dispersion medium, wherein the main dispersant is a nitrile-based copolymer and the auxiliary dispersant is a copolymer including an oxyalkylene unit and at least one selected from the group consisting of a styrene unit and an alkylene unit.

Abstract: A method of making a passively impact resistant battery includes the steps of providing a porous separator material having pores and a surface, and providing a suspension composition including shear thickening enabling particles and a particle suspension solvent for suspending the shear thickening enabling particles. The shear thickening particles have a polydispersity index of no greater than 0.1, an average particle size of in a range of 50 nm to 1 um, and an absolute zeta potential of greater than ±40 mV. The suspension composition is applied to the separator material, wherein a portion of the particles and suspension solvent penetrate the pores. The suspension solvent is evaporated from the separator material. An anode layer and a cathode layer are applied. An electrolyte composition is applied between the anode layer and the cathode layer. The electrolyte composition includes an electrolyte solvent and an electrolyte salt.

Abstract: A secondary battery includes: a positive electrode having a positive-electrode current collector and a positive-electrode active-material layer; a negative electrode having a negative-electrode current collector and a negative-electrode active-material layer; a electrolyte; and an insulating tape covering a portion of the positive electrode. Furthermore, the positive-electrode current collector has an exposed section that the positive-electrode active-material layer is not disposed. In addition, at least a portion of the exposed section is covered with the insulating tape; the insulating tape has a substrate material layer and an adhesive layer; and the adhesive layer includes an adhesive agent and an insulating inorganic material.

Abstract: A method for producing an electrode sheet includes a first feeding process, a roll press process, and a second feeding process, which are performed in this order. At least one of a first tension per unit area obtained by dividing a tension applied to the electrode sheet in a longitudinal direction in the first feeding process by a cross-sectional area of the electrode sheet being fed in the first feeding process and a second tension per unit area obtained by dividing a tension applied to the electrode sheet in a longitudinal direction in the second feeding process by a cross-sectional area of the electrode sheet being fed in the second feeding process is 5.0 MPa or less.

Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.

Abstract: A process for delineating a population of electrode structures in a web includes laser ablating the web to form ablations in the web, each ablation being formed by removing a portion of an electrochemically active layer to thereby expose a portion of an electrically conductive layer. The process includes forming alignment features in the web that are formed at predetermined locations on the web. The process also includes laser machining the web to form weakened tear patterns in the web that delineate members of the electrode structure population, each of the delineated members being individually bounded, at least in part, by a member of the weakened tear patterns that is adapted to facilitate separation of delineated members, individually, from the web by an application of a force, the alignment features being used to aid in the formation of the weakened tear patterns.

Abstract: To provide a negative electrode for a lithium ion secondary battery having more improved durability than conventionally, and a lithium ion secondary battery including the same. A negative electrode for a lithium ion secondary battery including a negative electrode active material in which an organic molecule having a dielectric constant larger than that of an electrolyte solvent is chemically bonded, and a lithium ion secondary battery including the same. Preferable examples of the organic molecule include a molecule having a relative dielectric constant of 90 or more at a frequency of 10 kHz, a molecule having a molecular structure that undergoes polarization in a single molecule or between molecules, a zwitter ion compound having a positive electric charge and a negative electric charge in one molecule, hydroxy acid, and a molecule having a molecular weight of 39 to 616.

Abstract: Provided are an anode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery containing the same. The present invention provides an anode active material for a lithium secondary battery including: a carbon based particle; a first carbon coating layer positioned on the carbon based particle and including pores; a silicon coating layer positioned on the pores and/or a pore-free surface of the first carbon coating layer; and second carbon coating layer positioned on the silicon coating layer, a method of preparing the same, and a lithium secondary battery containing the same.

Abstract: An example of a negative electrode includes silicon nanoparticles having a carbon coating thereon. The carbon coating has an oxygen-free structure including pentagon rings. The negative electrode with the silicon nanoparticles having the carbon coating thereon may be incorporated into a lithium-based battery. In an example of a method, silicon nanoparticles are provided. A carbon precursor is applied on the silicon nanoparticles. The carbon precursor is an oxygen-free, fluorene-based polymer. Then the silicon nanoparticles are heated in an inert gas atmosphere to form the carbon coating on the silicon nanoparticles. The carbon coating formed on the silicon nanoparticles has an oxygen-free structure including pentagon rings.

Abstract: This application provides a current collector and a preparation method thereof, a secondary battery containing such current collector, a battery module, a battery pack, and an electric apparatus. The current collector in this application includes a support layer, a binder layer, and a metal layer, where the binder layer is arranged between the support layer and the metal layer, the binder layer includes an organic binder and inorganic particles, a thickness D0 of the binder layer is 1.0-5.0 ?m, optionally 1.0-3.0 ?m; and the inorganic particles include large particles with a median particle size D50large and small particles with a median particle size D50small, and the median particle sizes of the large particles and the small particles satisfy the following relationships: D50large>D50small; D50large=(0.5-0.9)×D0; and D50small=(0.1-0.4)×D0.

Abstract: The present invention provides an all-solid state secondary cell equipped with: a positive electrode collector; a negative electrode collector; and a powder laminate placed between the positive electrode collector and the negative electrode collector. The powder laminate has: a positive electrode powder layer; a negative electrode powder layer; and solid electrolyte layers that are placed between the positive electrode powder layer and the negative electrode powder layer, and also cover the outer periphery of the positive electrode powder layer and the negative electrode powder layer. The powder laminate comprises a peripheral edge part, and a center part surrounded by this peripheral edge part. The thickness of the peripheral edge part is the thickness of the center part or greater.

Abstract: An organic electrochemical cell includes a cathode including a quinone compound, an anode including dipotassium terephthalate, an electrolyte, and a separator disposed between the anode and the cathode, the organic electrochemical cell configured such that, during a discharging operation, potassium ions travel through the separator and the electrolyte to the cathode.

Abstract: A nonaqueous electrolyte secondary battery disclosed herein includes a positive electrode plate including a positive composite layer, a negative electrode plate including a negative composite layer, and a nonaqueous electrolyte, in which the negative composite layer is composed of a facing portion facing a surface of the positive composite layer, and a non-facing portion that is on the same surface as the facing portion and does not face the surface of the positive composite layer, and the area ratio of the non-facing portion to a combined area of the facing portion and the non-facing portion of the negative composite layer is 7% or more, and the nonaqueous electrolyte contains a fluorinated carbonate and a cyclic sulfone compound.

Abstract: A method for fabricating an anode for a lithium ion battery cell is described and includes forming a solid electrolyte interface (SEI) layer on a raw anode prior to assembly into a battery cell by applying a first SEI-generating electrolyte to the raw anode to form a first intermediate anode, applying a second SEI-generating electrolyte to the first intermediate anode to form a second intermediate anode, and applying a third SEI-generating electrolyte to the second intermediate anode to form a cell anode, wherein the cell anode includes the raw anode having the SEI layer. Thus, a cell anode is formed by sequentially applying SEI-generating electrolytes to a raw anode to form the cell anode with an SEI layer, and a lithium ion battery cell is formed by assembling the cell anode into a cell pack, with a cathode, and a separator, and adding a cell electrolyte prior to sealing.

Abstract: Described herein are electrochemical cells that include composite gel positioned between the first electrode and second electrode, wherein the composite gel comprises an electrolyte, a polyaryl amine, and an oxidant. The composite gels described herein are easy to produce at a low-cost, which makes them suitable in a number of different applications electrochromic devices, supercapacitors, solar cells, and hybrid photoactive supercapacitors.

Abstract: Battery core packs employing minimum cell-face pressure containment devices and methods are disclosed for minimizing dendrite growth and increasing cycle life of metal and metal-ion battery cells.

Abstract: A secondary battery, including an electrode assembly and a housing accommodating the electrode assembly. The electrode assembly includes a first electrode plate, a second electrode plate, and a separator disposed there between. The first electrode plate and the second electrode plate are wound to form the electrode assembly. A tab is disposed in the first electrode plate and protrudes from the housing; and an adhesive layer is disposed in the tab. The adhesive layer includes a first portion sandwiched between a package area of the housing and a second portion extending from the first portion along a length direction of the tab. In a width direction of the tab, the first portion has a width greater than that of the second portion. In the length direction of the tab, the second portion protrudes into a space enclosed by an innermost layer of the separator.

Abstract: To provide a negative electrode for a secondary battery and a secondary battery having a large energy density and a capacity less likely to reduce even after repeated charging and discharging, and manufacturing methods thereof. The above-described problem is solved by a negative electrode for a secondary battery (3) comprising a negative electrode active material layer (3?) including at least a silicon-based active material and a binder, and a negative electrode current collector (14) having a structural form in which the silicon-based active material has an amorphous region including lithium and island-shaped lithium carbonate is distributed in the amorphous region.

Abstract: A manufacturing method for manufacturing a separator for a fuel cell includes a step of applying a laser beam to a surface of a plate-shaped metal plate having a rectangular shape such that an application range of the laser beam extends linearly. In the step, the laser beam is applied such that the application range includes a high-energy region in which energy to be given by the laser beam per unit distance in a direction where the application range extends linearly is high, and a low-energy region in which the energy is low. The high-energy region includes a first region, a second region, a third region, and a fourth region. The first region and the second region extend in parallel to one of long sides of the rectangular shape. The third region and the fourth region extend in parallel to the other one of the long sides.

Abstract: A capacitor may be configured with a dielectric laminate disposed on ordered or non-ordered structures. Materials for the dielectric laminate have high dielectric constant and reduce leakage current to increase breakdown voltage of the device. These materials may include titanium dioxide (TiO2) and silicon dioxide (SiO2). In one implementation, the capacitor may reside on a substrate. The capacitor may have structure (e.g., nano-tubes, nano-holes, etc;) disposed on the substrate having a surface area greater than the surface area of the substrate and a laminate conformally coating the structure, the laminate comprising a first layer and a second layer with materials that configure the capacitor with an energy density of at least 60 Wh/Kg.

Abstract: Systems, methods, and apparatus for encapsulating objects like that of microelectronic components and batteries. The system includes three successive layers that include a first covering layer composed of an electrically insulating material deposited by atomic layer deposition, which at least partly covers the object, a second covering layer that includes parylene and/or polyimide, and which is disposed on the first covering layer, and a third covering layer deposited on the second covering layer in such a way as to protect the second encapsulation layer, namely, with respect to oxygen, and thereby increase the service life of the object.

Abstract: A current collector of an electrochemical actuator is proposed, the current collector being coated with an interfacing layer, the interfacing layer being formed by coating on the current collector with a composition, the composition being formed by particles, at least 50% of the particles having a mean diameter by volume of less than or equal to 10 micrometers.

Abstract: A pouch-type secondary battery includes an electrode assembly, and a pouch member in which the electrode assembly is accommodated and a sealing portion is formed on an edge of the pouch member, where the sealing portion protruding on one side surface extends in a diagonal direction towards the other side surface adjacent to the at least one side surface.

Abstract: Materials and methods for preparing electrode film mixtures and electrode films including reduced damage bulk active materials are provided. In a first aspect, a method for preparing an electrode film mixture for an energy storage device is provided, comprising providing an initial binder mixture comprising a first binder and a first active material, processing the initial binder mixture under high shear to form a secondary binder mixture, and nondestructively mixing the secondary binder mixture with a second portion of active materials to form an electrode film mixture.

Abstract: An electrochemical device includes a cathode current collector, a first cathode active material layer, a second cathode active material layer and an insulating layer. The first cathode active material layer covers a first portion of a first surface of the cathode current collector, and the insulating layer covers a second portion of the first surface of the cathode current collector that is different from the first portion. A first distance exists between the insulating layer and the first cathode active material layer in a longitudinal direction of the cathode current collector. By providing a gap between the active material layer in a two-layer structure and the insulating layer in the cathode, thereby ensuring the mechanical safety performance of the electrochemical device.

Abstract: The present invention relates to a lithium-carbon composite having cavities formed therein and a method of manufacturing the same, the method including adding and mixing an organic solvent having an aromatic ring with a lithium precursor, arranging a pair of metal wires in the organic solvent, forming a lithium-carbon composite in which a carbon body is doped with lithium through plasma discharge in a solution, and annealing the lithium-carbon composite in order to remove hydrogen from the lithium-carbon composite and form cavities in the lithium-carbon composite. Accordingly, a lithium-carbon composite can be simply synthesized using plasma discharge in a solution, and the synthesized lithium-carbon composite can be annealed to thus form cavities therein, thereby increasing the lithium charge and discharge performance of a lithium secondary battery using the lithium-carbon composite.

Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.

Abstract: A method for manufacturing a spiral-wound battery is provided. The method includes the following steps: performing surface plasma treatment on a current collector; coating electrode slurry on a surface of the current collector, to form an electrode foil; performing surface plasma treatment on an isolating film, to improve hydrophilia of the isolating film; arranging and electrically connecting a plurality of metal conductive handles to the electrode foil, where the electrode foil is divided into a plurality of sections, and each section of the electrode foil corresponds to a jelly roll; and sequentially winding the isolating film and the electrode foil to form the spiral-wound battery. According to the method for manufacturing a spiral-wound battery provided in the present disclosure, internal impedance of a jelly roll is effectively reduced, and advantages of a high yield and low costs of a manufacturing process of the spiral-wound battery are maintained.

Abstract: A web coating platform for depositing molten metal on flexible substrates is provided. The web coating platform can be used for manufacturing solid lithium anodes for use in energy storage devices, for example, rechargeable batteries. The coating platform can be designed for double-sided coating of a continuous flexible substrate (e.g., a copper foil) with molten lithium followed by double-sided lamination or passivation. The coating platform integrates novel coating elements unique to handling and processing molten metals. For example, some implementations of the present disclosure incorporate double-sided molten metal coating elements, which include at least one of a molten metal application assembly (e.g., kiss roller, slot-die, Meyer bar, and/or gravure roller), a primary melt pool assembly, a secondary melt pool assembly, and an engagement mechanism.

Abstract: A web coating platform for depositing molten metal on flexible substrates is provided. The web coating platform can be used for manufacturing solid lithium anodes for use in energy storage devices, for example, rechargeable batteries. The coating platform can be designed for double-sided coating of a continuous flexible substrate (e.g., a copper foil) with molten lithium followed by double-sided lamination or passivation. The coating platform integrates novel coating elements unique to handling and processing molten metals. For example, some implementations of the present disclosure incorporate double-sided molten metal coating elements, which include at least one of a molten metal application assembly (e.g., kiss roller, slot-die, Meyer bar, and/or gravure roller), a primary melt pool assembly, a secondary melt pool assembly, and an engagement mechanism.

Abstract: A purpose of the present invention is to provide a lithium ion secondary battery having improved battery characteristics. The lithium ion secondary battery according to the present invention comprises a negative electrode comprising a negative electrode active material comprising a silicon material and an electrolyte solution comprising an electrolyte solvent comprising an open chain sulfone compound, a fluorinated cyclic carbonate and an open chain carbonate and a supporting salt comprising LiN(FSO2)2.

Abstract: A lithium metal oxide (LMO) cathode includes a current collector having a length defining a first end and a second end, a width, and a first side and a second side, LMO active material applied to the first side and the second side of the current collector such that the LMO active material applied to each respective side of the current collector has an inner face contiguous with the current collector and an outer face, and a plurality of channels extending widthwise across the cathode within the LMO active material applied to the first and second sides. The LMO active material on each current collector side can have a thickness of about 100 ?m to about 400 ?m. The channels on the same side of the current collector can be spaced apart by 0.1 mm to 10 mm. The channels can have widths of 10 ?m to 60 ?m.

Abstract: Articles and methods including composite layers for protection of electrodes in electrochemical cells are provided. In some embodiments, the composite layers comprise a polymeric material and a plurality of particles.

Abstract: A solid electrolyte composition includes: an inorganic solid electrolyte (A) having ion conductivity of a metal belonging to Group 1 or Group 2 in the periodic table; a binder (B); and a dispersion medium (C), in which the binder (B) includes a first binder (B1) that precipitates by a centrifugal separation process and a second binder (B2) that does not precipitate by the centrifugal separation process, the centrifugal separation process being performed in the dispersion medium (C) under a specific condition, and a content X of the first binder (B1) and a content Y of the second binder (B2) satisfy the following expression, 0.10?Y/(X+Y)?0.80.

Abstract: A solid electrolyte composition includes: an inorganic solid electrolyte (A) having ion conductivity of a metal belonging to Group 1 or Group 2 in the periodic table; a binder (B); and a dispersion medium (C), in which the binder (B) includes a first binder (B1) that precipitates by a centrifugal separation process and a second binder (B2) that does not precipitate by the centrifugal separation process, the centrifugal separation process being performed in the dispersion medium (C) at a temperature of 25° C. at a centrifugal force of 610000 G for 1 hour, and a content X of the first binder (B1) and a content Y of the second binder (B2) satisfy the following expression, 0.01?Y/(X+Y)<0.10.

Abstract: An all-solid-state battery includes a positive electrode layer, a solid electrolyte layer, and a negative electrode layer. The solid electrolyte layer separates the positive electrode layer from the negative electrode layer. The positive electrode layer includes a positive electrode active material, a conductive material, an oxide-based lithium ion conductor, and a sulfide-based solid electrolyte. A cross section of the positive electrode layer satisfies a relational expression (1): 3%?SB/SA?30%. In the relational expression (1), “SA” represents a partial area of the oxide-based lithium ion conductor that is in contact with the positive electrode active material, and “SB” represents a partial area of the oxide-based lithium ion conductor that is surrounded by the sulfide-based solid electrolyte.