Carbon Dioxide Or Hydrogen Sulfide Component Patents (Class 423/220)
  • Patent number: 12227412
    Abstract: In some aspects and embodiments, the present application provides a wide range of porous 1-D polymeric graphitic carbon-nitride materials that are atomically doped with binary metals in different morphologies. In some embodiments, the graphitic carbon-nitride materials can be prepared with high mass production from inexpensive and natural abundant precursors. In some embodiments, the materials were used successfully for the oxidation of CO to CO2 under ambient reaction temperature in addition to the reduction of CO2 into hydrocarbons. In some embodiments, the materials can be used for practical and large-scale gas conversion for household or industrial applications.
    Type: Grant
    Filed: October 20, 2020
    Date of Patent: February 18, 2025
    Assignee: Qatar University
    Inventors: Kamel Abdelmoniem Mohamed Eid, Aboubakr Moustafa Abdullah
  • Patent number: 12209029
    Abstract: Disclosed is a method for fast and cost-efficient preparation of ikaite crystals. The method comprises contacting an alkaline aqueous solution, which comprises carbonate and bicarbonate ions, with a water solution, which comprises Ca2+, at a temperature not exceeding 15° C., wherein contact between the alkaline aqueous solution and the water solution takes place at a permeable or porous surface, through which either solution is fed to the other at a flow rate facilitating formation of ikaite crystals. Also disclosed is system for carrying out the ikaite preparation process. The process and system provides a cost efficient and effective means for capture and storage of carbon dioxide.
    Type: Grant
    Filed: March 15, 2023
    Date of Patent: January 28, 2025
    Assignee: Climate Solutions ApS
    Inventor: Erik Trampe
  • Patent number: 12195334
    Abstract: Systems of producing hydrogen and biochar from biomass assisted by iron and steel slag extract include: a pretreatment system that the reactants, including the biomass, iron-based catalyst and alkaline reagent, are pretreated and fully mixed at specific ratios in the pretreatment system; thermal reactor that the mixed reactants from the pretreatment device are transferred into and fully reacted in the thermal reactor; a solid residue collector that the solid residue is collected by the solid residue collector at the discharge outlet of the thermal reactor after the reacted mixture is separated; a gas collection system that he generated hydrogen-based gas is collected by the gas collection system from the exhaust port of the thermal reactor.
    Type: Grant
    Filed: May 31, 2021
    Date of Patent: January 14, 2025
    Assignee: GREENORE HOLDING CO.
    Inventors: Xiaozhou Zhou, Huangjing Zhao
  • Patent number: 12168609
    Abstract: The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO2 and low carbon H2 into low-carbon syngas with greater than an 80% CO2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.
    Type: Grant
    Filed: May 3, 2021
    Date of Patent: December 17, 2024
    Assignee: Infinium Technology, LLC
    Inventors: Dennis Schuetzle, Robert Schuetzle, Orion Hanbury, Matthew Caldwell, Glenn McGinnis, Ramer Rodriguez
  • Patent number: 12161972
    Abstract: Provided herein are methods of removing carbon dioxide from an aqueous stream or gaseous stream by: contacting the gaseous stream comprising carbon dioxide, when present, with an aqueous solution comprising ions capable of forming an insoluble carbonate salt; contacting the aqueous solution comprising carbon dioxide with an electroactive mesh that induces its alkalinization thereby forcing the precipitation of a carbonate solid from the solution and thereby the removal of dissolved inorganic carbon by electrolysis; and removing the precipitated carbonate solids from the solution, or the surface of the mesh where they may deposit. Also provided herein are flow-through electrolytic reactors comprising an intake device in fluid connection with a rotating cylinder comprising an electroactive mesh, and a scraping device and/or liquid-spray based device for separating a solid from the mesh surface.
    Type: Grant
    Filed: July 26, 2022
    Date of Patent: December 10, 2024
    Assignee: The Regents of the University of California
    Inventors: Gaurav Sant, Erika Callagon La Plante, Jingbo Wang, David Jassby, Dante Simonetti, Abdulaziz Alturki, Xin Chen
  • Patent number: 12152469
    Abstract: Mineralizing carbon dioxide for storage may occur in a wellbore. For example, a method of mineralizing carbon dioxide may include: introducing, through a first wellbore to a subterranean formation, a first solution including a metal salt and a metal catalyst; introducing a second solution including a brine, wherein the second solution has nanobubble carbon dioxide at least partially dispersed therein, and wherein the second solution is introduced after introduction of the first solution; injecting carbon dioxide gas thereby at least partially dispersing the carbon dioxide gas in the first solution, thereby forming dissolved carbon dioxide; generating mineralized carbon dioxide from the dissolved carbon dioxide, wherein the generating includes catalytically reacting the metal salt and the dissolved carbon dioxide using the metal catalyst, thereby forming the mineralized carbon dioxide; and depositing the mineralized carbon dioxide within the subterranean formation.
    Type: Grant
    Filed: August 25, 2023
    Date of Patent: November 26, 2024
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Pramod Dhanaji Patil, Abdulaziz S. Qasim, Ali A. Alyousef, Zuhair A. Al-Yousef, Muhammad M. Almajid
  • Patent number: 12151212
    Abstract: An improved method for humidification of a facilitated-transport membrane incorporates delivering a non-selective hydration fluid incorporating liquid water to a permeate side of a pressure vessel containing the facilitated transport membrane. The non-selective hydration fluid includes water and may be configured on the permeate side interface of the facilitated-transport membrane as a liquid or a gas. A process for separation of components in a gaseous mixture utilizing the method for humidification produces higher permeation of gasses through the facilitated transport membrane. The non-selective hydration fluid may be static or flowing and is non-selective for the permeance of certain permeate-gas components over other components.
    Type: Grant
    Filed: September 26, 2019
    Date of Patent: November 26, 2024
    Assignee: Compact Membrane Systems, Inc.
    Inventor: Kenneth Evan Loprete
  • Patent number: 12123336
    Abstract: The present invention relates to an apparatus for reducing greenhouse gas emission in a vessel, and a vessel including the same, which are capable of satisfying IMO greenhouse gas emission regulations by separating and discharging NOX, SOX, and CO2 from exhaust gas exhausted from a vessel engine and increasing CO2 solubility and CO2 removal efficiency by removing CO2 after removing SOX.
    Type: Grant
    Filed: December 17, 2020
    Date of Patent: October 22, 2024
    Assignee: DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD.
    Inventor: Byung Tak Nam
  • Patent number: 12122722
    Abstract: Methods and systems for storing and mineralizing carbon dioxide in soil are disclosed herein. In some embodiments, the method comprises adding lime and carbon dioxide to a soil column including soil to form treated soil. After adding the lime and carbon dioxide, the method also includes strengthening the treated soil in the soil column by mineralizing the lime and carbon dioxide in the soil column. The method can further include adding a binder to the soil column and mixing the binder with the soil, lime, and carbon dioxide. The binder can include, for example, pozzolan, cement, cementitious material, and/or a manufactured calcium carbonate product.
    Type: Grant
    Filed: December 20, 2023
    Date of Patent: October 22, 2024
    Assignee: GRAYMONT WESTERN CANADA INC.
    Inventors: Narain Hariharan, Michael John Tate, Nikolas Andrei Romaniuk
  • Patent number: 12116322
    Abstract: A manufacturing process of a concrete product includes: (1) extracting calcium from solids as portlandite; (2) forming a cementitious slurry including the portlandite; (3) shaping the cementitious slurry into a structural component; and (4) exposing the structural component to carbon dioxide sourced from a flue gas stream, thereby forming the concrete product.
    Type: Grant
    Filed: July 14, 2023
    Date of Patent: October 15, 2024
    Assignees: The Regents of the University of California, Arizona Board of Regents on Behalf of Arizona State University
    Inventors: Gaurav Sant, Laurent G. Pilon, Bu Wang, Narayanan Neithalath, Zhenhua Wei, Benjamin Young, Gabriel D. Falzone, Dante Simonetti
  • Patent number: 12098078
    Abstract: A method of supplying ammonia to a gas chromatography-chemical ionization tandem mass spectrometry (GC/CI-MS/MS) includes the steps of: providing ammonium carbonate and diethanolamine in a reaction vessel; heating the reaction vessel to a temperature of 50-60° C. to decompose the ammonium carbonate to form ammonia, carbon dioxide and water; absorbing the carbon dioxide and water by the diethanolamine to form diethanolamine carbonate; and supplying the ammonia to the GC/CI-MS/MS. Another method of supplying ammonia to a gas chromatography-chemical ionization tandem mass spectrometry (GC/CI-MS/MS) includes the steps of: providing ammonium carbonate and a mixture of monoethanolamine and diethanolamine in a reaction vessel; reacting the ammonium carbonate with the monoethanolamine to form ammonia and monoethanolamine carbonate; and supplying the ammonia to the GC/CI-MS/MS.
    Type: Grant
    Filed: January 9, 2024
    Date of Patent: September 24, 2024
    Assignee: NAIF ARAB UNIVERSITY FOR SECURITY SCIENCES (NAUSS)
    Inventor: Khaled Masoud Mohamed Masoud
  • Patent number: 12070719
    Abstract: According to one embodiment, a gas processing equipment includes an oxygen remover 2 that removes oxygen contained in exhaust gas G, and a gas processing device 3 that processes pretreated exhaust gas G (P), from which the oxygen has been removed by the oxygen remover 2, with a carbon dioxide absorbent solvent S as a treatment agent.
    Type: Grant
    Filed: March 15, 2022
    Date of Patent: August 27, 2024
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Daigo Muraoka, Koshito Fujita, Shinji Murai, Hayato Morigaki, Osamu Shibasaki, Yasuhiro Kato, Satoshi Saito, Takehiko Muramatsu, Ryosuke Shibata, Yusuke Handa
  • Patent number: 12070720
    Abstract: A plant and a method for producing decarbonized oxide or hydroxide using carbonate, water and electric power. The plant includes an electric calciner, a contactor, a pH correction apparatus, and a dosing device. The plant is adapted to receive at the inlet electric power, carbonate and water, and to release at the outlet decarbonized oxide or hydroxide and a buffered ionic mixture rich in bicarbonates, which, once released into the sea, represents the permanent storage for CO2. The plant uses the bicarbonates as permanent CO2 storage in the sea: this storage allows a CO2 storage at low costs and in modular plants.
    Type: Grant
    Filed: December 16, 2021
    Date of Patent: August 27, 2024
    Assignee: LIMENET S.R.L. SOCIETA' BENEFIT
    Inventor: Giovanni Cappello
  • Patent number: 12059648
    Abstract: A carbon dioxide (CO2) capture system and method for removing CO2 from an inlet gas including a first fluid stream inlet providing for the flow of a first fluid stream, such as an inlet gas containing CO2, and a second fluid stream inlet providing for the flow of a second fluid stream, such as steam, an outlet providing for the flow of a CO2 depleted stream from the CO2 capture system, an outlet providing for the flow of a CO2 stream from the CO2 capture system and a concentrator in fluid communication with the first fluid stream. The system further including a first contactor and a second contactor. Each of the first contactor and the second contactor defining therein a first fluidically-isolated, sorbent-integrated, fluid domain for flow of the first fluid stream and CO2 adsorption and a second fluidically-isolated fluid domain for flow of the second fluid stream to assist in desorption.
    Type: Grant
    Filed: February 5, 2021
    Date of Patent: August 13, 2024
    Assignee: GE INFRASTRUCTURE TECHNOLOGY LLC
    Inventors: David Roger Moore, Vitali Victor Lissianski, Mark Daniel Doherty, Daniel Jason Erno, Anil Raj Duggal
  • Patent number: 12048895
    Abstract: In general, the subject matter described herein relates to wettable materials that can be used to expose a liquid phase to a gas phase. An example method includes: providing a material including a polymeric substrate and at least one of: a silicate coating disposed over the polymeric substrate; or a polar mineral additive dispersed within the polymeric substrate at a loading from about 1% to about 25%, by weight; and using the material in a chemical process in which the material is at least partially covered by a liquid phase and the liquid phase is exposed to a gas phase.
    Type: Grant
    Filed: July 10, 2023
    Date of Patent: July 30, 2024
    Assignee: Klöckner Pentaplast of America, Inc.
    Inventors: Timothy D. Weatherill, Gerald J. Fiorillo, Sarah C. Rogers, Jeffrey W. Smith, Carlos Daniel Stagnaro, Devesh Mathur, Ryan Joseph Carter
  • Patent number: 12044694
    Abstract: A method and system for adsorbed phase activity coefficients for mixed-gas adsorption includes: providing one or more processors, a memory communicably coupled to the one or more processors and an input/output device communicably coupled to the one or more processors; calculating a first gas activity coefficient ?1 for a first gas using the one or more processors and a first equation; calculating a second gas activity coefficient y2 for a second gas using the one or more processors and a second equation based on a bulk mole fraction of the first gas; providing the first gas activity coefficient y1 for the first gas and the second gas activity coefficient y2 for the second gas to the input/output device; and using the first gas activity coefficient y1 for the first gas and the second gas activity coefficient y2 for the second gas in the gas adsorption system.
    Type: Grant
    Filed: October 21, 2019
    Date of Patent: July 23, 2024
    Assignee: Texas Tech University System
    Inventors: Chau-Chyun Chen, Hla Tun, Harnoor Kaur
  • Patent number: 12042763
    Abstract: The invention relates to a carbon-sequestering desalination brine waste processing system comprising a carbon sequestration system and a plurality of brine removal system for a desalinization plant. The carbon sequestration system is configured to receive brine from a brine source and inject at least one of CO2 or CO into the brine to provide carbon sequestrated brine. The plurality of brine removal systems are connected in series or parallel and sequentially extract brine and water vapor from the carbon sequestrated brine. Each brine removal system includes at least one atomizing unit for spray atomization and vacuum flashing the carbon sequestrated brine into atomized water vapor and concentrated brine. Further, each subsequent brine removal system includes at least one mineral extraction unit allowing sequential removal of minerals from the concentrated brine received from a previous brine removal system, and provide minerals and stable carbon products, till substantially zero brine discharge is achieved.
    Type: Grant
    Filed: December 1, 2022
    Date of Patent: July 23, 2024
    Inventors: Larry M. Shultz, George E. Snider, Darin Diorio
  • Patent number: 12030785
    Abstract: Methods of processing magnesium silicate materials are described to produce a number of products including magnesium hydroxide. Related methods of use of processed magnesium silicate and other reaction products are described for energy production, cement manufacture and carbon sequestration. In one embodiment the method comprises subjecting a magnesium silicate source to an acid digestion; increasing the digested liquid pH to produce a magnesium salt solution; subjecting the magnesium salt solution to electrolysis; and recovering magnesium hydroxide produced from electrolysis. By-products such as silica, iron oxy(oxides) and others are also described along with further reaction products such as magnesium oxide and magnesium carbonate.
    Type: Grant
    Filed: August 20, 2021
    Date of Patent: July 9, 2024
    Assignee: ASPIRING MATERIALS LIMITED
    Inventors: Allan Charles Nye Scott, Christopher John-Paul Oze
  • Patent number: 12012362
    Abstract: Carbonatable calcium silicate-based cements and concretes are presented, which result in concrete compositions that have an improved aesthetics. A cement product includes a plurality of particles of a carbonatable calcium silicate cement and a first additive; wherein, the first additive is a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: June 18, 2024
    Assignee: SOLIDIA TECHNOLOGIES, INC.
    Inventors: Vincent Briaud, Frédéric Cervera, Vincent Meyer, Sadananda Sahu, Ahmet Cuneyt Tas, Deepak Ravikumar, Jason Elizan Bryant, Anuj Seth
  • Patent number: 12005390
    Abstract: In a general aspect, a carbon dioxide removal system is presented. In some cases, a gas-liquid contactor is wetted with an alkaline capture solution. A first flow from a first gaseous feed including CO2 from a first source is directed to interact with the alkaline capture solution in the gas-liquid contactor, which forms a first CO2-rich alkaline capture solution. A second flow from a second gaseous feed including CO2 from a second, distinct source is directed to interact with the first CO2-rich alkaline capture solution, which forms a second CO2-rich alkaline capture solution. In some cases, the second flow is independent of the first gaseous feed, and a concentration of CO2 in the second CO2-rich alkaline capture solution is higher than a concentration of CO2 in the first CO2-rich alkaline capture solution. CO2 can be separated from the second CO2-rich alkaline capture solution.
    Type: Grant
    Filed: November 15, 2023
    Date of Patent: June 11, 2024
    Assignee: AirMyne, Inc.
    Inventors: Bart Ludo Scherpbier, Jun Seon Hong, Derek Chase Popple, Mark Patrick Cyffka, Aryaman Bhartia, Cyndia Aiyun Cao, Arun Suresh Kamath, Sudip Mukhopadhyay
  • Patent number: 11992801
    Abstract: A device, system, and method for small scale CO2 extraction is disclosed. The device includes a sorbent bed having a sorbent resin. The device also includes a blower in fluid communication with the sorbent bed through at least one duct, as well as a collection tray beneath the sorbent bed and having a drain. The device also includes a capture configuration and a regeneration configuration. The capture configuration includes an air flow driven by the blower passing through the sorbent resin. The regeneration configuration includes the flooding of at least the sorbent resin with regeneration fluid. The regeneration fluid has a higher dissolve inorganic carbon concentration after flooding the sorbent resin. Multiple devices may be employed together as a system capable of providing a continuous product stream having an upgraded concentration of CO2.
    Type: Grant
    Filed: April 9, 2020
    Date of Patent: May 28, 2024
    Assignee: Arizona Board of Regents on Behalf of Arizona State University
    Inventor: Klaus Lackner
  • Patent number: 11964234
    Abstract: There are provided methods for treating a gas having an undesirable odor. The methods comprise contacting the gas with an acidic aqueous oxidizing composition having a pH of about 2.0 to about 3.0 and comprising at least one cation of a metal; a sequestering agent; and H2O2 and submitting the gas and the composition to UV radiation when the gas and the composition are contacting each other, wherein the treatment permits to reduce by at least 60% intensity of the undesirable odor.
    Type: Grant
    Filed: May 13, 2022
    Date of Patent: April 23, 2024
    Assignee: EXP SERVICES INC.
    Inventors: Martin Beaulieu, Stéphane Chabot, Yves Charest
  • Patent number: 11958788
    Abstract: The present invention discloses a method of preparing an alkali activation material by using red mud-based wet grinding and carbon sequestration and an application thereof. The preparation method includes: (1) adding water, red mud, a crystalline control agent, and a grinding aid into a wet grinding carbon sequestration apparatus to perform wet grinding, and simultaneously introducing CO2 until a slurry pH reaches 7 to 7.5; and removing wet grinding balls by a sieve to obtain a slurry A; (2) adding carbide slag, water and a water reducer to a wet planetary ball grinder tank for wet grinding, and removing wet grinding balls by a sieve to obtain a slurry B; (3) taking 50 to 80 parts of the slurry A and 20 to 50 parts of the slurry B and mixing them to obtain an alkali activation material.
    Type: Grant
    Filed: May 23, 2023
    Date of Patent: April 16, 2024
    Assignee: Hubei University Of Technology
    Inventors: Xingyang He, Weilong Li, Ying Su, Zhengqi Zheng, Jin Yang, Yingbin Wang, Hongbo Tan, Chenghao Li
  • Patent number: 11945999
    Abstract: The present invention relates to a composition for scavenging hydrogen sulphide and/or mercaptans in hydrocarbon streams, the composition comprising an oxazolidine compound and a synergistic additive.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: April 2, 2024
    Assignee: TOTAL MARKETING SERVICES
    Inventors: Hemant Surendra Mondkar, Frédéric Tort
  • Patent number: 11946344
    Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.
    Type: Grant
    Filed: July 14, 2022
    Date of Patent: April 2, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Hasmukh A. Patel, Katherine Leigh Hull, Younane N. Abousleiman, Rajesh Goteti, David Jacobi
  • Patent number: 11919774
    Abstract: A cooling absorption tower for a CO2 recovery device, comprises: an outer shell; a cooling section for cooling a flue gas, the cooling section being disposed in the outer shell; and an absorbing section configured to cause CO2 in the flue gas cooled by the cooling section to be absorbed in an absorption solvent, the absorbing section being disposed in the outer shell and above the cooling section.
    Type: Grant
    Filed: February 10, 2020
    Date of Patent: March 5, 2024
    Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Yoshiki Sorimachi, Takashi Kamijo, Shinya Kishimoto
  • Patent number: 11905303
    Abstract: Disclosed are metal organic frameworks (MOFs) for adsorbing guest species, methods for the separation of gases using the MOFs, and systems comprising the MOFs. The MOFs comprise a plurality of secondary building units (SBUs), each SBU comprising a repeating unit of one metal cation connected to another metal cation via a first moiety of an organic linker; a layer of connected adjacent SBUs in which a second moiety of the linker in a first SBU is connected to a metal cation of an adjacent SBU, and wherein adjacent layers are connected to each other via linker-to-linker bonding interactions.
    Type: Grant
    Filed: December 20, 2019
    Date of Patent: February 20, 2024
    Assignee: Massey University
    Inventors: Omid Taheri Qazvini, Shane Telfer
  • Patent number: 11826695
    Abstract: A gas separation system has system input inlet configured to receive a stream mixture including a target gas, one or more spray generators positioned to spray a non-sprayable liquid to change a concentration of the target gas in the non-sprayable liquid, one or more system outlets positioned to outlet an output material, wherein at least one of the system outlets outputs a material having a lower amount of the target gas than the input stream mixture, and a recirculating path connected to the one or more outputs and the input inlet to allow recirculation of the non-sprayable liquid. A method of performing gas separation includes absorbing a target gas from an input stream in a non-sprayable capture liquid, and releasing the target gas in an output gas stream by spraying the non-sprayable capture liquid into a heated volume using a spray generator.
    Type: Grant
    Filed: October 25, 2021
    Date of Patent: November 28, 2023
    Assignee: XEROX CORPORATION
    Inventors: Mahati Chintapalli, Jerome Unidad, Kathryn F. Murphy, Ravi Neelakantan, Rahul Pandey, Stephen Matthew Meckler, David Mathew Johnson
  • Patent number: 11813566
    Abstract: Described herein are membrane processes for separating CO2 from flue gas. An exemplary process involves passing a fluid stream including the flue gas across a membrane permeable to CO2 and H2O, removing treated gas from a feed side of the membrane that has less CO2 than the flue gas, and removing permeate from a permeate side of the membrane comprising CO2 and H2O. Suitably, the permeate is removed at a sub-atmospheric vacuum pressure. The permeate is then cooled to remove at least some of the H2O from the permeate and form a smaller volume of H2O-depleted, CO2 enriched permeate.
    Type: Grant
    Filed: May 10, 2021
    Date of Patent: November 14, 2023
    Assignee: Membrane Technology and Research, Inc.
    Inventor: Richard W. Baker
  • Patent number: 11795843
    Abstract: A gas turbine plant includes a gas turbine, an exhaust line, an exhaust heat recovery boiler that generates steam due to heat of exhaust gas and guides the exhaust gas to the exhaust line, a carbon dioxide recovery device that recovers carbon dioxide contained in the exhaust gas, a heat exchanger that cools the exhaust gas to a temperature set in advance, and a circulation line that branches from a position between the carbon dioxide recovery device and the heat exchanger and is connected to an inlet of the gas turbine. The carbon dioxide recovery device has an absorption tower that absorbs carbon dioxide contained in the exhaust gas by causing the exhaust gas at the set temperature and an absorption liquid to come into contact with each other. The heat exchanger is formed of a material having higher corrosion resistance than a material forming the exhaust heat recovery boiler.
    Type: Grant
    Filed: July 22, 2020
    Date of Patent: October 24, 2023
    Assignees: MITSUBISHI HEAVY INDUSTRIES, LTD., MITSUBSHI HEAVY INDUSTRIES ENGINEERING, LTD.
    Inventors: Atsushi Tsutsumi, Tetsuya Tanaka, Naoyuki Nagafuchi, Takashi Kamijo
  • Patent number: 11731080
    Abstract: A two or particularly three-phase process, and corresponding apparatus, desulfurizes sour hydrocarbon gas, e.g., natural gas, generally better than known, using a fixed-bed, two-phase processes in terms of the amount of H2S scavenged and the breakthrough time of H2S. The three-phase process is effective in scavenging H2S at ambient temperature and pressure, using a copper salt catalyst impregnated on alumina or other generally inert support, which is regenerable.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: August 22, 2023
    Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: Sagheer A. Onaizi, Reyad Shawabkeh, Zuhair Omar Malaibari, Nabeel Salim Abu-Ghander
  • Patent number: 11691104
    Abstract: Disclosed are methods and systems for capturing carbon dioxide (CO2) from an input gas stream (e.g., flue gas from a combustion process). In particular, the system includes a CO2 absorption module that directs supersaturated CO2 process water to a CO2 recovery process. The CO2 recovery process includes a sparging seal vessel, followed by an agitator, followed by a stripper unit, followed by an outgassing tank, and lastly a membrane separator, configured to outgas CO2 from the supersaturated process water and direct the gaseous CO2 into a CO2 collection header.
    Type: Grant
    Filed: August 5, 2022
    Date of Patent: July 4, 2023
    Assignee: Enviro Ambient Corporation
    Inventors: Andrew Verdouw, Sanjeev Jolly
  • Patent number: 11673804
    Abstract: Proposed is a process and a plant for production of pure carbon monoxide and hydrogen by steam reforming of hydrocarbons, preferably methane or naphtha, to afford a raw synthesis gas and subsequent, multistage workup, purification and fractionation of the raw synthesis gas to afford the target products, wherein the material streams obtained as by-products of the process chain are also to be advantageously utilized. This is achieved according to the invention by providing the recirculating compressor provided for recycling of the by-product material streams with a plurality of parallel, independently operable compressor stages.
    Type: Grant
    Filed: March 25, 2021
    Date of Patent: June 13, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Jean-Philippe Tadiello, Yue Chen
  • Patent number: 11666853
    Abstract: Disclosed are a carbon dioxide absorbent composition in which an N-alkylaminoalkanol; a polyhydroxyamine-based compound; and ethylenediamine and/or diethylenetriamine are mixed, a method for preparing the same, and a method and an apparatus for carbon dioxide absorption/separation using the same. Since the carbon dioxide absorbent according to the present disclosure has superior carbon dioxide absorption capacity and remarkably lower absorbent recycling temperature as compared to the existing absorbents such as monoethanolamine, etc., total energy consumption in the capturing process can be reduced greatly. In addition, since carbon dioxide is recovered at low recycling temperature, contamination by water or absorbent vapor may be prevented.
    Type: Grant
    Filed: February 15, 2021
    Date of Patent: June 6, 2023
    Assignees: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY, KOREA LAND & HOUSING CORPORATION
    Inventors: In Wook Nah, Jae Ik Kim, Soon Jong Kwak, In Hwan Oh, Daeseung Kyung, Youngjong Sim, Yeongmin Kim, Han-Guen Ahn, Sang-Ick Choi
  • Patent number: 11638897
    Abstract: The disclosure provides a method of treating flue gas that has one or more components. The method comprises passing a solution through both a magnetic field and an electric field to form an activated solution. The method also comprises contacting the activated solution with the flue gas so that the one or more components of the flue gas are at least partially absorbed by the activated solution to form a residue solution.
    Type: Grant
    Filed: February 14, 2022
    Date of Patent: May 2, 2023
    Inventor: Paul Steding
  • Patent number: 11612855
    Abstract: Disclosed are processes, apparatuses, and systems for Direct Air Carbon Capture utilizing waste heat from gas turbines and exhaust air from air cooled heat exchangers, such as in industrial facilities with sources of heat and using fans. The exhaust air from the air cooled heat exchangers may be used to drive one or more fans in one or more Direct Air Carbon Capture units. The waste heat—thus no electricity needed—may be used to regenerate the catalyst(s) in the Direct Air Carbon Capture units.
    Type: Grant
    Filed: March 1, 2022
    Date of Patent: March 28, 2023
    Assignee: NEXT CARBON SOLUTIONS, LLC
    Inventors: Ivan Van der Walt, Ben Heichelbech, Vikrum Subra
  • Patent number: 11577198
    Abstract: Methods of sequestering CO2 from a gaseous source of CO2 are provided. Aspects of the methods include employing an alkali enrichment protocol, such as a membrane mediated alkali enrichment protocol, in a CO2 sequestration protocol. Also provided are systems for practicing the methods.
    Type: Grant
    Filed: December 18, 2020
    Date of Patent: February 14, 2023
    Assignee: Blue Planet Systems Corporation
    Inventors: Brent R. Constantz, Chris L. Camire, Jacob Schneider, Mark Bewernitz
  • Patent number: 11571658
    Abstract: An apparatus includes a housing that defines a first zone, a second zone, a third zone, and a fourth zone. The apparatus includes an inlet, a first outlet, a second outlet, and a conveyor belt. The inlet is configured to receive a carbon dioxide-containing fluid in the first zone. The first outlet is configured to discharge a carbon dioxide-depleted fluid from the first zone. The second outlet is configured to discharge a carbon dioxide-rich fluid from the third zone. The conveyor belt passes through each of the zones. The conveyor belt includes a carbon dioxide sorbent. Within the first zone, the carbon dioxide sorbent is configured to adsorb carbon dioxide from the carbon dioxide-containing fluid to produce the carbon dioxide-depleted fluid. Within the third zone, the carbon dioxide sorbent is configured to desorb the captured carbon dioxide to produce the carbon dioxide-rich fluid.
    Type: Grant
    Filed: January 4, 2021
    Date of Patent: February 7, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Mourad Younes, Aqil Jamal
  • Patent number: 11571652
    Abstract: The present invention is directed to a method and system of purifying hydrogen supplied from a storage cavern, particularly to removing methane and other hydrocarbons from the hydrogen withdrawn from the cavern by using selective adsorption. The adsorbed impurities can be removed from the adsorbent by increasing the temperature, reducing the pressure, or a combination of both.
    Type: Grant
    Filed: June 22, 2021
    Date of Patent: February 7, 2023
    Assignee: PRAXAIR TECHNOLOGY, INC.
    Inventors: Minish Mahendra Shah, Joseph M. Schwartz, Marian Simo, Paul R. Munsterman, Werner Leitmayr, Keith A. Craigie, Ana Arevalo-Hidalgo, Olivier Dube
  • Patent number: 11484827
    Abstract: Disclosed are processes, apparatuses, and systems that can be used in natural gas pipelines to significantly reduce the CO2 emissions of the natural gas pipelines, by capturing combusted flue gas which is normally wasted and putting it back to the pipelines, which can also be monetized (e.g., carbon credits). One example process may include producing a captured CO2 stream from a combustion gas of a gas turbine in a natural gas pipeline, compressing the captured CO2 stream, and combining the compressed CO2 stream with natural gas transported in the natural gas pipeline.
    Type: Grant
    Filed: March 1, 2022
    Date of Patent: November 1, 2022
    Assignee: NEXT CARBON SOLUTIONS, LLC
    Inventors: Ivan Van der Walt, Ben Heichelbech, Vikrum Subra, Connor Rivard
  • Patent number: 11420150
    Abstract: An aminated magnesium oxide adsorbent, which is the reaction product of a magnesium oxide matrix having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the disordered mesopores of the magnesium oxide matrix, and wherein the aminated magnesium oxide adsorbent has an average pore volume of 0.2 to 0.4 cm3/g. A method of making the aminated magnesium oxide adsorbent and a method of capturing CO2 from a gas mixture with the aminated magnesium oxide adsorbent are also described.
    Type: Grant
    Filed: February 21, 2020
    Date of Patent: August 23, 2022
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Sagheer A. Onaizi, Ali M. Alkadhem
  • Patent number: 11414962
    Abstract: Systems and methods are described for sequestering carbon stored in organic matter while minimizing the release of carbon dioxide (CO2) and methane (CH4) into the atmosphere, with the carbon (C) being stored as char or coal through the coalification process. Organic matter will be moved to submarine hydrothermal vent fields where the extreme heat in the water will drastically accelerate the degradation of the material and destroy microbes that normally consume the organic material and release the carbon as CO2 or CH4. The oxygen level in the heated water around the vents is extremely low. The water surrounding these vents can reach temperatures of 400° C. (750° F.). Exemplary implementations may include constructing hydrothermal borehole vents to harness the energy continuously released from the Earth's core in the form of volcanic heat.
    Type: Grant
    Filed: September 3, 2021
    Date of Patent: August 16, 2022
    Inventor: Frederick William MacDougall
  • Patent number: 11331625
    Abstract: A gas treatment method includes an absorption step in which a gas to be treated containing an acidic compound, such as carbon dioxide, is brought into contact, in an absorber, with a treatment liquid that absorbs the acidic compound; and a regeneration step in which the treatment liquid, having the acidic compound absorbed therein, is sent to a regenerator, and the treatment liquid is then heated to separate the acidic compound from the treatment liquid. In the regeneration step, a gas almost insoluble to the treatment liquid, such as hydrogen gas, is brought into contact with the treatment liquid.
    Type: Grant
    Filed: November 12, 2018
    Date of Patent: May 17, 2022
    Assignees: Kobe Steel, Ltd., National University Corporation Tokai National Higher Education and Research System
    Inventors: Akira Kishimoto, Katsuya Akiyama, Hiroshi Machida, Tsuyoshi Yamaguchi, Takehiro Esaki, Koyo Norinaga
  • Patent number: 11311835
    Abstract: A method for capturing carbon dioxide (CO2) from an effluent gas using a rice-derived product can include providing a rice-derived product, adjusting a pH of the rice-derived product; and contacting the effluent gas with the rice-derived product to capture the carbon dioxide from the effluent gas mixture in the rice-derived product. In an embodiment, the rice-derived product includes puffed rice grains. In an embodiment, the rice-derived product includes a rice cake. In an embodiment, the rice-derived product is loaded into a gas contact device prior to contacting withe the effluent gas.
    Type: Grant
    Filed: July 18, 2021
    Date of Patent: April 26, 2022
    Assignee: UNITED ARAB EMIRATES UNIVERSITY
    Inventors: Ameera Fares Rasheed Mohammad, Abeer Fuad Othman Dar Saleh, Maatouk Khoukhi, Ali H. Al-Marzouqi
  • Patent number: 11305229
    Abstract: The present development is a method for capturing and purifying CO2 from a flue gas stream using a metal aluminate nanowire absorbent and then regenerating the absorbent. After the CO2 is adsorbed into the absorbent, the adsorbent is regenerated by subjecting the CO2 saturated adsorbent to a dielectric barrier discharge plasma or to a microwave plasma or to a radio frequency (RF) plasma while ensuring that the external temperature does not exceed 200° C.
    Type: Grant
    Filed: December 31, 2020
    Date of Patent: April 19, 2022
    Inventors: Juan He, Tu Nguyen, Mahendra Sunkara
  • Patent number: 11305228
    Abstract: The present invention provides a new method for fixing carbon dioxide. The method for fixing carbon dioxide of the present invention includes a contact step of bringing a mixed liquid containing sodium hydroxide and further containing at least one of a chloride of a Group 2 element or a chloride of a divalent metal element into contact with a gas containing carbon dioxide.
    Type: Grant
    Filed: August 29, 2019
    Date of Patent: April 19, 2022
    Assignees: SHINKO SANGYO Co., Ltd.
    Inventor: Kenji Sorimachi
  • Patent number: 11247940
    Abstract: A manufacturing process of a concrete product includes: (1) extracting calcium from solids as portlandite; (2) forming a cementitious slurry including the portlandite; (3) shaping the cementitious slurry into a structural component; and (4) exposing the structural component to carbon dioxide sourced from a flue gas stream, thereby forming the concrete product.
    Type: Grant
    Filed: September 28, 2018
    Date of Patent: February 15, 2022
    Assignees: The Regents of the University of California, Arizona Board of Regents
    Inventors: Gaurav Sant, Laurent G. Pilon, Bu Wang, Narayanan Neithalath, Zhenhua Wei, Benjamin Young, Gabriel D. Falzone, Dante Simonetti
  • Patent number: 11219860
    Abstract: A method of scrubbing a gas, such as flue gas or exhaust gas, comprising carbon dioxide to deplete the gas of carbon dioxide (CO2), the method comprising the steps of: scrubbing the gas in a scrubber (210) with a first alkaline, aqueous scrubbing liquid to dissolve carbon dioxide (CO2) as hydrogen carbonate (HCO3?) and/or as carbonate (CO32?) in the first alkaline, aqueous scrubbing liquid, thereby providing a first spent aqueous scrubbing liquid comprising hydrogen carbonate (HCO3?) and/or carbonate (CO32?), the first spent aqueous scrubbing liquid having a pH from about 7 to about 9; feeding the first spent aqueous scrubbing liquid to an anode chamber of an electrolytic cell (310) comprising the anode chamber (313) and a cathode chamber (312) separated by a membrane (311); regenerating the first spent aqueous scrubbing liquid in the electrolytic cell (310) by electrolysis, the electrolysis increasing the pH of the first spent aqueous scrubbing liquid in the cathode chamber (312), the electrolysis further
    Type: Grant
    Filed: May 26, 2021
    Date of Patent: January 11, 2022
    Assignee: ESTECH A/S
    Inventor: Jan Stougaard Jakobsen
  • Patent number: 11179698
    Abstract: Polymeric sorbents for carbon dioxide are provided. More particularly, the polymeric sorbents are a reaction product of a divinylbenzene/maleic anhydride precursor polymeric material with a nitrogen-containing compound. The nitrogen-containing compound is covalently attached to the polymeric sorbents. Additionally, methods of sorbing carbon dioxide on the polymeric sorbents and compositions resulting from sorbing carbon dioxide on the polymeric sorbents are provided. The polymeric sorbents typically are porous and can selectively remove carbon dioxide from other gases such as methane or hydrogen.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: November 23, 2021
    Assignee: 3M Innovative Properties Company
    Inventors: Michael S. Wendland, Michael W. Kobe
  • Patent number: 11167261
    Abstract: The present invention relates to a carbon dioxide absorbent used for absorbing carbon dioxide, a carbon dioxide absorbent composition used for producing the carbon dioxide absorbent, and a solid raw material for a carbon dioxide absorbent included in the carbon dioxide absorbent.
    Type: Grant
    Filed: November 18, 2016
    Date of Patent: November 9, 2021
    Assignees: KOREA ELECTRIC POWER CORPORATION, KOREA SOUTH-EAST POWER CO., LTD., KOREA MIDLAND POWER CO., LTD., KOREA SOUTH POWER CO., LTD., KOREA WESTERN POWER CO., LTD.
    Inventors: Joong Beom Lee, Tae Hyoung Eom, Hyun Geun Jo, Jeom In Baek, Ui Sik Kim