Molybdenum Or Tungsten Containing Patents (Class 420/448)
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Patent number: 8101122Abstract: The invention includes a turbine cover bucket of an alloy including carbon at less than approximately 0.04 weight percent, manganese at approximately 0.0-0.2 weight percent, silicon at approximately 0.0-0.25 weight percent, phosphorus at approximately 0.0-0.015 weight percent, sulfur at approximately 0.0-0.015 weight percent, chromium from approximately 20.0-23.0 weight percent, molybdenum from approximately 8.5-9.5 weight percent, niobium from approximately 3.25-4 weight percent, tantalum at approximately 0.0-0.05 weight percent, titanium from approximately 0.2-0.4 weight percent, aluminum from approximately 0.15-0.3 weight percent, iron from approximately 3.0-4.5 weight percent, and the remainder being nickel. The alloy is heat treated at 538° C. to 760° C. for up to 100 hours. A method of manufacturing the turbine bucket cover is also provided.Type: GrantFiled: May 6, 2009Date of Patent: January 24, 2012Assignee: General Electric CompanyInventor: Jeffrey Allen Hawk
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Patent number: 8066938Abstract: A wrought age-hardenable nickel-chromium-cobalt based alloy suitable for use in high temperature gas turbine transition ducts possessing a combination of three specific key properties, namely resistance to strain age cracking, good thermal stability, and good creep-rupture strength contains in weight percent 17 to 22 chromium, 8 to 15 cobalt, 4.0 to 9.1 molybdenum, up to 7 tungsten, 1.39 to 1.65 aluminum, 1.50 to 2.30 titanium, up to 0.80 niobium, 0.01 to 0.2 carbon, up to 0.01 boron, up to 3 iron, up to 1.5 tantalum and less than 0.02 zirconium, with a balance of nickel and impurities. Certain alloying elements must be present in amounts according to two equations here disclosed.Type: GrantFiled: June 13, 2006Date of Patent: November 29, 2011Assignee: Haynes International, Inc.Inventor: Lee M. Pike, Jr.
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Publication number: 20110240715Abstract: A nickel-based alloy and welding processes and consumables that use the alloy as a weld filler metal to fabricate, weld overlay, and repair components, including components of nuclear power plant reactors that contact the hot coolant water of the reactor. The nickel-based alloy consists of, by weight, 26 to about 30% chromium, 2 to about 4% iron, 2 to about 4% manganese, 2 to about 3% niobium, 1 to about 3% molybdenum, not more than 0.6% titanium, not more than 0.03% carbon, not more than 0.05% nitrogen, not more than 0.6% aluminum, not more than 0.5% silicon, not more than 0.01% copper, not more than 0.02% phosphorus, not more than 0.01% sulfur, with the balance nickel and incidental impurities.Type: ApplicationFiled: March 31, 2010Publication date: October 6, 2011Applicants: GE-Hitachi Nuclear Energy Americas LLC, The Tokyo Electric Power CompanyInventors: Raul Basilio Rebak, Peter Louis Andresen, Martin Mathew Morra, Suguru Oki, Hideshi Tezuka
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Publication number: 20110206553Abstract: A nickel-base alloy having favorable toughness and thermal fatigue resistance comprises, in weight percentages based on total alloy weight: 9 to 12 chromium; 25 to 35 iron; 1 to 3 molybdenum; 3.0 to 5.5 niobium; 0.2 to 2.0 aluminum; 0.3 to 3.0 titanium; less than 0.10 carbon; no more than 0.01 boron; nickel; and incidental impurities. Also disclosed are die casting dies, other tooling, and other articles of manufacture made from or comprising the nickel-base alloy.Type: ApplicationFiled: May 5, 2011Publication date: August 25, 2011Applicant: ATI Properties, Inc.Inventors: Wei-Di Cao, Richard L. Kennedy, Michael M. Antony, John W. Smythe
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Patent number: 7985304Abstract: A nickel-base alloy having favorable toughness and thermal fatigue resistance comprises, in weight percentages based on total alloy weight: 9 to 20 chromium; 25 to 35 iron; 1 to 3 molybdenum; 3.0 to 5.5 niobium; 0.2 to 2.0 aluminum; 0.3 to 3.0 titanium; less than 0.10 carbon; no more than 0.01 boron; nickel; and incidental impurities. Also disclosed are die casting dies, other tooling, and other articles of manufacture made from or comprising the nickel-base alloy.Type: GrantFiled: April 19, 2007Date of Patent: July 26, 2011Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Richard L. Kennedy, Michael M. Antony, John W. Smythe
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Publication number: 20110165432Abstract: A powder metallurgical article and process are disclosed. The article is a repaired or enlarged powder metallurgical article. The repaired or enlarged powder metallurgical article includes a formed article including a first alloy and a material including a second alloy. The material is welded to the formed article to form the repaired or enlarged powder metallurgical article. The repaired or enlarged powder metallurgical article includes a substantially uniform grain structure.Type: ApplicationFiled: January 4, 2010Publication date: July 7, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Daniel Anthony NOWAK, Raymond Joseph STONITSCH, Attila SZABO
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Publication number: 20110158844Abstract: This ring-shaped disk for a gas turbine includes a ring-shaped disk material consisting of a Ni-based alloy, wherein the Ni-based alloy has a composition that includes, in terms of percent by mass, Ni: 50.00 to 55.00%, Cr: 17.0 to 21.0%, Nb: 4.75 to 5.60%, Mo: 2.8 to 3.3%, Ti: 0.65 to 1.15%, Al: 0.20 to 0.80%, and C: 0.01 to 0.08%, with the balance being Fe and inevitable impurities, and has a microstructure in which ? phase particles are distributed in a matrix thereof, and wherein, in the microstructure, flattened ? phase particles of which maximum length directions are oriented at angles within a range of 60 to 120° with respect to a radial direction of the ring-shaped disk material are present in an amount of 60% or more of a total amount of the ? phase particles distributed in the matrix.Type: ApplicationFiled: May 8, 2009Publication date: June 30, 2011Inventors: Jun Ohsone, Akira Mitsuhashi, Takanori Matsui, Yuji Ishiwari
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Publication number: 20110142713Abstract: Disclosed is a welding material for a Ni-based alloy, comprising components expressed as follows: C?0.05 mass %; 8 mass %?Cr?25 mass %; Fe?4.0 mass %; W?15 mass %; 5 mass %?Mo+½(W+Re)?20 mass %; Co?20 mass %; 0.01 mass %?Al<2.0 mass %; 0.01 mass %?Ti<2.0 mass %; Al+½Ti?3.0 mass %; Nb+½Ta?1.5 mass %; B?0.007 mass %; Zr?0.04 mass %; 0.01 mass %?Si?0.5 mass %; Mn?1.0 mass %; P?0.010 mass %; S?0.002 mass %; O?0.005 mass %; and Ni and unavoidable impurities which constitute the balance.Type: ApplicationFiled: June 29, 2009Publication date: June 16, 2011Inventors: Kenji Kawasaki, Ryuichi Yamamoto, Yoshikuni Kadoya, Shin Nishimoto, Seiichi Kawaguchi
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Publication number: 20110120597Abstract: Low rhenium nickel base superalloy compositions and articles formed from the superalloy composition are provided. The nickel base superalloy composition includes in percentages by weight: about 5-8 Cr; about 6.5-9 Co; about 1.3-2.5 Mo; about 4.8-6.8 W; about 6.0-7.0 Ta; if present, up to about 0.5 Ti; about 6.0-6.4 Al; about 1-2.3 Re; if present, up to about 0.6 Hf; if present, up to about 0-1.5 C; if present, up to about 0.015 B; the balance being nickel and incidental impurities. Exemplary compositions are characterized by an Re ratio defined as the weight % of Re relative to the total of the weight % of W and the wt % of Mo, of less than about 0.3. Exemplary articles include airfoils for gas turbine engine blades or vanes, nozzles, shrouds, and splash plates.Type: ApplicationFiled: December 26, 2007Publication date: May 26, 2011Inventors: Kevin Swayne O'Hara, Laura Jill Carroll
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Patent number: 7922969Abstract: The corrosion-resistant nickel-base alloy combines thermal stability with corrosion resistance and mechanical strength. The alloy contains balanced proportions of nickel, molybdenum, chromium, and iron with an effective amount of yttrium to stabilize grain boundaries against unwanted reactions, which might degrade corrosion resistance, and an effective amount of boron to maintain an acceptable level of ductility. The alloy may contain minor amounts of additives or impurities, such as silicon, manganese, and aluminum. The alloy may contain between about 25-45% molybdenum, 2-6% chromium, 2-4% iron, 0.01-0.03% boron, 0.005-0.015% yttrium, and up to a maximum of 1% manganese, silicon, and aluminum, respectively, by weight, the balance being nickel. It is preferred that the combined ratio of molybdenum, chromium, and iron to nickel be in the range of about 25% to 45%.Type: GrantFiled: June 28, 2007Date of Patent: April 12, 2011Assignee: King Fahd University of Petroleum and MineralsInventor: Hani M. Tawancy
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Publication number: 20110076180Abstract: Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit creep and oxidation resistance substantially equivalent to or better than rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 ?m, if need be, so that further improvements in mechanical properties in the articles can be seen.Type: ApplicationFiled: September 30, 2009Publication date: March 31, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Akane Suzuki, Michael Francis Xavier Gigliotti, JR., Shyh-Chin Huang, Pazhayannur Ramanathan Subramanian
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Publication number: 20110076179Abstract: A nickel-base superalloy composition including (measured in % by weight) from about 6.8 to about 7.5% aluminum, from about 4 to about 8% tantalum, from about 4 to about 10% chromium, from about 2 to about 7% tungsten, from 0 to about 6% rhenium, from 0 to about 5% cobalt, from 0 to about 0.2% silicon, optionally, from about 0.15 to about 0.7% hafnium, from 0 to about 0.5% titanium, from 0 to about 4% molybdenum, from 0 to about 0.005% boron, from 0 to about 0.06% carbon, from 0 to about 0.03% of a rare earth addition selected from the group consisting of yttrium, lanthanum, cesium, and combinations thereof, balance nickel and incidental impurities. The nickel-base superalloy composition may be used in single-crystal or directionally solidified superalloy articles such as high pressure turbine blades for a gas turbine engine.Type: ApplicationFiled: March 24, 2009Publication date: March 31, 2011Inventors: Kevin Swayne O'Hara, Laura Jill Carroll
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Publication number: 20110076182Abstract: Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit creep resistance substantially equivalent to rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 ?m, if need be, so that further improvements in mechanical properties in the articles can be seen.Type: ApplicationFiled: September 30, 2009Publication date: March 31, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Akane Suzuki, Michael Francis Xavier Gigliotti, JR., Shyh-Chin Huang, Pazhayannur Ramanathan Subramanian
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Publication number: 20110076181Abstract: Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit oxidation resistance better than or comparable to rhenium-bearing single-crystal alloys, and creep rupture life comparable to rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 ?m, if need be, so that further improvements in mechanical properties in the articles can be seen.Type: ApplicationFiled: September 30, 2009Publication date: March 31, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Akane Suzuki, Michael Francis Xavier Gigliotti, Jr., Shyh-Chin Huang, Pazhayannur Ramanathan Subramanian
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Publication number: 20110062220Abstract: A nickel-base composition is disclosed that includes: about 15 to about 20 wt % Co; about 10 to about 19 wt % Cr; about 2.5 to about 3.4 wt % Al; less than about 0.5 wt % Ta; less than about 1.0 wt % Mo; less than about 0.06 wt % Zr; less than about 0.04 wt % B; about 1.1 to about 1.5 wt % Nb; about 3.0 to about 3.9 wt % Ti; about 3 to about 5 wt. % W; about 0.03 to about 0.07 wt. % C; and balance Ni; wherein aluminum, titanium, niobium, and tantalum are present within the alloy in a combined amount of 9 to 14 atomic percent.Type: ApplicationFiled: September 15, 2009Publication date: March 17, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Ganjiang Feng, Michael Douglas Arnett, Daniel Anthony Nowak
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Publication number: 20110058954Abstract: A nickel base alloy is provided which includes the following components by weight: Co: 2.75 to 3.25% Cr: 11.5 to 12.5% Mo: 2.75 to 3.25% Al: 3.75 to 4.25% Ti: 4.1 to 4.9% Ta: 1.75 to 2.25% C: 0.006 to 0.04% B: ?0.01% Zr: ?0.01% Hf: ?1.25% Nb: ?1.25% balance Ni.Type: ApplicationFiled: February 27, 2009Publication date: March 10, 2011Inventor: Magnus Hasselqvist
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Publication number: 20110058977Abstract: A Ni based cast alloy consisting essentially of C: 0.01 to 0.2% by weight, Si: 0.5 to 4.0% by weight, Cr: 14 to 22% by weight, Mo+W: 4.0 to 10% by weight, B: 0.001 to 0.02% by weight, Co: up to 10% by weight, Al: up to 0.5% by weight, Ti: up to 0.5% by weight, Nb: up to 5.0% by weight, Fe: up to 10% by weight, the balance being Ni and incidental impurities, wherein a ?? phase precipitates in a matrix phase thereof.Type: ApplicationFiled: August 27, 2010Publication date: March 10, 2011Inventors: Jun Sato, Shinya Imano, Hiroyuki Doi
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Publication number: 20110052443Abstract: Nickel based alloys are provided comprising from about 7.0 weight percent (wt %) to about 12.0 wt % chromium, from about 0.1 wt % to about 5 wt % molybdenum, from about 0.2 wt % to about 4.5 wt % titanium, from about 4 wt % to about 6 wt % aluminum, from about 3 wt % to about 4.9 wt % cobalt, from about 6.0 wt % to about 9.0 wt % tungsten, from about 4.0 wt % to about 6.5 wt % tantalum, from about 0.05 wt % to about 0.6 wt % hafnium, up to about 1.0 wt % niobium, up to about 0.02 wt % boron, and up to about 0.1 wt % carbon, with the remainder being nickel and incidental impurities. The alloys may be cast, directionally solidified and heat treated to provide articles having a gamma prime fraction of greater than about 50%.Type: ApplicationFiled: August 31, 2009Publication date: March 3, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Timothy Hanlon, Richard DiDomizio, Michael Francis Henry, Akane Suzuki, Arthur Samuel Peck, Stephen Joseph Balsone
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Patent number: 7887748Abstract: The invention relates to a method for repairing components that consist of superalloys, in particular for repairing components that consist of a superalloy with an aligned microstructure in such a way that the repaired site likewise has an aligned microstructure. The method comprises the following steps: a solder material is applied to the repair site; the repair site with the applied solder material is heated until the latter melts; and the melted solder material is left to solidify. The solder material is an alloy with the same alloy components as the component alloy. At least the fraction of one alloy component in the solder material composition is modified in relation to the fraction of that alloy component in the component alloy composition, in such a way that the melting temperature of the solder material is reduced in relation to the melting temperature of the component alloy.Type: GrantFiled: October 31, 2006Date of Patent: February 15, 2011Assignees: Siemens Aktiengesellschaft, MTU Aero Engines GmbHInventor: Andreas Volek
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Publication number: 20110011500Abstract: A Ni—Fe—Cr—Mo alloy containing a small amount of Cu and correlated percentages of Nb, Ti and Al to develop a unique microstructure to produce 145 ksi minimum yield strength. The unique microstructure is obtained by special annealing and age hardening conditions, by virtue of which the alloy has an attractive combination of yield strength, impact strength, ductility, corrosion resistance, thermal stability and formability, and is especially suited for corrosive oil well applications that contain gaseous mixtures of carbon dioxide and hydrogen sulfide. The alloy comprises in weight percent the following: 0-15% Fe, 18-24% Cr, 3-9% Mo, 0.05 3.0% Cu, 3.6-6.5% Nb, 0.5-2.2% Ti, 0.05-1.0% Al, 0.005-0.040% C, balance Ni plus incidental impurities and a ratio of Nb/(Al+Ti) in the range of 2.5-7.5. To facilitate formability, the composition range of the alloy is balanced to be Laves phase free.Type: ApplicationFiled: November 18, 2008Publication date: January 20, 2011Applicant: HUNTINGTON ALLOYS CORPORATIONInventor: Sarwan Kumar Mannan
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Publication number: 20100329876Abstract: Gamma prime nickel-base superalloy and components formed therefrom. The alloy contains, by weight, 11.3 to 13.3% cobalt, 12.4 to 15.2% chromium, 2.1 to 2.7% aluminum, 3.6 to 5.8% titanium, 3.5 to 4.5% tungsten, 3.1 to 3.8% molybdenum, 0.0 to 1.2% niobium, 0.0 to 2.3% tantalum, 0.0 to 0.5% hafnium, 0.040 to 0.100% carbon, 0.010 to 0.046% boron, 0.030 to 0.080% zirconium, the balance nickel and impurities, wherein the Nb+Ta content is 0.0-3.5%.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Kenneth Rees Bain, David Paul Mourer
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Publication number: 20100310412Abstract: Austentic heat-resistant nickel-base alloy comprising (in % by mass) 0.03-0.1% of C, 28-32% of Cr, 0.01-<0.5% of Mn, 0.01-<0.3% of Si, 0.01-<1.0% of Mo, 2.5-3.2% of Ti, 0.01-<0.5% of Nb, 0.01-<0.5% of Cu, 0.05-<2.0% of Fe, 0.7-1.0% of Al, 0.001-<0.03% of Mg, 0.01-<1.0% of Co, 0.01-0.10% of Hf, 0.01-0.10% of Zr, 0.002-0.02% of B, 0.001-0.01% of N, max. 0.01% of 5, max. 0.005% of Pb, max. 0.0005% of Bi, max. 0.01% of Ag, balance Ni and minor components due to the production method, where the sum of Ti +Al is from 3.3 to 4.3%, the sum of C+(10×B) is from 0.05 to 0.2%, the sum of Hf+Zr is from 0.05 to 0.15%, the Ti/Al ratio is >3 and Zr/Hf is 0.1 to 0.5.Type: ApplicationFiled: November 25, 2008Publication date: December 9, 2010Inventors: Jutta Kloewer, Bernd De Boer, Dietmar Schlager
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Publication number: 20100303665Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 16.0 to 30.0% cobalt, 11.5 to 15.0% chromium, 4.0 to 6.0% tantalum, 2.0 to 4.0% aluminum, 1.5 to 6.0% titanium, up to 5.0% tungsten, 1.0 to 7.0% molybdenum, up to 3.5% niobium, up to 1.0% hafnium, 0.02 to 0.20% carbon, 0.01 to 0.05% boron, 0.02 to 0.10% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.5 to 2.0.Type: ApplicationFiled: May 29, 2009Publication date: December 2, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Kenneth Rees Bain, David Paul Mourer, Richard DiDomizio, Timothy Hanlon, Laurent Cretegny, Andrew Ezekiel Wessman
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Publication number: 20100303666Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 18.0 to 30.0% cobalt, 11.4 to 16.0% chromium, up to 6.0% tantalum, 2.5 to 3.5% aluminum, 2.5 to 4.0% titanium, 5.5 to 7.5% molybdenum, up to 2.0% niobium, up to 2.0% hafnium, 0.04 to 0.20% carbon, 0.01 to 0.05% boron, 0.03 to 0.09% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.71 to 1.60.Type: ApplicationFiled: May 29, 2009Publication date: December 2, 2010Applicant: General Electric CompanyInventors: Kenneth Rees Bain, David Paul Mourer, Richard DiDomizio, Timothy Hanlon, Laurent Cretegny, Andrew Ezekiel Wessman
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Publication number: 20100284850Abstract: The invention includes a turbine cover bucket of an alloy including carbon at less than approximately 0.04 weight percent, manganese at approximately 0.0-0.2 weight percent, silicon at approximately 0.0-0.25 weight percent, phosphorus at approximately 0.0-0.015 weight percent, sulfur at approximately 0.0-0.015 weight percent, chromium from approximately 20.0-23.0 weight percent, molybdenum from approximately 8.5-9.5 weight percent, niobium from approximately 3.25-4 weight percent, tantalum at approximately 0.0-0.05 weight percent, titanium from approximately 0.2-0.4 weight percent, aluminum from approximately 0.15-0.3 weight percent, iron from approximately 3.0-4.5 weight percent, and the remainder being nickel. The alloy is heat treated at 538° C. to 760° C. for up to 100 hours. A method of manufacturing the turbine bucket cover is also provided.Type: ApplicationFiled: May 6, 2009Publication date: November 11, 2010Applicant: GENERAL ELECTRIC COMPANYInventor: Jeffrey Allen Hawk
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Publication number: 20100254822Abstract: A nickel-base superalloy composition including (measured in % by weight) from about 6.5 to about 7.5% aluminum, from about 4 to about 8% tantalum, from about 3 to about 10% chromium, from about 2 to about 7% tungsten, from 0 to about 4% molybdenum, from 0 to about 6% rhenium, from 0 to less than about 0.001% niobium, from 0 to about 5% cobalt, from 0 to about 0.2% silicon, from 0 to about 0.06% carbon, optionally, from 0 to about 0.5% titanium, from 0 to about 0.005% boron, from about 0.15 to about 0.7% hafnium, from 0 to about 0.03% of a rare earth addition selected from the group consisting of yttrium, lanthanum, cesium, and combinations thereof, balance nickel and incidental impurities. The nickel-base superalloy composition may be used in single-crystal or directionally solidified superalloy articles such as high pressure turbine blades for a gas turbine engine.Type: ApplicationFiled: September 30, 2009Publication date: October 7, 2010Inventors: Brian Thomas Hazel, Kevin Swayne O'Hara, Laura Jill Carroll
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Patent number: 7799271Abstract: Nickel base alloys for use in applications for highly corrosive and abrasive environments. The alloys contain a large volume fraction of metallic carbide particles that provide wear and abrasion resistance. The alloys are produced by induction melting and gas atomization to form alloy powder particles. The particles are consolidated by hot isostatic pressing to form a solid article.Type: GrantFiled: May 23, 2007Date of Patent: September 21, 2010Assignee: Compaction & Research Acquisition LLCInventor: Andrzej L. Wojcieszynski
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Patent number: 7789288Abstract: A process and braze paste suitable for filling and closing voids in relatively thin wall sections of high temperature components, such as an impingement plate of a combustor of a gas turbine engine. The process entails applying at least a first braze paste to the crack to form a braze paste patch comprising powders of first and second alloys and an organic binder. The first alloy has a higher melting temperature than the second alloy, and the powders of the first and second alloys are present in the braze paste patch at a weight ratio of about 30:70 to about 70:30 weight percent. The braze paste patch is then heated to burn off the binder and melt at least the powder of the second alloy to form a brazement within the crack that contains particles of the first alloy dispersed in a matrix formed by the second alloy.Type: GrantFiled: July 31, 2009Date of Patent: September 7, 2010Assignee: General Electric CompanyInventors: Jere A. Johnson, Timothy Channel
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Publication number: 20100196191Abstract: Nickel-base superalloys are provided. In an embodiment, a nickel-base superalloy includes a concentration of large radius elements disposed in the gamma phase of the nickel-base superalloy in a range of from about 3.6 to about 6.7, by atomic percent and a concentration of large radius elements disposed in the gamma prime phase of the nickel-base superalloy in a range of from about 4.2 to about 7.0, by atomic percent. The nickel-base superalloy has a density of about 9.0 grams per centimeter3 or less.Type: ApplicationFiled: February 5, 2009Publication date: August 5, 2010Applicant: HONEYWELL INTERNATIONAL INC.Inventor: Tom STRANGMAN
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Publication number: 20100166594Abstract: An austenitic heat resistant alloy, which comprises, by mass percent, C?0.15%, Si?2%, Mn?3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti?3%, Al?3%, N?0.03%, O?0.03%, with the balance being Fe and impurities, and among the impurities P?0.04%, S?0.03%, Sn?0.1%, As?0.01%, Zn?0.01%, Pb?0.01% and Sb?0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}?0.050], [0.2?P2=Ti+2Al?7.5?10×P1], [P2?9.0?100×O] and [N?0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on.Type: ApplicationFiled: December 24, 2009Publication date: July 1, 2010Inventors: Hiroyuki Hirata, Atsuro Iseda, Hirokazu Okada, Hiroyuki Semba, Kaori Kawano, Osamu Miyahara
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Publication number: 20100158682Abstract: A Ni-based alloy for a casting part of a steam turbine having excellent high temperature strength, castability and weldability includes, in percentage by mass, 0.01 to 0.15 of C, 18 to 28 of Cr, 10 to 15 of Co, 8 to 12 of Mo, 1.5 to 2 of Al, 0.1 to 3 of Ti, 0.001 to 0.006 of B, 0.1 to 0.7 of Ta, and the balance of Ni plus unavoidable impurities.Type: ApplicationFiled: December 8, 2009Publication date: June 24, 2010Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Kuniyoshi NEMOTO, Kiyoshi Imai, Yomei Yoshioka, Masayuki Yamada, Shigekazu Miyashita, Takeo Suga, Takeo Takahashi, Kazutaka Ikeda
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Patent number: 7740724Abstract: A method for preventing the formation of cellular gamma prime in nickel-based superalloys comprises the steps of: casting a nickel-based superalloy into a desired article; subjecting the cast article to hot isostatic pressing at a temperature in excess of 2000° F. at a pressure greater than 15,000 psi to close internal pores in the cast article; and avoiding any formation of the cellular gamma prime in the cast article.Type: GrantFiled: October 18, 2006Date of Patent: June 22, 2010Assignee: United Technologies CorporationInventor: Reade R. Clemens
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Publication number: 20100136368Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron, preferably 7.0 to 10.5% iron, less than about 1.0% manganese, preferably 0.05 to 0.35% manganese; about 2.1 to 4.0% niobium plus tantalum, preferably 2.1 to 3.5% niobium plus tantalum, and more preferably 2.2 to 2.8% niobium plus tantalum; 0 to 7.0% molybdenum, preferably 1.0 to 6.5%, and more preferably 3.0 to 5.0% molybdenum; less than 0.50% silicon, preferably 0.05 to 0.30% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron, preferably less than 0.0015% boron, and more preferably less than 0.001% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities.Type: ApplicationFiled: July 19, 2007Publication date: June 3, 2010Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
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Publication number: 20100135847Abstract: A nickel-containing alloy is disclosed. The alloy contains about 1.5 to about 4.5 weight percent aluminum; about 1.5 to about 4.5 weight percent titanium; about 0.8 to about 3 weight percent niobium; about 14 to about 28 weight percent chromium; up to about 0.2 weight percent zirconium; about 10 to about 23 weight percent cobalt; about 1 to about 3 weight percent tungsten; about 0.05 to about 0.2 weight percent carbon, about 0.002 to about 0.012 weight percent boron; and about 40 to about 70 weight percent nickel. The atomic ratio of aluminum to titanium is at least about 0.5. The alloy is also substantially free of tantalum. Related processes and articles are also disclosed.Type: ApplicationFiled: October 21, 2009Publication date: June 3, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Liang Jiang, Ji-Cheng Zhao, Ganjiang Feng
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Publication number: 20100092301Abstract: A component for a high-temperature steam turbine which operates at temperatures above 600° C., especially above 700° C., is formed of a nickel-based alloy. The negative influence of oxidation of the component which is induced by the superheated steam is prevented by the alloy which is used, having the following composition (in % by weight): C: ?0.2 Si: ?1.0 Mn: ?1.0 Cr: 22.0-25.0 Co: 15.0-25.0 Mo: ?3.0 Nb: ?2.0 Al: 1.0-3.0 Ti: 2.0-4.0 Fe: ?2.0 Zr: ?0.2 B: ??0.05 Ni: remainder.Type: ApplicationFiled: October 27, 2008Publication date: April 15, 2010Inventor: Richard Brendon Scarlin
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Publication number: 20100080729Abstract: A nickel-based alloy suitable for casting gas turbine components having a lower density and basic heat treating process while achieving improved strength is disclosed. Multiple embodiments of the alloy are disclosed capable of providing both directionally-solidified and equiaxed castings. Also disclosed is a method of making a cast and heat treated article utilizing the improved nickel-base alloy.Type: ApplicationFiled: July 25, 2006Publication date: April 1, 2010Applicant: Power Systems Manufacturing, LLCInventors: Charles Biondo, J. Page Strohl, Jeffery W. Samuelson, Gerhard E. Fuchs, Stanley T. Wlodek, Ramona T. Wlodek
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Publication number: 20100080730Abstract: A Ni-based superalloy contains 13.1 to 16.0 percent by mass of Cr, 1.0 to 6.8 percent by mass of Co, 3.0 to 3.4 percent by mass of Al, 4.6 to 5.6 percent by mass of Ti, 2.0 to 4.4 percent by mass of Ta, 3.5 to 4.9 percent by mass of W, 0.1 to 0.9 percent by mass of Mo, 0.3 to 1.4 percent by mass of Nb, 0.05 to 0.20 percent by mass of C, and 0.01 to 0.03 percent by mass of B with the remainder being nickel and inevitable impurities. The superalloy excels in corrosion resistance, oxidation resistance, has high strength, and is used in parts of a gas turbine to be used at high temperature. The resulting gas turbine excels in durability.Type: ApplicationFiled: August 19, 2009Publication date: April 1, 2010Inventor: Akira YOSHINARI
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Publication number: 20100047110Abstract: A Ni-base superalloy of the present invention essentially includes, by weight %, Co: 9 to 11%, Cr: 9 to 12%, Mo: up to 1%, W: 6 to 9%, Al: 4 to 5%, Ti: 4 to 5%, Nb: up to 1%, Ta: up to 3%, Hf: 0.5 to 2.5%, Re: up to 3%, C: 0.05 to 0.15%, B: 0.005 to 0.015%, Zr: up to 0.05%, and the balance of Ni and inevitable impurities. This alloy, as a component material of an industrial gas turbine, has an excellent resistance to corrosion at high temperatures to deal with low-quality fuel and a resistance to oxidation at high temperatures and high-temperature strength to deal with improvement in thermal efficiency due to high-temperature demands and can ensure a high yield at a casting process.Type: ApplicationFiled: September 8, 2009Publication date: February 25, 2010Applicants: Kawasaki Jukogyo Kabushiki Kaisha, Independent Administrative Institution National Institute for Materials ScienceInventors: Masahiro Sato, Tsuyoshi Takenaka, Seiya Nitta, Toshiharu Kobayashi, Yutaka Koizumi, Hiroshi Harada
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Publication number: 20100043924Abstract: A method for locally heat-treating a gas turbine engine superalloy article to improve resistance to strain-induced fatigue of the article is disclosed. The method comprises providing a gas turbine engine superalloy article having a gamma prime solvus temperature; and locally over aging only a selected portion of the article to locally improve fatigue resistance at the selected portion of the article, wherein the local over age cycle includes heating at about 843° C. for about 3 to 4 hours.Type: ApplicationFiled: December 18, 2008Publication date: February 25, 2010Inventor: Jon Raymond Groh
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Patent number: 7662740Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.Type: GrantFiled: June 3, 2004Date of Patent: February 16, 2010Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
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Publication number: 20100034692Abstract: An alloy composition and method by which the incidence of freckling can be reduced in castings produced with properties similar to the René N5 nickel-base superalloy. The casting has a unidirectional crystal structure and a composition consisting of, by weight, 6% to 8% chromium, 6% to 9% cobalt, 0% to 2% molybdenum, 4% to 6% tungsten, 6.4% to 6.9% tantalum, 0% to 2% titanium, 5% to 7% aluminum, 2.7% to 3.0% rhenium, 0.3% to 0.7% haffiium, 0.04% to 0.08% carbon, 0.002% to 0.006% boron, 0% to 0.075% yttrium, 0.002% to 0.004% zirconium, the balance being nickel and incidental impurities.Type: ApplicationFiled: August 6, 2008Publication date: February 11, 2010Applicant: General Electric CompanyInventors: Ganjiang Feng, Shyh-Chin Huang, Jian Zheng
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Publication number: 20100028197Abstract: The invention provides nickel-based alloys that are useful in the preparation of articles for applications requiring high mechanical and physical properties, such as high strength and high heat stability, while simultaneously reducing the cost of preparation of the alloys. The invention further provides articles, such as turbine wheels, prepared using the inventive alloys.Type: ApplicationFiled: September 21, 2006Publication date: February 4, 2010Inventor: Mark Heazle
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Publication number: 20100008790Abstract: A composition of matter comprises, in combination, in weight percent: a largest content of nickel; at least 16.0 percent cobalt; and at least 3.0 percent tantalum. The composition may be used in power metallurgical processes to form turbine engine turbine disks.Type: ApplicationFiled: March 30, 2005Publication date: January 14, 2010Inventor: Paul L. Reynolds
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Publication number: 20090321405Abstract: A nickel (Ni), chromium (Cr), cobalt (Co), iron (Fe), molybdenum (Mo), manganese (Mn), aluminum (Al), titanium (Ti), niobium (Nb), silicon (Si) welding alloy, articles made therefrom for use in producing weldments and methods for producing these weldments. The welding alloy contains in % by weight about: 23.5 to 25.5% Cr, 15 to 22% Co, up to 3% Fe, up to 1% Mo, up to 1% Mn, 1.1 to 2.0% Al, 0.8 to 1.8% Ti, 0.8 to 2.2% Nb, 0.05 to 0.28% Si, up to 0.3% Ta, up to 0.3% W, 0.005 to 0.08% C, 0.001 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, up to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities.Type: ApplicationFiled: June 22, 2009Publication date: December 31, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Publication number: 20090317288Abstract: A Ni-base superalloy having a chemical composition comprising Al: 4.5-7.0 wt %, Ta+Nb+Ti: 0.1-4.0 wt %, with Ta being less than 4.0 wt %, Mo: 1.0-8.0 wt %, W: 0.0-10.0 wt %, Re: 2.0-8.0 wt %, Hf: 0.0-1.0 wt %, Cr: 2.0-10.0 wt %, Co: 0.0-15.0 wt %, Ru: 0.0-5.0 wt %, and the balance being Ni and unavoidable impurities, and a method for producing the same are disclosed. The Ni-base superalloy has excellent creep property at high temperature and is suitable for use as a member at high temperature under high stress.Type: ApplicationFiled: March 16, 2007Publication date: December 24, 2009Inventors: Tadaharu Yokokawa, Yutaka Koizumi, Hiroshi Harada, Toshiharu Kobayashi
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Publication number: 20090257908Abstract: A high temperature, high strength Ni—Co—Cr alloy possessing essentially fissure-free weldability for long-life service at 538° C. to 816° C. contains in % by weight about: 23.5 to 25.5% Cr, 15-22% Co, 1.1 to 2.0% Al, 1.0 to 1.8 % Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, less than 0.3% Si, less than 3% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, 0.005% to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities. The strength and stability is assured at 760° C. when the Al/Ti ratio is constrained to between 0.95 and 1.25. Further, the sum of Al+Ti is constrained to between 2.25 and 3.0. The upper limits for Nb and Si are defined by the relationship: (% Nb+0.95)+3.32(% Si)<3.16.Type: ApplicationFiled: April 8, 2009Publication date: October 15, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Patent number: 7597843Abstract: Nickel based superalloys with excellent mechanical strength, corrosion resistance and oxidation resistance, which consist essentially of chromium in an amount of 3 to 7% by weight, cobalt in an amount of 3 to 15% by weight, tungsten in an amount of 4.5 to 8% by weight, rhenium in an amount of 3.3 to 6% by weight, tantalum in an amount of 4 to 8% by weight, titanium in an amount of 0.8 to 2% by weight, aluminum in an amount of 4.5 to 6.5% by weight, ruthenium in an amount of 0.1 to 6%, hafnium in an amount of 0.01 to 0.2% by weight, molybdenum in an amount of less than 0.5% by weight, carbon in an amount 0.06% by weight or less, boron in an amount of 0.01% by weight or less, zirconium in an amount of 0.01% by weight or less, oxygen in an amount of 0.005% by weight or less, nitrogen in an amount of 0.005% by weight or less and inevitable impurities and the balance being nickel.Type: GrantFiled: August 29, 2005Date of Patent: October 6, 2009Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc.Inventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
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Publication number: 20090214379Abstract: Disclosed is a single crystal alloy consisting essentially of, by weight, 0.06-0.09% carbon, 0.016-0.035% B, 0.2-0.4% Hf, 0-0.02% Zr, 6.5-8.5% Cr, 0.4-1.0% Mo, 5.5-9.5% W, 1.2-3.1% Re, 8-10% Ta, 0.3-1.0% Nb, 0-0.4% Ti, 4.7-5.4% Al, 0.5-5.0% Co, 0.1-5% Fe, and the balance of Ni and unavoidable impurities. The alloy is free from solidification cracks during casting a large-sized blade of gas turbines, has grain boundary strength sufficient for assuring the reliability during operation, and further has excellent oxidation resistance to a high combustion gas temperature while having excellent high-temperature strength comparable to that of a conventional single crystal alloy.Type: ApplicationFiled: February 20, 2009Publication date: August 27, 2009Inventors: Akira Yoshinari, Hideki Tamaki
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Publication number: 20090185944Abstract: Single crystal superalloy compositions and components made from such compositions are provided. One composition consists essentially of, in weight percent, from about 4 to about 7 percent chromium; from about 8 to about 12 percent cobalt; from about 1 to about 2.5 percent molybdenum; from about 3 to about 6 percent tungsten; from about 2 to about 4 percent rhenium; from about 5 to about 7 percent aluminum; from about 0 to about 1.5 percent titanium; from about 6 to about 10 percent tantalum; from about 0.08 to about 1.2 percent hafnium; no more than about 0.0002 percent sulfur; no more than about 0.007 percent zirconium; and the balance nickel.Type: ApplicationFiled: January 21, 2008Publication date: July 23, 2009Applicant: HONEYWELL INTERNATIONAL, INC.Inventor: Yiping Hu
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Patent number: H2245Abstract: A precipitation hardenable nickel base alloy that provides a novel combination of elevated temperature strength, ductility, and reduced notch sensitivity at temperatures up to about 1300° F. is described. The alloy contains, in weight percent, about Carbon 0.10 max. Manganese 0.35 max. Silicon 0.2-0.7 Phosphorus 0.03 max. Sulfur 0.015 max. Chromium 12-20 Molybdenum 4 max. Tungsten 6 max. Cobalt 5-12 Iron 14 max. Titanium 0.4-1.4 Aluminum 0.6-2.6 Niobium 3-7 Boron 0.003-0.015 the balance being nickel and usual impurities. An article made from the alloy and a method of making the alloy are also disclosed.Type: GrantFiled: March 12, 2008Date of Patent: August 3, 2010Assignee: CRS Holdings, Inc.Inventors: Karl A. Heck, Richard B. Frank