Abstract: An apparatus for quenching in hydroprocessing of a hydrocarbon feed stream, which provides a substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed which substantially fills the entire volume of a reactor vessel. Catalyst are selected to be essentially the same density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed catalyst bed at the design feed rates. The liquid and gas components of the hydrocarbon feed stream flow into the bed of catalyst and a quenching medium, which is preferably a liquid, is injected into the bed of catalyst. Injection of a liquid quench reduces the gas component of the hydrocarbon feed stream while simultaneously increasing the residence time and reducing the liquid velocity of the liquid component of the hydrocarbon feed stream within the substantially packed bed of catalyst.

Abstract: A device for separating inorganic material polluted by organic material from a fluid, especially of sand polluted by organic material in sewage devices, is provided with a circular shaped container (1), which in its upper region has a feed device (19) for the introduction of the fluid into the container (1), with an extractor device (32) for the inorganic material positioned in the lower region (7) of the container (1) and with an extractor device (29) to discharge the organic material and the fluid. A fluidized sand bed (14) is provided in the lower region (7) of the container (1) in order to separate the organic material from the inorganic material. The fluidized sand bed (14) is kept in motion by an upward flow of liquid distributed via a perforated base (8). A by-pass (38) is provided to transfer part of the sand from the fluidized sand bed (14) into the extractor device (32) in the lower region (7) of the container (1).

Abstract: A treatment device such as a filter device, containing a treatment bed (2) of particulate treatment medium. A fluidizing unit (9) associated with the treatment medium particles, for removing the treatment medium particles from the treatment bed for rejuvenation. The fluidizing unit (9) comprises a liquid supply duct (11) having an outlet (10) and which is arranged to be fed with liquid under pressure from outside the filter bed, and a discharge duct (14) having an inlet (15) and which projects beyond the outlet (10) of the liquid supply duct.

Abstract: A process of converting a feed of hydrocarbon-containing gases into liquid hydrocarbon products including a first reaction of converting the feed into one to 2.5 parts of hydrogen to one part carbon monoxide in the presence of carbon dioxide and then secondly reacting the hydrogen and carbon monoxide in a Fischer-Tropsch synthesis reactor using a promoted iron oxide catalyst slurry to form liquid hydrocarbon products, wherein the carbon dioxide from the first and second reactions is separated from the product streams and at least a portion of the separated carbon dioxide is recycled into the first reaction feed.

Abstract: An apparatus for separating a first component of a process stream from a second component of a process stream in a single vessel has been developed. The single vessel apparatus has a membrane contactor dividing the vessel into an upper portion and a lower portion where the membrane contactor is a material providing selective permeation of fluid components and restricting passage of at least one component to the upper portion of the vessel, and a plurality of vertically spaced apart distillation contactors disposed within the vessel for vapor and liquid distillation located in the lower and/or upper portion of the vessel. The benefit is the production of a process stream that is of high first component purity at reduced capital equipment costs.

Abstract: A method for the uniform loading of catalyst tubes with catalyst particles, which tubes are mounted at tube inlet side in a tube sheet, the method comprises introducing a feedstream of catalyst particles on the tubesheet in a number of substreams with a substantial equal particle flow and velocity by dividing the feedstream and each resulting substream into at least two streams in two or more dividing steps.

Abstract: A wet type flue gas desulfurization apparatus in which desulfurization of flue gas is carried out through gas/liquid phase contact of flue gas with an absorbent slurry. More particularly, disclosed in a combined absorption tower comprising an absorbent slurry liquid tank, a thickening tank serving for concentration by settling of a reaction product slurry formed through the reaction of the absorbent and SO.sub.

Abstract: A process and device for the treatment of fluid, such as flue gas. A moving bed reactor has several reaction chambers. The reaction chambers are located in parallel flow locations. A solid bulk material is located in the reaction chambers. The fluid flows through the reaction chambers in parallel, from bottom to top of each reaction chamber. As the fluid flows through the reaction chambers, the fluid interacts with the bulk material to alter the fluid. Specifically, the bulk material absorbs and/or acts as a catalyst to remove impurities from the fluid. Flow through each of the reaction chambers can be interrupted without interruption of flow through the other reaction chambers. Some of the bulk material in each reaction chamber can be removed, as a layer, from the bottom and a replacement amount can be added, as a layer to the top.

Abstract: An electrostatic gun for electrostatically charging and injecting sorbent particles into a flue gas stream to contact, and electrostatically charge, pollution particles in that flue gas stream. The electrostatic gun is for inclusion as a component of an apparatus for the remediation of pollution particles from a flue gas stream whereafter the clean gas flow is vented to atmosphere. The electrostatic gun receives laminar flow of a selected sorbent material and charges, either positively or negatively, the surface of each sorbent particle in that flow. To provide electrostatic charging to the individual particles, the flow is directed through a straight barrel of a housing of the electrostatic gun to pass alongside a charging wand that is centered axially in the straight barrel. The charging wand is connected to receive a voltage from a high voltage power supply to produce a corona discharge wherethrough the sorbent materials pass to electrostatically charge each sorbent particle.

Abstract: A method and apparatus for desulfurizing a gas and regenerating a sorbent is disclosed. The sulfur-containing feed gas which can be an effluent gas from a coal gasification reactor, for example, is desulfurized with a particulated metallic oxide sorbent in a transport riser. The sulfided sorbent is than separated from a desulfurized effluent gas and regenerated by contact with an oxygen-containing gas in a transport riser. The regenerated sorbent is separated from an SO.sub.2 containing offgas and recycled to the desulfurization step. The degree of sorbent conversion in the desulfurization step is held at a low level and the sorbent regeneration rate is increased to avoid excessive temperature rise in the regeneration step. In such manner, sorbent cooling can be substantially eliminated. The regeneration riser preferably comprises a once-through lift riser to minimize the riser transport gas requirements to just oxidant gas or oxidant gas mixed with a reduced amount of diluent gas.

Abstract: An apparatus is provided which is capable of removing impurities from an impurity-containing hydrogen gas without generating methane. A bed of particulate nickel in an amount of at least 5% by weight as elemental nickel at a temperature of from 0.degree. C. to 50.degree. C. removes all impurities except nitrogen. Then a bed of getter material, a zirconium, vanadium and iron alloy at a temperature of from 200.degree. C. to 800.degree. C. removes the nitrogen impurity thus producing purified hydrogen with an impurity content of less than 20 ppb.

Abstract: A reactor arrangement and process for contacting a fluid reactant with a particulate catalyst in a plurality of flow channels and discharging converted reactant fluid and particles from the flow channels. The particles are discharged axially from the bottom of the flow channels into an unconfined bed of particles. Reactants are discharged in a transverse direction through the sides of the flow channels and across screen openings located a short distance above the channel outlets. A plurality of chambers regulate fluid flow through sections of the screens and prevent excessive fluid velocity in any section from holding up particle flow through the flow channels. The reactor arrangement and process of this invention is particularly useful for arrangements that may be used to operate a reactor under isothermal or other controlled temperature controlled conditions where a heat transfer fluid surrounds a plurality of tubular conduits or multiple flow channels that confine the particles and reactants.

Abstract: A reactor has a reactor shell having an internal cavity. Within the reactor shell is an inlet means, which is connected to the internal cavity to afford passage of material into the cavity. Within the bottom of the reactor shell is an outlet means, which is connected to the internal cavity to afford passage of material out of the cavity. A porous scallop means lines a lower portion of the internal surface of the internal cavity, and a cover means rests upon the top of the porous scallop means. A porous, vertical, hollow centerpipe fits within the internal cavity, and below the cover means, to form an annulus between the porous scallop means and the centerpipe. The bottom of that centerpipe rests on a ledge within the outlet means, to block access of flow of solids from the annulus. A blocking sleeve is within the reactor shell for preventing the flow of solids from the annulus to the outlet means even if the centerpipe ratchets upward from the outlet means.

Abstract: A method is provided for removing catalyst from a distillation column reactor and replacing the catalyst with fresh or regenerated catalyst. More specifically a small particulate catalyst is supported by wire mesh or screen or filter medium on trays in a conventional distillation column and substantially submerged by the liquid on the trays. The vapor rising through the liquid tends to keep the catalyst in suspension in the liquid. A draw-off is provided for each tray having catalyst supported thereon whereby liquid containing the suspended or slurried catalyst can be removed to a separator during operation. The catalyst is separated, as in a settling tank separator, from the liquid recycled to the tray until all the catalyst has been removed. The separated catalyst is removed for either regeneration or discarding. Fresh catalyst can then be added to the separator where it is slurried into the liquid again being recirculated from the tray.

Abstract: A minute sample analysis system includes a micro-reactor device, a quantitative measuring device, an analyzing device and a controller, whereby, when a very small amount of sample is handled, its dilution and loss can be suppressed to minimum level, and analyzing operations ranging from reaction with a reactive reagent to separation/detection of the sample can be consistently carried out efficiently. The micro-reactor device controls the solution, reactive reagent and sample flowing in the form of electroosmotic flow generated by high-voltage application under control of passage change-over switches. The quantitative measuring device measures the quantity of reactive sample received from the micro-reactor device and introduces the measured reactive sample into the analyzing device. The analyzing device optically detects components separated from the sample through electrophoresis. The above operations are generally controlled under by the controller.

Abstract: An apparatus for treating liquid or slurry having a heat treating zone through which is provided counter current flow of heated gas and independently moveable bodies through the heat treating zone in contact with a feed stream. A steam reforming detoxification reactor is also provided and gas is circulated from the heat treating zone gas outlet, through the reactor and to the heat treating zone gas inlet.

Abstract: Disclosed are a process and apparatus for effecting chemical and/or physical reactions by means of solid-gas contact. The apparatus has a shaftlike reaction chamber widening in upward direction and divided into compartments by means of horizontal grids. The process is performed by introducing a particulate solid of about 0.5 to 5 millimeters particle size into the reaction chamber and passing a gas stream in upward direction through that chamber at an output sufficient to keep the particles in floating condition. A floating bed of solid particles will be formed in the reactors then and excellent solid-gas contact suitable for affecting chemical and physical reactions is provided hereby. A special embodiment relates to the removal of nitrogen oxides from flue gases with the aid of a particulate catalyst.

Abstract: Hydrocarbons are converted in a novel catalytic distillation zone comprising two or more cylindrical beds of dense loaded catalyst. Each catalyst bed is penetrated by a plurality of vertical vapor passageways which provide a means for vapor communication between fractionation sections located above and below the catalyst beds. The dense loading of the catalyst provides a low cost method of placing a large quantity of catalyst into the apparatus.

Abstract: In the absorption of acetylene from a crude gas mixture containing mostly C.sub.2 hydrocarbons, a substantially acetylene-free liquid C.sub.2 stream is introduced into a mixing chamber located in the column between the feed points for the crude gas mixture and the absorption agent. The C.sub.2 stream is distributed into fine droplets as it enters into accumulated absorption agent in the mixing chamber, so that foam is not formed in the absorption column. The mixing chamber can be formed of a mixing tank integrated with a plate.

Abstract: A catalyst feed system is described for intermittent delivery of supported and/or prepolymerized supported catalyst to a polymerization reactor. The system incorporates valves with cylindrical sealing surfaces as well as a venting stage incorporating a filter arranged such that it is self-cleaning.

Abstract: Disclosed is a substantially vertically disposed vessel for the continuous gravity plug flow of solid particles and countercurrent flow of fluid, the improvement comprising the vessel having at least one fluid inlet and a fluid distributing member communicating therewith and extending therefrom for the introduction of fluid into the vessel, the fluid distributor being of a generally inverted V-shape to provide for the substantially uninterrupted mass plug flow of particles past said distributor and discharge of gas out the bottom.

Abstract: Paraffin alkylation using solid, particulate catalyst is carried out by preparing an alkane-catalyst mixture in a wash zone, passing the alkane-catalyst mixture to a plug flow reactor where a minor amount of olefin is introduced to contact the alkane-catalyst mixture and react to form alkylate and the alkane-catalyst-alkylate mixture is passed through the reactor with a minimum of back mixing to restrict the reaction of alkylate with olefin, thus substantially preventing polymerization. The alkane-catalyst-alkylate mixture, substantially free of olefin is passed to a disengaging zone where the liquid is removed and the solid particulate catalyst is recovered and returned to the wash zone for recycle. The alkane is present in the reactor in sufficient molar excess to react substantially all of the olefin. Any unreacted isoalkane is recycled to the reactor with make-up isoalkane added to maintain the molar excess.

Abstract: The steps of the method of the invention are preferably practice on apparatus consisting of components arranged in a closed system for removing particulate matter and gases from a polluted gas stream that includes a sorbent particulate charging and injection gun for electrostatically charging sorbent particles and injecting them into a polluted gas stream to charge and agglomerize pollution particulates therein, the stream flowing into a collection system housing that contains a series of moving and static bed filters and provides for operations at pressures less than atmospheric, and at temperatures up to two thousand (2000) degrees F. The filter beds are maintained across the housing and spaced apart from front to back therein, each filter containing a media material selected for removing the charged agglomerized pollution and sorbent reacted particulates and reacting with gases in the polluted gas stream, providing for removal thereof to clean that gas stream that is then vented to atmosphere.

Abstract: A device for separating undesired exhaust gas components from a fluid comprises a reactor with a reaction chamber and having a top and a bottom. The top has a device for introducing a granular adsorption medium. The bottom comprises first and second oppositely slanted sidewalls arranged parallel to one another and forming between them a gutter open in an upward direction. Sections of the gutter form removal funnels with a funnel mouth for removing the granular adsorption medium. The bottom further has fluid inflow openings for admitting the fluid into the reaction chamber, whereby the funnel mouths and the fluid inflow openings are arranged alternatingly in the gutters. The funnel mouths are arranged to form a grid structure. The bottom also has distributing elements for covering the fluid inflow openings. The distributing elements have a pyramid, a cone, a pyramid sector, or a cone sector shape.

Abstract: A catalyst vessel including an inlet at an upstream end, a plurality of catalytic chambers located downstream of the conduit, wherein at least two chambers are connected by a plate having one or more orifices therein to permit gas flow through from the first chamber to the second chamber, and wherein at least one surface in the chamber is adapted for deposition of a metal selected from the group consisting of platinum, rhodium, and rhenium, and an outlet at its downstream end.

Abstract: A method and apparatus for concurrently catalytically reacting fluid streams and distilling the reaction product. A catalytic structure is provided within a distillation column reactor and includes mass transfer devices presenting hollow spaces and a fixed catalyst bed formed from solid catalyst particles. The mass transfer devices are interconnected gas and liquid permeable elements. The liquid phase preferentially flows along channels formed in the catalyst bed before contacting the devices for mass transfer with the vapor phase which primarily flows through the devices.

Abstract: Apparatus for withdrawing particulate spent catalyst particles from a packed, non-fluidized bed of such particles in contact with a liquid medium within a vessel wherein the apparatus is a withdrawal conduit or pipe which has an inlet that opens within the bottom of the bed and faces generally downwardly so that a first section extends upwardly from the inlet, and a second section extends downwardly, and the spent catalyst particles exits the packed bed through a uniform and continuous flow path opening into a solids recovery vessel whose pressure is controlled to regulate flow of such spent catalyst from the reaction vessel independent of the rate of flow through the withdrawal conduit.

Abstract: An apparatus for the direct fluorination of solid particles of polymeric resins capable of being fluorinated in which the solid particles are contacted by a flow of a mixture of fluorine and carrier fluid in a solid-gas reactor. In the solid-gas reactor, the fluid flow continuously agitates or fluidizes the solid particles to maintain the solid particles in motion. The degree of motion of the solid particles is a function of the linear velocity of the fluid and of the physical properties of the solid particles such as the solid bulk density, particle size, geometry of the solid particle, and adhesion or agglomeration of solid particles. The solid-gas reactor can be arranged with single or multi-reactors in batch or continous mode.

Abstract: The present invention relates to a process and a device for introducing a catalytically active powder into a reactor (20) for gas phase alpha-olefin polymerization. The device comprises a storage vessel (3) containing the powder, a metering valve (4) delivering metered quantities of the powder into an intermediate chamber (5) comprising at least one obstacle (6) separating an upper part (5a) of the chamber (5) comprising an auxiliary gas inlet (2a) from a lower part (5b) terminated by an outlet orifice (5c). A connecting pipe (18) connects the outlet orifice (5c) to a mixing device (8) situated on a conveying pipework (15) communicating with the reactor (20). The powder is introduced into the reactor in a dilute suspension form and in a more uniform rate.

Abstract: Production apparatus for vapor-grown fine fibers, comprising a vertical furnace and a horizontal furnace intersecting each other in an L-shaped configuration. Raw material and catalyst and carrier gas are injected into the top of the vertical furnace to form fine fibers that fall freely through the vertical furnace and land and rest on a conveyor in the horizontal furnace for conveying the fibers through the second furnace while the fibers grow in size. Gas and fibers are discharged from an end of the horizontal furnace remote from the vertical furnace. The horizontal furnace has second injecting structure injecting material for fiber growth but no catalyst into said horizontal furnace.

Abstract: A method and apparatus is provided for removing catalyst from a distillation column reactor and replacing the catalyst with fresh or regenerated catalyst. More specifically a small particulate catalyst is supported by wire mesh or screen or filter medium on trays in a conventional distillation column and substantially submerged by the liquid on the trays. The vapor rising through the liquid tends to keep the catalyst in suspension in the liquid. A draw-off is provided for each tray having catalyst supported thereon whereby liquid containing the suspended or slurried catalyst can be removed to a separator during operation. The catalyst is separated, as in a settling tank separator, from the liquid recycled to the tray until all the catalyst has been removed. The separated catalyst is removed for either regeneration or discarding. Fresh catalyst can then be added to the separator where it is slurried into the liquid again being recirculated from the tray.

Abstract: A reaction chamber (E) comprises a calender reactor (5) comprising a device (4) for introducing a feedstock; a device (6) for carrying off the treated feedstock; at least two elementary reaction cells (52), not contiguous to one another, each one consisting of an individual feedstock distributor, an individual collector of the treated feedstock, and a catalytic bed, the cells being separated from one another by a channel (51); at least one device (V) for circulating a heat-carrying fluid in each channel (51); at least n partitions (S) for separating the flow of the heat-carrying fluid, n being an integer greater than or equal to 1; and at least n+1 means (T) for heating the heat-carrying fluid. The chamber can be used for performing the catalytic reforming of naphtha under low pressure.

Abstract: An installation for steam cracking hydrocarbons comprises at least one hydrocarbon cracking furnace, an indirect quench heat exchanger for the effluents leaving the furnace, direct quench means for said effluent, and means (36, 38) for injecting erosive solid particles into the installation for decoking purposes. The installation also includes a cyclone (10) placed at the outlet from the indirect quench heat exchanger to separate the solid particles from the gaseous effluent, with the solid particle outlet (14) from said cyclone being connected to storage tanks (20, 30) connected in series with isolating valves (16, 28, 34), a source (38) of gas under pressure being provided to raise the pressure in one of the tanks and to inject the solid particles into the installation.

Abstract: A moving bed reactor for the treatment of fluid in a countercurrent process includes a reactor vessel having, in an upper region thereof, an inlet for receiving particulate material and an outlet for discharging treated fluid, the reactor vessel also having, in a lower region thereof, a downward tapering first funnel leading to an outlet, the first funnel guiding the particulate material to the outlet for discharge from the reactor vessel, the first funnel being formed by wall sections which mutually overlap in louvre fashion to create slot-shaped passages for the fluid to be treated to enter the vessel.

Abstract: Gas/solids contact apparatus includes a tower-like, vertical vessel divided by internal wall structures into three axially-extending, concentric spaces. An inner space, typically of generally circular cross section and extending along the axis of the vessel, receives the gas which is to be contacted with particulate solids. An intermediate space, which may have a variety of configurations, surrounds the inner space and, during operation the contactor, contains a downwardly moving bed of solids. An outer space, typically of annular configuration, surrounds the intermediate space and serves to collect gas which flows from the inner space, generally horizontally through the moving bed of solids and then into the outer space for discharge through a gas outlet. In a preferred embodiment the moving bed of solids is contained by louvered walls, and these walls are constructed as modules which can be arranged to provide contactors having different gas and solids handling capacities.

Abstract: The device has an opening provided through a side wall of the fluidization enclosure and a tube extends outside a enclosure and substantially perpendicular thereto. A duct is connected substantially perpendicularly to the tube and extends downwards. A piston is slidably mounted in sealed manner inside the tube to slide between a first position in which it constitutes a panel closing the opening and a second position in which it at least partially uncovers the opening of the duct into the tube, and control means for controlling displacement of the piston inside the tube.

Abstract: A method and apparatus is provided for removing catalyst from a distillation column reactor and replacing the catalyst with fresh or regenerated catalyst. More specifically a small particulate catalyst is supported by wire mesh or screen or filter medium on trays in a conventional distillation column and substantially submerged by the liquid on the trays. The vapor rising through the liquid tends to keep the catalyst in suspension in the liquid. A draw-off is provided for each tray having catalyst supported thereon whereby liquid containing the suspended or slurried catalyst can be removed to a separator during operation. The catalyst is separated, as in a settling tank separator, from the liquid recycled to the tray until all the catalyst has been removed. The separated catalyst is removed for either regeneration or discarding. Fresh catalyst can then be added to the separator where it is slurried into the liquid again being recirculated from the tray.

Abstract: A reactor for low pressure catalytic reforming of gasolines with heating by smoke gases comprises: at least one device for introducing and removing the charge; at least one device for introducing and removing the catalyst; at least two elementary reaction cells spaced apart from each other are made of substantially vertical and parallelepipedic enclosures (an individual charge distributor, an individual processed charge collector, a catalytic bed); at least one general charge distributor; and at least one general processed charge collector.

Abstract: A catalytic cracking process and apparatus operates with multiple feed injection points to a riser reactor with several enlarged regions. An elutriable catalyst mixture is used, comprising a conventionally sized cracking catalyst and a faster settling, shape selective additive cracking catalyst. Straight run naphtha, and a light, H.sub.2 -rich aliphatic stream are added to the base of a riser reactor. A resid feed is added higher up in the riser, with a gas oil and recycled heavy cycle oil and naphtha streams added even higher up in the riser. The riser has an elutriating base, and an elutriating upper portion, which increase residence time of the shape selective zeolite additive relative to the conventionally sized cracking catalyst.

Abstract: Heat transfer equipment is provided having a chamber adapted to contain a bed of free-flowing granular material and a plurality of spirally wound cylindrical tube coils nested together which extend concentrically around a centrally positioned tube collector. Each tube coil is wound on a cylindrical surface having an axis coinciding with the longitudinal axis of the chamber. The tubes at least at the top end of the chamber emerge from the coil and remain on the cylindrical surface as they extend in a direction substantially parallel to the longitudinal axis. The tubes then bend about 90.degree. and extend radially toward the longitudinal axis and connect to the centrally positioned tube collector. In the radial run, the tubes from different tube coils overlap one another on the top of the coils and extend radially over substantially the same outer surface of the tube coils. A retaining device adapted to be removed in sections is positioned below the tubes in the chamber.

Abstract: A uniform feed distribution system for selectively upgrading a feed stream of hydrocarbon fluid containing metallic components, such as organometallic compounds, and/or inert materials, which deactivate or contaminate catalyst particles counterflows into a descending bed of catalyst particles. The heated feed stream is at temperatures and pressures so that lighter hydrocarbon components or hydrogen evolve as gas components as it is introduced into the reaction vessel. The evolved gas is separated into reservoir or pocket above a reservoir of liquid components and both components are then uniformly and selectively introduced into the downflowing bed of catalyst. By forming a common supply volume of gaseous and liquid components, the gas components are independently accessible to the lower end of the moving bed of catalyst particles through an inclined distribution surface preferably in the form of a cone.

Abstract: Apparatus for catalytically reducing noxious substances in flue gas employes, in a first embodiment wherein combustion air is also pre-heated, a two-part heat-exchanger which is traversed from top to bottom by a plurality of catalytically active, separately movable heat-storage elements. Combustion gas is heated in a first portion of the heat-exchanger by heat transferred from the heat-storage elements and the noxious gases are catalytically reduced in a second portion of the heat-exchanger downstream from the first portion in the presence of ammonia and the heat-storage elements. The heat-storage elements can be removed from circulation and replaced by unspent or regenerated elements when the residual content of noxious substances in the flue gas remains elevated.

Abstract: An apparatus for cracking hydrocarbon with hot particulate solids wherein a curtain of hot particulate solids is delivered to a thermal reactor through peripheral openings and hydrocarbon feed is delivered to the reactor through the curtain of hot particulate solids at an angle.

Abstract: A structure and a method of producing such structure which includes a fiber reinforced composite article in which the surface of the article will generate a visible indication thereon upon impact of the surface by another object. The method comprises laying up multiple layers of a first material into the shape of the desired composite article. A relatively thin layer of a second filamentary material is then layed up on and bonded to the surface of the base structure formed by the layers of the first material. The second filamentary material forms a thin outer layer on the composite article, and upon impact of the outer layer with another object, the outer layer delaminates and forms a discoloration in the form of a whitened patch or spot in the immediate vicinity of the impact. The articles so produced can be visually inspected for damage, and only those articles showing a surface discoloration need be subjected to nondestructive testing.

Abstract: Apparatus for the treatment of fluids comprising a vessel containing a fixed bed of particulate material in which a plurality of fluid distribution baskets are suspended from the interior of the upper portion of the vessel and are partially submerged beneath the upper surface of the fixed bed of particulate material. Apparatus is disclosed for mutually securing the lower end portions of the fluid distribution baskets as well as preventing the flotation of the fluid distribution baskets on the surface of the particulate materials during charging of the vessel.

Abstract: A method and apparatus for reducing chemical oxygen demand levels in water which includes the steps of:(a) mixing the water to be treated with at least one oxygen source;(b) contacting the water with a first, activated alumina catalyst;(c) contacting the water with a catalyst selected from the group consisting of Group VIIIB metals, Group IB metals, or mixtures thereof;(d) reacting chemical contaminants in the water with the oxgen source; and finally(e) contacting the water with an adsorptive material such as activated carbon.The present invention also includes a method and apparatus for regenerating the catalyst in situ by contacting the catalyst with alkaline and acidic aqueous inorganic regeneration solutions.

Abstract: An apparatus for delivering fluidization gas to a bed of particulate solids to selectively, locally fluidize the solids above a delivery conduit in communication with a reaction chamber. Also an apparatus is disclosed for intimately mixing hydrocarbon feed with the particulate solids at the end of the delivery conduit in the reaction chamber.

Abstract: A reaction column for the physical or chemical treatment of a solution in heterogeneous phase. Such a column operates under a pressure substantially equal to the height of charge in the column; its lower part is conical, the lining comprises a static component and, arranged within the cone, layers of inert materials of a size and density increasing from the top to the bottom; a free height being left between the top of the upper layer and the top of the column.

Abstract: Each of a pair of heat exchangers in a combustion plant includes a storage space holding basic granules, and will alternatingly be flown through by combustion gas and air, respectively. Residual heat from the combustion gas will be absorbed by the granules, and the moisture contend of the gases will condense upon the granules. Sulphur dioxide in the combustion gas will react with the basic material to calcium sulphite, and the moist granules will catch ash particles and other cntaminants in the gas. When valves have been re-set, air is made to pass through the granules, whereby it will be preheated. The heated air may be conducted to a burner, to a regeneration apparatus for the granules, or through a conduit to the gas exhaust duct. After some time of operation the granules are transferred to the regeneration apparatus, which includes a rotatable drum, where the granules will be subjected to mechanical working and separation of calcium sulphate and dust particles, preferably while being heated.

Abstract: The present invention relates to methods and implementation, including apparatus comprising a two-stage, single-unit, and energy-efficient rotary drum-type granulator-dryer device having a granulator section and a separate dryer section in a new and novel combination designed for continuously granulating and/or ammoniating, and subsequently drying, respectively, a variety of materials together with specific processes for effecting such granulating and/or ammoniating, and subsequent drying.