Manganese Containing Patents (Class 420/480)
  • Patent number: 11473172
    Abstract: A wear-resistant copper-zinc alloy includes in mass %, 28 to 55% Zn, 0.5 to 2% P, and a balance of Cu and unavoidable impurities, and the wear-resistant copper-zinc alloy has an electrical conductivity of 10 to 33% IACS and a hardness of 3.6[Zn]-55 HBW or more, where [Zn] denotes the Zn content in mass %. Alternatively, a wear-resistant copper-zinc alloy includes in mass %, 40 to 55% Zn, 1 to 6% Mn, and a balance of Cu and unavoidable impurities, and the wear-resistant copper-zinc alloy has an electrical conductivity of 10 to 33% IACS and a hardness of 3.6[Zn]-55 HBW or more, where [Zn] denotes the Zn content in mass %.
    Type: Grant
    Filed: August 29, 2019
    Date of Patent: October 18, 2022
    Assignees: IHI CORPORATION, MIYOSHI GOKIN KOGYO CO., LTD.
    Inventors: Masaaki Yamane, Hayao Eguchi, Masato Arai, Yuta Arai, Mutsuki Ishijima, Hideharu Ito, Yoshihito Ogasawara, Shintaro Fujii, Genjiro Hagino
  • Patent number: 11427890
    Abstract: A copper alloy having a high corrosion resistance for a wide range of different lubricants, in particular different base oils and a variation of lubricant additives. The property of a low corrosion tendency for different tribological systems is also combined with good mechanical properties, and a high strength in particular. The alloy has a low wear and coefficient of friction. The lubricant-compatible copper alloy is suitable for producing components that come in contact with lubricant and are exposed to friction stresses, such as gear components, for example synchronizer rings. A method for manufacturing such components and a gear having at least one such component is also disclosed.
    Type: Grant
    Filed: September 28, 2019
    Date of Patent: August 30, 2022
    Assignee: OTTO FUCHS KOMMANDITGESELLSCHAFT
    Inventors: Hermann Gummert, Björn Reetz, Thomas Plett
  • Publication number: 20150071813
    Abstract: A brass alloy is provided having good mechanical properties and castability, and excellent general-purpose properties, while its dezincification corrosion is inhibited. The brass alloy contains 0.4% by mass or more and 3.2% by mass or less of Al; 0.001% by mass or more and 0.3% by mass or less of P; 0.1% by mass or more and 4.5% by mass or less of Bi; 0% by mass or more and 5.5% by mass or less of Ni; 0% by mass or more and 0.5% by mass or less of Mn, Fe, Pb, Sn, Si, Mg, and Cd, respectively; and Zn; the balance being Cu and a trace element or elements. The zinc equivalent (Zneq) calculated from the content of Zn and other elements, and the content of Al (% by mass) satisfy the following Equations (1) and (2): Zneq+1.7×Al?35.0??(1) Zneq?0.45×Al?37.0??(2).
    Type: Application
    Filed: February 21, 2013
    Publication date: March 12, 2015
    Inventors: Hiroshi Yamada, Masaaki Yamamoto
  • Publication number: 20140248175
    Abstract: Disclosed is a leadless free-cutting copper alloy that exhibits superior machinability, cold workability and dezincification resistance and a method for producing the same. The leadless free-cutting copper alloy comprises 56 to 77% by weight of copper (Cu), 0.1 to 3.0% by weight of manganese (Mn), 1.5 to 3.5% by weight of silicon (Si), and the balance of zinc (Zn) and other inevitable impurities, thus exhibiting superior eco-friendliness, machinability, cold workability and dezincification resistance.
    Type: Application
    Filed: July 31, 2012
    Publication date: September 4, 2014
    Applicant: POONGSAN CORPORATION
    Inventors: Beum Jae Lee, Won Hone Kim, Cheol Min Park, Young Re Cho, Min Jae Jeong
  • Patent number: 8580191
    Abstract: The present invention relates to a brass alloy having superior stress corrosion comprising: 59.0-64.0 wt % Cu, 0.6-1.2 wt % Fe, 0.6-1.0 wt % Mn, 0.4-1.0 wt % Bi, 0.6-1.4 wt % Sn, at least one element selected from Al, Cr and B, the balance being Zn and unavoidable impurities, wherein the content of Al is 0.1-0.8 wt %, the content of Cr is 0.01-0.1 wt %, the content of B is 0.001-0.02 wt %. The alloy according to the present invention does not contain toxic elements such as lead and antimony, has superior corrosion resistance and good cuttingability and is suitable for the accessories in the potable water supply systems produced by casting, forging and extruding.
    Type: Grant
    Filed: December 9, 2010
    Date of Patent: November 12, 2013
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Patent number: 8435361
    Abstract: A novel copper-zinc alloy is particularly suited for a valve guide. The copper-zinc alloy contains 59 to 73% copper, 2.7 to 8.3% manganese, 1.5 to 6% aluminum, 0.2 to 4% silicon, 0.2 to 3% iron, 0 to 2% lead, 0 to 2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: May 7, 2013
    Assignee: Diehl Metall Stiftung & Co. KG
    Inventors: Norbert Gaag, Alexander Dehnelt
  • Patent number: 8425697
    Abstract: A tin-free lead-free free-cutting magnesium brass alloy contains 56.0 to 64.0 wt % Cu, 1.05 to about 2.1 wt % Mg, 0.21 to 0.4 wt % P and other elements 0.002 to 0.9 wt % which contain at least two elements selected from Al, Si, Sb, rare earth elements, Ti and B and the balance being Zn with unavoidable impurities, accordingly a cutting percentage of the alloy is at least 80%. The process for producing such alloy is also proposed. The invented alloy is excellent in cuttability, castability, hot and cold workability, corrosion resistance, mechanical properties and weldability and particularly applicable in spare parts, forging and casting which need cutting and grinding process. The cost of necessary metal materials of the invented alloy is lower than lead-free free-cutting bismuth and antimony brass alloy and is equivalent to lead-contained brass alloy.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: April 23, 2013
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Publication number: 20120251382
    Abstract: A lead-free free-cutting corrosion-resistant silicon-bismuth brass alloy, including the following: between 60.0 and 65.0 wt % of Cu, between 0.6 and 1.8 wt % of Si, between 0.2 and 1.5 wt % of Bi, between 0.02 and 0.5 wt % of Al, less than 1.5 wt % of Ni+Mn+Sn, between 0.01 and 0.5 wt % of La—Ce alloy, between 0.002 and 0.02 wt % of B, with the remainder being Zn and inevitable impurities, wherein the total amount of impurities are no more than 0.5 wt %.
    Type: Application
    Filed: September 23, 2011
    Publication date: October 4, 2012
    Applicant: NINGBO XINGAODA ADVANCED METALLIC MATERIALS CO., LTD.
    Inventors: Feng Peng, Baoping Xia, Jianping Liu, Bin Feng, Changshun Zheng, Wenjian Liu
  • Patent number: 8273192
    Abstract: The present invention relates to a lead-free, bismuth-free free-cutting phosphorous brass alloy and its method of manufacture. The alloy comprises: Cu; Zn; 0.59 to 1.6 wt % P; and other elements in the amount of 0.005 to 0.6 wt %, which comprise at least two elements selected from the group consisting of Al, Si, Sb, Sn, Rare earth element (RE), Ti and B, and the balance being unavoidable impurities. The phosphorous brass alloy contains a combined wt % of Cu and Zn of between 97.0 wt % and 99.5 wt %, within which the content of Zn is above 40 wt %. Considering the solid solubility of P in the matrix of copper will be decreased rapidly with the temperature decrease and form the brittle intermetallic compounds Cu3P with Cu, the present invention relies upon P to ensure excellent cuttability of the invented alloy. The invented alloy is reasonably priced, and has excellent cuttability, castability, hot and cold workability, dezincification corrosion resistance, mechanical properties and weldability.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: September 25, 2012
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Publication number: 20120027638
    Abstract: A high-strength copper alloy contains 20 to 45% of zinc, 0.3 to 1.5% of iron, 0.3 to 1.5% of chromium, and a balance of copper, based on mass.
    Type: Application
    Filed: April 16, 2010
    Publication date: February 2, 2012
    Applicant: San-Etsu Metals Co., Ltd.
    Inventors: Yoshiharu Kosaka, Akimichi Kojima, Katsuyoshi Kondoh
  • Patent number: 8097208
    Abstract: A white bronze alloy consisting essentially of, in weight percent, about 0.3-1.5 wt % aluminum, about 0.5-2.0 wt % bismuth, about 61-66 wt % copper, about 0.0-0.5 wt % iron, about 11-15 wt % manganese, about 4.0-6.0 wt % nickel, about 0.5-2.0 wt % tin, and about 16-20 wt % zinc, as well as incidental amounts of impurities. The alloy is expected to have antimicrobial properties which make the alloy desirable for fabrication into food handling equipment and products for hospitals, bathrooms, and kitchens.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: January 17, 2012
    Assignee: G&W Electric Company
    Inventor: Geary R. Smith
  • Publication number: 20100297464
    Abstract: A melt-solidified substance includes melt-solidified portions formed by welding, build-up spray welding, metallizing or fusing. The melt-solidified portions have the alloy composition containing Zr: 0.0005 to 0.05 mass %, P: 0.01 to 0.34 mass %, Cu: the remainder and satisfying the relationship between the contents of P and Zr, [P]/[Zr]=0.3 to 20, and the mean grain size in the macrostructure after melt-solidification is 300 ?m or less. If Fe and/or Ni are contained in the melt-solidified portion as inevitable impurities, the content of Fe or Ni is restricted to be 0.3 mass % or less when either Fe or Ni is contained, and the total content of Fe and Ni is restricted to be 0.4 mass % or less when both Fe and Ni are contained.
    Type: Application
    Filed: September 30, 2005
    Publication date: November 25, 2010
    Applicant: SANBO SHINDO KOGYO KABUSHIKI KAISHA
    Inventor: Keiichiro Oishi
  • Patent number: 7736448
    Abstract: The present invention relates to a nanocrystalline metallic material, particularly to nano-twin copper material with ultrahigh strength and high electrical conductivity and its preparation method. High-purity polycrystalline Cu material with a microstructure of roughly equiaxed submicron-sized grains (300-1000 nm) has been produced by pulsed electrodeposition technique, by which high density of growth-in twins with nano-scale twin spacing were induced in the grains. Inside each grain, there are high densities of growth-in twin lamellae. The twin lamellae with the same orientations are inter-parallel, and the twin spacing ranges from several nanometers to 100 nm with a length of 100-500 nm. This Cu material invented has more excellent performance than existing ones.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: June 15, 2010
    Assignee: Institute of Metal Research Chinese Academy of Sciences
    Inventors: Lei Lu, Xiao Si, Yongfeng Shen, Ke Lu
  • Patent number: 7712965
    Abstract: A piston pin bushing consisting of a brass alloy containing between 30 and 32.2 wt. % zinc. between 1.8 and 2.2 wt. % aluminium, between 1.8 and 2.2 wt. % manganese, between 1.4 an 2.2 wt. % nickel and between 1.4 and 2.0 wt. % iron, in addition to optional contaminant-related constituents with a respective maximum content of 0.2 wt. % and a maximum total content of 1 wt. %, the remaining percentage consisting of copper. The bushing is cut in the form of a longitudinal section from a continuously cast pipe, whose exterior has been previously machined and can be used without being subjected to a forging process following the cutting operation.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: May 11, 2010
    Assignee: KS Gleitlager GmbH
    Inventors: Klaus Deicke, Werner Schubert, Theo Buschenhenke, Reimond Rathje, Heinbert Langner
  • Publication number: 20100061884
    Abstract: Disclosed is a white-colored copper alloy comprising by weight up to 30% zinc, up to 20% manganese, up to 5% nickel with the balance copper. This alloy may have from 6% to 25% zinc, from 4% to 17% manganese, from 0.1% to 3.5% nickel and the balance copper. The balance copper in the alloy may further contain at least one of: up to 0.5% of at least one of the group which consists of Sn, Si, Co, Ti, Cr, Fe, Mg, Zr, and Ag; and up to 0.1% of at least one of the group which consists of P, B, Ca, Ge, Se, Te. It may also contain up to 0.3% Zr by weight. The alloy may have an electrical conductivity greater than 2.5% IACS at eddy current gauge exciting frequencies between 60 kHz and 480 kHz.
    Type: Application
    Filed: September 8, 2009
    Publication date: March 11, 2010
    Applicant: PMX INDUSTRIES INC.
    Inventors: CRAIG CLARK, THOMAS D. JOHNSON, RICHARD PRATT, TIMOTHY SUH
  • Patent number: 7628872
    Abstract: A lead-free free-cutting copper-antimony alloy comprises in percentage by weight: 55 to 65% Cu, 0.3 to 2.0% Sb, 0.2 to 1.0% Mn, at least two elements selected from the group of Ti, Ni, B, Fe, Se, Mg, Si, Sn, P and rare-earth metal in amount of 0.1-1.0%, as well as balance Zn and unavoidable impurities. The brass alloys according to the present invention possess superior cutting property, weldability, corrosion resistance, dezincification resistance and high-temperature-oxidation resistance, and are suitable for use in drinking-water installations, domestic appliances, toy for children, fastener, etc. The process for producing such alloys is also proposed.
    Type: Grant
    Filed: June 11, 2004
    Date of Patent: December 8, 2009
    Assignee: Ningbo Powerway Alloy Material Co., Ltd.
    Inventors: Ming Zhang, Siqi Zhang, Jihua Cai, Haorong Lou, Xiao Xie
  • Publication number: 20090263272
    Abstract: There is provided a brass free from lead (Pb) and possessing excellent machinability, castability, mechanical properties and other properties. A brass consisting of not less than 55% by weight and not more than 75% by weight of copper (Cu), not less than 0.3% by weight and not more than 4.0% by weight of bismuth (Bi), and y % by weight of boron (B) and x % by weight of silicon (Si), y and x satisfying the following requirements: 0?x?2.0, 0?y?0.3, and y>?0.15x+0.015ab, wherein a is 0.2 when Bi is 0.3% by weight ?Bi<0.75% by weight; 0.85 when Bi is 0.75% by weight ?Bi<1.5% by weight; and 1 when Bi is 1.5% by weight ?Bi?4.0% by weight, b is 1 when the apparent content of zinc (Zn) is not less than 37% and less than 41%; and 0.75 when the apparent content of Zn is not less than 41% and not more than 45%, the balance consisting of Zn and unavoidable impurities, is excellent in castability, as well as, for example, in machinability and mechanical properties.
    Type: Application
    Filed: October 1, 2008
    Publication date: October 22, 2009
    Inventor: Toru Uchida
  • Publication number: 20090214380
    Abstract: The present invention relates to a copper alloy, in particular for components which carry media or drinking water, in particular fittings, valves or compression joints and also an advantageous use of the copper alloy and components for lines carrying media or drinking water. It is an object of the present invention to provide a copper alloy which has good corrosion resistance, good castability and mechanical workability and also good mechanical properties and displays good migration values, particularly in respect of the migration of lead and nickel ions into drinking water. The copper alloy provided for this purpose by the present invention comprises from 2% by weight to 4.5% by weight of silicon, from 1 to 15% by weight of zinc and from 0.05% by weight to 2% by weight of manganese. Furthermore, from 0.05 to 0.4% by weight of aluminium and from 0.05 to 2% by weight of tin can optionally be present. As balance, the copper alloy contains copper and unavoidable impurities.
    Type: Application
    Filed: December 13, 2006
    Publication date: August 27, 2009
    Applicants: GEBR. KEMPER GMBH & CO. KG METALLWERKE, JRG GUNZENHAUSER AG, R. NUSSBAUM AG METALLGIESSEREI UND ARMATURENFABRIK, VIEGA GMBH & CO. KG
    Inventors: Katrin Müller, Patrik Zeiter, Frank Leistritz
  • Publication number: 20090092517
    Abstract: A copper alloy extruded material is provided by extruding a copper alloy powder solidified billet and old grain boundaries remain in it.
    Type: Application
    Filed: July 25, 2006
    Publication date: April 9, 2009
    Inventors: Yoshiharu Kosaka, Masanori Okuyama, Akimichi Kojima, Katsuyoshi Kondoh
  • Publication number: 20080298999
    Abstract: The invention relates to a copper alloy which is used for mechanically stressed components which, during operation, are subjected to vibrations and/or impacts to produce the same, and have particularly good mechanical damping properties. The composition of said copper alloy depends upon the utilisation temperature or working temperature of the component. Said copper alloy consists of 2-12 wt.-% manganese, 5-14 wt.-% aluminum and individually or in total 0-18 wt.-% of one or several elements, nickel, iron, cobalt, zinc, silicon, vanadium, niobium, molybdenum, chromium, tungsten, beryllium, lithium, yttrium, cerium, scandium, calcium, titanium, phosphorous, zirconium, boron, nitrogen, carbon, whereby each element does not contain more that 6% and 100 wt.-% copper.
    Type: Application
    Filed: July 27, 2006
    Publication date: December 4, 2008
    Inventors: Hennadiy Zak, Soenke Vogelgesang, Agniezka Mielczarek, Babette Tonn, Werner Riehemann
  • Publication number: 20080283353
    Abstract: A wear-resistant brass alloy is ideally suited for manufacturing a synchronizing ring for use in couplings, brakes, transmissions, etc. The brass alloy contains 55-68% by weight of copper, 0-6% by weight of aluminium, 2-14% by weight of manganese, 0.5-3% by weight of phosphorus, 0-1% by weight of lead, unavoidable impurities and the rest zinc.
    Type: Application
    Filed: August 6, 2008
    Publication date: November 20, 2008
    Applicant: DIEHL METALL STIFTUNG & CO. KG
    Inventors: Meinrad Holderied, Norbert Gaag
  • Publication number: 20080240973
    Abstract: A copper-zinc alloy is particularly suitable for forming synchronizer rings. The novel alloy contains 55 to 75 wt. % copper, 0.1 to 8 wt. % aluminum, 0.3 to 3.5 wt. % iron, 0.5 to 8 wt. % manganese, 0 to less than 5 wt. % nickel, 0 to less than 0.1 wt. % lead, 0 to 3 wt. % tin, 0.3 to 5 wt. % silicon, 0 to less than 0.1 wt. % cobalt, 0 to less than 0.05 wt. % titanium, 0 to less than 0.02 phosphorus, unavoidable impurities and the remainder zinc.
    Type: Application
    Filed: June 5, 2008
    Publication date: October 2, 2008
    Applicant: DIEHL METALL STIFTUNG & CO. KG
    Inventors: Norbert Gaag, Meinrad Holderied, Friedrich Gebhard
  • Patent number: 7354489
    Abstract: A lead-free copper alloy based on Cu—Zn—Si and a method of manufacture thereof. The copper alloy is built on the basis of copper, zinc and silicon without toxic additives and consists of: 70 to 83% Cu, 1 to 5% Si and the further matrix-active elements: 0.01 to 2% Sn, 0.01 to 0.3% Fe and/or Co, 0.01 to 0.3% Ni, 0.01 to 0.3% Mn, the remainder Zn and unavoidable impurities.
    Type: Grant
    Filed: February 26, 2004
    Date of Patent: April 8, 2008
    Assignee: Wieland-Werke AG
    Inventors: Uwe Hofmann, Wolfgang Dannenmann, Doris Humpenoeder-Boegel, legal representative, Monika Breu, Guenter Schmid, Joerg Seeger, Andreas Boegel
  • Patent number: 6632300
    Abstract: A copper alloy having improved stress relaxation resistance is formed from a copper base alloy that consists, by weight, essentially of 1.8%-3.0% iron, 0.01%-1.0% zinc, 0.001 %-0.25% phosphorus, 0.1 %-0.35% magnesium and the balance is copper and unavoidable impurities. When compared to other copper base alloys that include iron, zinc and phosphorous, the disclosed alloy has improved resistance to stress relaxation. In addition, directionality of stress relaxation resistance (where stress relaxation resistance is typically poorer in a transverse strip direction relative to a longitudinal strip direction for a copper alloy that is strengthened by cold rolling) is reduced to being nearly equivalent, regardless of strip direction. The alloy is particularly useful for electronic applications, such as being formed into an electrical connectors.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: October 14, 2003
    Assignee: Olin Corporation
    Inventors: John F. Breedis, Dennis R. Brauer, Peter W. Robinson
  • Patent number: 6413330
    Abstract: A lead-free free-cutting copper alloy having 69 to 79 percent, by weight, of copper; greater than 3 percent, by weight, of silicon; and a remaining percent, by weight, of zinc. The alloy preferable has greater than 3.0 percent and less than or equal to 4.0 percent, by weight, of silicon; and at least one element selected from among 0.02 to 0.4 percent, by weight, of bismuth, 0.02 to 0.4 percent, by weight, of tellurium, and 0.02 to 0.4 percent, by weight, of selenium. The alloy also preferable has at least one element selected from among 0.3 to 3.5 percent, by weight, of tin, 1.0 to 3.5 percent, by weight, of aluminum, and 0.02 to 0.25 percent, by weight, of phosphorus. In further embodiments, the alloy has at least one element selected from among 0.02 to 0.15 percent, by weight, of antimony, and 0.02 to 0.15 percent, by weight, of arsenic.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: July 2, 2002
    Assignee: Sambo Copper Alloy Co., Ltd.
    Inventor: Keiichiro Oishi
  • Patent number: 6340446
    Abstract: A nickel-free white copper alloy represented by the general formula: CuaZnbMncAld or CuaZnbMncAldXe, wherein X is at least one element selected from the group consisting of Si, Ti and Cr; b, c, d and e are 0.5≦b<5, 7≦c≦17, 0.5≦d≦4 and 0<e≦0.3 in terms of % by weight; a is the balance, the alloy incidentally including unavoidable elements. The alloy is free from allergic problems, which may be caused by nickel, and has excellent strength, hardness, ductility, workability and corrosion resistance, suitable for use in elements, sliders, stoppers or the like for slide fasteners, or accessories such as metallic buttons, fasteners or the like for clothes.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: January 22, 2002
    Assignee: YKK Corporation
    Inventors: Kazuhiko Kita, Yasuhiko Sugimoto, Yasuharu Yoshimura, Takahiro Fukuyama
  • Patent number: 6059901
    Abstract: Bismuth bearing copper-nickel-manganese-zinc corrosion and gall resistant castable alloy, particularly for use in food processing machinery, with the following weight percentage range:Nickel=12-28Manganese=12-28Zinc=12-28Aluminum=0.5-2.00Bismuth=2-6Phosphorus=0-0.3Tin =0-1.5Iron=0-1.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: May 9, 2000
    Assignee: Waukesha Foundry, Inc.
    Inventor: Sudhari Sahu
  • Patent number: 5908517
    Abstract: A high-temperature, nickel-free alloy, in particular for spectacle frames, jewelry, etc. with the following composition in percentages by weight:______________________________________ Zn 13.0-16.0% Mn 9.0-11.0% Fe 1.0-2.0% Al 4.0-5.5% Cu the remainder.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: June 1, 1999
    Assignee: Berkenhoff GmbH
    Inventors: Juergen Fackert, Klaus Tauber, Bruno Rechtziegel
  • Patent number: 5658401
    Abstract: A copper-zinc alloy for semi-finished products and articles which are highly loaded and subjected to extreme wear especially synchronizing rings. The alloy possesses a composition of 40 to 65% Cu, 8 to 25% Ni, 2.5 to 5% Si, 0 to 3% Al, 0 to 3% Fe, 0 to 2% Mn and 0 to 2% Pb, with the balance being zinc and unavoidable impurities. The Ni:Si ratio is about 3 to 5:1, and the structure consists of at least 75% .beta.-phase, with the balance .alpha.-phase, in the absence of a .gamma.-phase. Nickel silicides occur predominantly as a round intermetallic phase. The alloy provides quite substantially higher levels of resistance to wear.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: August 19, 1997
    Assignee: Diehl GmbH & Co.
    Inventors: Norbert Gaag, Peter Ruchel
  • Patent number: 5626987
    Abstract: A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula:Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: May 6, 1997
    Assignee: SAFT
    Inventors: Bernard Knosp, Jacques Bouet, Christian Jordy, Michel Mimoun, Daniel Gicquel
  • Patent number: 5489417
    Abstract: Spray cast copper-manganese-zirconium alloys are disclosed. In one embodiment, the alloy is spray cast in nitrogen and contains from about 1 ppm to about 20 ppm of dissolved nitrogen. In a second embodiment, the alloy contains an addition selected from the group consisting of chromium, titanium, erbium and mixtures thereof. The alloys are useful for sound damping as the combination of zirconium and the addition inhibits degradation of the specific damping capacity of the alloy.
    Type: Grant
    Filed: April 14, 1994
    Date of Patent: February 6, 1996
    Assignee: Olin Corporation
    Inventors: William G. Watson, Harvey P. Cheskis, Sankaranarayanan Ashok
  • Patent number: 5487867
    Abstract: A copper based casting alloy in which lead is replaced by 0.1 to 7 wt % bismuth and 0.1 to 2 wt % mischmetal or its rare earth equivalent is used to improve the distribution of bismuth in the alloy. The alloy is further defined by additions of tin, zinc, nickel, manganese, silicon, aluminum, iron and/or antimony.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: January 30, 1996
    Assignee: Federalloy, Inc.
    Inventor: Akhileshwar R. Singh
  • Patent number: 5441696
    Abstract: A copper-nickel based alloy, which comprises 3 to 25 wt % of Ni, 0.1 to 1.5 t % of Mn, 0.0001 to 0.01 wt % of B and the rest being Cu and an unavoidable element.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: August 15, 1995
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Kenji Kubosono, Iwao Asamizu, Masazumi Iwase, Toshihiro Kurita
  • Patent number: 5282908
    Abstract: A Mn-Si-Co-Fe-based high-strength brass alloy comprises, on the weight basis, 15 to 25% of Zn, 1.0 to 5.0% of Mn, 0.3 to 2.0% of Si, 0.01 to 0.5% of Fe, 0.01 to 2.0% of Co, 0.2 to 1.0% of Sn, 5 to 10% of Pb and the balance being Cu and inevitable impurities. The alloy has a novel intermetallic compound [Mn,Si,Co,Fe] substantially in the form of spheroids and has also fine grains. The alloy is adapted for use as sliding members or parts and has very good resistances to wear and corrosion, anti-seizing property and durability.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: February 1, 1994
    Assignee: Chuetsu Metal Works Co., Ltd.
    Inventors: Kunio Nakashima, Takayuki Tanaka, Wataru Yago, Kenzo Yamamoto, Ken-ichi Ichida
  • Patent number: 5270001
    Abstract: An alloy, in particular for use in the manufacture of jewelry, frames for glasses, and the like. In order to be able to manufacture jewelry, frames for glasses, and the like of a nickel-free alloy inexpensively and well, the following alloy has been produced according to the invention, which, in percentages by weight, has the following composition: Cu 86.0-90.0 percent, Al 2.8-4.5 percent, Mn 0.4-1.3 percent, Fe 1.0-2.5 percent, Si 0-0.5 percent, the remainder being Zn.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: December 14, 1993
    Assignee: Berkenhoff GmbH
    Inventors: Bruno Rechtziegel, Wolfgang Brandstaetter, Juergen Fackert, Klaus Tauber
  • Patent number: 5246509
    Abstract: A copper base alloy suitable for use as a material of a sliding member, superior in seizure resistance, wear resistance and corrosion resistance. The alloy comprises 1.0 to 3.5 wt % Mn, 0.3 to 1.5 wt % Si, 11.5 to 25 wt % Zn, 5 to 18 wt % Pb and the balance substantially Cu and incidental impurities, the lead being uniformly distributed through the structure of the alloy. The alloy has a microstructure of which matrix is composed of .alpha.-phase alone. The alloy can further contain at least one selected from the group consisting of 0.02 to 1.5 wt % Mg and 0.1 to 1.5 wt % Te and/or at least one selected from the group consisting of 0.5 to 3.0 wt % Ni and 0.3 to 3.0 wt % Al.
    Type: Grant
    Filed: July 21, 1992
    Date of Patent: September 21, 1993
    Assignee: Daido Metal Company Ltd.
    Inventors: Tohru Kato, Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto
  • Patent number: 5183637
    Abstract: A wear-resistant copper alloy containing 1.2 to 8.5% Mn, 0.3 to 2.5% Si, 3.0 to 8.0% Al, 20 to 40% Zn, 0.05% to 1.5% Te, and the balance of Cu and unavoidable impurities. The alloy includes other variations based on by adding (1) 0.5 to 3% Ni, (2) 0.5 to 13% Pb, (3) 0.5 to 3% Ni and 0.5 to 13% Pb or (4) 0.5 to 13% Pb and 0.02 to 1.5% Mg. Lead provides the self-lubricating property to the alloy. Magnesium disperses lead finely and uniformly in the alloy.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: February 2, 1993
    Assignee: Daido Metal Company Ltd.
    Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tohru Kato
  • Patent number: 5069874
    Abstract: Disclosed herein is a wear-resistance alloy comprising 10 to 40 wt % of Zn, 3 to 10 wt % of Al, 0.1 to 4 wt % of Cr and the balance Cu.
    Type: Grant
    Filed: October 10, 1990
    Date of Patent: December 3, 1991
    Assignee: Oiles Corporation
    Inventors: Takehiro Shirosaki, Takashi Kikkawa, Hirotaka Toshima
  • Patent number: 4995924
    Abstract: A novel synchronizer ring for use in a speed variator that is made of a Cu base alloy and which exhibits good initial accommodation by mating surfaces while ensuring high wear resistance is disclosed. The ring is made of a Cu base alloy containing 20-40% Zn (all percents being on a weight basis), 2-8% Al, and at least two components (intermetallic compound forming components) selected from among the following five elements, i.e., 0.1-3% of at least one of Ti, Zr and Cr, 0.1-3% Sn, 0.1-6% of at least one of Fe, Ni and Co, 0.1-5% Mn and 0.2-2% Si, and optionally at least one additional component that differs from said selected two components and which is selected from among 0-5% Mn, 0-3% Sn and 0-3% of at least one of Ti, Zr and Cr, and the balance being Cu and incidental impurities. The ring also has either an oxide film layer of aluminum oxide base with an average thickness of 0.1-10 .mu.m or a work-hardened layer with an average thickness of 5-300 .mu.
    Type: Grant
    Filed: October 4, 1989
    Date of Patent: February 26, 1991
    Assignee: Mitsubishi Metal Corporation
    Inventor: Hidetoshi Akutsu
  • Patent number: 4954187
    Abstract: Utilization of a copper-zinc alloy for semifinished materials and semi-manufactured articles; especially synchronizing rings. The copper-zinc alloy is essentially constituted of 50 to 65% copper, 1 to 6% aluminum, 0.5 to 5% silicon, 5 to 8% nickel, as well as selectively 0 to 1% iron, 0 to 2% lead, 0 to 2% manganese, all in percent by weight, with zince as the remainder, as well as unavoidable impurities, whereby the nickel is overwhelmingly present in an intermetallic composition with silicon (nickel-silicide). The silicides are in round, uniformly distributed fine precipitate form.
    Type: Grant
    Filed: October 20, 1988
    Date of Patent: September 4, 1990
    Assignee: Diehl GmbH & Co.
    Inventors: Norbert Gaag, Peter Ruchel
  • Patent number: 4874439
    Abstract: A synchronizer ring for use in an automotive speed variator. The ring not only has high strength and toughness but also exhibits high wear resistance, as well as good synchronizing characteristics with respect to a mating member as expressed in terms of friction coefficient. The Cu alloy of which this ring is made has one of the following compositions: (1) 17-40% Zn (all percents are on a weight basis), 2-11% Al and 50-3,000 ppm of oxygen, as well as 0.1-3.5% of at least one element selected from among Ti, Zr and V, 0.003-0.3% Mg and with at least one optional element selected from among Fe, Ni, Co, P, Ca, Mn, Sn, Si and Pb, the balance being Cu and incidental impurities; or (2) 17-40% Zn, 2-11% Al, 0.5-6% Mn, 0.1-2% Si, 0.1-3% of at least one of Fe, Ni and Co, 0.003-0.3% of Mg, and 30-1,000 ppm of oxygen, with at least one optional element selected from among P, Ca, Cr, Pb and Sn, and with the balance being Cu and incidental impurities.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: October 17, 1989
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventor: Hidetoshi Akutsu
  • Patent number: 4786470
    Abstract: A new aluminum-bronze dental alloy and restoration technique is disclosed in which castability and burnishability are improved by the presence of 1 to 8 percent zinc.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: November 22, 1988
    Assignee: Aalba Dent, Inc.
    Inventors: Giulio Benetti, Vincent M. Benetti
  • Patent number: 4749548
    Abstract: Copper alloy lead materials used in the fabrication of semiconductor devices such as ICs and LSIs are required to have a tensile strength of 40 kgf/mm.sup.2 or more, an elongation of 4% or more, an electrical conductivity of 50% IACS or more, and a softening point of 400.degree. C. or higher.The copper alloy lead material of the present invention exhibits even higher degrees of tensile strength and elongation and yet satisfy the values of electrical conductivity and softening point that are required for Cu alloy lead materials to be used with ordinary semiconductor devices. Therefore, the Cu alloy lead material of the present invention is applicable not only to ordinary semiconductor devices but also to those with higher packing densities while displaying equally superior performance.
    Type: Grant
    Filed: September 3, 1986
    Date of Patent: June 7, 1988
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Hidetoshi Akutsu, Takuro Iwamura, Masao Kobayashi
  • Patent number: 4642146
    Abstract: A copper base alloy capable of forming a microstructure comprising a plurality of discrete particles in a surrounding metal matrix having a lower melting point than the particles. The alloy consists essentially of from about 3% to about 6% nickel, from about 2% to about 4.25% aluminum, from about 0.25% to about 1.2% silicon, from about 5% to about 15% zinc, up to about 5% iron and the balance essentially copper. When iron is included in an amount from about 3% to about 5% and zinc is restricted to a range of from about 8% to about 10%, the alloy is capable of forming the desired structure in the as-cast condition using a process which does not include stirring during casting.
    Type: Grant
    Filed: October 11, 1985
    Date of Patent: February 10, 1987
    Assignee: Olin Corporation
    Inventors: Sankaranarayanan Ashok, John F. Breedis
  • Patent number: 4632806
    Abstract: A Cu alloy having high resistance to oxidation for use in leads on semiconductor devices is disclosed. The alloy consists essentially of 7-15 wt % Mn, 10-30 wt % Zn, 0.2-10 wt % Ni, 0.1-3 wt % Al, with the balance being Cu and incidental impurities. Also disclosed is a Cu alloy clad material wherein the substrate is made of Cu or Cu alloy having high electrical conductivity and good heat dissipation, and the cladding or partial cladding is composed of the Cu alloy having the composition specified above.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: December 30, 1986
    Assignees: Mitsubishi Kinzoku Kabushiki Kaisha, Fujitsu Limited
    Inventors: Masaki Morikawa, Hideaki Yoshida, Kunio Kishida