Aluminum Or Tantalum Patents (Class 361/529)
  • Patent number: 6853540
    Abstract: A solid electrolytic capacitor including a valve metal positive electrode, an anodized layer formed on a surface of the positive electrode, a conductive polymer-containing negative electrode conductive layer, and a coupling agent layer and a surface active agent layer placed between the anodized layer and the negative electrode conductive layer.
    Type: Grant
    Filed: April 2, 2004
    Date of Patent: February 8, 2005
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuo Kudoh, Kenji Akami, Hiroki Kusayanagi, Yasue Matsuya
  • Patent number: 6850406
    Abstract: An Nb solid electrolytic capacitor is disclosed which comprises: an anode body made from an Nb-based material, the anode body having a nitrogen content of about 7,500 ppm to about 47,000 ppm; a dielectric layer formed over the surface of the anode body; a solid electrolyte layer formed on the dielectric layer; and a cathode body formed on the surface of the solid electrolyte layer. The Nb solid electrolytic capacitor shows small bias dependence. A method for preparing the same is also disclosed which comprises steps of: forming an anode body from an Nb-based material, the anode body having a nitrogen content of about 7,500 ppm to about 47,000 ppm; forming a dielectric layer over the surface of the anode body; forming a solid electrolyte layer on the dielectric layer; and forming a cathode body on the electrolyte layer.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: February 1, 2005
    Assignee: NEC Tokin Corporation
    Inventors: Tadamasa Asami, Katsuhiro Yoshida, Kunihiko Shimizu, Takashi Kono
  • Patent number: 6839224
    Abstract: Implantable defibrillators are implanted into the chests of patients prone to suffering ventricular fibrillation, a potentially fatal heart condition. A critical component in these devices is an aluminum electrolytic capacitors, which stores and delivers one or more life-saving bursts of electric charge to a fibrillating heart. These capacitors make up about one third the total size of the defibrillators. Unfortunately, conventional manufacturers of these capacitors have paid little or no attention to reducing the size of these capacitors through improved capacitor packaging. Accordingly, the inventors contravened several conventional manufacturing principles and practices to devise unique space-saving packaging that allows dramatic size reduction.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: January 4, 2005
    Assignee: Cardiac Pacemakers, Inc.
    Inventors: Michael J. O'Phelan, James M. Poplett, Robert R. Tong, Alexander Gordon Barr
  • Patent number: 6807049
    Abstract: A solid electrolytic capacitor includes a valve acting metal having microfine pores, a dielectric film formed on a surface of the valve acting metal, and a solid electrolyte layer provided on the dielectric film, in which at least a portion of the solid electrolyte layer is of a lamellar structure. In particular, a solid electrolytic capacitor includes an electrically conducting polymer having a specified condensed ring structure containing (1) a solid electrolyte layer containing a sulfoquinone anion having a sulfo anion group and a quinone structure and other anion, and (2) a solid electrolyte layer containing an anthracenesulfonate ion and other anion.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: October 19, 2004
    Assignee: Showa Denko K.K.
    Inventors: Hiroshi Konuma, Koro Shirane, Ryuji Monden, Atsushi Sakai, Yuji Furuta, Katsuhiko Yamazaki, Toru Sawaguchi, Hideki Ohata, Yoshiaki Ikenoue
  • Patent number: 6802884
    Abstract: The allows: Ta—Si, Nb—Si, TaN—Si, NbN—Si and variants are used as enhanced powder anode substrates for electrolytic capacitor anodes (sintered powder masses) with dielectric oxide formation at walls of the internal pores.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: October 12, 2004
    Assignee: H.C. Starck, Inc.
    Inventors: Leah Simkins, Anastasia Conlon
  • Patent number: 6801423
    Abstract: A capacitor element includes a porous member made of valve metal powder, an anode wire projecting from the porous member, and a cathode layer formed on the porous member. The cathode layer is formed to have a thickness of no less than 35 &mgr;m, and more preferably, no less than 40 &mgr;m.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: October 5, 2004
    Assignee: Rohm Co., Ltd.
    Inventor: Takahiro Nakamura
  • Patent number: 6793690
    Abstract: Method of manufacturing a conductive composition precursor prepared by dispersing or dissolving at least one additive having high dielectric layer repairing ability in conductive polymer solution, the conductive composition made by removing a medium or solvent from this composition precursor. The additive is at least one of “phosphoric acid or phosphoric acid ester compounds”, “phenol or phenol derivatives”, “nitrobenzene derivatives”, “alkyl or naphthalene sulfonic acid anion”, “fluorocarbon surface active agent” and “fluorocarbon surface active agent and binder.
    Type: Grant
    Filed: January 7, 2003
    Date of Patent: September 21, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuo Kudoh, Kenji Akami, Hiroki Kusayanagi, Yasue Matsuya
  • Patent number: 6788524
    Abstract: A drop-fill assembly and method for uniformly distributing electrode active particles onto a current collector is described. The drop-fill assembly comprises a conduit containing two or more spaced apart sifting screens. A funnel is located upstream of the sifting screens to distribute an electrode active powder into the center of the conduit with a downward velocity. The mesh of any one sifting screen is out of direct alignment with respect to the next or previous screen. The electrode active powder is poured into the funnel and distributed across the conduit's cross-section as it bounces off and passes through the misaligned sifting screens. The powder exits at the bottom of the conduit lying in a thin, uniform layer on a current collector, taking on the shape of the desired electrode due to the boundary of the conduit and pressing fixtures located above and beneath the current collector. The powder layer is then pressed on to the current collector to produce an electrode.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: September 7, 2004
    Assignee: Wilson Greatbatch Technologies, Inc.
    Inventors: Tina Urso, Dominick Frustaci, Michael Guidi
  • Patent number: 6788525
    Abstract: A tantalum or niobium powder that can provide a porous sintered tantalum or niobium body having a large surface area and involving a lower risk of failure to form a solid electrolyte film, where a material serving as a tantalum or niobium ion source is dissolved in a molten salt, upon which a reducing agent is allowed to act, resulting in reduction to the metal state of the tantalum or niobium ions dissolved in the molten salt, to thereby obtain a tantalum or niobium powder including aggregated columnar particles. A tantalum or niobium powder contains radially aggregated particles formed by a plurality of columnar particles aggregated radially.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: September 7, 2004
    Assignee: Cabot Supermetals K.K.
    Inventors: Ryosuke O. Suzuki, Rieko Ishii, Tadao Nishiyama, Hitoshi Iijima
  • Patent number: 6785123
    Abstract: A porous aluminum anode is used in a capacitor. The porous anode is constructed by a solid freeform fabrication (SFF) process and has a plurality of pores. Each of the plurality of pores has a pore size. An electrolyte is infiltrated in the plurality of pores. An oxide layer is formed on the aluminum surface to provide a dielectric for the capacitor.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: August 31, 2004
    Assignee: Intel Corporation
    Inventor: Milan Keser
  • Patent number: 6775125
    Abstract: A solid electrolytic capacitor having a high capacitance and excellent high frequency response including a valve metal sheet which is made porous, a dielectric layer formed on the porous portion, a solid electrolyte layer formed on the dielectric layer, a collector layer and an electrode exposure area formed on the solid electrolyte layer, and an insulating section electrically insulating the electrode exposure area from the collector layer, in which the electrode exposure area and the collector layer are formed on the same surface of the valve metal sheet.
    Type: Grant
    Filed: January 13, 2003
    Date of Patent: August 10, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Suzushi Kimura, Katsumasa Miki, Yuji Mido, Tatsuo Fujii, Hideki Masumi
  • Patent number: 6768632
    Abstract: The present invention aims to address a problem of contact failure likely to occur in the joint between an internal lead and an external terminal and to provide a reliable aluminum electrolytic capacitor. To this end, an aluminum electrolytic capacitor of the present invention is structured so that a through-hole provided through an internal lead has a diameter smaller than the outer diameter of an aluminum rivet and the peripheral edge of this through-hole is drawn to provide a cylindrical portion integral with the through-hole.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: July 27, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Toshiyuki Hata, Yoshinori Oe, Nario Niibo, Makoto Uemura, Tsuyoshi Yoshino
  • Patent number: 6762927
    Abstract: An anode is described that has a niobium-based barrier layer, which includes a niobium metal core, a conducting niobium suboxide layer and a dielectric barrier layer of niobium pentoxide.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: July 13, 2004
    Assignee: H.C. Starck GmbH & Co. KG
    Inventors: Christoph Schnitter, Karlheinz Reichert
  • Patent number: 6744621
    Abstract: A solid electrolytic capacitor comprising a foil coated with a dielectric oxide film, wherein the coated foil has slit or cut edges, and the slit or cut edges have been reformed by forming the foil in an aqueous citrate electrolyte, then depolarizing the foil, and then forming the foil in an aqueous phosphate electrolyte wherein the foil is not anodized in an aqueous acid electrolyte prior to forming the foil in an aqueous citrate electrolyte.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: June 1, 2004
    Assignee: Kemet Electronics Corporation
    Inventors: Philip Michael Lessner, Albert Kennedy Harrington, Brian John Melody, John Tony Kinard
  • Patent number: 6741451
    Abstract: A solid electrolytic capacitor includes a capacitor element and a resin package enclosing the capacitor element. Two anode leads, partially enclosed by the package, are connected to the opposite ends of the anode bar that are allowed to protrude in the opposite directions from an anode chip of the capacitor element. The capacitor element is provided with a cathode layer connected to an external cathode electrode arranged between the paired anode leads. With this symmetrical structure of two anode leads and one cathode electrode, the solid electrolytic capacitor can be mounted onto a printed circuit board without worrying about the polarity of the capacitor. Further, the proximity of the cathode electrode and the respective anode leads serves to reduce the self-induction in a high-frequency range.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: May 25, 2004
    Assignee: Rohm Co., Ltd.
    Inventor: Makoto Aoyama
  • Patent number: 6716389
    Abstract: A process for producing sintered pellets made from blends of refractory metal and refractory metal nitride powders were found to have a higher fraction of intra-agglomerate pores than those made from the refractory metal or refractory metal nitride alone resulting in improved capacitor grade powders, anodes and finished capacitors therefrom. The pellet porosity and total intrusion volume maximizes when the mixture is in the 50-75 W/W % refractory metal nitride range. The total pellet pore surface area was found to be relatively independent of refractory metal nitride concentration above 50%. A substrate consisting of a 50/50 or 25/75 W/W % refractory metal/refractory metal nitride powder mixture should produce solid capacitors with higher capacitance recovery and lower ESR.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: April 6, 2004
    Assignee: H. C. Starck Inc
    Inventors: Terrance B. Tripp, Barbara L. Cox
  • Patent number: 6696138
    Abstract: A solid electrolytic capacitor comprises a porous valve acting metal having formed thereon a dielectric film and a solid electrolyte formed on the dielectric film. The solid electrolyte occupies from 10 to 95% of the space within a pore of the porous metal.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: February 24, 2004
    Assignee: Showa Denko K.K.
    Inventors: Atsushi Sakai, Ryuji Monden, Toru Sawaguchi, Katsuhiko Yamazaki, Yuji Furuta, Hideki Ohata
  • Patent number: 6689187
    Abstract: The tantalum powder for capacitors of the present invention has a specific surface area SB as determined by the BET method of 1.3 m2/g or more, and an SB/SF ratio between the specific surface area SB as determined by the BET method and the specific surface area SF determined by the FSS method of 4 to 10. This tantalum powder not only has a large specific surface area SB, but also has suitable cohesive strength and uniform porosity. Consequently, a solid state electrolytic capacitor having high capacitance and low ESR can be obtained by providing with a capacitor anode formed from a sintered body of this tantalum powder. In addition, whether or not this tantalum powder is suitable for the production of a tantalum capacitor having high capacitance and low ESR can be determined easily and reliably by evaluating the tantalum powder using the specific surface area SB as determined by the BET method and the SB/SF ratio between SB and the specific surface area SF determined by the FSS method.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: February 10, 2004
    Assignee: Cabot Supermetals K.K.
    Inventor: Yukio Oda
  • Patent number: 6674635
    Abstract: A solid electrolytic capacitor having an anode that contains a valve-action metal (e.g., tantalum, niobium, and the like) and a dielectric film overlying the anode is provided. The capacitor also include a protective coating overlying the dielectric film, wherein the protective coating contains a relatively insulative, resinous material. For example, in one embodiment, the resinous material can be a drying oil, such as olive oil, linseed oil, tung oil, castor oil, soybean oil, shellac, and derivatives thereof. The capacitor also includes a conductive polymer coating overlying the protective coating. As a result of the present invention, it has been discovered that a capacitor can be formed that can have a relatively low leakage current, dissipation factor, and equivalents series resistance.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: January 6, 2004
    Assignee: AVX Corporation
    Inventors: James A. Fife, Zebbie L. Sebald
  • Patent number: 6660057
    Abstract: A powder composition for a capacitor comprising a tantalum or niobium and a compound having a silicon-oxygen bond, at least a part of which may be nitrided and which has an average particle size of from 0.1 to 5 &mgr;m; a sintered body using the composition; and a capacitor constituted by the sintered body as one part electrode, and another part electrode. A capacitor favored with high reliability, lower dissipation level of power and smaller deterioration of capacitance than conventional tantalum capacitors using tantalum can be produced by using a sintered body of the powder composition for a capacitor.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: December 9, 2003
    Assignee: Showa Denko K.K.
    Inventors: Kazumi Naito, Kazuhiro Omori, Nobuyuki Nagato
  • Publication number: 20030206390
    Abstract: A tantalum or niobium powder that can provide a porous sintered tantalum or niobium body having a large surface area and involving a lower risk of failure to form a solid electrolyte film, where a material serving as a tantalum or niobium ion source is dissolved in a molten salt, upon which a reducing agent is allowed to act, resulting in reduction to the metal state of the tantalum or niobium ions dissolved in the molten salt, to thereby obtain a tantalum or niobium powder comprising aggregated columnar particles. A tantalum or niobium powder contains radially aggregated particles formed by a plurality of columnar particles aggregated radially.
    Type: Application
    Filed: May 7, 2003
    Publication date: November 6, 2003
    Inventors: Ryosuke O. Suzuki, Rieko Ishii, Tadao Nishiyama, Hitoshi Iijima
  • Publication number: 20030169561
    Abstract: A solid electrolytic capacitor has an anode terminal and a cathode terminal for external electrical connection that are formed on one surface of a plate-like or foil-like anode member, and a cathode conductor layer formed such that it covers the area of the one surface of the anode member except for the portion where the anode terminal is secured. A first metal plate or metal foil functioning as the cathode terminal is closely joined to the one surface of the cathode conductor layer so as to cover the one surface of the cathode conductor layer. A second metal plate or metal foil is closely joined to the other surface of the cathode conductor layer so as to cover the other main surface of the cathode conductor layer. The first metal plate or metal foil and the second metal plate or metal foil function to intercept the ventilation between the anode member and the outside.
    Type: Application
    Filed: February 20, 2003
    Publication date: September 11, 2003
    Applicant: NEC Tokin Corporation
    Inventors: Kazumasa Ohya, Satoshi Arai, Takayuki Inoi, Yoshihiko Saiki
  • Patent number: 6611422
    Abstract: Sub pits are suppressed from branching in a surface layer of an aluminum foil, and an electrode foil for an aluminum electrolytic capacitor with a large electrostatic capacitance and a method of manufacturing the same are provided. A large number of main pits are formed by etching on both surfaces of the aluminum foil to extend from the surfaces in a thickness direction of the foil, sub pits are formed to branch away from the main pits for a range from a vicinity of a surface layer portion of each main pits excluding the surface layer portion, to inner ends of the main pits. Since the sub pits are not formed in the surface layer of the aluminum foil, the sub pits can be increased in density effectively to the electrostatic capacitance, allowing the electrode foil for the aluminum electrolytic capacitor to have high mechanical strength and high electrostatic capacitance.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: August 26, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Nobuhiko Yamazaki, Kazuaki Nakanishi, Shinichi Yamaguchi, Hisao Ohishi, Ryoichi Shimatani, Akihiro Yamaguchi, Kazuko Hasegawa
  • Patent number: 6563695
    Abstract: A tantalum or niobium powder that can provide a porous sintered tantalum or niobium body having a large surface area and involving a lower risk of failure to form a solid electrolyte film, where a material serving as a tantalum or niobium ion source is dissolved in a molten salt, upon which a reducing agent is allowed to act, resulting in reduction to the metal state of the tantalum or niobium ions dissolved in the molten salt, to thereby obtain a tantalum or niobium powder comprising aggregated columnar particles. A tantalum or niobium powder contains radially aggregated particles formed by a plurality of columnar particles aggregated radially.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: May 13, 2003
    Assignee: Cabot Supermetals K.K.
    Inventors: Ryosuke O. Suzuki, Rieko Ishii, Tadao Nishiyama, Hitoshi Iijima
  • Patent number: 6560090
    Abstract: A solid electrolytic capacitor having excellent solder wettability and heat resisting adhesion and a method of manufacturing same are obtained by a simple plating configuration. The capacitor includes a capacitor element, positive electrode terminal and negative electrode terminal. The positive electrode terminal and the negative electrode terminal include a metallic member containing (i) at least one selected from the group consisting of nickel, nickel alloy, copper and copper alloy, (ii) a first plated layer of tin or tin alloy, directly disposed without undercoat on the metallic member, and (iii) an intermetallic compound layer formed between the metallic member and the first plated layer. The intermetallic compound layer contains tin-nickel or tin-copper formed through heat reflow treatment of the metallic member disposed on the first plated layer.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: May 6, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoshitsugu Uenishi, Tsuneshi Nakamura, Minoru Omori, Masashi Kadoya, Yoshihiro Higuchi, Tsuyoshi Yoshino
  • Patent number: 6529366
    Abstract: A sintered body (10) made of valve action metal powders such as Ta powders, in which an anode lead (11) is embedded in one of wall faces is formed. A dielectric layer (oxide layer) (14) is formed around the metal powders. A manganese dioxide layer (15) is formed around the sintered body in which the dielectric layer is provided on the metal powders. A graphite layer is formed on the manganese dioxide layer. The graphite layer is made by an aqueous graphite layer (16) on the manganese dioxide layer side and a resin graphite layer (17) formed on the aqueous graphite layer. A metal layer (18) is formed on the graphite layer. In such a manner, a capacitor (1) element is formed. Preferably, the graphite layer is burned at a temperature ranging from 230 to 300° C. As a result, an increase in impedance caused by a thermal stress between cathode layers is prevented. Thus, a solid electrolytic capacitor having a small impedance between the anode and the cathode is obtained.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: March 4, 2003
    Assignee: Rohm Co., Ltd.
    Inventor: Takahiro Nakamura
  • Patent number: 6522527
    Abstract: The anode member for a solid electrolytic capacitor according to the present invention comprises an anode body made of a valve metal foil having a purity of not less than 99 wt %, and an anode layer formed on the anode body and made of a sintered body of a valve metal powder. By limiting the amount of impurity contained in the valve metal foil to an amount of not more than 1 wt %, impurities in a dielectric oxide film formed by anodic oxidation, namely defects in the dielectric oxide film can be suppressed, so that the resultant solid electrolytic capacitor can have its leakage current lowered with its ESR (equivalent series resistance) being kept low, and that the electrolytic capacitor can be made to have a smaller size and a higher capacitance. The present invention also provides an electrolytic capacitor having a low leakage current, a low ESR, a small size and a high capacitance by using the above novel anode member as well as a method of making the same.
    Type: Grant
    Filed: June 4, 2002
    Date of Patent: February 18, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Kojima, Kiyoshi Hirota, Junichi Kurita, Yuji Mido, Ayumi Kochi
  • Patent number: 6515848
    Abstract: The present invention relates to solid electrolytic capacitors with low ESRs in the high frequency range and methods for manufacturing the same. The solid electrolytic capacitor induce a porous anode body made of a valve action metal and on the surface of which body a dielectric oxide layer is formed; and a chemically polymerized layer made of conductive polymers which are formed by chemical oxide polymerization on the dielectric oxide layer which are located on the surfaces inside pores of the porous anode body; and an electrolytic polymerized layer made of conductive polymers which are formed by electrolytic polymerization on the dielectric oxide layer which are located on the external surface of the porous anode body; wherein the dielectric oxide layer and the electrolytic polymerized layer are in contact with each other and the chemically polymerized layer and the electrolytic polymerized layer are electrically connected with each other near the contacting parts.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: February 4, 2003
    Assignee: NEC Corporation
    Inventors: Katsuhiro Yoshida, Kunihiko Simizu, Toshihiko Nishiyama
  • Patent number: 6512668
    Abstract: A tantalum chip capacitor with a cut-grooved anode lead frame is disclosed. The cut-grooved lead frame is designed to allow the tantalum element set in the small-sized epoxy mold package of the capacitor to have a desired size, thus restricting an increase in impedance of the tantalum chip capacitor regardless of a reduction in the size of the package according to the recent trend of smallness of the tantalum chip capacitors. This tantalum chip capacitor has a tantalum element, a anode lead wire extending from the tantalum element, and a cathode lead frame attached at its inside end to the tantalum element and forming a mounting terminal at its outside end. The cut-grooved anode lead frame is welded at its inside end to the lead wire while overlapping a part of the lead wire at the inside end having the cut groove. This anode lead frame also forms a mounting terminal at its outside end.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: January 28, 2003
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Kwang Kim, Hyun Sub Oh
  • Patent number: 6510045
    Abstract: A solid electrolytic capacitor of the present invention includes a sheet of valve metal, of which a part constitutes an positive electrode, a dielectric layer formed on a surface of the valve metal, a solid electrolyte layer formed on the dielectric layer, a negative electrode formed on the solid electrolyte layer, and an insulating protective layer for protecting the positive electrode, the dielectric layer, the solid electrolyte layer and the negative electrode. It is further provided with a bump formed on the insulating protective layer and connected to at least one of the positive electrode and the negative electrode. The solid electrolytic capacitor of the present invention is useful to constitute a semiconductor device or a circuit having outstanding high frequency response.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: January 21, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yuji Mido, Tetsuhiro Korechika, Suzushi Kimura, Koichi Kojima, Hideki Masumi, Seiji Takagi
  • Publication number: 20030007319
    Abstract: An electrode for use in a ferroelectric device includes a bottom electrode; a ferroelectric layer; and a top electrode formed on the ferroelectric layer and formed of a combination of metals, including a first metal take from the group of metals consisting of platinum and iridium, and a second metal taken from the group of metals consisting of aluminum and titanium; wherein the top electrode acts as a passivation layer and wherein the top electrode remains conductive following high temperature annealing in a hydrogen atmosphere.
    Type: Application
    Filed: August 27, 2002
    Publication date: January 9, 2003
    Inventors: Fengyan Zhang, Tingkai Li, Hong Ying, Yoshi Ono, Sheng Teng Hsu
  • Patent number: 6504705
    Abstract: In an electrolytic capacitor of the present invention, a dielectric layer is provided on a surface of a valve metal element for an anode having a capacitor forming part and an electrode lead part, and further, a solid electrolyte layer and a charge collecting layer for a cathode are provided in this order thereon. The capacitor forming part and the electrode lead part of the valve metal element for an anode have rough surface layers on their surfaces, and are compressed in the thickness direction of the rough surface layers. Further, a region other than the electrode lead part and the charge collecting element for cathode is molded with a molding material. Exposed portions of the electrode lead part and the charge collecting element for cathode function as electrode terminals, respectively.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: January 7, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Mikinari Shimada, Yasuhiko Nakada, Seiichi Nakatani, Seigo Shiraishi, Hiroyuki Handa, Akihiro Ishikawa
  • Patent number: 6480370
    Abstract: The present invention includes a dielectric. The dielectric comprises a polymer that has a high dielectric constant. The polymer comprises polarizable species. The present invention also includes an embedded capacitor, and an IC package made with the dielectric.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: November 12, 2002
    Assignee: Intel Corporation
    Inventors: Paul A. Koning, Paul H. Wermer
  • Patent number: 6475670
    Abstract: It is intended to provide an electrode material, which is excellent in electrostatic capacitance and low resistance, by improving conductive fine particle deposition factor and also improving the close contact between the conductive fine particles and the conductive base. A binder for a porous electrode, which is obtained by dispersing conductive fine particles such as active carbon and graphite and non-conductive fine particles 3 such as aluminum and zinc oxide in a rubber type binder 1 having been made porous by cross-linking, is developed on a conductive base 5 to form a porous electrode.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: November 5, 2002
    Inventor: Junji Ito
  • Patent number: 6466430
    Abstract: A capacitor comprising a porous metal sheet, part of which forms an electrode section, an organic dielectrics formed on a metal surface, a solid electrolyte layer formed on the organic dielectrics, an electrode layer formed on the solid electrolyte layer, and an insulating protection layer provided for protecting said electrode section, dielectrics, solid electrolyte layer and electrode layer. The capacitor is provided with bumps, which are formed on the insulating protection layer and connected at least with the electrode section or the electrode layer. The capacitor of the present invention provides a semiconductor device or a circuit superior in the high frequency response.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: October 15, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yuji Mido, Tetsuhiro Korechika, Suzushi Kimura, Seiji Takagi, Koichi Kojima
  • Patent number: 6459565
    Abstract: Aluminum surface mount capacitors containing one or more anode foil coupons are initially anodized in an aqueous phosphate solution in order to produce an anodic oxide film having extreme resistance to hydration and attack by corrosive anions for the purpose of producing surface mount capacitors at high yield and of high stability.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: October 1, 2002
    Assignee: Kemet Electronics Corporation
    Inventors: Philip Michael Lessner, Brian John Melody, John Tony Kinard, Erik Karlsen Reed, Albert Kennedy Harrington, Daniel F. Persico, David Alexander Wheeler
  • Patent number: 6454817
    Abstract: Disclosed is a method for manufacturing a solid electrolytic capacitor using a functional polymer composition. The method comprises immersing the rolled aluminum electrolytic capacitor device in polyaniline solution with high electric conductivity to impregnate the device with polyaniline, drying the impregnated device in a drying oven which is maintained at constant temperature to fully remove the solvent, inserting the dried device to a capacitor aluminum can and then sealing with epoxy resin, to manufacture a solid electrolytic capacitor using a functional polymer. As such, the impregnation can be performed well at not only normal temperature and pressure, but also high temperature and reduced pressure. The solid electrolytic capacitor has the advantages of high capacity, low impedance and low ESR, and also, low manufacturing cost, simple processes and high reliability.
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: September 24, 2002
    Assignee: Samwha Electric Co., Ltd.
    Inventors: Dal-Woo Shin, Jong-Joo Park, Young-Hoon Lee, Yong-Chul Kim, Sung-Ho Kim
  • Patent number: 6452783
    Abstract: An anode for an electrolytic capacitor includes aluminum foil as a substrate. On the aluminum foil is an alloy including aluminum and a further metal whose oxide has a higher dielectric constant than aluminum oxide. This alloy increases the surface roughness and is in vapor deposited in vacuum in several process steps at different angles of incident. A porous layer thereby is formed and a subsequent anodic oxidation is carried out.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: September 17, 2002
    Assignee: Becromal S.p.A.
    Inventors: Giovanni Pietro Chiavarotti, Francesco Di Quarto, Monica Santamaria, Carmelo Sunseri
  • Publication number: 20020122287
    Abstract: A capacitor comprising a porous metal sheet, part of which forms an electrode section, an organic dielectrics formed on a metal surface, a solid electrolyte layer formed on the organic dielectrics, an electrode layer formed on the solid electrolyte layer, and an insulating protection layer provided for protecting said electrode section, dielectrics, solid electrolyte layer and electrode layer. The capacitor is provided with bumps, which are formed on the insulating protection layer and connected at least with the electrode section or the electrode layer. The capacitor of the present invention provides a semiconductor device or a circuit superior in the high frequency response.
    Type: Application
    Filed: February 22, 2002
    Publication date: September 5, 2002
    Inventors: Yuji Mido, Tetsuhiro Korechika, Suzushi Kimura, Seiji Takagi, Koichi Kojima
  • Patent number: 6430034
    Abstract: The present invention provides a chip capacitor, a fabrication method for the same, and a metal mold that can prevent the occurrence of the chip standing phenomenon even when carrying out soldering using reflow soldering, and that be applied to further down-sizing an decreasing of weight. Curved parts 26 and 36 that extend beyond the connecting tongue pieces 21 and 31 of side piece parts 22 and 32 rising in an upward diagonal direction with respect to the connecting tongue pieces 21 and 31 are formed by press bending processing, and thereby the side piece parts 22 and 32 are exposed in an upward rising direction relative to the connecting tongue pieces 21 and 31 at the external end surfaces 15b and 15c of the external resin packaging.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: August 6, 2002
    Assignee: NEC Corporation
    Inventors: Mitsunori Sano, Kazunori Watanabe, Hideaki Sato, Kazuhiro Mine
  • Patent number: 6423110
    Abstract: A powder composition for a capacitor comprising a tantalum or niobium and a compound having a silicon-oxygen bond, at least a part of which may be nitrided and which has an average particle size of from about 0.1 to about 5 &mgr;m; a sintered body using the composition; and a capacitor constituted by the sintered body as one part electrode, and another part electrode. A capacitor favored with high reliability, lower dissipation level of power and smaller deterioration of capacitance than conventional tantalum capacitors using tantalum can be produced by using a sintered body of the powder composition for a capacitor.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: July 23, 2002
    Assignee: Showa Denko K.K.
    Inventors: Kazumi Naito, Kazuhiro Omori, Nobuyuki Nagato
  • Patent number: 6420043
    Abstract: A flaked niobium powder is disclosed as well as electrolytic capacitors formed from the flaked niobium powders. Niobium powders having a BET surface area of at least about 0.50 m2/g are also disclosed and capacitors made therefrom, as well as niobium powders doped with an oxygen content of at least 2,000 ppm. Methods to reduce DC leakage in a niobium anode are also disclosed.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: July 16, 2002
    Assignee: Cabot Corporation
    Inventors: James A. Fife, Jane Jia Liu, Roger W. Steele
  • Patent number: 6421226
    Abstract: Implantable defibrillators are implanted into the chests of patients prone to suffering ventricular fibrillation, a potentially fatal heart condition. A critical component in these devices is an aluminum electrolytic capacitors, which stores and delivers one or more life-saving bursts of electric charge to a fibrillating heart. To reduce the size of these devices, capacitor manufacturers have developed special aluminum foils, for example core-etched and tunnel-etched aluminum foils. Unfortunately, core-etched foils don't work well in multiple-anode capacitors, and tunnel-etched foils are quite brittle and tend to break when making some common types of capacitors. Accordingly, the inventors devised a new foil structure having one or more perforations and one or more cavities with a depth less than the foil thickness.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: July 16, 2002
    Assignee: Cardiac Pacemakes, Inc.
    Inventors: Michael J. O'Phelan, Luke J. Christenson, James M. Poplett, Robert R. Tong
  • Patent number: 6414836
    Abstract: Graphitic nanofibers, which include tubular fullerenes (commonly called “buckytubes”), nanotubes and fibrils, which are functionalized by chemical substitution, are used as electrodes in electrochemical capacitors. The graphitic nanofiber based electrode increases the performance of the electrochemical capacitors.
    Type: Grant
    Filed: October 1, 1999
    Date of Patent: July 2, 2002
    Assignee: Hyperion Catalysis International, Inc
    Inventors: Howard Tennent, David Moy, Chun-Ming Niu
  • Patent number: 6414837
    Abstract: An electrochemical capacitor is provided having double-layer electrode elements interposed with a separator. The electrode elements being made of activated carbon and impregnated with a nonaqueous electrolytic liquid yields a capacitor with low internal resistance, greater capacitance and higher energy density. Methods for producing the activated carbon electrodes and the capacitor assembly are also described.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: July 2, 2002
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Mitsubishi Chemical Corp.
    Inventors: Kenji Sato, Shigeki Oyama, Hiroto Kobayashi, Minoru Noguchi, Takashi Higono, Yasuhiro Matsumoto, Makoto Ue, Akiko Toriumi, Yasushi Ohura
  • Patent number: 6409776
    Abstract: Implantable medical devices (IMDs) and their various components, including flat electrolytic capacitors for same, and methods of making and using same, particularly an improved electrolytic capacitor with optimized ESR and anode layer surface area. An electrode stack assembly and electrolyte are located within the interior case chamber of a hermetically sealed capacitor case. The electrode stack assembly comprises a plurality of capacitor layers stacked in registration upon one another, each capacitor layer comprising a cathode layer having a cathode tab, an anode sub-assembly comprising at least one anode layer having an anode tab, and a separator layer located between adjacent anode and cathode layers, whereby all adjacent cathode layers and anode layers of the stack are electrically insulated from one another by a separator layer.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: June 25, 2002
    Assignee: Medtronic, Inc.
    Inventors: Jenn-Feng Yan, Darrel F. Untereker, Ann M. Crespi
  • Patent number: 6409777
    Abstract: A conductive high polymer layer as an electrolyte is formed on the entire surface of fine pores of a dielectric oxide layer of an anode electrode having an undulated surface of fine pores or the like. As a result, a solid electrolytic capacitor having characteristics such as capacitance, impedance, and leak current exactly as designed will be obtained. It comprises a manganese dioxide layer composed of a porous sinter of valve metal or roughened meal foil, placed continuously on the entire surface of the undulated surface of a dielectric oxide layer of an anode electrode having an undulated surface, a conductive high polymer layer formed by electrolytic polymerization, in contact with the surface of the manganese dioxide layer, and a cathode electrode placed on this conductive high polymer layer.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: June 25, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuhiro Kobatake, Yukihiro Nitta, Kazuyo Saito
  • Patent number: 6404618
    Abstract: An aluminum electrolytic capacitor which has the capacity to operate at a constant A/C voltage as long as the capacitor is energized. The aluminum foil used in the capacitor is an amorphous oxide which causes the oxide to be “fluffy” such that the oxide stacks up and becomes thicker. The aluminum foil is of the heavy-duty type exceeding the specification of EIA RS463.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: June 11, 2002
    Assignee: Yosemite Investment Co. Inc.
    Inventors: Kenneth D. Beard, Robert Borton
  • Patent number: 6402793
    Abstract: Flat electrolytic capacitors particularly for use in implantable medical devices having stacked cathode and anode layers particular electrical connections of the capacitor anode and cathode layers with a capacitor connector assembly. Anode terminal means extend through the capacitor case side wall for electrically connecting a plurality of the anode tabs to one another and providing an anode connection terminal at the exterior of the case that is electrically insulated from the case. A cathode terminal extends through or to an encapsulation area of the capacitor case side wall via a cathode terminal passageway for electrically connecting a plurality of the cathode tabs to one another and providing a cathode connection terminal at the exterior of the case. The connector assembly is electrically attached to the anode connection terminal for making electrical connection with the anode tabs and to the cathode connection terminal for making electrical connection with the cathode tabs.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: June 11, 2002
    Assignee: Medtronic, Inc.
    Inventors: Thomas P. Miltich, Paul A. Pignato, Mark D. Breyen, Kurt J. Casby, William L. Johnson
  • Patent number: 6400554
    Abstract: The present invention provides an electrolytic capacitor and its anode body using a laminate of plurality of sheets of valve metal foil, exhibiting excellent high-frequency response and lower inner impedance as a electrolytic capacitor. The anode body for a electrolytic capacitor includes; a laminate of plurality of rectangular anode valve metal foil each which has dielectric layers of its metal oxide film anodized on roughened surfaces of each anode valve metal foil; and a fixing frame to clamp the laminate in the laminating direction to fix the laminate and connect electrically with anode layers of the laminated foil. Such an anode body may be used to be filled in the liquid electrolyte in the container to make a capacitor.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: June 4, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Seigo Shiraishi, Emiko Igaki, Masakazu Tanahashi