Abstract: The invention relates to a method for maintaining a continuous mixing in a liquid throughout the transversal reactor space, and for simultaneously separating from the liquid either another liquid, a solid material or possibly gas. The invention also relates to an apparatus whereby the mixing is maintained and simultaneously another phase is separated from the liquid under agitation.

Abstract: An improved system for performing an alkylation process and a method for handling liquid catalyst in an alkylation process. This improvement involves a method and apparatus by which liquid alkylation catalyst contained in alkylation process equipment can be safely stored and isolated from the external environment. Additionally, the apparatus improvement will allow for an improved method for controlling the circulation of liquid alkylation catalyst by providing means for quickly stopping the circulation of alkylation catalyst. The apparatus improvement comprises a baffle contained within a vessel which is attached to the bottom of the vessel and extends upwardly into the vessel. The baffle is designed to allow for the liquid flow between the inside of the vessel and the inside of the baffle and it allows for the venting into a vapor space from the top of the baffle. Within the baffle is standpipe which provides for fluid flow from within the baffle to a region outside the vessel.

Abstract: An apparatus and method for processing an influent liquid including at least a solvent and non-volatile impurities by combining the liquid with a vapor to produce a precipitated sludge is disclosed. The influent liquid is introduced into a wet well. A saturated, water containing reflux and a precipitated sludge are transferred to the well from a reactor. The saturated, water containing reflux precipitated sludge and influent liquid are mixed to form a mixture of saturated, water containing reflux and precipitated sludge. The saturated, water containing reflux is then transferred to the reactor and contacted with a vapor to form the precipitated sludge. The vapor is then discharged from the reactor, and the precipitated sludge is discharged from the wet well.

Abstract: A continuous stirred-tank reactor suitable for the liquid-phase oxidation of an aromatic alkyl to an aromatic carboxylic acid is provided with vertically disposed, relatively narrow baffles on the reactor wall and with oxidizing gas inlet means below the agitator in the reactor. The baffle width is about 0.02 to about 0.04 times the diameter of the reactor.

Abstract: An apparatus for testing performance of a catalyst in a gaseous phase catalytic reaction for a given reactant comprises a reactor receiving a predetermined quantity of fluid reactant discharging the reaction mixture, including reaction products, from the reactor after a predetermined residence time. The reactor comprises a confined reactor volume with an upflow zone and a downflow zone. A device circulates fluids upwardly through the upflow zone and downwardly through the downflow zone where particulate catalysts in the upflow zone are fluidized by the upward flow of the fluid. The circulating device is adapted to circulate the fluid about the reactor volume at a rate which provides at any moment during the residence time for the reactants an essentially uniform concentration of reactants throughout the reactor volume to simulate conditions in a catalytic riser reactor.

Abstract: A stirring reactor for a viscous material. The reactor comprises a stirring vessel; a revolvable shaft provided in the vessel; a surface layer stirring vane provided on the revolvable shaft in the vicinity of interface of the gas and the liquid to be stirred; a stirring vane having at least a pair of radially directed multiple portion blades which extend radially towards the inner wall, a first of which blade portions is fastened on the revolving shaft below the upper layer stirring vane and the other of which blade portions extends outwardly radially from said first portion to terminate close to the inner wall of the vessel; and baffle plates provided on the inner side wall at positions substantially parallel to the surface layer stirring vane, and at a height between the heights of any stirring vanes having multiple blades.

Abstract: A process for purifying the effluent originating from urea production plants, consisting of three successive treatment stages, namely stripping of the volatile components, thermal hydrolyis of the urea and biuret in a plurality of zones traversed with piston flow, and final stripping of the volatile components produced by the hydrolysis.

Abstract: A method and means for continuous precipitation of granular uranium peroxide. The reaction vessel and agitation method practiced in it avoid filter plugging and caking problems.

Abstract: In concepts relating to biotechnology, fermentor and bioreactor apparatus and technology are provided for maximizing aeration for the cultivation and growth of aerobic microorganisms and tissue cells in artificial media such as aqueous growth media. The apparatus comprises a chamber with an impeller assembly for downward peripheral rotary flow under circumferential baffles that are downwardly disposed alongside microporous air sparger tubes. The agitation system preferably comprises a tree-turbine or a spherical-shaped impeller system. The apparatus provides advantages with respect to low shear, low power requirement, and high oxygen absorption rate, the latter being higher than conventional rates by an order of magnitude. In a preferred embodiment for the suppression of headspace foam, the invention comprises an assembly for forcing foam-destructive downdraft air into the headspace as well as stirrer or agitator assembly for stirring and breaking up foam that is present in the headspace.

Abstract: An apparatus for processing high viscosity materials consisting of a heatable, horizontal vessel with a product inlet on the one end and a product outlet on the other end and, parallel to the axis of the vessel, a heatable rotating hollow shaft, supporting a plurality of heatable stirrer elements, and between these stirrer elements, fixed to the wall of the vessel, stationary baffle and scraping elements of different configurations.Each stirrer element comprises one to four stirrer wings, each with two hollow spokes and a peripheral, hollow ring-segment connecting the spokes, and fixed to the peripheral end of these ring-segment connections trailing product dragging blades.

Abstract: Fat or oil is hydrolyzed with water and lipase effectively by supplying the fat or oil and water continuously each at a constant rate or semicontinuously in portions and simultaneously withdrawing a solution containing fatty acid(s) and an aqueous solution containing glycerol formed by the enzymatic reaction from the reaction system continuously at the same rates as those of the supplied fat or oil and water respectively or semicontinuously in portions to thereby maintain the glycerol concentration in the aqueous phase of the reaction system constant within a range of 10 to 40% by weight.

Abstract: A device for injecting additive products into a liquid includes a conduit in which flows a liquid, a nozzle which penetrates into the conduit for injecting additive products, and a chamber in fluid communication with the conduit and situated above the latter. The nozzle is situated within the chamber, and means are provided for introducing and maintaining a gaseous atmosphere in the chamber whereby the nozzle is entirely contained in the gaseous atmosphere.

Abstract: An apparatus to allow reaction in the liquid phase. The apparatus is a vessel having a baffle. There are openings in the baffle through each of which a liquid passes as a jet. Neighboring openings are sufficiently close to allow impingement of the jets thereby allowing for reaction of the liquids. The invention finds application in reactions where the reactants are immiscible and is particularly suitable in the nitration of aromatic hydrocarbons using mixed acids in aqueous solution. A method of conducting a reaction between at least two reactants in the liquid phase is also provided comprising passing a liquid containing the reactants through a plurality of adjacent spaced openings to create a series of impinging jets.

Abstract: This invention provides an improved apparatus for stripping hydrocarbons from spent catalyst which has been used in effecting hydrocarbon conversion reactions prior to the regeneration of this catalyst by combustion of carbon deposits upon the catalyst. The invention is described in terms of its use in FCC processes, since such processes are the most common application of the invention. In order to better distribute stripping gas, which is normally steam, so that the gas contacts and passes through substantially all of the catalyst, distribution ports are added to the skirts of the stripper baffles which direct catalyst flow in a generally side-to-side manner as it moves downward through a stripping vessel. The ports are sized to vary penetration of the stripping gas into the stream catalyst that moves past the grids. Use of these ports increases the amount of hydrocarbons removed from the spent catalyst and/or decreases stripping gas requirements.

Abstract: A tubular reactor for heat treatment of granular material in suspension has a vessel (1) up through which a flow of gas and burning fuel passes. The vessel contains vanes (20) which cause the gas to follow a helical path and fling outwards entrained material, which falls down the vessel wall and is displaced inwardly by frusto-conical rings (30).

Abstract: An apparatus for reaction according to the present invention includes a horizontal-type reactor having first and second portions and a liquid circulator for circulatorily feeding a liquid from the first portion of the reactor, through the second portion of the reactor which is spaced apart from the first portion of the reactor in the direction of axis of the reactor. The reactor includes stirring blades on a stirring shaft whereby the liquid can be stirred in the rotational directions of the stirring blades of the horizontal-type reactor, while it is stirred in the axial direction thereof by the liquid circulator, thereby enabling the liquid to be stirred uniformly throughout the interior of the reacting apparatus without damaging surface renewal effects on a vapor-liquid interface.

Abstract: An apparatus for peptide synthesis in which a plurality of supply valves are arranged in series to define a line for supplying successive reagents to a reaction vessel in which a peptide is to be synthesized. A corresponding plurality of containers contain respective reagents and each, by actuation of its corresponding valve, is connectable through downstream ones of the series of valves to supply its respective reagent to the reaction vessel. For cleaning or reacting with peptide starting material therein further valving permits draining of the reaction vessel to waste and, between applications of successive reagents to the reaction vessel, cleaning of the line of valves by flushing with a cleaning reagent sent from the upstream end of the series of valves through the line to waste.

Abstract: A mixing apparatus is disclosed which comprises a vessel; first impeller means positioned within said vessel immediately subjacent to the top of said vessel but sufficiently spaced from said top to rotate; second impeller means positioned within said vessel immediately superjacent to the bottom of said vessel but sufficiently spaced from said bottom to rotate; third impeller means positioned within said vessel between said first and said second impeller means; paddle means positioned within said vessel between said second and said third impeller means; and means for rotating said first, second and third impeller means and said paddle means.

Abstract: A fluid diffuser for dispersing a gas or liquid into a body of receiving liquid in which it is immersed. The diffuser includes a rotatable shaft, a thin disk-like member mounted for rotation on the shaft, and an annular ring positioned adjacent the outer perimeter of the disk-like member. At least one of the top and bottom walls of the annular ring is porous. These top and bottom walls define a fluid plenum, into which gas or liquid under pressure is introduced to be emitted from the plenum as small, nascent fluid spheroids on the surface of the annular ring. The boundary layer flow from rotation of the disk-like member within the body of receiving liquid shears fine gas bubbles or liquid particles from the foraminous surface or surfaces of the annular ring. The annular ring may be fixed, or rotatable in the opposite annular direction from the rotation of the disk. Impeller blades may be mounted on the top and/or bottom surfaces of the rotatable disk.

Abstract: A gas-liquid contacting apparatus is constituted by an upright vessel, at least one perforated gas distributor for supplying a gaseous medium into a liquid medium within the vessel, a plate-like rotary disintegrator positioned within the vessel and above the gas distributor for disintegrating bubbles of the gaseous medium into fine bubbles, and a drive shaft concentrically extending through the vessel for the support of the rotary disintegrator.

Abstract: Apparatus for the extraction of fruit and vegetable pressings and plant raw materials in a closed system. The extraction is effected by simultaneous mechanical and hydrodynamic effects on the materials, the fruit or plant mass being subjected to several extractions in two cyclically alternating modes of fountain-type and turbulent agitation with different intensities with bladed agitator tip speeds in an over-all range of 3 to 25 m/sec. The apparatus has a closed heat-insulated vessel with internal draining wall, a conical bottom, a cover having a ventilation opening, and an opening for the raw material, with a driving unit mounted on the cover with two driving speeds. The driving unit is a shaft on the lower end of which there is mounted an impeller, the shaft resting on a special bearing supported on a grid of blades rectifying the material flow, an elongated diffuser surrounding the impeller, the impeller together with a suction unit leading to the diffuser being fixed to the bottom of the vessel.

Abstract: Vortex apparatus for the continuous production of a precipitate by reacting together at least two reactants wherein it comprises a rotary bowl, having a vertical axis a fixed cylinder arranged coaxially within the bowl in order to define with the latter an annular raising chamber, thus providing a fluid flow connection with a reaction chamber defined within the fixed cylinder, reactant inlet pipes issuing into the upper part of the reaction chamber in the vicinity of the axis of the bowl, at least one weir fixed to the rotary bowl at the upper end of the raising chamber and a turbine fixed to the rotary bowl in the lower part of the reaction chamber, so as to produce a vortex in the latter and ensure the raising of part of the precipitate into the raising chamber.

Abstract: A soft nonwoven web of entangled fibers or filaments having a pattern of fused bond areas and a stretched, loopy filament configuration outside of the patterned bond areas. The result is a soft web with high bulk that retains to a high degree the original bonded strength properties. In one embodiment, product may be obtained by pattern bonding a meltblown microfiber web under conditions of heat and pressure and then stretching the web under controlled conditions up to preferably about 140% of its original dimension in at least one direction. When relaxed, the stretched filaments bulk and loop except in the fused bond areas where they retain bonding properties. Preferred stretching conditions include room temperature and the use of draw rolls at speed differentials producing the desired stretch. Examples of thermoplastics polymers useful in accordance with the invention include polypropylene, polyethylene, polyesters and polyamides, as well as copolymers and polymer blends.

Abstract: In a reactor for continuous polymerization in which an olefinic monomer is polymerized by contacting the olefinic monomer under suitable reaction conditions with an initiator, the formation of residue in the reactor is reduced by introducing the olefinic monomer and initiator into opposite sides of a turbulent zone produced by an agitator in the reactor. This improves mixing of the olefinic monomer and the initiator and prevents the initiator from contacting high concentrations of the olefinic monomer which results in reduced residue formation in the reactor.

Abstract: A catalytic heat exchanger useful for carrying out a catalytic reaction wherein a gaseous or vaporized mixture is flowed into contact with a catalytic material reactive with such mixture. The heat exchanger includes a reaction zone divided by a plurality of baffle plates into regions of progressive increasing or decreasing volume. The baffle plates form a tortuous flow path for the gaseous or vaporized mixture that provides intermittent contact with a bundle of heat exchange tubes and the catalytic material. The intermittent contact in turn provides a uniform reaction temperature which promotes reaction specificity.

Abstract: An apparatus for removing sulfur oxides and nitrogen oxides from the gaseous combustion products of sulfur-containing fossil fuel, such as high sulfur coal, comprising passing the combustion products into a reaction chamber, introducing atomic oxygen and air into the chamber, subjecting the resulting gaseous mixture to a plurality of confined, upwardly spiralling vortical movements in series, maintaining a reservoir of sulfuric acid in the reaction chamber, each vortical movement being of sufficient velocity as to atomize and elevate the sulfuric acid in the reservoir and to intermix it with the combustion products, impinging the vortical mixture against rapidly rotating surfaces whereby to discharge the mixture outwardly against the chamber walls to fall by gravity into the reservoir, and repeating the plurality of vortical movements in series in at least one additional reaction chamber, thereby producing sulfuric acid and/or nitrosyl sulfuric acid as a saleable by-product and reducing the sulfur oxides cont

Abstract: This invention relates to an apparatus for the continuous preparation of aqueous solution of slaked lime solids with fresh water. The apparatus comprises a main vessel having an inverted truncated cone including a smallest and closed bottom. There is provided a dispenser for supplying material slaked lime solids to said main vessel at or nearly at the top end thereof from above, and a constant headed fresh water reservoir for supplying fresh water to the main vessel at a place selected therein in close proximity to the smallest bottom through a piping. A flow rate adjusting means is arranged in this piping. At least a mechanical or fluid agitator is provided at a close proximity to the vessel bottom. Means for the take-up of the formed product solution in an overflowing manner from the main vessel is provided at the top thereof.

Abstract: Stirring apparatus for stirring particles in a liquid medium comprising a cylindrical stirring vessel having a stirring rod extending within the vessel to stir its contents. The rod has a bulbous tip which describes an orbital path in the vessel to sweep out an annular trough or channel formed in the bottom of the vessel. The annular trough or channel is contoured in section to follow the flow lines set up in the medium by secondary motion stirring effects. In this way accumulation of particles due to the secondary motion, which would otherwise occur at the corners and center of the bottom of the vessel, is avoided. The apparatus is advantageously useful in cell culture research particularly for stirring microcarriers in a liquid culture medium because it becomes possible to maintain the microcarriers in uniform suspension at lower stirring speeds than heretofore possible thus avoiding damage to the growing cells and improving overall cell yield.

Abstract: A continuous-stream zeolite crystallization apparatus comprising a combination of a tubular reactor, a central stirring element contained therein, ingress and egress means for the reactor for charging crystalline zeolite forming reactants therein and recovering crystallized zeolites therefrom, respectively, recovery vessels for collecting and processing crystallized zeolites continuously, the reactor and recovery vessels optionally being subjected to a controlled pressure system.

Abstract: This invention relates to an apparatus for the continuous preparation of aqueous solution of slaked lime solids with fresh water. The apparatus comprises a main vessel having an inverted truncated cone including a smallest and closed bottom. There is provided a dispenser for supplying material slaked lime solids to said main vessel at or nearly at the top end thereof from above, and a constant headed fresh water reservoir for supplying fresh water to the main vessel at a place selected therein in close proximity to the smallest bottom through a piping. A flow rate adjusting means is arranged in this piping. At least a mechanical or fluid agitator is provided at a close proximity to the vessel bottom. Means for the take-up of the formed product solution in an overflowing manner from the main vessel is provided at the top thereof.

Abstract: Continuous fluorination of carbon is carried out by employing an apparatus for contact reaction of solid powder and reactive gas which comprises a horizontal reactor having a trough provided with weirs (e.g. height: 1 to 6 mm., interval: 5 to 30 cm.) and a vibrating means for vibrating the trough, and in which carbon particles supplied continuously are transported on the trough in a form of thin layer by the vibration of the trough while continuing the reaction by contacting efficiently the carbon particles with a fluorine gas. The contact reaction is efficiently conducted without accumulating the reaction heat to produce the fluorinated carbon in high yields, and the process is useful for the mass production. The apparatus is also useful for various contact reaction of a solid powder and a reactive gas.

Abstract: An arrangement for discharging coke from a cooling shaft supplied with cooling gas, has one or several coke stripping members arranged to engage in a mass of coke discharged from the cooling shaft, a supporting element for supporting stripping members and rotating together with the latter, and a housing in which the supporting element together with the coke stripping member are accommodated and which is sealed from the atmosphere.

Abstract: For extracting phosphates with alcohol in the presence of water and a strong mineral acid, with the resultant formation of an alcoholic phosphoric acid solution and an aqueous salt phase, a plurality of mixing settlors are arranged one upon another, so that the bottom outlet for the aqueous salt phase of each mixing settlor serves as the feeder for the next mixing settlor below and the outlet for the alcoholic solution of each settlor is connected with the feed pipe for this solution of the next mixing settlor above. Each mixing settlor is subdivided by means of two partitions into a mixing chamber A, a separating chamber B and a settling chamber C. The said two partitions do not extend to the bottom of the mixing settlor and are arranged so that the three chambers A, B and C communicate with one another.

Abstract: The invention is directed to a device for the discontinuous production of block foam comprising a mixing unit, a means for moving the unit approximately vertically into and/or out of a mold with the unit having reaction component feed lines, a stirring means, and a mixing container having a plate with feed openings for the reaction components characterized in that(A) a distributing device is arranged below the feed opening for one of the components and(B) the mixing container comprises a bottomless cylindrical shell, the lower rim of which can be placed on the bottom of the mold.

Abstract: A modular chlorine dioxide generating unit (10) is disclosed wherein recycled reaction mixture passes along a flow path (18) internally of the generator vessel (12) out of direct fluid flow communication with the reaction medium (13) from the lower end (16) of the vessel (12) to a discharge point in the vapor phase (15 ) above the liquid level (13) in the generator vessel (12).

Abstract: In an apparatus for oxidizing an alkyl-substituted aromatic compound in the liquid phase with a molecular oxygen-containing gas in a lower aliphatic carboxylic acid solvent in the presence of an oxidation catalyst, said apparatus comprising a reaction vessel, a gas exhaust port at the top of the vessel, an inlet at the bottom of the vessel for feeding said molecular oxygen-containing gas, an inlet for feeding said solvent, an inlet for feeding said catalyst, an inlet for feeding said alkyl-substituted aromatic compound, an outlet for withdrawing the oxidation reaction product, and an agitator within the vessel, said agitator consisting of a rotating shaft provided along the axial direction of the vessel and a plurality of stages of agitating blades secured to said rotating shaft at spaced intervals; the improvement wherein at least one stage of agitating blades consists of comb-like flat blades each of which is composed of a plurality of comb tooth-like pieces aligned at spaced intervals.

Abstract: Apparatus for the continuous production of phosphoric acid from phosphate-containing rock and sulfuric acid, consisting of a reaction tank with a cylindrical side wall and a planar horizontal bottom and cover, wherein the improvement comprises a rigid vertical internal S-shaped baffle with one end smoothly merging into the said cylindrical side wall of the reaction tank and the other end freely projecting into the tank so as to permit of free circulation and flow of the reaction mixture from one side of the baffle to the other but dividing the reaction tank into two distinct zones.

Abstract: In the illustrative embodiments of the invention disclosed, an installation for mixing and separating two non-miscible liquids includes, inter alia, an improved pump structure for raising the liquid dispersion from the mixing tank to the inlet level to the decanting tank, a low flat chute for conveying the dispersion from the mixing tank to the remote end of the decanting tank, height-controlling means for controlling the level of the interphase within the decanting tank, and provision for recycling the lighter liquid phase to the mixing tank.

Abstract: A mixing device and method of mixing a liquid, vapor, or gas into a slurry of material in a vat in which the liquid, vapor, or gas is introduced into a stream of the slurry passing from the vat through a venturi at the diverging portion of the venturi, and in which the slurry with the entrained liquid, vapor, or gas is returned to the vat below an umbrella of a high velocity stream of slurry in the vat produced by an agitator so as to dissipate the heat of reaction between the two fluids.

Abstract: There is disclosed a reactor designed to produce phosphoric acid by wet process. The reaction vessel proper is a cylindrical body divided into two compartments by a sinusoidal wall. The first space formed inside by the cylindrical wall of the vessel and the sinusoidal one and by one curved segment joining them is semi-circular and serves as pre-mixer provided with a stirring device and a pocket to allow the fluid flowing down through the bottom to reach the reaction space overhead. The reaction vat has two compartments and provided with a series of stirring devices so located as to permit an efficient, intimate mixture of the reaction medium. The vat is integrally roofed by a tight cover with many orifices left in it fitted for connection sleeves, such as: supply, gas venting, sight holes, and manholes, etc.

Abstract: The entrainment of reaction medium in the vapor phase is decreased in a chlorine dioxide generator producing a gaseous mixture of chlorine dioxide, chlorine and steam from a boiling reaction medium and wherein generator liquor is recycled with make up chemicals by providing a tangential entry of recycled liquor to the generator in the vapor space above the liquid level in the generator and a helically-arranged baffle projecting inwardly from the generator wall at least in the height of the generator corresponding to the tangential entry opening into the vapor space. The baffle is arranged to be above the trajectory of the recycled liquor as it enters the generator. Decreased liquor entrainment enables the generator diameter to be decreased, with consequentially decreased capital costs.

Abstract: A turbine mixer for a polyethylene reactor of the stirred autoclave type in which a turbine rotor is mounted on a rotating stirrer shaft extending along the longitudinal axis of the reactor and a turbine stator is mounted adjacent to and upstream of the rotor. The turbine mixer is positioned in the final stage of a three-stage, stirred autoclave reactor, and a baffle plate is positioned so as to extend across the reactor at the inlet to the final zone. The mixer produces intense stirring of the reactor materials within the final stage, but does not cause significant backmixing into the reactor zone immediately upstream thereof. The turbine mixer may also be utilized in other zones of the reactor wherein intense axial mixing of the reactor materials is required, in which case the baffle plate would be omitted so as to produce intensive axial mixing of the reactor materials within that zone.

Abstract: Method and apparatus for continuous preparation of an acrylonitrilebutadienestyrene copolymer comprises on-stream mounted: a prepolymerization reactor, a polymerization reactor, a reactor for the final polymerization and an apparatus for the removal of the non-polymerized monomers from the reaction mass. The polymerization reactor contains a stirring means which has a tube fixedly mounted coaxially with a shell and a mixing member disposed inside the tube. The stirring member is embodied in the form of a closed cylinder. At least one slot is provided in the tube wall. This slot is extending over the entire length of the tube. In the reactor there is also a partition positioned between the reactor shell wall and the stirring member. The partition is passing through the middle of the slot and intended for division of the reactor shell cavity into a suction zone and a pumping zone.

Abstract: A method and apparatus for calcining calcium sulphate dihydrate in a calcination vessel in which the dihydrate is heated in the vessel to calcination temperature not only by heat applied to the exterior of the vessel but also by hot gas, especially hot gaseous combustion products, supplied into the interior of the mass of calcining material within the vessel. The supply of hot gas according to the invention can improve the production rate in both batch and continuous calcination operations without adversely affecting the product quality, by permitting increase in the heat input to the vessel without entailing the risk of vessel bottom burn-out.