Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the invention relates to electrochemichromic solutions, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. That is, the responsiveness observed in terms of solution coloring is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art. Preparation of these solutions involve the novel process of pre-treating at least one of the electrochemichromic compounds with a redox agent prior to placing it in contact with the other electrochemichromic compound. Moreover, the present invention relates to methods of preparing such novel solutions and processes for using these solutions to provide devices that exhibit and benefit from the aforementioned superior characteristics.

Abstract: Electrochromic compositions suitable for use in electrochromic media in electrochromic devices contain minimally two electrochromic compounds of the same redox type, whose redox potentials are greater than 30 mV. The lower redox potential electrochromic compound makes a large contribution to the absorbancy of the electrochromic medium despite being present in only minor concentration.

Abstract: An electrochromic device (10) of reversible light-transmissivity comprises a pair of spaced-apart window plate members (11, 13) bearing electrically-conductive surface layers (12, 14) and containing an electrochromotropic electrolyte solution in the intervening space (16). The electrolyte comprises an aqueous inorganic solution of a silver salt and may further comprise a salt of a transition metal. The electrolyte solutions are responsive to varying applied voltages by transitioning between solution phases of varying light-transmissivity which, depending upon solution composition, may be persistent or passively reversible.

Abstract: An electrochromic glazing assembly is disclosed with reduced ultraviolet (UV) radiation transmission and safety protection. The assembly may include at least a pair of glass or other elements confining an electrochromic medium therebetween. Ultraviolet radiation reducing means are incorporated for reducing ultraviolet radiation transmission through the assembly. A polymeric antilacerative layer is disposed on one surface of one of the glass elements for preventing lacerative injuries.

Abstract: A reversible electrochemical mirror (REM) includes a first electrode and a second electrode, one of which is substantially transparent to at least a portion of the spectrum of electromagnetic radiation. An electrolytic solution, disposed between the first and second electrodes, contains ions of a metal which can electrodeposit on the electrodes. The electrolytic solution also contains halide and/or pseudohalide anions having a total molar concentration ratio of at least 6:1 compared to that of the electrodepositable metal. A negative electrical potential applied to the first electrode causes deposited metal to be dissolved from the second electrode into the electrolytic solution and to be electrodeposited from the solution onto the first electrode to form a mirror deposit, thereby affecting the reflectivity of the REM device for electromagnetic radiation.

Abstract: A light-reactive thermal window is disclosed having external and internal panes. The external pane is composed of photochromic glass, while the internal pane is composed of clear glass. The panes are separated by a space having a uniform thickness. Each of the panes has a peripheral edge, with a spacer located between the peripheral edges of the external and internal panes. A sealant seals the peripheral edges of the external and internal panes. The window may include a frame securing together the spacer, the sealant, and the peripheral edges of the panes. Also disclosed is a method of preventing glare on a screen while minimizing climate control costs by installing a light-reactive thermal window near the screen.

Abstract: Electrochromic and photoelectrochromic devices using nanocrystalline semiconductor electrodes with a high specific surface area and surface-absorbed electrochromic molecules are disclosed.

Abstract: An improved electrochromic device for rearview mirror for motor vehicles and windows, the device incorporating an improved conductive clip comprising an elongated unitary member having a resilient backwall section connecting a plurality of first resilient sections separated from one another by a plurality of recesses and a plurality of second resilient sections Laterally spaced from the plurality of first resilient sections and separated from one another by a plurality of recesses, where each of the plurality of first resilient sections have at least one dimple adapted to bear against a surface of an electrozhromic device that is coated with a transparent conductor, and where each of the plurality of second resilient sections are adapted to bear against another surface of said electrochromic device, where said unitary member is capable of bending in three directions and supplying a potential to the transparent conductor in a stable manner for long periods of time.

Abstract: An electrochromic variable reflectance mirror for a vehicle includes a reflector/electrode on the third surface of the mirror. This reflector/electrode forms an integral electrode in contact with the electrochromic media, and may be a single layer of a highly reflective material or may comprise a series of coatings. When a series of coatings is used for the reflector/electrode, there should be a base coating which bonds to the glass surface and resists any adverse interaction, e.g.

Abstract: Single-compartment, self-erasing, solution-phase electrochromic devices, solutions of electrochromic compounds for use as media of variable transmittance in such devices, and electrochromic compounds for such solutions are provided. The devices of the invention are surprisingly stable to cycling between light and dark states, have continuously variable transmittance to light as a function of electrical potential applied across the solution in a device, and have transmittance that can be varied over more than a factor of 10, from clear to dark or from dark to clear, in several seconds. Thus, the devices are especially suitable as variable transmittance components of variable transmission light filters, including windows, and variable reflectance mirrors, including anti-glare rearview mirrors in automobiles.

Abstract: Electrochromic devices and processes for preparing the same are provided which do not require a separate process step of ion intercalation by employing an electrochromically-inert reducing or oxidizing additive in the electrochemically active material or the electrolyte of the electrochromic devices.

Abstract: An electrochromic glazing assembly is disclosed with reduced near-infrared radiation transmission and reduced ultraviolet (UV) radiation transmission. The assembly may include at least a pair of glass or other elements confining an electrochromic medium therebetween. Ultraviolet radiation reducing means are incorporated for reducing ultraviolet radiation transmission through the assembly. A polymeric antilacerative layer is disposed on one surface of one of the glass elements for preventing lacerative injuries. Reduced near-infrared radiation transmission means may also be included.

Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the invention relates to electrochemichromic solutions, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. That is, the responsiveness observed in terms of solution coloring is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art. Preparation of these solutions involve the novel process of pre-treating at least one of the electrochemichromic compounds with a redox agent prior to placing it in contact with the other electrochemichromic compound. Moreover, the present invention relates to methods of preparing such novel solutions and processes for using these solutions to provide devices that exhibit and benefit from the aforementioned superior characteristics.

Abstract: An active anti-glare filter system in the form of a monoblock or solid unit which can be easily inserted into areas of protective helmets and goggles as a replacement or alternate filter includes an active and a passive optical filter elements, electronics which control the active optical filter element and a current supply, preferably in the form of a solar cell, which powers the electronics. Transparent cover plates surround the foregoing elements and are joined together and protected by a jointing mass.

Abstract: Printed electrochemical display cells are arranged in layer form with two electrode layers and an electrolyte layer occupying distinct areas of a substrate. An electrolyte layer overlaps most of one electrode layer but contacts a smaller portion of the other electrode layer, which is made of a thin film. When activated, an electrochemical reaction progressively increases the area occupied by the electrolyte layer and progressively decreases the area occupied by the thin-film electrode layer. The thin-film electrode layer recedes at a boundary in common with the electrolyte layer and provides an irreversible indication of change at a rate governed by the electrochemical reaction.

Abstract: An electrochemical mirror includes a transparent first electrode and a second electrode distributed in localized areas. An electrolytic solution is disposed between the first and second electrodes and contains ions of a metal which can electrodeposit on the first and second electrodes. A negative electrical potential applied to the first electrode causes deposited metal to be dissolved from the second electrode into the electrolytic solution and to be electrodeposited from the solution onto the first electrode, thereby affecting the propagation of electromagnetic radiation through the mirror. A surface modification layer applied to the first electrode ensures that the electrodeposit is substantially uniform, resulting in a mirror layer which increases the reflectivity of the mirror.

Abstract: An electrochemical device includes a transparent first electrode and a second electrode distributed in localized areas. An electrolytic solution, disposed between and in electrical contact with the first and second electrodes, contains ions of a metal which can electrodeposit on the first and second electrodes. Atoms of this metal are deposited on the first or the second electrode. A negative electrical potential applied to the first electrode causes deposited metal to be dissolved from the second electrode into the electrolytic solution and to be electrodeposited from the solution onto the first electrode, thereby affecting the propagation of electromagnetic radiation through the device. Conversely, a positive electrical potential applied to the first electrode causes deposited metal to be dissolved from the first electrode and electrodeposited from the solution onto the second electrode, thereby increasing the transmissivity of the device.

Abstract: An optical device in which a solution prepared by dissolving a silver halide in a solvent and adding an alkali metal halide such as LiBr as a support salt is disposed between working electrodes and counter electrode, and which is adapted such that silver is deposited or dissolved by driving control for the electrodes. The optical device can be driven at a low power consumption, can control the light transmittance or reflectance in a visible light region, has satisfactory spectral characteristics upon light shielding and can prevent an overvoltage to the electrode, thereby enabling to increase the working life, and an electrolytic solution used therefor is provided.

Abstract: An electrochromic glazing assembly is disclosed with reduced near-infrared radiation transmission and reduced ultraviolet (UV) radiation transmission. The assembly may include a pair of glass or other elements confining an electrochromic medium therebetween. Near-infrared reflective means are preferably included as at least one of a semitransparent, elemental thin metal film and a low emittance coating. Preferably, the assembly reflects at least about 30% of the solar energy for Air Mass 2 in the spectral region from about 800 nanometers to about 2500 nanometers.

Abstract: A method and apparatus are disclosed for filling a cell cavity positioned between a first substrate and a second substrate with a cell filling liquid. The method entails forming at least one evacuation cavity encompassing at least a portion of an outer surface of each of the first and second substrates of a cell containing a cell cavity and isolating the cell cavity from the evacuation cavity; reducing a pressure in each of the evacuation cavity and the cell cavity; and dispensing the cell filling fluid into the cell cavity.

Abstract: An improved optical cell (light valve) of the type which includes a liquid suspension of particles orientable by an electrical field to vary the amount of luminous transmission is described. The cell comprises two adjacent plates held apart by a spacer to define a space occupied by the suspension. The cell further includes a first opening which passes through the spacer into the space to permit introduction of the suspension into the cell and a second opening which passes through the spacer at or near the furthest possible distance permitted by the configuration of the cell from the first opening, whereby the introduction of the suspension displaces through the second opening any fluid such as air which is initially present in the space.

Abstract: The present invention provides variable reflectance automobile mirrors wherein the component of variable transmittance is an electrochromic device wherein the medium of variable transmittance comprises an electrochromic compound in a gel or a thickened solution.

Abstract: A method of forming an optically transparent seal involves the steps of providing an uncured resinous material, adding a spacing media to the resinous material and curing the resinous material. The spacing media can have an index of refraction similar to that of the resinous or an antireflective coating provided thereon. A filler material can also be added to the resinous material.

Abstract: Electrochromic devices and processes for preparing the same are provided which do not require a separate process step of ion intercalation by employing an electrochromically-inert reducing or oxidizing additive in the electrochemically active material or the electrolyte of the electrochromic devices.

Abstract: A control system for an optical cell (light valve) is provided which comprises a first (oscillator) circuit supplied by a low voltage power source and including a primary winding of an induction coil and a secondary (resonant) circuit which includes the optical cell and a secondary winding of the induction coil. The secondary circuit includes the inductance of the secondary winding and the optical cell, and the induction coil provides a weak coupling between the primary and secondary windings. The resonant circuit provides a large over-voltage coefficient and great stability and the configuration made possible by the invention facilitates a significant reduction in the bulk of the control system.

Abstract: An optical apparatus includes a first electrode that can be kept in a transparent state in a visible light region, and a second electrode electrically separated from the first electrode. A space is provided between the first and second electrodes. A certain function is used to provide a driving potential to the first and second electrodes. An electrolyte is poured into the space between the electrodes. The electrolyte is composed of a solution prepared by dissolving a silver salt in at least one type of solvent selected from a group consisting of dimethylformamide, diethylformamide, N, N-dimethylacetamide, N-methylpropionamide, N-methylpyrrolidone, 2-ethoxyethanol, and 2-methoxyethanol. By use of this electrolyte, silver is precipitated and dissolved under driving control over the first and second electrodes. As a result, color-developing and color-fading are effected by precipitation and dissolution of silver, respectively.

Abstract: The present invention provides variable reflectance automobile mirrors wherein the component of variable transmittance is a single-compartment, self-erasing, solution-phase electrochromic device.

Abstract: A label for electrochemical cell employs an electrochromic material so that when the material is connected to power provided by the electrochemical cell, the material will undergo a visible change as a result of a chemical reaction.

Abstract: The present invention provides electrochromic layers, which comprise polymeric matrices with electrochromic solutions interspersed therein. Varying an electrical potential difference across a layer of the invention results in reversible variation in the transmittance of light across the layer because of electrochemical processes in the electrochromic solution of the layer. The invention further provides electrochromic devices, in which the electrochromic layers of the invention provide reversibly variable transmittance to light, and various apparatus in which the devices of the invention provide light-filtering or light-color modulation. Such apparatus include windows, including those for use inside and on the outside walls of buildings and in sunroofs for automobiles, and variable reflectance mirrors, especially rearview mirrors for automobiles.

Abstract: An electrochromic device comprising three elements. The first element is a first electrode. The second element is a second electrode. The second electrode is spaced apart from the first electrode so that there is a space between the first electrode and the second electrode. The third element is a dispersion positioned in the space. The dispersion is in electrical contact with the first electrode and with the second electrode. The dispersion comprises a transition metal surface substituted polyoxometalate and a solvent. The first and second electrodes can be a transparent electronically conducting layer of indium-tin oxide coated upon a panel of glass. The transition metal surface substituted polyoxometalate can be Li.sub.x MnPW.sub.11 O.sub.40. The dispersion is resistant to photodegradation such as discoloring in sunlight.

Abstract: An optical apparatus of this invention comprises a first spatial light modulator, an array of imaging elements, and a plurality of light sources, and an image surface. Each of the imaging elements of the array is arranged to form an image of the plurality of light sources via the spatial light modulator at a respective position on the image surface.

Abstract: An EC mirror having an end surface of layers consisting of an ECD, an output electrode, and a clip electrode, prevents attacking by water submerging through the end surface, improves sealing ability with the mirror holder, prevents the mirror from chattering and a strange noise due to a vibration of the mirror, improves an anti-impact ability of the ECD end surface. An insulating member is disposed to cover ECD periphery portions and connecting portions of an output electrode, the clip electrode and a harness cord. A water proof member is disposed on an outer periphery of the insulating member.

Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the invention relates to electrochemichromic solutions, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. That is, the responsiveness observed in terms of solution coloring is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art. Preparation of these solutions involve the novel process of pre-treating at least one of the electrochemichromic compounds with a redox agent prior to placing it in contact with the other electrochemichromic compound. Moreover, the present invention relates to methods of preparing such novel solutions and processes for using these solutions to provide devices that exhibit and benefit from the aforementioned superior characteristics.

Abstract: The invention relates to a variable transparency electro-optical device comprising: at least one lens formed by an electro-optical cell (4) comprising a first plate (6) and a second plate (8) each provided with a control electrode (14, 16) and a sealing frame (10) interposed between the two plates to form a sealed volume enclosing an electro-optical material (12), voltage generating means (18) connected to said electrodes to apply a variable voltage to said material in order to automatically or manually vary the transmission of the cell (4) as a function of the ambient light. According to the invention the cell (4) comprises at least one element (6) charged with a photochromic substance having an absorption that varies in reversible manner as a function of the intensity of the light impinging on said cell. The invention has particular applications in devices for protecting the eyes.

Abstract: An electrochromic device comprises two electrodes separated by an electrolytic medium and means to permit the application of a potential between the electrodes, so as to create a circuit for charge transfer, and an electrochromic material in contact with the electrolyte and an electrode so that a change in spectral properties of the material is detectable from the exterior of the device, the electrochromic material comprising an aluminium and/or silicon containing monophthalocyanine or monotetrabenzoazaporphyrin complex.

Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the present invention relates to electrochemichromic compounds and processes for preparing the same. The present invention also relates to electrochemichromic solutions of such compounds, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. And, these solutions, when contained within electrochemichromic devices, demonstrate ultraviolet stability, thermal stability and cycle stability. The responsiveness observed in terms of solution coloring with respect to the solutions, and devices containing the same, of the present invention is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art.

Abstract: The present invention relates to a method of producing a plurality sets of prints from a plural-page original in an image forming apparatus having an endless transfer member onto which images are transferred from an image retaining member. The endless transfer member is operable to support a predetermined number (X) of images during one cyclic movement thereof. In this method, a first printing operation is executed in which the predetermined number (X) of images of a first page of the original are formed on the endless transfer member during one cyclic movement thereof when a desired number (Y) of sets of prints exceeds said predetermined number (X). Second, the first printing operation is repeated until a remaining number (M) of image(s) of the first page becomes less than said predetermined number (X).

Abstract: Prismatic variable reflectance mirrors are provided. In the mirrors of the invention, transmittance of reflected light is varied by thermochromic, electrochromic, photochromic or electro-optic means and the reduction in transmittance, which is required to eliminate perceptible reflection of an object to the eyes of an observer, is reduced by disposing the plane of the highly reflective surface of the mirror at an angle with respect to the plane of the surface through which light from the object enters the mirror.

Abstract: An automatic electrochromic rearview mirror for automotive vehicles, the mirror being particularly adapted for use as an outside rearview mirror and incorporating improved means enabling the mirror to survive, over a relatively long useful life, extreme environmental conditions, such as extreme heat and/or cold, ultraviolet light exposure, alternate wetting, freezing and thawing conditions, exposure to salt spray and other corrosive conditions as well as high pressure sprays such as may be encountered in car wash facilities. Mirrors embodying the present invention may be manufactured and assembled with a minimum of breakage of glass components and/or rupture of sealing components during the manufacturing and assembly operations, and also incorporate improved means for increasing the efficiency of heating elements which may be utilized for defrosting purposes.

Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the invention relates to electrochemichromic solutions, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. That is, the responsiveness observed in terms of solution coloring is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art. Preparation of these solutions involve the novel process of pre-treating at least one of the electrochemichromic compounds with a redox agent prior to placing it in contact with the other electrochemichromic compound. Moreover, the present invention relates to methods of preparing such novel solutions and processes for using these solutions to provide devices that exhibit and benefit from the aforementioned superior characteristics.

Abstract: A selectively variable window tinting system for limiting a passage of both visible light and radiative heat through an automobile window. Embodiments of the system include window glass assemblies which utilize photochromatic glass, electrochromatic glass, and a pair of spaced glass panes fillable with a tinted fluid. The latter embodiment also utilizes a plurality of differently tinted fluids which may be selectively injected between the glass panes to provide various amounts of tinting therein.

Abstract: The invention relates to an electrochromic glazing successively comprising a glass sheet, a first electrode constituted by a transparent electroconductive layer, whose square resistance is below 5 Ohms, a layer of a cathodic electrochromic material, an electrolyte, a layer of an anodic electrochromic material and a second transparent electroconductive electrode, barrier layers being inserted between the said electrodes and the said electrochromic material layers, the square resistance of the assembly formed by an electrode and its barrier layer being below 5 Ohms.

Abstract: The specification discloses electrochemichromic solutions and devices based on the use of solvents comprising at least about 25% 3-hydroxypropionitrile, 3,3'-oxydipropionitrile, 2-acetylbutyrolactone, 2-methylglutaronitrile, 3-methylsulfolane and mixtures thereof. The specification also discloses vacuum backfilling techniques for filling electrochemichromic cells and enhanced UV stability through solvent self-screening.

Abstract: The present invention provides solution-phase electrochromic devices, including such devices that are single-compartment and self-erasing, in which the media of variable transmittance are solutions comprising, as cathodic electrochromic compounds, certain 4,4'-bipyridinium salts, such as salts of 1,1'-dibenzyl-2,2',6,6'-tetraalkyl-4,4'-bipyridinium cations. Electrochromic devices of the invention are components of variable transmittance in display devices, windows and other types of light filters, and variable reflectance mirrors, such as those that can be used as dimmable rearview mirrors in motor vehicles.

Abstract: The present invention provides variable reflectance mirrors wherein the component of variable transmittance is a single-compartment, self-erasing, solution-phase electrochromic device.

Abstract: The invention provides improved solution-phase electrochromic devices, wherein the solution of reversibly variable transmittance is tinted with a tint-providing compound, and solutions of reversibly variable transmittance for use in the improved devices of the invention. An electrochromic device of the invention can be used, for example, as the component of reversibly variable transmittance in a variable-reflectance motor vehicle mirror. Among such mirrors provided by the invention are blue-tinted mirrors.

Abstract: The present invention relates to electrochromic solutions and devices manufactured therefrom. More precisely, the invention relates to electrochemichromic solutions, and those devices manufactured with the same, that demonstrate superior responsiveness to those solutions known heretofore when an applied potential is introduced thereto. That is, the responsiveness observed in terms of solution coloring is of a greater rapidity, intensity and uniformity than those electrochemichromic solutions of the prior art. Preparation of these solutions involve the novel process of pre-treating at least one of the electrochemichromic compounds with a redox agent prior to placing it in contact with the other electrochemichromic compound. Moreover, the present invention relates to methods of preparing such novel solutions and processes for using these solutions to provide devices that exhibit and benefit from the aforementioned superior characteristics.

Abstract: The method for sealing electrochromic devices disclosed in the present invention allows the cell cavity of a device to be established and filled with media at substantially the same time, without requiring spacer beads, fill holes and the like to complete the assembly. Moreover, the method of the present invention allows the cell cavity to be filled without accurately pre-measuring the media. Further, the sealing means used herein is constructed of a thermoplastic material that is inert to, and compatible with, the media commonly used and which forms an integral seal, even while in intimate contact with the media in the cell cavity.

Abstract: Materials possessing ionic conductivity which are suitable for use as electrolytes, notably in electrochromic systems, comprising an ionomer obtained by the neutralization of a Bronsted polyacid by an MOH alkali metal hydroxide, the neutralization rate .alpha. being such that 0<.alpha.<.alpha..sub.m, where .alpha..sub.m is the neutralization rate beyond which a phase separation takes place. The ionomer comprises a polymeric chain having a plurality of anionic groups affixed thereto and a plurality of alkaline cations associated therewith. The material further comprises a polar solvent, capable of solubilizing or plasticizing the ionomer and of assuring a partial ionic diassociation as well as transporting the M.sup.+ ions. Optionally, this material may comprise, in addition to the above, a Bronsted polybase soluble in the polar solvent which does not form a solid precipitate with the ionomer and an MX inorganic salt wherein M.sup.

Abstract: The performance and operating characteristics of electrochromic devices may be improved by the incorporation of a moisture control layer comprised of either water reservoir material or water scavenger material in conjunction with a moisture permeable intermediate barrier layer within the device. The water reservoir material provides a source of water for those electrochromic stacks which require water for proper operation. For stacks which require protection from moisture, water scavenger material may be utilized. A moisture permeable intermediate barrier layer separates the moisture control layer from the electrochromic stack. The invention is also directed towards methods of incorporating such layers into electrochromic devices during their manufacture.