Abstract: The manufacturing method of titanium dioxide solution includes: mixing choline chloride, urea, boric acid, and titanium tetrachloride to form a first solution, wherein a molar concentration ratio of choline chloride to urea is 1:2, a molar concentration of titanium tetrachloride is 0.2 M to 0.4 M, and weight/volume of boric acid is 5 g/300 ml to 15 g/300 ml; and heating the first solute ion to form a second solution, wherein the second solution contains carbon/nitrogen doped titanium dioxide. In the manufacturing method of the present disclosure, the deep eutectic solution formed by choline chloride and urea may be used as a solvent, and may also be used as a carbon source and/or a nitrogen source. Therefore, titanium dioxide may be doped with carbon and/or nitrogen during the formation process.

Abstract: The invention relates to a process for the preparation of nanoparticles of MoS2 supported on TiO2 wherein the preparation is performed by reductive coprecipitation using aqueous solutions containing Ti and Mo precursor salts, and wherein MoS2 may be non-promoted or Co-promoted. Further, the invention relates to the use of said nanoparticles as hydrodesulfurization catalysts.

Abstract: The disclosure relates to a method for forming a conformal coating on a substrate having a topography presenting a relief. One method of the disclosure includes setting the temperature of the substrate within the range 140-275° C., and coating an aqueous solution including a sol-gel precursor on said substrate. The disclosure also relates to a method for fabricating a battery, a capacitor, a catalyst, a photovoltaic cell or a sensor using such a method, and to an aqueous solution for use in such a method.

Abstract: A robust sunscreen composition is disclosed herein comprising a water soluble polymer and a water insoluble film former providing a synergistic effect in SPF retention and critical wavelength after immersion in water, salt water, and chlorinated water. The water soluble polymer comprises poloxamer 338 (and) PPG-12/SMDI copolymer, poloxamer 407 (and) PPG-12/SMDI copolymer, or a combination thereof.

Abstract: The present disclosure relates to modified textile material, wherein the modification is carried out by treating textile material with Hydroxyapatite. Such modified textile materials show bacterio-repulsion by preventing bacteria from attaching to their surfaces, thereby preventing malodor formation. The present disclosure also relates to process for obtaining the modified textile material as well as use of Hydroxyapatite as a bacterial repellent agent for preparing odor free textile material.

Abstract: A process operating at super-atmospheric pressure for leaching a titanium containing ore with an HCl and producing titanium dioxide with integrated steps of solvent extraction for removing iron from the leached ore and solvent extraction of a resulting titanium enriched raffinate to produce particles suitable for finishing into pigment grade TiO2. The process can integrate the recovery of HCl from both solvent recovery steps and the recovery of solvent. The process also produces commercial grade ferric chloride.

Abstract: The method of fabricating a photocatalyst for water splitting includes electrospinning a Zn-based solution mixed with CdS nanoparticles and then calcining to produce CdS nanoparticle decorated ZnO nanofibers having significant photocatalytic activity for water splitting reactions. The photocatalyst fabricated according to the method can produce H2 at a rate of 820 ?molh?1g?1 catalyst from aqueous solution under light irradiation.

Abstract: Photocatalysts for reduction of carbon dioxide and water are provided that can be tuned to produce certain reaction products, including hydrogen, alcohol, aldehyde, and/or hydrocarbon products. These photocatalysts can form artificial photosystems and can be incorporated into devices that reduce carbon dioxide and water for production of various fuels. Doped wide-bandgap semiconductor nanotubes are provided along with synthesis methods. A variety of optical, electronic and magnetic dopants (substitutional and interstitial, energetically shallow and deep) are incorporated into hollow nanotubes, ranging from a few dopants to heavily-doped semiconductors. The resulting wide-bandgap nanotubes, with desired electronic (p- or n-doped), optical (ultraviolet bandgap to infrared absorption in co-doped nanotubes), and magnetic (from paramagnetic to ferromagnetic) properties, can be used in photovoltaics, display technologies, photocatalysis, and spintronic applications.

Abstract: A titanium oxide particle includes bonded thereon a metal-containing compound which has a hydrocarbon group, wherein the titanium oxide particle has an absorption at 450 nm and 750 nm in a visible absorption spectrum, and with respect to a surface of the particle, an element ratio M/Ti between metal M of the metal-containing compound and titanium is from 0.1 to 0.4 and an element ratio C/Ti between carbon C and titanium is from 0.3 to 1.2.

Abstract: A process is provided for the preparation of lacing resistant, titanium dioxide particles for use in photodurable thin film production. Said process involves dewatering titanium dioxide particles that have been encapsulated with a layer of amorphous alumina in continuous fashion at temperatures in excess of 100° C.

Abstract: A titanium oxide compound according to the present invention comprises bronze-type titanium oxide or titanium oxide mainly composed of bronze-type titanium oxide, and contains calcium and/or silicon. The titanium oxide compound contains 0.005 to 2.5 mass % inclusive of calcium or 0.15 to 0.55 mass % inclusive of silicon, or contains 0.005 to 1.2 mass % inclusive of calcium and 0.15 to 0.2 mass % inclusive of silicon, or contains 0.005 to 0.1 mass % inclusive of calcium and 0.15 to 0.5 mass % inclusive of silicon.

Abstract: The invention relates to compositions which contain polyorganosiloxanes, a hydrosilylation catalyst, an inhibitor or moderator and doped pyrogenic titanium dioxide, to the use thereof for applying protective coatings to an electrical or electronic component or device and to the protective coatings as such.

Abstract: The present invention provides a process and catalyst for the direct and selective conversion of ethane to ethylene. The process provides a direct single step vapor phase selective dehydrogenation/oxidative dehydrogenation of ethane to ethylene over Mo supported nanocrystalline TiO2. The process provides ethane conversion of 65-96% and selectivity of ethylene up to 100%. The process may be conducted in the presence or absence of oxygen.

Abstract: Titanium dioxide and an electro-conductive titanium oxide which each includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 ?m and in which particles having a major-axis length of 10 ?m or longer account for 15 wt. % or more of all the particles. A solution of a tin compound and a solution of compounds of antimony, phosphorus, etc.

Abstract: A thin film circuit includes a thin film transistor with a metal oxide semiconductor channel having a conduction band minimum (CBM) with a first energy level. The transistor further includes a layer of passivation material covering at least a portion of the metal oxide semiconductor channel. The passivation material has a conduction band minimum (CBM) with a second energy level. The second energy level being lower than, equal to, or no more than 0.5 eV above the first energy level. The circuit is used for an electronic device including any one of an AMLCD, AMOLED, AMLED, AMEPD.

Abstract: Disclosed is a photocatalyst, and methods for its use, that includes a photoactive material comprising a photonic band gap and an electronic band gap, wherein the photonic band gap at least partially overlaps with the electronic band gap, and an electrically conductive material deposited on the photoactive material.

Abstract: Ordered acicular aggregates of elongated TiO2 crystallites which resemble nano-sized flower bouquets and/or triangular funnels, and process for their preparation by thermally hydrolyzing a soluble TiO2 precursor compound in aqueous solution in the presence of a morphology controlling agent selected from carboxylic acids and amino acids.

Abstract: Embodiments of the present disclosure provide for multi-component metal-organic materials (MOMs) systems that exhibit permanent porosity and using MOMs to separate components in a gas mixture, methods of separating polarizable gases from a gas mixture, and the like.

Abstract: Digestion of a laterite ore with sulfuric acid dissolves all constituents except silica. The resulting sulfates—aluminum sulfate, ferric sulfate, titanyl sulfate, and magnesium sulfate—remain in solution at approximately 90° C. Hot filtration separates silica. Solution flow over metallic iron reduces ferric sulfate to ferrous sulfate. Controlled ammonia addition promotes hydrolysis and precipitation of hydrated titania from titanyl sulfate that is removed by filtration. Continued addition of ammonia forms ferrous ammonium sulfate and ammonium aluminum sulfate solutions. Alum is preferentially separated by crystallization. Ammonia addition to ammonium alum solution precipitates aluminum hydroxide, leaving ammonium sulfate in solution. The remaining iron rich liquor also contains magnesium sulfate. The addition of oxalic acid generates insoluble ferrous oxalate which is thermally decomposed to ferrous oxide and carbon monoxide which is used to reduce the ferrous oxide to metallic iron.

Abstract: Present disclosure provides a process for the synthesis of visible light responsive doped titania photocatalysts. The process involves step a) milling a mixture containing titania and a precursor compound, the compound selected from the group consisting of chloroauric acid and a mixture containing chloroauric acid and silver nitrate, in the presence of water and oxide milling media, at a temperature in the range of 20 to 50° C. for a period of 60-120 minutes, to form a slurry, wherein the amount of water is in the range of 15 to 25% by weight of the total mixture; and b) filtering the slurry to separate the oxide milling media and obtain a filtrate containing doped titania nanoparticles.

Abstract: A copper compound-carried titanium oxide photocatalyst which is excellent in a photocatalytic activity and a viral inactivation property and a production process for the same can be provided by a copper compound-carried titanium oxide photocatalyst comprising titanium oxide in which a content of rutile type titanium oxide is 50% by mole or more and a monovalent copper compound and a divalent copper compound which are carried on a surface of the titanium oxide described above and a production process for a copper compound-carried titanium oxide photocatalyst, comprising a step of carrying a monovalent copper compound and a divalent copper compound on a surface of titanium oxide in which a content of rutile type titanium oxide is 50% by mole or more.

Abstract: The invention provides a process for producing an aqueous dispersion of particles of rutile titanium oxide, which comprises: a first step in which after a chloride ion concentration of an aqueous solution of titanium tetrachloride is adjusted to 0.5 mole/L or more and less than 4.4 mole/L, the aqueous solution of titanium tetrachloride is heated at a temperature in a range of from 25° C. to 75° C.

Abstract: A one-pot synthesis of Nb5+-doped TiO2 nanoparticles (NPs) with low cost and high efficiency for dye sensitized solar cells (DSSCs) is disclosed in the present invention. The Nb5+-doped TiO2 NPs with Nb dopants of 0˜5 mol % are prepared by directly mixing TiO2 slurry with Nb2O5 gel obtained by UV treatment of a mixture of NbCl5 powder, ethanol and water in a certain ratio, following by heat treatment without using hydrothermal method. The as-prepared NPs exhibit well-crystallized pure anatase TiO2 phase with uniform particle distribution. The incorporation of Nb5+ leads to a stronger and broader light absorption in visible light range and a decrease of band gap with increasing Nb dopant content, which enhances the efficiencies of light-harvesting and electron injection and suppresses the charge recombination. The present method provides a simple and cost-effective mass-production route to synthesize n-type metallic ion doped TiO2 nanoparticles as excellent photoanode materials.

Abstract: Some embodiments include methods of forming charge-trapping zones. The methods may include forming nanoparticles, transferring the nanoparticles to a liquid to form a dispersion, forming an aerosol from the dispersion, and then directing the aerosol onto a substrate to form charge-trapping centers comprising the nanoparticles. The charge-trapping zones may be incorporated into flash memory cells.

Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

Abstract: The present invention relates to a process for the preparation of materials with nanometric dimensions and controlled shape, based on titanium dioxide. The invention also relates to a process for the preparation of titanium dioxide nanorods and nanocubes with anatase phase composition, which are highly suitable for photocatalytic use, in particular for applications involving photovoltaic cells, for example Dye Sensitized Solar Cells (DSSC), photoelectrolysis cells and tandem cells for the conversion of solar energy and the production of hydrogen.

Abstract: A photovoltaic cell and method of forming the cell includes providing an electroformed metallic article having a plurality of electroformed elements that form a free-standing, unitary piece. The metallic article has gridlines that are spaced apart at a pitch PM. A semiconductor substrate has a top surface with a plurality of silver, where at least one of the silver patterns comprises pattern segments spaced apart at a pitch PS. The pattern segments have a length LS defined by the equation LS=PM?k*PS/2, k being a value from 1.0 to 1.4. The metallic article is coupled to the semiconductor substrate, in which a first electroformed element in the plurality of electroformed elements is coupled to a first silver pattern in the plurality of silver patterns.

Abstract: A domestic appliance includes at least one component having a surface that can become laden with organic dirt. The surface includes a photocatalyst and is made from a primary-formed first material in which the photocatalyst is dispersed. A photoradiation source is provided for irradiating the photocatalyst with an activating electromagnetic radiation.

Abstract: The present invention relates to a process for manufacturing low-dusting, smoothly-discharging, easily dispersible, powders such as pigmentary titanium dioxide that resist compaction, aging, lumping, and/or caking. Particularly, the present invention relates to a process for treating powders such as pigmentary titanium dioxide with ammonia or a similarly basic substance prior to or during agglomeration to produce a powder with improved bulk handling properties.

Abstract: Titanium dioxide and an electro-conductive titanium oxide which each includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 ?m and in which particles having a major-axis length of 10 ?m or longer account for 15 wt. % or more of all the particles. A solution of a tin compound and a solution of compounds of antimony, phosphorus, etc.

Abstract: A method for producing isolatable oxide microparticles or hydroxide microparticles using an apparatus that processes a fluid between processing surfaces of processing members that are arranged opposite each other so as to be able to approach to or separate from each other and such that at least one can rotate relative to the other. At least two fluids are mixed and oxide microparticles or hydroxide microparticles are separated, said two fluids including: a fluid containing a microparticle raw material solution comprising a microparticle raw material mixed into a solvent, and a fluid containing a microparticle-separation solution.

Abstract: The present invention disclosed use of lactam as a solvent in the preparation of nanomaterials by precipitation method, sol-gel method or high temperature pyrolysis. These methods are able to recycle lactam solvent, which meet requirements of environmental protection.

Abstract: Disclosed are: a visible-light-responsive titanium oxide microparticle dispersion comprising an aqueous dispersion medium and titanium oxide microparticles dispersed therein, and a peroxotitanium component, an iron component and/or a copper component and a tin component, wherein the content of the peroxotitanium component is 0.1 to 20 mass % relative to the titanium oxide content; and a process for producing a visible-light-responsive titanium oxide microparticle dispersion, comprising (1) producing peroxotitanic acid containing a tin compound from a raw material titanium compound, a tin compound and hydrogen peroxide, (2) heating an aqueous solution of peroxotitanic acid containing the tin compound to 80 to 250° C.

Abstract: The present invention relates to spherical beads comprising at least one metal and/or semimetal oxide, having a mean diameter in the range from 10 to 120 ?m, a BET surface area in the range from 400 to 800 m2/g and a pore volume in the range from 0.3 to 3.0 cm3/g, wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average diameter of said bead and the surface of said bead is substantially smooth, and also to a process for producing these spherical beads, to a particulate catalyst comprising the spherical beads and to the use of the spherical beads as catalysts or catalyst carriers.

Abstract: A Rutile-type titanium dioxide having a rectangular particulate form configured such that major axial planes of rod-shaped particles having a minor axis diameter of 3 to 10 nm are oriented and aggregated in the minor axial direction, and a rod-shaped rutile-type titanium dioxide obtained by treating the rectangular rutile-type titanium dioxide with heat, wherein an apparent average major axial length of the oriented and aggregated particles is 100 to 400 nm, an apparent average minor axial length thereof is 30 to 150 nm, an apparent average axial ratio represented by apparent average major axial length/apparent average minor axial length is 2 to 5 and a specific surface area thereof is 10 to 100 m2/g.

Abstract: Compositions and methods of making are provided for treated mesoporous metal oxide microspheres electrodes. The compositions include microspheres with an average diameter between about 200 nanometers and about 10 micrometers and mesopores on the surface and interior of the microspheres. The methods of making include forming a mesoporous metal oxide microsphere composition and treating the mesoporous metal oxide microspheres by at least annealing in a reducing atmosphere, doping with an aliovalent element, and coating with a coating composition.

Abstract: The present invention relates to a coating composition containing metal oxide particles with a high refractive index and low photocatalytic activity and a coating film obtained by applying the coating composition onto a substrate. The coating composition contains metal oxide particles with a high refractive index obtained by coating the specific fine particles of the titanium-based oxide on their surfaces with at least a silica-based oxide or a silica-based composite oxide, and the coating film is obtained by applying the coating composition onto a substrate. The metal oxide particles with not only a high refractive index but also low photocatalytic activity, and therefore a coating film with excellent weathering resistance and light resistance can be formed on a substrate.

Abstract: The present invention relates to the preparation of a mesoporous substantially pure anatase titanium oxide (meso-TiO2) and its use in electrochemical devices, in particular lithium-ion batteries.

Abstract: TiO2 nanoparticles having improved consistent particle morphology, uniform particle size, and which contain uniform intra-particle pores in the mesopore size range are produced by wet chemical hydrolysis.

Abstract: The present invention is related to a family of Group 4 metal precursors represented by the formula: M(OR1)2(R2C(O)C(R3)C(O)OR1)2 wherein M is a Group 4 metals of Ti, Zr, or Hf; wherein R1 is selected from the group consisting of a linear or branched C1-10 alkyl and a C6-12 aryl, preferably methyl, ethyl or n-propyl; R2 is selected from the group consisting of branched C3-10 alkyls, preferably iso-propyl, tert-butyl, sec-butyl, iso-butyl, or tert-amyl and a C6-12 aryl; R3 is selected from the group consisting of hydrogen, C1-10 alkyls, and a C6-12 aryl, preferably hydrogen. In a preferred embodiment of this invention, the precursor is a liquid or a solid with a melting point below 60° C.

Abstract: The present invention relates to a method for tuning shape, exposed crystal face and size of titanium dioxide by using inorganic salts and changing pH value of the reaction environment. The present invention changes the shape of titanium dioxide crystal and the exposed face thereof by adding different inorganic salts during the reaction to utilize different alkali metal ions of the inorganic salts and also can change the size of titanium dioxide crystal by tuning different pH value in the reaction. By this synthesis method, the shape and size of titanium dioxide can be tuned for different applications, such as photocatalysis, dye-sensitized solar cells, photolysis of water and other optoelectronic components or materials, to achieve their optimal efficiencies.

Abstract: The invention provides a process for producing a mesoporous single crystal of a semiconductor, wherein the shortest external dimension of said single crystal, measured along any of the crystallographic principal axes of said single crystal, is x, wherein x is equal to or greater than 50 nm, which process comprises growing a single crystal of a semiconductor within a mesoporous template material until said shortest external dimension of the single crystal is equal to or greater than x. Further provided is a mesoporous single crystal obtainable by the process of the invention. The invention also provides a mesoporous single crystal of a semiconductor, wherein the shortest external dimension of said single crystal measured along any of the principal axes of said single crystal is equal to or greater than 50 nm. Further provided is a composition comprising a plurality of mesoporous single crystals of the invention. The invention also provides a semiconducting layer of a mesoporous single crystal of the invention.

Abstract: According to one embodiment, a negative electrode active material for nonaqueous electrolyte battery includes a titanium oxide compound having a crystal structure of monoclinic titanium dioxide. When a monoclinic titanium dioxide is used as the active material, the effective capacity is significantly lower than the theoretical capacity though the theoretical capacity was about 330 mAh/g. The invention comprises a titanium oxide compound which has a crystal structure of monoclinic titanium dioxide and a (001) plane spacing of 6.22 ? or more in the powder X-ray diffraction method using a Cu—K? radiation source, thereby making an attempt to improve effective capacity.

Abstract: The invention relates to a method for preparing a colloidal nanoparticle solution, including: (a) dissolving a titanium-oxide precursor, referred to as a precursor, in one or more solvents, referred to as precursor solvents; and (b) chemically converting, preferably by means of hydrolysis, said titanium-oxide precursor and said precursor solvent into a colloidal-solution solvent so as to form titanium-oxide nanoparticles that are dispersed in the colloidal-solution solvent, said colloidal solution having a dynamic viscosity of between 4 and 54 cP at 20° C. and 101,325 Pa. The invention also relates to a colloidal titanium-oxide nanoparticle solution containing a dispersion of titanium-oxide nanoparticles in a solvent or system of solvents, the viscosity of which is between 4 and 54 cP, said solution being particularly obtainable according to the method of the invention, as well as to the uses thereof, in particular for preparing photovoltaic cells.

Abstract: The present invention relates to new precast cementitious products with photocatalytic activity, and to a process to obtain them.

Abstract: Ordered acicular aggregates of elongated TiO2 crystallites which resemble nano-sized flower bouquets and/or triangular funnels, and process for their preparation by thermally hydrolyzing a soluble TiO2 precursor compound in aqueous solution in the presence of a morphology controlling agent selected from carboxylic acids and amino acids.

Abstract: An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

Abstract: The invention relates to a method of forming (rutile) titanium dioxide-coated platelet-like pigments in which hydrous titanium dioxide is deposited on platelet-like particles followed by calcining, comprising (a) effecting the titanium deposit in the presence of an ?-hydroxy carboxylic acid, especially glycolic acid, or oxalic acid, and an amino acid, especially glycine, alanine, valine, aspartic acid (?-, ?- and ?-form); or an amino acid; to the pigments obtained by the method and the use thereof. The method can work in the absence of exogenous metal and Ti(III). The rutile TiO2-coated substrate of the present invention has at least the same advantages and characteristics of a tin containing product which includes luster, color, color homogeneity and few small particle formation during manufacture.

Abstract: Compositions and methods of making are provided for treated mesoporous metal oxide microspheres electrodes. The compositions comprise (a) microspheres with an average diameter between 200 nanometers (nm) and 10 micrometers (?m); (b) mesopores on the surface and interior of the microspheres, wherein the mesopores have an average diameter between 1 nm and 50 nm and the microspheres have a surface area between 50 m2/g and 500 m2/g, and wherein the composition has an electrical conductivity of at least 1×10?7 S/cm at 25° C. and 60 MPa. The methods of making comprise forming a mesoporous metal oxide microsphere composition and treating the mesoporous metal oxide microspheres by at least one method selected from the group consisting of: (i) annealing in a reducing atmosphere, (ii) doping with an aliovalent element, and (iii) coating with a coating composition.

Abstract: The present invention relates to titanium dioxide nanoparticles, titanate, lithium titanate nanoparticles, and preparation methods thereof. According to the present invention, titanium dioxide nanoparticles having a quasicrystalline phase corresponding to an intermediate form between a crystalline phase and an amorphous phase may be provided.