Nitrogen Or Nitrogenous Component Patents (Class 423/235)
  • Patent number: 8241597
    Abstract: A system and method for removing pollutants and greenhouse gases SO2, NO2, and CO2 from a flue gas stream, includes: a) contacting natural seawater with a flue gas for a given period of time to remove SO2 from the flue gas; b) contacting treated alkaline water to the flue gas to remove CO2 and NOx from the flue gas and generate oxygen and carbon particles; and c) collecting or emitting the flue gas after step b). The method and the system of the invention are significantly more economical and convenient and do not cause harm to the environments. The invention also exhibits a novel and unique feature that elemental carbon and oxygen are generated as final products and can be recovered as an energy source.
    Type: Grant
    Filed: June 3, 2009
    Date of Patent: August 14, 2012
    Assignee: Ecospec Global Technology Pte. Ltd.
    Inventor: Hwee Hong Chew
  • Patent number: 8242049
    Abstract: A catalytic material which includes a metal oxide catalyst anchored to a nano-sized metal oxide crystal as support and functions well at low temperatures. The catalytic material may optionally include another metal oxide as a promoter deposited on the surface of the support to modify the properties of the metal oxide catalyst and/or the properties of the support. The catalyst may be vanadium oxide, tungsten oxide, manganese oxide, chromium oxide or molybdenum oxide; the support may be TiO2, SiO2, Al2O3, ZrO2, or WO3; and the promoter may be vanadium oxide, tungsten oxide, manganese oxide, chromium oxide or molybdenum oxide. The present invention also provides a method of producing the catalytic materials, which is useful in removing ammonia and other nitrogen containing contaminants.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: August 14, 2012
    Assignee: The Hong Kong University of Science and Technology
    Inventors: King-Lun Yeung, Pik-Ying Lui, Ka-Yee Ho, Miguel Angel Banares
  • Publication number: 20120189519
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Application
    Filed: March 26, 2012
    Publication date: July 26, 2012
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Publication number: 20120189520
    Abstract: Concentrated aqueous hydrogen peroxide or another reactive compound in a liquid carrier is activated by atomization and contact with a suitable catalyst that is concurrently atomized in a carrier liquid. Concentrated hydrogen peroxide and a hydrogen peroxide activation catalyst are atomized into a droplet spray for catalytic activation of the hydrogen peroxide in this invention, useful for treatment of a combustion flue gas containing contaminants such as NO? and/or Hg.
    Type: Application
    Filed: July 29, 2010
    Publication date: July 26, 2012
    Applicants: INDIGO TECHNOLOGIES GROUP PTY. LTD., FMC CORPORATION
    Inventors: Henry A. Pfeffer, Timothy A. Holtz, Rodney J. Truce, JoAnn Pacinelli, Luke F. Wilkinson
  • Patent number: 8226912
    Abstract: A gaseous mixture, comprising CO2, H2, H2S and optionally CO, is separated into an H2 or H2 and CO product stream (H2/CO product stream), and a CO2 enriched stream containing at least one combustible component selected from H2S, H2, CO and any additional combustible components present in the gaseous mixture. A support fuel stream, comprising one or more combustible components, is combusted to form a stable flame, and the CO2 enriched stream and flame are contacted in the presence of sufficient O2 to combust all or substantially all of the combustible component(s) present in said CO2 enriched stream. A CO2 product stream is formed from said combustion effluent. The support fuel stream may be generated from the process of generating or separating the gaseous mixture or from the H2/CO product stream. Where the CO2 enriched stream contains H2S, the support fuel stream may also be a stream obtained off-site that comprises H2S.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: July 24, 2012
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Jeffrey William Kloosterman, Kevin Boyle Fogash, Andrew David Wright
  • Patent number: 8226916
    Abstract: Inhalation of low levels of nitric oxide can rapidly and safely decrease pulmonary hypertension in mammals. A nitric oxide delivery system that converts nitrogen dioxide to nitric oxide employs a surface-active material, such as silica gel, coated with an aqueous solution of antioxidant, such as ascorbic acid.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: July 24, 2012
    Assignee: Geno LLC
    Inventors: David R. Rounbehler, David H. Fine
  • Patent number: 8221712
    Abstract: An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: July 17, 2012
    Assignee: BASF SE
    Inventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Erika Dengler
  • Patent number: 8221687
    Abstract: A system and a method are provided for removing greenhouse gases, particulates and pollutants from the atmosphere utilizing a greenhouse gas collection apparatus. An atmospheric mixture is collected and progressively treated in first, second and third tube furnaces and a scrubber to produce an effluent for treatment in a chemical processing plant. The first tube furnace oxidizes hydrocarbons, the second tube furnace oxidizes any remaining nitrous and nitric oxides, and the third tube furnace oxidizes sulfur dioxide. The scrubber precipitates carbon dioxide as calcium carbonate. A vacuum pump draws the atmospheric mixture through tube furnaces and the scrubber.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: July 17, 2012
    Inventor: Ernest John Shearing
  • Publication number: 20120171093
    Abstract: The present invention generally relates to compositions comprising and methods for forming functionalized carbon-based nanostructures.
    Type: Application
    Filed: November 3, 2011
    Publication date: July 5, 2012
    Applicant: Massachusetts Institute of Technology
    Inventors: Timothy M. Swager, William R. Collins, Wiktor Lewandowski, Ezequiel Schmois, Stefanie Sydlik, Joseph Walish, John B. Goods
  • Patent number: 8197753
    Abstract: A virtual analyzer is provided to estimate either an attribute of a reactant applied during performance of, or an amount of a reactant exhausted by, a process having multiple process parameters (MPPs) that is performed to control an amount of a pollutant emitted into the air. The virtual analyzer includes an interface which receives signals corresponding to attributes of the MPPs. If the process is a wet flue gas desulfurization (WFGD) process, the signals include a signal corresponding to a measured pH level of the applied reactant. If the process is a selective catalytic reduction (SCR) process, the signals include a signal corresponding to a measured amount of the reactant exhausted by the process.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: June 12, 2012
    Assignee: Alstom Technology Ltd.
    Inventors: Scott A. Boyden, Stephen Piche
  • Publication number: 20120141346
    Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOx is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.
    Type: Application
    Filed: February 9, 2012
    Publication date: June 7, 2012
    Applicant: FMC CORPORATION
    Inventors: Henry A. Pfeffer, David E. Smith
  • Publication number: 20120141345
    Abstract: The invention includes an apparatus and process for the catalytic production of HCN from a feed gas of ammonia and a hydrocarbon gas by means of heat tubes supplying heat to the feed gas stream and heat tubes for removal of heat from the products. The invention further includes a process for N2O abatement comprising transferring heat from an exothermic N2O degradation reaction through a heat pipe.
    Type: Application
    Filed: May 14, 2008
    Publication date: June 7, 2012
    Inventor: Colin S. Slaten
  • Patent number: 8192528
    Abstract: A method and apparatus for separating mercury and other undesired constituents from a natural gas stream includes passing the raw gas stream sequentially through a first separator, an amine treatment unit, a cooler, a second separator, a dehydrator, a cooler and a third separator. The first separator receives the natural gas stream and separates hydrocarbon and water condensates from the stream; the amine treatment unit removes acid gases; the cooler reduces the temperature of the gas stream to condense additional hydrocarbons and water that are removed by the second separator; and the dehydrator removes water vapor. Next, the temperature of the stream is reduced by the second cooler to condense the mercury and any remaining hydrocarbon vapors.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: June 5, 2012
    Assignee: Saudi Arabian Oil Company
    Inventor: Faisal M. Al-Faqeer
  • Patent number: 8187544
    Abstract: Various systems, devices, NO2 absorbents, NO2 scavengers and NO2 recuperator for generating nitric oxide are disclosed herein. According to one embodiment, an apparatus for converting nitrogen dioxide to nitric oxide can include a receptacle including an inlet, an outlet, a surface-active material coated with an aqueous solution of ascorbic acid and an absorbent wherein the inlet is configured to receive a gas flow and fluidly communicate the gas flow to the outlet through the surface-active material and the absorbent such that nitrogen dioxide in the gas flow is converted to nitric oxide.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: May 29, 2012
    Assignee: Geno LLC
    Inventors: David Fine, Gregory Vasquez, David P. Rounbehler
  • Patent number: 8182776
    Abstract: An integrated process for operating a fossil fuel fired power plant including: producing hydrogen gas and an aqueous solution of hydrogen peroxide via a process including: dissociating hydrogen gas and oxygen gas from water; pressurizing the hydrogen gas and the oxygen gas; and mixing, under pressure, the oxygen gas and at least about a stoichiometric portion of the hydrogen gas with an aqueous solution of a catalyst and a promoter to form the aqueous solution of hydrogen peroxide; supplying a remainder of the hydrogen gas to at least one of (a) a storage means, (b) a boiler detonation cleaning system of the fossil fuel fired power plant, and (c) an electrical generator of the fossil fuel fired power plant; and injecting the aqueous solution of hydrogen peroxide into an air pollution control system of the fossil fuel fired power plant.
    Type: Grant
    Filed: August 10, 2010
    Date of Patent: May 22, 2012
    Assignee: Electric Power Research Institute, Inc.
    Inventor: Bruce Edward Scherer
  • Publication number: 20120121491
    Abstract: A system for forming metal hydroxide from a metal carbonate utilizes a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide.
    Type: Application
    Filed: December 13, 2011
    Publication date: May 17, 2012
    Applicant: Lawrence Livermore National Security, LLC
    Inventor: Gregory Hudson Rau
  • Patent number: 8176654
    Abstract: By a method and a device for preventing corrosion on and in the region of a gas inlet nozzle during nitric acid condensation, contact of the condensing gas with the nozzle and with the surroundings of the nozzle are supposed to be minimized. This is achieved in that the gas inlet nozzle has a sleeve on the inside in the transition region to the interior of the condenser, by which sleeve a gas inlet orifice in the form of an annular gap is formed, whereby the annular space is provided with at least one feed opening for secondary air, so that an enveloping flow of secondary air is produced around the entering NO gas.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: May 15, 2012
    Assignee: ThyssenKrupp Uhde GmbH
    Inventor: Rainer Maurer
  • Patent number: 8168148
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: May 1, 2012
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Patent number: 8155509
    Abstract: A device and method for providing a gaseous substance mixture which includes at least one reducing agent and/or at least one reducing agent precursor, includes a reservoir for an aqueous solution which includes at least one reducing agent precursor that can be flow connected to an evaporator chamber, and a device for dosing the aqueous solution in the evaporator chamber. A device can heat the evaporator chamber to a temperature higher than or equal to a critical temperature, in which the aqueous solution is at least partially evaporated. The device and method enable reducing agent to be provided for selective catalytic reduction of nitrogen oxides in the exhaust of an internal combustion engine. Preferably, an evaporator unit is configured as the evaporator chamber and a hydrolysis catalytic converter is disposed outside the exhaust system. As a result, the size of the hydrolysis catalytic converter is reduced, allowing compact construction.
    Type: Grant
    Filed: November 17, 2008
    Date of Patent: April 10, 2012
    Assignee: Emitec Gesellschaft fuer Emissionstechnologie mbH
    Inventors: Rolf Brück, Marc Brugger, Thomas Härig, Peter Hirth, Ulf Klein
  • Publication number: 20120082605
    Abstract: An exhaust treatment method is provided. Method of increasing activation of NOx reduction catalyst using two or more reductant is discussed. The NOx catalyst is disposed to receive both the exhaust stream and reductant stream. The sensor is disposed to sense a system parameter related to carbon loading of the catalyst and produce a signal corresponding to the system parameter. The controller is disposed to receive the signal and to control dosing of the reductant stream based at least in part on the signal. The method includes sensing a system parameter related to carbon loading of a catalyst, producing a signal corresponding to the system parameter and sending the signal to a controller; and controlling a dosing of a reductant stream based at least in part on the signal.
    Type: Application
    Filed: December 12, 2011
    Publication date: April 5, 2012
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Daniel George Norton, Benjamin Hale Winkler, Ashish Balkrishna Mhadeshwar, Dan Hancu, Stanlee Teresa Buddle
  • Patent number: 8147784
    Abstract: Combined removal of both ammonia from an ammonia-containing waste gas and nitrogen oxides from a nitrogen oxide-containing waste gas in a combined ammonia/urea synthesis plant is accomplished by mixing the gases and employing one or both of selective non-catalytic reduction at a temperature of 850° C. to 1100° C. or selective catalytic reduction at a temperature of 150° C. to 550° C., in which the ammonia and the nitrogen oxides react with one another to give nitrogen and water, the ammonia-containing waste gas derived from a low-pressure and/or atmospheric absorber of the urea synthesis plant, and the nitrogen oxide-containing waste gas derived from a flue gas duct of a primary reformer of the ammonia synthesis plant, both the ammonia and the nitrogen oxides of the mixed waste gas flows being depleted simultaneously during the same process step.
    Type: Grant
    Filed: March 12, 2010
    Date of Patent: April 3, 2012
    Assignee: Thyssenkrupp Uhde GmbH
    Inventors: Ivo Mueller, Joachim Johanning
  • Patent number: 8142745
    Abstract: The present invention relates to the selective separation of carbon dioxide (“CO2”) from nitrogen (“N2”) in streams containing both carbon dioxide and nitrogen utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from combustion gas (e.g., flue gas) streams preferably for sequestration of at least a portion of the carbon dioxide produced in combustion processes.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: March 27, 2012
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Sebastian C. Reyes, Jose G. Santiesteban, legal representative, Zheng Ni, Charanjit S. Paur, Pavel Kortunov, John Zengel, Harry W. Deckman
  • Patent number: 8142746
    Abstract: The present invention relates to the selective separation of carbon dioxide (“CO2”) from methane (“CH4”) in streams containing both carbon dioxide and methane utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from natural gas streams preferably for sequestration of at least a portion of the carbon dioxide present in the natural gas.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: March 27, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Sebastian C. Reyes, Jose G. Santiesteban, legal representative, Zheng Ni, Charanjit S. Paur, Pavel Kortunov, John Zengel, Harry W. Deckman
  • Patent number: 8145044
    Abstract: An air ammonia heater and vaporization chamber system utilizing a contiguous vaporization chamber having an inlet for receiving dilution air, which is passed across at least one heating element integrated into the vaporization chamber to heat and pre-heat the vaporization chamber. Aqueous or anhydrous ammonia is injected from at least one ammonia injector, which is integrated into the vaporization chamber, into the heated dilution air. The heated ammonia/air mixture may then be passed through a bed of packing prior to being released from the vaporization chamber. The bed of packing maintains the heated, homogenous ammonia/air mixture at a minimum temperature of 350° F. to ensure the air/ammonia mixture does not condense. The air ammonia heater and vaporization chamber system may be used in the vaporization and bleeding of ammonia with air for NOx reduction in the flue gas from heat recovery steam generation systems, packaged boilers, simple cycle catalyst systems or fired heaters.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: March 27, 2012
    Assignee: Honeywell International Inc.
    Inventors: Jeffrey Philip Wirt, Dan W. Ott
  • Publication number: 20120070354
    Abstract: The invention relates to a method for removing nitrogen monoxide (NO) and nitrogen oxides (NOx with x>1) from a gas stream, implementing a device including a catalytic bed for converting a portion at least a part of the NO into NOx with x>1, and a unit for reducing the NOx with x>1, and in which the gas stream is placed into contact with the catalytic bed before entering the unit for reducing the NOx with x>1.
    Type: Application
    Filed: May 18, 2010
    Publication date: March 22, 2012
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Alain Briglia, Ludovic Granados, Christian Monereau, Elise Renou
  • Patent number: 8137649
    Abstract: Horizontal gas-liquid scrubbing systems and associated gas scrubbing methodologies are provided. In one embodiment, a horizontal duct scrubbing system includes a horizontally disposed housing having a waste gas inlet and a treated gas outlet, a liquid inlet manifold disposed within the horizontally disposed housing, the liquid inlet manifold comprising a plurality of nozzles oriented to spray a scrubbing liquor co-current to the flow of a gas stream flowing through the horizontally disposed housing, and a demister located proximal the treated gas outlet, where the horizontally disposed housing is substantially free of flow deflection members between the liquid inlet manifold and the demister.
    Type: Grant
    Filed: February 14, 2011
    Date of Patent: March 20, 2012
    Assignee: Alcoa Inc.
    Inventors: Rajat Ghosh, Peter Bowen, Charles Dobbs, Roger Nichols, Neal Richard Dando, John R. Smith, Richard R. Lunt, Gregory Charles Kraft
  • Publication number: 20120058033
    Abstract: The present invention relates to a method for treating fluoro-containing and silicon-containing gas. The method comprises treating the gas with thermal-treating, particles-treating, catalyst-treating, and acid-removing sequentially to remove perfluorocompounds. The invention achieves results of reducing the working temperature, increasing the lifetime of the catalyst, reducing the operating cost of the system, and increasing the applications of the catalyst in the aspect of fluoride-containing gas, silicon-containing gas and particles containing gas treatment by sequential treating.
    Type: Application
    Filed: November 15, 2011
    Publication date: March 8, 2012
    Applicant: Industrial Technology Research Institute
    Inventors: Sheng-Jen YU, Shou-Nan LI, Shao-I YEN, Tzu-Ming CHEN
  • Publication number: 20120045379
    Abstract: In a method of storing and releasing gaseous ammonia from solid storage materials a first solid storage material (14) capable of releasing ammonia by desorption in a first container (10) and a second solid storage material (24) capable of ad- or absorbing ammonia reversibly and having a higher affinity for ammonia than the first storage material (14) in a second container (20) smaller than said first container (10) are in fluid communication. The pressure in at least the first container (10) is kept below the equilibrium pressure between ammonia and the storage material contained therein by means of a pump (28).
    Type: Application
    Filed: March 18, 2010
    Publication date: February 23, 2012
    Applicant: Amminex A/S
    Inventors: Tue Johannessen, Ulrich Quaade
  • Patent number: 8114367
    Abstract: A method of sequestering a greenhouse gas is described, which comprises: (i) providing a solution carrying a first reagent that is capable of reacting with a greenhouse gas; (ii) contacting the solution with a greenhouse gas under conditions that promote a reaction between the at least first reagent and the greenhouse gas to produce at least a first reactant; (iii) providing a porous matrix having interstitial spaces and comprising at least a second reactant; (iv) allowing a solution carrying the at least first reactant to infiltrate at least a substantial portion of the interstitial spaces of the porous matrix under conditions that promote a reaction between the at least first reactant and the at least second reactant to provide at least a first product; and (v) allowing the at least first product to form and fill at least a portion of the interior spaces of the porous matrix, thereby sequestering a greenhouse gas.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: February 14, 2012
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Richard E. Riman, Vahit Atakan
  • Patent number: 8110164
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: February 7, 2012
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Publication number: 20120017848
    Abstract: A method of safely vaporizing liquid chlorine containing high concentrations of nitrogen trichloride contaminant from a chloralkali plant. In a vertical plug-flow vaporizer having an upward flow direction, a stream of liquid chlorine containing nitrogen trichloride is received. A gas such as air, nitrogen or chlorine gas is introduced into the liquid stream upstream of the boiling zone of the vaporizer to induce a flow regime, for example annular flow or mist flow, that prevents a mass accumulation of nitrogen trichloride in the vaporizer. The liquid chlorine containing nitrogen trichloride is vaporized. The resulting gas stream may be processed to destroy the nitrogen trichloride and recycled to the chlorine production train.
    Type: Application
    Filed: March 6, 2010
    Publication date: January 26, 2012
    Applicant: NORAM International Limited
    Inventors: Clive Brereton, Sergio Berretta
  • Patent number: 8097074
    Abstract: An air filtration system and method for the remediation of hydrazine from contaminated air. The system is provided in the form of a container with an inlet port and an outlet port containing absorbent pads or filters or wipes saturated with a solution of a dicarbonyl compound. As contaminated air passes through the container, hydrazine present within the air reacts with the dicarbonyl compound and becomes neutralized, thereby resulting in the exit of pure air from the container. The absorbent pads can also be used independently to remove hydrazine liquid spill.
    Type: Grant
    Filed: July 17, 2009
    Date of Patent: January 17, 2012
    Assignee: New Mexico Highlands University
    Inventors: Merritt C. Helvenston, Rodolfo A. Martinez, Jose C′ De Baca, John R. Juarez
  • Publication number: 20120009107
    Abstract: Sulfur dioxide (SO2) is removed from carbon dioxide feed gas comprising SO2 as a contaminant by maintaining the carbon dioxide feed gas at an elevated pressure in contact with an alkaline sorbent for a period of time sufficient to react said alkaline sorbent with SO2. Where NOx, oxygen (O2) and water are also present, not only is the rate of reaction with the sorbent increased, but also additional SO2 is removed by conversion to sulfuric acid, and NOx is removed as nitric acid. The method has particular application in the removal of SO2 and NOx from flue gas produced by oxyfuel combustion of a hydrocarbon or carbonaceous fuel.
    Type: Application
    Filed: July 8, 2010
    Publication date: January 12, 2012
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Francis Peter Petrocelli, Kevin Boyle Fogash, Vincent White
  • Publication number: 20120009106
    Abstract: Sulfur dioxide (SO2) may be removed from carbon dioxide feed gas by contacting the carbon dioxide at an elevated temperature and an elevated pressure with a catalyst for oxidizing SO2, in the presence of oxygen (O2) to convert SO2 to sulfur trioxide (SO3); contacting SO3 in the resultant SO3-enriched carbon dioxide gas with water to produce sulfuric acid and SO2-depleted carbon dioxide gas; and separating the sulfuric acid from the SO2-depleted carbon dioxide gas. If present, NOx is also removed from the carbon dioxide feed gas as nitric acid to produce SO2-depleted, NOx-lean carbon dioxide gas. The method has particular application in the removal of SO2 and NOx from flue gas produced by oxyfuel combustion of a hydrocarbon fuel or carbonaceous fuel, within or downstream of the CO2 compression train of a CO2 recovery and purification system.
    Type: Application
    Filed: July 8, 2010
    Publication date: January 12, 2012
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Francis Peter Petrocelli, Kevin Boyle Fogash, Vincent White
  • Publication number: 20120009105
    Abstract: Sulfur dioxide (SO2) is removed from a carbon dioxide feed gas by maintaining the feed gas at elevated pressure(s) in the presence of oxygen (O2), water and NOx for a period of time sufficient to convert SO2 to sulfuric acid and NOx to nitric acid and produce SO2-depleted, NOx-lean carbon dioxide gas. The invention resides in separating the sulfuric and nitric acids from said SO2-depleted, NOx-lean carbon dioxide gas, and then neutralizing the acids by reaction with an alkaline sorbent in an acid/sorbent reactor system to produce sorbent-derive sulfate. The method has particular application in the removal of SO2 and NOx from flue gas produced by oxyfuel combustion of a carbonaceous fuel.
    Type: Application
    Filed: July 8, 2010
    Publication date: January 12, 2012
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Vincent White, Kevin Boyle Fogash, Francis Peter Petrocelli
  • Patent number: 8092767
    Abstract: A method of decomposing nitrogen dioxide to nitrogen monoxide in an exhaust gas of a lean-burn internal combustion engine, such as a diesel engine, comprises adjusting the C1 hydrocarbon:nitrogen oxides (C1 HC:NOx) ratio of the exhaust gas to from 0.1 to 2 and contacting this exhaust gas mixture with a particulate acidic refractory oxide selected from the group consisting of zeolites, tungsten-doped titania, silica-titania, zirconia-titania, gamma-alumina, amorphous silica-alumina and mixtures of any two or more thereof and passing the effluent gas to atmosphere.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: January 10, 2012
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Stephen David Pollington, Raj Rao Rajaram, Andrew Peter Walker
  • Patent number: 8088348
    Abstract: An air pollution control system for a coal combustion boiler includes: a NOx removing apparatus that reduces nitrogen oxide contained in flue gas emitted from this coal combustion boiler, an air pre-heater that recovers heat in the gas, a precipitator 15 that reduces particulates from the gas, a liquid-gas contact type desulfurizer that removes sulfur oxide by way of a limestone-gypsum method and reduces mercury oxide in the gas, a stack that releases the gas after SOx removal to the exterior, and a solid-liquid separator that extracts limestone-gypsum containing slurry from the desulfurizer to the exterior and performs a solid-liquid separation, where water separated in the solid-liquid separator is removed, and concentrated slurry is sent back to the bottom of the desulfurizer to make the gypsum concentration of slurry equal to or higher than 10 percent in the desulfurizer.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: January 3, 2012
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Shintaro Honjo, Susumu Okino
  • Publication number: 20110318245
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Application
    Filed: June 22, 2011
    Publication date: December 29, 2011
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Publication number: 20110318247
    Abstract: The present invention concerns a process for purifying a flow of combustion fumes from a clinker production plant comprising the following operating steps: a) removing dust at a temperature comprised between 250 and 400° C. from a flow of combustion fumes exiting from a suspension preheater with formation of a flow of combustion fumes free of dust; b) carrying out on said flow of combustion fumes free of dust a selective catalytic NOx reduction treatment with a reducing agent, with formation of a purified flow of combustion fumes. The present invention also concerns an apparatus for carrying out the aforementioned process.
    Type: Application
    Filed: December 17, 2009
    Publication date: December 29, 2011
    Applicant: Italcementi S.p.A.
    Inventors: Roberto Fedi, Antonio Clausi, Giovanni Cinti
  • Publication number: 20110311424
    Abstract: A selective catalytic reduction system and method for reducing nitrogen oxide (NOx) emissions comprising a boiler producing flue gas emissions, a particulate control device receiving flue gas emissions from the boiler, a selective catalytic reduction unit (SCR) receiving flue gas emissions from the particulate control device and reducing nitrogen oxide (NOx) emissions, and a heat exchanger located downstream of the selective catalytic reduction unit (SCR) for removing heat from the flue gas for preheating at least one of boiler feed water and combustion air for the boiler.
    Type: Application
    Filed: June 20, 2011
    Publication date: December 22, 2011
    Applicant: 2E Environmental, LLC
    Inventor: Robert Ellery
  • Publication number: 20110311423
    Abstract: Waste treatment comprises heating it in a chamber to effect pyrolysis of the waste, introducing oxygen into the chamber to effect combustion of the pyrolyzed waste, and contacting off-gas from the pyrolysis and/or combustion steps with an oxidation catalyst to convert carbon monoxide and hydrocarbons in the off-gas into carbon dioxide and water and with a reduction catalyst to convert nitrous oxides to nitrogen and oxygen. Thus, domestic waste is treated in a batch process using catalytic converters to reduce the level of toxic components before off-gas reaches the atmosphere.
    Type: Application
    Filed: December 22, 2009
    Publication date: December 22, 2011
    Inventors: Howard Morgan Clarke, Peter Bartl
  • Patent number: 8080225
    Abstract: A functional fluid for the removal of contaminates such as but not limited to, acid causing components in gas, sulfur components and carbon oxides from fluid streams, and removal and treatment of NOX & SOX from post combustion emissions. Also described is the manufacturing process to produce the functional fluid both in a batch atmospheric process system as well as a closed system capable of operating at above or below atmospheric conditions.
    Type: Grant
    Filed: November 7, 2006
    Date of Patent: December 20, 2011
    Assignee: Specialist Process Technologies Limited
    Inventors: Theodore E. Dickinson, David J. Parkinson, Kevin E. Collier
  • Publication number: 20110300046
    Abstract: A process for removing impurities, in particular oxides of sulphur (SOx) and/or oxides of nitrogen (NOx) from oxygen-containing gas streams by scrubbing with at least one washing agent is described. In order to achieve effective gas purification in an economical manner even in the case of so-called large “oxyfuel” furnaces which operate with oxygen as fuel gas, it is proposed to convert the impurities at an elevated pressure of at least 2 bar with at least one basic constituent of the washing agent into salts and to wash out said impurities as dissolved salts.
    Type: Application
    Filed: November 26, 2009
    Publication date: December 8, 2011
    Inventors: Nicole Schodel, Hans Zander, Florian Winkler, Roland Ritter, Torsten Stoffregen
  • Patent number: 8071060
    Abstract: A flue gas control system of a coal combustion boiler comprises an HCl atomizer that sprays hydrogen chloride to flue gas from a coal combustion boiler that uses coal as a fuel; NOx removing apparatus that removes nitrogen oxides by ammonia denitration by adding ammonia to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater that recovers heat in the gas after removal of nitrogen oxides; a precipitator that removes particulates in the gas; an activated carbon atomizer that sprays activated carbon into the gas after particulate collection; a bag filter that collects activated carbon having adsorbed mercury; a desulfurizer that removes sulfur oxides in the flue gas after removal of activated carbon; a stack that discharges the gas which has undergone desulfurization to outside; and an ORP meter that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: December 6, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Shintaro Honjo, Susumu Okino
  • Patent number: 8066963
    Abstract: The exhaust gas of internal combustion engines operated with a predominantly stoichiometric air/fuel mixture contains, as well as the gaseous hydrocarbon (HC), carbon monoxide (CO) and nitrogen oxide (NOx) pollutants, also ultrafine particulates. There is disclosed a catalytically active particulate filter, an exhaust gas cleaning system and a process for cleaning the exhaust gases of predominantly stoichiometrically operated internal combustion engines, as well as the gaseous CO, HC and NOx pollutants, also for removing particulates from the exhaust gas. The particulate filter comprises a filter body and a catalytically active coating consisting of two layers. Both layers contain alumina. The first layer contains palladium. The second layer contains rhodium. The latter is disposed above the first layer.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: November 29, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Raoul Klingmann, Martin Roesch, Dieter Lindner
  • Patent number: 8062618
    Abstract: A diesel exhaust aftertreatment system and method are provided. The system includes a lean NOx trap for reducing NOx and a transition metal-exchanged zeolite booster catalyst positioned downstream from the lean NOx trap for further reducing NOx. The lean NOx trap includes a NOx adsorbent material and one or more platinum group metals, and has a platinum group metal loading of less than about 90 g/ft3. The aftertreatment system provides high NOx conversion over a broad temperature range without the use of ammonia as a major reductant.
    Type: Grant
    Filed: April 17, 2009
    Date of Patent: November 22, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Lifeng Xu, Harendra S Gandhi, Robert Walter McCabe, Clifford Norman Montreuil
  • Publication number: 20110280779
    Abstract: Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.
    Type: Application
    Filed: November 27, 2009
    Publication date: November 17, 2011
    Applicant: UHDE GMBH
    Inventors: Helmut Gehrke, Dennis Lippmann
  • Publication number: 20110274605
    Abstract: A process for simultaneously desulfurizing and denitrating the flue gas with seawater includes the following steps: 1) catalytically scrubbing the flue gas containing SO2 and NOx with the seawater to obtain purified flue gas and acidic seawater, optionally adding a certain quantity of iron ions into the seawater or applying magnetic field during scrubbing; 2) adding seawater into the acidic seawater while blowing air in so as to restore the quality of the acidic seawater up to the environmental standards. Also a device used in the process is provided.
    Type: Application
    Filed: October 17, 2008
    Publication date: November 10, 2011
    Inventor: Sigan Peng
  • Patent number: 8052950
    Abstract: A method of decreasing a concentration of nitrogen oxides in a combustion gas flowing through a vessel including: generating a flue gas in a combustion zone of the vessel, the flue gas containing nitrogen oxides and carbon monoxide; providing overfire air into a burnout zone of the vessel from a first injector of overfire air to oxidize at least some of the carbon monoxide in the flue gas; injecting a selective reducing agent concurrent with overfire air at a level in the burnout zone downstream of the first injector of overfire air and downstream of the oxidization of the carbon monoxide, and reacting the selective reducing agent with the flue gas to reduce the nitrogen oxides.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: November 8, 2011
    Assignee: General Electric Company
    Inventors: Larry William Swanson, Wei Zhou, David Kelly Moyeda, Roy Payne
  • Publication number: 20110268637
    Abstract: An air pollution control system 10A includes a boiler 11 that burns fuel, an air heater 13 that recovers heat of flue gas 17 from the boiler 11, and a desulfurizer 15 that reduces sulfur oxides contained in the flue gas 17 after heat recovery by an absorbent, and waste-water supplying units P0 to P5 that supply desulfurized waste water 28 discharged from the desulfurizer 15 to at least one of a path for supplying fuel to the boiler 11, inside of a furnace of the boiler 11, and the inside of a flue gas duct between the boiler 11 and the air heater 13 are installed. With this configuration, an amount of desulfurized waste water to be returned into the flue gas duct per unit time can be increased as compared to conventional systems, without increasing the size of the entire air pollution control system.
    Type: Application
    Filed: February 25, 2010
    Publication date: November 3, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa