By Suspension Of Metal Oxide Or Hydroxide Particles In Liquid Patents (Class 423/225)
  • Patent number: 4276271
    Abstract: An aqueous solution of a zinc salt is used to selectively remove hydrogen sulfide from a gas mixture. An insoluble basic zinc compound is added to the solution to regenerate, or replenish, the salt. A dispersant is added to both decrease the surface tension of the liquid and reduce the degree of hydration of the basic compound, thereby retarding significantly the agglomeration, settling and loss of the basic zinc compound.
    Type: Grant
    Filed: December 3, 1979
    Date of Patent: June 30, 1981
    Assignee: Combustion Engineering, Inc.
    Inventors: William P. Manning, Stephen J. Rehm, Jeffrey L. Schmuhl
  • Patent number: 4246243
    Abstract: Iron rich dusts created during steelmaking, as in the basic oxygen and open hearth processes, are useful for scavenging hydrogen sulfide. For example, basic oxygen furnace dusts, which are in more abundant supply, are found to consist of fine, nearly spherical particles of iron oxide whose crystalline composition comprises Fe.sub.3 O.sub.4 (major portion) and Fe.sub.2 O.sub.3 (minor portion) as seen by X-ray diffraction. Their great surface area makes them highly reactive to hydrogen sulfide gas. Their reaction yields unexpected products, namely, free sulfur and iron hydroxides. According to the present invention such iron rich dusts are used in water slurries through which sour hydrocarbon gas is bubbled, and in water based drilling muds to scavenge hydrogen sulfide encountered in well drilling.
    Type: Grant
    Filed: November 27, 1978
    Date of Patent: January 20, 1981
    Inventor: Irwin Fox
  • Patent number: 4246244
    Abstract: A process for scavenging hydrogen sulfide from hydrocarbon gases utilizes iron oxide particles of unique chemical and physical properties. These particles have large surface area, and are comprised substantially of amorphous Fe.sub.2 O.sub.3 containing a crystalline phase of Fe.sub.2 O.sub.3, Fe.sub.3 O.sub.4 and combinations thereof. In scavenging hydrogen sulfide, the iron oxide particles are suspended in a liquid which enters into intimate mixing contact with hydrocarbon gases; the hydrogen sulfide is reacted at an exceptional rate and only acid-stable reaction products are formed. Thereafter, the sweetened hydrocarbon gases are collected.
    Type: Grant
    Filed: May 31, 1979
    Date of Patent: January 20, 1981
    Assignee: Gas Sweetener, Inc.
    Inventor: Irwin Fox
  • Patent number: 4244930
    Abstract: Wet separation at high temperatures of acidic impurities from gases. The gases are scrubbed with a melt of an alkali metal compound in which a solid alkaline earth metal compound is dispersed.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: January 13, 1981
    Inventor: Ekkehard Weber
  • Patent number: 4049399
    Abstract: Process and apparatus are disclosed for the treatment of flue gases to remove particulates, sulfur oxides, hydrogen sulfide and organic sulfur compounds using an alkaline scrubbing liquor containing activated carbon.
    Type: Grant
    Filed: January 26, 1976
    Date of Patent: September 20, 1977
    Assignee: Teller Environmental Systems, Inc.
    Inventor: Aaron Joseph Teller
  • Patent number: 3993730
    Abstract: A continuous process is provided which has the primary purpose of removing NH.sub.3, H.sub.2 S, HCN, and (CN).sub.2 from the subject gas mixtures and the secondary purpose of producing (NH.sub.4).sub.2 SO.sub.4 and iron oxide for industrial uses. The gas mixture which contains tar and other condensible vapors, NH.sub.3, H.sub.2 S, HCN, and (CN).sub.2 together with small volumes of gas from the ammonia still of the system, and gas from a system H.sub.2 SO.sub.4 plant, is contacted in a single three-stage reaction chamber in the presence, if need be, of a tar solvent, additional NH.sub.3, and the reagent Fe(OH).sub.2, which itself is a product of a concurrent reaction between NH.sub.3 and FeSO.sub.4. The unpurified gas mixture's condensible vapors are largely prevented from condensing by maintaining a steady, elevated temperature, while the mixture is essentially freed of HCN, (CN).sub.2, NH.sub.3, and H.sub.2 S in the reactor before the gas mixture passes through a primary gas cooler.
    Type: Grant
    Filed: January 30, 1976
    Date of Patent: November 23, 1976
    Inventor: Franklin D. Cooper
  • Patent number: 3992293
    Abstract: A method of reducing foaming of a liquid containing dissolved carbon dioxide during filtering. The carbonated liquid to be filtered is adjusted in pH to a value of 6.5 to 8.0 by the addition of an alkaline material which reacts with the dissolved carbon dioxide to remove the carbon dioxide from solution. The elimination of the dissolved carbon dioxide results in decreasing foaming during filtering and substantially increases the rate of filtration.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: November 16, 1976
    Assignee: Jos. Schlitz Brewing Company
    Inventors: John E. Sawicki, James P. Murdock
  • Patent number: 3957674
    Abstract: Discloses a fluid aqueous suspension of magnesium hydroxide having a solid concentration between about 35 and 60 percent by weight and a viscosity up to 10,000 cp. comprising at least 0.5% by weight of a sodium naphthalenesulfonate surface active agent based on the weight of magnesium hydroxide.
    Type: Grant
    Filed: September 21, 1973
    Date of Patent: May 18, 1976
    Assignee: Shin Nihon Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Sano, Nozomu Matsuno, Katsumi Okina