Utilizing Solid Sorbent, Catalyst, Or Reactant Patents (Class 423/239.1)
  • Patent number: 7891324
    Abstract: A heater and a method for heating a circulating liquid in a gas-to-liquid heat exchanger and an indirect heat exchanger to produce a hot liquid stream for use for heat exchange in a selected process to supply heat to the process. One particularly useful application of the present invention is the revaporization of liquefied natural gas (LNG).
    Type: Grant
    Filed: June 6, 2007
    Date of Patent: February 22, 2011
    Inventors: David A. Franklin, Martin J. Rosetta
  • Patent number: 7887768
    Abstract: An air pollution control apparatus according to the present invention reduces nitrogen oxides and oxidizes mercury in flue gas 16 discharged from a boiler by an ammonia denitrating catalyst. The air pollution control apparatus includes an economizer bypassing unit 15a that diverts high-temperature combustion gas 11 to a downstream side while bypassing an economizer 15 provided in a gas flue 10a for combustion gas 11 from the boiler, provided with an ammonium-chloride supply unit 101 that supplies powdery ammonium chloride (NH4Cl) to the economizer bypassing unit 15a. The air pollution control apparatus sublimates the ammonium chloride in an atmosphere at a high temperature of the combustion gas 11, and supplies hydrogen chloride and ammonium into the flue gas flue 102.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: February 15, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shintaro Honjo, Katsumi Nochi, Yoshiaki Obayashi, Masashi Kiyosawa
  • Publication number: 20110033360
    Abstract: Provided is a method of operating a hydrolytic separator in which ammonia gas to be used as a reducing agent in a flue gas denitrization apparatus is generated by the hydrolysis of an aqueous urea solution. When the hydrolytic separator is started and ammonia gas injection is initiated, the hydrolytic separator is operated in a constant-pressure mode in which the internal pressure of the hydrolytic separator is kept constant regardless of the increasing temperature of the hydrolytic separator. Thereafter, the constant-pressure operation is switched to a variable pressure operation in which the pressure is raised as the temperature of the hydrolytic separator rises. In the method, the constant-pressure operation is switched to the variable pressure operation after the temperature of the hydrolytic separator in the constant-pressure operation has reached or exceeded the variable pressure operation temperature corresponding to that pressure.
    Type: Application
    Filed: May 27, 2009
    Publication date: February 10, 2011
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Satoru Shishido, Tooru Ogasahara, Yoshiyuki Takeuchi, Yoshinori Nagai
  • Patent number: 7883678
    Abstract: There is disclosed a hydrothermally stable microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure, such as SAPO-34 or aluminosilicate zeolite, able to retain a specific percentage of its surface area and micropore volume after treatment with heat and moisture, such as at least 80% of its surface area and micropore volume after exposure to temperatures of up to 900° C. in the presence of up to 10 volume percent water vapor for a time ranging from 1 to 16 hours. Methods of using the disclosed crystalline material, such as in the SCR of NOx in exhaust gas are also disclosed, as are methods of making such materials.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: February 8, 2011
    Assignee: PQ Corporation
    Inventors: Hong-Xin Li, William E. Cormier, Bjorn Moden
  • Patent number: 7879758
    Abstract: A catalytically active porous element for promoting catalytic gas phase reactions is proposed, said element comprising a porous structural element of sintered ceramic or metallic primary particles, which are selected from fibrous and/or granular particles, a secondary structure of titania nano particles deposited on the surface of said sintered primary particles and a catalytic component deposited on the surface of the titania nano particles. Thereby porous catalytic elements for catalytic gas phase reactions which are useful not only in NOX reduction reactions but also for other catalytic gas phase reactions are provided.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: February 1, 2011
    Assignee: Pall Corporation
    Inventors: Steffen Heidenreich, Manfred Nacken
  • Patent number: 7879759
    Abstract: DeNOx catalysts for the reduction of NOx compounds and porous catalyst support materials are provided. The inventive catalysts comprise an active metal catalyst component and mixed TiO2/ZrO2 porous support particles that comprise a) a crystalline phase comprising titanium dioxide and/or a titanium/zirconium mixed oxide, b) an amorphous phase comprising zirconium, and c) a small amount of one or more metal oxide(s) or metalloid oxide(s) deposited on the amorphous outer layer. The inventive catalysts exhibit superior activity and ammonia selectivity.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: February 1, 2011
    Inventors: Steve M. Augustine, Guoyi Fu, Mark Watson
  • Publication number: 20110008230
    Abstract: The invention provides a system for regenerative selective catalytic reduction including a catalyst chamber that contains a catalyst for reducing NOx in a gas stream passing therethrough. The system also includes a reactant injector, first and second heat exchangers, and a valve manifold adapted to direct a substantially continuous gas stream through the heat exchangers and catalyst chamber in such a manner as to flow through the catalyst chamber in the same flow direction during each cycle of the system. The invention also provides a process of regenerative selective catalytic reduction wherein the gas stream through the catalyst chamber flows in the same flow direction during each cycle of the process.
    Type: Application
    Filed: July 19, 2010
    Publication date: January 13, 2011
    Applicant: Babcock Power Inc.
    Inventors: John R. Harold, James D. Dougherty
  • Publication number: 20110002828
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes a chemical supplying unit that mixes an NH4Cl solution, an NH3 solution, and an HCl solution in liquid states, and supplies a mixed solution into a flue provided downstream of the boiler, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with limestone-gypsum slurry.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110002827
    Abstract: A mercury reduction system includes an NH4Cl supplying unit that sprays an NH4Cl solution into a flue of the boiler, a reduction denitration apparatus that includes a denitration catalyst for reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus for reducing Hg oxidized in the reduction denitration apparatus with limestone-gypsum slurry. The NH4Cl supplying unit includes an NH4Cl solution feed pipe that supplies the NH4Cl solution into the flue in a liquid state, a blow pipe that is inserted into the flue so as to surround the NH4Cl solution feed pipe and through which air is injected into the flue, and a two-fluid nozzle that is fitted to an end of the NH4Cl solution feed pipe and through which the NH4Cl solution is injected. Through the two-fluid nozzle, the NH4Cl solution is injected and sprayed in fine liquid droplets.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110002829
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes an NH4Cl solution spraying unit that sprays an NH4Cl solution into a flue of the boiler in a liquid state, a mixed gas spraying unit that is provided downstream of the NH4Cl solution spraying unit and sprays mixed gas containing NH3 gas and HCl gas into the flue, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with a limestone-gypsum slurry.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110002830
    Abstract: A preferred apparatus arrangement utilizes the enthalpy of the flue gas, which can be supplemented if need be, to convert urea (30) into ammonia for SCR. Urea (30), which decomposes at temperatures above 140 .degree. C., is injected (32) into a flue gas stream split off (28) after a heat exchanger (22), such as a primary superheater or an economizer. Ideally, the side stream would gasify the urea without need for further heating; but, when heat is required it is far less than would be needed to heat either the entire effluent (23) or the urea (30). This side stream, typically less than 3% of the flue gas, provides the required temperature and residence time for complete decomposition of urea (30). A cyclonic separator can be used to remove particulates and completely mix the reagent and flue gas. This stream can then be directed to an injection grid (37) ahead of SCR using a blower (36).
    Type: Application
    Filed: July 2, 2010
    Publication date: January 6, 2011
    Applicant: FUEL TECH, INC.
    Inventors: William H. Sun, William E. Cummings, Piers de Havilland, Paul G. Carmignani, John M. Boyle
  • Patent number: 7862787
    Abstract: A boiler conveys an exhaust gas stream to a heat recovery device. The heat recovery device includes an air straightener, a heat recovery unit or feedwater heater, and a catalyst assembly positioned between the air straightener and the feedwater heater. The catalyst assembly has a catalyst drawer or bed that holds a quantity of catalyst materials for removing contaminants from the exhaust gas stream. The air straightener has a plurality of baffles that are arranged in a manner that optimizes the performance of the catalyst drawer or bed. The baffles also prevent condensation from leaking from the feedwater heater into the boiler. The feedwater heater recovers a quantity of heat from the exhaust gas stream.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: January 4, 2011
    Assignee: Cannon Boiler Works, Inc.
    Inventors: Arthur P. Skelley, Alan L. Stehman, Steven G. Rendos
  • Publication number: 20100329955
    Abstract: A method for controlling multipollutant (e.g., SO2, NOx, Hg0 and Hg2+) emissions from a gas stream of a stationary combustion source, an apparatus for controlling multipollutant emissions, and a wet scrubber additive composition for controlling multipollutant emissions are disclosed.
    Type: Application
    Filed: June 25, 2009
    Publication date: December 30, 2010
    Applicant: Enviromental Protection Agency, Government of the United States of America, as represented by the
    Inventors: Nick D. HUTSON, Ravi K. SRIVASTAVA
  • Patent number: 7858062
    Abstract: Embodiments of the present invention relate to a method for synthesizing nanocrystalline zeolites, the method comprising contacting starting products that comprise a solvent, a silicon source, a cation base, an organic template, and an aluminum source, or any combination thereof sufficient to produce a zeolite gel by hydrolysis, heating the zeolite gel sufficient to produce a first batch of zeolite crystals and a first clear solution, separating the first batch of zeolite crystals from the first clear solution, heating the first clear solution sufficient to produce a second batch of zeolite crystals and second clear solution and separating the second batch of zeolite crystals from the second clear solution.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: December 28, 2010
    Assignee: University of Iowa Research Foundation
    Inventors: Sarah Larsen, Vicki Grassian, Weiguo Song, Gonghu Li
  • Publication number: 20100322834
    Abstract: An apparatus for treating gas containing nitrous oxide, according to the present invention, includes dampers (113-116, 118-120, and 123-125) for introducing gas to be treated and for exhausting treated gas; a plurality of heat accumulating layers (102) charged with ceramic heat storage media; a plurality of catalyst layers (103) arranged in accordance with the respective heat accumulating layers, heat-decomposing nitrous oxide contained in the introduced gas to be treated into nitrogen; and a heating device (107) for increasing a temperature of the introduced gas to be treated to a heat-decomposable temperature in the catalyst layers.
    Type: Application
    Filed: April 13, 2006
    Publication date: December 23, 2010
    Inventors: Takehiko Ito, Fumio Kondo
  • Publication number: 20100322835
    Abstract: A boiler conveys an exhaust gas stream to a heat recovery device. The heat recovery device includes an air straightener, a heat recovery unit or feedwater heater, and a catalyst assembly postioned between the air straightener and the feedwater heater. The catalyst assembly has a catalyst drawer or bed that holds a quantity of catalyst materials for removing contaminants from the exhaust gas stream. The air straightener has a plurality of baffles that are arranged in a manner that optimizes the performance of the catalyst drawer or bed. The baffles also prevent condensation from leaking from the feedwater heater into the boiler. The feedwater heater recovers a quantity of heat from the exhaust gas stream.
    Type: Application
    Filed: June 22, 2009
    Publication date: December 23, 2010
    Inventors: Arthur P. Skelley, Steven G. Rendos, Alan L. Stehman
  • Patent number: 7850935
    Abstract: Process for reducing nitrogen oxides to nitrogen in an exhaust gas comprising passing the exhaust gas in the presence of an oxygen-containing organic reducing agent through a catalyst system comprising at least two catalyst beds, in which a first catalyst bed comprises only alumina and a second catalyst bed downstream comprises only indium supported on alumina.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: December 14, 2010
    Assignee: Haldor Topsøe A/S
    Inventors: Alexandr Yu. Stakheev, Pär Gabrielsson
  • Publication number: 20100310440
    Abstract: The present invention relates to a process for the preparation of pure silicoaluminophosphate (SAPO-34) and which contains Cu wherein said molecular sieve material is obtained in a single process stage. This process stage is a hydrothermal crystallization stage to which an aqueous solution is subjected which, apart from source of silica, alumina and phosphorous usually employed framework elements of the zeolite framework, already contains all the Cu necessary for the preparation of the final Cu containing silicoaluminophosphate (SAPO34). In addition, the present invention relates to a pure copper containing molecular sieve material as such, having framework structure SAPO-34, having a molar composition according to formula: Cu0.007-0.125Si0.01-0.25Al0.44-0.54P0.25-0.49O2, having an amount of impurity phase of less than 25% and having a BET surface area of at least 400 m2/g.
    Type: Application
    Filed: June 4, 2010
    Publication date: December 9, 2010
    Applicant: BASF SE
    Inventors: Ivor BULL, Ulrich MULLER
  • Patent number: 7846405
    Abstract: A method for monitoring and/or controlling performance of a selective catalytic reduction (SCR) emission control system includes injecting a quantity of a pollution neutralizing gas into a combustion gas stream containing a pollutant gas. The method also includes passing the stream over a catalyst bed to facilitate a reaction of the pollution neutralizing gas with the pollutant gas to produce an effluent and measuring a ratio of the pollution neutralizing gas to the pollutant gas in the effluent.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: December 7, 2010
    Assignee: General Electric Company
    Inventors: William Steven Lanier, Frederic Francis Ahlgren, Theodore Paul Kircher
  • Publication number: 20100303698
    Abstract: A process is provided for increasing mixing in a regenerator. Streamlines of gas and some catalyst may form in a regenerator as a result of cyclone inlet horns positioned in the same direction. Overall mixing in the regenerator may decrease because of these streamlines. A dampening device may be used to interrupt the streamlines and increase mixing in the regenerator. The dampening device may be a baffle and direct streamlines from the outside of the chamber toward the center to collide and mix. In another embodiment, a dampening device may be a secondary disengager such as a T-disengager or an inverted can arrangement that may discharge gas and catalyst near the center of the upper chamber and interrupt the streamlines. In another embodiment, a dampening device may have swirl arms that redirect stream lines counter to the direction of flow.
    Type: Application
    Filed: June 14, 2010
    Publication date: December 2, 2010
    Applicant: UOP LLC
    Inventors: Robert L. Mehlberg, Mohammad-Reza Mostofi-Ashtiani, Keith A. Couch
  • Publication number: 20100300061
    Abstract: A process for the catalytic reduction of nitrogen oxides (NOx) in a gas stream (29) in the presence of H2 is provided. The process comprises contacting the gas stream with a catalyst system (38) comprising zirconia-silica washcoat particles (41), a pre-sulfated zirconia binder (44), and a catalyst combination (40) comprising palladium and at least one of rhodium, ruthenium, or a mixture of ruthenium and rhodium.
    Type: Application
    Filed: May 4, 2010
    Publication date: December 2, 2010
    Inventors: Anatoly Sobolevskiy, Joseph A. Rossin, Michael J. Knapke
  • Publication number: 20100303699
    Abstract: The invention provides a N2O removal method for a waste gas which is capable of stably decomposing and removing N2O even if the steam concentration in the waste gas is fluctuated. N2O is reduced and removed by bringing the waste gas containing N2O into contact with a reducing agent in the presence of a N2O decomposition catalyst 9. The temperature of the waste gas to be brought into contact with the N2O decomposition catalyst 9 or the addition amount of the reducing agent is controlled in accordance with the steam concentration in the waste gas in a prior stage of the N2O decomposition catalyst 9. Therefore, the N2O decomposition efficiency is prevented from being decreased. An iron-zeolite based catalyst may be used as the N2O decomposition catalyst and methane, propane, ammonia, etc. may be used as the reducing agent.
    Type: Application
    Filed: July 14, 2010
    Publication date: December 2, 2010
    Applicant: Metawater Co., Ltd.
    Inventor: Toichiro SASAKI
  • Publication number: 20100303697
    Abstract: A process and system (18) for reducing NOx in a gas using hydrogen as a reducing agent is provided. The process comprises contacting the gas stream (29) with a catalyst system (38) comprising sulfated zirconia washcoat particles (41), palladium, a pre-sulfated zirconia binder (44), and a promoter (45) comprising at least one of titanium, zinc, or a mixture thereof. The presence of zinc or titanium increases the resistance of the catalyst system to a sulfur and water-containing gas stream.
    Type: Application
    Filed: May 4, 2010
    Publication date: December 2, 2010
    Inventors: Anatoly Sobolevskiy, Joseph A. Rossin, Michael J. Knapke
  • Patent number: 7842266
    Abstract: A method of exhaust gas denitration in which nitrogen oxides contained in a low-temperature exhaust gas are removed at a high NOx removal efficiency. A injection pipe (11) is disposed in a flue (10) for an exhaust gas (x) so that the pipe protrudes from the inner wall of the flue. A hydrocarbon compound (b) and a nitrogen compound (a) are supplied through the injection pipe (11) into the flue (10). The hydrocarbon compound (b) is burned to form a combustion region (s). In this combustion region (s), amine radicals are produced from the nitrogen compound (a). These amine radicals are mixed with nitrogen oxides contained in the exhaust gas (x) to reductively remove the nitrogen oxides.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: November 30, 2010
    Assignee: Mitsui Engineering & Shipbuilding Co., Ltd.
    Inventors: Youichi Takahashi, Yutaka Tsukui, Nobuyasu Kanda, Kimihiko Sugiura, Shoichi Ibaragi, Toshiharu Inaba
  • Publication number: 20100296992
    Abstract: Honeycomb catalyst structures and methods of using them, where the structures have honeycomb channel walls of selective catalytic reduction catalyst, the channel walls occupy at least 20% of the volume of the structure, the structure exhibits a pressure drop for flowing air not exceeding about 110 Pa at a space velocity of 20,000 hr?1, and the channel walls are of a thickness insuring high degree of catalyst utilization and NOx conversion efficiency.
    Type: Application
    Filed: May 22, 2009
    Publication date: November 25, 2010
    Inventors: Yi Jiang, Ameya Joshi, Steven Bolaji Ogunwumi, Jianhua Weng
  • Publication number: 20100296991
    Abstract: In a method for the purifying of the waste gases of a sintering process of ores in the production of metals, in which ore material is sintered with a solid fuel, with the combustion of the solids and passage through a smoldering process, at least the pollutants SOx and/or HCl and NOx are reduced or extensively eliminated. To this end, the sintering waste gas is guided into a moving bed reactor (50) from below through a lower and upper layer (54B; 54A) of an adsorption and/or absorption agent already polluted with NOx and SOx and/or HCl, wherein at least the main quantity of SOx and/or HCl components is adsorbed from the sintering waste gas into the pore system of the NOx-loaded adsorption and/or absorption agent.
    Type: Application
    Filed: December 14, 2007
    Publication date: November 25, 2010
    Inventor: Horst Grochowski
  • Publication number: 20100290966
    Abstract: A method for the removal of a fluorinated gas from a gas stream (1) comprising the steps of: conveying the gas stream (1) containing the fluorinated gas to a combustion region (2), decomposing the fluorinated gas in the combustion region (2), entraining a calcium salt (4) capable of reacting with the fluorinated gas decomposition products into the gas stream to react with the fluorinated gas decomposition products to form calcium fluoride and then removing (10) the calcium fluoride salt from the gas stream.
    Type: Application
    Filed: May 23, 2007
    Publication date: November 18, 2010
    Inventor: Andrew James Seeley
  • Patent number: 7833501
    Abstract: A method and apparatus for treating an exhaust gas comprising heavy metals, wherein the apparatus comprises a heat recovery unit, recovering exhaust gas heat at an exit of the air preheater; a precipitator, collecting soot/dust contained in an exhaust gas at an exit of the heat recovery unit; a wet flue gas desulfurizer, removing sulfur oxides contained in the exhaust gas at the exit of the precipitator; and a reheater, heating the exhaust gas at the exit of the wet flue gas desulfurizer. Each of the heat recovery unit and the reheater has a heat exchanger tube, and a circulation line is disposed to connect the heat exchanger tubes. A sulfur trioxide (SO3) removing agent is supplied to the upstream side of the heat recovery unit, and the temperature of the exhaust gas at the exit of the heat recovery unit is adjusted to not more than a dew point of sulfur trioxide.
    Type: Grant
    Filed: December 24, 2007
    Date of Patent: November 16, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Goki Sasaki, Hiroyuki Nosaka
  • Publication number: 20100284877
    Abstract: The present invention provides monolithic structural catalysts. The catalysts have a thin wall structure and are advantageous for catalyzing reactions of gaseous fluid or liquid fluid molecules, such as the denitration or selective catalytic reduction (SCR) of nitrogen oxides (NOx) in combustion flue gases. In an embodiment, the honeycomb-like monolithic structural body includes catalytically active outer peripheral walls and a plurality of catalytically active thin-walled inner partition walls, the thin-walled inner partition walls adapted to enhance fluid flow through the monolithic catalytic body and to increase interaction of the fluid molecules with the catalyst body.
    Type: Application
    Filed: July 20, 2010
    Publication date: November 11, 2010
    Inventors: Chris E. DiFrancesco, James C. Altizer, Thomas W. Hastings, Edward F. Kassman, Christian Trefzger
  • Publication number: 20100284876
    Abstract: Low temperature activity and high temperature ammonia selectivity of a vanadium-free selective catalytic reduction catalyst are controlled with a mixed oxide support containing oxides of titanium and zirconium, and a plurality of alternating layers respectively formed of a metal compound and titanium oxide present on the surface of the mixed oxide support. The metal compound is selected from the group consisting of manganese oxide, iron oxide, cerium oxide, tin oxide, and mixtures thereof.
    Type: Application
    Filed: May 11, 2009
    Publication date: November 11, 2010
    Inventor: Steven M. Augustine
  • Patent number: 7829033
    Abstract: A preferred apparatus arrangement utilizes the enthalpy of the flue gas, which can be supplemented if need be, to convert urea (30) into ammonia for SCR. Urea (30), which decomposes at temperatures above 140 .degree. C., is injected (32) into a flue gas stream split off (28) after a heat exchanger (22), such as a primary superheater or an economizer. Ideally, the side stream would gasify the urea without need for further heating; but, when heat is required it is far less than would be needed to heat either the entire effluent (23) or the urea (30). This side stream, typically less than 3% of the flue gas, provides the required temperature and residence time for complete decomposition of urea (30). A cyclonic separator can be used to remove particulates and completely mix the reagent and flue gas. This stream can then be directed to an injection grid (37) ahead of SCR using a blower (36).
    Type: Grant
    Filed: February 8, 2006
    Date of Patent: November 9, 2010
    Assignee: Fuel Tech, Inc.
    Inventors: William H. Sun, William E. Cummings, Jr., Piers de Havilland, Paul G. Carmignani, John M. Boyle
  • Patent number: 7824636
    Abstract: A method and system for reducing the amount of nitrogen oxides (NOx) in a combustion gas waste stream by (1) analyzing the waste stream to determine the amount of NOx; (2) determining the stoichiometric amount of ammonia required to reduce the NOx concentration down to a required level or less; (3) determining the flow rate profile of NOx components across the combustion gas waste stream upstream of an ammonia injection grid; (4) selecting specific locations within the ammonia injection grid to activate ammonia valves; (5) injecting controlled amounts of ammonia vapor into the gas stream at grid locations corresponding to the location of NOx in the gas stream; and (6) treating the gas stream using a selective catalytic reduction unit to reduce the amount of NOx down to acceptable levels.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: November 2, 2010
    Assignee: General Electric Company
    Inventors: Gilbert Otto Kraemer, Garth Curtis Frederick
  • Patent number: 7824635
    Abstract: A particulate material removing filter for exhaust gas from a diesel engine is provided. The particulate material removing filter is formed by laminating metal laths having an oxidation catalyst layer containing a noble metal that oxidizes nitrogen oxide in exhaust gas into nitrogen dioxide. The metal laths are laminated to form a laminate in such a manner that the drawing direction of the metal lath processing differs by 90 degrees with each other.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: November 2, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Eiji Miyamoto, Masatoshi Fujisawa, Naomi Imada, Hiroshi Ishizaka, Kazuki Kobayashi, Takeshi Hirota
  • Patent number: 7820123
    Abstract: As a device for the purification of exhaust gas, a three-way catalyst A purifying hydrocarbon, carbon monoxide and nitrogen oxide in the vicinity of theoretical air-fuel ratio is disposed at an upstream side of the exhaust gas and an adsorption catalyst B provided with zeolite effective for the adsorption of hydrocarbon is disposed at a downstream side of the exhaust gas.
    Type: Grant
    Filed: July 15, 2008
    Date of Patent: October 26, 2010
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Takuya Ikeda, Maki Kamikubo
  • Publication number: 20100266471
    Abstract: A diesel exhaust aftertreatment system and method are provided. The system includes a lean NOx trap for reducing NOx and a transition metal-exchanged zeolite booster catalyst positioned downstream from the lean NOx trap for further reducing NOx. The lean NOx trap includes a NOx adsorbent material and one or more platinum group metals, and has a platinum group metal loading of less than about 90 g/ft3. The aftertreatment system provides high NOx conversion over a broad temperature range without the use of ammonia as a major reductant.
    Type: Application
    Filed: April 17, 2009
    Publication date: October 21, 2010
    Applicant: FORD GLOBAL TECHNOLOGIES, LLC
    Inventors: Lifeng Xu, Harendra S. Gandhi, Robert Walter McCabe, Clifford Norman Montreuil
  • Publication number: 20100266470
    Abstract: Described herein is a photocatalytic composite comprising a titanium dioxide supported on metakaolin. In comparison to known embodiments of the sector, the composite of the present invention makes it possible to obtain binders and derived products with high photocatalytic efficiency, even when using photocatalyst quantities which are lesser than those present in products of prior technical art.
    Type: Application
    Filed: December 17, 2008
    Publication date: October 21, 2010
    Inventors: Renato Ancora, Massimo Borsa, Luigi Cassar
  • Patent number: 7814747
    Abstract: An exhaust gas aftertreatment installment and associated exhaust gas aftertreatment method utilizes a nitrogen oxide storage catalytic converter and an SCR catalytic converter. A particulate filter is provided upstream of the nitrogen oxide storage catalytic converter or between the latter and the SCR catalytic converter or downstream of the SCR catalytic converter. The time of regeneration operating phases of the nitrogen oxide storage catalytic converter can be determined as a function of the nitrogen oxide content of the exhaust gas downstream of the nitrogen oxide storage catalytic converter or of the SCR catalytic converter and/or as a function of the ammonia loading of the latter. Moreover, a desired ammonia generation quantity can be determined for a respective regeneration operating phase. The installation and method are adopted for use for motor vehicle internal combustion engines and other engines which are operated predominantly in lean-burn mode.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: October 19, 2010
    Assignee: Daimler AG
    Inventors: Brigitte Bandl-Konrad, Andreas Hertzberg, Bernd Krutzsch, Arno Nolte, Markus Paule, Stefan Renfftlen, Norbert Waldbuesser, Michel Weibel, Guenter Wenninger, Rolf Wunsch
  • Patent number: 7815881
    Abstract: Disclosed are a process and apparatus for selective catalytic reduction of NOx. The process is enabled by bypassing a heat exchanger section, such as an economizer, of the boiler in advance of an SCR unit at low load conditions to enable NOx reduction even at low loads using urea instead of ammonia. In a preferred form, under high load conditions, the bypass can be almost fully closed and the economizer can be operated normally without excessively cooling the combustion gases, using only a portion of bypassed gases which are hot enough to decompose the urea into its active components including ammonia.
    Type: Grant
    Filed: November 10, 2009
    Date of Patent: October 19, 2010
    Assignee: Fuel Tech, Inc.
    Inventors: M. Linda Lin, William H. Sun, John M. Boyle, Penelope Stamatakis
  • Patent number: 7811536
    Abstract: Nitrogen oxides (NOx) storage catalysts comprising cobalt and barium with a lean NOx storage ratio of 1.3 or greater. The NOx storage catalysts can be used to reduce NOx emissions from diesel or gas combustion engines by contacting the catalysts with the exhaust gas from the engines. The NOx storage catalysts can be one of the active components of a catalytic converter, which is used to treat exhaust gas from such engines.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: October 12, 2010
    Assignee: University of Delaware
    Inventors: Jochen Lauterbach, Christopher M. Snively, Rohit Vijay, Reed Hendershot, Ben Feist
  • Publication number: 20100242438
    Abstract: The present invention is directed towards methods and systems for treatment of exhaust gas from an engine. In one embodiment, an exhaust gas treatment system for a diesel engine is provided. The system includes a urea selective catalytic reduction (U-SCR) catalyst in fluid communication with a diesel engine to receive an exhaust gas flow therefrom. The system also includes a four-way catalyst in fluid communication with the U-SCR catalyst to receive the exhaust gas flow therefrom, the four-way catalyst comprising a lean nitrogen oxide (NOX) trap (LNT) and diesel particulate filter (DPF).
    Type: Application
    Filed: March 26, 2009
    Publication date: September 30, 2010
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventor: Rahul Mital
  • Publication number: 20100247409
    Abstract: A method of converting nitrogen oxides in a gas stream to nitrogen comprises contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a non-zeolite base metal catalyst consisting of: (a) at least one transition metal dispersed on a mixed oxide or composite oxide or a mixture thereof as support material consisting of cerium and zirconium; or (b) cerium oxide and zirconium oxide as single oxides or a composite oxide thereof or a mixture of the single oxides and the composite oxide dispersed on an inert oxide support material, whereon is dispersed at least one transition metal.
    Type: Application
    Filed: June 25, 2008
    Publication date: September 30, 2010
    Applicant: JOHNSON MATTHY PUBLIC LIMITED COMPANY
    Inventors: Jillian Elaine Collier, Sylvie Cecile Laroze, Raj Rao Rajaram, David William Prest
  • Publication number: 20100247411
    Abstract: Compositions useful for treating exhaust gases contain zirconium, titanium and tungsten oxides, and optionally the oxide of an element M selected from among silicon, aluminum, iron, molybdenum, manganese, zinc, tin, and rare earths in the following mass proportions of these different elements: titanium oxide: 20%-50%; tungsten oxide: 1%-20%, M-element oxide: 1%-20%; the balance being zirconium oxide; such compositions are prepared by placing in a liquid medium a zirconium compound, a titanium compound, optionally an M-element compound and a basic compound, adding a tungsten compound to the precipitate suspension thus obtained and having a pH value ranging from 1 to 7, maturing the suspension resulting from the preceding step, and optionally separating the precipitate and calcining same.
    Type: Application
    Filed: October 19, 2007
    Publication date: September 30, 2010
    Applicants: RHODIA OPERATIONS, MAGNESIUM ELEKTRON LIMITED
    Inventors: Olivier Larcher, Emmanuel Rohart, Stephan Verdier, Heather Bradshaw, Clive Butler, Deborah Harris, Mairead Feeley, Hazel Stephenson
  • Patent number: 7803338
    Abstract: A method and apparatus for catalytically processing a gas stream passing therethrough to reduce the presence of NOx therein, wherein the apparatus includes a first catalyst composed of a silver containing alumina that is adapted for catalytically processing the gas stream at a first temperature range, and a second catalyst composed of a copper containing zeolite located downstream from the first catalyst, wherein the second catalyst is adapted for catalytically processing the gas stream at a lower second temperature range relative to the first temperature range.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: September 28, 2010
    Assignees: ExonMobil Research and Engineering Company, Caterpillar Inc.
    Inventors: Richard F. Socha, James C. Vartuli, El-Mekki El-Malki, Mohan Kalyanaraman, Paul W. Park
  • Publication number: 20100239480
    Abstract: The present invention is a method of treating nitrogen oxides using an ozone and catalyst hybrid system, as well as an apparatus, specifically relating to a method of treating nitrogen oxide using an ozone and catalyst hybrid system comprising: 1) removing moisture from the nitrogen oxide polluted air to be treated; 2) contacting the moisture-removed nitrogen oxide polluted air with ozone to oxidize NO in said polluted air to NO2; 3) reacting the residual ozone with a catalyst to generate oxygen radicals and then, reacting the oxygen radicals with the nitrogen oxide polluted air from step 2) to oxidize NO2 in the polluted air to NO3?. The nitrogen oxide treatment method and apparatus according to the present invention can effectively treat harmful nitrogen oxides, such as NO, NO2, using an ozone and catalyst hybrid system at room temperature without requiring a high temperature reaction or an ammonia gas as a reducing agent.
    Type: Application
    Filed: December 16, 2009
    Publication date: September 23, 2010
    Inventors: Jong Soo Jurng, Ju Young Jeong, Sung Min Chin
  • Patent number: 7799297
    Abstract: This combustion exhaust gas processing device comprises a dust collector collecting dust in combustion exhaust gas, a wet dust collector collecting water soluble components and dust in the combustion exhaust gas passed through the dust collector, and a catalyst tower decomposing and removing NOx and/or dioxins in the combustion exhaust gas passed through the wet dust collector. The device also comprises a reheater heating the combustion exhaust gas discharged from the wet dust collector at the front stage of the catalyst tower, an oxidizer adding device adding an oxidizer to the combustion exhaust gas passed through the dust collector, a solid/liquid separator separating slurry discharged from the wet dust collector into solid and liquid phases, a mercury adsorbing tower adsorbing mercury in liquid separated in the solid/liquid separator, and a heat recovering device heating the combustion exhaust gas discharged from the catalyst tower at the rear stage thereof.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: September 21, 2010
    Inventor: Shinichiro Saito
  • Patent number: 7799298
    Abstract: The invention relates to a catalyst arrangement for purifying the exhaust gases of internal combustion engines operated under lean conditions. It is proposed that a thinwalled, porous carrier be coated on one side with a nitrogen oxide storage catalyst and on the other side with an SCR catalyst. When the exhaust gas is passed through the catalytic coatings and the support material, a significant improvement in the nitrogen oxide conversion is achieved compared to a series arrangement of the catalysts on separate carriers. Wall flow filters have been found to be useful as thin-walled carriers.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: September 21, 2010
    Assignee: Umicore AG & Co. KG
    Inventors: Marcus Pfeifer, Nicola Soeger, Yvonne Demel, Tobias Kuhl, Paul Christian Spurk, Jürgen Gieshoff, Egbert Lox, Thomas Kreuzer
  • Publication number: 20100233053
    Abstract: A method is provided. The method comprises reacting a reactive solution and a templating agent to form a gel; and calcining the gel to form a catalyst composition comprising homogeneous solid mixture. The homogenous solid mixture contains (i) at least one catalytic metal and (ii) at least one metal inorganic network. The templating agent comprises an octylphenol ethoxylate having a structure [I]: wherein “n” is an integer having a value of about 8 to 20. A catalyst composition prepared using the templating agent having a structure [1] is also provided.
    Type: Application
    Filed: May 28, 2010
    Publication date: September 16, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Ashish Balkrishna Mhadeshwar, Ming Yin
  • Patent number: 7794680
    Abstract: A first catalyst for reducing nitrogen oxides comprising a crystalline silicate containing an iron in ?-framework structure wherein a SiO2/Fe2O3 mol ratio is 20-300 and at least 80% of the contained iron is an isolated iron ion Fe3+. A second catalyst for reducing nitrogen oxides comprising a crystalline silicate containing an iron in ?-framework structure wherein a SiO2/Fe2O3 mol ratio is 20-300 and log(SiO2/Al2O3) by mol is at least 2. A predominant part of the contained iron is isolated iron ion Fe3+ and at least a part thereof preferably has a tetrahedral coordination. These catalysts have high hydrothermal stability and exhibit enhanced activity for reducing nitrogen oxides by a reaction with a reducing agent such as ammonia, urea or an organic amine in a broad temperature range between lower temperature and higher temperature.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: September 14, 2010
    Assignee: Tosoh Corporation
    Inventors: Yusuke Naraki, Kou Ariga, Hidekazu Aoyama
  • Patent number: 7790127
    Abstract: A method of reducing NOx in a lean burn engine exhaust stream from a hydrocarbon burning engine may be first passing the exhaust stream over a thrifted diesel oxidation catalyst that substantially completes the oxidation of carbon monoxide to carbon dioxide and the oxidation of hydrocarbons (HC) to carbon dioxide and water. Next, separate additions of ozone and ammonia or urea may be introduced to the exhaust gas stream upstream of the catalytic reduction reactor at temperatures below 250 degrees Celsius. The additions of ozone and ammonia or urea modify the exhaust gas composition to improve the performance of NOx reduction catalysts in the catalytic reduction reactor. At temperatures above 250 degrees, the ozone addition may be reduced or eliminated, while the ammonia addition can be controlled as a function of the amount of NOx in the exhaust stream and the temperature of the catalytic reduction reactor.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: September 7, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Jong H. Lee, Byong Kwon Cho
  • Patent number: 7790126
    Abstract: The invention is directed to a method for cleaning exhaust gases of a glass melting process. The raw material for production of the glass is charged to the glass furnace and molten glass is removed from the glass furnace. The exhaust gases of the glass melting process are freed of the pollutant components in a moving bed reactor system on a catalytically active adsorbent and/or absorbent. Catalyst damaging pollutant components are bound by absorption and the particulate components are adhesively removed. Catalytic removal of nitrogen is performed in the layer area adjacent to the immediate oncoming flow area of the catalyst damaging pollutant components. Other pollutant components that do not damage the catalyst, such as dioxins and furans, are removed by absorption in the layer area.
    Type: Grant
    Filed: January 12, 2006
    Date of Patent: September 7, 2010
    Inventor: Horst Grochowski