From Gaseous Reactants Patents (Class 423/447.3)
  • Patent number: 11939219
    Abstract: The carbon nanotube assembled wire includes a plurality of carbon nanotubes oriented at a degree of orientation of 0.9 or more and 1 or less.
    Type: Grant
    Filed: December 26, 2019
    Date of Patent: March 26, 2024
    Assignees: SUMITOMO ELECTRIC INDUSTRIES, LTD., UNIVERSITY OF TSUKUBA
    Inventors: Toshihiko Fujimori, Takeshi Hikata, Soichiro Okubo, Jun-ichi Fujita
  • Patent number: 11912900
    Abstract: Carbon nanotube (CNT) agglomerates can be aligned along the field lines between adjacent electrodes to form conductive bridges. The present invention is directed to a stepwise process of dielectrophoretic deposition of CNTs to form conducting bridges between adjacent electrodes spanning lengths over 50 microns. The CNT bridges are permanently secured using electrodeposition of the conducting polymer polypyrrole. Morphologies of the CNT bridges formed within a frequency range of 1 kHz and 10 MHz are employed and explained as a consequence of interplay between dielectrophoretic and electroosmotic forces. Postdeposition heat treatment increases conductivity of CNT bridges likely due to solvent evaporation and resulting surface tension inducing better contact between CNTs.
    Type: Grant
    Filed: April 6, 2021
    Date of Patent: February 27, 2024
    Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Lawrence Kulinsky, Tuo Zhou
  • Patent number: 11895429
    Abstract: An infrared detector includes a thermoelectric element, an infrared light absorber located on the thermoelectric element, and an electrical signal detecting element. The infrared light absorber includes a first drawn carbon nanotube film, a second drawn carbon nanotube film, and a third drawn carbon nanotube film stacked on each other. The first drawn carbon nanotube film includes a plurality of first carbon nanotubes substantially extending along a first direction. The second drawn carbon nanotube film includes a plurality of second carbon nanotubes substantially extending along a second direction. The third drawn carbon nanotube film includes a plurality of third carbon nanotubes substantially extending along a third direction. The first direction and the second direction form an angle of about 42 degrees to about 48 degrees, and the first direction and the third direction form an angle of about 84 degrees to about 96 degrees.
    Type: Grant
    Filed: June 15, 2020
    Date of Patent: February 6, 2024
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Yuan-Hao Jin, Qun-Qing Li, Shou-Shan Fan
  • Patent number: 11740184
    Abstract: Provided is a fiber web for a gas sensor. In one exemplary embodiment of the present invention, there is provided a fiber web for a gas sensor including nanofibers including a fiber-forming material and a sensing material for reacting with a target substance in a test gas. According to the exemplary embodiment, the fiber web for a gas sensor is capable of identifying the presence or absence of a target substance in a test gas and quantitatively determining the concentration of a target substance, and exhibits improved sensitivity due to having an increased area of contact and reaction with a target substance contained in a test gas.
    Type: Grant
    Filed: January 26, 2018
    Date of Patent: August 29, 2023
    Assignee: Amogreentech Co., Ltd.
    Inventor: Young Woo Yoon
  • Patent number: 11719307
    Abstract: Adhesive damping systems are described. A damping system for reducing the effects on a substrate caused by a disruption in the substrate environment includes an adhesive having a plurality of three-dimensional particles dispersed therein. The particles are configured to provide a controlled response to an applied force field. The system further includes a sensor which measures an amplitude and frequency spectrum of the disruption. In a use configuration, the sensor determines the amplitude and frequency spectrum of the disruption received by the substrate; and the applied force field is dependent on the amplitude and frequency spectrum of the disruption.
    Type: Grant
    Filed: September 28, 2018
    Date of Patent: August 8, 2023
    Assignee: Newtonoid Technologies, L.L.C.
    Inventors: Fielding B. Staton, David Strumpf
  • Patent number: 11719585
    Abstract: Fracture-induced composite sensors and methods of their fabrication are disclosed. The sensors can be used as strain sensors, piezo-resistive sensors, piezo-capacitive sensors, and non-contact displacement wearable sensors.
    Type: Grant
    Filed: December 3, 2018
    Date of Patent: August 8, 2023
    Assignee: University of Washington
    Inventors: Jae-Hyun Chung, Jinyuan Zhang, Dayong Gao, Jinkyu Yang
  • Patent number: 11708312
    Abstract: Steam cracking of ethane, a non-catalytic thermochemical process, remains the dominant means of ethylene production. The severe reaction conditions and energy expenditure involved in this process incentivize the search for alternative reaction pathways and reactor designs which maximize ethylene yield while minimizing cost and energy input. According to the present invention, ethylene yields as high as 68% were obtained with a quartz open tube reactor without the use of a catalyst or a cofed stream of oxidizing agents. The open tube reactor design promotes simplicity, low cost, and negligible coke formation. Reactor designs can be optimized to improve the conversion of ethane to ethylene via non-oxidative dehydrogenation, an approach which shows promise for decentralized production of ethylene from natural gas deposits.
    Type: Grant
    Filed: July 14, 2022
    Date of Patent: July 25, 2023
    Assignees: National Technology & Engineering Solutions of Sandia, LLC, UNM Rainforest Innovation
    Inventors: Christopher Ryan Riley, Andrew De La Riva, Stanley Shihyao Chou, Abhaya Datye
  • Patent number: 11697592
    Abstract: Provided is a method for highly efficiently producing highly pure single-walled carbon nanotubes. This method for producing carbon nanotubes by fluidized CVD includes: a step for heating a material (A) to 1200° C. or higher, in which the total mass of Al2O3 and SiO2 constitutes at least 90% of the total mass of the material (A) and the mass ratio of Al2O3/SiO2 is in the range of 1.0-2.3; and a step for bringing a gas, which is present in the environment in which the material (A) is being heated to 1200° C. or higher, into contact with a feed gas to generate carbon nanotubes.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: July 11, 2023
    Assignees: Osaka Soda Co., Ltd., Meijo Nano Carbon Co., Ltd.
    Inventors: Naruhito Iwasa, Daigo Hirayama, Jitsuo Oda, Yasushi Miki, Hisato Kagawa, Takeshi Hashimoto, Kei Takano
  • Patent number: 11685655
    Abstract: A carbon nanostructure producing method includes a growth step in which a plurality of catalyst particles in close contact with each other are separated in a flow of a carbon-containing gas so as to grow carbon nanotubes between the plurality of catalyst particles, and an elongation step in which the carbon nanotube is elongated by a wind pressure of the carbon-containing gas with at least one of the catalyst particles being retained.
    Type: Grant
    Filed: June 29, 2018
    Date of Patent: June 27, 2023
    Assignees: SUMITOMO ELECTRIC INDUSTRIES, LTD., UNIVERSITY OF TSUKUBA
    Inventors: Takeshi Hikata, Soichiro Okubo, Ryusuke Nakai, Jun-ichi Fujita
  • Patent number: 11624113
    Abstract: Systems and methods related to temperature zone control systems can include a reactant source cabinet that is configured to be at least partially evacuated, a vessel base that is configured to hold solid source chemical reactant therein, and a lid that is coupled to a distal portion of the vessel base. The lid may include one or more lid valves. The system may further include a plurality of gas panel valves that are configured to deliver gas from a gas source to the vessel. The system may include a heating element that is configured to heat the one or more lid valves. The system may include a heat shield, a first portion of which is disposed between the one or more lid valves and the vessel base. A second portion of the heat shield may be disposed between the first heating element and the plurality of gas panel valves.
    Type: Grant
    Filed: September 3, 2020
    Date of Patent: April 11, 2023
    Assignee: ASM IP HOLDING B.V.
    Inventors: Carl Louis White, Eric James Shero, Kyle Fondurulia
  • Patent number: 11616247
    Abstract: A fuel cell membrane electrode assembly having: a proton exchange membrane, an anode catalyst coating on one side of the membrane, and a cathode catalyst coating on the other side of the membrane. The cathode catalyst coating has at least two carbon catalyst layers, with a low porosity layer adjacent to a high porosity layer. The high porosity layers have a volume fraction that is higher than the volume fraction of the low porosity layers.
    Type: Grant
    Filed: June 16, 2021
    Date of Patent: March 28, 2023
    Assignee: The Government of the United States of America, as represented by the Secretary of the Navy
    Inventors: Yannick Garsany, Robert Atkinson, III, Benjamin Gould
  • Patent number: 11560313
    Abstract: Provided herein are graphene nanoribbons with high structural uniformity and low levels of impurities and methods of synthesis thereof. Also provided herein are graphene nanoplatelets of superior structural uniformity and low levels of impurities and methods of synthesis thereof. Further provided herein are mixtures of graphene nanoribbons and graphene nanoplatelets of good structural uniformity and low levels of impurities and methods of synthesis thereof. The method includes, for example, the steps of depositing catalyst on a constantly moving substrate, forming carbon nanotubes on the substrate, separating carbon nanotubes from the substrate, collecting the carbon nanotubes from the surface where the substrate moves continuously and sequentially through the depositing, forming, separating and collecting steps. Further processing steps convert the synthesized carbon nanotubes to graphene nanoribbons, graphene nanoplatelets and mixtures thereof.
    Type: Grant
    Filed: April 1, 2020
    Date of Patent: January 24, 2023
    Assignee: NTHERMA CORPORATION
    Inventor: Cattien V. Nguyen
  • Patent number: 11548793
    Abstract: A process for gas-phase synthesis of titanium dioxide aerosol gels with controlled monomer size and crystalline phase using a diffusion flame aerosol reactor operated in a buoyancy-opposed configuration is disclosed. The process includes introducing a precursor stream into a diffusion flame aerosol reactor, introducing a fuel stream into the reactor, combusting the precursor stream and the fuel stream in a flame to form at least one nanoparticle, and operating the reactor in a down-fired buoyancy-opposed configuration to produce the aerosol gel.
    Type: Grant
    Filed: October 19, 2017
    Date of Patent: January 10, 2023
    Assignee: Washington University
    Inventors: Rajan K. Chakrabarty, Pai Liu
  • Patent number: 11542164
    Abstract: The present invention relates to a carbon nanotube dispersion including carbon nanotubes, a polymer dispersant containing an amine, a phenolic compound including two or more aromatic rings, and an aqueous solvent, wherein the polymer dispersant and the phenolic compound including two or more aromatic rings are included in a weight ratio of 100:1 to 100:90, and having low viscosity and a small change of viscosity over time.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: January 3, 2023
    Assignee: LG Chem, Ltd.
    Inventors: Dong Hyun Kim, Houng Sik Yoo, Jin Myung Cha, Gye Min Kwon, Hyun Sik Chae, Dong Hyun Cho, Sang Hoon Choy, Hyeon Choi, Hyung Suk Cho
  • Patent number: 11542635
    Abstract: Carbon nanotube (CNT) fiber and sheets formed by a specialized gas assembly pyrolytic reactor method that permits gas phase integration of nano and micro particles (NMPs) are processed into yarn and fabric used in the manufacture of personal protective clothing and equipment that can be tailored via selection of NMPs for a wide variety of functionality depending on target application. The CNT-NMP hybrid fabrics may be designed to exhibit enhanced electrical and thermal conductivity, moisture wicking, air filtering, and environmental sensing properties.
    Type: Grant
    Filed: July 10, 2018
    Date of Patent: January 3, 2023
    Assignee: UNIVERSITY OF CINCINNATI
    Inventors: Mark J. Schulz, Sathya Kanakaraj, David Mast, Vesselin Shanov, Devika Chauhan, Guangfeng Hou, Vianessa Ng, Chenhao Xu, Rui Daniel Chen, Ashley Kubley, Xiaoda Hou, Richard Kleismit, Zhangzhang Yin
  • Patent number: 11542163
    Abstract: A carbon nanotube field emitter comprises at least two electrodes and at least one graphitized carbon nanotube structure. The at least one graphitized carbon nanotube structure comprises a first end and a field emission end. The first end is opposite to the field emission end. The first end is fixed between the at least two electrodes, and the field emission end is exposed from the at least two electrodes and configured to emit electrons.
    Type: Grant
    Filed: October 26, 2020
    Date of Patent: January 3, 2023
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Peng Liu, Duan-Liang Zhou, Chun-Hai Zhang, Li Qian, Yu-Quan Wang, Xue-Wei Guo, Li-Yong Ma, Fu-Jun Wang, Shou-Shan Fan
  • Patent number: 11479467
    Abstract: Disclosed here is a method of fabricating a covalently reinforced carbon nanotube (CNT) assembly. The method includes producing a CNT assembly by pulling entangled CNTs from a CNT array fabricated on a substrate, the CNT assembly including a plurality of CNTs that are aligned; and creating covalent bonding between the CNTs of the CNT assembly by applying a high energy ion irradiation to the CNT assembly.
    Type: Grant
    Filed: January 10, 2018
    Date of Patent: October 25, 2022
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Xavier N. Lepro Chavez, Chantel M. Aracne-Ruddle, Leonardus Bimo Bayu Aji, Sergei O. Kucheyev, Michael Stadermann
  • Patent number: 11477856
    Abstract: A carbon allotrope element includes a carbon allotrope layer formed from a carbon allotrope material impregnated with a dielectric resin and having a first surface. The carbon allotrope element further includes a first bus bar in communication with the first surface, and a second bus bar in communication with the first surface and non-adjacent to the first bus bar. The first surface includes a layer of the dielectric resin and a plurality of abraded regions, and each of the first and second bus bars is in communication with one of the plurality of abraded regions of the first surface.
    Type: Grant
    Filed: January 21, 2020
    Date of Patent: October 18, 2022
    Assignee: Goodrich Corporation
    Inventors: Nathaniel Ching, Casey Slane, Jin Hu
  • Patent number: 11453590
    Abstract: Effective techniques for patterning carbon nanotube (CNT) sheets are disclosed herein. A carbon nanotube forest is grown on a catalyst-incorporated substrate, CNT sheets are drawn from the carbon nanotube forest, the CNT sheets are stacked on a substrate, followed by etching the CNT sheets by using a shadow mask through a controlled etch process. In some implementations, etching of the CNT sheets is carried out in a capacitively coupled plasma (CCP) etching system, where the CNT sheets are selectively exposed, in a controlled environment, to oxygen plasma via the shadow mask.
    Type: Grant
    Filed: October 21, 2019
    Date of Patent: September 27, 2022
    Assignee: Board of Regents, The University of Texas System
    Inventors: Behnoush Dousti, Gil Sik Lee, Negar Geramifard
  • Patent number: 11447391
    Abstract: A method of growing a graphene coating or carbon nanotubes on a catalytic substrate by chemical vapor deposition is provided. In the method, the chemical vapor deposition is carried out in an atmosphere in which a ratio Pox/Pred is about 5×10?26 or less, wherein Pox is the partial pressure oxidizing species in the atmosphere and Pred is the partial pressure of reducing species in the atmosphere. A catalytic substrate coated with a graphene coating grown according to this method is also provided.
    Type: Grant
    Filed: June 22, 2016
    Date of Patent: September 20, 2022
    Inventors: Saman Choubak, Pierre Lévesque, Philippe Gagnon, Richard Martel, Patrick Desjardins
  • Patent number: 11408097
    Abstract: The present invention provides a process for preparing a yarn, which comprises introducing a raw material that comprises a carbon source and a catalyst into a reaction chamber having a heating means, converting the carbon source into a plurality of carbon nanotubes in a heating part of the reaction chamber with thermal energy supplied by the heating means, and growing the plurality of carbon nanotubes in the vertical direction to form a yarn by the interactions among the carbon nanotubes.
    Type: Grant
    Filed: September 17, 2019
    Date of Patent: August 9, 2022
    Assignee: AweXome Ray, Inc.
    Inventors: Se Hoon Gihm, Keun Soo Jeong, Yeon Su Jung
  • Patent number: 11377354
    Abstract: A process for growing carbon nanotubes includes making carbon nanotubes by flowing methane into a tube. The process also includes increasing pressure to a high predefined pressure for the carbon nanotubes and maintaining temperature at a low predefined temperature for the carbon nanotubes. The high pressure and low temperature produce carbon nanotubes within minutes.
    Type: Grant
    Filed: September 13, 2019
    Date of Patent: July 5, 2022
    Assignee: THE AEROSPACE CORPORATION
    Inventors: Teresa A. Moore, Brian B. Brady, Robert B. Driscoll
  • Patent number: 11370191
    Abstract: A density of a nanofiber sheet can be changed using an edged surface, and in particular an arcuate edged surface. As described herein, a nanofiber sheet is drawn over (and in contact with) an arcuate edged surface. Depending on whether the arcuate surface facing a direction opposite the direction in which the nanofiber sheet is being drawn is convex or concave determines whether the nanofiber sheet density is increased relative to the as-drawn sheet or decreased relative to the as-drawn sheet.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: June 28, 2022
    Assignee: LINTEC OF AMERICA, INC.
    Inventors: Marcio D. Lima, Julia Bykova
  • Patent number: 11369929
    Abstract: Systems and methods of synthesizing nanoparticles on substrates using rapid, high temperature thermal shock. A method involves depositing micro-sized particles or salt precursors on a substrate, and applying a rapid, high temperature thermal shock to the micro-sized particles or the salt precursors to become nanoparticles on the substrate. A system may include a rotatable member that receives a roll of a substrate sheet having micro-sized particles or salt precursors; a motor that rotates the rotatable member so as to unroll the substrate; and a thermal energy source that applies a short, high temperature thermal shock to the substrate. The nanoparticles may be metallic, ceramic, inorganic, semiconductor, or compound nanoparticles. The substrate may be a carbon-based substrate, a conducting substrate, or a non-conducting substrate. The high temperature thermal shock process may be enabled by electrical Joule heating, microwave heating, thermal radiative heating, plasma heating, or laser heating.
    Type: Grant
    Filed: June 22, 2018
    Date of Patent: June 28, 2022
    Assignee: UNIVERSITY OF MARYLAND, COLLEGE PARK
    Inventors: Liangbing Hu, Yanan Chen, Yonggang Yao
  • Patent number: 11352259
    Abstract: A method of producing carbon nanotubes in a fluidized bed reactor includes preparing a carbon nanotube by supplying a catalyst and a carbon source to an interior of the fluidized bed reactor having an internal pressure of 0.5 barg to 1.2 barg (gauge pressure), thereby improving the yield and purity of carbon nanotubes.
    Type: Grant
    Filed: May 24, 2018
    Date of Patent: June 7, 2022
    Assignees: SK Innovation Co., Ltd., SK Global Chemical Co., Ltd.
    Inventors: Sung Real Son, Ji Min Kim, Min Ji Sung, Sang Uk Kim, Jung Yul Son
  • Patent number: 11286163
    Abstract: A method for making a carbon nanotube array includes placing a gas diffusing unit defining an outlet in a chamber including a first inlet and a second inlet. A gas transporting pipe haves a first end and a second end opposite to the first end, the second end is connected to the gas diffusing unit, and the first end passes through the second inlet and extends out of the chamber. A growth substrate defining a through hole covers the outlet. A carbon source gas and a protective gas is supplied to the chamber from the first inlet, to grow a carbon nanotube array including multiple carbon nanotubes. Each carbon nanotube has a bottom end. Then the carbon source gas is stopped supplying, and an oxygen containing gas is supplied to the gas transporting pipe, to oxidize the bottom end.
    Type: Grant
    Filed: August 10, 2020
    Date of Patent: March 29, 2022
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Liang Liu, Qi Cai, Shou-Shan Fan
  • Patent number: 11271158
    Abstract: Described herein is a method for the production of electronic or optoelectronic devices with an anisotropic molecular structure of an organic semiconductor material. Also described herein are electronic or optoelectronic devices including an organic semiconductor material with anisotropic molecular structure. Also described herein are fibers comprising a hollow core and a shell comprising an organic semiconductor material.
    Type: Grant
    Filed: May 18, 2018
    Date of Patent: March 8, 2022
    Assignee: InnovationLab GmbH
    Inventors: Tobias Roedlmeier, Anthony Morfa, Gerardo Hemandez-Sosa, Ralph Eckstein
  • Patent number: 11271220
    Abstract: A multilayer structure, of use as composite diffusion layer in a proton-exchange membrane fuel cell, including at least one mat of carbon nanotubes having a unit diameter of less than or equal to 20 nm, defining at least one face of the structure, the mat of carbon nanotubes being superposed on a support based on carbon fibres. It also relates to a process for preparing such a multilayer structure and to the use thereof for an electrode of a PEMFC.
    Type: Grant
    Filed: October 19, 2018
    Date of Patent: March 8, 2022
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Arnaud Morin, Jean Dijon, Raphael Ramos
  • Patent number: 11255015
    Abstract: A system for chemical vapor densification includes a reaction chamber having an inlet and outlet; a trap; a conduit fluidly coupled between the outlet of the reaction chamber and the trap; a cryogenic cooler fluidly coupled to the trap though a frustoconical conduit; a first exit path from the cryogenic cooler that vents hydrogen gas to an exhaust; and a second exit path from the cryogenic cooler that recirculates silane and hydrocarbon-rich gas back to the inlet of the reaction chamber—and a related method places a substrate in the reaction chamber; establishes a sub-atmospheric pressure inert gas atmosphere within the reaction chamber; densifies the substrate by inputting virgin gas into the reaction chamber; withdraws effluent gas from the reaction chamber; extracts silane and hydrocarbon-rich gas from the effluent gas; and recirculates the silane and hydrocarbon-rich gas back to the reaction chamber.
    Type: Grant
    Filed: May 6, 2020
    Date of Patent: February 22, 2022
    Assignee: Goodrich Corporation
    Inventors: Gavin Charles Richards, Tod Policandriotes, Afshin Bazhushtari
  • Patent number: 11171324
    Abstract: A method of producing a composite product is provided. The method includes providing a fluidized bed of metal oxide particles in a fluidized bed reactor, providing a catalyst or catalyst precursor in the fluidized bed reactor, providing a carbon source in the fluidized bed reactor for growing carbon nanotubes, growing carbon nanotubes in a carbon nanotube growth zone of the fluidized bed reactor, and collecting a composite product comprising metal oxide particles and carbon nanotubes.
    Type: Grant
    Filed: March 7, 2017
    Date of Patent: November 9, 2021
    Assignees: HONDA MOTOR CO., LTD., NANOSYNTHESIS PLUS, LTD.
    Inventors: Avetik Harutyunyan, Neal Pierce, Elena Mora Pigos
  • Patent number: 11133503
    Abstract: Process for making an at least partially coated particulate material, said process comprising the following steps: (a) providing a particulate material selected from lithiated nickel-cobalt aluminum oxides and layered lithium transition metal oxides, (a) treating said cathode active material with a metal alkoxide or metal amide or alkyl metal compound in a fluidized bed, (b) treating the material obtained in step (b) with moisture in a fluidized bed, and, optionally, repeating the sequence of steps (b) and (c), wherein the superficial gas velocity in the fluidized beds in steps (b) and (c) decreases with increasing reactor height.
    Type: Grant
    Filed: January 12, 2018
    Date of Patent: September 28, 2021
    Assignee: BASF Corporation
    Inventors: Dominik Garella, Axel Binder, Stefan Strege, Tillmann Liebsch
  • Patent number: 11053123
    Abstract: Provided is a method of producing carbon nanotubes by supplying a catalyst and a carbon source to a fluidized bed reactor. The fluidized bed reactor has an expanded zone. A flow velocity (linear velocity) of a raw material supplied to the fluidized bed reactor is equal to or higher than a terminal velocity of an internal material in the fluidized bed reactor.
    Type: Grant
    Filed: June 28, 2018
    Date of Patent: July 6, 2021
    Assignees: SK Innovation Co., Ltd., SK Global Chemical Co., Ltd.
    Inventors: Sung Real Son, Ji Min Kim, Min Ji Sung, Sang Uk Kim, Jung Yul Son
  • Patent number: 11002908
    Abstract: Methods for fabricating flexible substrate nanostructured devices are disclosed. The nanostructures comprise nano-pillars and metallic bulbs or nano-apertures. The nanostructures can be functionalized to detect biological entities. The flexible substrates can be rolled into cylindrical tubes for detection of fluidic samples.
    Type: Grant
    Filed: October 24, 2016
    Date of Patent: May 11, 2021
    Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: Chieh-feng Chang, Sameer Walavalkar, Scott E. Fraser, Axel Scherer
  • Patent number: 10994990
    Abstract: A method for making nanomaterials includes introducing into a catalyzed reactor vessel: a carrier gas at a first carrier gas feed rate; at least one carbon-based reactant at a first reactant feed rate; and optionally, at least one additive at a first additive feed rate. The reactor vessel is heated to a first temperature of at least 150° C., so that a portion of the carbon-based reactant within the reactor vessel reacts to form a plurality of nanomaterials. An exhaust gas is removed from the reactor and periodically sampled by exposing a paper web to the gas so that a sample of the nanomaterials from the gas are deposited on a region of the paper web for analysis. Based on this analysis, at least one reaction parameter selected from the group consisting of the first carrier gas feed rate, the first reactant feed rate, and first temperature may be adjusted.
    Type: Grant
    Filed: October 7, 2019
    Date of Patent: May 4, 2021
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventors: Rahul S. Rao, Benji Maruyama
  • Patent number: 10988382
    Abstract: The instant disclosure is related to the growth of carbon-based nanostructures and associated systems and products. Certain embodiments are related to carbon-based nanostructure growth using active growth materials comprising alkali metals and/or alkaline earth metals. In some embodiments, the growth of carbon-based nanostructures is performed at relatively low temperatures.
    Type: Grant
    Filed: March 30, 2017
    Date of Patent: April 27, 2021
    Assignee: Massachusetts Institute of Technology
    Inventors: Brian L. Wardle, Richard Li, Erica Freire Antunes, Andrew H. Liotta
  • Patent number: 10967587
    Abstract: Methods of forming composite materials, which may include filament winding two or more carbon nanotube yarns to form one or more material layers, contacting the yarns with a resin, and applying one or more stretching forces to the material layers. Composite materials also are provided.
    Type: Grant
    Filed: August 13, 2019
    Date of Patent: April 6, 2021
    Assignee: The Florida State University Research Foundation, Inc.
    Inventors: Zhiyong Liang, Gerald Horne, Ayou Hao, Claire Jolowsky
  • Patent number: 10954128
    Abstract: A method of producing fibrous carbon nanostructures uses a fluidized bed process, and comprises supplying a source gas to a reaction site in which a supported catalyst having a particulate carrier and a catalyst supported on a surface of the carrier is fluidizing, to form fibrous carbon nanostructures on the catalyst of the supported catalyst, wherein the source gas contains a double bond-containing hydrocarbon and carbon dioxide, and a content of the carbon dioxide is 0.3 vol % or more with respect to a total volume of the source gas.
    Type: Grant
    Filed: January 20, 2017
    Date of Patent: March 23, 2021
    Assignees: WASEDA UNIVERSITY, ZEON CORPORATION
    Inventors: Suguru Noda, Soichiro Hachiya, Zhongming Chen, Takayoshi Hongo
  • Patent number: 10930473
    Abstract: Apparatus and method for plasma synthesis of carbon nanotubes couple a plasma nozzle to a reaction tube/chamber. A process gas comprising a carbon-containing species is supplied to the plasma nozzle. Radio frequency radiation is supplied to the process gas within the plasma nozzle, so as to sustain a plasma within the nozzle in use, and thereby cause cracking of the carbon-containing species. The plasma nozzle is arranged such that an afterglow of the plasma extends into the reaction tube/chamber. The cracked carbon-containing species also pass into the reaction tube/chamber. The cracked carbon-containing species recombine within the afterglow, so as to form carbon nanotubes in the presence of a catalyst.
    Type: Grant
    Filed: December 14, 2016
    Date of Patent: February 23, 2021
    Assignee: FGV Cambridge Nanosystems Limited
    Inventors: Catharina Paukner, Lukasz Kurzepa, Krzysztof Kazimierz Koziol
  • Patent number: 10923293
    Abstract: High-frequency supercapacitors that can respond at kilohertz frequencies (AC-supercapacitors). The electrodes of the AC-supercapacitors include edge oriented graphene (EOG) electrodes or carbon nanofiber network (CNN) electrodes. The EOG electrodes are formed by utilizing a plasma and feedstock carbon gas to carbonize cellulous paper and deposit graphene implemented in one step. The CNN electrodes are formed by pyrolyzing a carbon nanofiber network utilizing a plasma.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: February 16, 2021
    Assignee: TEXAS TECH UNIVERSITY SYSTEM
    Inventor: Zhaoyang Fan
  • Patent number: 10920368
    Abstract: A method for coloring a carbon nanotube (CNT) product is provided, including placing a CNT product in an electric circuit to ground the product, charging a plurality of pigment molecules with an opposite charge from the CNT product, applying a coating of the charged pigment molecules to a surface of the CNT product, and exposing the coating to a temperature sufficient to cure the coating, while allowing the coating to form a substantially conformal film on the surface of the CNT product.
    Type: Grant
    Filed: February 23, 2017
    Date of Patent: February 16, 2021
    Assignee: Nanocomp Technologies, Inc.
    Inventors: Peter L. Antoinette, Mark A. Banash, Ashley Hart
  • Patent number: 10910636
    Abstract: A method for making a battery electrode is provided. A carbon nanotube material is provided. The carbon nanotube material is placed into a furnace containing carbon dioxide. The furnace is heated to a temperature about 800° C. to about 950° C., and the carbon nanotube material is oxidized. The oxidized carbon nanotube material is dispersed in a first solution to form a carbon nanotube suspension. An active material is ultrasonically dispersed in a second organic solvent to form an active material dispersion. The carbon nanotube suspension is mixed with the active material dispersion to form a second solution. The second solution is stirred by ultrasonic means and dried after filtering.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: February 2, 2021
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Da-Tao Wang, Ke Wang, Jia-Ping Wang, Shou-Shan Fan
  • Patent number: 10894718
    Abstract: A nanofiber forest is described that has been processed to increase a number of nanofibers per unit area (referred to as “areal density” or, equivalently, “density”) compared to the nanofiber forest in its as-synthesized state. This increase in areal density is accomplished by physically manipulating a deformable substrate on which the nanofiber forest is disposed. At a high level, this physical manipulation begins by transferring the nanofiber forest from a growth substrate to a deformable substrate. A surface area of the deformable substrate is reduced relative to a surface area of the substrate when the nanofiber forest was attached. This reduction in area causes the nanofibers in the forest to move closer to one another, thus increasing the number of nanofibers per unit area.
    Type: Grant
    Filed: April 18, 2018
    Date of Patent: January 19, 2021
    Assignee: LINTEC OF AMERICA, INC.
    Inventor: Chi Huynh
  • Patent number: 10894717
    Abstract: A method for making a carbon nanotube field emitter is provided. A carbon nanotube film is dealed with a carbon nanotube film in a circumstance with a temperature ranged from 1400 to 1800° C. and a pressure ranged from 40 to 60 MPa to form at least one first carbon nanotube structure. The at least one first carbon nanotube structure is heated to graphitize the at least one first carbon nanotube structure to form at least one second carbon nanotube structure. At least two electrodes is welded to fix one end of the at least one second carbon nanotube structure between adjacent two electrodes to form a field emission preparation body. The field emission preparation body has a emission end. The emission end is bonded to form a carbon nanotube field emitter.
    Type: Grant
    Filed: October 23, 2019
    Date of Patent: January 19, 2021
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Peng Liu, Duan-Liang Zhou, Chun-Hai Zhang, Li Qian, Yu-Quan Wang, Xue-Wei Guo, Li-Yong Ma, Fu-Jun Wang, Shou-Shan Fan
  • Patent number: 10830094
    Abstract: A graphene heat pipe for a gas turbine engine includes a body of graphene. The body has a hot side to accept heat from the gas turbine engine, a cold side to reject heat from the body, and an adiabatic portion to flow heat within the body between the hot side and the cold side.
    Type: Grant
    Filed: September 28, 2016
    Date of Patent: November 10, 2020
    Assignee: RAYTHEON TECHNOLOGIES CORPORATION
    Inventors: Matthew P. Forcier, Joseph B. Staubach
  • Patent number: 10799390
    Abstract: An energy harvesting, heat managing, multi-effect therapeutic garment, defining an inner surface and an outer surface, seamlessly knitted using a predetermined number of yarns is provided. The yarns for constructing the therapeutic garment are selected from a yarn that absorbs, stores, and releases heat energy through a phase change, yarns that convert heat energy and ultra violet radiation energy into far infrared radiation energy and radiate the far infrared radiation energy to other yarns and to a wearer's body part, a yarn that adsorbs moisture from the wearer's body part and/or ambient environment and generates heat energy through an exothermic reaction, a heat insulting and hydrophobic yarn, and a heat conductive yarn that maintains a uniform temperature within the yarns. The yarns of the therapeutic garment are bundled and knitted to create a uniform surface area distribution of the yarns that contact each other and cover the wearer's body part.
    Type: Grant
    Filed: August 2, 2016
    Date of Patent: October 13, 2020
    Assignee: New York Knitworks, LLC
    Inventors: Sidney Samuel Estreicher, Gabor Stein, George Joseph Szekely, Herbert Stevan Quinn
  • Patent number: 10777367
    Abstract: A fibrous electrode includes a carbon nanotube sheet which is coated on an elastic fiber and has a buckle structure. Thus, the fibrous electrode may maintain a fiber shape, may be light and small and may maintain excellent conductivity even when variously deformed. In addition, the fibrous electrode has high elasticity and thus is capable of being variously deformed (e.g., bent or stretched) and of being realized in the form of textile. As a result, the fibrous electrode may be effectively applied to flexible electronic devices such as implantable medical devices, microelectronic devices, Google glasses, smart watches, wearable computers, and smart clothing. Furthermore, a supercapacitor using the fibrous electrode includes flexible materials and thus is not easily damaged by external force such as tension or pressure. As a result, the supercapacitor may be applied to various fields because of its excellent flexibility.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: September 15, 2020
    Assignee: IUCF-HYU (INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY)
    Inventors: Seon Jeong Kim, Chang Soon Choi, Kang Min Kim
  • Patent number: 10714293
    Abstract: A carbon nanotube fiber carpet structure includes a backing material; and a plurality looped carbon nanotube (CNT) fiber conductors fixed to the backing material extending outward from the backing material in an array. The CNT fiber conductor may include at least one of a CNT thread, a CNT fiber, a CNT film, and a CNT ribbon, and the CNT fiber conductor may include a first end and a second end, the first end fixed to the backing material, and the second end fixed to the backing material a predetermined distance from the first end in order to form a loop of the CNT fiber conductor extending away from a backing material surface. The CNT fiber conductor may be woven into the backing material to form a plurality of loops of the CNT fiber conductor extending away from a backing surface material, and the backing material may be a conductive material.
    Type: Grant
    Filed: October 17, 2019
    Date of Patent: July 14, 2020
    Inventor: Steven B Fairchild
  • Patent number: 10700361
    Abstract: A nanofibrous catalyst and method of manufacture. A precursor solution of a transition metal based material is formed into a plurality of interconnected nanofibers by electro-spinning the precursor solution with the nanofibers converted to a catalytically active material by a heat treatment. Selected subsequent treatments can enhance catalytic activity.
    Type: Grant
    Filed: May 2, 2016
    Date of Patent: June 30, 2020
    Assignee: UChicago Argonne, LLC
    Inventors: Di-Jia Liu, Jianglan Shui, Chen Chen
  • Patent number: 10689258
    Abstract: A method for making a carbon nanotube array includes providing a substrate having a first substrate surface and a second substrate surface opposite to the first substrate surface. The substrate has a plurality of through holes spaced from each other, and each of the plurality of through holes extends from the first substrate surface to the second substrate surface. A catalyst layer is deposited on the first substrate surface, to form a composite structure. The composite structure is placed in a chamber. The carbon source gas and protective gas are supplied to the chamber, and the composite structure is heated to a first temperature, to grow a carbon nanotube array on the first substrate surface.
    Type: Grant
    Filed: May 29, 2018
    Date of Patent: June 23, 2020
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Liang Liu, Qi Cai, Qiu-Qiu Zheng
  • Patent number: 10689755
    Abstract: A process for synthesizing a biphasic material, the biphasic material comprising at least one mesoporous substrate surrounded with carbon nanotubes, the process comprising step (a) of providing a catalyst on the at least one mesoporous substrate, the catalyst being configured to favour the growth of the carbon nanotubes, and the process comprising step (b) of performing the growth of the carbon nanotubes. The synthesis process is remarkable in that the two steps (a) and (b) are performed in a one-pot synthesis.
    Type: Grant
    Filed: June 21, 2016
    Date of Patent: June 23, 2020
    Assignee: LUXEMBOURG INSTITUTE OF SCIENCE AND TECHNOLOGY (LIST)
    Inventors: Didier Arl, Damien Lenoble, Mouhamadou Moustapha Sarr, Noureddine Adjeroud