Abstract: A down-fired flame burner includes a flame charger and one or more field electrodes configured to control flame shape and/or heat transfer to a chemical reactor.

Abstract: A system and method for producing Syngas from the CO2 in a gaseous stream, such as an exhaust stream, from a power plant or industrial plant, like a cement kiln, is disclosed. A preferred embodiment includes providing the gaseous stream to pyrolysis reactor along with a carbon source such as coke. The CO2 and carbon are heated to about 1330° C. and at about one atmosphere with reactants such as steam such that a reaction takes place that produces Syngas, carbon dioxide (CO2) and hydrogen (H2). The Syngas is then cleaned and provided to a Fischer-Tropsch synthesis reactor to produce Ethanol or Bio-catalytic synthesis reactor.

Abstract: A syngas treatment plant has a decarbonization section and a desulfurization section that use the same solvent to remove various acid gases. Contemplated methods and plants are highly effective in removal of CO2, recycle sulfurous contaminants to extinction. Minimal loss of H2 while maximizing H2S concentration in a Claus plant feed during regeneration of the solvent is achieved by stripping the solvent with both treated syngas and a flash vapor of the desulfurization section.

Abstract: The invention provides an integrated catalyst and membrane reactor for the production a predetermined gas such as hydrogen. The reactor comprises a gas flow channel, comprising a plurality of alternating catalyst sections and membrane sections, wherein each catalyst section comprises a catalyst bed and each membrane section comprises a plurality of membranes, and wherein the membranes are selectively permeable for the predetermined gaseous species.

Abstract: A food container (2) includes a rigid thermoformed plastics carton (4) which holds a dry food 6 and is closed by a removable film closure (8). The film (8) incorporates a hydride which is arranged to generate hydrogen on contact with moisture. Additionally, the film (8) is arranged to have relatively high water vapour permeability and relatively low hydrogen gas permeability. In use, water vapour from air surrounding the container (2) passes into the film (8) and reacts with the hydride to generate hydrogen. Due to the relatively low hydrogen permeability of the film (8), the hydrogen is restricted from escaping from the container. Instead, the hydrogen then reacts with any oxygen within the container in a reaction catalysed by a catalyst associated with the carton (4), thereby to scavenge oxygen within the container (2) and protect the food (6) from oxidation.

Abstract: Disclosed herein are (Ga1-xZnx)(N1-xOx) nanocrystals and syntheses and devices related thereto.

Abstract: The present invention provides an auxiliary power system to provide supplemental power by compressed hydrogen. The system includes a motor configured to be driven by the compressed hydrogen. The motor includes a cartridge for the generation of hydrogen. The cartridge is configured to generate high pressure and high temperature hydrogen. The motor is configured such that hydrogen generated by the cartridge is directed through a manifold and moves pistons in a cylinder block such that the cylinder block rotates. A clutch assembly is provided to transmit power from the motor.

Abstract: An apparatus for carrying out a carbon monoxide shift reaction, which includes converting carbon monoxide and water into carbon dioxide and hydrogen, the converting proceeding in a liquid phase with removal of a product gas including carbon dioxide and hydrogen, is provided. The apparatus includes dry methanol, as a first solvent in a first region for an absorption of carbon monoxide with simultaneous formation of methyl formate, and water, as a second solvent in a second region for a liberation of the product gas in order to avoid losses of hydrogen in a carbon dioxide region.

Abstract: A method of gasifying carbonaceous material is described. The method comprises a first step of pyrolysing and partially gasifying the carbonaceous material to produce volatiles and char. The volatiles and the char are then separated and, subsequently, the char is gasified and the volatiles are reformed. The raw product gas is then finally cleaned with char or char-supported catalysts or other catalysts.

Abstract: The moisture absorption capacity of biofuels can be more or less 10 times that of fossil diesel oil, causing biofuels to form acids that induce metal corrosion and form deposits in the fuel tank and pipe lines. Methods for removing moisture from stored biofuels and plant oils are described wherein glycerol is used as a solvent to extract the moisture from the bioliquid or oil, comprising the steps of placing the biofuel or oil in fluid contact with glycerol, incubating for a time, and then removing the glycerol. A cellulous ester dialysis or other semi-permeable membrane may be used to prevent the glycerol from contaminating the biofuel while allowing moisture to pass. Crude glycerol produced as a by-product of biodiesel production may be used in the method of the disclosed invention with good result. Preferred embodiments of apparatus that employ the method of the subject invention are described.

Abstract: The present invention provides a motor powered by an expandable, combustible gas. The motor includes a cartridge for the generation of hydrogen. The cartridge is configured to generate high pressure and high temperature hydrogen. The motor is configured such that hydrogen generated by the cartridge is directed into a series of expandable chambers defined by at least one flywheel. The flywheel is connected to a shaft such that power generated by the hydrogen can be transmitted out of the motor. The motor is configured such that power can be generated by expansion of the hydrogen and subsequent combustion of the hydrogen.

Abstract: An object of the present invention is to provide a fuel processor that can reduce reforming catalyst deterioration caused by thermal deformation of a structure. The fuel processor includes a reformer 8 that is fed with fuel gas 70 to refine hydrogen-rich reformed gas 73 by a reaction of a reforming catalyst 7. A plurality of partition plates 20 for dividing the reforming catalyst 7 are provided in a space filled with the reforming catalyst 7 between an internal cylinder 18 and an external cylinder 19. All the partition plates 20 are cantilevered from the external cylinder, preventing the partition plates 20 from coming into contact with each other in temperature variations. This can reduce deterioration such as crushing or powdering that is caused by a compressive stress of the reforming catalyst 7.

Abstract: A heat exchange apparatus is disclosed for use in the production of nitric acid and which provides for feed-effluent heat exchange and integrated nitrogen dioxide absorption. The apparatus includes a core structure having first and second groups of diffusion bonded corrosion resistant metal plates having fluid flow channel systems formed therein. A feed-effluent heat exchange system is provided by first channel systems of the first and second groups of plates being juxtaposed in heat exchange relationship and an absorption system is provided by second channel systems of the first and second groups of plates being juxtaposed in heat exchange relationship.

Abstract: A method for removing contaminants from industrial exhaust gas. The method includes contacting the exhaust gas with a mist of water and RNH2 (amine) to form a liquid solution of CO2. The method further includes extracting the liquid solution of CO2 and contacting the exhaust gas with granular activated carbon.

Abstract: An instrument for producing hydrogen-dissolved liquid comprises a hydrogen generating system stored in a separator, and the hydrogen generating system comprises: a hydrogen generating agent that reacts with raw water to generate hydrogen; a metal-ion sequestering agent that sequesters metal ions dissolved from the hydrogen generating agent; and a pH adjusting agent.

Abstract: This invention is directed to a sterilization method of contaminated areas with biological agents by making use of the acidic ozone water that very effectively kills spores of Bacillus atrophaeus, thereby demonstrating the capability of sterilizing a large surface-area in a very short time and reinstating the contaminated environment as free from toxic biological agents. The effective sterilization of the acidic ozone water is due to synergic benefits derived from the combination of ozone and acidity. The acidic ozone water can also effectively kill other ordinary microbes of viruses, bacteria, and fungi, hence being applicable to agriculture, seafood and livestock industries for the preservation of various products as well as being useful in hospitals or other germ infested areas for disinfections. Particularly, the acidity and ozone in the seawater sterilize microbes effectively, demonstrating a potential for the sterilization of a large amount of seawater in a short time.

Abstract: Embodiments of the invention provide filtering structures and methods. At least filtering structure includes a filtering medium for removing impurities from a gas produced by gasifying coal or biomass, and a catalyst for converting methane and carbon dioxide into synthesis gas by a dry reforming reaction and a steam reforming reaction. The filtering medium, according to various embodiments, is coated with the catalyst.

Abstract: In a gas separation apparatus that separates carbon dioxide and water vapor from a first mixture gas containing a predetermined major component gas, carbon dioxide, and water vapor, the energy utilization efficiency thereof is improved. Also, by utilizing the function of this gas separation apparatus, a membrane reactor and a hydrogen production apparatus exhibiting high energy utilization efficiency are provided. The gas separation apparatus is constructed to include a first separation membrane 33 and a second separation membrane 34 that are made of different materials. When the first mixture gas is supplied at a temperature of 100° C. or higher, the first separation membrane 33 separates a second mixture gas containing carbon dioxide and water vapor that permeate through the first separation membrane by allowing carbon dioxide and water vapor to permeate selectively.

Abstract: Present invention refers to a device and method for obtaining a mixture of hydrogen Hz and oxygen Oz through the activity of UV radiation on ice microcrystals. The device comprises a source of UV radiation (2); optical fibre (3) via which the UV radiation is directed from the source of the UV radiation (2) towards the chamber (10) containing the ice microcrystals subjected to the activity of the UV rays; internal chamber (6) in which water vapour is introduced via an injector, in which the internal chamber (6) is situated within the chamber (10) from which it is separated by longitudinal barriers (9); a rotating hollow cylinder (5) around whose perimeter fibres (4) are distributed, cooling device (7) that provides ice microcrystals on the fibres (4), where the cooling device (7) is placed within the rotating hollow cylinder (5) and the outflow (8) for the gaseous Oz and Hz towards the feeder.

Abstract: The present invention relates to a fuel manufacturing system and has an object to provide a fuel manufacturing system which can simplify in term of the system construction. An electrolytic solution having a property of absorbing CO2 is used in the system. Therefore, a mixed gas can be generated directly with the electrolytic solution in which CO2 has absorbed. In short, a CO2 absorbing process is only needed to execute, which is shown in FIG. 6. Thus, the mixed gas generating process can be simplified as compared to a system including the CO2 releasing process (FIG. 4, 5). And the system construction can be downsized since a device for the CO2 releasing process can be omitted.

Abstract: The present invention discloses an apparatus and method for treating perfluoro-compounds (PFCs). The method for treating PFCs includes: (a) decomposing PFCs and eliminating a first acid gas generated by the decomposition through a pre-cleaner; (b) filtering out dust particles from the exhaust gas through a filter; (c) electrifying the dust particles in the exhaust gas by electrical discharge and collecting dusts through a dust collector; (d) decomposing PFCs using a regenerative/catalytic reaction through a catalytic reactor; (e) eliminating a second acid gas generated by the regenerative/catalytic reaction through a post-cleaner; and (f) letting the purified exhaust gas out through a fan.

Abstract: A system and process are provided for extracting a substance from a molecular combination. The process comprises heating the molecular combination to dissociate the molecular combination into cations and anions, moving the cations and anions through a magnetic field to separate cations and anions, and isolating cations from anions with a barrier. The system comprises a non-conductive conduit for guiding an ionized particle stream, a magnetic field source for creating a magnetic field through which the ionized particle stream moves, and a barrier located in the conduit. The ionized particle stream has a velocity relative to the conduit, and the magnetic field source is oriented relative to the velocity of the ionized particle stream so that cations are separated from anions as the ionized particle stream moves through the magnetic field. The barrier is oriented in the conduit so that cations are isolated from anions after separation.

Abstract: Embodiments of a compact pressure swing reformer are disclosed. Certain embodiments have a construction comprising multiple rotating reformer beds, high temperature rotary valves at the bed ends, and E-seals to seal the beds to the valves. Several possible designs for introducing reactants into the beds also are disclosed. The multiple reformer beds are configured to provide for pressure equalization and ‘steam push’. The compact pressure swing reformer is suitable for use in fuel cell vehicle applications.

Abstract: A method and apparatus for gas-phase reduction/oxidation is disclosed. The apparatus includes a reactor including at least one reactor tube or containment vessel with active redox material within the reactor tube or containment vessel, a first reactant gas or vacuum for reducing the active redox material, and a second reactant gas for oxidizing the active redox material. The method may be run under substantially isothermal conditions and/or energy supplied to the apparatus may include solar energy, which may be concentrated.

Abstract: A fuel cell supply device that generates hydrogen for fuel cells in an aircraft includes a reaction chamber which reacts hydrogenated polysilanes or mixtures thereof with water; a feed device that feeds at least one reactant into the reaction chamber; and a discharge device that leads hydrogen formed in the reaction to a fuel cell.

Abstract: A method for feeding reducing agent or reducing agent precursor into exhaust systems of mobile internal combustion engines and an exhaust system are preferably used for internal combustion engines with high nitrogen oxide compound emissions. A feed time is established. An exhaust parameter and/or necessary quantity of reducing agent is determined and a feed state of the reducing agent is defined. The reducing agent is treated if the feed state does not correspond to a stored state. The reducing agent feed to the exhaust system takes place last. The steps are repeated multiple times. This permits reducing agent to be fed into an exhaust system in a state suitable for the exhaust temperature, so that complete conversion of reducing agent takes place and selectively catalytic reduction is also ensured. This reduces the quantity of electrical energy necessary for converting reducing agent. A motor vehicle having the system is also provided.

Abstract: A process for passivation of surfaces of heat exchange apparatus exposed to a synthesis gas containing carbon monoxide, includes the steps of: adding arsine to the synthesis gas to provide a total As concentration in the synthesis gas in range 0.001 to 10 ppmv, (ii) exposing the mixture of hot synthesis gas and arsine to the shell-side surfaces of said heat exchange apparatus to reduce the interaction between the carbon monoxide present in said gas and metals in said surfaces, (iii) recovering a cooled synthesis gas from the shell-side of said apparatus, and (iv) passing the cooled synthesis gas, optionally after further cooling, through a sorbent bed to remove arsenic compounds from the synthesis gas.

Abstract: The present invention is directed to the recovery of hydrocarbons wherein a portion of carbon is removed from the product by a combination of reforming and water-gas shift. The resulting carbon dioxide is removed by known techniques to provide a fuel having reduced levels of carbon.

Abstract: An integrated plant generates syngas from biomass, where the integrated plant includes a Thermo Mechanical Pulping (TMP) process, a biomass gasifier, a methanol synthesis process, and a liquid fuel generation process. Biomass is received as a feedstock in the TMP process. The biomass is pre-treated in the TMP process for subsequent supply to the biomass gasifier by using a combination of heat, pressure, moisture, and mechanical agitation that are applied to the biomass to make the biomass into a pulp form. The TMP process breaks down a bulk structure of the received biomass, at least in part, by applying steam to degrade bonds between lignin and hemi-cellulose from cellulose fibers of the biomass. Next, the broken down particles of the biomass are reacted in a biomass gasification reaction at a temperature of greater than 700 degrees C. to create syngas components, which are fed to a methanol synthesis process.

Abstract: A nozzle reactor includes a passage having one or more regions with a converging-diverging shape. The nozzle reactor accelerates a reacting fluid to supersonic velocities and mixes it with a feed material. The reacting fluid and the feed material may be pre-heated. The high speed collision between the reacting fluid and the feed material at elevated temperatures causes the materials to react.

Abstract: A process is described for the passivation of the surfaces of heat exchange apparatus exposed to a synthesis gas containing carbon monoxide and hydrogen, including the steps of: (i) adding an arsenic compound to the synthesis gas at a temperature ?850° C. to generate volatile arsenic passivation species, (ii) exposing the mixture of hot synthesis gas and arsenic passivation species to surfaces on the shell-side of said heat exchange apparatus to reduce the interaction between the carbon monoxide present in said gas and metals said in said surfaces, (iii) recovering a cooled synthesis gas from the shell-side of said apparatus, and (iv) passing the cooled synthesis gas, optionally after further cooling, through a sorbent bed to remove arsenic compounds from the synthesis gas.

Abstract: The invention is directed to a method for photocatalytic water splitting, and to an apparatus for carrying out said method.

Abstract: Systems, devices, and methods combine thermally stable reactant materials and aqueous solutions to generate hydrogen and a non-toxic liquid by-product. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Springs and other pressurization mechanisms pressurize and deliver an aqueous solution to the reaction. A check valve and other pressure regulation mechanisms regulate the pressure of the aqueous solution delivered to the reactant fuel material in the reactor based upon characteristics of the pressurization mechanisms and can regulate the pressure of the delivered aqueous solution as a steady decay associated with the pressurization force.

Abstract: A manufacturing facility for quicklime is provided, which can manufacture highly active quicklime by a simple manufacturing facility, and which can also separate and recover, in a high concentration, CO2 gas generated at the time of manufacturing quicklime.

Abstract: A double helix gas hydrate reactor is disclosed. The reactor includes an inlet port (510) into which water and gas are supplied, an outlet port (540) disposed opposite the inlet port, a hollow jacket (580) extending from the inlet port to the outlet port, a hollow outer helix (550) installed in the hollow jacket, and an inner helix (560) installed in the outer helix. The gas and water that are supplied into the inlet port react with each other to form gas hydrate in a channel defined between the inner helix and the hollow jacket.

Abstract: A thermochemical reactor (4) and associated processes are disclosed. The reactor (4) and processes are used to conduct reactions relating to the hydrolysis of cupric chloride (CuCl2) within any one of the five-, four- and three-step Cu—Cl cycles. The reactor (4) comprises a reaction chamber (22) including a first zone (24) configured to conduct a spray operation and a second zone (26) configured to conduct a fluidized, fixed and/or moving bed operation. The first zone (24) includes a first inlet (28) configured to introduce a first reactant and an additional inlet (30) configured to introduce an additional reactant. A distributor (34) is configured to introduce the additional reactant to the second zone (26). One or more product outlets (44, 46) for communication with the reaction chamber (22) are provided.

Abstract: A reaction system suitable for production of a methionine salt contains a reactive rectification column containing a weir having a height of 100 mm or more.

Abstract: A tar destruction unit for a biomass gasifier is described, comprising a catalyst and/or heating means situated within the free-board section of the gasifier. Also described is a biomass gasifier having such a tar destruction unit.

Abstract: Partial oxidation/steam reformers (222) which use heat integrated steam cycles and steam to carbon ratios of at least about 4:1 to enable efficient operation at high pressures suitable for hydrogen purification unit operation such as membrane separation (234) and pressure swing adsorption.

Abstract: A polyethylene terephthalate container having a hydrogen generator and catalyst disposed or otherwise incorporated in components of the container. The container further comprises an activation system or means for activating the hydrogen generator and/or catalyst system at a predetermined time or in response to a predetermined stimulus.

Abstract: A process and a device are described for producing high purity and high temperature steam from non-pure water which may be used in a variety of industrial processes that involve high temperature heat applications. The process and device may be used with technologies that generate steam using a variety of heat sources, such as, for example industrial furnaces, petrochemical plants, and emissions from incinerators. Of particular interest is the application in a thermochemical hydrogen production cycle such as the Cu—Cl Cycle. Non-pure water is used as the feedstock in the thermochemical hydrogen production cycle, with no need to adopt additional and conventional water pre-treatment and purification processes. The non-pure water may be selected from brackish water, saline water, seawater, used water, effluent treated water, tailings water, and other forms of water that is generally believed to be unusable as a direct feedstock of industrial processes.

Abstract: A method and apparatus for eliminating COS and/or CS2 from a hydrocarbon-containing feed stream, and further eliminating H2S from such feed stream or converting all sulfur species in such feed stream to H2S and SO2 to allow for easy subsequent conversion of such H2S and SO2 to elemental sulfur in a Claus reaction. The method comprises: (i) injecting water so that the feed stream contains greater than 10 vol % (water equivalent); (ii) passing the feed stream through catalyst means which hydrogenates COS and/or CS2 to H2S; (iii) injecting O2 so that the stoichiometric ratio of O2 to H2S is at least 0.5:1.0; (iv) passing the stream though a reaction zone having oxidation catalyst means which oxidizes H2S to elemental sulfur or SO2 (depending on the amount of oxygen and water added); where the temperature of the reaction zone is above the elemental sulfur dew point.

Abstract: In one embodiment, an assembly for use with a lean NOx catalyst (LNC) is described. An outer tube is coupled to the LNC. An inner tube is disposed completely inside the outer tube. The exhaust flow is split between the inner tube and the outer tube. The inner tube houses a catalytic fuel vaporizer and a catalytic fuel reformer that convert at least a portion of the injected hydrocarbons to hydrogen and carbon monoxide, and vaporized hydrocarbons for NOx reduction.

Abstract: A process for the efficient capture of CO2 and sulfur from combustion flue gas streams and gasification based fuel gas mixtures using regenerable and recyclable calcium based sorbents. The regeneration of the calcium sorbent is accomplished by hydrating the sorbent at high temperatures of about 600° C. and a pressure higher than 6 bars to lower the parasitic energy consumption.

Abstract: A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

Abstract: A steam reformer tube assembly includes a reformer tube including a wall defining an interior space for receiving fluid delivered into the reformer tube, a plug at least partially positioned in an opening in the interior space such that a gap is defined between the plug and the wall of the reformer tube, and a sealing member positioned in the gap to either limit or prevent the passage of fluid toward the opening in the interior space of the reformer tube and along the gap that is defined between the exterior surface of the plug and the interior wall of the reformer tube. A method of assembling a steam reformer tube assembly is also provided.

Abstract: Embodiments are disclosed that relate to a compact steam boiler which may provide steam to a steam reformer in a fuel cell system. For example, one disclosed embodiment provides a steam boiler including an outer shell and a first inner tube and a second inner tube within the outer shell, the first and second inner tubes spaced away from one another. The steam boiler further includes a twisted ribbon positioned inside each of the first and second inner tubes.

Abstract: The subject of the invention is a method for reduction of the CO2 content of flue and atmospheric gases and equipment for application of the method. The characteristic of the solution according to the invention is, that “hydroxide” ionized water containing (OH?) ions of alkaline characteristics is used as reaction medium for binding carbon dioxide (CO2) gas, and carbon dioxide (CO2) gas gets into reaction with alkaline ionized water, and during the reaction from the carbon dioxide (CO2) gas and water, carbonate ion (CO32?) and hydrogencarbonate/bicarbonate (2HCO3?) are formed, and they leave for the outside atmosphere and/or outside water with the bound CO2 content in stable gas or liquid form.

Abstract: The present invention provides assembly for use with a cartridge for the generation of hydrogen and a method for bonding metals with the cartridge. The cartridge includes a case, an igniter, and a structural component. The case defines an interior cavity and the igniter is positioned within the cavity. The structural component is also positioned within the cavity and is formed of a particulate embedded in a matrix and the particulate includes a metallic material. An oxidizing agent is positioned within the cavity. The structural component is configured such that the metallic material and the oxidizing agent react together to generate hydrogen after the igniter generates sufficient heat to remove the matrix from the structural component and to initiate the reaction between the metallic material and the oxidizing agent. The cartridge is positioned within the assembly relative to a metal flyer such that when the cartridge is discharged, the flyer is bonded to a metal anvil.

Abstract: To enable long-term continuous operation by preventing blocking of a reaction pipe line disposed in a multi-pipe or double-walled-pipe heat exchanger, provided is a device for producing gas hydrate including a multi-pipe or double-walled-pipe device 1 for generating gas hydrate having a reaction pipe line 2 for flowing raw material water w and raw material gas g and a coolant circulation region 3 for circulating a coolant c and thereby cooling the reaction pipe line 2, wherein a coil spring 4 extending in the longitudinal direction of the reaction pipe line 2 is provided in the reaction pipe line 2.