By Reacting Halogen Containing Compound Patents (Class 423/424)
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Patent number: 9839220Abstract: The present invention provides aqueous alkaline, storage stable, abrasive containing hard surface treatment compositions which provide good cleaning to a treated hard surface, and concurrently a useful sanitizing or disinfecting benefit to such treated surfaces, wherein the compositions comprise: 0.01-15% wt. of at least one anionic surfactant and at least one nonionic surfactant, and preferably wherein the amount of the at least one anionic surfactant is in excess of the amount of the at least one nonionic surfactant; 0.1-50% wt. of one or more inorganic abrasive particulate materials which are based on inorganic carbonate compounds; a thickener; at least one non-cationic germicide constituent, which preferably are one or more compounds selected from the group consisting of: parachlorometaxylenol, and halogenated carbanilides (e.g.Type: GrantFiled: December 5, 2013Date of Patent: December 12, 2017Assignee: RECKITT BENCKISER (BRANDS) LIMITEDInventors: Mark Evans, Jason Geno, Michael Maledi
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Patent number: 9327995Abstract: Provided is a method for preparing barium titanate, which comprises: dissolving BaCl2.2H2O into TiCl4 solution to prepare Ba—Ti mixed solution with a Ba/Ti mol ratio of 1:1; adding ammonia and ammonium bicarbonate into deionized water to prepare synthetic agent with a NH4OH/NH4HCO3 mol ratio of 5:1; adding Ba—Ti mixed solution and synthesis agent into a reactor for synthesis to obtain a slurry; pressure filtering, thermal washing and then pressure filtering, to obtain a filter cake; calcining the filter cake for 1 hour at 590-610° C., followed by further calcining for 2 hours at 700-950° C.; crushing the obtained solid produced by a crusher, and thereby obtaining barium titanate. The obtained barium titanate is spherical, and has a narrower particle size distribution. The method reduces costs.Type: GrantFiled: July 20, 2010Date of Patent: May 3, 2016Assignees: GUIZHOU REDSTAR DEVELOPING CO., LTD., BEIJING MAXQUEEN TECHNOLOGY CO., LTD.Inventors: Zhiguang Jiang, Dong Hua
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Publication number: 20140286850Abstract: A method of making sodium carbonate and/or sodium bicarbonate is disclosed in which carbon dioxide gas is reacted with an aqueous solution sodium hydroxide solution in the presence of a compound of the formula (I): Na+[X—O]? where X is Cl, Br, or I.Type: ApplicationFiled: August 30, 2013Publication date: September 25, 2014Applicant: New York Synthetics, Inc.Inventors: Richard L. Peterson, Luke Ice, Omar Bradley Sheikh, Omar Ayaz Hussein, Vasilios Spiridon Koutsogiannis
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Patent number: 8623316Abstract: The proposed invention uses a classical chemical equation where carbon dioxide CO2 is reacted with quick lime Ca(OH)2 to produce soda carb NaHCO3 and concentrating it to 6% using advanced membrane and resin technology. The invention requires three chemicals CO2, Ca(OH)2, and sodium chloride NaCl to produce NaHCO3. The output of many industrial processes lacks waste heat and in many instances CO2 and the present invention combines a solid waste processing unit to the above processes which allows the production of solid products or high % liquors. Availability of waste heat sources can lead to high efficiency in NaHCO3, Na2CO3, and NaOH production. The process is not chloro-alkali electrochemical or Solvay column ammonia processing technique. Advanced membrane uses technologies of reverse osmosis and nanofiltration systems while resin technology uses ion exchange systems. Therefore, we conveniently call it the solid waste-quicklime membrane SWQM process.Type: GrantFiled: July 23, 2008Date of Patent: January 7, 2014Inventors: Fze Engsl, Tarek R. Farhat
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Patent number: 8460463Abstract: A silicon wafer is produced through the steps of forming a silicon ingot by a CZ method with an interstitial oxygen concentration of not more than 7.0×1017 atoms/cm3 and with a diameter of a COP occurring region not more than a diameter of a crystal, slicing a wafer from the silicon ingot after doping the silicon ingot with phosphorus, forming a polysilicon layer or a strained layer on one main surface of the wafer, and mirror polishing the other main surface of the wafer.Type: GrantFiled: August 20, 2009Date of Patent: June 11, 2013Assignee: Sumco CorporationInventors: Shigeru Umeno, Manabu Nishimoto, Masataka Hourai
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Publication number: 20120093708Abstract: Provided is an extracting and separating device which includes: an ash reactor 12 for preparing a solution having a temperature of about 60° C. by using incineration ash containing sodium, potassium, and chlorine; a cooling crystallizer 16 for reducing the temperature of the solution to 30° C. to produce and separate potassium chloride; an absorption tower 11 for reacting the solution with carbon dioxide-containing gas to produce and separate sodium hydrogen carbonate; and a circulation path 13 for returning to the ash reactor 12 a liquid obtained after the production and separation of the potassium chloride in the cooling crystallizer 16 and the sodium hydrogen carbonate in the absorption tower 11.Type: ApplicationFiled: July 22, 2010Publication date: April 19, 2012Inventors: Shuji Hamano, Tsunehira Yamamoto, Satoshi Okumura, Katsuya Sasaki
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Publication number: 20110217227Abstract: The proposed invention uses a classical chemical equation where carbon dioxide CO2 is reacted with quick lime Ca(OH)2 to produce soda carb NaHCO3 and concentrating it to 6% using advanced membrane and resin technology. The invention requires three chemicals CO2, Ca(OH)2, and sodium chloride NaCl to produce NaHCO3. The output of many industrial processes lacks waste heat and in many instances CO2 and the present invention combines a solid waste processing unit to the above processes which allows the production of solid products or high % liquors. Availability of waste heat sources can lead to high efficiency in NaHCO3, Na2CO3, and NaOH production. The process is not chloro-alkali electrochemical or Solvay column ammonia processing technique. Advanced membrane uses technologies of reverse osmosis and nanofiltration systems while resin technology uses ion exchange systems. Therefore, we conveniently call it the solid waste-quicklime membrane SWQM process.Type: ApplicationFiled: July 23, 2008Publication date: September 8, 2011Inventors: Fze Engsl, Tarek R. Farhat
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Patent number: 6419887Abstract: A process for the treatment of residual liquors from the ammoniation and carbonation of alkali metal salts containing ammonium salts, sodium salts, soluble sodium bicarbonate, ammonium bicarbonate and water and producing purified ammonium salts, comprising the steps of: eliminating the sodium bicarbonate, and ammonium bicarbonate mixed in the residual liquor by mixing sulfuric acid with the residual liquor in order to obtain a solution of an ammonium salt and a sodium salt; and separating the sodium salt from the solution or mixing the solution with sodium chloride crystals in order to obtain a magma containing sodium salt crystals and ammonium chloride crystals and separating the sodium salt crystals and the ammonium chloride crystals from the magma.Type: GrantFiled: May 8, 2000Date of Patent: July 16, 2002Inventor: José Cabello-Fuentes
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Patent number: 6066606Abstract: The blooming type, hard surface cleaning concentrate compositions according to the invention comprise the following constituents:0.1-10% wt. of a terpene containing solvent which desirably includes both pine oil and d-limonene;0.1-12% wt. of at least one organic solvent other than a terpene containing solvent constituent;0.1-20% wt. of a nonionic surfactant system which includes both at least one non-ionic surfactant constituent which desirably includes at least one nonionic surfactant having an HLB of greater than or equal to 10, and at least one nonionic surfactant based on a C.sub.8 -C.sub.18 primary alcohol ethoxylate which exhibits a cloud point of about 20.degree. C. or less in water;a bloom enhancing effective amount at least one amphoteric surfactant selected from alkylampho(mono)- and (di)-acetates, as well as alkylampho(mono)- and (di)-propionates, and aminopropionates;and the balance, to 100% wt. of water.Type: GrantFiled: February 24, 1999Date of Patent: May 23, 2000Assignee: Reckitt & Colman Inc.Inventors: Robert Zhong Lu, Andrew Arno Kloeppel
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Patent number: 5449506Abstract: A method for producing potassium carbonate using a continuous countercurrent exchange system. A continuous ion exchange system with resin in the ammonium form is flushed with a saturated potassium chloride solution which displaces the ammonium ion and replaces it with potassium. Ammonium carbonate is then passed through the ion exchanger to place the ammonium in the reserve form, by displacing the potassium, and produce a concentrated potassium carbonate solution. This process is done in a continuous countercurrent manner which allows maximum recovery of the potassium carbonate as a 15-18% by weight solution with minimum impurities, and at high throughput rates. The potassium carbonate solution is then removed, evaporated, dried, sized and stored for subsequent shipment.Type: GrantFiled: July 6, 1994Date of Patent: September 12, 1995Assignee: K-Technologies, Inc.Inventors: William W. Berry, Thomas E. Baroody, James M. Crawford
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Patent number: 5275794Abstract: Production of sodium bicarbonate from natural soda deposits that may occur as natural brines or solid soda salts is disclosed. The alkalinity in these natural soda deposits consists of carbonates and bicarbonates. The carbonates are converted to bicarbonates by reacting sodium carbonate with ammonium bicarbonate which acts as a carbon dioxide carrier until all the sodium carbonate is exhausted. The solubility of the sodium bicarbonate is lowered by the presence of non-alkaline sodium salts, e.g., sodium chloride. The regeneration of the cyclic reagent (NH.sub.3) is done using the sodium bicarbonate formed by the double decomposition of sodium chloride and ammonium bicarbonate giving a final soda free brine exempt of contaminants foreign to its original components.Type: GrantFiled: November 20, 1991Date of Patent: January 4, 1994Inventor: Raymundo R. Luna
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Patent number: 5270023Abstract: A process for producing sodium carbonate from a variety of crude ores and brine containing sodium bicarbonate and sodium carbonate without the use of calcium carbonate. The process includes the steps of reacting the raw materials containing sodium bicarbonate and sodium carbonate with a bicarbonate filtrate containing ammonium chloride brine solution under heat, producing ammonia, carbon dioxide, and a mother liquor containing an aqueous solution of sodium chloride which is recycled. This solution may contain also sodium bicarbonate and sodium carbonate to enhance production. The mother liquor is separated and reacted with ammonia and carbon dioxide collected from the reacting step to crystalize sodium bicarbonate and produce an ammonium chloride brine solution which is recycled to react with the crude ore.Type: GrantFiled: October 30, 1992Date of Patent: December 14, 1993Inventors: Frank H. May, Fred C. Hohne
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Patent number: 4767605Abstract: Method and apparatus for separating at least one harmful substance such as SO.sub.2, HCl or NO.sub.x where x is 1 or 2, from combustion exhaust gases containing the same. The exhaust gases are contacted with at least one particulate adsorbent which, at a release temperature below 400.degree. C., releases at least one of water, ammonia, or carbon dioxide, for reaction with the harmful substances. This reactant leaves the adsorbent in activated condition. Thus, the reactant and activated adsorbent serve to remove harmful substances from the flowing exhaust gas.Type: GrantFiled: December 2, 1985Date of Patent: August 30, 1988Assignee: Waagner-Biro AktiengesellschaftInventors: Ralf Lindbauer, Alfred Glasner
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Patent number: 4605537Abstract: Residual hypochlorite contained in chlorinated slurries of either carbonaceous gold-containing ores or mixtures of carbonaceous and oxide gold-containing ores are reduced by reaction with sulfide ion-providing chemical compounds preferably sodium hydrosulfide, sodium sulfide or hydrogen sulfide. The hypochlorite "kill" step enables subsequent cyanide leach operations to be conducted more efficiently.Type: GrantFiled: September 17, 1984Date of Patent: August 12, 1986Assignee: Freeport Minerals CompanyInventor: Freddie J. Touro
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Patent number: 4493818Abstract: Phosgene is removed from an off gas containing phosgene by contacting the off gas with an aqueous solution containing alkali metal hydroxide and a tertiary amine compound having 3 to 20 carbon atoms. The concentration of the alkali metal hydroxide can vary from 1 to 25 weight percent and the concentration of the tertiary amine can be any amount which is effective in the contact apparatus chosen. The amines found to be useful are trialkyl amines having 1 to 4 carbon atoms and pyridines having 0 to 3 alkyl groups of 1 to 5 carbon atoms and diamines such as 4-dimethylaminepyridine.Type: GrantFiled: January 27, 1984Date of Patent: January 15, 1985Assignee: The Dow Chemical CompanyInventor: James R. Gross
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Patent number: 4337234Abstract: A process for preparing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide under pressure in the presence of an amine and of an organic solvent.1. Carbon dioxide is introduced under a pressure of5-80 bars into a mixture essentially containing1.1 an aqueous sodium chloride solution,1.2 a tertiary amine,1.3 a non-polar, organic solvent, and1.4 a polar, organic solvent having a boiling point above 140.degree. C.,2. the aqueous and organic phases obtained are separated under the same pressure as step 1,3. the aqueous phase is rid of the precipitated sodium bicarbonate and following reconcentration with sodium chloride is fed back into process stage 1 (carbonization),4. the organic phase(s) containing the polar and non-polar organic solvents is (are) heated and the hydrogen chloride released is evacuated, and5. the tertiary amine, polar and non-polar organic solvents from step 4 are recirculated to step 1.Type: GrantFiled: October 3, 1980Date of Patent: June 29, 1982Assignee: Chemische Werke Huls AGInventors: Bernhard Hentschel, Jurgen Ziebarth, Alfred Coenen, Kurt Kosswig, Ferdinand von Praun
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Patent number: 4321247Abstract: A process for producing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide in the presence of an amine and an organic solvent. The steps of the process are carried out, wherein:(1) carbon dioxide is introduced into a mixture containing essentially(1.1) an aqueous sodium chloride solution,(1.2) a tertiary amine, and(1.3) a polar, organic solvent;(2) the aqueous and organic phases so obtained are separated;(3) the aqueous phase freed from the separated sodium bicarbonate following reconcentration with sodium chloride is fed back into process stage 1 (carbonization stage);(4) the organic phase (s) (is) are separated from the polar organic solvent and possibly of water to the widest possible extent and/or required; and(5) the residue containing a non-polar solvent is heated and the hydrogen chloride is removed.Type: GrantFiled: October 3, 1980Date of Patent: March 23, 1982Assignee: Chemische Werke Huls AGInventors: Alfred Coenen, Kurt Kosswig, Ferdinand v. Praun, Hans Regner
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Patent number: 4320106Abstract: A process for preparing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide under pressure in the presence of an amine and of an organic solvent.1. Carbon dioxide is introduced under a pressure of8-80 bars into a mixture essentially containing1.1 an aqueous sodium chloride solution,1.2 a tertiary amine,1.3 a non-polar organic solvent, and1.4 a polar, organic solvent having a boiling point above 140.degree. C.,2. the aqueous and organic phases obtained are separated under the same pressure as step 1,3. the aqueous phase is rid of the precipitated sodium bicarbonate and following reconcentration with sodium chloride is fed back into process stage 1 (carbonization),4. the organic phase(s) containing the polar and non-polar organic solvents is (are) heated and the hydrogen chloride released is evacuated, and5. the tertiary amine, polar and non-polar organic solvents from step 4 are recirculated in step 1.Type: GrantFiled: October 23, 1980Date of Patent: March 16, 1982Assignee: Chemische Werke Huls AGInventors: Bernhard Hentschel, Jurgen Ziebarth, Alfred Coenen, Kurt Kosswig, Ferdinand V. Praun
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Patent number: 4282187Abstract: A process for manufacturing synthetic hydrocarbons such as gasoline and/or kerosene from the synthesis of carbon dioxide and hydrogen. The carbon dioxide is obtained from the atmosphere while the hydrogen is obtained during the electrolysis of water. An intermediate fuel, namely methyl alcohol may be stored for use or upgraded to higher heating value hydrocarbons by a catalytic conversion.Type: GrantFiled: September 21, 1979Date of Patent: August 4, 1981Assignee: Grumman Aerospace CorporationInventors: Marshall J. Corbett, Salvatore C. Salina
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Patent number: 4256719Abstract: Production of sodium bicarbonate by the Solvay-soda method, employing a volatile aliphatic amine instead of ammonia, is combined with the oxychlorination of olefins in liquid phase by using the amine hydrochloride side-product of the soda plant as chlorine source in the oxidative regeneration of the spent chlorinating liquid. The chlorinating liquid contains iodine and copper chloride or iron chloride and on regenerating the spent liquid the amine is recovered in the vapor phase and recycled to the soda plant.Type: GrantFiled: January 9, 1980Date of Patent: March 17, 1981Assignee: Akzo N.V.Inventor: Eleonoor van Andel
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Patent number: 4066416Abstract: A carbonating tower for the production of sodium bicarbonate magma has a hollow casing accommodating perforated plates arranged one above another which divide the inner space of the casing into a separation compartment and reaction compartments communicating with one another via overflow pipes. Each reaction compartment has an annular baffle coaxial therewith arranged adjacent to the upper end of the overflow pipe, the baffle being adapted to define a zone for accumulation of solid crystalline phase in the magma. There are also provided means for removing said magma from one reaction compartment into the next compartment. The provision of the accumulation zone and the means for removal of magma contributes to the reduction of supersaturation of the solution with sodium bicarbonate, whereby crystals of uniform shape and size are obtained.Type: GrantFiled: March 30, 1976Date of Patent: January 3, 1978Inventors: Vadim Ivanovich Panov, Grigory Anatolievich Tkach, Viktor Mikhailovich Tomenko, Boris Mikhailovich Zolotukhin, Erik Konstantinovich Belyaev
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Patent number: 4010243Abstract: A process is provided for converting potassium chloride to potassium bicarbonate with desirable conversions which bicarbonate can then be calcined to potassium carbonate. In one embodiment the potassium bicarbonate is formed in a reaction medium which is an admixture of water and a water miscible alcohol with the other reactants employed being carbon dioxide and an alkylamine. In a more preferred embodiment an alcoholic solution of an alkylamine which solution is saturated with carbon dioxide will be prepared and then an aqueous solution of a potassium halide, preferably potassium chloride, will be added to the alcoholic solution so as to form potassium bicarbonate.Type: GrantFiled: November 28, 1975Date of Patent: March 1, 1977Assignee: Owens-Illinois, Inc.Inventor: Ian M. Thomas
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Patent number: 4002729Abstract: Water is thermochemically decomposed to produce hydrogen by the following sequence of reactions: KI, NH.sub.3, CO.sub. 2 and water in an organic solvent such as ethyl or propyl alcohol are reacted to produce KHCO 3 and NH.sub.4 I. The KHCO.sub.3 is thermally decomposed to K.sub.2 CO.sub.3, H.sub.2 O and CO.sub.2, while the NH.sub.4 I is reacted with Hg to produce HgI.sub.2, NH.sub.3 and H.sub.2. The K.sub.2 CO.sub.3 obtained by calcining KHCO.sub.3 is then reacted with HgI.sub.2 to produce Hg, KI, CO and O.sub.2. All products of the reaction are recycled except hydrogen and oxygen.Type: GrantFiled: April 6, 1976Date of Patent: January 11, 1977Assignee: The United States of America as represented by the United States Energy Research and Development AdministrationInventors: Bernard M. Abraham, Felix Schreiner