Plural Metal Or Metal And Ammonium Containing Patents (Class 423/306)
  • Publication number: 20020039681
    Abstract: An active material of formula LiCu1+xPO4(0≦x≦1) which could be used as cathode material in lithium primary and secondary batteries.
    Type: Application
    Filed: September 20, 2001
    Publication date: April 4, 2002
    Applicant: JAPAN STORAGE BATTERY CO., LTD.
    Inventor: Khalil Amine
  • Patent number: 6350429
    Abstract: This invention relates to the synthesis of large pore composite molecular sieves and to the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: February 26, 2002
    Assignee: ABB Lummus Global Inc.
    Inventors: Lawrence L. Murrell, Rudolf A. Overbeek, Yun-feng Chang, Nelleke Van Der Puil, Chuen Y. Yeh
  • Patent number: 6334994
    Abstract: Microporous crystalline silico-alumino-phosphate (SAPO) compositions, catalytic materials comprising the composition, and use of these for production of olefins from methanol. The catalysts contain silico-alumino-phosphate materials with AEI/CHA-mixed phase composition. The catalysts have prolonged life compared to those belonging to the prior art.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: January 1, 2002
    Assignee: Norsk Hydro ASA
    Inventors: Rune Wendelbo, Duncan E. Akporiaye, Anne Andersen, Martin Ivar Dahl, Helle Brit Mostad, Terje Fuglerud, Steinar Kvisle
  • Publication number: 20010055718
    Abstract: A positive electrode active material and a non-aqueous electrolyte cell which uses the positive electrode active material. The cell has a high discharge voltage without lowering the capacity and superior charging/discharging characteristics. To this end, the positive electrode active material contains a compound represented by the general formula LixMnyFe1-yPO4, wherein 0<x≦2 and 0.5<y<0.95, or a compound represented by the general formula LixMnyA1-yPO4, where 0<x≦2 and 0<y<1 and wherein A is a metal element selected from among Ti, Zn, Mg and Co or plural metal elements selected from among Ti, Fe, Zn, Mg and Co.
    Type: Application
    Filed: April 25, 2001
    Publication date: December 27, 2001
    Inventors: Guohua Li, Atsuo Yamada
  • Patent number: 6323146
    Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 Å. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: November 27, 2001
    Assignee: Millenium Biologix, Inc.
    Inventors: Sydney M. Pugh, Timothy J. N. Smith, Michael Sayer, Sarah Dorthea Langstaff
  • Publication number: 20010043900
    Abstract: A process for utilizing the material of ammonium-containing effluent which contains further soluble constituents and, possible additional solids, comprising:
    Type: Application
    Filed: July 6, 1999
    Publication date: November 22, 2001
    Inventors: THOMAS HIRTH, RAINER SCHWEPPE, KAI HOEHN
  • Patent number: 6319487
    Abstract: A method for making molecular sieves comprising silicoaluminophosphate 44 (SAPO-44) or substantially pure SAPO-44 and a method for using the molecular sieves so prepared for oxygenate conversion to olefins.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: November 20, 2001
    Assignee: Exxon Mobil Chemical Patents Inc.
    Inventors: Zhongmin Liu, Xiexian Guo, Guangyu Cai
  • Patent number: 6306308
    Abstract: A coagulant which is the reaction product of a trivalent metal salt (eg., FeCl3), excluding chromium salts, an acid phosphorous compound and an aluminum hydroxy chloride, and a process for preparing such coagulant. This coagulant may be effectively used to remove suspended solids and various impurities in most water treatment applications.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: October 23, 2001
    Assignee: Nalco Chemical Company
    Inventors: Denis E. Hassick, Michael P. Flaherty, Pamela J. Dotter, Robert J. Guerrini
  • Patent number: 6306494
    Abstract: Novel, fine particulate synthetic chalcoalumite, process for preparation thereof, and a heat insulating agent and agricultural film containing said fine, particulate synthetic chalcoalumite. The above objects are met by synthetic chalcoalumite represented by formula (1) below: (M12+)a−x(M22+)Al3+4(OH)b(An−)c. mH2O  (1)  (in which M12+ stands for Zn2+ or Cu2+,  M22+ is at least one divalent metal ion selected from Ni2+, Co2+, Cu2+, Zn2+ and Mg2+,  a is 0.3<a<2.0 (with the proviso that M1 and M2 are not the same),  x is 0 ≦x<1.0, and x<a  b is 10<b<14,  An− is at least one selected from SO42−, HPO42−, CO32−, SO32−, HPO32−, NO3−, H2PO4−, Cl−, OH− and silicate ion,  c is 0.4<c<2.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: October 23, 2001
    Assignee: Kyowa Chemical Industry Co Ltd
    Inventors: Hideo Takahashi, Akira Okada
  • Patent number: 6294493
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions and high catalytic cracking activity, a method for their preparation and their use as FCC catalysts. More particularly, the new SAPOs have a high silica:alumina ratio and favorable Si atom distribution. The new SAPOs may have a small crystal size and may be synthesized from a single- phase synthesis solution.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: September 25, 2001
    Assignee: Exxon Mobil Chemical Patents Inc.
    Inventors: Karl G. Strohmaier, David E. W. Vaughan
  • Patent number: 6261988
    Abstract: A metal ion-exchanged phosphorus-vanadium compound having an interlayer distance in the range of 7.0 to 8.2 Å and an ion exchange ratio of the divalent metal at least 20% obtained by treating vanadyl hydrogen orthophosphate hydrate represented by the formula (1) VOHPO4 .nH2O (1) wherein n fulfills the expression, 0<n≦2.0, with an aqueous divalent metal salt solution thereby effecting the exchange of N+ present between the layers of said vanadyl hydrogen orthophosphate hydrate, drying the resultant ion exchanged compound, and if necessary calcining the dried ion exchanged compound, a solid acid and a partial oxidation catalyst for hydrocarbons containing the compound.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: July 17, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventor: Ikuya Matsuura
  • Patent number: 6254844
    Abstract: A sintered lithium titaniumphosphate is produced by subjecting the powder of a mixture consisting of a Li source, a Ti source, and a P source to spark plasma sintering under an increased pressure.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: July 3, 2001
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Tomonari Takeuchi, Kazuaki Ado, Mitsuharu Tabuchi, Hiroyuki Kageyama
  • Patent number: 6241960
    Abstract: A method for the preparation of small zeotype crystals with controlled sizes comprising the steps of synthesizing inside a porous material having a majority of pores less than 1000 Å a synthesis gel consisting essentially of (a) a zeotype precursor composition comprising hydratized oxides of Si, Al and P and metal compounds (b) a zeolite template; and heating or autoclaving the porous support material containing synthesis gel, whereby zeotype crystals are formed; and rinsing and drying the porous support material containing zeotype crystals.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: June 5, 2001
    Assignee: Haldor Topsoe A/S
    Inventors: Haldor F. A. Topsøe, Claus J. H. Jacobsen, Michael Brorson, Claus Madsen, Iver Schmidt
  • Patent number: 6225253
    Abstract: The present invention relates to a chromium/silca-aluminophosphate catalyst, titanated under specific conditions and used for the homopolymerisation or the copolymerisation of ethylene. The polyethylene obtained with this catalyst has a high melt potential and a high shear resistance. The catalyst has a high level of activity.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: May 1, 2001
    Assignee: Fina Technology, Inc.
    Inventor: Guy Debras
  • Patent number: 6207872
    Abstract: A catalyst for converting methanol to light olefins along with the process itself are disclosed and claimed. The catalyst is a metalloaluminophosphate molecular sieve having the empirical formula (ELxAlyPz)O2 where EL is a metal such as silicon or magnesium and x, y and z are the mole fractions of EL, Al and P respectively. The molecular sieve has predominantly a plate crystal morphology in which the average smallest crystal dimension is at least 0.1 microns and has an aspect ratio of no greater than 5. Use of this catalyst gives a product with a larger amount of ethylene versus propylene.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: March 27, 2001
    Assignee: UOP LLC
    Inventors: Paul T. Barger, Stephen T. Wilson, Thomas M. Reynolds
  • Patent number: 6162415
    Abstract: A method for making molecular sieves comprising silicoaluminophosphate 44 (SAPO-44) or substantially pure SAPO-44 and a method for using the molecular sieves so prepared for oxygenate conversions to olefins.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: December 19, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Zhongmin Liu, Guangyu Cai, Xiexian Guo, deceased, by Juan Liang, legal representative
  • Patent number: 6156931
    Abstract: A new family of crystalline manganese phosphate compositions has been prepared. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of:(A.sup.3+).sub.v (Mn.sup.b+)(M.sup.c+).sub.x P.sub.y O.sub.zwhere A is a structure directing agent such as an alkali metal, M is a metal such as Al, Fe.sup.3+ and "b" is the average manganese oxidation state and varies from greater than 2.0 to a maximum of 3.0. These compositions can be used as adsorbents and as catalysts in the oxidation of hydrocarbons.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: December 5, 2000
    Assignee: UOP LLC
    Inventor: Gregory J. Lewis
  • Patent number: 6051339
    Abstract: A cathode for use in an electrochemical cell comprising a lithiated isopolyvanadate or heteropolyvanadate wherein the isopolyvanadate or heteropolyvanate has a cage structure, and an electrochemical battery comprising an alkali metal anode, an ionically conductive electrolyte and a cathode which comprises a lithiated isopolyvanadate or heteropolyvanadate having a cage structure, are described.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: April 18, 2000
    Assignee: Rentech, Inc.
    Inventors: Dale R. Shackle, Benjamin Chaloner-Gill
  • Patent number: 6040264
    Abstract: A method for converting starting material to olefins comprising contacting the starting material with a small pore non-zeolitic molecular sieve catalyst under effective conditions to produce olefins, wherein the non-zeolitic molecular sieve has been prepared in-situ or modified after synthesis by incorporation using an alkaline earth metal compound, wherein the alkaline earth metal ion is selected from the group consisting of strontium, calcium, barium, and mixtures thereof.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: March 21, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Hsiang-Ning Sun, Stephen Neil Vaughn
  • Patent number: 6000341
    Abstract: This invention involves new compositions and methods of use and delivery of amorphous calcium compounds such as: amorphous calcium phosphate (ACP), amorphous calcium phosphate fluoride (ACPF), amorphous calcium carbonate phosphate (ACCP), amorphous calcium carbonate phosphate fluoride (ACCPF), and amorphous calcium fluoride (ACF) for use in remineralizing and fluoridating teeth. These amorphous compounds or solutions which form the amorphous compounds or calcium phosphate jelly which forms the amorphous compounds, when applied either onto or into dental tissue to prevent and/or repair dental weaknesses such as dental caries, exposed roots and dentin sensitivity. The compounds have the highest solubilities, fastest formation rates and fastest conversion rates (to apatite) among all the calcium phosphates under physiological conditions. Moreover, in the presence to fluoride the amorphous compound convert rapidly to fluoride containing apatite.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: December 14, 1999
    Assignee: American Dental Association Health Foundation
    Inventor: Ming S. Tung
  • Patent number: 6001328
    Abstract: Microporous crystalline metallophosphate composition having an essential framework structure whose chemical composition in the as synthesised form expressed in terms of mole rations of oxides is: mR(M.sub.x Al.sub.y P.sub.z)O.sub.2 where M is silicon, x+y+z=1, m may have a value from 0.02 to 0.3, R is at least one templating agent, x, y and z represent the mole fractions of silicon, aluminium and phosphorous presentin the product, and where x may have a value from 0 to 0.5, y may have a value from 0.25 to 0.5 and z may have a value from 0.25 to 0.5, and where one reactive form of fluoride may be present in an effective amount to form the product, and having a characteristic X-ray powder diffraction pattern containing at least the d-spacings as set forth in Table 1.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: December 14, 1999
    Assignee: Norsk Hydro ASA
    Inventors: Karl Petter Lillerud, Erling N. Halvorsen, Arne Karlsson, Duncan Akporiaye, Jorun Hustveit
  • Patent number: 5989714
    Abstract: A composition comprising the product precipitated in the admixing of a soluble metal salt and one or more compounds having a component selected from silicates, phosphates and borates; and a method for controlling drainage and/or retention in the formation of a paper matrix or for treating water comprising the use of such product.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: November 23, 1999
    Assignee: Minerals Technologies Inc.
    Inventor: Donald Kendall Drummond
  • Patent number: 5989518
    Abstract: Applicants have developed a continuous process for synthesizing various molecular sieves. The process enables one to control both the particle size and particle size distribution. Any of the molecular sieves represented by the empirical formula on an anhydrous basis: rR.sub.2 O:(Si.sub.x Al.sub.y P.sub.z)O.sub.2, where R is at least one templating agent, "r" "x" "y" and "z" are the mole fractions of R, Si, Al and P respectively, can be prepared using this process. The process involves continuously adding reactive sources of the desired components along with a structure directing agent into a continuous crystallization reactor. Either interstage backmixing is introduced or the number of stages is adjusted in order to control particle size. Finally, one way to control particle size distribution is to split the product stream into at least two streams and flowing each stream to a wet miller operated at different severity and then reblending to obtain at least a bimodal distribution.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: November 23, 1999
    Assignee: UOP LLC
    Inventors: Medhat Khalil Tannous, Sonu Marchioretto, Lyle Edward Monson
  • Patent number: 5980856
    Abstract: This invention relates to synthetic chalcoalumite-type compounds represented by formula (1) below:M.sup.2+.sub.a-x/2 Li.sub.x.sup.1+ Al.sub.4.sup.3+ (OH).sub.b (A.sup.n-).sub.c.mH.sub.2 O (1)(whereinM.sup.2+ represents at least one of the following divalent metal ions: Zn.sup.2+, Cu.sup.2+, Ni.sup.2+ and Mg.sup.2+,a is 0.6<a<1.2,x is 0<x<1.4,b is 11<b<13,A.sup.n- is at least one member of the group consisting of SO.sub.4.sup.2-, HPO.sub.4.sup.2-, CO.sub.3.sup.2-, SiO.sub.3.sup.2-, SO.sub.3.sup.2-, HPO.sub.3.sup.2-, H.sub.2 PO.sub.4.sup.-, NO.sub.3.sup.- and OH.sup.-,c is 0.5<c<1.2, andm represents a number of 1 to 4)and processes for their preparation. The synthetic chalcoalumite-type compounds of the present invention are conveniently used for adsorbing agents of acidic substances, anion exchangers, infrared absorption agents for agricultural films, deodorants and recording media for ink jet, etc.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: November 9, 1999
    Assignee: Kyowa Chemical Industry Co., Ltd.
    Inventors: Akira Okada, Kazushige Oda, Kanako Shimizu
  • Patent number: 5976491
    Abstract: The present invention is a large-pore aluminophosphate or substituted aluminophosphate comprising a compositionaR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein R represents an organic templating agent, and a=0 to 0.4, X=0 to 0.4, y=0.35 to 0.5, and Z=0.25 to 0.5 and characterized by the diffraction pattern of Table 1 and M may be Si, Ga, Ge, Co, Ni, Zn, Fe, V, Ti and mixtures thereof.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventor: David E. W. Vaughan
  • Patent number: 5962028
    Abstract: Carbonated hydroxyapatite compositions and their preparation are described. The compositions are biologically resorbable and are prepared as flowable masses which can be administered by syringe to set in situ to serve as a support structure, filler, prosthesis or the like. Optionally the compositions may include proteins or serve as a depot for compositions of phrarmacological interest.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: October 5, 1999
    Assignee: Norian Corporation
    Inventor: Brent R. Constantz
  • Patent number: 5955048
    Abstract: There is provided a flash activated hydrotalcite which, when extruded to sizes of about 1/16 inch or more, has a crush load strength of at least about 7 pounds. The process for making this extrudate includes: (a) providing a hydrotalcite compound; (b) heating said compound for less than two seconds to one or more temperatures above about 482.degree. C. (900.degree. F.); (c) cooling said heated compound; (d) collecting said cooled compound; (e) forming said compound into an extrudate; and (f) reactivating said extrudate by heating to one or more temperatures above about 400.degree. C. (752.degree. F.) for about 20 minutes or more. Further strength improvements are achieved by exposing these extrudates to steam for at least about 8 hours prior to step (f).
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: September 21, 1999
    Assignee: Aluminum Company of America
    Inventors: Vito Cedro, III, John M. Stinson, Jr., Mark L. Weaver, James H. Richardson
  • Patent number: 5952399
    Abstract: A dental material based on an organic polymerisable binding agent has a content ofA) one or more mixed apatites of the typeA1) A.sub.10 (XO.sub.4).sub.6 Z.sub.2 +/B*.sub.10-u C*.sub.u (Y*).sub.6 Z'.sub.2 and/orA2) A'.sub.10-r (X'O.sub.4).sub.6-s Z".sub.2-t +/B'.sub.r (Y').sub.s Q.sub.t -B".sub.10-u' C'.sub.u' (Y").sub.6 Z'".sub.2 and/orA3) A".sub.10-r' (X"O.sub.4).sub.6-s' Z"".sub.2-t' +/A'".sub.r' (X'"O.sub.4).sub.s' +/B'".sub.10-u" C".sub.u" (Y'").sub.6 Z'"".sub.2in which the formulae assume the significance specified in the description, in a quantity that is effective for the absorption of ions from the biological application environment of the dental material. The polymerisable dental material has variably adjustable transparency, good polishability, high strength and the capacity to release and absorb ions into and from a biological environment. Also described is a process for using the mixed apatites A1), A2) and/or A3) in polymerisable dental materials.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: September 14, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventor: Harald Rentsch
  • Patent number: 5952010
    Abstract: Carbonated hydroxyapatite compositions and their preparation are described. The compositions are biologically resorbable and are prepared as flowable masses which can be administered by syringe to set in situ to serve as a support structure, filler, prosthesis or the like.
    Type: Grant
    Filed: December 9, 1997
    Date of Patent: September 14, 1999
    Assignee: Norian Corporation
    Inventor: Brent R. Constantz
  • Patent number: 5922297
    Abstract: A compound having the general formula AM.sub.1+y.sup.3+ M.sub.2-2y.sup.4+ M.sub.y.sup.5+ Si.sub.2 P.sub.6 O.sub.25, wherein A can be K, Rb, or Cs, M.sup.3+ can be Al, Ga, Cr, Fe, Sc, In, Y, lanthanide series elements, or combinations of these, M.sup.4+ can be Si, Ge, Ti, Ir, Ru, Sn, Hf, Zr, or combinations of these, M.sup.5+ can be V, Nb, Ta, or combinations of these, 0.ltoreq.y.ltoreq.1, the mean ionic radius of the M.sup.3+ cations and the mean ionic radius of the M.sup.5+ cations are each about 0.4 to 1.00 .ANG. when coordinated by six oxygen anions, and the mean ionic radii of the M.sup.4+ cations and the M.sup.5+ cations are each no greater than about 0.53+(0.30.times.the mean ionic radius of the M.sup.3+ cations). The compound can be made by a dry powder method that involves providing a homogeneous powder mixture of raw materials to form the compound, shaping the mixture into a preform, and firing the preform at a sufficient temperature and for a sufficient time to form the product compound.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: July 13, 1999
    Assignee: Corning Incorporated
    Inventor: Gregory A. Merkel
  • Patent number: 5912393
    Abstract: A catalyst for converting methanol to light olefins along with the process itself are disclosed and claimed. The catalyst is a metalloaluminophosphate molecular sieve having the empirical formula (EL.sub.x Al.sub.y P.sub.z)O.sub.2 where EL is a metal such as silicon or magnesium and x, y and z are the mole fractions of EL, Al and P respectively. The molecular sieve has a crystal morphology in which the average smallest crystal dimension is at least 0.1 microns. Use of this catalyst gives a product with a larger amount of ethylene versus propylene.
    Type: Grant
    Filed: December 9, 1997
    Date of Patent: June 15, 1999
    Assignee: UOP LLC
    Inventors: Paul T. Barger, Stephen T. Wilson, Thomas M. Reynolds
  • Patent number: 5900254
    Abstract: Carbonated hydroxyapatite compositions and their preparation are described. The compositions are biologically resorbable and are prepared as flowable masses which can be administered by syringe to set in situ to serve as a support structure, filler, prosthesis or the like. Optionally the compositions may include proteins or serve as a depot for compositions of phrarmacological interest.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: May 4, 1999
    Assignee: Norian Corporation
    Inventor: Brent R. Constantz
  • Patent number: 5888404
    Abstract: The invention relates to a method for treating waste water sludge comprising at least one metal originating from a waste water treatment coagulant, and phosphorus and heavy metals in order to recover said at least one metal and phosphorus and to discharge said heavy metals. In this method said waste water sludge is acidified to dissolve metals contained in the sludge thereby yielding an acidified sludge solution containing at least 1% by weight of at least one metal to be recovered. In a first precipitation stage the pH of said acidified sludge solution is raised to precipitate at least one metal to be recovered as a phosphate, and thereafter the phosphate precipitate is separated, thereby leaving a solution comprising heavy metals. In a second precipitation stage the pH of said solution comprising heavy metals is raised and, if necessary, an appropriate chemical is added to precipitate heavy metals, and thereafter the precipitate is discharged.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: March 30, 1999
    Assignee: Kemira Kemi Ab
    Inventor: Simo Jokinen
  • Patent number: 5879655
    Abstract: The present invention is a method for synthesizing non-zeolitic molecular sieves which have a three-dimensional microporous framework structure comprising ?AlO.sub.2 ! and ?PO.sub.2 ! units. In preparing the reaction mixture, a critical feature of the invention is for the molar ratio of the templating agent to phosphorus be greater than about 0.05 before the molar ratio of aluminum to phosphorus is greater than about 0.5.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: March 9, 1999
    Assignee: Chevron Research and Technology Company
    Inventors: Stephen J. Miller, Charles R. Wilson
  • Patent number: 5868873
    Abstract: Disclosed is a composition for the pre-rinsing of a metal surface prior to phosphating, a method for preparing the composition, and a method for using the composition to pre-condition the metal surface. The composition is an aqueous suspension containing a water-insoluble manganese phosphate having the formula Mn.sub.x X.sub.y H.sub.2 (PO.sub.4).sub.4.nH.sub.2 O, in which X is a divalent metal ion other than manganese, x+y is 5 and x is a positive number of from 1 to 5, y is 0, 1, 2, 3 or 4, and n is less than 4.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: February 9, 1999
    Assignee: Brent International PLC
    Inventors: Kevin Brown, Gianfranco Filippo Liberti, Sarfraz Ali, David Thomas Gawne
  • Patent number: 5861133
    Abstract: A synthetic chalcoalumite compound represented by the formula (1)(Zn.sub.a-x.sup.2+ M.sub.x.sup.2+)Al.sub.4.sup.3+ (OH).sub.b (A.sup.n-).sub.c.mH.sub.2 O (1)whereinM.sup.2+ represents at least one of Cu, Ni, Co and Mg;a represents 0.3<a<2.0;x represents 0.ltoreq.x<1.0;b represents 10<b<14;A.sup.n- represents one or two selected from SO.sub.4.sup.2-, HPO.sub.4.sup.2-, CO.sub.3.sup.2-, CrO.sub.4.sup.2-, SiO.sub.3.sup.2-, NO.sub.3.sup.2-, OH.sup.- and Cl.sup.- ;c represents 0.4<c<2.0 andm represents a number of 1 to 4,and a process for the production thereof.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: January 19, 1999
    Assignee: Kyowa Chemical Industry Co., Ltd.
    Inventors: Akira Okada, Kanako Shimizu, Kazushige Oda
  • Patent number: 5849852
    Abstract: Support for catalysts, containing at least two constituents chosen from silica, alumina and aluminium phosphate, having a specific surface of 100 to 800 m.sup.2 /g, a crystallization temperature greater than or equal to 700.degree. C. and a pore volume of 1.5 to 4 cm.sup.3 /g, the specific surface (SS) and the pore volume (PV) corresponding to the relationship:SS<(PV.times.564-358).Process for the manufacture of such a support, according to which an alcohol, water, a silicon alkoxide and an acid are mixed under conditions such that gelling or precipitation of silica is prevented, an acidic solution of an aluminium compound and/or a solution of a source of phosphate ions are added thereto, a gelling agent is added thereto, a gel is recovered which is washed with water and then by means of an organic liquid, the gel is then dried until a powder is obtained, and the powder is calcined. Polymerization of olefins in the presence of a catalyst containing chromium on a support as described above.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: December 15, 1998
    Assignee: Solvay Polyolefins Europe--Belgium (Societe Anonyme)
    Inventors: Benoit Koch, Andre Rulmont, Fabienne Wijzen
  • Patent number: 5824239
    Abstract: A method for removing biguanide from aqueous sources, such as swimming pools, is disclosed. The method includes the steps of bringing at least one polymeric metaphosphate into contact with the aqueous source in a sufficient concentration to form particles containing the biguanide. The particles containing at least a portion of the biguanide can then be removed by various means, including filtration or vacuuming.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: October 20, 1998
    Assignee: Buckman Laboratories International, Inc.
    Inventor: Percy A. Jaquess
  • Patent number: 5792721
    Abstract: The present invention provides a process for the preparation of acidic aqueous solutions consisting essentially of, phosphomolybdovanadate salts. Certain processes of the present invention dissolve in water an oxide, oxoacid, or mixtures thereof, and at least one oxoanion salt of phosphorus, molybdenum, and vanadium, wherein the sum of salt cationic charges does not exceed the sum of the phosphomolybdovanadate anionic charges in the solution. Other processes of the present invention dissolve in water a) an oxide, oxoacid, oxoanion salt, or mixtures thereof of phosphorus, molybdenum, and vanadium and b) a carbonate salt, bicarbonate salt, hydroxide salt or mixtures thereof, wherein the sum of salt cationic charges does not exceed the sum of the phosphomolybdovanadate anionic charges in the solution.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: August 11, 1998
    Assignee: Catalytica, Inc.
    Inventors: John H. Grate, David R. Hamm, Robert J. Saxton
  • Patent number: 5780003
    Abstract: A new family of crystalline manganese phosphate compositions has been prepared. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of:(A.sup.a+).sub.v (Mn.sup.b+)(M.sup.c+).sub.x P.sub.y O.sub.zwhere A is a templating agent such as an alkali metal, M is a metal such as Al, Fe.sup.3+ and "b" is the average manganese oxidation state and varies from greater than 3.0 to about 4.0. These compositions can be used as adsorbents and as catalysts in the oxidation of hydrocarbons.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: July 14, 1998
    Assignee: UOP LLC
    Inventor: Gregory J. Lewis
  • Patent number: 5776424
    Abstract: There is provided a method for making a monovalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a monovalent inorganic anion, in its acid or soluble salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a bromide-, chloride-, nitrate- or vanadate-intercalated, hydrotalcite-like material.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: July 7, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, Vito Cedro, III, William E. Horn, Jr.
  • Patent number: 5770739
    Abstract: An apparatus and process for hydrogen peroxide vapor sterilization of medical instruments and similar devices make use of hydrogen peroxide vapor released from a substantially non-aqueous organic hydrogen peroxide complex, such as a urea-peroxide complex. Optionally, a plasma can be used in conjunction with the vapor. A method for preparing substantially non-aqueous hydrogen peroxide complexes is also provided. These complexes are useful as a source of peroxide vapor in hydrogen peroxide vapor sterilizers and as a component of self-sterilizing packaging materials.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: June 23, 1998
    Assignee: Johnson & Johnson Medical, Inc.
    Inventors: Szu-Min Lin, James Archie Swanzy, Paul Taylor Jacobs
  • Patent number: 5741751
    Abstract: This invention provides a method for preparing non-zeolitic molecular sieves using inexpensive reagents and at lower manufacturing cost. The method includes using a low density, small size particulate hydrated alumina, such as aluminum hydroxide, in place of aluminum alkoxides and other more costly reagents. The preferred particulate hydrated alumina has a density of less than 1.0 g/cm.sup.3, an average particle size of less than about 40 microns and an alkali content of less than 0.12 wt %.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: April 21, 1998
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 5730951
    Abstract: There is provided a method for making a polyvalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a polyvalent inorganic anion, in its acid, acid salt or ammonium salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a borate- metatungstate- and paramolybdate-intercalated hydrotalcite-like material.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: March 24, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, Vito Cedro, III, William E. Horn, Jr.
  • Patent number: 5728365
    Abstract: There is provided a method for making a divalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a divalent inorganic anion, in its acid, acid salt or ammonium salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a sulfate- and metavanadate-intercalated hydrotalcite-like material.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: March 17, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, Vito Cedro, III, William E. Horn, Jr.
  • Patent number: 5728364
    Abstract: There is provided an improved method for making synthetic hydrotalcite by first reacting a divalent metal compound with a trivalent metal oxide powder in a carboxylic acid-free, aqueous solution or suspension to form an intermediate. This intermediate is then contacted with an anion source such as carbon dioxide; a carbonate-containing compound; an acid or an ammonium salt to form a layered double hydroxide having the formula:A.sub.1-x B.sub.x (OH).sub.2 C.sub.z.mH.sub.2 O, where A represents a divalent metal cation, B represents a trivalent metal cation, C represents a mono- to polyvalent anion, and x, z and m satisfy the following conditions: 0.09<x<0.67; z=x/n, where n=the charge on the anion; and 2>m>0.5. Said layered double hydroxide is typically separated from the suspension by filtering, centrifugation, vacuum dehydration or other known means.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: March 17, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, Vito Cedro, III, William E. Horn, Jr.
  • Patent number: 5728363
    Abstract: There is provided an improved method for making synthetic hydrotalcite by first reacting powdered magnesium oxide with a high surface area, transition alumina in a solution or suspension to form a meixnerite-like intermediate. This intermediate is then contacted with an anion source such as an acid, and most preferably carbon dioxide, to form the layered double hydroxide which is separated from the suspension by filtering, centrifugation, vacuum dehydration or other known means. On a preferred basis, the transition alumina combined with activated magnesia consists essentially of an rehydratable alumina powder having a surface area of 100 m.sup.2 /g or greater. To make related double hydroxide compounds, still other reactants such as bromides, chlorides, boric acids, or salts thereof, may be substituted for the carbon dioxide gas fed into this suspension.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: March 17, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, William E. Horn, Jr., Vito Cedro, III
  • Patent number: 5728359
    Abstract: Sodium ammonium phosphate and ammonium chloride are prepared from an ammonium phosphate (e.g., diammonium phosphate) and sodium chloride in water. The crystallization of sodium ammonium phosphate may take place between -10.degree. C. to 40.degree. C. Using the present invention, technical grade sodium ammonium phosphate and ammonium chloride can be produced from fertilizer grade diammonium phosphate.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: March 17, 1998
    Inventor: Raymond L. Nip
  • Patent number: 5728366
    Abstract: There is provided a method for making monovalent organic anion-intercalated hydrotalcite-like materials by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a monovalent organic anion to form a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a stearate-, acetate- or benzoate-intercalated hydrotalcite-like material.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: March 17, 1998
    Assignee: Aluminum Company of America
    Inventors: Edward S. Martin, John M. Stinson, Vito Cedro, III, William E. Horn, Jr.
  • Patent number: 5718757
    Abstract: The invention relates to a phosphomagnesium cement obtained by mixing water and a binding phase based on at least one phosphorus compound, at least one magnesium compound and at least one inorganic compound, characterized in that the inorganic compound is introduced in the form:- either of particles (1) of size smaller than 0.1 .mu.m,- or of aggregates (2) of size smaller than 0.1 .mu.m,- or of agglomerates (3) capable of deagglomerating at least partially during the mixing of the said binding phase and of water, into particles of size smaller than 0.1 .mu.m or into aggregates of size smaller than 0.1 .mu.m.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: February 17, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Bruno Le Guillou, Giiies Orange