Iron (fe) Containing Patents (Class 423/594.1)
  • Patent number: 7803348
    Abstract: Oxygen is reduced in the presence of a catalyst at the cathode of an alkaline-electrolyte fuel cell. Catalysts of the formula Sr3?xA1+xCo4?yByO10.5?z wherein ?0.6?x?1.0; 0?y?3; and ?1.5?z?0.5; wherein A represents Eu, Gd, Tb, Dy, Ho, or Y; and wherein B represents Fe, Ga, Cu, Ni, Mn, and Cr, demonstrate high catalytic activity and high chemical stability when used as the oxygen-reduction catalyst in alkaline fuel cells.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: September 28, 2010
    Assignee: Horizon Fuel Cells, LLC
    Inventors: Evgeny V. Antipov, Galina A. Tsirlina, Sergey Y. Istomin, Oleg A. Drozhzhin, Eduard E. Levin
  • Patent number: 7799459
    Abstract: A compound for use as active material of a positive electrode of a lithium-ion cell. This compound has an average discharge voltage above 4.5V in relation to the Li+/Li couple of approximately 4.7V. The compound includes: a) a spinel-type crystalline phase of formula LiaNiII0.5?xMnIII2xMnIV1.5?x?yMyO4 in which elements Ti and Al, or a mixture of these; 0.8<a<1.3; 0<x?0.15; 0<y?0.15; b) a cubic crystalline phase of formula Li1?tNi1+tO in which 0?t?1; and c) a rhomboedric crystalline phase of formula Li1?ZNi1+zO2 in which 0?z?1.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: September 21, 2010
    Assignee: Saft Groupe SA
    Inventors: Jean-Paul Peres, Stephane Gillot, Frederic Chouquais, Claudette Audry, Andre Lecerf
  • Patent number: 7799232
    Abstract: A reducing water purification material having a reducing iron-based precipitate selected from green rust, iron ferrite, reducing iron hydroxide, and a mixture thereof. A wastewater treatment process having steps of adding a reducing iron compound to wastewater, leading the wastewater to which the reducing iron compound is added to a reaction tank and forming a precipitate, separating the formed precipitate by a solid-liquid separation to obtain a sludge, and alkalinizing all or a portion of the separated sludge to form an alkaline sludge followed by returning to the reaction tank, wherein in the precipitation step, the wastewater to which the reducing iron compound is added and the alkaline sludge are mixed and are allowed to react in a non-oxidizing atmosphere under alkaline condition to form a reducing iron compound precipitate as the precipitate, thereby incorporating contaminants in the precipitate to remove the contaminants from the wastewater.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: September 21, 2010
    Assignee: Mitsubishi Materials Corporation
    Inventors: Hiroshi Hayashi, Hitoshi Takeuchi, Hajime Negishi, Shigeyuki Tsuzaki, Yoshio Aikawa, Ayako Mimoto, Shintaro Nakaya
  • Publication number: 20100208412
    Abstract: Provided are a ferroelectric material having good ferroelectricity and good insulation property, and a ferroelectric device using the ferroelectric material. In the present invention, the ferroelectric material includes a metal oxide having a perovskite-type crystal structure, in which: the metal oxide contains bismuth ferrite whose iron is substituted by manganese, and at least one of a copper oxide and a nickel oxide; the bismuth ferrite is substituted by manganese at a substitution ratio of 0.5 at. % or more to 20 at. % or less with respect to a total amount of iron and manganese; and at least one of the copper oxide and the nickel oxide is added in an amount of 0.5 mol % or more to 20 mol % or less with respect to the bismuth ferrite whose iron is substituted by manganese.
    Type: Application
    Filed: February 4, 2010
    Publication date: August 19, 2010
    Applicants: CANON KABUSHIKI KAISHA, TOKYO UNIVERSITY OF SCIENCE EDUCATIONAL FOUNDATION ADMINISTRATIVE ORGANIZATION
    Inventors: Kenji Takashima, Makoto Kubota, Soichiro Okamura, Takashi Nakajima, Tomosato Okubo, Yosuke Inoue
  • Patent number: 7759007
    Abstract: A lithium ion secondary battery is provided. The battery includes a positive electrode having at least a cathode active material and a binder, a negative electrode, an electrolyte, and a separator which are arranged between the positive electrode and the negative electrode, and in which an open circuit voltage per unit cell in a full charging state lies within (4.25V?voltage?6.00V). The cathode active material includes either a lithium-cobalt composite oxide expressed by a general formula: LiaCo1-xMexO2-b (Me denotes metal elements of at least one, two or more kinds selected from V, Cu, Zr, Zn, Mg, Al, and Fe; 0.9?a?1.1; 0?x=0.3; and ?0.1?b?0.1) or a lithium-cobalt-nickel-manganese oxide expressed by a general formula: LiaNi1-x-y-zCoxMnyMezO2-b (0.9?a?1.1; 0<x<0.4; 0<y<0.4; 0<z<0.3; and ?0.1?b?0.1). The binder includes a polyacrylonitrile resin.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: July 20, 2010
    Assignee: Sony Corporation
    Inventors: Takashi Tokunaga, Yoshiaki Obana, Hiroyuki Akashi
  • Patent number: 7754099
    Abstract: A reducing water purification material having a reducing iron-based precipitate selected from green rust, iron ferrite, reducing iron hydroxide, and a mixture thereof. A wastewater treatment process having steps of adding a reducing iron compound to wastewater, leading the wastewater to which the reducing iron compound is added to a reaction tank and forming a precipitate, separating the formed precipitate by a solid-liquid separation to obtain a sludge, and alkalinizing all or a portion of the separated sludge to form an alkaline sludge followed by returning to the reaction tank, wherein in the precipitation step, the wastewater to which the reducing iron compound is added and the alkaline sludge are mixed and are allowed to react in a non-oxidizing atmosphere under alkaline condition to form a reducing iron compound precipitate as the precipitate, thereby incorporating contaminants in the precipitate to remove the contaminants from the wastewater.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: July 13, 2010
    Assignee: Mitsubishi Materials Corporation
    Inventors: Hiroshi Hayashi, Hitoshi Takeuchi, Hajime Negishi, Shigeyuki Tsuzaki, Yoshio Aikawa, Ayako Mimoto, Shintaro Nakaya
  • Patent number: 7749321
    Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: July 6, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jerome D. Smith, Pedro A. Jimenez, Tony Jackson
  • Patent number: 7741396
    Abstract: Disclosed herein is a composition comprising a polymeric material; and non-linear dielectric ceramic fillers; wherein the non-linear dielectric ceramic fillers have a dielectric constant that is greater than or equal to about 100 and wherein the dielectric constant of the composition is tunable. Disclosed herein too is a composition comprising a polymeric material; and perovskites; wherein the dielectric constant of a composition is tunable and further wherein the composition has a dielectric constant of about 2 to about 100. Disclosed herein too is a method comprising blending a polymeric resin with non-linear dielectric ceramic fillers to form a composition; wherein the non-linear dielectric ceramic fillers have a dielectric constant of greater than or equal to about 100 and wherein the dielectric constant of the composition is tunable.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: June 22, 2010
    Assignee: General Electric Company
    Inventors: Qi Tan, Patricia Chapman Irwin
  • Publication number: 20100135937
    Abstract: Nanocrystalline forms of metal oxides, including binary metal oxide, perovskite type metal oxides, and complex metal oxides, including doped metal oxides, are provided. Methods of preparation of the nanocrystals are also provided. The nanocrystals, including uncapped and uncoated metal oxide nanocrystals, can be dispersed in a liquid to provide dispersions that are stable and do not precipitate over a period of time ranging from hours to months. Methods of preparation of the dispersions, and methods of use of the dispersions in forming films, are likewise provided. The films can include an organic, inorganic, or mixed organic/inorganic matrix. The films can be substantially free of all organic materials. The films can be used as coatings, or can be used as dielectric layers in a variety of electronics applications, for example as a dielectric material for an ultracapacitor, which can include a mesoporous material. Or the films can be used as a high-K dielectric in organic field-effect transistors.
    Type: Application
    Filed: September 24, 2009
    Publication date: June 3, 2010
    Applicant: The Trustees of Columbia University in the City of New York
    Inventors: Stephen O'Brien, Limin Huang, Zhuoying Chen, Ioannis Kymissis, Zhang Jia
  • Patent number: 7722848
    Abstract: Lithium iron phosphate cathode materials for lithium secondary batteries and methods of preparation thereof are disclosed. Better cathode materials may be produced by multiple annealing and/or heating steps. The annealing step can be carried out before and/or after the heating steps to provide cathode materials, which exhibit superior electrical properties. In some instances, divalent iron compounds are incorporated as starting materials.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: May 25, 2010
    Assignee: BYD Company Limited
    Inventors: Quan Dai, Julin Shen
  • Publication number: 20100119429
    Abstract: Methods of preparing metal oxide nanoparticles are described. The methods involve the thermal decomposition of a metal-carboxylate complex within a continuous, flow-through, tubular reactor. The resulting metal oxide nanoparticles contain iron and can be magnetic, non-agglomerated, crystalline or a combination thereof.
    Type: Application
    Filed: February 28, 2007
    Publication date: May 13, 2010
    Inventors: Sarah M. Mullins, Grant F. Tiefenbruck, Danny B. Anderson
  • Publication number: 20100111803
    Abstract: Disclosed herein is a spinel article. The article comprises a spinel material, wherein the spinel material has a monomodal grain size distribution with average grain sizes of less than or equal to about 15 micrometers, and a biaxial flexural strength of greater than or equal to about 300 megapascals when measured by a ring-on-ring flexural test as per ASTM Standard C1499-08. Disclosed herein too is a spinel article manufactured by a method comprising calcining a spinel powder; milling the powder in a milling medium; granulating the powder; screening the powder to a mesh size of about 40 to about 200 mesh; pressing the powder to form an article; burning out organics from the article; sintering the article; and hot isostatically pressing the article.
    Type: Application
    Filed: November 6, 2008
    Publication date: May 6, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Milivoj Konstantin Brun, Anteneh Kebbede, Sean Michael Sweeney, Timothy James Yosenick
  • Patent number: 7695698
    Abstract: A method of producing an iron-arsenic compound by adding an oxidizing agent to an aqueous solution containing arsenic ions and bivalent iron ions and allowing an iron-arsenic compound precipitation reaction to proceed under stirring of the solution, wherein the precipitation reaction is terminated at a solution pH in the range of 0 to 1. When the arsenic concentration of the pre-reaction solution is 25 g/L or greater, the reaction can be terminated at a solution pH in the range of ?0.45 to 1.2. The pH of the pre-reaction solution is preferably greater than 0 and not greater than 2.0. A ferrous sulfate is can be used as the source of the bivalent iron ions. Even when some amount of impurity elements is present in the arsenic-containing solution, the method is nevertheless capable of forming a scorodite compound excellent in crystallinity in the form of a compact compound barely swollen by moisture and the like, i.e., a niron-arsenic compound excellent in filterability.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: April 13, 2010
    Assignee: Dowa Metals & Mining Co., Ltd.
    Inventors: Tetsuo Fujita, Ryoichi Taguchi
  • Patent number: 7691352
    Abstract: A new set of additives to be sued in the preparation of inorganic materials; especially of perovskite nature is proposed. The chemical compositions of the perovskites prepared in the presence of the mentioned additives are found to be more homogenous, leading to better catalytic behavior, including higher selectivity and yields as compared to catalysts of identical formulations prepared through the conventional method of using EDTA/citrate (or other organic additive) method.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: April 6, 2010
    Assignee: Research Institute of Petroleum Industry (RIPI)
    Inventors: Khodadad Nazari, Zahra Taheri, Naser Seyed Matin, Reza Ahmadi, Saeed Zarrinpashneh, Morteza Rezapour
  • Patent number: 7666526
    Abstract: Non-volatile resistance-switching oxide films, and devices therewith, are disclosed. One embodiment of a suitable device is composed of a SRO-CZO thin film having a thickness of from about 6 to about 30 nm, and composed of from about 3 to about 10 molar % of a SrRuO3 conducting oxide dopant and from about 90 to about 97 molar % of a CaZrO3 insulating oxide material.
    Type: Grant
    Filed: April 26, 2007
    Date of Patent: February 23, 2010
    Assignee: The Trustees of the University of Pennsylvania
    Inventors: I-Wei Chen, Yudi Wang, Soo Gil Kim
  • Publication number: 20100040531
    Abstract: A non-lead composition for use as a thick-film resistor paste in electronic applications. The composition comprises particles of Li2RuO3 of diameter between 0.5 and 5 microns and a lead-free frit. The particles have had the lithium at or near primarily the surface of the particle at least partially exchanged for atoms of other metals.
    Type: Application
    Filed: October 23, 2009
    Publication date: February 18, 2010
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: PAUL DOUGLAS VERNOOY, ALFRED T. WALKER, KENNETH WARREN HANG
  • Publication number: 20100028674
    Abstract: Nanofibers and methods for making the nanofibers are described. Porous metal oxide nanofibers and porous metal oxide nanofibers comprising metal nanoparticles made via electrospinning methods are also described.
    Type: Application
    Filed: July 31, 2008
    Publication date: February 4, 2010
    Inventor: Fredrick O Ochanda
  • Publication number: 20100015446
    Abstract: The present invention relates to a process for the preparation of nanocrystalline mixed metal oxide particles from at least two different starting compounds, comprising the steps of a) introducing a stoichiometric mixture of the starting compounds into a reaction chamber by means of a carrier fluid, b) subjecting the starting compound to a pulsating thermal treatment in a treatment zone under a pulse in the reaction chamber, c) formation of nanocrystalline mixed metal oxide particles, d) the removal from the reactor of the nanocrystalline mixed metal oxide particles obtained in steps b) and c), wherein the stoichiometric mixture of the starting compounds takes place at a temperature of >50° C. Further, the present invention relates to a nanocrystalline mixed metal oxide, in particular for use as a catalyst, obtainable by the process according to the invention.
    Type: Application
    Filed: September 7, 2007
    Publication date: January 21, 2010
    Applicant: SÜD-CHEMIE AG
    Inventor: Hans Jörg Wölk
  • Patent number: 7645907
    Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: January 12, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Patent number: 7632477
    Abstract: This invention relates to a process for preparing zirconium oxide, in its various forms, including zirconium-based mixed oxides. There is described a process for preparing a zirconium oxide in the absence of a cerium salt which comprises precipitating a zirconium hydroxide from an aqueous solution of a zirconium salt by reaction with an alkali in the presence of a controlled amount of sulphate anions at a temperature not greater than 50° C. and then calcining the hydroxide to form an oxide, wherein the oxide thus formed is essentially sulphate free. Catalysts and ceramics can be produced from the product oxides having improved thermal stability and improved sinterability, respectively. A particular use of the product oxide is as a promoter or catalyst support in automobile exhaust systems.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: December 15, 2009
    Assignee: Magnesium Elektron, Ltd.
    Inventors: Yasuhide Takao, Colin Norman, Gavin Edwards, Ian Chisem, Clare Jones
  • Patent number: 7605110
    Abstract: A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.
    Type: Grant
    Filed: April 5, 2007
    Date of Patent: October 20, 2009
    Assignees: Denso Corporation, Nippon Soken, Inc.
    Inventors: Keiichi Yamada, Kazuhiko Koike, Katsumi Yoshida, Hideki Kita, Naoki Kondo, Hideki Hyuga
  • Patent number: 7604789
    Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: October 20, 2009
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Kohei Yoshida, Akio Koyama
  • Patent number: 7601325
    Abstract: To provide a perovskite-type composite oxide which has stable quality in which a solid solution of Pd is formed at a high rate, a method for producing the perovskite-type composite oxide, and a catalyst composition containing the perovskite-type composite oxide, the perovskite-type composite oxide is produced by formulating materials in accordance with each atomic ratio of a perovskite-type composite oxide represented by the following general formula (1): AxB(1-y)PdyO3+???(1) wherein A represents at least one element selected from rare earth elements and alkaline earth metals; B represents at least one element selected from transition elements (excluding rare earth elements, and Pd), Al and Si; x represents an atomic ratio satisfying the following condition: 1<x; y represents an atomic ratio satisfying the following condition: 0<y?0.5; and ? represents an oxygen excess.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: October 13, 2009
    Assignees: Daihatsu Motor Co., Ltd., Hokko Chemical Industry Co., Ltd., Cataler Corporation
    Inventors: Hirohisa Tanaka, Isao Tan, Mari Uenishi, Nobuhiko Kajita, Masashi Taniguchi, Kimiyoshi Kaneko, Senshu Mitachi, Mareo Kimura, Keiichi Narita, Noboru Sato
  • Patent number: 7585474
    Abstract: A single crystalline ternary nanostructure having the formula AxByOz, wherein x ranges from 0.25 to 24, and y ranges from 1.5 to 40, and wherein A and B are independently selected from the group consisting of Ag, Al, As, Au, B, Ba, Br, Ca, Cd, Ce, Cl, Cm, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Ho, I, In, Ir, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Tc, Te, Ti, Tl, Tm, U, V, W, Y, Yb, and Zn, wherein the nanostructure is at least 95% free of defects and/or dislocations.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: September 8, 2009
    Assignee: The Research Foundation of State University of New York
    Inventors: Stanislaus S. Wong, Tae-Jin Park
  • Patent number: 7575735
    Abstract: The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: August 18, 2009
    Assignee: The Research Foundation of State University of New York
    Inventors: Stanislaus S. Wong, Yuanbing Mao
  • Publication number: 20090196818
    Abstract: A multiferroic element having a simple structure in which orientation of electric polarization or magnetization of a solid state material can be controlled by applying a magnetic field or an electric field, respectively. By applying an external magnetic field to a multiferroic solid state material that exhibits ferroelectricity and ferromagnetism having a spin structure such that the orientation of spin is rotating along the outside surface of a cone (apex angle ? at the top of the cone is in a range of 0<??90 degrees), an electric polarization with orientation substantially perpendicular to the direction of the externally applied magnetic field can be controlled. Meanwhile, by applying an external electric field to the multiferroic solid state material, a magnetization with an orientation substantially perpendicular to the direction of the externally applied electric field can be controlled.
    Type: Application
    Filed: April 12, 2007
    Publication date: August 6, 2009
    Applicant: JAPAN SCIENCE AND TECHNOLOGYAGENCY
    Inventors: Yoshinori Tokura, Takahisa Arima, Yoshio Kaneko
  • Publication number: 20090192032
    Abstract: Disclosed herein is a light-responsive photocatalyst composition, which is a composite oxide semiconductor containing tungsten, and which can efficiently absorb visible light emitted from the sun and light emitted from interior lamps, such as fluorescent lamps, etc., and a method of preparing the light-responsive photocatalyst composition. The visible light-responsive photocatalyst composition can decompose volatile organic compounds or harmful organic matter causing sick house syndrome, even indoors, because it can be activated by visible light outdoors and can respond to light emitted from interior lamps, such as fluorescent lamps, etc.
    Type: Application
    Filed: March 26, 2008
    Publication date: July 30, 2009
    Applicant: Seoul National University Industry Foundation
    Inventors: In Sun Cho, Sang Wook Lee, Jun Hong Noh, Shin Tae Bae, Dong Wook Kim, Chin Moo Cho, Chae Hyun Kwak, Tae Hoon Noh, Duk Kyu Lee, Kug Sun Hong
  • Patent number: 7553474
    Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: June 30, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
  • Patent number: 7550098
    Abstract: Active materials of the invention contain at least one alkali metal and at least one other metal capable of being oxidized to a higher oxidation state. Preferred other metals are accordingly selected from the group consisting of transition metals (defined as Groups 4-11 of the periodic table), as well as certain other non-transition metals such as tin, bismuth, and lead. The active materials may be synthesized in single step reactions or in multi-step reactions. In at least one of the steps of the synthesis reaction, reducing carbon is used as a starting material. In one aspect, the reducing carbon is provided by elemental carbon, preferably in particulate form such as graphites, amorphous carbon, carbon blacks and the like. In another aspect, reducing carbon may also be provided by an organic precursor material, or by a mixture of elemental carbon and organic precursor material.
    Type: Grant
    Filed: July 27, 2005
    Date of Patent: June 23, 2009
    Assignee: Valence Technology, Inc.
    Inventors: Jerry Barker, Yazid Saidi, Ming Dong, Jeffrey Swoyer
  • Patent number: 7547400
    Abstract: A method for making monodispersed magnetic nanoparticles of nickel zinc ferrite (NZFO) at room temperature by mixing together two micelle solutions. The first micelle solution comprises zinc, nickel, and iron metal salts; a surfactant; and a hydrocarbon. The second micelle solution comprises an aqueous hydroxide, a surfactant, and a hydrocarbon. After mixing the two micelle solutions, the ferrite precipitates.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: June 16, 2009
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Everett E. Carpenter, Vincent G. Harris, Shannon A. Morrison
  • Patent number: 7534528
    Abstract: An electrode material for an anode of a rechargeable lithium battery, containing a particulate comprising an amorphous Sn.A.X alloy with a substantially non-stoichiometric ratio composition. For said formula Sn.A.X , A indicates at least one kind of an element selected from a group consisting of transition metal elements, X indicates at least one kind of an element selected from a group consisting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Pb, Bi, Sb, Al, Ga, In, Tl, Zn, Be, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, As, Se, Te, Li and S, where the element X is not always necessary to be contained. The content of the constituent element Sn of the amorphous Sn.A.X alloy is Sn/(Sn+A+X)=20 to 80 atomic %.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: May 19, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Soichiro Kawakami, Masaya Asao
  • Publication number: 20090104107
    Abstract: A method of making scorodite includes the following steps: (1) an acidic aqueous solution containing pentavalent As and trivalent Fe is heated at a temperature for a time, the temperature and the time being effective for synthesis of crystalline scorodite; (2) the synthesized scorodite is separated from the post-reaction solution by solid-liquid separation; and (3) the scorodite is washed with water and is separated from the washing solution by solid-liquid separation. Step (3) is repeated until the concentration of at least one component of the post-reaction solution contained in the washing solution used for washing the scorodite decreases to a predetermined level.
    Type: Application
    Filed: June 4, 2008
    Publication date: April 23, 2009
    Applicant: NIPPON MINING & METALS CO., LTD.
    Inventors: Yukio Kimura, Shigeo Katsura
  • Publication number: 20090087658
    Abstract: A method for manufacturing ferrite powder comprises a step (a) of causing a precursor, obtained by a liquid-phase reaction method, to pass through a sieve with openings of 2 mm or less, and a step (b) of causing free fall, through the interior of a furnace tube heated to the range 750 to 1250° C. by a heater, of the precursor which has passed through the sieve. In the process of causing free fall through the interior of the furnace tube heated by the heater, ferrite powder, which is a single phase of hexagonal ferrite, is obtained by heating the precursor to a prescribed temperature and holding the precursor at the prescribed temperature.
    Type: Application
    Filed: September 25, 2008
    Publication date: April 2, 2009
    Applicant: TDK CORPORATION
    Inventor: Mamoru SATOH
  • Patent number: 7510693
    Abstract: Process for the production of a metal oxide powder having a BET surface area of at least 20 m2/g by reacting an aerosol with oxygen in a reaction space at a reaction temperature of more than 700° C. and then separating the resulting powder from gaseous substances in the reaction space, wherein the aerosol is obtained by atomisation using a multi-component nozzle of at least one starting material, as such in liquid form or in solution, and at least one atomising gas, the volume-related mean drop diameter D30 of the aerosol is from 30 to 100 ?m and the number of aerosol drops larger than 100 ?m is up to 10%, based on the total number of drops, and metal oxide powder obtainable by this process.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: March 31, 2009
    Assignee: Degussa AG
    Inventors: Stipan Katusic, Michael Kraemer, Michael Kroell, Peter Kress, Edwin Staab
  • Publication number: 20090078584
    Abstract: The present invention is to provide a process for producing a scorodite that can shorten the time required for synthesizing the scorodite, and further can improve the yield of arsenic and iron into the scorodite. Accordingly, a process for producing a crystalline scorodite from an acidic aqueous solution containing pentavalent As and trivalent Fe, wherein the synthesis of the crystalline scorodite is performed after the molar ratio of trivalent Fe to pentavalent As contained in the acidic aqueous solution is adjusted to be equal to or more than 0.9 and equal to or less than 1.1 is provided.
    Type: Application
    Filed: June 4, 2008
    Publication date: March 26, 2009
    Applicant: NIPPON MINING & METALS CO., LTD.
    Inventors: Yukio Kimura, Shigeo Katsura
  • Patent number: 7488464
    Abstract: Methods and systems for processing metal oxides from metal containing solutions. Metal containing solutions are mixed with heated aqueous oxidizing solutions and processed in a continuous process reactor or batch processing system. Combinations of temperature, pressure, molarity, Eh value, and pH value of the mixed solution are monitored and adjusted so as to maintain solution conditions within a desired stability area during processing. This results in metal oxides having high or increased pollutant loading capacities and/or oxidation states. These metal oxides may be processed according to the invention to produce co-precipitated oxides of two or more metals, metal oxides incorporating foreign cations, metal oxides precipitated on active and inactive substrates, or combinations of any or all of these forms.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: February 10, 2009
    Assignee: EnviroScrub Technologies Corporation
    Inventors: Charles F. Hammel, Richard M. Boren
  • Patent number: 7482382
    Abstract: The present invention is directed to novel sol-gel methods in which metal oxide precursor and an alcohol-based solution are mixed to form a reaction mixture that is then allowed to react to produce nanosized metal oxide particles. The methods of the present invention are more suitable for preparing nanosized metal oxide than are previously-described sol-gel methods. The present invention can provide for nanosized metal oxide particles more efficiently than the previously-described sol-gel methods by permitting higher concentrations of metal oxide precursor to be employed in the reaction mixture. The foregoing is provided by careful control of the pH conditions during synthesis and by ensuring that the pH is maintained at a value of about 7 or higher.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: January 27, 2009
    Assignees: The Texas A&M University System, Kaneka Corporation
    Inventors: Yuntao Li, Hung-Jue Sue, Riichi Nishimura, Nobuo Miyatake
  • Publication number: 20090023972
    Abstract: Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.
    Type: Application
    Filed: June 27, 2008
    Publication date: January 22, 2009
    Inventors: Helge Jaensch, Wilfried J. Mortier
  • Patent number: 7476467
    Abstract: The present invention provides a non-aqueous electrolyte-based high power lithium secondary battery having a long-term service life and superior safety at both room temperature and high temperature, even after repeated high-current charging and discharging, wherein the battery comprises a mixture of a particular lithium manganese-metal composite oxide (A) having a spinel structure and a particular lithium nickel-manganese-cobalt composite oxide (B) having a layered structure, as a cathode active material.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: January 13, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Hey Woong Park, Ji-Sang Yu, Sung-Woo Kim, Min Su Kim
  • Patent number: 7476376
    Abstract: Disclosed is metal composite oxides having the new crystal structure. Also disclosed are ionic conductors including the metal composite oxides and electrochemical devices comprising the ionic conductors. The metal composite oxides have an ion channel formed for easy movement of ions due to crystallographic specificity resulting from the ordering of metal ion sites and metal ion defects within the unit cell. Therefore, the metal composite oxides according to the present invention are useful in an electrochemical device requiring an ionic conductor or ionic conductivity.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: January 13, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Seung Tae Hong, Yun Ho Roh, Eung Je Lee, Mi Hyae Park
  • Publication number: 20080242815
    Abstract: The invention provides a process which enables, in preparation of acrolein by catalytic gas-phase oxidation of propylene in the presence of molecular oxygen or a molecular oxygen-containing gas or in preparation of acrylic acid by catalytic gas-phase oxidation of acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas, using single kind of atalyst, to suppress occurrence of localized extraordinarily high temperature spots (hot spots) in the catalyst layer and can stably maintain high acrolein or acrylic acid yield for a long time. The process is characterized by use of an oxide catalyst containing molybdenum as an essential component and having relative standard deviation of its particle size in a range of 0.02 to 0.20.
    Type: Application
    Filed: March 28, 2008
    Publication date: October 2, 2008
    Inventor: Naohiro Fukumoto
  • Publication number: 20080233033
    Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Publication number: 20080206125
    Abstract: The present invention relates to a catalyst system for the selective conversion of hydrocarbons into multi-walled carbon nanotubes and hydrogen comprising a compound of the formula: (Ni,Co)FeyOz(Al2O3)w wherein ‘y’ represents the molar fraction of Fe relative to Co and Ni and wherein 0.11?y?9.0, 1.12?z?14.5, and 1.
    Type: Application
    Filed: August 25, 2006
    Publication date: August 28, 2008
    Applicant: Nanocyl S.A.
    Inventors: Ricardo Prada Silvy, Christophe Pirlot, Benedicte Culot
  • Publication number: 20080163994
    Abstract: The present invention relates to a security feature for security papers, value documents and the like having an acid-labile feature substance as the core and a shell consisting substantially of metal oxide, the security feature exhibiting greater stability against the action of acids compared with the acid-labile feature substance.
    Type: Application
    Filed: December 15, 2005
    Publication date: July 10, 2008
    Inventors: Rainer Hoppe, Thomas Giering
  • Patent number: 7381394
    Abstract: Methods of producing a safe and hygienic method for industrially and efficiently producing a perovskite-type composite oxide are provided that can maintain the catalytic activity of a noble metal at a high level. Methods include preparing a precursor of the perovskite-type composite oxide by mixing organometal salts of elementary components of the perovskite-type composite oxide and heat treating the precursor. The precursor may be prepared by mixing all elementary components constituting the perovskite-type composite oxide, or by mixing one or more organometal salts of part of the elementary components with the other elementary components prepared as alkoxides, a coprecipitate of salts, or a citrate complex of the respective elements.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: June 3, 2008
    Assignees: Daihatsu Motor Co., Ltd., Hokko Chemical Industry Co. Ltd.
    Inventors: Hirohisa Tanaka, Kimiyoshi Kaneko
  • Publication number: 20080124265
    Abstract: An anode in a Direct Carbon Fuel Cell (DCFC) operating in a temperature range between 500 and 1200 degrees Celsius is provided. The anode material has high catalytic activity and selectivity for carbon oxidation, sufficient oxygen non-stoichiometry, rapid oxygen chemical diffusion, wide thermodynamic stability window to withstand reducing environment, sufficient electronic conductivity and tolerance to sulfur and CO2 environments. The anode has doped ruthenate compositions A1?xA?xRuO3, AB1?yRuyO3, or A1?xA?xB1?yRuyO3. A and A? may be divalent, trivalent, or tetravalent cation, and B is a multivalent cation. A is among lanthanide series elements La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er or Yb, and dopant A? is from Group IIA, IIIB, or IVB elements. The doped ruthenates can also be a (AB1?yRuyO3) structure or an ordered Ruddlesden-Popper series ((A1?xAx?)n+1(B1?yRuy)nO3n+1) structure where n=1 or 2. The dopant B is among Group IVB, VB, VIB, VIII, IB, and IIB elements.
    Type: Application
    Filed: October 16, 2007
    Publication date: May 29, 2008
    Inventor: Turgut M. Gur
  • Publication number: 20080121584
    Abstract: Methods of making unique water treatment compositions are provided. In one embodiment, a method of making a doped metal oxide or hydroxide for treating water comprises: disposing a metal precursor solution and a dopant precursor solution in a reaction vessel comprising water to form a slurry; and precipitating the doped metal oxide or hydroxide from the slurry.
    Type: Application
    Filed: June 14, 2007
    Publication date: May 29, 2008
    Applicants: INFRAMAT CORPORATION, UNIVERSITY OF HOUSTON
    Inventors: Huimin Chen, Dennis A. Clifford
  • Patent number: 7368095
    Abstract: The present invention provides a composite oxide for a high performance solid oxide fuel cell which can be fired at a relatively low temperature, and which has little heterogeneous phases of impurities other than the desired composition. The composite oxide is the one having a perovskite type crystal structure containing rare earth elements, and having constituent elements homogeneously dispersed therein. A homogeneous composite oxide having an abundance ratio of heterogeneous phases of at most 0.3% by average area ratio, and a melting point of at least 1470° C., is obtained by using metal carbonates, oxides or hydroxides, and reacting them with citric acid in an aqueous system.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: May 6, 2008
    Assignee: Seimi Chemical Co., Ltd.
    Inventors: Fumio Munakata, Kenji Furuya, Masaharu Hatano, Yoshinori Fujie, Manabu Suhara
  • Patent number: 7357910
    Abstract: Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: April 15, 2008
    Assignee: Los Alamos National Security, LLC
    Inventors: Jonathan Phillips, Daniel Mendoza, Chun-Ku Chen
  • Patent number: 7354565
    Abstract: The present invention discloses a relaxor material lead iron tungstate which has been synthesized in doped and undoped conditions by single and two step heat treatment. The relaxor material is seen to exhibit almost negligible hysteresis and a transducer made thereby shows pressure measurement capability over a wide range from 0.5 MPa to 415 MPa with accuracy of ±0.05%.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: April 8, 2008
    Assignees: Council of Scientific & Industrial Research, Indian Institute of Technology - Delhi
    Inventors: Kamlesh Kumar Jain, Vinay Kumar, Subhash Chand Kashyap