Abstract: Master alloys and methods of producing same are disclosed, wherein an intermetallic compound, for example Al.sub.3 Cb is first prepared via thermite processing, then size reduced, then mixed with other components in amounts yielding a mixture in the desired proportion for the master alloy. The mixture is compacted, then heated to produce the master alloy by fusion.

Abstract: Fatigue crack growth-resistant articles are made from powder metal or cast and wrought gamma prime precipitation strengthened nickel-base superalloy material, wherein a relatively high predetermined minimum strain rate, .epsilon..sub.min, is employed during hot working at or near the alloy's recrystallization temperature; or alternatively a relatively high strain level, .epsilon..sub.min, is employed during cold or warm working at temperatures below the alloy's recrystallization temperature. The worked articles are characterized by a uniform fine grain size, and grains which coarsen uniformly after heating at the supersolvus solutioning temperature, thereby alleviating non-uniform grain growth within the material.

Abstract: Disclosed is a manufacturing process of an alloy material comprising a chromium component and a base component which comprises at least one element selected from tile group consisting of copper and silver, the manufacturing process comprising steps of: subjecting a chromium material with a carbon material to heat treatment; and manufacturing the alloy material using the chromium material treated at the heat treatment subjecting step and a raw material for tile base component. At the heat treatment subjecting step, the chromium material, mixed with 50 ppm to 5,000 ppm of the carbon material, is heated to a temperature within the range of 800.degree. C. to 1,400.degree. C. in a non-oxidizing atmosphere. According to this manufacturing process, the level of oxygen content in the alloy material are decreased to be not more than 200 ppm. The obtained alloy material can be used as a contact material for vacuum circuit breakers.

Abstract: Disclosed is a stainless steel member with a high corrosion resistance suitable for a structural member used in highly corrosive environments, such as an edge seal plate of a molten carbonate fuel cell. This stainless steel member includes a base material consisting of stainless steel containing chromium, and a corrosion-protective layer formed on the surface of the base material. In this corrosion-protective layer, a granular heterophase containing chromium is precipitated in an ordered alloy consisting of aluminum and the constituent elements of the base material.

Abstract: Master alloys and methods of producing same are disclosed, wherein an intermetallic compound is first prepared via thermite processing, then size reduced, then mixed with other components in amounts yielding a mixture in the desired proportion for the master alloy. The mixture is compacted, then heated to produce the master alloy, which is used for making Nickel-based alloys used, (for example), in hydrogen battery electrodes.

Abstract: There is now provided a method of manufacturing a sintered body of titanium-based carbonitride alloy comprising hard constituents in 5-25% binder phase where the hard constituents contain, in addition to Ti, one or more of the metals V, Nb, Ta, Cr, Mo or W and the binder phase is based on cobalt and/or nickel by powder metallurgical methods, i.e., milling, pressing and sintering. The composition of the hard constituents is:0.88<a<0.96;0.04<b<0.08;0.ltoreq.c<0.04;0.ltoreq.d<0.04;0.60<f<0.73;0.80<x<0.90; and0.31<h<0.40.and the overall composition of the hard constituents phase is expressed by the formula:(Ti.sub.a,Ta.sub.b,Nb.sub.c,V.sub.d).sub.x (Mo.sub.e,W.sub.f).sub.y (C.sub.g,N.sub.h).sub.z.

Abstract: Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.

Abstract: Porous metal components for high temperature fuel cells which are made by integrating the heretofore employed, separate tape casting and pack cementation processes. Particles of a base metal and a master alloy are suspended in a liquid medium in which a binding agent and a halide activator are dispersed. The suspension is cast into the shape wanted in the component, typically by tape casting; and the cast structure is heated to remove the liquid medium, leaving a flexible, green cast structure commonly referred to as a tape. The green tape is so heated as to: (a) burn out the binder in the tape; (b) form an alloy of the base metal and an alloying metal in the master alloy; and (c) sinter the alloy particles into a porous, coherent metal structure.

Abstract: A titanium-tungsten target material capable of limiting the amount of particles generated during sputtering and a method of manufacturing this titanium-tungsten material. The titanium-tungsten target material has a titanium-tungsten alloy phase which occupies 98% or more of the whole area of the material as observed in a micro-structure thereof. In one example of the manufacturing method, an ingot obtained by melting tungsten and titanium is processde by a solution treatment to form a titanium-tungsten target, or a power obtained by melting the ingot is sintered to form a target. Preferably, the melting may be performed under reduced pressure in an electron beam melting manner. In another example of the manufacturing method, a powder is formed from a molten metal by an atomization method and the obtained powder is sintered to form a titanium-tungsten target. For sintering of the powder, it is preferable to apply hot isostatic pressing or hot pressing.

Abstract: An aluminum-alloy main-starting powder for producing a sintered aluminum-alloy consists of from 0.1 to 3.0% of Cu, the balance being Al and unavoidable impurities. Mother alloy powder consists of from 4 to 20% of Mg, from 12 to 30% of Si, and Al and unavoidable impurities in balance.

Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.

Abstract: Methods are provided for fabricating a sintered and solid element from an otherwise unsinterable material, utilizing the property of that material that it will form an eutectic composition or alloy with a suitable alloying agent at a temperature which is below the plastic deformation temperature of the material. Discrete particles of the material to be sintered--such as grains or wire pieces--are coated with a thin coating of the alloying agent and are packed into the position where they are to be sintered. Then, the coated grains or wire pieces are heated so that at least the coating and the regions of the grains just below the coating are slowly raised in temperature. Diffusion regions of the alloying agent into the grains of the sinterable material will then occur. Further heating continues so that at least the diffusion regions increase in temperature to just slightly above the eutectic melting point.

Abstract: A composite material is provided which includes a discrete phase including grains made of a first substance; and a continuous phase including a thin coating film made of a second substance and formed on the surface of each of the grains. The thin coating film has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film. The porosity of the composite material is 5% or less.

Abstract: A method is described for manufacturing foamable metal bodies in which a ture (17) of a metal powder (15) and a gas-splitting propellent powder (16) is hot-compacted to a semifinished product (19) at a temperature at which the joining of the metal powder particles takes place primarily by diffusion and at a pressure which is sufficiently high to hinder the decomposition of the propellent in such fashion that the metal particles form a solid bond with one another and constitute a gas-tight seal for the gas particles of the propellant. The foamable metal body can also be produced by rolling. In addition, a use of the foamable metal body (19) thus produced for manufacturing a porous metal body (21) is proposed.

Abstract: Pyrophorically activated aluminides of iron, nickel and cobalt, or mixtures thereof, are formed as discs or as coatings on substrates such as thin foils. The aluminide can be formed in situ by reacting aluminum powder with the aluminide-forming metal. Mixtures of these reactants can be applied to a substrate as such or suspended in a liquid like water or volatilizable organic liquids. Water is preferably used with a little binder such as an alkali metal silicate. An inhibitor is used to keep the water from reacting with finely-divided aluminum, and those silicates also perform such function. The pyrophoric products can be discharged to decoy heat-seeking missiles, or they can have their pyrophoricity destroyed to make catalysts. Pyrophoric action can be heightened by additives such as boron, and by post treatment with mild acid.

Abstract: A method is disclosed for preparing an intimate mixture of powders of nickel-boron-silicon alloy and molybdenum metal powder suitable for thermal spray coatings which comprises milling a starting mixture of the alloy and molybdenum powder to produce a milled mixture wherein the average particle size is less than about 10 micrometers in diameter, forming an aqueous slurry of the resulting milled mixture and a binder which can be an ammoniacal molybdate compound or polyvinyl alcohol, and agglomerating the milled mixture and binder. The intimate mixture and binder are preferably sintered in a reducing atmosphere at a temperature of about 800.degree. C. to about 950.degree. C. for a sufficient time to form a sintered partially alloyed mixture wherein the bulk density is greater than about 1.2 g/cc.

Abstract: Process for producing a ductile, high strength, oxide dispersion hardened sintered alloy based on a metal having a high melting point. In the past, oxide dispersion has played only a minor role in comparison with other known processes for increasing strength. The process disclosed permits cost effective production of metallic materials which possess a strength hitherto unattainable by oxide dispersion and a higher ductility than prior art materials. As a result, the metallic and nonmetallic foreign components in the sintered alloy can be restricted to the relatively small quantities of dispersoids and any dissolved residual oxygen. The process consists in an annealing treatment and calls for a specific choice of basis metal and suitable oxide dispersoid.

Abstract: A method of repairing damages in a superalloy component is disclosed wherein existing brazed joints and protective coatings are not harmed. The method entails the use of a silicon-free metal mixture comprising (i) a low melting alloy having a liquidus below the temperature to be used to deposit the metal mixture, (ii) an alloy melting above about 2100.degree. F., and (iii) optionally nickel. The resultant repair has a solidus temperature of at least 1950.degree. F., preferably at least 2000.degree..

Abstract: Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Abstract: The invention relates to a gas sensor for measuring an air-fuel ratio of an air-fuel mixture of an internal combustion engine and to a method of manufacturing the gas sensor. The sensor of the invention comprises: a solid state electrolyte layer made of an oxygen ion conductive metal oxide; a first electrode of a porous thin film having the catalyst function which was coated on one surface of the solid state electrolyte layer; a second electrode of a porous thin film having the catalyst function which was coated on the other surface of the solid state electrolyte layer; an electrode shielding layer made of a sintered material of ultra fine particulates whose average grain diameter is 1 .mu.m or less which covers the surface other than the region of a predetermined area of the second electrode; and a gas diffusion layer made of a porous electric insulative metal oxide which covers the region of the predetermined area of at least the second electrode.

Abstract: To reduce tailing, the frit at the outlet to the liquid chromatographic column has a diameter substantially equal to that of the inside diameter of the outlet end of the column and less than two millimeters. It is held directly against the packing of the column within a cylindrical member having a shoulder with a central aperture at least the size of the diameter of the frit and cylindrical walls which are fastened to resist force in the direction of the axis of the column from its inlet to its outlet. A gasket seals the cylindrical holder against the column wall. The frit is formed of gold-plated nickel spheres sintered together at temperature lower than the gold-nickel eutectic temperature of 950 degrees Celsius but above the phase-immiscibility temperature of 720 degrees Celsius. The size and shape of the frit is selected to reduce tailing by causing the flow path from the column to be uniform.

Abstract: Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Abstract: A sintered hard metal body having improved heat resistance and higher cutting performance is produced by a process including mixing together at least one hard substance, at least one binder material, and at least one of at least one complex carbide and at least one complex nitride to form a starting mixture each constituent of which is in powdered form. The at least one hard substance is selected from the group consisting of carbides, nitrides, and carbonitrides of transition metals of Groups IVB, VB and VIB of the Periodic Table of Elements, is present as at least one of a carbide, a mixed carbide, a nitride, a mixed nitride, a carbonitride, and a mixed carbonitride, and has a cubic crystal form. The at least one binder metal is selected from the group including iron, nickel and cobalt.

Abstract: The quality or durability of an oxidation protective coating produced by alitizing or aluminizing on the surface of a structural component made of titanium or titanium alloy, is improved by adding niobium to the surface of the structural component. The addition may be accomplished prior to the aluminizing or during the aluminizing. Prior application may involve, for example, vapor deposition of the niobium. Simultaneous application involves including a niobium donator powder in the aluminizing powder mixture.

Abstract: A method for producing foil of titanium aluminide is described which comprises providing a preselected quantity of blended powder of chloride free commercially pure elemental titanium, aluminum and other alloying metal(s) in preselected proportions, rolling the blended powder into a green foil, sintering the green foil, and thereafter pressing the sintered foil to full density.

Abstract: A method of producing dispersion hardened metal alloys which incorporate highly reactive metals or their alloys whose oxides are not adapted to be easily reduced. According to the method, the highly reactive metals of their alloys are added as powder particles to a solution of a salt of a reducible metal which is to form a metallic matrix in which the reactive metals or their alloys are to be integrated, after which the solution is atomized to form particles from which the solvent is removed to yield the final product of the metal matrix with the highly reactive metals or their alloys integrated therein as a second phase.

Abstract: The present invention is directed to a process for the synthesis of a compositionally graded substantially amorphous metal alloy comprising:(a) combining a bulk hydrogen storage material with an A-containing material to obtain a mixture thereof;(b) sealing the mixture in a mechanical milling device under an inert atmosphere; and(c) milling the mixture.Alloys produced by this process are useful for the efficient cyclic storage and release of hydrogen in large quantities without becoming embrittled, inactivated or corroded.

Abstract: A diamond composite combined with a cobalt-containing substrate, comprising: a sintered mass of diamond, in which practically all the diamond particles are joined immediately with adjacent particles, a mass of cobalt-containing carbide, said latter mass being larger than the former and said first and latter masses being of a same cross section at the opposed ends, and an intermediate layer of a solid material which consists of Mo, Co and C with a minor proportion of inevitable impurities and which comprises a molybdenum carbide exhibiting a melting point within 200 degrees C. of that of the first said carbide material, said layer intervening between the masses and having a total radial cross sectional area of at least 80% but not greater than 97% of that of the diamond mass and carbide masses at the joint and a thickness of, at least, 25 microns over the whole cross sectional area and method for producing the same.

Abstract: A process is disclosed for producing a sheet of tungsten heavy alloy which involves forming a solution of chemical compounds containing the metal values of the alloy in the correct proportion as in the alloy, crystallizing the compounds from solution and drying the compounds, reducing the compounds to their respective metals wherein each particle is an admixture of the allow components; forming a slurry of the metals and a liquid medium, removing the liquid medium from the metals and forming a planar cake of the metals, drying the cake, and sintering the cake to a density equal to or greater than about 90% of the theoretical density of the alloy to form the sheet.

Abstract: A process is disclosed for producing tungsten heavy alloy sheet. The process comprises crystallizing from solution the compounds of the component metals of the alloy, and drying the compounds, introducing the compounds into a container so that the compounds are loosely and uniformly packed in the container, the container being made of molybdenum coated with a ceramic, and having the same shape as the sheet which is to be made. The compounds are then reduced to their respective metals and the resulting metal powder is sintered to a density equal to or greater than about 90% of the theoretical density of the alloy to form the sheet.

Abstract: A process is disclosed for producing a sheet of tungsten heavy alloy which comprises forming a solution of chemical compounds containing the metal values of the alloy in the correct proportion as in the alloy, forming from the solution a precipitate of the compounds containing the metal values, removing the precipitate from the resulting liquor an forming a planar cake of the precipitate, drying the cake, and reducing the compounds in the cake to their respective metals wherein each of the resulting reduced particles is an admixture of the alloy components and sintering the cake to a density equal to or greater than about 90% of the theoretical density of the alloy to form the sheet.

Abstract: This invention deals with a method of producing a bulk amorphous metal alloy article. The method involves mechanically alloying an amorphous matrix material and a crystalline element which is a fast diffuser in the matrix material to give a powder mixture which is at least 50% but less than 100% amorphous. This powder mixture is then formed into a bulk amorphous metal alloy article by ordinary forming methods such as hot-pressing. The resultant bulk amorphous metal alloy article can be heated above its glass transition temperature to provide a bulk crystalline metal alloy article.

Abstract: Reactive sintering process for producing a shaped body containing the nickel aluminide compound Ni.sub.3 Al, which comprises sintering a compacted shaped mass containing an intimate mixture of substances, e.g. including elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni.sub.3 Al, by heating the mass, e.g. in a vacuum, to an elevated sintering temperature, e.g. 500-750.degree. C., sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering sufficiently to form a densified shaped body containing the nickel aluminide compound Ni.sub.

Abstract: The present invention provides a method of producing a bulk amorphous metal alloy article. The method involves mechanically alloying a matrix metal and a fast diffuser element into a powder mixture consisting of particles having a modulated structure and whereby the powder is at least 50% but less than 100% amorphous. The resultant powder mixture is formed into a bulk amorphous metal alloy article by standard forming methods such as cold or hot-pressing. This bulk article can be further processed into a bulk crystalline metal alloy article by heating at a temperature above the glass transition temperature of the amorphous metal alloy article.

Abstract: A method for sintering a metal powder, a ceramic powder, or a mixture thereof accomplishes compact sintering of even a high melting substance by heating the powder at an elevated temperature for a short time under not less than 10,000 atmospheres of pressure. To attain the quick high-temperature heating under the ultrahigh pressure, a Thermit reaction is generated in an ultrahigh pressure generating apparatus which is provided with a gasket made of pyrophyllite and cylinders and anvils protected with heat insulators.For the purpose of preventing the Thermit reaction from inducing a reaction between the Thermit composition and the powder under treatment and the heater and ensuring electrical insulation of these components, barriers made of hexagonal boron nitride and/or tantalum are suitably disposed within the apparatus.

Abstract: An aluminum matrix composite containing evenly dispersed reinforcement particles in the aluminum matrix wherein the contents of oxygen and carbon are controlled so that their volume percentage is not larger than 20% and wherein the contents of the reinforcement particles, oxygen and carbon are controlled so that their volume percentage is not larger than 40%. The control of oxygen and carbon is effected by carrying out the main process at a non-oxidizing atmosphere and minimizing the addition of an anti-seizure agent required to facilitate the mechanical alloying treatment.

Abstract: A process is disclosed for producing tungsten heavy alloy billets. The process involves forming a uniform blend of elemental powders to form a tungsten alloy having a tungsten content of equal to or less than about 91% by weight and wherein the particle size of the tungsten is no less than about 2 micrometers in diameter. This blend is uniformly packed into a container having thermal expansion similar to that of the powder. The blend is then sintered in a hydrogen atmosphere at a temperature sufficient to impart strength to the powder and to reduce oxides and remove volatile impurities from the powder without significant densification in the powder. The powder is then solid state sintered in a reducing atmosphere at a sufficient temperature to densify the powder to at least about 90% of the theoretical density but at a temperature below the liquid phase sintering temperature of the powder, to form the billet.

Abstract: A method is disclosed for bonding liquid phase sintered metal powder parts of a tungsten alloy containing nickel. The method involves placing a sheet of copper based material between the parts at their adjoining surfaces to join the parts with the sheet covering essentially the entire area of the surfaces, heating the resulting assembly at a temperature sufficient to melt the copper based material without melting the parts, cooling the resulting heated assembly to room temperature, reheating the assembly at a temperature which is high enough to cause diffusion of the copper based material and the matrix alloying elements into one another without melting the parts, and cooling the resulting twice heated assembly.

Abstract: By the inventive method, an amorphous material in powder form can be produced, whereby at least two starting components in powder form are mechanically alloyed by means of a milling process so that a boron component which cannot be alloyed mechanically can nevertheless be alloyed. According to the invention, a boron component in powder form is admixed to the starting components; this powder mixture is subjected to the milling process, an amorphous alloying component being formed from the starting components with embedded or deposited fine particles of the boron components; and the mixture powder so produced is subjected to an annealing treatment below the crystallization temperature of the amorphous alloy component for diffusing the boron into the amorphous alloy component.

Abstract: An alloy of nickel and titanium in the atomic ratio of 49:51 to 56:44 can be prepared at a temperature much lower than the eutectic point of the corresponding alloy. Thus, a green compact of a powdery mixture of the component metals is subjected to a heat treatment under high vacuum first at a rate of temperature elevation of 5.degree. to 30.degree. C./minute up to a temperature of, for example, 600.degree. C. and then at a rate of temperature elevation of at least 40.degree. C./minute up to a temperature of 815.degree.-900.degree. C. The surface of the metal particles is activated at the first stage along with degassing and the surface-activated metal particles are brought into an exothermic reaction at the second stage to cause explosive fusion and alloying.

Abstract: Mill scale, iron ore, or taconite is utilized in a powder metallurgy process to form steel articles having approximately the same density as that of conventional rolled steel. Particulate iron is mixed with manganese, carbon, additional alloying ingredients, and a binder to form a particulate admixture. The particulate admixture is then compressed, preferably under extreme pressure until the density of the compressed particulate admixture is from about 0.2408 lbs/in.sup.3 (6.67 g/cm.sup.3) to about 0.2833 lbs/in.sup.3 (7.83 g/cm.sup.3), which corresponds to a density of from about 85% to about 100% of the density of conventional rolled steel. The resultant coherent mass is subjected to sintering and below fusion heating to form an alloyed article which can be swaged, rolled, drawn, or worked at elevated temperature to decrease the grain size of the alloyed article. The resultant end-product will preferably have a density of from about 0.2408 lbs/in.sup.3 (6.67 g/cm.sup.3) to about 0.2833 lbs/in.sup.3 (7.

Abstract: A reduction process for the production of a product metal which includes the step of reacting at least one reducible metal compound and a reducing metal in a sealed reaction zone by heating the reactants without any substantial agitation from a temperature below the melting point of the reducing metal to a temperature which is both above the melting point of the reducing metal and below the temperature at which the reduction reaction between the metal compound(s) and the reducing metal will proceed spontaneously; initiating a reduction reaction between the reducible metal compound(s) and a molten reducing metal by causing the surface of the molten reducing metal to be suddenly disrupted, thereupon releasing the reaction mixture from said first reaction zone into a product collection zone while permitting the reduction reaction to continue to thereby produce a reduced metal or alloy in zero valent state; and apparatus for conducting the above process.

Abstract: Ag-SnO system alloy electrical contact materials. The Ag alloy before internal oxidation thereof contains Sn of an amount of 5-20 weight %, 0.5-15 weight % of which amount is in the powder form of SnO.sub.2. The existence of SnO.sub.2 particles in the alloy accelerates the internal oxidation speed, allowing oxygen to readily pass aside and between the particles, while the internal oxidation per se makes the alloy more dense by eliminating spaces between SnO.sub.2 grain particles on account of the volumeric expansion of Sn which results from the internal oxidation thereof.

Abstract: Improvements in the positive temperature dependence of yield strength and in the work hardening rate of tri-nickel aluminide base alloys are achieved. The novel alloy composition has seven alloying ingredients as follows:______________________________________ Concentration Ingredient in Atomic % ______________________________________ Ni balance Co 8-12 Al 16-20 Si 4-6 Nb 0.26-0.30 Zr 0.02-0.04 B 0.2-0.7 ______________________________________The novel composition may be prepared by forming a melt of the composition and atomizing the melt with an inert gas to form fine particles with Ll.sub.2 type crystal structure. The powder is densified by heat and pressure to a novel alloy composition having the improvements in positive temperature dependence of yield strength and work hardening rate as noted above.

Abstract: A method for forming intermetallic and intermetallic-type precursor alloys for subsequent mechanical alloying applications. Elemental powders are blended in proportions approximately equal to their respective intermetallic compounds. Heating of the blend results in the formation of intermetallic compounds whereas lack of heating results in intermetallic-type powder without the intermetallic structure. The resultant powder is then blended to form a final alloy. Examples involving aluminum-titanium alloys are discussed.

Abstract: Bulk metastable, amorphous or fine crystalline alloy materials are produced by reacting cold-worked, mechanically deformed filamentary precursors such as metal powder mixtures or intercalated metal foils. Cold-working consolidates the metals, increases the interfacial area, lowers the free energy for reaction, and reduces at least one characteristic dimension of the metals. For example, the grains (13) of powder or the sheets of foil are clad in a container (14) to form a disc (10). The disc (10) is cold-rolled between the nip (16) of rollers (18,20) to form a flattened disc (22). The grains (13) are further elongated by further rolling to form a very thin sheet (26) of a lamellar filamentary structure (FIG. 4) containing filaments having a thickness of less than 0.01 microns.

Abstract: The present invention provides a molybdenum alloy which suitably comprises in the range of from 0.2 to 1.0% by weight of an oxide of a specified metal prepared by adding a salt of the metal in dissolved form to molybdenum and/or a molybdenum oxide or a mixture of different molybdenum components, reducing this mixture at a temperature of up to 1150.degree. C. using hydrogen, pressing the reduced metal without the addition of a binder suitably under a pressure of from 150 to 300 mPA, and sintering the product at a temperature in the range of from 1750.degree. to 2200.degree. C. It is preferable to add salts of zirconium to the molybdenum oxide.

Abstract: A sintered Fe-Cr-Co type magnetic alloy consisting essentially of 20-35% Cr, 3-15% Co and the balance substantially of Fe and a method of producing an article made of the alloy are disclosed. The method comprises the steps of blending at least one of an Fe-Cr powder and Fe-Cr-Co powder with a carbonyl Fe-powder and a Co-powder, if necessary to make up to said alloy composition, to provide a powder blend, the average particle size of said Fe-Cr powder and Fe-Cr-Co powder being 200 mesh or smaller in size, and the surface of these powders having been activated; compacting the resulting powder blend to provide a compact; sintering the resulting compact in an atmosphere in which the total amount of oxygen and nitrogen has been restricted to not more than 3 ppm; and effecting the heat treatment and magnetization of the resulting sintered alloy.

Abstract: A process for the production of valve seat rings by powder metallurgy wherein molybdenum disulfide in the range of about 0.5% to 1.5% by weight is added to a powder mixture containing 0.8% to 1.5% by weight graphite, 1.0% to 4% by weight lead, 0.5% to 5% by weight nickel, 1.2% to 1.8% by weight molybdenum, 9.6% to 14.4% by weight cobalt, and the remainder iron. The resulting powder mixture is pressed into valve seat rings at a pressing force between 40 and 60 and preferably 50 KN/cm.sup.2. The rings are then sintered in a neutral atmosphere at a temperature of 1100.degree. C. to 1200.degree. C., finally compressed at a pressing force above 120 KN/cm.sup.2 and heat-treated if required. The resulting valve seat rings have greatly improved wear properties when used in internal combustion engines using lead-free gasoline.

Abstract: A method of producing .Iadd.permanent magnet material for .Iaddend.high performance permanent magnets is disclosed in which particles of a master alloy consisting of Fe.sub.2 B having a maximum particle size of 50 microns is admixed with Fe powder and particles of a rare earth capable of combining with Fe and B to form a tetragonal compound of Fe.sub.14 R.sub.2 B type. The admixture is compacted and a magnetic material is formed of the master alloy, Fe powder and .[.rate.]. .Iadd.rare .Iaddend.earth particles which includes a major phase of at least one intermetallic compound of the Fe-R-B type having a crystal structure of the substantially tetragonal system and while the particle size of the crystal structure is controlled by sintering the compacted admixture at a temperature of about 700.degree. C. to 1000.degree. C. for from a fraction of an hour to 36 hours. The magnetic material is then annealed at a temperature of about 550.degree. C. to 650.degree. C. for a fraction of an hour to 2 hours.