Including Plural Sequential Reaction Stages Patents (Class 422/134)
  • Patent number: 8252888
    Abstract: The present invention relates to a method for the continuous production of high-molecular polyesters by esterification of dicarboxylic acids and/or transesterification of dicarboxylic acid esters with diols and/or mixtures thereof in the presence of catalysts with formation of a prepolymer in a tower reactor and polycondensation thereof to form a high-molecular polyester in a polycondensation reactor, a prepolymer with >40 to 70 repeat units (DP) being produced in the tower reactor and this prepolymer being polycondensed in only one further reactor to form a polyester with >150 to 205 DP.
    Type: Grant
    Filed: January 23, 2012
    Date of Patent: August 28, 2012
    Assignee: Uhde Inventa-Fischer GmbH
    Inventor: Eike Schulz Van Endert
  • Patent number: 8242234
    Abstract: An epoxy resin with amine functionality is manufactured continuously through a first reaction zone in which an epoxide-functional resin is made by ring-opening addition, a second reaction zone in which the resin is reacted with amine to make an epoxide-functional product, and a third reaction zone in which the epoxide functional product is reacted with amine to make the epoxy resin with amine functionality. In other embodiments, some amine may be added in the first reaction zone to produce an epoxide functional product, with elimination of the second reaction zone, or all of the amine reactant may be added in the first reaction zone to produce an amine functional product, with elimination of both the second and third reaction zones. Optionally, solvent may be removed in an evaporation zone and recycled into the continuous process and further zones may be included to incorporate crosslinker, additives, and to emulsify the resin.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: August 14, 2012
    Assignee: BASF Coatings GmbH
    Inventors: Charles L Tazzia, Marco A Villalobos, Paul J Harris
  • Publication number: 20120202962
    Abstract: A device and a method for producing high-quality polybutylene succinate are provided. The method for producing polybutylene succinate comprises the steps of: preparing a raw-material slurry by mixing succinic acid or a derivative thereof with 1,4-butanediol in a raw-material slurry preparation tank; storing the raw-material slurry in a raw-material slurry storage tank while maintaining flowability; carrying out an esterification reaction of the raw-material slurry in an esterification reactor; and synthesizing polybutylene succinate with a polycondensation reaction of the ester in a polycondensation reactor, in which the polycondensation reactor is divided, from the upstream side, into at least an initial polycondensation reactor, an intermediate polycondensation reactor, and a final polycondensation reactor, a catalyst is added in an amount from 1000 ppm to 3000 ppm in relation to succinic acid or a derivative thereof, the reaction time in the intermediate polycondensation reactor ranges from 0.
    Type: Application
    Filed: October 21, 2010
    Publication date: August 9, 2012
    Inventors: Masayuki Kamikawa, Toshiaki Matsuo, Kenichiro Oka, Takeyuki Kondo, Yasunari Sase, Masashi Tanto
  • Patent number: 8232079
    Abstract: After various sugar nucleotide solutions and glycosyltransferases (or primers) have been mixed, they are introduced into a reaction tank (column) with primers (or glycosyltransferases) immobilized thereon. Then solutions coming out of the reaction tank are led to an ultrafiltration column. The oligosaccharide synthesizer according to the present invention is equipped with a flow path for ensuring that glycosyltransferases or primers separated by the ultrafiltration column are returned into a container for storing each solution in a sample injector.
    Type: Grant
    Filed: August 5, 2005
    Date of Patent: July 31, 2012
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Kisaburo Deguchi, Genzou Hirata, Masahito Ito, Hiroaki Nakagawa, Shinichiro Nishimura
  • Publication number: 20120178879
    Abstract: The present invention relates to a process for recycling product streams that have been separated from a hydrocarbon-containing feed stream comprising olefin monomer, olefin co-monomer, hydrocarbon diluent and components such as H2, N2, O2, CO, CO2, and formaldehyde. In accordance with the present process a hydrocarbon-containing feed stream is separated into a) a first side stream comprising hydrocarbon diluent and olefin monomer; b) a second side stream which is substantially hydrogen-free and comprises hydrocarbon diluent and olefin monomer, c) a bottom stream comprising substantially olefin-free hydrocarbon diluent, and d) an overhead vapor stream comprising olefin monomer, hydrocarbon diluent and components such as formaldehyde, H2, N2, O2, CO and CO2. The present process further includes recycling said first and said second side streams in a polymerization process for preparing bimodal polyolefin.
    Type: Application
    Filed: September 10, 2010
    Publication date: July 12, 2012
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Denis Mignon, David Vandewiele, Bernard Van Der Schrick, Camille Vercruysse
  • Patent number: 8206593
    Abstract: New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: June 26, 2012
    Assignees: Fluidigm Corporation, California Institute of Technology, The Regents of the University of California, Siemens Medical Solutions USA, Inc.
    Inventors: Chung-cheng Lee, Guodong Sui, Arkadij Elizarov, Hartmuth C. Kolb, Jiang Huang, James R. Heath, Michael E. Phelps, Stephen R. Quake, Hsian-rong Tseng, Paul Wyatt, Antoine Daridon
  • Patent number: 8202485
    Abstract: Process for providing a flow of particulate matter to a reactor, by intermittently adding the particulate matter and a diluent to a mixing tank, and continuously withdrawing a slurry of particulate matter in diluent from the mixing tank for introduction into the reactor. Prior to each addition of particulate matter and diluent to the mixing tank, the concentration of particulate matter in the diluent already in the mixing tank is measured or calculated, and the amount of particulate matter and diluent subsequently added is measured so as to achieve the same concentration at the end of the addition as that measured or calculated prior to the addition.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: June 19, 2012
    Assignee: Ineos Manufacturing Belgium NV
    Inventor: Brent Walworth
  • Publication number: 20120145956
    Abstract: The present invention relates to a process for producing surface-modified water-absorbing polymer structures, comprising the process steps of providing a multitude of water-absorbing polymer structures and treating the surface of the water-absorbing polymer structures with a plasma and mixing a filler with the water-absorbing polymer structures. The invention also relates to an apparatus for this process, to the surface-modified water-absorbing polymer structures obtainable by this process, to a composite comprising these surface-modified water-absorbing polymer structures and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising these surface-modified water-absorbing polymer structures or the composite, and to the use of the surface-modified water-absorbing polymer structures or of the composite in chemical products.
    Type: Application
    Filed: August 18, 2010
    Publication date: June 14, 2012
    Inventors: Mirko Walden, Christoph Loick, Jürgen Erwin Lang, Maciej Olek, Harald Schmidt
  • Publication number: 20120149956
    Abstract: One exemplary embodiment can be a process for oligomerizing one or more hydrocarbons. Usually, the process includes providing a feed including one or more C3 and C4 hydrocarbons to a separation zone, separating a first stream including an effective amount of C3 olefins for oligomerizing, separating a second stream including an effective amount of one or more C4 olefins for oligomerizing, providing at least a portion of the first stream to a first oligomerization zone for producing at least one of a C9 and a C12 hydrocarbon, and providing at least a portion of the second stream to a second oligomerization zone for producing at least one of a C8 and a C12 hydrocarbon.
    Type: Application
    Filed: December 10, 2010
    Publication date: June 14, 2012
    Applicant: UOP, LLC
    Inventors: Steven Lee Krupa, Christian D. Freet, Mohamed Shakur
  • Patent number: 8198392
    Abstract: The polymer degassing apparatus includes a barrel-shaped horizontal container 41 having a supply port 42 for supplying a reactant, a discharge port 43 for discharging a reactant, a stirring means 45 for stirring a reactant, and a degassing means for drawing a gas via a degassing port 44 of the horizontal container. The supply port is positioned below the molten liquid level of the reactant. A recovery container 37 that is connected to the degassing port for recovering a volatile substance in the gas and a vacuum pump 36 are provided. The stirring means includes a plurality of stirring rods 46 oriented along the same direction as the axis in the horizontal container and coupling members 47 for coupling the stirring rods along the same direction as the axis, provided that the coupling members are placed at a distance from the virtual rotation center of the stirring means.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: June 12, 2012
    Assignee: Hitachi Plant Technologies, Ltd.
    Inventors: Toshiaki Matsuo, Masayuki Kamikawa, Kenichiro Oka, Naruyasu Okamoto, Ryuji Kajiya
  • Publication number: 20120136127
    Abstract: A process for the polymerization of olefins is disclosed. The process may include: feeding a catalyst, a liquid diluent, and an olefin to a polymerization vessel having, from a polymerization vessel bottom to a polymerization vessel top, a vapor introduction zone, a three-phase reaction zone and a vapor disengagement zone; contacting the catalyst and olefin under conditions of temperature and pressure in the presence of the liquid diluent as a continuous phase in the three-phase reaction zone to form a solid phase polyolefin; withdrawing a gas phase composition from an outlet in fluid communication with the vapor disengagement zone; circulating the gas phase composition through a gas circulation loop to an inlet in fluid communication with the vapor distribution zone at a rate sufficient to agitate the solid and liquid phases within the three-phase reaction zone; and withdrawing a reaction mixture comprising polyolefin and diluents from the three-phase reaction zone.
    Type: Application
    Filed: July 20, 2010
    Publication date: May 31, 2012
    Applicant: Univation Technologies, LLC
    Inventors: F. David Hussein, Michael E. Muhle, Ping Cai, Mark W. Blood
  • Patent number: 8163246
    Abstract: An olefin polymerization reactor according to the present invention comprises: a vertically extending cylinder; a decreasing diameter portion on the cylinder, having an inside diameter that decreases progressively downward, and having a gas inlet orifice at a bottom end thereof; and a plurality of through holes passing through from an outside surface towards an inside surface of the decreasing diameter portion. Inside a reaction zone enclosed by an inside surface of the decreasing diameter portion and an inside surface above the decreasing diameter portion of the cylinder, a spouted-fluidized bed or a spouted bed is formed.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: April 24, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hideki Sato, Hiroyuki Ogawa
  • Publication number: 20120093693
    Abstract: The present invention provides a multiple loop reactor suitable for polymerizing olefins comprising at least two interconnected loop reactors, whereby said connection essentially consists of one or more transfer lines suitable for transferring polymer slurry from a reactor to another reactor and whereby said transfer line extends substantially horizontally. The invention further relates to a process for producing olefin polymers in a multiple loop react or according to the invention. The invention also relates to the use of a transfer line for transferring polymer slurry from a reactor to another reactor in a multiple loop reactor comprising at least two interconnected loop reactors, whereby said transfer line extends substantially horizontally.
    Type: Application
    Filed: December 20, 2011
    Publication date: April 19, 2012
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventor: Hugo Vandaele
  • Patent number: 8158086
    Abstract: A gas treatment apparatus for treating a gas by bringing the gas into contact with a treatment liquid. The gas treatment apparatus includes a gas-liquid contact chamber for a gas-liquid contact of the gas with the treatment liquid, a storage chamber, located over the gas-liquid contact chamber, for storing the treatment liquid, and a treatment liquid supplying unit for supplying the treatment liquid stored in the storage chamber to an inside of the gas-liquid contact chamber with a gravity-drop.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: April 17, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kouichirou Terada, Takashi Yamaguchi, Takuya Saeki
  • Patent number: 8153754
    Abstract: An equipment for producing polyhydroxycarboxylic acid, includes a ring-opening polymerization apparatus, a liquid phase devolatilizing apparatus, and a drying apparatus, wherein an indirect heat exchanger is connected to a vent gas discharge path of the liquid phase devolatilizing apparatus. The indirect heat exchanger captures a dispersed in-process substance containing hydroxycarboxylic acid cyclic dimers and transfers the substance to the ring-opening polymerization apparatus; a wet condenser and a hot well are connected to a vent gas discharge path of the indirect heat exchanger and that of the drying apparatus, respectively.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: April 10, 2012
    Assignee: Hitachi Plant Technologies, Ltd.
    Inventors: Masayuki Kamikawa, Toshiaki Matsuo, Naruyasu Okamoto, Kenichiro Oka, Takeyuki Kondo
  • Patent number: 8153735
    Abstract: The invention provides a process for preparing polymers based on vinyl ester, ethylene and optionally further comonomers in the form of aqueous polymer dispersions thereof or of water-redispersible polymer powders by means of free-radically initiated continuous emulsion polymerization and optionally drying of the resulting polymer dispersions, characterized in that the emulsion polymerization is carried out in a cascade comprising at least one upstream heat exchanger and at least two downstream pressurized stirred tank reactors connected in series, such that the conversion on leaving the heat exchanger is at least 10% of the overall polymerization conversion.
    Type: Grant
    Filed: August 11, 2008
    Date of Patent: April 10, 2012
    Assignee: Wacker Chemie AG
    Inventors: Hans-Peter Weitzel, Robert Braunsperger
  • Publication number: 20120076696
    Abstract: The present invention provides an apparatus and a method for continuous hydrogenation of conjugated diene polymer. By feeding the conjugated diene polymer, a catalyst composition and a hydrogen to the apparatus for hydrogenation. This apparatus for hydrogenation includes at least one hydrogenation reaction unit each comprising at least one a hydrogenation reactor with an outlet and at least one heat exchanger. In the hydrogenation reaction unit, the conjugated diene polymer, the catalyst composition and the hydrogen are mixed in a non-mechanical mixing mode and proceed hydrogenation with heat exchanger being connected to the outlet of the hydrogenation reactor.
    Type: Application
    Filed: October 13, 2011
    Publication date: March 29, 2012
    Inventors: Chen-Pao Huang, Kuei-Lun Chen
  • Publication number: 20120053309
    Abstract: This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefin and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) is produced.
    Type: Application
    Filed: August 12, 2011
    Publication date: March 1, 2012
    Inventors: Matthew W. Holtcamp, John R. Hagadorn, Matthew S. Bedoya
  • Patent number: 8124018
    Abstract: A modular device for the continuous degas sing of reaction products, such as of a carboxylic acid or a polycarboxylic acid with a multi-functional alcohol suitable for application in the production of precondensates (or also prepolymers), has a heated enclosure in which a plurality of modules are stacked one above the other, each said module having a base. There is a vapor inlet to the uppermost module and a discharge port at the lower most module with at least one module intermediate the uppermost and lowest modules to provide space for expansion of the vapor. The base of each module preferably is concave and there are conduits that provide flow communication between the modules.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: February 28, 2012
    Assignee: EPC Industrial Engineering GmbH
    Inventors: Michael Streng, Clifford Schaeferskuepper, Stephan Biller, Andreas Hilpert
  • Patent number: 8114353
    Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: February 14, 2012
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Elizabeth A. Benham, Max P. McDaniel, Ted H. Cymbaluk, Charles K. Newsome, Charles R. Nease, H. Kenneth Staffin, Thomas R. Parr
  • Publication number: 20120035342
    Abstract: The invention relates to a method and to a device for producing a thermoplastic polyester, having the following steps: a) producing polyester pre-polymer particles; b) crystallizing the polyester pre-polymer particles for producing partially crystalline polyester pre-polymer particles; c) heating the partially crystalline polyester pre-polymer particles to a suitable reaction temperature for producing heated polyester pre-polymer particles; d) reacting the heated polyester pre-polymer particles for producing polyester polymer particles having an intrinsic viscosity between 0.70 and 0.95 dl/g. The reaction in step d) takes place in at least one reactor through which the particles flow by means of gravity. The dwell time in the reactor equals between 6 and 30 hours. The particles are supplied at least to step d) at a mass flow of between 40 and 100 t/h. The present invention is characterized in that a settling rate of the particles in the reactor equals between 2 and 6 m/h.
    Type: Application
    Filed: February 23, 2010
    Publication date: February 9, 2012
    Applicant: Buhler AG
    Inventors: Brent Allan Culbert, Mauricio Rodrigues, Andreas Christel, Franz Giger
  • Patent number: 8110149
    Abstract: The present invention relates to a method for the continuous production of high-molecular polyesters by esterification of dicarboxylic acids and/or transesterification of dicarboxylic acid esters with diols and/or mixtures thereof in the presence of catalysts with formation of a prepolymer in a tower reactor and polycondensation thereof to form a high-molecular polyester in a polycondensation reactor, a prepolymer with >40 to 70 repeat units (DP) being produced in the tower reactor and this prepolymer being polycondensed in only one further reactor to form a polyester with >150 to 205 DP.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: February 7, 2012
    Assignee: Uhde Inventa-Fischer GmbH
    Inventor: Eike Schulz Van Endert
  • Patent number: 8084555
    Abstract: A spouted bed device according to the present invention includes a vertically extending cylinder; a decreasing diameter member which is formed on the cylinder, has an inside diameter that decreases progressively downward, and has a gas inlet orifice at a bottom end thereof; and a tubular portion which extends downward from an edge of the gas inlet orifice. A spouted bed is formed in a treatment zone enclosed by a top surface of the decreasing diameter member and an inner wall of the cylinder above the decreasing diameter member.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: December 27, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyuki Ogawa, Hideki Sato, Hiroshi Ueda
  • Patent number: 8071032
    Abstract: The invention discloses a method and a system for manufacturing organopolysiloxane. The system comprises N raw material tanks, N gauging tanks, a first reactor, a second reactor and at least one product tanks which are arranged in order from high to low. The manufacturing method comprises the following steps of: firstly, N raw materials are added into the N raw material tanks respectively. Then, a plurality of processing parameters about the organopolysiloxane are inputted to control the N gauging tanks to measure the dosage of the N raw materials according to the processing parameters, which along with a cyclic siloxane monomer are inputted into the first reactor. The first reactor is controlled to carry on ring-opening and re-distribution polymerization equilibrium reaction to the N raw materials and the cyclic siloxane monomer, so as to generate an intermediate product, and transfer the intermediate product into the second reactor.
    Type: Grant
    Filed: June 7, 2009
    Date of Patent: December 6, 2011
    Assignee: Chung-Shan Institute of Science and Technology Armaments Bureau, Ministry of National Defense
    Inventors: Tai-Kang Liu, Chi-Fa Hsieh
  • Patent number: 8066948
    Abstract: A device for degassing a flowable, viscous and pasty product includes a reactor having a product inlet and a product discharge outlet. A plurality of rotors each defining a reaction zone are located side-by-side in the reactor and a separate driving system mounted outside of the reactor for rotating each rotor with each driving system being an hydraulic system.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: November 29, 2011
    Assignee: EPC Industrial Engineering GmbH
    Inventors: Michael Streng, Clifford Schaeferskurpper, Andreas Hilpert
  • Publication number: 20110275770
    Abstract: The invention relates to high pressure tubular reactor olefin polymerization plants having improved specific energy consumption. The plants may be newly constructed or made by de-bottlenecking an existing plant. The tube of the tubular reactor may have improved arrangements for cooling to increase conversion and optimized polymer-recycle gas separation arrangements using a jet pump for recycling unreacted monomer while permitting haze to be maintained. The improved cooling arrangements include a reduced pressure cooling zone forming the tail end of the tube and/or a shortened heating zone for the front feed and allowing more monomer to be fed as a side feed.
    Type: Application
    Filed: December 18, 2008
    Publication date: November 10, 2011
    Inventors: Henri A. Lammens, Tom Van Nuland, Ivo T. Goossens, Roger L. Claessens, Geert Vaes, Paul Jan Clymans
  • Publication number: 20110263800
    Abstract: [Summary] The present invention relates to an apparatus for manufacturing polymer particles and a method for manufacturing the same. The present invention provides an apparatus and a method, by which polymer particles having excellent monodispersity and homogeneous physical properties, such as homogeneous cross-linking degree and polymerization degree, may be efficiently prepared. In the present invention, particles having excellent monodispersity with the desired particle diameter, and also having a high cross-linking degree or a core-shell or core-double shell structure may also be effectively prepared. In addition, the processes for manufacturing said polymer particles are exceptionally reproducible in the present invention.
    Type: Application
    Filed: November 23, 2009
    Publication date: October 27, 2011
    Applicant: LG CHEM, LTD.
    Inventors: Jae Hoon Choe, Chang Houn Rhee, Jung Hyun Seo, Yoo Seok Kim, In Hyoup Song, Jung Uk Choi, Kwang Ho Song
  • Publication number: 20110243797
    Abstract: The apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The oligomerization reactor is in communication between a primary absorber column and a secondary absorber column in an FCC product recovery section. The oligomerization catalyst may have a low silica base with a Group VIIIB metal and operate at low pressure without excessive deactivation. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons.
    Type: Application
    Filed: March 31, 2010
    Publication date: October 6, 2011
    Applicant: UOP LLC
    Inventors: Joao Jorge da Silva Ferreira Alves, Christopher P. Nicholas
  • Patent number: 8030420
    Abstract: An olefin polymerization reaction unit includes a multistage gas phase polymerization reactor which is divided into two or more polymerization stages, in which polyolefin particles move from an initial stage to a final stage, and in which an olefin monomer-containing gas is fed from the final stage toward the initial stage. The reaction unit also includes first circulating means for feeding to the final stage a gas that is discharged from the initial stage and then cooled with a first heat exchanger, and second circulating means for feeding to one of the polymerization stages a condensate formed by condensing, with a second heat exchanger different from the first heat exchanger, a gas removed from one of the polymerization stages.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: October 4, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyuki Ogawa, Hideki Sato
  • Patent number: 8025847
    Abstract: Reactor systems suitable for the polymerization of an olefin monomer including first and second loop reactors effective for the polymerization of an olefin monomer and polymers formed therefrom are described herein.
    Type: Grant
    Filed: May 11, 2010
    Date of Patent: September 27, 2011
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Louis Fouarge, Carl VanCamp
  • Patent number: 8017717
    Abstract: Polyesters such as polyethylene, polypropylene and polybutylene terephthalate are made from melts of precondensates of polyesters by first conducting vapors comprising precondensate components distributed in the form of an aerosol through a polycondensation reactor in which precondensate components are deposited on the reactor wall and in an outlet chamber of the reactor on a separator. Then the deposits are conducted to the unstirred discharge sump. Upper layers of the discharge sump are continuously recirculated in the stirred reactor area and thus subjected to reconversion and further polycondensation.
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: September 13, 2011
    Assignee: Lurgi Zimmer GmbH
    Inventors: Fritz Wilhelm, Michael Reisen, Ludwig Hoelting, Peter Seidel, Peter Reichwein
  • Publication number: 20110213073
    Abstract: The invention provides a process for preparing polymers based on vinyl ester, ethylene and optionally further comonomers in the form of aqueous polymer dispersions thereof or of water-redispersible polymer powders by means of free-radically initiated continuous emulsion polymerization and optionally drying of the resulting polymer dispersions, characterized in that the emulsion polymerization is carried out in a cascade comprising at least one upstream heat exchanger and at least two downstream pressurized stirred tank reactors connected in series, such that the conversion on leaving the heat exchanger is at least 10% of the overall polymerization conversion.
    Type: Application
    Filed: August 11, 2008
    Publication date: September 1, 2011
    Applicant: Wacker Chemie AG
    Inventors: Hanns-Peter Weitzel, Robert Braunsperger
  • Patent number: 7993593
    Abstract: An olefin polymerization reactor of the present invention includes a cylinder which extends vertically, and a decreasing diameter member which is formed on the cylinder, has an inside diameter that decreases progressively downward and has a gas inlet orifice at a bottom end thereof. A spouted bed is formed inside a reaction zone enclosed by an inside surface of the decreasing diameter member and an inside surface of the cylinder above the decreasing diameter member.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: August 9, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hideki Sato, Hiroyuki Ogawa
  • Publication number: 20110172375
    Abstract: Described herein in one embodiment is a plant for the continuous solution polymerization of one or more monomers in a solvent, e.g., a hydrocarbon solvent. In one aspect, the plant comprises a high pressure pump and at least one heat exchanger downstream of the pump. In another aspect a feed is cooled by three heat exchangers which are refrigerated by means of a common three stage compressor. In another aspect, the plant comprises a primary reactor and a secondary reactor arranged to operate in parallel, in which the ratio of volume of the primary reactor to the secondary reactor is in the range of 60:40 to 95:5. In another aspect, a method of defouling a heat exchanger is provided in which the level of liquid refrigerant in the heat exchanger is temporarily lowered.
    Type: Application
    Filed: December 17, 2010
    Publication date: July 14, 2011
    Inventors: Richard Cheng-Ming Yeh, Bruce C. Devoy, Vetkav R. Eswaran, Rui Zhao
  • Patent number: 7977448
    Abstract: The invention relates to a continuous or discontinuous method for the production of highly condensed polyesters in the solid state, comprising a crystallization of a polyester material, wherein the crystallization is carried out in the presence of a gas with a dew point of (less than or equal to) ?approximately ?10° C. The invention also relates to a method for the production of polyester formed bodies using the polyester material obtained for the production of bottles, films and high strength threads.
    Type: Grant
    Filed: February 25, 2005
    Date of Patent: July 12, 2011
    Assignee: Lurgi Zimmer GmbH
    Inventors: Brigitta Otto, Hans Reitz, Holger Bachmann, Klaus Kirsten
  • Publication number: 20110166304
    Abstract: The present invention relates to a process for preparing unsaturated aldehydes or unsaturated carboxylic acids by heterogeneous catalytic gas phase oxidation of unsaturated or saturated hydrocarbons, comprising the process steps of: i) providing a gas mixture comprising a saturated hydrocarbon and catalytically dehydrogenating the saturated hydrocarbon in the gas phase to obtain a gas mixture comprising an unsaturated hydrocarbon in a dehydrogenation reactor having a dehydrogenation catalyst material; or ii) providing a gas mixture comprising oxygen and an unsaturated hydrocarbon; iii) catalytically oxidizing the unsaturated hydrocarbon obtained in process step i) or provided in process step ii) in the gas phase to obtain a gas mixture comprising an unsaturated aldehyde in a first oxidation reactor having a first oxidation catalyst material; wherein at least one of the reactors selected from the dehydrogenation reactor, the first oxidation reactor and the second oxidation reactor comprises at least one foam b
    Type: Application
    Filed: July 29, 2009
    Publication date: July 7, 2011
    Inventors: Horst-Werner Zanthoff, Nicole Brausch, Franz-Felix Kuppinger, Jorg Sauer, Andreas Sabbagh, Dennis Fruhling, Markus Weber, Oliver Becker
  • Publication number: 20110158856
    Abstract: A continuous polymerization apparatus is provided for producing an amphoteric electrolyte resin by continuous bulk polymerization at low cost, which apparatus includes a reaction vessel, the reaction vessel including at least four polymerization zones adjacent to each other in series, each polymerization zone being separated by a partition plate, the partition plates admitting a stirring shaft with stirrers, each of the polymerization zones having a thermosensor for sensing temperature within the polymerization zone, a heating device for heating the polymerization zone and a cooling device for cooling the polymerization zone.
    Type: Application
    Filed: December 29, 2010
    Publication date: June 30, 2011
    Inventors: Takashi SUNAMORI, Akira Otsuki, Akihiko Itaya
  • Patent number: 7964152
    Abstract: The present invention relates to a reactor apparatus for free-flowing media, especially for polymers, for polycondensation of polyesters, comprising a rotor which rotates in a reactor casing having an inlet and outlet, said rotor being supported horizontally via a support apparatus by means of stub shaft arrangements which reach beyond the end walls of the reactor casing, wherein annular film-forming elements and, between the annular film-forming elements, strippers are arranged on the inner surfaces of the reactor casing on the rotor, such that the cylindrical rotor has at least one partly heated section.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: June 21, 2011
    Assignee: Uhde Inventa-Fischer GmbH
    Inventor: Eike Schulz Van Endert
  • Patent number: 7939597
    Abstract: The present invention relates to a process for production of acrylic acid, comprising the steps of a) dehydration of glycerine to an acrolein-comprising dehydration product; b) gas phase oxidation of the dehydration product to obtain an acrylic acid-comprising monomer gas; c) bringing into contact of the monomer gas with a quench agent to obtain an acrylic acid-comprising quench phase; and d) work-up of the quench phase to obtain an acrylic acid-comprising monomer phase; whereby, during the dehydration a liquid phase a1 and a gas phase a2 is present, whereby in the liquid phase a1 a plurality of gas bubbles is generated, as well as a process for production of polymers by polymerization of acrylic acid, preferably for production of water-absorbing polymers, the water-absorbing polymers obtainable by this process, a composite, a process for production of a composite, the composite obtainable by this process, and further chemical products.
    Type: Grant
    Filed: August 22, 2007
    Date of Patent: May 10, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Günther Bub, Jürgen Mosler, Franz-Felix Kuppinger, Andreas Sabbagh, Guido Stochniol, Jörg Sauer, Markus Winterberg, Udo Knippenberg, Günter Latoschinski, Franck Furno, Thorsten Schwärtzke, Jörg Leistner
  • Patent number: 7931872
    Abstract: A polymerization processor synthesizes a high quality polymer from a raw material in a molten state. Lactide sent from an apparatus for supplying lactide 1 is heated and molten in an apparatus for melting lactide 2, and a catalyst is added to the lactide in an apparatus for supplying a catalyst 3. The molten lactide is supplied through an apparatus for supplying lactide 4 to a horizontal reaction tank 5, and flows by a head difference with a polymerization reaction proceeding. A discharged reaction solution is supplied to the upper part of a vertical reaction tank 6, and flows through the vertical reaction tank 6 by gravity with the polymerization reaction proceeding. Thereafter, the reaction solution is transported to an apparatus for removing remaining lactide 7, where unreacted lactide is removed, and then the reaction solution is discharged.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: April 26, 2011
    Assignee: Hitachi Plant Technologies, Ltd.
    Inventors: Toshiaki Matsuo, Takayuki Matsumoto, Naruyasu Okamoto
  • Patent number: 7919568
    Abstract: The current invention provides a method of improving the efficiency of one or more heat exchangers used in cooperation with a high temperature solution polymerization process. Addition of surface active agents, such as C6 to C22 carboxylic acids, to a two phase liquid-liquid polymer solution downstream of a reactor system and upstream of a heat exchanger system can increase the efficiency of heat exchange by more than 10%.
    Type: Grant
    Filed: August 19, 2008
    Date of Patent: April 5, 2011
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Eric Cheluget, Arun Sood
  • Publication number: 20110054071
    Abstract: The present invention relates to a method for the continuous production of a polymer by radical polymerization, wherein at least three materials are mixed with microstructures in one or more mixers and are then polymerized in at least one reaction zone.
    Type: Application
    Filed: April 30, 2009
    Publication date: March 3, 2011
    Applicant: BASF SE
    Inventors: Wolfgang Mattmann, Wolfgang Loth, Bolette Urtel, Elke Guetlich-Hauk, Christian Hubert Weidl, Andreas Daisse
  • Publication number: 20110054126
    Abstract: A final polymer product is formed using a two-stage process and system. In the first stage, a catalyst system is used to polymerize an alpha-olefin monomer to form an effluent. In the second stage, additional alpha-olefin monomer is supplied and is polymerized in the presence of the effluent from the first stage. The second stage produces the final polymer product, which may have a lower molecular weight and viscosity than the polymer foamed in the first stage. The final polymer product may be used as a base stock for lubricant compositions.
    Type: Application
    Filed: August 28, 2009
    Publication date: March 3, 2011
    Applicant: Chemtura Corporation
    Inventors: Daniel C. KNOWLES, Jesus R. FABIAN
  • Patent number: 7892498
    Abstract: A polyester production system employing a vertically elongated esterification reactor. The esterification reactor of the present invention is an improvement over conventional CSTR esterification reactors because, for example, in one embodiment, the reactor requires little or no mechanical agitation. Further, in one embodiment, the positioning of the inlets and outlets of the reactor provides improved operational performance and flexibility over CSTRs of the prior art.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: February 22, 2011
    Assignee: Eastman Chemical Company
    Inventor: Bruce Roger DeBruin
  • Publication number: 20110034657
    Abstract: A process for the polymerization of olefin's, including: introducing an olefin and a polymerization catalyst into a polymerization reactor to form a polyolefin, the polymerization reactor including: a fluidized bed region having a top and a bottom; and a motive bed region; wherein a first end of the motive bed region is fluidly connected to the top of the fluidized bed region; and wherein a second end of the motive bed region is fluidly connected to the bottom of the fluidized bed region; and wherein a diameter of the fluidized bed region is greater than a diameter of the motive bed region; circulating at least a portion of the olefin, the catalyst, and the polyolefin through the fluidized bed region and the motive bed region; maintaining a dense-phase fluidized bed within the fluidized bed region; recovering polyolefin from the fluidized bed region, is provided. A reactor system directed to the process is also provided.
    Type: Application
    Filed: April 21, 2009
    Publication date: February 10, 2011
    Applicant: UNIVATION TECHNOLOGIES, LLC
    Inventors: Fathi D. Hussein, Ping Cai, Jose F. Cevallos-Candau, Ian D. Burdett, W. Scott Hamilton, Daniel N. Thomas, JR.
  • Patent number: 7883873
    Abstract: The present invention provides a sugar chain synthesizer capable of continuously reacting sugar chains when a plurality of sugar chains are successively reacted. The sugar chain synthesizer of the present invention includes a plurality of vessels containing respective sugar nucleotide solutions, a plurality of vessels containing respective glycosyltransferases, and a reactor containing a primer that is a water-soluble polymer, into which the above described sugar nucleotide solution and glycosyltransferase are introduced. In the present invention, components in a reaction solution obtained in the reactor are separated through an ultrafiltration column, and a reaction product is then returned to the above described reactor, so as to continuously synthesize sugar chains. Although it is a complicated synthesis of sugar chains, it becomes possible to carry out such synthesis continuously and automatically.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: February 8, 2011
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Masanori Takaki, Kuriko Yamada, Kisaburo Deguchi, Hiroaki Nakagawa, Shinichiro Nishimura
  • Publication number: 20100316536
    Abstract: In an oligomerization process comprising at least two oligomerization reactors, at least portions of product streams from two reactors are separated in the same separator vessel. In an embodiment, a liquid product stream from the first oligomerization reactor is fed to a fractionation column and a side cut from the fractionation column feeds the second oligomerization reactor.
    Type: Application
    Filed: August 20, 2010
    Publication date: December 16, 2010
    Applicant: UOP LLC
    Inventors: Bipin V. Vora, Charles P. Luebke, Jill M. Meister, Michael A. Schultz, Dale J. Shields
  • Patent number: 7850926
    Abstract: A process for the discontinuous production of granules from polycondensation polymers by precondensation of an oligomer at 5 to 400 mbar and subsequent polycondensation in a stirring reactor and subsequent granulation. In the vicinity of the outlet port, the density of the entraining surfaces lies between 1 and 8 m2 per m3 reactor space and constantly increases with increasing distance from the discharge region. Inside the reactor, there is a viscosity gradient between the region most remote from the discharge port and the zone of the discharge port. The thermal decomposition of the polymer melt flowing out of the reactor is compensated during granulation. The stirring reactor with horizontal longitudinal axis approximately has the shape of a single or double truncated cone. The reactor has rotatable, vertical product entraining surfaces and stationary scrapers between the same.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: December 14, 2010
    Assignee: Lurgi Zimmer GmbH
    Inventors: Fritz Wilhelm, Ferdinand Finkeldei
  • Patent number: 7851514
    Abstract: The invention provides a process for producing a recycled resin, which includes: a first step of decomposing a resin composition containing a thermosetting resin in a supercritical or subcritical solvent having a monomer constituting the thermosetting resin or a derivative thereof as an essential component and a second step of adding a polyfunctional compound thereto to process; a recycled resin or a processed and recovered matter obtained according to the process for producing; a recycled resin composition formed from a recycled resin and/or a processed and recovered matter of the resin composition; and a method for recycling a resin composition, which reuses said recycled resin and/or said processed and recovered matter of a resin composition as a raw material of a recycled resin composition.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: December 14, 2010
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Junya Goto, Masaki Ishikawa, Kazunori Shimoyachi
  • Publication number: 20100311923
    Abstract: An olefin polymerization reactor according to the present invention comprises: a vertically extending cylinder; a decreasing diameter portion on the cylinder, having an inside diameter that decreases progressively downward, and having a gas inlet orifice at a bottom end thereof; and a plurality of through holes passing through from an outside surface towards an inside surface of the decreasing diameter portion. Inside a reaction zone enclosed by an inside surface of the decreasing diameter portion and an inside surface above the decreasing diameter portion of the cylinder, a spouted-fluidized bed or a spouted bed is formed.
    Type: Application
    Filed: June 7, 2010
    Publication date: December 9, 2010
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Hideki Sato, Hiroyuki Ogawa