Product Patents (Class 423/447.2)
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Patent number: 11591220Abstract: Mineralization occurs during weathering of silicate materials/rocks rich in CA+ and Mg+, particularly peridotite which composes Earth's upper mantle. The carbon mineralization mantle peridotite is the base activated carbon for nanostructured-carbon-base-material. The nanostructured-carbon-base-material using mantle peridotite carbon mineralization based activated carbon nanotubes is a new catalyst for batteries and fuel-cell use that doesn't use precious metal such as platinum and that performs as effectively as many well-known, expensive precious-metal catalysts. The nanostructured-carbon-base-material using mantle peridotite carbon mineralization based activated carbon nanotubes makes possible the creation of economical lithium-air batteries that could power electric vehicles. The carbon nanotubes have useful qualities such as slim, strong, lightweight, high electronic conductivity, has metallic/semiconductive properties that are useful in (1) electronics i.e.Type: GrantFiled: July 27, 2020Date of Patent: February 28, 2023Inventor: Teresita Amponin Canuto
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Patent number: 11564864Abstract: A graphene nano-steam generator and a beauty instrument are provided. The graphene nano-steam generator includes a coarse steam channel, a nano-steam channel and a high-voltage power supply device. The coarse steam channel is connected to a coarse steam manufacturing device and the nano-steam channel. The coarse steam channel is provided with a steam sieving device, and an end of the coarse steam channel is provided with a first electrode and a second electrode. The high-voltage power supply device is coupled to the first electrode and the second electrode. The high-voltage power supply device supplies high-voltage electricity to the first electrode and the second electrode, and forms a high-voltage arc discharge between the first electrode and the second electrode, thus the coarse steam molecular group flowing through is ionized by the high-voltage arc to generate a large amount of active nano-scale steam to be flowed out from the nano-steam channel.Type: GrantFiled: October 29, 2018Date of Patent: January 31, 2023Assignee: Hangzhou Tsingke Energy and Environmental Technology Co., Ltd.Inventors: Feng Tang, Feng Jiang, Chao Yuan
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Patent number: 11559769Abstract: A nanocarbon separation device includes a first porous structure configured to hold a solution containing a surfactant, a second porous structure configured to hold a dispersion medium, a holding part provided between the first porous structure and the second porous structure and configured to hold the dispersion liquid containing the nanocarbons and the surfactant and having a smaller content of the surfactant than that of the solution, a separation tank in which the first porous structure, the holding part and the second porous structure are disposed and accommodated in an order of the first porous structure, the holding part and the second porous structure, a first electrode provided on a lower section of the first porous structure, and a second electrode provided on an upper section of the second porous structure.Type: GrantFiled: October 3, 2018Date of Patent: January 24, 2023Assignee: NEC CORPORATIONInventor: Mayumi Kosaka
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Patent number: 11549202Abstract: The present invention relates to a method for producing a carbon nanotube fiber aggregate and provides a carbon nanotube fiber aggregate having an improved level of alignment through ultrasonic wave application and low speed recovery.Type: GrantFiled: October 27, 2017Date of Patent: January 10, 2023Assignee: POSTECH ACADEMY-INDUSTRY FOUNDATIONInventors: Eugene Oh, Juhan Kim, Ji Eun Kim, Won Jae Lee, Hyunjung Cho, Kun-Hong Lee
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Patent number: 11511995Abstract: Provided herein are methods and devices for production of carbon nanotubes (CNTs) which have high structural uniformity and low levels of impurities. The device includes, for example, a module for depositing catalyst on a substrate, a module for forming CNTs, a module for separating CNTs from the substrate, a module for collecting the CNTs and a module for continuously and sequentially advancing the substrate through the above modules. The method includes, for example, the steps of depositing catalyst on a moving substrate, forming carbon nanotubes on the substrate, separating carbon nanotubes from the substrate and collecting the carbon nanotubes from the surface, where the substrate moves sequentially through the depositing, forming, separating and collecting steps.Type: GrantFiled: October 30, 2019Date of Patent: November 29, 2022Assignee: NTHERMA CORPORATIONInventor: Cattien V. Nguyen
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Patent number: 11485641Abstract: In order to provide an apparatus for industrially producing a fibrous carbon nanohorn aggregate (CNB), the apparatus comprises: a target holding unit holding a carbon target in sheet form containing a metal catalyst such as Fe; a light source irradiating a laser beam on a surface of the carbon target; a movement unit moving one of the target held by the target holding unit and the light source relative to the other to move the irradiation position of the laser beam on the surface of the target; a production chamber configured to irradiate the carbon target with the laser beam in an atmosphere of non-oxidizing gas to produce a product including the fibrous carbon nanohorn aggregate; a collection mechanism collecting carbon vapor evaporated from the target by irradiation of the laser beam to collect nanocarbon including the fibrous carbon nanohorn aggregate; and a control unit controlling an operation of the movement unit or the light source so that the power density of the laser beam irradiated to the surfaceType: GrantFiled: August 4, 2017Date of Patent: November 1, 2022Assignee: NEC CORPORATIONInventor: Ryota Yuge
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Patent number: 11486086Abstract: Disclosed in the present disclosure are a self-fused graphene fiber and a method of preparing the same. Dried graphene oxide fibers are soaked in a solvent to swell and then the fibers are pulled out and coalesced. After being dried, the graphene oxide fibers are fused together, and then are further reduced to obtain a self-fused graphene fiber. The entire self-fusion process can be quickly finished within one minute without adding any additional binder. The operation is simple and time-saving. The process is environmentally friendly; the bond strength is high, and the excellent properties such as outstanding mechanical strength and electrical conductivity of the graphene fibers themselves can be maintained. The present disclosure has great research and application value for further preparation of two-dimensional graphene fabrics or three-dimensional network bulks with excellent performance.Type: GrantFiled: February 27, 2018Date of Patent: November 1, 2022Assignee: ZHEJIANG UNIVERSITYInventors: Chao Gao, Dan Chang, Zheng Li, Weiwei Gao
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Patent number: 11469300Abstract: A reinforced thin-film device (100, 200, 500) including a substrate (101) having a top surface for supporting an epilayer; a mask layer (103) patterned with a plurality of nanosize cavities (102, 102?) disposed on said substrate (101) to form a needle pad; a thin-film (105) of lattice-mismatched semiconductor disposed on said mask layer (103), wherein said thin-film (105) comprises a plurality of in parallel spaced semiconductor needles (104, 204) of said lattice-mismatched semiconductor embedded in said thin-film (105), wherein said plurality of semiconductor needles (104, 204) are substantially vertically disposed in the axial direction toward said substrate (101) in said plurality of nanosize cavities (102, 102?) of said mask layer (103), and where a lattice-mismatched semiconductor epilayer (106) is provided on said thin-film supported thereby.Type: GrantFiled: April 23, 2019Date of Patent: October 11, 2022Assignee: Epinovatech ABInventor: Martin Andreas Olsson
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Patent number: 11427657Abstract: The present invention relates to a solid catalyst for propylene polymerization and a method of producing a propylene polymer or copolymer using the solid catalyst for propylene polymerization, and provides a solid catalyst which prepares a dialkoxymagnesium carrier and is formed of a carrier produced through a reaction of the carrier with a metal halide, a titanium halide, an organic electron donor, etc., and a method of producing a propylene polymer or copolymer through copolymerization of propylene-alpha olefin using the solid catalyst, wherein the dialkoxymagnesium carrier has an uniform particle size range of 10 to 100 ?m and a spherical particle shape by adjusting injection amounts, injection numbers, and reaction temperatures of metal magnesium, alcohol and a reaction initiator during a reaction process of metal magnesium and alcohol.Type: GrantFiled: December 19, 2019Date of Patent: August 30, 2022Assignee: HANWHA TOTAL PETROCHEMICAL CO., LTD.Inventors: Young Joo Lee, Eun Il Kim, Hyeong Cheol Park, Su Min Ko
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Patent number: 11299824Abstract: A method for making carbon fiber in which the tensile strength of carbon fiber is increased without dehumidifying the ambient air that enters every oxidation oven in a multiple oxidation oven system. A positive effect on tensile strength is provided when ambient air entering only the first oven in a series of oxidation ovens is dehumidified. In addition, the ambient air entering the last oven is not dehumidified when one or more of the preceding oxidation ovens is operated with dehumidified air.Type: GrantFiled: August 21, 2019Date of Patent: April 12, 2022Assignee: HEXCEL CORPORATIONInventors: Peter Andrew Ferrin, Devon Cadwaladar Todd Thomas
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Patent number: 11223064Abstract: Provided is a method of producing a multivalent metal-ion battery comprising an anode, a cathode, and an electrolyte in ionic contact with the anode and the cathode to support reversible deposition and dissolution of a multivalent metal, selected from Ni, Zn, Be, Mg, Ca, Ba, La, Ti, Ta, Zr, Nb, Mn, V, Co, Fe, Cd, Cr, Ga, In, or a combination thereof, at the anode, wherein the anode contains the multivalent metal or its alloy as an anode active material and the cathode comprises a cathode active layer of graphitic carbon particles or fibers that are coated with a protective material. Such a metal-ion battery delivers a high energy density, high power density, and long cycle life.Type: GrantFiled: August 22, 2019Date of Patent: January 11, 2022Assignee: Global Graphene Group, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 11214869Abstract: A heat treatment apparatus for high-quality graphene synthesis comprises an upper roll chamber, a deposition chamber connected to the upper roll chamber to deposit graphene on a catalytic metal film, and a lower roll chamber mounted on a lower portion of the deposition chamber. The upper roll chamber includes a supply roller and the lower roll chamber includes a lower direction shifting roller shifting a direction of the catalytic metal film supplied from the supply roller. In the deposition chamber, a catalytic metal film at a supply side transferred from the supply roller to the lower direction shifting roller and a catalytic metal film at a discharge side transferred from the lower direction shifting roller to a winding roller are passed, and a heater portion is mounted around the catalytic metal film at the supply side and the catalytic metal film at the discharge side.Type: GrantFiled: June 21, 2017Date of Patent: January 4, 2022Assignee: CHARMTRON CO., LTD.Inventor: Yong Ki Kim
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Patent number: 11130678Abstract: A novel carbon formation reactor for forming carbon from a carbon-bearing fluidic stream, and method of using the same, is described. The reactor uses a catalyst bearing surface placed within a heated zone in a carbon-bearing fluidic stream to form carbon, which can then be removed from the reactor, with the process repeatable to achieve high extraction efficiencies.Type: GrantFiled: July 20, 2017Date of Patent: September 28, 2021Inventors: Paul H. Matter, Michael G. Beachy, James Gaydos
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Patent number: 11024895Abstract: A charging apparatus for a lithium-ion secondary battery in which a cathode, an anode, and an electrolyte are housed in a battery case, includes an electrode shape changing unit that physically changes the shape of at least one electrode of the cathode and the anode at the time of charging or discharging the lithium-ion secondary battery so as to expand at least a part of a void which is formed in the electrode and which is to be penetrated by the electrolyte, and restores the physically changed shape of the electrode after charging or discharging the lithium-ion secondary battery.Type: GrantFiled: October 16, 2018Date of Patent: June 1, 2021Assignee: Toyota Jidosha Kabushiki KaishaInventor: Daisuke Akihisa
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Patent number: 10975501Abstract: A method for producing a carbon material, the method including a step of performing a carbonization treatment by heating an organic polymer material to a temperature higher than 400° C. in a non-oxidizing atmosphere containing a gaseous substance (A) composed of at least one of acetylene and an acetylene derivative.Type: GrantFiled: July 14, 2016Date of Patent: April 13, 2021Assignee: Mitsubishi Chemical CorporationInventors: Manabu Yamatani, Tomoyuki Kotani, Tomoyoshi Yamashita, Kazunao Hareyama
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Patent number: 10947122Abstract: The present invention discloses a method for the production of low ash activated charcoal from a carbon-containing raw material such as peat, in which method a damp mass of raw material is subjected to a hydrothermal carbonization process, in which the mass is heated to a temperature of 150 to 350 C and the process pressure increased to 10 to 40 bar, and the carbonized material obtained from the hydrothermal carbonization process is activated by heating it to a temperature above 400° C. The present invention further relates to the use of carbonized material obtained from the hydrothermal carbonization process for the production of activated charcoal.Type: GrantFiled: January 9, 2017Date of Patent: March 16, 2021Assignee: Vapo OyInventors: Mika Timonen, Hannu Lamberg
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Patent number: 10942143Abstract: A biosensor electrode, comprising: a porous metal structure; and a carbon nanotube structure comprising a plurality of carbon nanotubes, the carbon nanotube structure is fixed on a surface of the porous metal structure, wherein the porous metal structure and the carbon nanotube structure are shrunk together to form a plurality of wrinkled parts.Type: GrantFiled: October 31, 2017Date of Patent: March 9, 2021Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Hong-Ying Fu, Wen-Zhen Li
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Patent number: 10821687Abstract: The present invention relates to a method of producing hollow carbon capsules which can simply and effectively produce hollow carbon capsule by using polymer particles as soft templates and using a spray-drying method.Type: GrantFiled: September 30, 2015Date of Patent: November 3, 2020Assignee: LG CHEM, LTD.Inventors: In Young Kim, Jin Yeong Lee, Kwon Nam Sohn, Eui Yong Hwang, Won Jong Kwon
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Patent number: 10793964Abstract: A method of manufacturing a functionalized pre-treated carbon nanotube. Atomic Layer deposition is utilized to functionalize a pre-treated carbon nanotube. The functionalized pre-treated carbon nanotube may be used in a chemiresistor, including for methane detection.Type: GrantFiled: May 4, 2016Date of Patent: October 6, 2020Assignees: UChicago Argonne, LLC, The Regents of the University of CaliforniaInventors: Ralu Divan, M. Tanim Humayun, Igor Paprotny, Lara A. Gundel
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Patent number: 10774449Abstract: The present invention relates to an apparatus for producing a carbon nanotube fiber. The apparatus includes: a vertical reactor having a reaction zone; a concentric double-pipe inlet tube disposed on top of the reaction zone and consisting of an inner pipe through which a spinning feedstock including a spinning solution and a first gas is introduced into the reaction zone and an outer pipe defining a concentric annular portion surrounding the inner pipe and through which a second gas is introduced into the reaction zone; heating means for heating the reaction zone; and a discharge unit disposed under the bottom of the reaction zone to discharge a carbon nanotube fiber therethrough. The spinning feedstock entering the reaction zone through the inner pipe of the inlet tube is carbonized and graphitized while flowing from the top to the bottom of the reaction zone to form a carbon nanotube fiber consisting of a continuous sock (or aggregates) of carbon nanotubes.Type: GrantFiled: October 28, 2015Date of Patent: September 15, 2020Assignee: LG CHEM, LTD.Inventors: Ki Yong Yoon, YoungHo Lee, Ji Eun Kim, Yongjin Choe
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Patent number: 10759663Abstract: A catalyst composition for the production of carbon nanotubes (CNT) with controlled morphology is disclosed. The catalyst is represented by formula [(MxMny)Moz][binary metal oxide](100?(x+y+z)), where x is in the range 1 to 25 wt %, y is in the range 0.1 to 20 wt %, and z is in the range 0.0 to 10 wt %. Further M represents either iron or cobalt or nickel along with manganese and molybdenum supported on binary metal oxides comprising of boron, magnesium, aluminum, silicon, calcium, barium, and combination thereof. The CNT morphology can be tailor-made with the plural combination of nature of metal and promoters in appropriate proportions. The process yields the CNT with bulk density in the range of 0.01 to 0.20 g/cc, diameter in the range of 5 to 30 nm and purity greater than 95 wt %.Type: GrantFiled: March 8, 2018Date of Patent: September 1, 2020Assignee: Indian Oil Corporation LimitedInventors: Narayanam Seshubabu, Palvannan Mohanasundaram, Bhanumurthy Samala, Naduhatty Selai Raman, Rashmi Bagai, Sankara Sri Venkata Ramakumar, Biswapriya Das
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Patent number: 10751697Abstract: A process for producing activated carbon includes carbonizing an organic material to produce a charcoal, heating the charcoal in a chamber in the presence of oxygen at a temperature in the range of 400 to 500° C. for a duration of time sufficient to produce the activated carbon, and removing the charcoal from the heat once the activated carbon is formed.Type: GrantFiled: December 7, 2018Date of Patent: August 25, 2020Assignee: University of North DakotaInventor: Feng Xiao
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Patent number: 10703019Abstract: A resin-impregnated fiber bundle that can provide a molded article with a high surface impact strength is prepared by impregnating and integrating 100 parts by mass of a bundle of a fiber material (A) with 25 to 300 parts by mass of a thermoplastic resin (B). The fiber bundle has a flattened shape with a lateral cross-sectional shape having a major axis and a minor axis (length of the major axis>length of the minor axis). An average length (D1) of the major axis is 0.5 to 2.0 mm. An average flatness ratio (D1/D2), determined from the average length (D1) of the major axis and an average length (D2) of the minor axis, is 1.2 to 8.01. The fiber bundle has a length (L) of 11 to 50 mm, a ratio (L/D1) between L and D1 is 10 to 50, and a bulk density is 0.1 to 0.4 g/cm3.Type: GrantFiled: March 9, 2017Date of Patent: July 7, 2020Assignee: DAICEL POLYMER LTD.Inventors: Shigeyuki Kosaka, Satoru Shibata
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Patent number: 10646846Abstract: Inter-allotropic transformations of carbon are provided using moderate conditions including alternating voltage pulses and modest temperature elevation. By controlling the pulse magnitude, small-diameter single-walled carbon nanotubes are transformed into larger-diameter single-walled carbon nanotubes, multi-walled carbon nanotubes of different morphologies, and multi-layered graphene nanoribbons.Type: GrantFiled: September 14, 2015Date of Patent: May 12, 2020Assignees: Northeastern University, Massachusetts Institute of TechnologyInventors: Yung Joon Jung, Hyun Young Jung, Swastik Kar, Chi Won Ahn, Mildred Dresselhaus, Paulo Antonio Trindade Araujo
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Patent number: 10573879Abstract: In an example of a method for enhancing the performance of a silicon-based negative electrode, the silicon-based negative electrode is pre-lithiated in an electrolyte including a lithium salt dissolved in a solvent mixture of dimethoxyethane (DME) and fluoroethylene carbonate (FEC). The DME and FEC are present in a volume to volume ratio ranging from 10 to 1 to 1 to 10. The pre-lithiation forms a stable solid electrolyte interface layer on an exposed surface of the negative electrode.Type: GrantFiled: February 9, 2015Date of Patent: February 25, 2020Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Li Yang, Qiangfeng Xiao, Mei Cai, Meng Jiang, Xingcheng Xiao
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Patent number: 10563303Abstract: An article comprises a body having a coating. The coating comprises a Y-O-F coating or other yttrium-based oxy-fluoride coating generated either by performing a fluorination process on a yttrium-based oxide coating or an oxidation process on a yttrium-based fluorine coating.Type: GrantFiled: April 27, 2018Date of Patent: February 18, 2020Assignee: Applied Materials, Inc.Inventors: Xiaowei Wu, David Fenwick, Guodong Zhan, Jennifer Y. Sun, Michael R. Rice
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Patent number: 10553873Abstract: Provided is aluminum secondary battery comprising an anode, a cathode, a porous separator electronically separating the anode and the cathode, and an electrolyte in ionic contact with the anode and the cathode to support reversible deposition and dissolution of aluminum at the anode, wherein the anode contains aluminum metal or an aluminum metal alloy as an anode active material and the cathode comprises a layer of graphitic carbon particles or fibers, preferably selected from meso-phase carbon particles, meso carbon micro-beads (MCMB), coke particles or needles, soft carbon particles, hard carbon particles, amorphous graphite containing graphite micro-crystallites, multi-walled carbon nanotubes, carbon nano-fibers, carbon fibers, graphite nano-fibers, graphite fibers, or a combination thereof.Type: GrantFiled: March 9, 2017Date of Patent: February 4, 2020Assignee: Global Graphene Group, Inc.Inventors: Yu-Sheng Su, Aruna Zhamu, Hui He, Baofei Pan, Bor Z. Jang
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Patent number: 10479853Abstract: Provided is a surface-treated carbon nanotube having few surface fractures, not reducing the molecular weight of the resin to be mixed and having excellent extrudability. In the surface-treated carbon nanotube, the thermal reduction amount at 600° C. in a nitrogen atmosphere is 0.2 to 40%, the surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) is 1.5 to 40 atm % and the surface sulfur concentration is less than 0.1 atm %.Type: GrantFiled: March 5, 2013Date of Patent: November 19, 2019Assignee: ASAHI KASEI CHEMICALS CORPORATIONInventors: Aya Takagiwa, Teruaki Sakuma, Yasukazu Shikano, Kazuya Noda
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Patent number: 10468324Abstract: A microelectronic device includes a heat spreader layer on an electrode of a component and a metal interconnect on the heat spreader layer. The heat spreader layer is disposed above a top surface of a substrate of the semiconductor device. The heat spreader layer is 100 nanometers to 3 microns thick, has an in-plane thermal conductivity of at least 150 watts/meter-° K, and an electrical resistivity less than 100 micro-ohm-centimeters.Type: GrantFiled: June 16, 2016Date of Patent: November 5, 2019Assignee: TEXAS INSTRUMENTS INCORPORATEDInventors: Archana Venugopal, Marie Denison, Luigi Colombo, Sameer Pendharkar
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Patent number: 10431692Abstract: Embodiments of the present disclosure provide preparation methods for a semiconductor layer and a TFT, a TFT and an array substrate. The preparation method for a semiconductor layer includes forming a silicon dioxide film on a substrate; forming sidewalls at two ends of the semiconductor layer to be formed by patterning process; performing amination treatment on the sidewalls so that an aminosiloxane monolayer self-assembly is formed on the surface of the sidewalls; carboxylating a carbon nanotube solution and making the carboxylated carbon nanotube solution on the surface of the substrate with the sidewalls formed to form a carbon nanotube film; removing portions of the carbon nanotube film other than the portion between the sidewalls to form a semiconductor layer.Type: GrantFiled: May 20, 2016Date of Patent: October 1, 2019Assignee: BOE TECHNOLOGY GROUP CO., LTD.Inventor: Hu Meng
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Patent number: 10336619Abstract: Graphene oxide is synthesized by chemical treatment of graphite using only H2SO4, KMnO4, H2O2 and/or H2O as reagents. Graphene oxide films obtained using the method disclosed herein were characterized using various analytical techniques. These analytical techniques confirmed the creation of single to few layer graphene oxide with relatively large lateral size distribution using the method disclosed herein.Type: GrantFiled: July 27, 2016Date of Patent: July 2, 2019Assignee: Sri Lanka Institute of Nanotechnology (PVT) Ltd.Inventors: Viraj C. Jayawardena, Dilushan Rukmal Jayasundara, Gehan Amaratunga, Vimukthi Jayaweera
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Patent number: 10294108Abstract: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.Type: GrantFiled: May 30, 2018Date of Patent: May 21, 2019Assignee: ZEON CORPORATIONInventor: Akiyoshi Shibuya
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Patent number: 10266411Abstract: A method of producing a carbon nanotube-containing composition is a method of producing a carbon nanotube-containing composition for synthesizing carbon nanotube aggregates by introducing a ferrocene derivative, a sulfur compound, a carbon source, and a carrier gas into a gas phase flowing in a heating furnace within a temperature range of higher than 1,200° C. to 1,800° C. The carbon source substantially consists of benzene or toluene. The carrier gas includes hydrogen at 10% by volume to 85% by volume. The carrier gas has a linear velocity of 500 cm/min to 2,200 cm/min.Type: GrantFiled: July 13, 2016Date of Patent: April 23, 2019Assignee: Toray Industries, Inc.Inventors: Takayoshi Hirai, Kenshi Miyaura, Hidekazu Nishino, Shiro Honda
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Patent number: 10233566Abstract: Systems and methods for synthesizing continuous single crystal graphene are provided. A catalytic substrate is drawn through a chemical vapor deposition chamber in a first lengthwise direction while flowing a hydrogen gas through the chemical vapor deposition chamber in the same lengthwise direction. A hydrocarbon precursor gas is supplied directly above a surface of the catalytic substrate. A high concentration gradient of the hydrocarbon precursor at the crystal growth front is generated to promote the growth of a continuous single crystal graphene film while suppressing the growth of seed domains ahead of the crystal growth front.Type: GrantFiled: December 29, 2016Date of Patent: March 19, 2019Assignee: UT-Battelle, LLCInventors: Frederick Alyious List, III, Yijing Y. Stehle, Ivan V. Vlassiouk, Sergei N. Smirnov
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Patent number: 10189713Abstract: Provided is a method for efficiently producing a carbon nanotube dispersion liquid in which less-damaged carbon nanotubes are highly dispersed. The method for producing a carbon nanotube dispersion liquid includes: (A) obtaining a carbon nanotube dispersion liquid by applying a shear force to a coarse dispersion liquid that includes carbon nanotubes having a specific surface area of 600 m2/g or more to whereby disperse the carbon nanotubes, wherein the step (A) includes at least one of applying a back pressure to the carbon nanotube dispersion liquid and cooling the carbon nanotube dispersion liquid.Type: GrantFiled: July 23, 2014Date of Patent: January 29, 2019Assignee: ZEON CORPORATIONInventors: Mitsugu Uejima, Masahiro Shigeta
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Patent number: 10170752Abstract: A method for producing an amorphous carbon particle includes the steps of: obtaining a first crosslinked product by admixing mesophase particles with an amorphous carbon precursor and thereafter subjecting the mixture to a crosslinking treatment, or obtaining a second crosslinked product by crosslinking the amorphous carbon precursor and thereafter admixing the mesophase particles with the crosslinked precursor; and subjecting the first or second crosslinked product to an infusibilization treatment and thereafter firing the product to produce amorphous carbon particles including the mesophase particles within the particles.Type: GrantFiled: June 12, 2013Date of Patent: January 1, 2019Assignee: JFE CHEMICAL CORPORATIONInventors: Makiko Ijiri, Ryuta Haga, Tetsuo Shiode, Katsuhiro Nagayama
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Patent number: 10151051Abstract: The invention is directed to carbon fibers having high tensile strength and modulus of elasticity. The invention also provides a method and apparatus for making the carbon fibers. The method comprises advancing a precursor fiber through an oxidation oven wherein the fiber is subjected to controlled stretching in an oxidizing atmosphere in which tension loads are distributed amongst a plurality of passes through the oxidation oven, which permits higher cumulative stretches to be achieved. The method also includes subjecting the fiber to controlled stretching in two or more of the passes that is sufficient to cause the fiber to undergo one or more transitions in each of the two or more passes. The invention is also directed to an oxidation oven having a plurality of cooperating drive rolls in series that can be driven independently of each other so that the amount of stretch applied to the oven in each of the plurality of passes can be independently controlled.Type: GrantFiled: February 19, 2018Date of Patent: December 11, 2018Assignee: Hexcel CorporationInventor: Carlos A. León y León
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Patent number: 10138120Abstract: Nanostructured assemblies are manufactured by condensing an evaporated wetting agent onto a nanostructure array formed from a plurality of generally aligned carbon nanotubes or other nanostructures. The condensed wetting agent draws the individual nanostructures together to form various geometries of nanostructured assemblies based on various parameters including process variables and the starting shape and dimensional features of the nanostructure array. Various simple and complex geometries can be achieved in this manner, including geometries that are curved, bent, or twisted. Adjacent nanostructure arrays of the same or different starting geometries can be shaped into compound or interrelating structures. Additional process steps such as plasma etching, coating and others can be used to control the shaping and structural attributes of the nanostructured assemblies. A method of making a molded replica of a shaped nanostructure array is also disclosed.Type: GrantFiled: March 31, 2010Date of Patent: November 27, 2018Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Anastasios John Hart, Sameh Tawfick, Michael DeVolder, Davor Copic
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Patent number: 10138347Abstract: Provided is a method for efficiently producing a carbon nanotube (CNT) dispersion liquid of highly dispersed CNTs while also suppressing damage to the CNTs. The method for producing a carbon nanotube dispersion liquid includes a dispersing step that includes at least one cycle of dispersing treatment in which pressure is applied to a coarse dispersion liquid containing carbon nanotubes and a dispersion medium, the coarse dispersion liquid is fed under pressure, and shear force is applied to the coarse dispersion liquid such as to disperse the carbon nanotubes. A plurality of repetitions of the dispersing step are performed while altering the pressure that is applied to the coarse dispersion liquid. In at least one instance, the pressure applied to the coarse dispersion liquid is altered by at least 10 MPa between consecutive repetitions of the dispersing step.Type: GrantFiled: May 18, 2015Date of Patent: November 27, 2018Assignee: ZEON CORPORATIONInventors: Masahiro Shigeta, Mitsugu Uejima
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Patent number: 10099950Abstract: The invention relates to bio-electrochemical systems for treating wastewater, and sour gas produced by anaerobic digestion of organic material. The invention further relates to novel anode/cathode pairing schemes, and electric and hydraulic architectures for use in bio-electrochemical systems.Type: GrantFiled: April 14, 2011Date of Patent: October 16, 2018Assignee: CAMBRIAN INNOVATION LLCInventors: Matthew Silver, Justin Buck, Patrick Kiely, Juan J. Guzman
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Patent number: 10099460Abstract: A method for producing a preform for manufacture of a fiber-reinforced plastic molding. The method includes: fixing a resin-equipped film rolled out from a roll state including a release film and a fixing resin and containing a partially-cured thermosetting resin, to a surface of the dry fiber fabric rolled out from a roll with the fixing resin interposed therebetween, thereby obtaining a first dry fiber fabric; separately fixing the resin-equipped film to a surface of the dry fiber fabric rolled out from a roll with the fixing resin interposed therebetween, and detaching the release film, thereby obtaining one or more second dry fiber fabrics; and laminating the second dry fiber fabrics on a surface of the first dry fiber fabric with the fixing resin of the second dry fiber fabrics interposed therebetween.Type: GrantFiled: September 6, 2012Date of Patent: October 16, 2018Assignee: Mitsubishi Electric CorporationInventors: Sohei Samejima, Hajime Takeya, Michihito Matsumoto, Hiroki Kobayashi, Kazuki Kubo, Yuhei Awano, Takahiro Mabuchi
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Patent number: 10023979Abstract: A bundle of carbon fibers has a value A obtained from a nonlinear approximation formula of a stress ?-strain ? curve in a tensile strength test of resin-impregnated strands and an orientation parameter ? (%) of crystallites in a wide-angle x-ray diffraction measurement which satisfy a predetermined relational expression, and has tensile strength with a predetermined value or more, and tensile modulus within a predetermined range and a product E×d/W of a ratio d/W of a single-fiber diameter d to a loop width W just before loop fracture evaluated by a single-fiber loop test and a tensile modulus E of the strands has a predetermined value or more, or apparent single-fiber stress has a predetermined value or more when the number of fiber breaks by a single-fiber fragmentation method for a single-fiber composite is 0.30 breaks/mm and when the number of the fiber breaks by the single-fiber fragmentation method for the single-fiber composite is 0.Type: GrantFiled: October 23, 2015Date of Patent: July 17, 2018Assignee: Toray Industries, Inc.Inventors: Naohiro Matsumoto, Jun Watanabe, Haruki Okuda, Fumihiko Tanaka
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Patent number: 9988412Abstract: The present invention relates to fractions of high purity lignin which are thermally stable, and to methods of producing said fractions from lignocellulosic material.Type: GrantFiled: May 12, 2017Date of Patent: June 5, 2018Assignee: VIRDIA, INC.Inventors: Robert Jansen, James Alan Lawson, Noa Lapidot, Bassem Hallac, Perry Rotem
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Patent number: 9988313Abstract: We provide a method for the in situ development of graphene containing silicon carbide (SiC) matrix ceramic composites, and more particularly to the in situ graphene growth within the bulk ceramic through a single-step approach during SiC ceramics densification using an electric current activated/assisted sintering (ECAS) technique. This approach allows processing dense, robust, highly electrical conducting and well dispersed nanocomposites having a percolated graphene network, eliminating the handling of potentially hazardous nanostructures. Graphene/SiC components could be used in technological applications under strong demanding conditions where good electrical, thermal, mechanical and/or tribological properties are required, such as micro and nanoelectromechanical systems (MEMS and NEMS), sensors, actuators, heat exchangers, breaks, components for engines, armors, cutting tools, microturbines or microrotors.Type: GrantFiled: September 19, 2013Date of Patent: June 5, 2018Assignee: The Penn State Research FoundationInventors: Pilar Miranzo, Carmen Ocal, Maria Isabel Osendi, Manuel Belmonte, Cristina Ramirez, Benito Roman-Manso, Humberto R. Gutierrez, Mauricio Terrones
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Patent number: 9938643Abstract: The invention is directed to carbon fibers having high tensile strength and modulus of elasticity. The invention also provides a method and apparatus for making the carbon fibers. The method comprises advancing a precursor fiber through an oxidation oven wherein the fiber is subjected to controlled stretching in an oxidizing atmosphere in which tension loads are distributed amongst a plurality of passes through the oxidation oven, which permits higher cumulative stretches to be achieved. The method also includes subjecting the fiber to controlled stretching in two or more of the passes that is sufficient to cause the fiber to undergo one or more transitions in each of the two or more passes. The invention is also directed to an oxidation oven having a plurality of cooperating drive rolls in series that can be driven independently of each other so that the amount of stretch applied to the oven in each of the plurality of passes can be independently controlled.Type: GrantFiled: May 5, 2017Date of Patent: April 10, 2018Assignee: Hexel CorporationInventor: Carlos A. León y León
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Patent number: 9917308Abstract: The present invention provides a method for producing metal-supported carbon, which includes supporting metal microparticles on the surface of carbon black, by a liquid-phase reduction method, in a thin film fluid formed between processing surfaces arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, as well as a method for producing crystals comprising fullerene molecules and fullerene nanowhisker/nanofiber nanotubes, which includes uniformly stirring and mixing a solution containing a first solvent having fullerene dissolved therein, and a second solvent in which fullerene is less soluble than in the first solvent, in a thin film fluid formed between processing surfaces arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other.Type: GrantFiled: January 29, 2015Date of Patent: March 13, 2018Assignee: M. TECHNIQUE CO., LTD.Inventor: Masakazu Enomura
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Patent number: 9847181Abstract: The present invention provides: a film that comprises single-layer carbon nanotubes having shapes which enable the characteristics thereof to be sufficiently exhibited; and a process for producing the film. The film, which comprises single-layer carbon nanotubes, has portions where single-layer carbon nanotubes are densely present and portions where single-layer carbon nanotubes are sparsely present, the dense portions forming a pseudo-honeycomb structure in a surface of the film.Type: GrantFiled: March 3, 2014Date of Patent: December 19, 2017Assignee: THE UNIVERSITY OF TOKYOInventors: Shigeo Maruyama, Shohei Chiashi, Kehang Cui
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Patent number: 9765448Abstract: A flame resistant polymer is obtained by reacting polyacrylonitrile with amine and nitro compounds, the polyacrylonitrile being polymerized by aqueous suspension polymerization using a redox initiator and containing an S component at an amount of 3,000 ?g/g or less. A PAN-based polymer in which both yarn producing properties and flame resistance are improved can be realized.Type: GrantFiled: July 11, 2014Date of Patent: September 19, 2017Assignee: The University of TokyoInventors: Tetsunori Higuchi, Mami Sakaguchi
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Patent number: 9745471Abstract: A prepreg 10 comprises: a reinforcing fiber layer 3 including reinforcing fibers 1 and a resin composition 2 with which the space between fibers of the reinforcing fibers 1 is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and a surface layer 6a or 6b provided on at least one surface of the reinforcing fiber layer 3 and containing (A) a benzoxazine resin, (B) an epoxy resin, (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule, and (D) polyamide resin particles 4 having an average particle size of 5 to 50 ?m, wherein the polyamide resin particles 4 include a particle made of a polyamide 11.Type: GrantFiled: March 24, 2014Date of Patent: August 29, 2017Assignees: JX NIPPON OIL & ENERGY CORPORATION, FUJI JUKOGYO KABUSHIKI KAISHAInventors: Yoshihiro Fukuda, Takayuki Matsumoto, Masaki Minami, Naoyuki Sekine, Masanori Nakajima
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Patent number: 9711296Abstract: An energy storage device includes a first electrode and a second electrode comprising nanostructures. The nanostructures comprise defects that increase charge storage capabilities of the energy storage device. A method of fabricating an energy storage device includes producing a nanomaterial comprising nanostructures and generating defects in the nanomaterial using an electrophilic or nucleophilic additive for increasing charge storage capability of the nanomaterial.Type: GrantFiled: November 2, 2011Date of Patent: July 18, 2017Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Prabhakar R. Bandaru, Mark Hoefer