Nitride Containing Patents (Class 419/13)
  • Patent number: 5666631
    Abstract: A compacted, single phase or multiphase composite article. Particles for use in the compacted article are produced by providing a precursor compound containing at least one or at least two metals and a coordinating ligand. The compound is heated to remove the coordinating ligand therefrom and increase the surface area thereof. It may then be reacted so that at least one metal forms a metal-containing compound. The particles may be consolidated to form a compacted article, and for this purpose may be used in combination with graphite or diamonds. The metal-containing compound may be a nonmetallic compound including carbides, nitrides and carbonitrides of a refractory metal, such as tungsten. The metal-containing compound may be dispersed in a metal matrix, such as iron, nickel or cobalt. The dispersed nonmetallic compound particles are no larger than about 0.1 micron in particle size and have a volume fraction greater than about 0.15 within the metal matrix.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: September 9, 1997
    Assignee: Exxon Research & Engineering Company
    Inventors: Richard S. Polizzotti, Larry E. McCandlish, Edwin L. Kugler
  • Patent number: 5659872
    Abstract: There is provided a sintered titanium-based carbonitride alloy for metal cutting containing hard constituents based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and 3-30% binder phase based on Co and/or Ni. The structure contains 10-50% by weight well-dispersed Ti-rich hard constituent grains essentially without core-rim structure with a mean grain size of 0.8-5 .mu.m in a conventional carbonitride alloy matrix with a mean grain size of the hard constituents of 1-2 .mu.m. The Ti-rich hard constituent grains are essentially rounded, non-angular grains with an approximately logarithmic normal grain size distribution with a standard deviation of <0.23 logarithmic .mu.m.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: August 19, 1997
    Assignee: Sandvik AB
    Inventors: Niclas During, Gerold Weinl
  • Patent number: 5649278
    Abstract: Aluminum nitride powder, aluminum nitride platelets, powdered solid solutions of aluminum nitride and at least one other ceramic material such as silicon carbide, and composites of aluminum nitride and transition metal borides or carbides are prepared by combustion synthesis at low gaseous nitrogen pressures. Porous bodies of aluminum nitride or composites of aluminum nitride and transition metal borides or carbides are also prepared by combustion synthesis at these pressures. The porous bodies are suitable for infiltration, either as formed or after being coated with at least one layer of a silicate material, by polymers or metals.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: July 15, 1997
    Assignee: The Dow Chemical Company
    Inventors: Stephen D. Dunmead, William G. Moore, Kevin E. Howard, Kevin C. Morse
  • Patent number: 5641921
    Abstract: This invention is directed toward a material which is used to coat or create a surface for machine cutting tools, all types of drill bit teeth, saw teeth, bearing surfaces valve seats, nozzles and the like, thereby producing surfaces which are highly abrasion and erosion resistant. Furthermore, this invention includes some of the possible methods for producing such a material given that the methods and apparatus required provide a significant cost reduction over those required for producing prior art surface materials with similar abrasion and erosion resistant properties. More specifically, the material set forth can be formed at relatively low temperatures and relatively low pressures by sintering mixtures for a relatively short period of time.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: June 24, 1997
    Assignee: Dennis Tool Company
    Inventors: Mahlon Denton Dennis, Barton Hampshire
  • Patent number: 5635654
    Abstract: A particulate reinforced NiAl-AlN composite alloy has a NiAl matrix and greater than about 13 volume percent fine particles of AlN within the matrix. The particles preferably have a diameter from about 15 nanometers to about 50 nanometers. The particulate reinforced NiAl-AlN composite alloy may be prepared by cryomilling prealloyed NiAl in liquid nitrogen using grinding media having a diameter of from about 2 mm to about 6 mm at an impeller speed of from about 450 RPM to about 800 RPM. The cryomilling may be done for a duration of from about 4 hours to about 20 hours to obtain a cryomilled powder. The cryomilled powder may be consolidated to form the particulate reinforced NiAl-AlN composite alloy. The particulate reinforced alloy can further include a toughening alloy. The toughening alloy may include NiCrAlY, FeCrAY and FeAl.
    Type: Grant
    Filed: May 5, 1994
    Date of Patent: June 3, 1997
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Mohan G. Hebsur, John D. Whittenberger, Carl E. Lowell
  • Patent number: 5614684
    Abstract: A method for the production of a superplastic Mg-based composite material comprises preparing a composite material consisting of ceramic particles formed of at least one compound selected from among TiC, AlN, Si.sub.3 N.sub.4, and TiB.sub.2 and a matrix formed of a magnesium alloy, dispersing the ceramic particles in the matrix, hot extruding the composite material, and then hot rolling the resultant extrudate; and a superplastic Mg-based composite material produced by the method.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: March 25, 1997
    Assignee: Agency of Industrial Science and Technology, Ministry of International Trade & Industry
    Inventors: Suk-Won Lim, Tsunemichi Imai, Yoshinori Nishida, Takao Choh
  • Patent number: 5607630
    Abstract: A ceramic moulded body containing at least 10 vol. % fine-grained Al.sub.2 O.sub.3, and a process for its production(a) milling aluminium metal in powder form alone or together with Al.sub.2 O.sub.3 or/and if desired further suitable inorganic substances for ceramic formation in a non-aqueous liquid in the presence of oxygen until 10 to 80% of the metallic aluminium powder has reacted to form one or several aluminium oxidation precursors from the group amorphous Al.sub.2 O.sub.3, .gamma.-Al.sub.2 O.sub.3 and aluminium-organic compounds and the powder has a maximum oxidation rate between 510.degree. and 610.degree. C. according to differential thermoanalytical measurement;(b) molding the powder of step (a) into a green body;(c) slowly heating the green body in an atmosphere containing oxygen to a temperature which is below the melting temperature of aluminium until at least 50% of the metallic aluminium powder remaining after the milling has reacted to Al.sub.2 O.sub.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: March 4, 1997
    Inventor: Nils Claussen
  • Patent number: 5603070
    Abstract: Metal carbide supported polycrystalline diamond (PCD) compacts having improved shear strength and impact resistance properties, and a method for making the same under high temperature/high pressure (HT/HP) processing conditions. A sintered polycrystalline cubic boron nitride (PCBN) compact interlayer is provided to be bonded at a first interface to a sintered PCD compact layer, and at a second interface to a cemented metal carbide support layer comprising particles of a metal carbide in a binder metal. The supported compact is characterized as having a substantially uniform sweep through of the binder metal from the cemented metal carbide support layer, which sweep through bonds the sintered PCD compact layer to the sintered PCBN interlayer, and the sintered PCBN interlayer to the cemented metal carbide support layer.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: February 11, 1997
    Assignee: General Electric Company
    Inventors: David B. Cerutti, Henry S. Marek
  • Patent number: 5590383
    Abstract: A porous membrane produced by preparing a slurry made from at least one micropyretic substance and at least one liquid carrier. The slurry is dried into a green form having a desired geometric configuration. Combustion of the green form produces the porous membrane.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: December 31, 1996
    Assignee: Micropyretics Heaters International, Inc.
    Inventors: Jainagesh A. Sekhar, James J. Liu, Naiping Zhu
  • Patent number: 5589652
    Abstract: In the metallic member of the invention, ceramic super fine particles, and solid lubricant particles or short size fibers are dispersed, and the grain size of the ceramic particles is smaller than the solid lubricant particle size or fiber diameter.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: December 31, 1996
    Assignee: Hitachi, Ltd.
    Inventors: Toshiaki Arato, Yasuhisa Aono, Shigeo Tsuruoka, Katsuhiro Komuro
  • Patent number: 5581798
    Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 3-25 weight % binder phase with extremely good properties at intermittent machining of materials difficult to machine. The method relates to the use of a raw material comprising a complex cubic carbonitride containing the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition0.86.ltoreq.X.sub.IV .ltoreq.0.970.44.ltoreq.X.sub.C .ltoreq.0.55where X.sub.IV is the molar ratio of the group IV elements of the alloy and X.sub.C is the molar ratio of carbon.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: December 3, 1996
    Assignee: Sandvik AB
    Inventors: Gerold Weinl, Rolf Oskarsson
  • Patent number: 5568653
    Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 3-25 weight-% binder phase with extremely good properties at semifinishing operations at turning. The method relates to the use of a raw material consisting of a complex cubic carbonitride comprising the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition0.85.ltoreq.X.sub.IV .ltoreq.0.990.58.ltoreq.X.sub.C .ltoreq.0.69where X.sub.IV is the molar ratio of the group IV elements of the alloy and X.sub.C is the molar ratio of carbon.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: October 22, 1996
    Assignee: Sandvik AB
    Inventors: Gerold Weinl, Rolf Oskarsson
  • Patent number: 5561829
    Abstract: A method of preparing a metal alloy product from a powder blend. The method comprising: (a) cold pressing a blend to form a compact, the metal blend comprising a metal powder phase and at least one reinforcement phase having a hardness greater than the metal phase; (b) heating the compact to form a preheated compact; and (c) hot working the heated compact. In a preferred method, the powder metal blend comprises 50 to 90 vol. % of an aluminum alloy powder and 10 to 50 vol. % of silicon carbide; the heating of the compact perforated in a nitrogen atmosphere to form a preheated compact; and the extruded hot compact is hot worked. Hot working may take the form of forging, rolling, upset forging, exuding, compacting or other processes known in the art.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: October 1, 1996
    Assignee: Aluminum Company of America
    Inventors: Ralph R. Sawtell, Warren H. Hunt, Jr., Thomas J. Rodjom, Erik J. Hilinski, John H. Milsom
  • Patent number: 5561831
    Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 3-25 weight-% binder phase with extremely good properties at fine to medium coarse milling. The method relates to the use of a raw material consisting of a complex cubic carbonitride comprising the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition0.89.ltoreq.X.sub.IV .ltoreq.0.970.52.ltoreq.X.sub.C .ltoreq.0.61where X.sub.IV is the molar ratio of the group IV elements of the alloy and X.sub.C is the molar ratio of carbon.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: October 1, 1996
    Assignee: Sandvik AB
    Inventors: Ake Ostlund, Rolf Oskarsson
  • Patent number: 5561830
    Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 325 weight-% binder phase with extremely good properties at extremely fine machining with high cutting speeds and low feeds. The method relates to the use of a raw material comprising a complex cubic carbonitride containing the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition0.87.ltoreq.X.sub.IV .ltoreq.0.990.66.ltoreq.X.sub.C .ltoreq.0.76where X.sub.IV is the molar ratio of the group IV elements of the alloy and X.sub.C is the molar ratio of carbon.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: October 1, 1996
    Assignee: Sandvik AB
    Inventors: Gerold Weinl, Rolf Oskarsson
  • Patent number: 5552108
    Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 3-25 weight-% binder phase with extremely good properties at extreme fine machining when turning with high cutting rates. The method relates to the use of a raw material comprising a complex cubic carbonitride containing the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition0.86.ltoreq.X.sub.IV .ltoreq.0.990.74.ltoreq.X.sub.C .ltoreq.0.83where X.sub.IV is the molar ratio of the group IV elements of the alloy and X.sub.C is the molar ratio of carbon.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: September 3, 1996
    Assignee: Sandvik AB
    Inventors: Gerold Weini, Rolf Oskarsson
  • Patent number: 5552107
    Abstract: Disclosed is an aluminum nitride body having graded metallurgy and a method for making such a body. The aluminum nitride body has at least one via and includes a first layer in direct contact with the aluminum nitride body and a second layer in direct contact with, and that completely encapsulates, the first layer. The first layer includes 30 to 60 volume percent aluminum nitride and 40 to 70 volume percent tungsten and/or molybdenum while the second layer includes 90 to 100 volume percent of tungsten and/or molybdenum and 0 to 10 volume percent of aluminum nitride.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: September 3, 1996
    Inventors: Jon A. Casey, Carla N. Cordero, Benjamin V. Fasano, David B. Goland, Robert Hannon, Jonathan H. Harris, Lester W. Herron, Gregory M. Johnson, Niranjan M. Patel, Andrew M. Reitter, Subhash L. Shinde, Rao V. Vallabhaneni, Robert A. Youngman
  • Patent number: 5541006
    Abstract: Methods for making, methods for using and articles comprising ferromagnetic cermets, preferably cemented carbides and more preferably tungsten carbide, having at least two regions exhibiting at least one property that differs are discussed. The multiple-region cermets are particularly useful in wear applications. The cermets are manufactured by juxtaposing and densifying at least two powder blends having different properties (e.g., differential carbide grain size or differential carbide chemistry or differential binder content or differential binder chemistry or differential magnetic saturation or any combination of the preceding). Preferably, a first region of the cermet comprises a first hard component having a prescribed binder content and a first magnetic saturation and a second region, juxtaposing or adjoining the first region, comprising a second binder content different than the binder content of the first region and a second magnetic saturation different than that of the first region.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: July 30, 1996
    Assignee: Kennametal Inc.
    Inventor: Edward V. Conley
  • Patent number: 5536485
    Abstract: A powder of diamond or high-pressure phase boron nitride core particles charged into a coating space as it is dispersed, and a precursor of a coat forming substance allowed to contact and/or impinge against the particles in the powder of core particles so that their surfaces are covered with the coat forming substance, thereby preparing coated diamond or high-pressure phase boron nitride particles which are subsequently sintered. The thusly produced diamond of high-pressure phase boron nitride sinter is composed of coated core particles of high performance that are superhard, uniform, dense and sintered firmly, and which have a controlled microstructure.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: July 16, 1996
    Assignees: Agency of Industrial Science & Technology, Nisshin Flour Milling Co., Ltd., Reed Co., Ltd
    Inventors: Shoichi Kume, Haruo Yoshida, Yukiyoshi Yamada, Tadashi Fuyuki, Satoshi Akiyama, Yoshiaki Hamada, Eisuke Kuroda, Tadakatsu Nabeya, Yukio Sumita, Kenichi Kimura
  • Patent number: 5529804
    Abstract: A process for the production of hard materials wherein hard constituent powders are coated with cobalt and/or nickel metal in solution by reducing the metals from a suitable compound such as an oxide, hydroxide or salt with a polyol while keeping the powder in suspension. The polyol functions both as a solvent and a reducing agent at the same time and is present in an amount of at least 5 times more moles polyol than moles metal. There is obtained an even distribution of the cobalt and/or nickel over the surface of the hard constituent powder without the formation of islands of pure metal.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: June 25, 1996
    Assignees: Sandvik AB, Eurotungstene Poudres S.A.
    Inventors: Maxime Bonneau, Nicolas Chardon, Sara Andersson, Mamoun Muhammed
  • Patent number: 5520878
    Abstract: An unsintered aluminum nitride body including:(a) 1 to 5 weight percent of a vitreous solid of boria, alumina, and calcia in the proportions of (1) boria between 3 and 25 weight percent, (2) alumina between 10 and 50 weight percent, and (3) calcia between 40 and 80 weight percent; and(b) aluminum nitride powder as the balance of the aluminum nitride body.The invention further relates to a method of forming the unsintered aluminum nitride body and then sintering it at a temperature between 1550 and 1650 degrees Centrigrade so as to form a dense, thermally conductive aluminum nitride body.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: May 28, 1996
    Assignee: International Business Machines Corporation
    Inventors: Peter R. Duncombe, Subhash L. Shinde, Takeshi Takamori
  • Patent number: 5520880
    Abstract: This invention relates to a method for producing a self-supporting body comprising the steps of:(a) forming a permeable mass comprising at least one solid-phase oxidant selected from the group consisting of the halogens, sulphur and its compounds, metals, metal oxides other than the silicates, and metal nitrides other than those of boron and silicon;(b) orienting said permeable mass and a source of said parent metal relative to each other so that formation of said oxidation reaction product will occur into said permeable mass;(c) heating said source of parent metal to a temperature above the melting point of said parent metal but below the melting point of said oxidation reaction product to form a body of molten parent metal;(d) reacting said body of molten parent metal with said at least one solid-phase oxidant at said temperature to permit said oxidant at said temperature to permit said oxidation reaction product to form; and(e) maintaining at least a portion of said at least one oxidation reaction product
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: May 28, 1996
    Assignee: Lanxide Technology Company, LP
    Inventors: William B. Johnson, Eugene S. Park, Gerhard H. Schiroky, Danny R. White, Terry D. Claar
  • Patent number: 5476632
    Abstract: A process of forming a sintered article of powder metal comprising: selecting elemental iron powder; determining the desired properties of said sintered article and selecting, a quantity of carbon, and ferro alloy from the group of ferro manganese, ferro chromium, ferro molybdenum, ferro vanadium, ferro silicon and ferro boron; grinding said ferro alloy to a mean particle size of approximately 8 to 12 microns; introducing a lubricant while blending the carbon, ferro alloy, with said elemental iron powder; pressing the mixture to form the article; and then high temperature sintering the article at a temperature between 1,250.degree. C. and 1,350.degree. C. in a neutral or reducing atmosphere; so as to produce the sintered article of powdered metal; and includes the product formed thereby.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: December 19, 1995
    Assignee: Stackpole Limited
    Inventors: Rohith Shivanath, Peter Jones
  • Patent number: 5472487
    Abstract: Molybdenum disilicide base materials and methods for producing them are described. Mixtures of MoSi.sub.2 powder and other powders including SiO.sub.2, Si.sub.3 N.sub.4, SiC and Mo.sub.5 Si.sub.3 are plasma sprayed. Another embodiment which involves oxidation of MoSi.sub.2 is also disclosed. The resistant materials have particular utility as coatings for Nb alloys.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: December 5, 1995
    Assignee: United Technologies Corporation
    Inventors: Stephen Chin, Norman S. Bornstein
  • Patent number: 5460775
    Abstract: The invention provides aluminum sintered alloys with high dimensional accuracy and high density which are superior in mechanical and physical characteristics as well as wear resistance, and a method of producing such alloys not by plastic working but by atmospheric sintering with high economy. Rapidly solidified aluminum alloy powder resulting from solidifying aluminum alloy molten metal containing 0.4 to 4.0% by weight of Mg at a solidification rate of 10.sup.2 .degree. C./sec or more is press molded in the cold, after annealing in the temperature range of 250 to 450.degree. C. if necessary, and then the molded product is sintered by generating nitrogen compounds on the powder surface at atmospheric pressure with a nitrogen partial pressure of 0.8 atm or more and a steam partial pressure of 0.01 atm or less in which a reducing gas component has been added as a nitrogen-combining acceleration gas component by 0.01 atm or more. Thus, a nitrogen-combined aluminum sintered alloy containing 0.4 to 4.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: October 24, 1995
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Tetsuya Hayashi, Yoshinobu Takeda
  • Patent number: 5460640
    Abstract: A fully dense ceramic-metal body including 40-88 v/o of an oxide hard phase of, in v/o of the body, 4-88 v/o M-aluminum binary oxides, where the binary oxide has a C-type rare earth, garnet, .beta.-MAl.sub.11 O.sub.18, or perovskite crystal structure, and M is a lanthanide or indium, and 0-79 v/o .alpha.-alumina; about 10-50 v/o of a hard refractory carbide, nitride, or boride as a reinforcing phase; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing phase is silicon carbide partially incorporated into the oxide grains, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the starting formulation as Ni powder and Al powder.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: October 24, 1995
    Assignee: Valenite Inc.
    Inventor: Sergej-Tomislav Buljan
  • Patent number: 5443786
    Abstract: A composition for the formation of vias on a ceramic substrate, the composition including (a) at least one powder containing copper, gold, silver, tungsten, molybdenum, nickel, palladium, platinum, aluminium, or an alloy thereof; and (b) 5 to 40 wt %, based on the weight of the powder in the composition, of one or more of an organosilicic compound, an organoaluminium compound, an organozirconium compound, and an organomagnesium compound. A further embodiment of a composition for the formation of vias includes (a) and (b) above and, in addition, (c) a binder material including a cellulose derivative or a heat decomposable polymethamethyl acrylate binder, and (d) a high boiling point organic solvent. The invention also includes a method for use in the formation of vias on a substrate having perforating holes therein. Such a substrate could be a glass ceramic composite substrate, an alumina substrate, a magnesia substrate, a zirconia substrate, or green sheets thereof.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: August 22, 1995
    Assignee: Fujitsu Limited
    Inventors: Hiromitsu Yokoyama, Koji Omote, Hitoshi Suzuki, Mineharu Tsukada, Nobuo Kamehara, Koichi Niwa
  • Patent number: 5441694
    Abstract: In a method for preparing a high .alpha.-type silicon nitride powder by adding to and mixing with metallic silicon powder a copper catalyst and nitriding the mixture in a non-oxidizing gas atmosphere containing nitrogen or ammonia at 1,000.degree. to 1,500.degree. C., the amount of copper catalyst is limited to from 0.05 % to less than 0.5 % by weight of copper based on the weight of the metallic silicon. There is obtained silicon nitride powder of high purity at low cost and high efficiency since the copper catalyst can be efficiently removed from the silicon nitride powder through conventional acid treatment.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: August 15, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masanori Fukuhira, Hirofumi Fukuoka, Yoshiharu Konya, Masaki Watanabe
  • Patent number: 5441693
    Abstract: The present invention relates to a method of producing a sintered body comprising one or more hard constituents and a binder phase based on cobalt, nickel and/or iron by powder metallurgical methods milling, pressing and sintering of powders. At least part of the binderphase powder consists of non-agglomerated particles of spheroidal morphology having dimensions of 0.1 to 20 .mu.m.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: August 15, 1995
    Assignee: Sandvik AB
    Inventors: Stefan Ederyd, Jan Akerman, Robert Beaufoy, Michael Carpenter, Maxime Bonneau, Jacques Pillot
  • Patent number: 5439499
    Abstract: A cermet useful in the fabrication of metal cutting, rockdrilling and mineral tools, as well as wear parts. The cermet comprises (i) a hard phase of a simple boride of a transition metal, a mixture of simple borides of transition metals, or a mixed boride of transition metals; (ii) a binder phase of Fe, Ni, Co, Cr, or alloys thereof; (iii) a dispersion of particles of oxides of transition metals in which the oxygen can be replaced by nitrogen and/or carbon; and (iv) a dispersion of oxides of metals chosen from aluminum and Group IIA and IIIA metals.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: August 8, 1995
    Assignee: Sandvik AB
    Inventors: Henri Pastor, Colette Allibert, Laurent Ottavi, Manuel Albajar, Francisco Castro-Fernandez
  • Patent number: 5439744
    Abstract: This invention relates generally to a novel directed metal oxidation process which is utilized to produce self-supporting bodies. In some of the more specific aspects of the invention, a parent metal (e.g., a parent metal vapor) is induced to react with at least one solid oxidant-containing material to result in the directed growth of a reaction product which is formed from a reaction between the parent metal and the solid oxidant-containing material. The inventive process can be utilized to form bodies having substantially homogeneous compositions, graded compositions, and macrocomposite bodies.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: August 8, 1995
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, Vilupanur A. Ravi, Philip J. Roach
  • Patent number: 5437833
    Abstract: This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 --ZrC--Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: August 1, 1995
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, Gerhard H. Schiroky, William B. Johnson
  • Patent number: 5436080
    Abstract: A structural member is produced using starting powder consisting of composite particulates each containing AlN grain within its surface covered by an Al layer of a single crystal structure, and Al alloy particulates of a single crystal structure, and then by sintering the Al layers of the composite particulates with the Al alloy particulates. The Al layers and the Al alloy particulates of the single crystal structure have no dislocation fault, crystal grain boundary. etc., produced therein, and for this reason, they have a low chemical activity. Therefore, the Al layers and the like have a characteristic that they are extremely difficult to oxidize. This ensures that the Al layers and the Al alloy particulates can be reliably sintered to achieve the densification of the resulting structural member.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: July 25, 1995
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Akihisa Inoue, Tsuyoshi Masumoto, Jun Sasahara, Katsutoshi Nosaki, Tadashi Yamaguchi
  • Patent number: 5427600
    Abstract: A low alloy sintered steel contains at least 0.15 percent by weight and less than 0.8 percent by weight of carbon. Its matrix is formed by a tempered martensite containing prior austenite crystal grains of not more than 15 .mu.m in mean grain size. Pores and nonmetallic inclusions contained in the matrix are not more than 50 .mu.m in maximum diameter, and the density of the low alloy sintered steel is at least 96 percent of theoretical density. A raw material powder for forming the low alloy sintered steel includes iron alloy powder which is prepared by an atomizing process, and is treated with a dry mill in an inert gas atmosphere or in the atmospheric air. Thus, dislocations are introduced into the raw material powder, and nonmetallic inclusions contained in the raw material powder are pulverized to be not more than 50 .mu.m in maximum diameter. Not only static characteristics but also dynamic characteristics, such as fatigue strength, of the low alloy sintered steel are improved.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: June 27, 1995
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshiaki Itoh, Kozo Ito, Yoshinobu Takeda
  • Patent number: 5421851
    Abstract: The present invention relates to a sintered titanium-based carbonitride alloy for milling and turning where the hard constituents are based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and the binder phase based on Co and/or Ni. The structure comprises 10-50% by volume hard constituent grains with core-rim-structure with a mean grain size for the cores of 2-8 .mu.m in a more fine-grained matrix with a mean grain size of the hard constituents of <1 .mu.m and where said mean grain size of the coarse hard constituents grains is >1.5 .mu.m, preferably >2 .mu.m, larger than the mean grain size for the grains in the matrix. The coarse grains can be Ti(C,N), (Ti,Ta)C, (Ti,Ta)(C,N) and/or (Ti,Ta,V)(C,N).
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: June 6, 1995
    Assignee: Sandvik AB
    Inventors: Rolf G. Oskarsson, Gerold Weinl, Ake Ostlund
  • Patent number: 5405573
    Abstract: The present invention addresses problems in the diamond saw blade and segment art. One aspect of the invention comprises a method for making handleable, strong, discrete, metal-clad abrasive pellets. This method comprises the steps of:(a) spraying onto a bed of gas-fluidized abrasive particles a slurry of metallic powder, a binding agent, and a volatile solvent until substantially all the abrasive particles are coated with at least about 20 wt-% of the metallic powder;(b) recovering the metal powder coated abrasive particles; and(c) heating said recovered coated particles under conditions to form a sintered continuous metal coating enveloping said abrasive particles. The resulting sintered metal-clad pellets form another aspect of the invention.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: April 11, 1995
    Assignee: General Electric Company
    Inventors: Thomas J. Clark, Roger R. Matarrese, Roger W. McEachron, Sergio Sinigaglia
  • Patent number: 5403542
    Abstract: Method of manufacturing a sintered carbonitride alloy comprising wet milling powders of forming binder phase containing Co, Ni and mixture thereof and powder forming hard constituents of nitrides and carbonitrides with Ti as the main component to a mixture with desired composition; compacting said mixture to form compact; heating the compact at 100-300 C. in oxygen or air and subjecting said compact in multiple heating steps to effect sintering.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: April 4, 1995
    Assignee: Sandvik AB
    Inventors: Gerold Weinl, Rolf G. Oskarsson, Per Gustafsson
  • Patent number: 5403373
    Abstract: A hard sintered component of a cemented carbide or a stellite alloy having a complex three-dimensional shape and a small hole or the like and the high strength originally provided by the used material for making the component without any secondary working, is formed by injection molding a compact molding die having an inner mold surface roughness R.sub.max of not more than 3 .mu.m. Where a core pin is used the outer surface of the pin has a surface roughness R.sub.max of not more than 3 .mu.m. The compact is then sintered. The hard sintered component is composed of a cemented carbide or a stellite alloy. In such a hard sintered component, the surface of a complex three-dimensional shape such as a disc portion or a thin portion, or the inner surface of a small hole, is defined by a sintered surface which has a surface roughness R.sub.max of not more than 4 .mu.m.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: April 4, 1995
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Nobuyuki Kitagawa, Toshio Nomura
  • Patent number: 5403374
    Abstract: A watch exterior part is formed of cemented carbide or stellite alloy, and has a three-dimensionally curved as-sintered surface or a small hole with an as-sintered interior peripheral surface, or has a three-dimensionally curved polished surface obtained by polishing an as-sintered surface. The watch exterior part is manufactured by a method in which organic binder is milled into a material powder, and a molded body obtained by injection molding is subjected to a binder removing process and then sintered. By the manufacturing method, a watch exterior part formed of cemented carbide or stellite alloy has a high strength and a complicated configuration such as a three-dimensional curved surface and a small hole, without applying secondary machining operations such as discharge operations.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: April 4, 1995
    Assignees: Sumitomo Electric Industries, Ltd., Namiki Precision Jewel Co., Ltd.
    Inventors: Nobuyuki Kitagawa, Toshio Nomura, Yoichi Yaguchi, Hidehiro Uchiumi, Naoko Iwashimizu
  • Patent number: 5403541
    Abstract: Method of making sintered insert for milling and turning formed of a titanium-based carbonitride containing hard constituents and binder phase metal comprising milling at least one hard constituent with binder phase metal, adding a second hard constituent at a later time during milling, pressing and sintering the pressed constituents to form the insert.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: April 4, 1995
    Assignee: Sandvik AB
    Inventors: Rolf G. Oskarsson, Gerold Weinl, Ake stlund
  • Patent number: 5382405
    Abstract: A method of manufacturing a shaped article from a powdered precursor, wherein the components of the powdered precursor are subjected to a self-propagating high-temperature synthesis (SHS) reaction and are consolidated essentially simultaneously. The shaped article requires essentially no machining after manufacture.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: January 17, 1995
    Assignee: Inland Steel Company
    Inventors: Kenneth F. Lowrance, II, Eric C. Knorr, William M. Goldberger, Daniel Boss, Doreen Edwards
  • Patent number: 5372775
    Abstract: To prepare an aluminum matrix particle composite alloy, a molten metal, mainly composed of aluminum, containing ceramic particles is disintegrated by atomization, to prepare atomized powder. The atomized powder is mechanically ground/reflocculated with a ball mill or the like, to prepare mechanically ground/reflocculated powder containing ceramic particles of not more than 8 .mu.m in maximum diameter and not more than 3 .mu.m in mean particle diameter. The mechanically ground/reflocculated powder is then warm-formed/solidified. Alternatively, an aluminum alloy molten metal containing dispersed particles is disintegrated by atomization, and thereafter the powder containing the dispersed particles of not more than 20 .mu.m in mean particle diameter is warm-formed/solidified by powder forging. Thus, it is possible to obtain an aluminum matrix particle composite alloy in which extra-fine ceramic particles are homogeneously distributed without segregation.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: December 13, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Tetsuya Hayashi, Yoshinobu Takeda
  • Patent number: 5371049
    Abstract: A ceramic composite is disclosed which may be used as lightweight armor or for other impact or wear resisting purposes. The ceramic composite may comprise distinct phases of AlN and SiC; may be a solid solution of SiC; or may contain AlN or SiC, or both AlN and SiC as residual phase(s) in a solid solution matrix of SiC and AlN.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: December 6, 1994
    Assignee: FMC Corporation
    Inventors: Keith R. Moffett, John D. Morrow
  • Patent number: 5364586
    Abstract: A filter membrane and a process for making the filter membrane are provided. The filter membrane comprises a metal substrate having a filtering layer thereon comprising sintered ultra-fine particles of metal or ceramic compounds. The filtering layer preferably has an average pore size of from about 30 nanometers to about 200 nanometers. The filter membranes can withstand pressure drops of up to about 0.6 MPa and are useful for a variety of filtering applications.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: November 15, 1994
    Assignee: Ultram International L.L.C.
    Inventors: Lev I. Trusov, Vladimir N. Lapovok, Victor I. Novikov
  • Patent number: 5364442
    Abstract: A composite electrode for electrochemical processing having improved high temperature properties, and a process for making the electrode by combustion synthesis. A composition from which the electrode is made by combustion synthesis comprises from about 4% to about 90% by weight of a particulate or fibrous combustible mixture which, when ignited, is capable of forming an interconnected network of a ceramic or metal-ceramic composite, and from about 10% to about 60% by weight of a particulate or fibrous filler material capable of providing the electrode with improved oxidation resistance and maintenance of adequate electrical conductivity at temperatures above 1000.degree. C. The filler material is molybdenum silicide, silicon carbide, titanium carbide, boron carbide, boron nitride, zirconium boride, cerium oxide, cerium oxyfluoride, or mixtures thereof.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: November 15, 1994
    Assignee: Moltech Invent S.A.
    Inventor: Jainagesh A. Sekhar
  • Patent number: 5354536
    Abstract: A silicon carbide material is made following a procedure including hot pressing to provide a finished product having a microstructure with an optimal grain size of less than 7 micrometers. The material exhibits a dominant failure mode of intergranular fracture requiring significant energy for crack propagation. The method of manufacturing is cost-effective by allowing the use of "dirty" raw materials since the process causes impurities to segregate at multi-grain boundary junctions to form isolated pockets of impurities which do not affect the structural integrity of the material. End uses include use as protective projectile-resistant armor.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: October 11, 1994
    Assignee: Cercom Inc.
    Inventor: Andre Ezis
  • Patent number: 5354534
    Abstract: The invention provides a method for manufacturing sintered parts, which uses as a debinder solvent a substance harmless to the human body and which can enhance the strength of an injection-molded product.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: October 11, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Nobuyuki Kitagawa, Toshio Nomura, Katuyosi Saito
  • Patent number: 5352538
    Abstract: A surface hardened aluminum part having excellent heat resistance and abrasion resistance obtained by forming, on the surface of an aluminum base material, an alloy layer that has a uniform composition and uniform hardness, being free from cracks. An aluminum alloy powder made of aluminum and metals each of which forms an intermetallic compound of high hardness with aluminum is prepared. This aluminum alloy powder is supplied onto the aluminum base material and the aluminum or aluminum alloy contained in the aluminum base material is alloyed with the aluminum alloy powder using a high-density energy heat source to form an alloy layer. The alloy layer thus formed has an intermetallic compound of high hardness uniformly distributed throughout the layer so that the hardness of the alloy layer is uniform and cracking is unlikely to occur.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: October 4, 1994
    Assignee: Komatsu Ltd.
    Inventors: Toshihide Takeda, Kaoru Adachi
  • Patent number: 5342571
    Abstract: Dual phase sputter targets consisting essentially of TiN and Al, methods of manufacture thereof, and cathodic sputtering methods using such targets are disclosed. The targets are prepared by blending TiN and Al powders followed by compaction to full density. The thus compacted materials are optionally sintered and are then formed into the desired target shape. The targets are used in cathodic sputtering processes to form opaque, dark colored decorative and wear resistant coatings.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: August 30, 1994
    Assignee: Tosoh SMD, Inc.
    Inventors: Mark B. Dittmar, Paul E. Scheiderer
  • Patent number: 5340532
    Abstract: A method for manufacturing a sintered body by a) forming a slurry comprising a powder mixture, a dispersant providing steric stabilization for the powders and an organic solvent with a possible addition of one or more soluble polymers; b) transferring the slurry into a mold; and c) changing the temperature sufficient to cause gelation of the sterically stabilized suspension to form a green body. The method also includes d) removing the green body from the mold; e) transferring the green body to a chamber where the gelation temperature can be maintained and the pressure decreased to facilitate removal of the solvent to form a dried body; f) heating the body for a time sufficient to substantially remove the dispersant from the body and; g) sintering the body. The sintered body can be an insert for metal cutting tools.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: August 23, 1994
    Assignee: Sandvik AB
    Inventor: Lennart Bergstrom