Titanium, Or Zirconium Containing Patents (Class 420/586)
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Patent number: 12012640Abstract: A method of forming a hot stamped coated steel product includes providing a precoated steel strip, the precoated steel strip including a base steel having a first side and a second side, and a precoating on at least one of the first side and the second side, the precoating being made of aluminum or an aluminum alloy; heating the precoated steel strip in a furnace, wherein the precoated strip experiences a temperature rise at a heating rate (Vc) between 4° and 12° C./s, wherein Vc is a mean heating rate between 20 and 700 C; removing the heated precoated steel strip from the furnace; and then hot stamping the precoated strip to deform the precoated steel strip into a hot stamped coated steel product, the hot stamped coated steel product having a coating including, proceeding from the base steel outwards: (a) an interdiffusion layer, (b) an intermediate layer, (c) an intermetallic layer, and (d) a superficial layer.Type: GrantFiled: December 12, 2023Date of Patent: June 18, 2024Assignee: ArcelorMittalInventors: Pascal Drillet, Dominique Spehner, Ronald Kefferstein
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Patent number: 11981875Abstract: Reactor components formed using an erosion resistant alloy having desirable high temperature mechanical strength are provided. The erosion resistant components can include, but are not limited to, tubes, reactors walls, fittings, and/or other components having surfaces that can be exposed to a high temperature reaction environment in the presence of hydrocarbons and/or that can provide pressure containment functionality in processes for upgrading hydrocarbons in a high temperature reaction environment. The erosion resistant alloy used for forming the erosion resistant component can include 42.0 to 46.0 wt. % nickel; 32.1 to 35.2 wt. % chromium; 0.5 to 2.9 wt. % carbon; 0 to 2.0 wt. % titanium; 0 to 4.0 wt. % tungsten, and iron, with at least one of titanium and tungsten is present in an amount of 1.0 wt. % or more. The iron can correspond to the balance of the composition.Type: GrantFiled: December 13, 2019Date of Patent: May 14, 2024Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jorge J. Perdomo, Ivan A. Morales, Changmin Chun
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Patent number: 11976346Abstract: A solar tower system is disclosed in which the heat transfer media is a molten salt at a temperature greater than 650° C. The components that carry or hold the molten salt are made from commercially available alloys made by Haynes International and sold under the designations HR-120® alloy, 230® alloy and 233™ alloy whose compositions are described herein. The molten salt preferably is MgCl2—KCl.Type: GrantFiled: October 11, 2018Date of Patent: May 7, 2024Assignees: Haynes International, Inc., ICL-IP America, Inc.Inventors: Vinay Deodeshmukh, Reinhard Effenberger
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Patent number: 11952742Abstract: A cast lip for an excavating bucket composed of a ferrous alloy having at least seven percent chromium by weight, 3%-6% nickel by weight, and ?0.12% carbon by weight, and a primarily martensitic structure.Type: GrantFiled: March 27, 2020Date of Patent: April 9, 2024Assignee: ESCO GROUP LLCInventors: Robin K. Churchill, Michael B. Roska, Ulf Daniel Widlund
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Patent number: 11530472Abstract: Disclosed is an austenitic stainless steel alloy that includes or consists of, by weight, about 20.0% to about 21.5% chromium, about 8.5% to about 10.0% nickel, about 4.0% to about 5.0% manganese, about 0.5% to about 2.0% silicon, about 0.4% to about 0.5% carbon, about 0.2% to about 0.3% nitrogen, and a balance of iron with inevitable/unavoidable impurities. The elements niobium, tungsten, and molybdenum are excluded beyond impurity levels. Turbocharger turbine housings made of the stainless steel alloy, and methods of making the same, are also disclosed. The stainless steel alloy is suitable for use in turbocharger turbine applications for temperatures up to about 1020° C.Type: GrantFiled: October 30, 2019Date of Patent: December 20, 2022Assignee: Garrett Transportation I Inc.Inventors: Pavan Chintalapati, Philippe Renaud, Piotr Gawron, Bjoern Schenk
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Patent number: 11448407Abstract: An air conditioner according to the present embodiment includes: an outdoor unit including a compressor, an outdoor heat exchanger, and a main expansion device, wherein a refrigerant is circulated by a refrigerant pipe configured to connect the compressor, the outdoor heat exchanger, and the main expansion device, an indoor unit including an indoor heat exchanger; and a connection pipe configured to connect the outdoor unit and the indoor unit, wherein the air conditioner has a cooling capability between 23 kW and 35 kW, a mixed refrigerant containing R32 of 50% or more is used as the refrigerant, and the refrigerant pipe comprises a ductile stainless steel pipe having a delta ferrite matrix structure of 1% or less on a basis of a grain area.Type: GrantFiled: January 11, 2018Date of Patent: September 20, 2022Assignee: LG ELECTRONICS INC.Inventor: Seokpyo Hong
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Patent number: 11420896Abstract: The present invention relates to a metal alloy, characterized in that it comprises, in percent by weight on the total weight of the alloy, 1-4% of niobium (Nb), 0-0.5% of hafnium (Hf), 27-29% of chromium, 1-5% of nickel (Ni), 0.3-0.45% of carbon (C), 0-2% of tantalum (Ta), 0-2% of titanium, 1-3% of iron, less than 0.5% of manganese (Mn), less than 0.3% of silicon (Si), less than 0.2% of zirconium (Zr), the remainder being cobalt (Co) and unavoidable impurities. This metal alloy has superior mechanical strength characteristics at high temperature which make it suitable for the manufacture of a manufactured article, in particular a spinner, for the production of mineral fibers, such as glass fiber, rock fiber and the like.Type: GrantFiled: November 6, 2018Date of Patent: August 23, 2022Assignee: STM TECHNOLOGIES S.R.L.Inventors: Marco La Greca, Roberto Massini
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Patent number: 11180830Abstract: The invention relates to gamma, gamma'-cobalt-based alloys for additive manufacturing methods or soldering, welding, powder and component. By using a cobalt-based alloy based on Co-7W-7 Al-23Ni-2Ti-2Ta-12Cr-0.0IB-0.IC-(0-0.1Si), an alloy that is especially well-suited for additive manufacturing methods or high-temperature soldering is proposed.Type: GrantFiled: December 14, 2016Date of Patent: November 23, 2021Inventors: Christian Gindorf, Stefan Krause
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Publication number: 20150129644Abstract: A metal chemistry includes an amount of chromium weight of between about 9.0% and about 16% by weight, an amount of cobalt of between about 7.0% and about 14% by weight, an amount of molybdenum of between about 10% and about 20% by weight, an amount of iron of between about 1.0% and about 5.0% by weight, an amount of aluminum of between about 0.05% and about 0.75% by weight, an amount of titanium of between about 0.5% and about 2.0% by weight, an amount of manganese not to exceed about 0.8% by weight, an amount of carbon of between about 0.02% and about 0.10% by weight, an amount of a titanium+aluminum alloy of between about 0.55% and about 2.75% by weight, and an amount of nickel.Type: ApplicationFiled: January 22, 2015Publication date: May 14, 2015Inventors: Yan Cui, Srikanth Chandrudu Kottilingam, Dechao Lin, Brian Lee Tollison
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Publication number: 20150010428Abstract: A cobalt-nickel alloy composition comprising by weight: about 29 to 37 percent cobalt; about 29 to 37 percent nickel; about 10 to 16 percent chromium; about 4 to 6 percent aluminium; at least one of Nb, Ti and Ta; at least one of W, Ta and Nb; the cobalt and nickel being present in a ratio between about 0.9 and 1.1.Type: ApplicationFiled: June 25, 2014Publication date: January 8, 2015Inventors: Mark Christopher HARDY, David DYE, Huiyu YAN, Matthias KNOP, Howard James STONE
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Patent number: 8889066Abstract: The invention relates to a solid-solution strengthened iron-nickel alloy with a high level of ductility and an expansion coefficient <5×10?6/K in the temperature range between room temperature and ?200° C. Said alloy consists of (in wt. %): between 0.005 and 0.05% of C; <0.02% of S; between 1 and 2% of Cr; between 35 and 38% of Ni; between 0.3 and 1.5% of Mn; <0.5% of Si; between 1.0 and 3.5% of ?Mo+W; between 0.2 and 1.0% of Ti; between 0.2 and 1.0% of Nb; <0.02% of P; and between 1.0 and 4.0% of Co; Fe constituting the remainder, in addition to production-related impurities.Type: GrantFiled: October 20, 2007Date of Patent: November 18, 2014Assignee: Outokumpu VDM GmbHInventors: Bernd Hoberg, Bernd De Boer
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Publication number: 20140314618Abstract: A cast nickel-base superalloy that includes iron added substitutionally for nickel. The cast nickel base superalloy comprises, in weight percent about 1-6% iron, about 7.5-19.1% cobalt, about 7-22.5% chromium, about 1.2-6.2% aluminum, optionally up to about 5% titanium, optionally up to about 6.5% tantalum, optionally up to about 1% Nb, about 2-6% W, optionally up to about 3% Re, optionally up to about 4% Mo, about 0.05-0.18% C, optionally up to about 0.15% Hf, about 0.004-0.015 B, optionally up to about 0.1% Zr, and the balance Ni and incidental impurities. The superalloy is characterized by a ?? solvus temperature that is within 5% of the ?? solvus temperature of the superalloy that does not include 1-6% Fe and a mole fraction of ?? that is within 15% of the mole fraction of the superalloy that does not include 1-6% Fe.Type: ApplicationFiled: April 23, 2013Publication date: October 23, 2014Inventors: Ganjiang FENG, Jon Conrad SCHAEFFER, Michael Douglas ARNETT
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Patent number: 8808473Abstract: An austenitic heat resistant alloy includes, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 10.14 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 0.05%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 1.36% or less, Ti: 3% or less, and Nb: 3% or less, and the balance being Fe and impurities. The contents of P and S in the impurities are P: 0.03% or less and S: 0.01% or less. The alloy satisfies 1?4×Al+2×Ti+Nb?12 and P+0.2×Cr×B?0.035, where an element in the Formulas represents the content by mass percent.Type: GrantFiled: May 16, 2012Date of Patent: August 19, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroyuki Hirata, Hirokazu Okada, Hiroyuki Semba, Kazuhiro Ogawa, Atsuro Iseda, Mitsuru Yoshizawa
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Patent number: 8801877Abstract: An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si?2%, Mn?3%, P?0.03%, S?0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co?20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N?0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P?3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr?Ni+Co?1.85×Cr . . . (2), Al?1.5×Zr . . . (3).Type: GrantFiled: June 3, 2013Date of Patent: August 12, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroyuki Semba, Hirokazu Okada, Masaaki Igarashi
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Publication number: 20140060707Abstract: Alloys, processes for preparing the alloys, and manufactured articles including the alloys are described. The alloys include, by weight, about 10% to about 20% chromium, about 4% to about 7% titanium, about 1% to about 3% vanadium, 0% to about 10% iron, less than about 3% nickel, 0% to about 10% tungsten, less than about 1% molybdenum, and the balance of weight percent including cobalt and incidental elements and impurities.Type: ApplicationFiled: August 28, 2013Publication date: March 6, 2014Applicant: QuesTek Innovations LLCInventors: James A. Wright, Jeremy Hoishun Li
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Publication number: 20140030141Abstract: Nickel-chromium-iron-molybdenum alloy, comprising 40 to 48 wt % nickel, 30 to 38 wt % chromium, 4 to 12 wt % molybdenum and iron, wherein the alloy optionally further comprises up to 5 wt % manganese, up to 2 wt % copper, up to 0.6 wt % nitrogen, up to 0.5 wt % aluminium and up to 0.5 wt % vanadium.Type: ApplicationFiled: November 18, 2011Publication date: January 30, 2014Inventors: Per Henrik Asteman, Georg-Wilheim Overbeck
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Publication number: 20130294964Abstract: A weldable, high temperature oxidation resistant alloy with low solidification crack sensitivity and good resistance to strain age cracking. The alloy contains by weight percent, 25% to 32% iron, 18% to 25% chromium, 3.0% to 4.5% aluminum, 0.2% to 0.6% titanium, 0.2% to 0.43% silicon, up to 0.5% manganese and the balance nickel plus impurities. The Al+Ti content should be between 3.4 and 4.2 and the Cr/Al ratio should be from about 4.5 to 8.Type: ApplicationFiled: July 12, 2013Publication date: November 7, 2013Applicant: HAYNES INTERNATIONAL, INC.Inventors: Dwaine L. Klarstrom, Steven J. Matthews, Venkat R. Ishwar
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Patent number: 8486204Abstract: The hinge is made with a metal injection molding process from an alloy having at least: from 4 to 32 wt % Mn, from 16 to 37 wt % Cr, and from Fe that fills up the rest of the percentage.Type: GrantFiled: November 17, 2010Date of Patent: July 16, 2013Assignee: Shin Zu Shing Co., Ltd.Inventors: Yu-Chi Lu, Yu-Chan Hsieh, Shun-Tian Lin
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Publication number: 20130160466Abstract: It is an objective of the invention to provide an Ni-based forged alloy having good large ingot formability and good hot formability as well as high mechanical strength at high temperature. There is provided an Ni-based forged alloy comprising: 0.001 to 0.1 mass % of C; 0.001 to 0.01 mass % of B; 16 to 22 mass % of Cr; 0.5 to 1.5 mass % of Al; 0.1 to 6.0 mass % of W; 3.5 to 5.5 mass % of Nb; 0.8 to 3.0 mass % of Ti; 16 to 20 mass % of Fe; 2.0 mass % or less of Mo; and the balance including Ni and unavoidable impurities, in which: a segregation parameter Ps defined by a formula of “Ps (mass %)=1.05[Al concentration (mass %)]+0.6[Ti concentration (mass %)]?0.8[Nb concentration (mass %)]?0.3[Mo concentration (mass %)]” satisfies a relationship of “Ps??3.0 mass %”; and total amount of W and Mo is 1.75 atomic % or less.Type: ApplicationFiled: December 20, 2012Publication date: June 27, 2013Applicant: HITACHI, LTD.Inventor: Hitachi, Ltd.
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Publication number: 20130143042Abstract: A method of making steel wire includes the step of forming a length of wire from an alloy that preferably contains in weight percent: Carbon 0.03 max. Manganese 0.15 max. Silicon 0.15 max. Phosphorus 0.015 max.? Sulfur 0.010 max.? Chromium 19.00-21.00 Nickel 33.00-37.00 Molybdenum ?9.00-10.50 Titanium 1.00 max. Boron 0.010 max.? Iron 1.00 max. The balance is cobalt and usual impurities. The wire is annealed at a combination of temperature and time effective to provide a grain size of about ASTM 6 or finer and is then drawn to provide a reduction in cross-sectional area of about 50 to 80%. The wire is—then heat treated under temperature and time conditions effective to provide the wire with high strength and sufficient wrap ductility that the wire does not crack or break in a standardized wrap test.Type: ApplicationFiled: December 5, 2012Publication date: June 6, 2013Applicant: CRS HOLDINGS, INC.Inventor: CRS Holdings, Inc.
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Publication number: 20130048700Abstract: A filler metal chemistry includes an amount of chromium weight of between about 9.0% and about 16% by weight, an amount of cobalt of between about 7.0% and about 14% by weight, an amount of molybdenum of between about 10% and about 20% by weight, an amount of iron of between about 1.0% and about 5.0% by weight, an amount of aluminum of between about 0.05% and about 0.75% by weight, an amount of titanium of between about 0.5% and about 2.0% by weight, an amount of manganese not to exceed 0.8% by weight, an amount of carbon of between 0.02% and about 0.10% by weight, an amount of titanium+aluminum of between about 0.55% and 2.75% by weight, and an amount of nickel.Type: ApplicationFiled: August 29, 2011Publication date: February 28, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Yan Cui, Srikanth Chandrudu Kottilingam, Dechao Lin, Brian Lee Tollison
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Patent number: 8318083Abstract: The present invention addresses the need for new austenitic steel compositions with higher creep strength and higher upper temperatures. The new austenitic steel compositions retain desirable phases, such as austenite, M23C6, and MC in its microstructure to higher temperatures. The present invention also discloses a methodology for the development of new austenitic steel compositions with higher creep strength and higher upper temperatures.Type: GrantFiled: July 20, 2010Date of Patent: November 27, 2012Assignee: UT-Battelle, LLCInventors: Roman I Pankiw, Govindarajan Muralidharan, Vinod Kumar Sikka, Philip J. Maziasz
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Patent number: 8313591Abstract: An austenitic heat resistant alloy, which contains, by mass percent, C?0.15%, Si?2%, Mn?3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti?3%, Al?3%, N?0.03%, O?0.03%, with the balance being Fe and impurities, and among the impurities P?0.04%, S?0.03%, Sn?0.1%, As?0.01%, Zn?0.01%, Pb?0.01% and Sb?0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}?0.050], [0.2?P2=Ti+2Al?7.5?10×P1], [P2?9.0?100×O] and [N?0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on.Type: GrantFiled: December 24, 2009Date of Patent: November 20, 2012Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hiroyuki Hirata, Atsuro Iseda, Hirokazu Okada, Hiroyuki Semba, Kaori Kawano, Osamu Miyahara
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Publication number: 20120288400Abstract: An austenitic heat resistant alloy consisting of, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 0.03 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 4%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 3% or less, Ti: 3% or less, and Nb: 3% or less, the balance being Fe and impurities. The contents of P and S in the impurities being P: 0.03% or less and S: 0.01% or less. The alloy satisfies 1?4×Al+2×Ti+Nb?12 and P+0.2×Cr×B?0.035, is excellent in weld crack resistance and toughness of HAZ, and is further excellent in creep strength at high temperatures.Type: ApplicationFiled: May 16, 2012Publication date: November 15, 2012Applicant: SUMITOMO METAL INDUSTRIES., LTD.Inventors: Hiroyuki Hirata, Hirokazu Okada, Hiroyuki Semba, Kazuhiro Ogawa, Atsuro Iseda, Mitsuru Yoshizawa
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Patent number: 8075839Abstract: A wroughtable, cobalt alloy capable of through thickness nitridation and strengthening using practical treatments and practical sheet thicknesses contains in weight percent about 23 to about 30% chromium, about 15 to about 25% iron, up to about 27.3% nickel, about 0.75 to about 1.7% titanium, about 0.85 to about 1.9% niobium or zirconium, up to 0.2% carbon, up to 0.015% boron, up to 0.015% rare earth elements, up to 0.5% aluminum, up to 1% manganese, up to 1% silicon, up to 1% tungsten, up to 1% molybdenum, and the balance cobalt plus impurities and the total weight percent of titanium plus niobium or equivalents is from about 1.6 to about 3.6.Type: GrantFiled: September 15, 2006Date of Patent: December 13, 2011Assignee: Haynes International, Inc.Inventor: S. Krishna Srivastava
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Publication number: 20110272070Abstract: A nickel chromium alloy with 0.4 to 0.6% carbon, 28 to 33% chromium, 15 to 25% iron, 2 to 6% aluminum, up to 2% silicon, up to 2% manganese, up to 1.5% niobium, up to 1.5% tantalum, up to 1.0% tungsten, up to 1.0% titanium, up to 1.0% zirconium, up to 0.5% yttrium, up to 1.0% cerium, up to 0.5% molybdenum, up to 0.1% nitrogen, remainder nickel, has a high oxidation and carburization stability, long-term rupture strength and creep resistance. This alloy is particularly suited as a material for components of petrochemical plants and for parts, for example tube coils of cracker and reformer furnaces, pre-heaters, and reformer tubes, as well as for use for parts of iron ore direct reduction plants.Type: ApplicationFiled: October 13, 2009Publication date: November 10, 2011Applicant: Schmidt + Clemens GmbH + Co. KGInventors: Dietlinde Jakobi, Peter Karduck, Alexander Freiherr Von Richthofen
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Publication number: 20110274579Abstract: A welding additive is provided. A component including a welding additive is also provided. The welding additive improves the weldability of a few nickel-based superalloys and includes the following contents (in wt %): 10.0%-20.0% chromium, 5.0%-15.0% cobalt, 0.0%-10.0% molybdenum, 0.5-3.5% tantalum, 0.0%-5.0% titanium, 1.5%-5.0% aluminum, 0.3%-0.6% boron, remainder nickel.Type: ApplicationFiled: September 10, 2009Publication date: November 10, 2011Inventor: Nikolai Arjakine
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Publication number: 20110250463Abstract: Nickel based alloy intended for use at high temperatures wherein it comprises in percent by weight (wt-%) C 0.05-0.2 Si max 1.5 Mn max 0.5 Cr 15-20 Al 4-6 Fe 15-25 Co max 10 N 0.03-0.15 O max 0.5 one or more elements selected from the group consisting of Ta, Zr, Hf, Ti and Nb 0.25-2.2 one or more elements selected from the group consisting of REM max 0.5 balance Ni and normally occurring impurities.Type: ApplicationFiled: November 6, 2009Publication date: October 13, 2011Applicant: Sandvik Intellectual Property ABInventors: Thomas Helander, Mats Lundberg, Bo Jönsson
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Publication number: 20110088819Abstract: An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si?2%, Mn?3%, P?0.03%, S?0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co?20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N?0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P?3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr?Ni+Co?1.85×Cr . . . (2), Al?1.5×Zr . . . (3).Type: ApplicationFiled: December 13, 2010Publication date: April 21, 2011Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Hiroyuki SEMBA, Hirokazu OKADA, Masaaki IGARASHI
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Publication number: 20110079944Abstract: Provided are an alloy for spring, a plate material for spring, and a spring member, all of which are high in mechanical strength, also high in fatigue strength, and excellent in corrosion resistance. An alloy for spring of the present invention includes, as composition in terms of weight ratio, 28 to 42% Co, 10 to 27% Cr, 3 to 12% Mo, 15 to 40% Ni, 0.1 to 1.0% Ti, 1.5% or less Mn, 0.1 to 26.0% Fe, 0.1% or less C, and inevitable impurities, and at least one kind selected from 3.0% or less Nb, 5.0% or less W, 0.5% or less Al, 0.1% or less Zr, and 0.01% or less B.Type: ApplicationFiled: September 30, 2010Publication date: April 7, 2011Inventors: Yasunori Akasaka, Kyotaro Takahashi, Takashi Kamada, Ryo Sugawara, Tomoo Kobayashi
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Publication number: 20110064569Abstract: In one embodiment, a nickel-base alloy for forging or rolling contains, in weight %, carbon (C): 0.05 to 0.2, silicon (Si) 0.01 to 1, manganese (Mn): 0.01 to 1, cobalt (Co): 5 to 20, iron (Fe): 0.01 to 10, chromium (Cr): 15 to 25, and one kind or two kinds or more of molybdenum (Mo), tungsten (W) and rhenium (Re), with Mo+(W+Re)/2: 8 to 25, the balance being nickel (Ni) and unavoidable impurities.Type: ApplicationFiled: August 11, 2010Publication date: March 17, 2011Applicant: Kabushiki Kaisha ToshibaInventors: Masayuki YAMADA, Kiyoshi Imai, Kuniyoshi Nemoto, Shigekazu Miyashita, Takeo Suga
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Patent number: 7833631Abstract: A multi metal base thermal resistance alloy and a mold with the multi metal base thermal resistance alloy layer are provided. The weight percent of each element in this alloy is less than 45%. The structure of the alloy is an amorphous structure and the phonon thermal conductivity of the amorphous structure is intrinsically low. Therefore, the alloy is a metal material with low thermal conductivity coefficient and high thermal stability, which can increase the heat retaining property of the die casting mold, enhance the forming yield and stability of a metal sheet with a low fusion point, and is suitable to be used as a thermal-resistance coating material on die casting molds.Type: GrantFiled: December 22, 2006Date of Patent: November 16, 2010Assignee: Industrial Technology Research InstituteInventors: Chi-San Chen, Chih-Chao Yang, Chih-Jung Weng, Chao-Ming Chen
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Publication number: 20100244310Abstract: An alloy, characterized in that it contains the following elements (the proportions being indicated in percentages by weight of the alloy): Cr: ?23 to 34% Ti: 0.2 to 5% Ta: 0.5 to 7% C: 0.2 to 1.2% Ni: less than 5% Fe: less than 3% Si: less than 1% Mn: less than 0.5%, the balance consisting of cobalt and inevitable impurities. An article for the manufacture of mineral wool, especially fiberizing spinner, made of such an alloy.Type: ApplicationFiled: November 27, 2008Publication date: September 30, 2010Applicants: Saint-Gobain Isover, Saint-Gobain SevaInventors: Jean-Luc Bernard, Patrice Berthod, Ludovic Hericher, Christophe Liebaut, Sylvain Michon
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Publication number: 20100166594Abstract: An austenitic heat resistant alloy, which comprises, by mass percent, C?0.15%, Si?2%, Mn?3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti?3%, Al?3%, N?0.03%, O?0.03%, with the balance being Fe and impurities, and among the impurities P?0.04%, S?0.03%, Sn?0.1%, As?0.01%, Zn?0.01%, Pb?0.01% and Sb?0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}?0.050], [0.2?P2=Ti+2Al?7.5?10×P1], [P2?9.0?100×O] and [N?0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on.Type: ApplicationFiled: December 24, 2009Publication date: July 1, 2010Inventors: Hiroyuki Hirata, Atsuro Iseda, Hirokazu Okada, Hiroyuki Semba, Kaori Kawano, Osamu Miyahara
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Publication number: 20100092301Abstract: A component for a high-temperature steam turbine which operates at temperatures above 600° C., especially above 700° C., is formed of a nickel-based alloy. The negative influence of oxidation of the component which is induced by the superheated steam is prevented by the alloy which is used, having the following composition (in % by weight): C: ?0.2 Si: ?1.0 Mn: ?1.0 Cr: 22.0-25.0 Co: 15.0-25.0 Mo: ?3.0 Nb: ?2.0 Al: 1.0-3.0 Ti: 2.0-4.0 Fe: ?2.0 Zr: ?0.2 B: ??0.05 Ni: remainder.Type: ApplicationFiled: October 27, 2008Publication date: April 15, 2010Inventor: Richard Brendon Scarlin
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Publication number: 20100086433Abstract: The invention relates to a solid-solution strengthened iron-nickel alloy with a high level of ductility and an expansion coefficient <5×10?6/K in the temperature range between room temperature and ?200° C. Said alloy consists of (in wt. %): between 0.005 and 0.05% of C; <0.02% of S; between 1 and 2% of Cr; between 35 and 38% of Ni; between 0.3 and 1.5% of Mn; <0.5% of Si; between 1.0 and 3.5% of ? Mo+W; between 0.2 and 1.0% of Ti; between 0.2 and 1.0% of Nb; <0.02% of P; and between 1.0 and 4.0% of Co; Fe constituting the remainder, in addition to production-related impurities.Type: ApplicationFiled: October 20, 2007Publication date: April 8, 2010Applicant: THYSSENKRUPP VDM GMBHInventors: Bernd Hoberg, Bernd De Boer
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Publication number: 20090321405Abstract: A nickel (Ni), chromium (Cr), cobalt (Co), iron (Fe), molybdenum (Mo), manganese (Mn), aluminum (Al), titanium (Ti), niobium (Nb), silicon (Si) welding alloy, articles made therefrom for use in producing weldments and methods for producing these weldments. The welding alloy contains in % by weight about: 23.5 to 25.5% Cr, 15 to 22% Co, up to 3% Fe, up to 1% Mo, up to 1% Mn, 1.1 to 2.0% Al, 0.8 to 1.8% Ti, 0.8 to 2.2% Nb, 0.05 to 0.28% Si, up to 0.3% Ta, up to 0.3% W, 0.005 to 0.08% C, 0.001 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, up to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities.Type: ApplicationFiled: June 22, 2009Publication date: December 31, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Publication number: 20090291016Abstract: A Ni-base casting superalloy containing, in masse, C: 0.05 to 0.2, Si: 0.01 to 1, Mn: 0.01 to 1, Co: 5 to 20, Fe: 10 or less, Cr: 15 to 25, and one kind or two kinds or more of Mo, W, and Re, with Mo+(W+Re)/2: 8 to 25, the balance being Ni and unavoidable impurities.Type: ApplicationFiled: May 20, 2009Publication date: November 26, 2009Applicant: Kabushiki Kaisha ToshibaInventors: Masayuki Yamada, Kiyoshi Imai, Kuniyoshi Nemoto, Shigekazu Miyashita, Kazutaka Ikeda, Takeo Suga
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Publication number: 20090257908Abstract: A high temperature, high strength Ni—Co—Cr alloy possessing essentially fissure-free weldability for long-life service at 538° C. to 816° C. contains in % by weight about: 23.5 to 25.5% Cr, 15-22% Co, 1.1 to 2.0% Al, 1.0 to 1.8 % Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, less than 0.3% Si, less than 3% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, 0.005% to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities. The strength and stability is assured at 760° C. when the Al/Ti ratio is constrained to between 0.95 and 1.25. Further, the sum of Al+Ti is constrained to between 2.25 and 3.0. The upper limits for Nb and Si are defined by the relationship: (% Nb+0.95)+3.32(% Si)<3.16.Type: ApplicationFiled: April 8, 2009Publication date: October 15, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Publication number: 20090123324Abstract: A method and cast wear resistant component made of an alloy that includes carbon, tungsten, chromium, and cobalt with the balance essentially iron and other alloying components made using waste, surplus or worn-out cemented carbide product, such as cemented carbide cutting tool inserts. In one method, the alloy further includes silicon, manganese, nickel, titanium, and molybdenum. In practicing the method, pieces of waste, surplus or worn-out cemented carbide product having tungsten carbide (WC) are added to a cast iron alloy melt. The melt includes enough chromium to control solubility of the WC. In one method, precipitated carbide structure having chromium and carbon is produced with tungsten in the melt being substitutionally dissolved. In one implementation, tungsten is substitutionally dissolved in a lattice of the precipitated carbide structure. Carbide can be added to the melt via super inoculation. The cast wear resistant component can be a cutting tool.Type: ApplicationFiled: October 22, 2008Publication date: May 14, 2009Inventors: Carl-Hakan Andersson, Mikael Andersson, Henrik Andersson, Helena Andersson, Anders Nilsson, Jan-Eric Stahl
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Publication number: 20090041611Abstract: A cobalt-based braze alloy composition comprises: 22 to 24.75% chromium by weight; 9 to 11% nickel by weight; 6.5 to 7.6% tungsten by weight; 3 to 4% tantalum by weight; 0.55 to 0.65% carbon by weight; 0.3 to 0.6% zirconium by weight; 0.15 to 0.3% titanium by weight; 1.5 to 2.6% boron by weight; 1 to 10% silicon by weight; and cobalt. There are also provided methods of using the same.Type: ApplicationFiled: August 7, 2007Publication date: February 12, 2009Applicant: GENERAL ELECTRIC COMPANYInventors: Sujith Sathian, Gene A. Murphy
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Publication number: 20090016926Abstract: A nickel-chromium casting alloy comprising, in weight percent, up to 0.8% of carbon, up to 1% of silicon, up to 0.2% of manganese, 15 to 40% of chromium, 0.5 to 13% of iron, 1.5 to 7% of aluminum, up to 2.5% of niobium, up to 1.5% of titanium, 0.01 to 0.4% of zirconium, up to 0.06% of nitrogen, up to 12% of cobalt, up to 5% of molybdenum, up to 6% of tungsten and from 0.01 to 0.1% of yttrium, remainder nickel, has a high resistance to carburization and oxidation even at temperatures of over 1130° C. in a carburizing and oxidizing atmosphere, as well as a high thermal stability, in particular creep rupture strength.Type: ApplicationFiled: July 8, 2008Publication date: January 15, 2009Applicant: Schmidt + Clemens GmbH + Co. KGInventors: Rolf KIRCHHEINER, Dietlinde JAKOBI, Petra BECKER, Ricky DURHAM
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Publication number: 20080159905Abstract: A controlled combustion synthesis apparatus comprises an ignition system, a pressure sensor for detecting internal pressure, a nitrogen supply, a gas pressure control valve for feeding nitrogen and exhausting reaction gas, means for detecting the internal temperature of the reaction container, a water cooled jacket, and a cooling plate. A temperature control system controls the temperature of the reaction container by controlling the flow of cooling water supplied to the jacket and the cooling plate in response to the detected temperature. By combustion synthesizing, while controlling the internal pressure and temperature, the apparatus can synthesize a silicon alloy including 30-70 wt. % silicon, 10-45 wt. % nitrogen, 1-40 wt. % aluminum, and 1-40 wt % oxygen.Type: ApplicationFiled: April 19, 2007Publication date: July 3, 2008Applicant: ISMAN J CorporationInventors: Toshiyuki Watanabe, Masafumi Matsushita, Toshitaka Sakurai, Kazuya Sato, Yoko Matsushita
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Publication number: 20080066831Abstract: A wroughtable, cobalt alloy capable of through thickness nitridation and strengthening using practical treatments and practical sheet thicknesses contains in weight percent about 23 to about 30% chromium, about 15 to about 25% iron, up to about 27.3% nickel, about 0.75 to about 1.7% titanium, about 0.85 to about 1.9% niobium or zirconium, up to 0.2% carbon, up to 0.015% boron, up to 0.015% rare earth elements, up to 0.5% aluminum, up to 1% manganese, up to 1% silicon, up to 1% tungsten, up to 1% molybdenum, and the balance cobalt plus impurities and the total weight percent of titanium plus niobium or equivalents is from about 1.6 to about 3.6.Type: ApplicationFiled: September 15, 2006Publication date: March 20, 2008Inventor: S. Krishna Srivastava
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Patent number: 7241365Abstract: The invention relates to an apparatus and a process for the preparation of anhydrous or substantially anhydrous formic acid. This apparatus is constructed partly or entirely of substantially zirconium-free materials. The extractant employed is a liquid of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1–C4-alkyl group. The apparatus has a synthesis reactor (6), a hydrolysis reactor (1), three distillation devices (2,4,5) and an extraction device (3).Type: GrantFiled: January 24, 2001Date of Patent: July 10, 2007Assignee: BASF AktiengesellschaftInventors: Heinz Auer, Bernd Bessling, Hans Hammer, Hans Hasse, Friedrich Sauer, Maximilian Vicari, Gerhard Wagner, Till Adrian
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Patent number: 6771490Abstract: A metal frame for electronic hardware and a method of manufacturing such a frame wherein at least a portion of the frame is made of bulk-solidifying amorphous alloys or bulk-solidifying amorphous alloy-composites is provided. The metal frames of the invention are preferably made of bulk-forming amorphous alloys or bulk-forming amorphous alloy-composites having an elastic limit for the metal frame of at least about 1.5%, and preferably greater than about 2.0%, a &Dgr;Tsc of more than 30° C., and at least one of the following properties: a hardness value of about 4 GPA or more, and preferably 5.5 GPA or more; a yield strength of about 2 GPa or more; a fracture toughness of about 10 ksi-sqrt(in) (sqrt:squre root) or more, and preferably 20 ksi sqrt(in) or more; and a density of at least 4.5 g/cc or more.Type: GrantFiled: June 7, 2002Date of Patent: August 3, 2004Assignee: Liquidmetal TechnologiesInventors: Atakan Peker, William L. Johnson
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Publication number: 20040115089Abstract: Conventional weld fillers contain copper, aluminum and manganese. These weld fillers are as a rule not suited for the welding of thin or rust-free sheet metals. The inventive weld filler contains 0.5 to 6.0 percent by weight Al, 0.5 to 8.0 percent by weight Mn, the usual impurities are less than or equal to 1.0 percent by weight and as the remainder Cu. This weld filler is better suited for the welding of thin or rust-free sheet metals than the up to now known weld fillers.Type: ApplicationFiled: September 24, 2003Publication date: June 17, 2004Applicant: Berkenhoff GmbH.Inventors: Bruno Rechtziegel, Juergen Fackert, Eberhard Schmid, Uwe Berger, Juergen Schlottner, Klaus Tauber
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Patent number: 6719945Abstract: This invention is related to galvanizing roll assemblies provided with self-aligning hydrodynamically lubricated roller-bearings used in equipment submerged in molten metal.Type: GrantFiled: January 10, 2002Date of Patent: April 13, 2004Inventor: Jorge A. Morando
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Patent number: 6709528Abstract: A method of enhancing the corrosion resistance of an austenitic steel includes removing material from at least a portion of a surface of the steel such that corrosion initiation sites are eliminated or are reduced in number relative to the number resulting from processing in a conventional manner. Material may be removed from the portion by any suitable method, including, for example, grit blasting, grinding and/or acid pickling under conditions more aggressive than those used in conventional processing of the same steel.Type: GrantFiled: August 7, 2000Date of Patent: March 23, 2004Assignee: ATI Properties, Inc.Inventors: John F. Grubb, James D. Fritz, Ronald E. Polinski
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Patent number: 6685881Abstract: Disclosed is an austenitic stainless cast steel which has such a good heat resistance as can be used at a high temperature higher than 950° C. and a good machinability. The stainless cast steel consists essentially of, by weight %, C: 0.2-0.4%, Si: 0.5-2.0%, Mn: 0.5-2.0%, P: up to 0.10%, S: 0.04-0.2%, Ni: 8.0-42.0%, Cr: 15.0-28.0%, W: 0.5-7.0%, Nb: 0.5-2.0%, Al: up to 0.02%, Ti: up to 0.05%, N: up to 0.15%, Se: 0.001-0.50% and the balance of Fe and inevitable impurities.Type: GrantFiled: September 20, 2001Date of Patent: February 3, 2004Assignee: Daido Steel Co., Ltd.Inventors: Shuji Hamano, Michio Okabe