And Means Downstream Of A Stage For Injecting A Reactant Into Waste Gas For Interreaction In Subsequent Stage Patents (Class 422/172)
  • Patent number: 6391266
    Abstract: A limestone furnace calcination process involves injecting finely divided limestone particles into a zone in a furnace at which the temperature of the flue gas stream, as it passes through the zone, is above the minimum calcination temperature and below the minimum effective quicklime utilization/sulfation temperature. In conventional furnaces, the minimum calcination temperature, or the calcium carbonate decomposition temperature, ranges from about 1,365 to 1,430° F. The minimum effective quicklime utilization/sulfation temperature refers to the temperature below which the rate of quicklime sulfation of the lime produced by calcination of the limestone is sufficiently slow to result in negligible calcium sulfate formation on the resultant lime, and in conventional furnace applications ranges from 1,600 to 1,800° F.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: May 21, 2002
    Assignee: Black & Veatch Corporation
    Inventor: Lloyd L. Lavely, Jr.
  • Patent number: 6387335
    Abstract: A hopper for collecting soot included in the exhaust gasses is disposed on a lower portion of a filter. There is a backwashing means for introducing a compressed air into the filter from the exhaust gas-downstream side through an air conduit and dropping the soot deposited in the filter on to the hopper. A combustion pipe is disposed on a lower end of the hopper, and an air nozzle for supplying a combustion air is disposed in the combustion pipe. A combustion medium which is capable of collecting the soot arriving at the combustion pipe and the burned ashes and of letting the combustion air pass therethrough is inserted detachably into the combustion pipe and arranged on a porous ceramic plate. A heater is disposed around the combustion pipe for burning the soot which is collected by the combustion medium. The soot is burned completely at the combustion medium, and most of the ashes remain at the combustion medium and the rest of the ashes is completely collected by the plate.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: May 14, 2002
    Assignee: Hino Motors, Ltd.
    Inventors: Jun Ichikawa, Toshio Igarashi
  • Patent number: 6383463
    Abstract: A process for the denitration of combustion exhaust gas from combustion equipment by passing the exhaust gas through an ammonia reduction denitrator, comprises providing a bypass having a low-temperature denitrator installed therein; while the temperature of the exhaust gas is not high enough to allow the ammonia reduction denitrator to function properly, as encountered immediately after starting the combustion equipment, passing the exhaust gas through the bypass to perform the denitration thereof by means of the low-temperature denitrator; when the ammonia reduction denitrator has come to function properly, closing the bypass to perform the denitration of the exhaust gas by means of the ammonia reduction denitrator; and regenerating a catalyst within said low-temperature denitrator while the by-pass is closed.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: May 7, 2002
    Assignees: Mitsubishi Heavy Industries, Ltd., Osaka Gas Company Limited
    Inventors: Isao Mochida, Akinori Yasutake, Toshihiko Setoguchi, Norihisa Kobayashi, Hitoshi Nakamura, Takahiro Kasuh, Masaaki Yoshikawa
  • Patent number: 6375904
    Abstract: A wastewater collection system is provided with a gas withdrawal vent including a gas suction apparatus. The gas is preferably withdrawn at a rate in excess of the gas production by microbes in the wastewater collection system so that a slight negative pressure is created in the immediate vicinity of the gas withdrawal vent. A gas mixing chamber is coupled to the fan or blower to receive the gas withdrawn from the wastewater collection system. An ozone generation apparatus is also coupled to the gas mixing chamber that is adjusted to provide sufficient ozone to react with any noxious or malodorous components of the withdrawn gas. A reaction conduit is provided at an output of the gas mixing chamber to receive the withdrawn gas and ozone. The reaction conduit has surface features assuring turbulent flow of the gasses through the length of the conduit.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: April 23, 2002
    Assignee: Airtex Manufacturing, Inc.
    Inventors: David B. Skillman, Henry A. Berman, William C. Weaver
  • Publication number: 20020044897
    Abstract: A diesel engine aftertreatment exhaust system uses catalyzed soot filters for particulate matter reduction and urea SCR catalysts for NOx reduction on diesel engines in a combined system to lower particulate matter and NOx at the same time. With this integral emission control system, diesel engines are able to meet ultra low emission standards.
    Type: Application
    Filed: March 23, 2001
    Publication date: April 18, 2002
    Inventors: Ramesh M. Kakwani, Kenneth C. Voss, Joseph A. Patchett, Karl R. Grimston
  • Patent number: 6372187
    Abstract: A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: April 16, 2002
    Assignee: McDermott Technology, Inc.
    Inventors: Deborah A. Madden, Michael J. Holmes
  • Publication number: 20020037241
    Abstract: A catalytic converter of the type having an inlet plenum between a converter inlet and an axial inlet face of a substrate and an outlet plenum between a converter outlet and an axial outlet face of the substrate, wherein a first axial length of the inlet plenum is in a range of 20-40% of the first axial length of the inlet plenum summed with a second axial length of the outlet plenum to minimize flow resistance in said catalytic converter.
    Type: Application
    Filed: October 26, 1998
    Publication date: March 28, 2002
    Inventors: MICHAEL RALPH FOSTER, SCOTT CHRISTOPHER BLANCHET
  • Publication number: 20020031454
    Abstract: A nitrogen oxide reducing system of a diesel engine can reduce nitrogen oxide contained in an exhaust gas of the diesel engine and whereby cab adapt to a restriction. At a tip end of a mixer, air holes required by the engine are formed, a nitrogen gas generating device for increasing concentration of nitrogen in the air is mounted to introduce nitrogen into the mixer, the mixer is mounted to the induction opening of the engine at opposite side of the air hole to introduce increased amount of nitrogen to prevent oxidation of nitrogen and discharge nitrogen.
    Type: Application
    Filed: February 13, 2001
    Publication date: March 14, 2002
    Inventors: Toshiaki Ooe, Tokanori Iima
  • Patent number: 6348177
    Abstract: A lean sulfur trap and a rich sulfur trap are arranged to prevent the passage of sulfur-containing exhaust gases through a sulfur-sensitive component of an aftertreatment system. After a determined period of operation, the lean sulfur trap and rich sulfur trap are purged in sequential operations, during which time exhaust gas flow is diverted around the sulfur-sensitive component, and then restored after purging of the traps.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: February 19, 2002
    Assignee: Southwest Research Institute
    Inventors: Gordan James J. Bartley, Magdi K. Khair
  • Publication number: 20020018737
    Abstract: An effluent gas stream treatment system for treatment of gaseous effluents such as waste gases from semiconductor manufacturing operations. The effluent gas stream treatment system comprises a pre-oxidation treatment unit, which may for example comprise a scrubber, an oxidation unit such an electrothermal oxidizer, and a post-oxidation treatment unit, such as a wet or dry scrubber. The effluent gas stream treatment system of the invention may utilize an integrated oxidizer, quench and wet scrubber assembly, for abatement of hazardous or otherwise undesired components from the effluent gas stream. Gas or liquid shrouding of gas streams in the treatment system may be provided by high efficiency inlet structures.
    Type: Application
    Filed: October 4, 2001
    Publication date: February 14, 2002
    Inventors: Mark Holst, Kent Carpenter, Scott Lane, Prakash V. Arya
  • Publication number: 20020007731
    Abstract: The invention is in an apparatus for the remediation of particulate material and gaseous pollutants from a flue gas flow that is simple and highly efficient in removing nearly all toxic pollutants, particularly sulfur dioxide, from a flue gas flow, and includes a manifold that is to receive and pass a polluted flue gas flow that mounts an injector that is fitted into the manifold wall to inject finely ground sorbent materials counter-current to the flue gas flow, creating turbulence and a thorough mixing to effect compaction and/or agglomerization of the pollutant and sorbent particles.
    Type: Application
    Filed: June 26, 2001
    Publication date: January 24, 2002
    Inventors: Richard A. Steinke, Christian Plank, Christian Bergemann
  • Publication number: 20020006363
    Abstract: A method of at least periodically removing from a lean gaseous stream a sorbable component such as SOx includes passing the gaseous stream through a trap member having an oxidation catalyst combined with a sorbent material at a temperature within the sorbing temperature range of the sorbent material. The sorbed component is periodically removed by introducing a combustible component into the gaseous stream and oxidizing it on the trap member to thermally desorb the sorbed component. The amount of combustible component introduced is limited to maintain the gaseous stream composition lean, but is sufficient to increase the surface temperature of at least part of the trap member to above the bulk temperature of the gaseous stream. Sorbing and desorbing periods are alternated and a composition and an apparatus to carry out the process is provided.
    Type: Application
    Filed: March 4, 1998
    Publication date: January 17, 2002
    Inventors: JENNIFER S. FEELEY, ROBERT J. FARRAUTO, MICHEL DEEBA, JORDAN K. LAMPERT
  • Publication number: 20020004024
    Abstract: In an exhaust-gas cleaning system and method for performing desulphating operations, a catalytic converter having oxidation properties is connected downstream of an NOx-adsorber, and a secondary-air feed device is provided between the NOx-adsorber and the catalytic converter having oxidation properties. The feed device is connected to a control device so that secondary air is introduced between the NOx-adsorber and the catalytic converter having oxidation properties during the desulphating operations.
    Type: Application
    Filed: May 18, 2001
    Publication date: January 10, 2002
    Inventor: Andreas Hertzberg
  • Patent number: 6334410
    Abstract: An exhaust heat recovery boiler in which an exhaust gas discharged from a gas turbine into a boiler duct to recover a heat of the exhaust gas and ammonia is injected to and mixed with the exhaust gas to reduce nitrogen oxide contained in the exhaust gas, the exhaust heat recovery boiler comprising: a boiler duct of a horizontal installation type having an inner hollow portion along which an exhaust gas flows from an upstream side to a downstream side; a superheater; an evaporator; a denitration reactor; and an economizer, which are disposed inside the boiler duct in this order from the upstream side to the downstream side of the exhaust gas flow therein. A drum is disposed outside the boiler duct and connected to the evaporator and a downcomer pipe extending from the drum into the boiler duct.
    Type: Grant
    Filed: December 4, 2000
    Date of Patent: January 1, 2002
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hideaki Shimada, Norihide Egami, Takayuki Nagashima
  • Patent number: 6333010
    Abstract: An effluent gas stream treatment system for treatment of gaseous effluents such as waste gases from semiconductor manufacturing operations. The effluent gas stream treatment system comprises a pre-oxidation treatment unit, which may for example comprise a scrubber, an oxidation unit such an electrothermal oxidizer, and a post-oxidation treatment unit, such as a wet or dry scrubber. The effluent gas stream treatment system of the invention may utilize an integrated oxidizer, quench and wet scrubber assembly, for abatement of hazardous or otherwise undesired components from the effluent gas stream. Gas or liquid shrouding of gas streams in the treatment system may be provided by high efficiency inlet structures.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: December 25, 2001
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Mark Holst, Kent Carpenter, Scott Lane, Prakash V. Arya
  • Patent number: 6332901
    Abstract: A carbon monoxide reducing device supplies oxygen to a reformate gas obtained through a reforming reaction so as to oxidize carbon monoxide contained in the reformate gas by means of the oxygen and thereby reduces a concentration of carbon monoxide contained in the reformate gas. This carbon monoxide reducing device is equipped with an oxygen supply amount controller designed to oxidize CO. The oxygen supply amount controller controls an amount of oxygen supplied to oxidize carbon monoxide contained in the reformate gas based on an amount of supply of fuel contributing to the reforming reaction. Thereby, the amount of oxygen for oxidizing carbon monoxide contained in the reformate gas is adjusted appropriately, and a high-quality reformate gas can be obtained.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: December 25, 2001
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Kiyomi Nagamiya, Masashi Yamashita, Iwao Maeda, Masaaki Yamaoka, Masayoshi Taki, Satoshi Aoyama, Yasushi Araki
  • Publication number: 20010051115
    Abstract: A NOx removal system for boilers in which the need for any special heat retention means or any warming means is eliminated. Ammonia jet nozzles 7 are disposed on a gas passage (5) of a boiler (1) or flue (6), and ammonia generating means (8) connected to the jet nozzles (7) is disposed within the flue (6).
    Type: Application
    Filed: March 8, 2001
    Publication date: December 13, 2001
    Inventors: Satoshi Wakasa, Noboru Takubo, Yukihiro Isshiki, Kouichi Masuda, Nobuyuki Ishizaki
  • Patent number: 6325985
    Abstract: A method and an apparatus for reducing NOx emissions in CFB reactors used for combusting fuel at atmospheric pressure. The CFB reactor includes a combustion chamber having a fluidized bed of particles therein, a particle separator section including one or more consecutive particle separators, a convection section and a clean gas duct connecting the particle separator to the convection section. The apparatus also includes a device for injecting ammonia or its precursor into the flue gases, for reducing NOx therein. The ammonia or its precursor is injected into the clean gas duct connecting the last separator to the convection section, the clean gas duct having a very small density of solid particles herein. The temperature in the clean gas duct is sufficient for NOx reducing reactions.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: December 4, 2001
    Assignee: Foster Wheeler Energia Oy
    Inventors: Jari Koskinen, Harri Vilokki
  • Patent number: 6325967
    Abstract: A process and apparatus for incinerating certain volatile organic compounds especially odorants commonly used in the natural gas industry. The procedure uses a first (car bottom) furnace as a heating chamber, where precise temperature control during both low and high temperature process stages ensures safe and controlled feed of volatile substances into a second (primary) furnace for incineration. The combustion process is completed in an afterburner and all generated gases are scrubbed in a conventional wet scrubber.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: December 4, 2001
    Assignee: Material Resource Recovery SRBP Inc.
    Inventor: Jan Strmen
  • Patent number: 6325973
    Abstract: An apparatus for performing a binding assay for an analyte of interest in a sample based upon measurement of clectrochemiluminescence at an electrode surface comprising: (a) a cell defining a sample; (b) an electrode adjacent a portion of the sample containing volume; (c) a voltage control device for impressing electrochemical energy upon the electrode sufficient to generate luminescence; (d) means for magnetically collecting particles along the electrode surface; and (e) a light detection device for measuring the luminescence.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: December 4, 2001
    Assignee: IGEN International, Inc.
    Inventors: John K. Leland, Haresh P. Shah, John H. Kenten, Jack E. Goodman, George E. Lowke, Yuzaburo Namba, Gary F. Blackburn, Richard J. Massey
  • Patent number: 6322756
    Abstract: An effluent gas stream treatment system for treatment of gaseous effluents such as waste gases from semiconductor manufacturing operations. The effluent gas stream treatment system comprises an oxidation unit to which an oxygen-containing gas such as ozone may be added, with input of energy (e.g., thermal, radio frequency, electrical, microwave, etc.), to effect oxidation of oxidizable species in the effluent, such as halocompounds (e.g., chlorofluorocarbons, perfluorocarbons), CO, NF3, nitrogen oxides, and sulfur oxides). The effluent gas stream treatment system may include a wet scrubber associated with the oxygen-containing gas source, so that the gas stream is contacted with the oxygen-containing gas during the wet scrubbing operation, to enhance removal of oxidizable species in the gas stream during treatment.
    Type: Grant
    Filed: May 7, 1999
    Date of Patent: November 27, 2001
    Assignee: Advanced Technology and Materials, Inc.
    Inventors: Jose I. Arno, Mark Holst, Kent Carpenter, Scott Lane
  • Publication number: 20010043890
    Abstract: A purification system of exhaust gases in an internal combustion engine is disposed to a reaction furnace capable of reducing noxious components of the exhaust gases in an exhaust pipe of the internal combustion engine in order to purify the exhaust gases. The purification system comprises a reactor including a honeycomb carrier having a plurality of carrier cells, each of which a photocatalyst layer is coated, in the reaction furnace, and a plasma generating means having a plurality of electrode cells and mounted on an inner end and an outer end of the honeycomb carrier. The honeycomb carrier includes a photocatalyst layer coated on a wall surface of each of the carrier cells, the photocatalyst layer being activated by a plasma optical source. Further, a volume and a number of each of the electrode cells are varied depending upon the variation of that of each of the carrier cells, the carrier cells having 100-900 numbers per the unit area(1 inch×1 inch).
    Type: Application
    Filed: May 24, 2001
    Publication date: November 22, 2001
    Inventor: Geon Seog Son
  • Publication number: 20010031228
    Abstract: An exhaust gas containing a perfluoride component (PFC) and SiF4 is conducted into a silicon remover and brought into contact with water. A reaction water supplied from a water supplying piping and air supplied from an air supplying piping are mixed with the exhaust gas exhausted from the silicon remover. The exhaust gas containing water, air, and CF4 is heated at 700° C. by a heater. The exhaust gas containing PFC is conducted to a catalyst layer filled with an alumina group catalyst. The PFC is decomposed to HF and CO2 at a high temperature exhausted from the catalyst layer is cooled in a cooling apparatus. Subsequently, the exhaust gas is conducted to an acidic gas removing apparatus to remove HF. In this way, the silicon component is removed from the exhaust gas before introducing the exhaust gas into the catalyst layer. Therefore, the surface of the catalyst can be utilized effectively, and the decomposition reaction of the perfluoride compound can be improved.
    Type: Application
    Filed: May 16, 2001
    Publication date: October 18, 2001
    Inventors: Kazuyoshi Irie, Toshihiro Mori, Hisao Yokoyama, Takayuki Tomiyama, Toshihide Takano, Shin Tamata, Shuichi Kanno
  • Patent number: 6303083
    Abstract: A method and system for removing SO3 and SO2 from a flue gas produced by the burning of a fossil fuel. Particulates are removed from the flue gas to produce partially cleaned flue gas. A sufficient amount of calcium-based, sodium based or magnesium-based dry sorbent, preferably having a particle size larger than 1.0-2.0 microns, is injected into the flue gas to react with and remove substantially all of the SO3 from the partially cleaned flue gas to produce a substantially SO3-free flue gas containing reacted and unreacted dry sorbent. The substantially SO3-free flue gas is conveyed to wet scrubber means for removing SO2 to produce cleaned flue gas. In a first embodiment, sufficient dry sorbent is provided to remove desired amounts of SO3 and SO2.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 16, 2001
    Assignee: The Babcock & Wilcox Company
    Inventors: Dennis Wayne Johnson, Pervaje Ananda Bhat, Thomas Robert Goots
  • Patent number: 6299853
    Abstract: A system for generating hydrogen-rich gas has a reformer for catalytic water vapor reforming of a water vapor/fuel mixture by an input supply of thermal energy, and a CO oxidation stage for removing carbon monoxide from the hydrogen-rich gas while emitting heat, with the reformer and the CO oxidation stage being thermally coupled. An oxygen quantity fed to the CO oxidation stage is adjusted as a function of the gas temperature in or at the output of the reformer/oxidation stage. This can take place by an automatic (feedback) control, a combination of open loop control and automatic control or by an adaptive characteristic diagram.
    Type: Grant
    Filed: October 13, 1999
    Date of Patent: October 9, 2001
    Assignee: Xcellsis GmbH
    Inventors: Stefan Boneberg, Stefan Brauchle, Dirk Georg, Joachim Guertler, Martin Schaefer, Martin Schuessler, Matthias Wolfsteiner
  • Patent number: 6294135
    Abstract: A small-scale scrapped tire boiler system for heating a small-scale facility using heat generated by burning scrapped tires. The system includes a scrapped tire burner furnace, a heat exchanger for heating a cool heat transfer medium from the facility by the combustion gas from the furnace and supplying the heated medium to the facility, and an exhaust gas purifier for purifying sulfurous acid gas and carbon dust contained in exhaust gas. The purifier includes an exhaust gas tower having a vertical path to discharge the combustion gas, a water sprayer for spraying water from the upper side of the tower so that the sulfurous acid gas is made to melt to water and the carbon dust is made to adsorb to fall down, a neutralizer for precipitating sulfurous acid gas components into alkali salts in a sulfurous acid aqueous solution to thereby neutralize water, and a tank containing the solution and water.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: September 25, 2001
    Inventors: Seungki Joo, Doyoung Yoon, Changwon Park, Yongchurl Kim
  • Patent number: 6294373
    Abstract: The invention relates to a method for biological cleaning of a contaminated gas flow containing gaseous and/or particulate contaminants comprising the steps of contacting the contaminated gas flow counter-currently with a jet of suitable microorganism-containing scrubbing liquid in order to enhance absorption of gaseous and particulate contaminants in the scrubbing liquid; recovering the scrubbing liquid in a vessel; draining part of the scrubbing liquid from the vessel and compensating the drained part with fresh liquid. The method is carried out in a reverse jet scrubber and does not use any packing material for support to the microorganisms.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: September 25, 2001
    Assignee: Mansanto Europe S.A.
    Inventor: Christianus Petrus Maria van Lith
  • Patent number: 6289850
    Abstract: An exhaust heat recovery boiler in which an exhaust gas discharged from a gas turbine into a boiler duct to recover a heat of the exhaust gas and ammonia is injected to and mixed with the exhaust gas to reduce nitrogen oxide contained in the exhaust gas, the exhaust heat recovery boiler comprising: a boiler duct of a horizontal installation type having an inner hollow portion along which an exhaust gas flows from an upstream side to a downstream side; a superheater; an evaporator; a denitration reactor; and an economizer, which are disposed inside the boiler duct in this order from the upstream side to the downstream side of the exhaust gas flow therein. A drum is disposed outside the boiler duct and connected to the evaporator and a downcomer pipe extending from the drum into the boiler duct.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: September 18, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hideaki Shimada, Norihide Egami, Takayuki Nagashima
  • Patent number: 6284199
    Abstract: A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: September 4, 2001
    Assignee: McDermott Technology, Inc.
    Inventors: William Downs, Ralph T. Bailey
  • Publication number: 20010018033
    Abstract: The invention provides a NOx removal system for use in a boiler for realizing further reduction in NOx. Loading means for loading a reducing agent is provided at the outlet of a gas passageway in the boiler body, and a NOx removal catalyst is provided downstream of the loading means.
    Type: Application
    Filed: February 12, 2001
    Publication date: August 30, 2001
    Inventors: Satoshi Wakasa, Noboru Takubo, Yukihiro Isshiki, Kouichi Masuda, Nobuyuki Ishizaki
  • Patent number: 6277335
    Abstract: The invention concerns a process and unit for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, the catalyst being in a moving bed, comprising combustion, oxychlorination and calcining steps, in which at least one chlorinating agent, at least one oxygen-containing gas, and water are introduced into the oxychlorination step such that the H2O/HCl molar ratio is 1 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600° C., and in which the combustion step is carried out in at least two combustion zones, each zone being separated from the adjacent zones, and at least one gas charged with oxygen is introduced into each zone, the gases produced being extracted from each zone, and in which the severity of the operating conditions increases in the direction of flow of the catalyst.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: August 21, 2001
    Assignee: Institut Francais de Petrole
    Inventors: Marianne Capelle, Jean-Marie Deves, Frédéric Hoffmann, Michel Thery, François-Xavier Brunet, Emmanuelle Bromet
  • Publication number: 20010014298
    Abstract: An exhaust-gas cleaning installation and a process for the catalytic reduction of a pollutant level in exhaust gas from a combustion system are provided for solving the problem of exact metering of reagent in regulated diesel catalytic converters. The metering of the reagent is linked to operationally relevant parameters of the combustion system through the use of a functional relationship and the functional relationship is corrected through the use of pollutant measurement. The pollutant measurement and, if appropriate, the correction, are carried out by an exhaust-gas testing installation which does not form part of the exhaust-gas cleaning installation.
    Type: Application
    Filed: March 21, 2001
    Publication date: August 16, 2001
    Inventor: Ronald Neufert
  • Publication number: 20010014297
    Abstract: An exhaust gas laden with nitrogen oxides is subjected to a catalytic oxidation in an oxidizing catalyst. The exhaust gas is subsequently brought into contact with water and oxygen or air in a mixing device. This results in an exhaust gas freed of nitrogen oxides and in an aqueous solution. In a reaction vessel, the aqueous solution is reacted with a nitrogen-containing reducing agent, in particular with urea ((HN2)2CO), in an acidic aqueous medium under reducing conditions. The gas occurring at the same time is discharged through a discharge line.
    Type: Application
    Filed: February 5, 2001
    Publication date: August 16, 2001
    Inventor: Ronald Neufert
  • Patent number: 6274098
    Abstract: An apparatus for the treatment of exhaust gases containing hydrogen which permits always stable treatment with certainty of the exhaust gases from a semiconductor manufacturing line or the like irrespective of violent fluctuations in the flow rate of the exhaust gases, without having adverse effects on the operation of the semiconductor manufacturing line. The apparatus comprises: an ejector-type vacuum generator having a suction port connected to the discharge source of exhaust gases containing hydrogen and having a drive fluid supply port connected to an oxygen supply source, a hydrogen-oxygen reactor provided with a catalyst and connected to a drive fluid discharge port of the vacuum generator, and a drain reservoir connected to an outlet of the reactor for storing water discharged therefrom.
    Type: Grant
    Filed: January 5, 1999
    Date of Patent: August 14, 2001
    Assignee: Fujikin Incorporated
    Inventors: Yoshikazu Tanabe, Yukio Minami, Koji Kawada, Nobukazu Ikeda, Akihiro Morimoto, Keiji Hirao
  • Patent number: 6248299
    Abstract: A device which generates sulphurous acid in a simplified, efficient way comprises a burn chamber for burning sulphur to produce sulphur dioxide gas, a first conduit for conducting sulphur dioxide gas produced in the burn chamber, a second conduit for conducting water, a third conduit having means for bringing sulphur dioxide gas from the first conduit and water from the second conduit into contained co-directional flow in the third conduit to create sulphurous acid, a mixing tank to receive sulphurous acid, sulphur dioxide gas and water from the third conduit, and an absorption tower and a vent conduit for reacting unreacted sulphur dioxide gas with water. The system is open meaning sulphur dioxide gas in the system is not under significant pressure as the sulphur dioxide gas is conducted through the system.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: June 19, 2001
    Inventor: Edward Jackson
  • Patent number: 6238628
    Abstract: A photolytic device for breaking down organic chlorine compounds, such as trichloroethylene and tetrachloroethylene, in a fluid includes a first reaction chamber, a second reaction chamber, and an acid component absorption column. The first reaction chamber and the second reaction chamber are connected in series, and the second reaction chamber and the acid component absorption column are connected in series. The first reaction chamber is a perfect mixing type chamber, and the second reaction chamber is an imperfect mixing type chamber. The first reaction chamber and the second reaction chamber each have an ultraviolet light source capable of emitting light of wavelength 300 nm or less.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: May 29, 2001
    Assignee: Kurita Water Industries, Ltd.
    Inventor: Hiroshi Matsutani
  • Patent number: 6235248
    Abstract: A device for purifying flue gas containing nitrogen oxides, in which the flue gas is scrubbed with a circulating scrubbing liquid which contains a transition metal chelate such as Fe(II) EDTA and the complex formed from nitrogen oxide and transition metal chelate and/or spent transition metal chelate is regenerated biologically in the presence of an electron donor, nitrogen oxide being reduced to molecular nitrogen. The biological reactor can be combined with the gas scrubber. The electron donor is, for example, hydrogen or methanol, but may also be sulphite which originates from sulphur dioxide in the flue gas.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: May 22, 2001
    Assignee: Biostar Development C.V.
    Inventors: Cees Jan Nico Buisman, Hendrik Dijkman, Petrus Leonardus Verbraak, Adrianus Johannes Den Hartog
  • Patent number: 6228329
    Abstract: A two chamber regenerative thermal oxidizer comprises an oxidizing chamber and a pair of regenerator chambers. Inlet and outlet valves control fluid flow to and from said regenerator chambers. A transition duct communicates with a contaminated fluid feed duct upstream of the regenerator inlet valves and with the oxidizing chamber of said oxidizer. A purge air duct directs the output of the regenerator chambers back to the chambers, selectively. Electronic control means effects powered actuation of said valves, selectively, in a prearranged sequence whereby the inlet and outlet valves in the respective regenerators are never open at the same time thereby precluding short circuiting of the regenerative chamber, yet all of the inlet and outlet valves to the regenerative chambers are never simultaneously closed thereby to maintain the pressure of fluid flow through said regenerator chambers relatively constant.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: May 8, 2001
    Assignee: Durr Environmental
    Inventor: Richard Garvey
  • Publication number: 20010000725
    Abstract: This invention provides a wet flue gas desulfurizer wherein the slurry oxidation tank is equipped with a return pipeline for returning a portion of the slurry to a position at or near the bottom of the slurry oxidation tank, and an oxygen-containing gas is blown in at the discharge end of the return pipeline so as to divide the oxygen-containing gas finely by the action of the slurry returned through the return pipeline, and an oxygen-containing gas blowing device for use in a wet flue gas desulfurizer wherein a fluid reservoir for an absorbing fluid is equipped with a delivery pipe for discharging the absorbing fluid so that its discharge end is open in the fluid reservoir, and an oxygen feed nozzle for injecting an oxygen-containing gas is disposed in the area of the discharged stream in the neighborhood of the discharge end of the delivery pipe.
    Type: Application
    Filed: December 29, 2000
    Publication date: May 3, 2001
    Inventors: Takeo Shinoda, Toru Takashina, Masakazu Onizuka
  • Patent number: 6224834
    Abstract: An oxidation exhaust trap for filtering a particulate product of a first gas contacted with a gaseous oxidizing agent. The oxidation exhaust trap has a vessel having an interior cavity. The vessel further having a first inlet in communication with the interior cavity for introduction of the first gas into the interior cavity and a second inlet in communication with the interior cavity for introduction of the gaseous oxidizing agent into the interior cavity, the gaseous oxidizing agent mixing with the first gas thereby causing oxidation of the first gas for producing the particulate product suspended in a gaseous product. Lastly, the vessel has an outlet in communication with the interior cavity. A filter is disposed in the interior cavity for filtering the particulate product from the gaseous product which is exhausted through the outlet. In a preferred embodiment of the present invention, the first gas is silane and the gaseous oxidizing agent is air.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: May 1, 2001
    Assignee: International Business Machines Corporation
    Inventors: Charles A. Choate, Michael R Lunn
  • Publication number: 20010000094
    Abstract: An exhaust heat recovery boiler in which an exhaust gas discharged from a gas turbine into a boiler duct to recover a heat of the exhaust gas and ammonia is injected to and mixed with the exhaust gas to reduce nitrogen oxide contained in the exhaust gas, the exhaust heat recovery boiler comprising: a boiler duct of a horizontal installation type having an inner hollow portion along which an exhaust gas flows from an upstream side to, a downstream side; a superheater; an evaporator; a denitration reactor; and an economizer, which are disposed inside the boiler duct in this order from the upstream side to the downstream side of the exhaust gas flow therein. A drum is disposed outside the boiler duct and connected to the evaporator and a downcomer pipe extending from the drum into the boiler duct.
    Type: Application
    Filed: December 4, 2000
    Publication date: April 5, 2001
    Inventors: Hideaki Shimada, Norihide Egami, Takayuki Nagashima
  • Patent number: 6203763
    Abstract: A filter or catalyst apparatus in which a fluid medium is brought in a housing as completely as possible into contact with the surface of an arrangement disposed in the housing, the arrangement having openings in the direction of flow of the medium, wherein the arrangement comprises stationary parts (24; 124; 224) and movable parts (22; 122; 322) and the fluid medium is so guided that it flows alternately through respective stationary parts (24; 124; 224) and moved parts (22; 122; 322) of the arrangement, and a catalyst apparatus by which a fluid medium, preferably gas, is brought into contact with a catalytic substance, by said medium flowing through a carrier body (409; 425; 439) for the catalytic substance, wherein the carrier body (409; 425; 439) includes grills or apertured plates which carry the catalytic substance and through which the fluid medium flows, and there is provided a drive device (408; 432) which moves the grills or apertured plates perpendicularly to the direction of flow of the fluid medi
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: March 20, 2001
    Inventor: Anton Theiler
  • Patent number: 6200535
    Abstract: The present invention is directed to a purification device that includes a porous body and a catalyst. To reduce the emission of pollutants, a pollutant-containing stream of gas flows through the porous body.
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: March 13, 2001
    Assignee: DaimlerChrysler AG
    Inventors: Martin Hartweg, Rolf-Dirc Roitzheim, Andrea Seibold, Leonhard Walz, Thomas Fetzer, Bernd Morsbach
  • Patent number: 6177052
    Abstract: The invention pertains to a device for cleaning flue gas, with a container (31) to which raw gas and an adsorbant/absorbant for cleaning of the raw gas can be supplied via at least one supply opening (33) and from which the cleaned gas can be removed via at least one outlet opening (35), whereby moveable built-in parts (39) are located in the container (31), whereby the moveable built-in parts (39) have flexible swirling elements (43).
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: January 23, 2001
    Assignee: FHW-Brenntechnik, GmbH
    Inventors: Hermann Weichs, Andreas Friedl
  • Patent number: 6156277
    Abstract: The installation (10) proposed in intended for the cleaning of flue gases from an oven (12), particularly a revolving cylindrical cement kiln. It includes at least one reduction catalyst (14) for gaseous pollutants and a dust collector. The reduction catalyst (14), together with a reagent-injection point on the input side of the catalyst, is located immediately after the oven (12), i.e. before the dust collector. In preferred embodiments, the reduction catalyst (14) has a basic honeycomb structure with wide gas-circulation channels (66) and/or the honeycombs are screened off upstream by at least one screen. Gaseous pollutants removed by the system are, in particular, NO.sub.x, CO and hydrocarbons.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: December 5, 2000
    Assignee: Elex AG
    Inventors: Ulrich Leibacher, Walter Eckert
  • Patent number: 6139807
    Abstract: An apparatus for removing SO.sub.2 from flue gas treats the hot flue gas with a sump liquid to quench the flue gas and saturate it with water while concentrating ammonium sulfate in the recycled liquid. The gas is then scrubbed in a packed scrubbing zone with a solution of ammonia water, untreated recycled ammonium sulfite and ammonium hydrogen sulfite, and ammonium sulfate solution from an oxidizer to which a partial stream of the scrubbing liquid is fed.
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: October 31, 2000
    Assignee: Lurgi Lentjes Bischoff GmbH
    Inventors: Theo Risse, Louren.cedilla.o Ferrao
  • Patent number: 6138378
    Abstract: This invention is related to a wet gas process which would not require a spray pump, and which would allow the absorption liquid to be recovered smoothly even if the flow velocity of the gases entrained to the liquid should decrease. A wet gas processing apparatus in which the absorption liquid collected in the first liquid storage tank is sprayed in a specified direction (which may be upward, horizontal or downward) by a discharge unit consisting of spray nozzles (14) or the like in the absorption tower. The sprayed liquid is brought into contact with the exhaust gases which are conducted into the tower, and the targeted components of the gases are absorbed and removed. This processing apparatus is distinguished by the following. The first liquid storage tank for the absorption liquid comprises a pressure tank (11) which generates a pressurized gas in the space above the surface of the collected liquid (11a).
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: October 31, 2000
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Toru Takashina, Naoyuki Kamiyama, Takeo Shinoda, Hiromitsu Nagayasu, Susumu Okino, Masakazu Onizuka, Koichiro Iwashita, Satoshi Nakamura, Kenji Inoue
  • Patent number: 6126906
    Abstract: An apparatus for removing harmful components in a semiconductor exhaust gas includes: a first water scrubber for washing with water a gas to be processed; a gas decomposer tower disposed downstream of the first water scrubber; a second water scrubber disposed downstream of the gas decomposer tower; and a burner tower disposed downstream of the second water scrubber for burning the processed gas, wherein the gas decomposer tower is capable of thermally decomposing a mixture gas of a saturated or unsaturated hydrocarbon gas and a perfluorocarbon or a perfluoride compound by maintaining the mixture gas at a temperature of 600.degree. C. or more in the absence of separated O.sub.2.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: October 3, 2000
    Assignee: Kanken Techno Co., Ltd.
    Inventor: Hiroshi Imamura
  • Patent number: 6117403
    Abstract: A process and apparatus for reducing particulate, nitrogen oxides ("NOx"), sulfur dioxide ("SO.sub.2 "), and mercury ("Hg") emissions from the combustion exhaust of fossil fuel fired plants while producing an end product that is commercially useful, comprising the steps of oxidizing Hg, NOx and SO.sub.2 using a barrier, pulse, corona, or electron beam electrical discharge apparatus (100) to produce HgO and the acids HNO.sub.3 and H.sub.2 SO.sub.4 collecting the HgO, acids and particulates in a wet ESP (120), and separating the particulates from the collected acid mixture, then separating and concentrating the acids for industrial use.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: September 12, 2000
    Assignee: Zero Emissions Technology Inc.
    Inventors: Francis R. Alix, S. Edward Neister, Christopher R. McLarnon
  • Patent number: 6067943
    Abstract: The circulating fluidized bed boiler comprises a combustion hearth and a separator cyclone interconnected by a duct which extends along a longitudinal axis and which channels a flow of particles and gas containing nitrogen oxides. It also includes means for injecting into the flow a reagent for reducing nitrogen oxides. Said means comprises at least a first injection tube disposed in a setback of the top portion of the combustion hearth which extends over the duct so as to inject the reagent along the longitudinal axis of the duct in the same direction as the flow.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: May 30, 2000
    Assignee: Alstom Energy Systems SA
    Inventors: Jean-Xavier Morin, Michel Vandycke, Corinne Beal